Abstract: The invention provides aqueous resin emulsion containing a resin obtained by reaction of a composition containing at least: at least one polyhydric alcohol having at least two hydroxyl groups, at least one polyetherpolyol having a molecular weight of 400 to 8000 g/mol, at least one monobasic carboxylic acid, and at least one polybasic carboxylic acid having at least two carboxyl groups or its anhydride, to form a resin and the resin emulsion is modified by providing basic groups. The invention further relates to a process for preparing a resin, to a resin as obtained by the process and to a coating film obtained from the resin emulsion.

Abstract: The invention discloses an acrylic acid-modified epoxy polyester resin and the preparation process thereof. The resin comprises 100 pbw of a copolymer (A) formed from an unsaturated fatty acid-modified polyester and a bisphenol A type epoxy resin, and 20-40 pbw of poly(meth)acrylic acid (ester) (B). The preparation process comprises the following steps: (1) alcoholyzing a drying oil with a polyol; (2) adding successively, to the product from step (1), a dibasic anhydride, a fatty acid containing a conjugated double bond and an epoxy resin, and esterifying to obtain an epoxy polyester; and (3) copolymerizing the epoxy polyester from step (2) and an acrylic monomer. This invention also provides a water-based emulsion containing said resin, and a water-based paint exhibiting excellent antirust property and having low production cost.

Abstract: An aqueous emulsion of a resin which includes as an emulsifier at least one compound of the formula (I): R1—CO—NR2R3 wherein R1 is a polyunsaturated hydrocarbyl group; R2 is a polyhydroxy hydrocarbyl radical; and R3 is hydrogen, a hydrocarbyl, particularly alkyl, group, a hydroxy or hydrocarbyloxy substituted hydrocarbyl, particularly hydroxy or alkoxy substituted alkyl, or is a group defined for R2. The resin is preferably an alkyd resin, and the emulsions are particularly useful for incorporating into paints.

Abstract: This invention relates to a process of preparing vesiculated granules of crosslinked carboxylated polyester resin utilising a particular class of non-alkylphenolethoxylate surfactant.

Abstract: A method of making a sterile adhesive composition includes placing a mixture of a polymerizable adhesive monomer and a thickening agent in a container, sealing the container, and sterilizing the mixture and the container. The method provides superior viscosity for the monomer composition. An adhesive composition includes 2-octyl cyanoacrylate and at least one thickener. The sterile adhesive composition is particularly useful as a medical adhesive and can comprise 1,1-disubstituted ethylene monomers, such as &agr;-cyanoacrylates.

Abstract: The present invention relates to a binder composition including a polymer formed from at least one vinyl type monomer and at least one water dispersible polyester-ionomer.

Abstract: A method of making a sterile adhesive composition includes placing a mixture of a polymerizable adhesive monomer and a thickening agent in a container, sealing the container, and sterilizing the mixture and the container. The method provides superior viscosity for the monomer composition. The sterile adhesive composition is particularly useful as a medical adhesive and can comprise 1,1-disubstituted ethylene monomers, such as &agr;-cyanoacrylates.

Abstract: The present invention provides adhesive compositions which include free radical polymerizable compounds and a redox catalyst system to accelerate polymerization thereof. The redox catalyst includes an aniline derivative substituted in the para position by halogen as an accelerator. The use of para-halogenated aniline derivatives as an accelerator in the cure of free radical polymerizable compounds results in good bond strength and greatly improved surface cure of the adhesive composition.

