Contains Solid Polymer Derived From Ethylenic Reactants Only, One Of Which Contains Chalcogen; Or Solid Polymer Reacted With Ethylenic Reactant Containing Chalcogen Patents (Class 523/523)
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Patent number: 11566130Abstract: The disclosure relates to light barrier compositions, methods of making the compositions, articles prepared from the compositions, and methods of making the articles. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: GrantFiled: November 30, 2016Date of Patent: January 31, 2023Assignee: PLASTIPAK PACKAGING, INC.Inventor: Shenshen Li
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Patent number: 10843445Abstract: A sheet-shaped matched-type electromagnetic wave absorber can obtain electromagnetic wave absorption performance with a relatively small thickness but has a problem that particularly a dimensional change in an electromagnetic wave absorption layer (resin composition layer) has a large influence on the electromagnetic wave absorption performance when being exposed to a high temperature. By laminating a resin composition layer in which a filler with an aspect ratio of 5 or more and a filler with an aspect ratio of less than 5 are dispersed and fixed with an electromagnetic wave reflection layer in a cured product of a resin composition containing an acrylic polymerizable resin and a polymerization initiator, it is possible to provide a matched-type electromagnetic wave absorber having high heat resistant dimensional stability and high electromagnetic wave absorption performance.Type: GrantFiled: November 22, 2016Date of Patent: November 24, 2020Assignee: Tomoegawa Co., Ltd.Inventors: Takeshi Hashimoto, Takuma Hattori, Kojiro Tsuruta
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Patent number: 8975331Abstract: The present invention relates to a waterborne polyurethane containing biodegradable segments and the process for synthesizing the same. The waterborne polyurethane according to the present invention has excellent biodegradable, biocompatible and mechanical characteristics and thus is a useful biomedical material, in particular for making films for medical applications.Type: GrantFiled: October 25, 2011Date of Patent: March 10, 2015Assignees: Great Eastern Resins Industrial Co., Ltd., National Chung Hsing UniversityInventors: Shenghong A. Dai, Chien-Wen Chen, You-Sing Chen, Shan-Hui Hsu
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Patent number: 8883884Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a polymer blend comprising a copolymer and an additional polymer, the copolymer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer immiscible with the backbone; the additional polymer consisting of a polymer miscible with the polymeric sidechains.Type: GrantFiled: November 27, 2012Date of Patent: November 11, 2014Assignee: The Goodyear Tire & Rubber CompanyInventors: Liqing Ma, Robert Fokko Roskamp, Ralf Mruk, Frank James Feher, Bruce Raymond Hahn
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Patent number: 8765844Abstract: A manufacturing method of rubber composition for tire tread or the other, which is comprised of adding 30-110 mass parts of silica powders to 100 mass parts of diene rubber component and adding silane coupling agent by 3-15 mass % of the silica powders, comprising: preparing hetero-modified SBR having hetero atom functional group; a first kneader-mixing step, in which 60-85 mass parts of the diene rubber component including no less than 20 mass % of the hetero-modified SBR is mixed in a kneader device with substantially all of the reinforcing fillers; taking out of obtained mixture to give a master batch; and second kneader-mixing step, in which the master batch is mixed substantially solely with remaining mass parts of the diene component.Type: GrantFiled: February 6, 2012Date of Patent: July 1, 2014Assignee: Toyo Tire & Rubber Co., Ltd.Inventor: Yuki Masumoto
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Publication number: 20140031457Abstract: Disclosed is a process for the manufacture of a polyalkylene terephthalate such as polybutylene terephthalate. In particular, the process comprises employing a titanium-containing catalyst formed by the reaction product of tctraalkyl titanate and a complexing agent comprising a phosphorous, nitrogen or boron atom. The process is used to prepare polyalkylene terephthalates characterized by improved hydrostability, as well as compositions derived therefrom.Type: ApplicationFiled: July 25, 2013Publication date: January 30, 2014Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: HUSNU ALP ALIDEDEOGLU, Tianhua Ding, Ganesh Kannan
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Patent number: 8198348Abstract: A coating composition including an unsaturated resin selected from polyesters, alkyds or combinations thereof; an alkoxy (meth)acrylic functional monomer, and a thermoplastic compound containing active hydrogen groups; a curing agent; and a curing promoter such as at least one metal drier.Type: GrantFiled: April 21, 2011Date of Patent: June 12, 2012Assignee: Valspar Sourcing, Inc.Inventors: Shaobing Wu, Larry B. Brandenburger
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Patent number: 7951856Abstract: A coating composition including an unsaturated resin selected from polyesters, alkyds or combinations thereof; an alkoxy(meth)acrylic functional monomer, and a thermoplastic compound containing active hydrogen groups; a curing agent; and a curing promoter such as at least one metal drier.Type: GrantFiled: July 13, 2007Date of Patent: May 31, 2011Assignee: Valspar Sourcing, Inc.Inventors: Shaobing Wu, Larry B. Brandenburger
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Publication number: 20100280152Abstract: A thermoformable packaging material, in an exemplary embodiment, includes a thermoplastic composition that includes a polyethylene terephthalate modified with an isophthalic acid co-monomer. The amount of isophthalic acid co-monomer used is sufficient to render the thermoplastic composition RF sealable.Type: ApplicationFiled: April 29, 2009Publication date: November 4, 2010Applicant: Spartech CorporationInventor: Phillip S. Barhouse
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Patent number: 7683109Abstract: A conductive composition comprises a ? conjugated conductive polymer, a dopant composed of polyanion, and at least one crosslinking site forming compound selected from (a) compounds having a glycidyl group and (b) compounds having a hydroxyl group and one selected from the group consisting of allyl, vinyl ether, methacryl, acryl methacrylamide, and acrylamide groups. An antistatic coating material comprises a ? conjugated conductive polymer, polyanion, at least one crosslinking site forming compound selected form the above (a) and (b), and a solvent. An antistatic coating is formed by applying the above-mentioned antistatic coating material. In a capacitor comprising an anode composed of a valve metal porous body; a dielectric layer formed by oxidizing the suds of the anode; and a cathode formed on the dielectric layer, the cathode has a solid electrolyte layer formed by crosslinking complexes of a ? conjugated conductive polymer and a dopant composed of a polyanion.Type: GrantFiled: September 21, 2005Date of Patent: March 23, 2010Assignee: Shin-Etsu Polymer Co., Ltd.Inventors: Kazuyoshi Yoshida, Tailu Ning, Yasushi Masahiro
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Publication number: 20090275678Abstract: A thermoplastic resin composition and a molded article thereof, respectively excellent in flowability and mechanical properties, and, in a preferred mode, also excellent in low warping property, laser transmittance and laser weldability, is obtained by mixing (B) 0.1 to 4 parts by weight of a polyfunctional compound having three or more functional groups, in which at least one of the terminal structures having the functional groups is a structure containing alkylene oxide units, with (A) 100 parts by weight of a thermoplastic resin, and further provides a molded particle thereof. It is preferred that the (A) thermoplastic resin is one or more selected from a polyester resin and polycarbonate resin.Type: ApplicationFiled: June 27, 2007Publication date: November 5, 2009Inventors: Sadanori Kumazawa, Hiroyuki Ohme, Yuki Amano, Takamusa Owaki
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Publication number: 20090182070Abstract: Polyester fibers comprising a polyester resin composition which contains carbon black and comprises trimethylene terephthalate units as the main repeating structural units, and having an average resistivity (P) of 1.0×1012 [?/cm] or lower; and a polyester textile product at least part of which is made of the polyester fibers. The polyester fibers have high conductivity and are highly excellent in conductivity stability to humidity fluctuations. The textile product comprising the polyester fibers has excellent performances, and examples thereof include a fibrous brush.Type: ApplicationFiled: September 22, 2006Publication date: July 16, 2009Applicant: Toray Industries, Inc.Inventors: Kouki Miyazono, Norio Suzuki, Katsuhiko Mochizuki
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Patent number: 7309560Abstract: There is provided a composition for forming anti-reflective coating for use in a lithography process with irradiation light from F2 excimer laser (wavelength 157 nm) which has a high effect of inhibiting reflected light and causes no intermixing with resist layers, and an anti-reflective coating prepared from the composition, and a method of controlling attenuation coefficient of the anti-reflective coating. Concretely, the composition is one containing a polymer compound containing halogen atom for forming anti-reflective coating for use in a lithographic process in manufacture of a semiconductor device. The polymer compound is one which halogen atom is introduced to a main chain thereof and/or a side chain bonded to the main chain. The attenuation coefficient can be controlled by changing the content of halogen atom in the solid content of the composition.Type: GrantFiled: February 14, 2003Date of Patent: December 18, 2007Assignee: Nissan Chemical Industries, Ltd.Inventors: Rikimaru Sakamoto, Ken-ichi Mizusawa
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Patent number: 7256223Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.Type: GrantFiled: January 10, 2005Date of Patent: August 14, 2007Assignee: Michigan State University, Board of TrusteesInventors: Amar K. Mohanty, Lawrence T. Drzal, Brian P. Rook, Manjusri Misra
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Patent number: 7129278Abstract: The overall performance of water-reducible polymer dispersions, more specifically alkyd dispersions, can be substantially improved by utilizing resins derived from acidolysis reaction products of polyalkylene terephthalates and polyalkylene naphthalates. According to this invention, polymer dispersions can be produced from low acid value polymers and yet have good water dispersibility. When an aqueous coating composition is formulated using the dispersion of this invention, a final coating is formed that has good hydrolytic stability, and when blended with a latex, exhibits improved gloss and wet adhesion.Type: GrantFiled: February 16, 2001Date of Patent: October 31, 2006Assignee: The Sherwin-Williams CompanyInventors: Paul M. Kayima, Joseph L. McJunkins, James K. Marlow, Madhukar Rao, Richard F. Tomko, Syed Y. Hasan