Abstract: A binder mixture for stoving lacquers comprising A) at least one alkyd resin; and B) at least one poly-N-acyl alkyleneimine prepared by cationic polymerization of a monomer mixture ofa) from 10 to 90% by weight of at least one monomer corresponding to formula (I): ##STR1## in which Z is a direct bond or the group CR.sup.5 R.sup.6, R.sup.1 to R.sup.4 can be the same or different and represent H or a C.sub.1-8 alkyl group, R.sup.5 and R.sup.6 can be the same or different and represent H or a C.sub.1-2 alkyl group, R.sup.7 is a hydroxyl-containing alkyl or alkylene group of a hydroxycarboxylic acid containing 2 to 32 carbon atoms,b) from 90 to 10% by weight of at least one monomer corresponding to formula (II): ##STR2## in which Z and R.sup.1 to R.sup.6 are as defined above and R.sup.8 is the radical of an aromatic monocarboxylic acid, andc) from 0 to 80% by weight of at least one monomer corresponding formula (III): ##STR3## in which Z and R.sup.1 to R.sup.6 are as defined above, and R.sup.

Abstract: A coating composition for the attenuation of the reflection electromagnetic radiation and particularly electromagnetic radiation have a wavelength of greater than 800 nm including the near infrared is described. The composition comprises a chromophore capable of absorbing up to about 95% of the electromagnetic radiation having a wavelength greater than 800 nm. Optionally, the composition may comprise microbeads that serve the purpose of also scattering the electromagnetic radiation.

Abstract: An alkyd composition which is one of an aqueous emulsion or an aqueous microemulsion and which is autoxidatively drying, including an alkyd which is autoxidatively-drying; and an emulsifier which at least partly consists of an alkoxylate of monoalkanolamide of the general formula: ##STR1## wherein R is a polyunsaturated alkyl group having 7-23 carbon atoms, X is an alkyleneoxy group derived from an alkylene oxide having 2-3 carbon atoms, m is 2-4, and n is 2-30.

Abstract: This invention includes new water-dilutable binder mixtures based on alkyd resins modified by poly{ethylene glycol} and poly{N-acyl alkylene imines}, a process for preparing such binder mixtures, and the use of such binders in oxidatively drying paints and varnishes.

Abstract: This invention relates to high solids alkyds, non-aqueous dispersions, and coating compositions containing those alkyds and non-aqueous dispersions, having non-volatile materials contents greater than about 75% NVM, with very low volatile organic contents of less than 305 g/l, which exhibit excellent stability, viscosity and tack-free and dry times when formulated as air dry coating compositions.

Abstract: Chemically treated glass fibers of the present invention provide good processing properties in reinforcing thermosetting polymers while resulting in fiber reinforced thermosetting materials having good strength properties. The chemically treated glass fibers have a dried residue of an aqueous chemical treating composition having: two film forming polymers, at least an acryloxy alkyl trialkoxysilane, a fiber lubricant and polyester curing agent and water. One film forming polymer is a polyvinylacetate copolymer having a low solubility in acetone and the other film forming polymer is unsaturated, curable, essentially linear polyester polymer. The fiber lubricant is a nonionic polyethylene-containing polymer or a cationic lubricant like polyalkylene polyamine polyamino amide, and partially amidated polyalkylenimines and mixtures thereof present in an effective lubricating amount.

Abstract: An additive composition for enhancing curing and color clarity properties of polyester resins. The additive comprises from about 50 to 75 parts by weight of a mercaptan, and from about 50 to about 25 parts by weight of a quaternary ammonium salt. From about 0.5 to about 25 parts by weight of a polymerization initiator can be incorporated into the additive when the polyester resin is utilized as a gel coat. Resinous compositions formulated with the additive consist essentially of from about 50 to about 99.5 parts by weight of a polyester resin, from about 0.5 to about 35 parts by weight of the mercaptan, from about 0.1 to about 15 parts by weight of the quaternary ammonium salt, and a minor effective amount of an oxidizing agent for the polyester resin.

Abstract: Chrome-free aqueous size compositions containing quanternary salts reduce fuzz and fly in glass fiber gun roving. The roving particularly achieves a desirable ease and completeness of chopping in conventional chopping and spraying equipment for molding operations.

Abstract: The invention relates to the use of novel N,N-disubstituted arylamines containing polymerizable groups as hardening accelerators for polymerizable compositions based on unsaturated polyester resins, in particular for trowelling and water compositions.

Abstract: Chrome-free aqueous size compositions containing quanternary salts reduce fuzz and fly in glass fiber gun roving. The roving particularly achieves a desirable ease and completeness of chopping in conventional chopping and spraying equipment for molding operations.

Abstract: An aqueous size composition has been developed for glass fibers produced for molded products having appearance surfaces known as Class A surfaces. The size contains a cure stable polyester emulsion and a static insensitive lubricant system. The resulting coated glass fibers are especially useful in improving processability and product uniformity of SMC applications.

Abstract: Novel .alpha.-aminoacetamides are powerful stabilizers for organic materials subject to oxygen and heat degradation, and particularly for synthetic natural rubber, synthetic ester lubricants and synthetic resinous materials. A wide range of substituents on the amine and amide N atoms, at least one of which substituents is an alkylene imine (cyclic), and an even wider range of substituents on the saturated carbon atom, yields an array of stabilizers having a wide range of compatibility in compositions comprising various synthetic resinous compounds to be stabilized.Novel syntheses are provided utilizing at least one amine nucleophilic agent, a trichloromethide ion generating agent, and an alkoxide ion generating agent, which together in the presence of aqueous alkali and an onium salt, yield novel .alpha.-aminoacetamides in which a wide choice of substituents may be introduced. The nucleophilic agent may be a primary or secondary amine, or one of each. The trichloromethide ion generating agent is a haloform.

Abstract: Rapid cure polymerizable monomer sealing and bonding compositions are disclosed. The polymerizable compositions comprise at least one polymerizable acrylate monomer system comprising a urethane acrylate monomer having vinyl reactive ends, and at least one hydroxy-terminated, monofunctional, short chain monomer which is soluble in or miscible with the urethane acrylate monomer; an effective amount for initiation of a free radical initiator; and a compatible filler material.

Abstract: Non-gelled resins formed by reacting an ethylenically unsaturated polyester with ethylenically unsaturated monomers which include an ethylenically unsaturated acid are provided which are useful in coatings having better stability.

Abstract: Chrome-free aqueous sizing composition for glass fiber gun roving contains a mixture of emulsified film-forming polymers, titanium acetyl acetonate, silylated polyazamide, cationic lubricant and methacryloxypropylsilane.

Abstract: An aerosol paint system under sprayable pressures in the container is provided comprising two film-forming polymeric binders. One of the two being monomer modified alkyd resin of relatively low molecular weight having an acid value (before neutralization with selected bases) of about 40 to 80 and the second polymeric binder of water-reducible nature being an emulsion polymer latex of high molecular weight, but capable of forming a continuous film in the total aerosol paint system aided by the monomer modified alkyd and a selection from co-solvents including in a first group low molecular weight alcohols, ketones, and esters and in a second group the co-solvents illustrated by the Cellosolves, Cellosolve acetates and other esters and the Carbitols as to chemical class.Pressures essential to spray application are principally provided by dimethyl ether and closely related ethers as a class.

Abstract: The crosslinking of unsaturated polyester resins at room temperature in the presence of a peroxyester initiator is accelerated by a mercapto compound and a metal salt wherein the metal is selected from the group consisting of copper, and iron, or a mixture of the metal salts.

Abstract: A method for the uniform blending of additives into thermoplastic synthetic resins. A solution or finely divided dispersion of the additive is produced in a polymerizable cyclic ester of the general formula: ##STR1## wherein R represents respectively hydrogen or an alkyl group of 1-18 carbon atoms,A represents a --O-- or --COO-- group,x and y represent integers from 1 to 15, andz represents 0 or 1.This solution or dispersion, optionally after polymerization of the cyclic ester, is admixed to the thermoplastic synthetic resin at the end of its manufacturing process or in a subsequent processing stage.