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Patent number: 7129286Abstract: A process for preparing an acrylic-modified alkyd resin comprising the steps of: d) preparing a sulfonated alkyd resin product; e) preparing an acrylated fatty acid product; and f) reacting the product of step a) and the product of step b) under appropriate polymerization conditions, and for preparing a waterbome composition on the basis thereof as well as products obtainable by those processes.Type: GrantFiled: November 12, 2001Date of Patent: October 31, 2006Assignee: Hexion Specialty Chemicals, Inc.Inventor: Bernd Kuhneweg
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Patent number: 6869985Abstract: Polymeric materials and products, including sheet flooring materials prepared from the polymeric materials, and processes for preparing the polymeric materials, are disclosed. The polymeric materials include a polylactic acid-based polymer in combination with plasticizer and a compatibilizer, and optionally include a filler. The polymeric material can include between about 30 to about 50 percent by weight polyvinyl chloride, polyethylene glycol, polyglycolide, ethylene vinyl acetate, polycarbonate, polycaprolactone, polyhydroxyalkanoates, or polyolefins modified with polar groups, for example, ionomers. The plasticizer is typically an epoxidized vegetable oil or esterified and epoxidized vegetable oil and is typically present in an amount of between about 10 and about 50% by weight. In some embodiments, the compatibilizer is a polyolefin modified with one or more polar functional groups, and is typically present in an amount of between about 5 and about 10% by weight.Type: GrantFiled: November 26, 2002Date of Patent: March 22, 2005Assignee: AWI Licensing CompanyInventors: Amar Kumar Mohanty, Lawrence T. Drzal, Brian P. Rook, Manjusri Misra
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Patent number: 6841612Abstract: Composite plastic compositions based on the dispersion of selected cross-linked polymers in certain thermoplastic matrices are disclosed. The composite compositions are readily formed and processed by thermal extrusion processes versus conventional casting processes. Preferred composite plastics compositions based on cross-linked poly(alkyl (meth)acrylate) polymers and modified poly(alkyl (meth)acrylate) thermoplastics are especially useful in the preparation of synthetic architectural materials having a mineral-like appearance, such as that of granite.Type: GrantFiled: June 15, 1998Date of Patent: January 11, 2005Assignee: Elf Atochem S.A.Inventors: Shijun Yang, Paul Joseph Keating
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Patent number: 6369136Abstract: The present invention relates to a binder composition including a polymer formed from at least one vinyl type monomer and at least one water dispersible polyester-ionomer.Type: GrantFiled: December 31, 1998Date of Patent: April 9, 2002Assignee: Eastman Kodak CompanyInventors: Louis J. Sorriero, Dinesh Tyagi
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Patent number: 6291575Abstract: This invention relates to a phosphoric acid group-containing non-aqueous dispersion wherein polymer particles are dispersed in a solution of a macromolecular dispersion stabilizer dissolved in an organic solvent, said polymer particle being a particle of polymer comprising a phosphoric acid group-containing polymerizable unsaturated monomeric unit as a constituent component. With use of said phosphoric acid group-containing non-aqueous dispersion, there can be improved interlayer adhesivity between a metallic coating film, which is formed from a leafing type aluminum flake pigment, and another coating film adjacent thereto, without reducing the excellent effects such as dense metallic feeling of the coated surface, a chrome plating-like finish, and strong brightness feeling and strong flip-flop perperties, which are produced by such a metallic coating film.Type: GrantFiled: June 5, 1998Date of Patent: September 18, 2001Assignee: Kansai Paint Co., Ltd.Inventors: Yoshiyuki Yukawa, Yutaka Masuda, Akimasa Nakahata
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Patent number: 6280846Abstract: Curable compositions for making fibre-reinforcement structural composites such as GRP comprise an unsaturated polyester resin base, a co-polymerizable monomer and preferably, one or more performance-enhancing additives. Thixotropy is endowed by 5% by weight or less of an organic amide.Type: GrantFiled: August 20, 1999Date of Patent: August 28, 2001Assignee: Cray Valley LimitedInventors: Paul Darby, Paul Sutton
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Publication number: 20010014713Abstract: This invention relates to a phosphoric acid group-containing non-aqueous dispersion wherein polymer particles are dispersed in a solution of a macromolecular dispersion stabilizer dissolved in an organic solvent, said polymer particle being a particle of polymer comprising a phosphoric acid group-containing polymerizable unsaturated monomeric unit as a constituent component. With use of said phosphoric acid group-containing non-aqueous dispersion, there can be improved interlayer adhesivity between a metallic coating film, which is formed from a leafing type aluminum flake pigment, and another coating film adjacent thereto, without reducing the excellent effects such as dense metallic feeling of the coated surface, a chrome plating-like finish, and strong brightness feeling and strong flip-flop perperties, which are produced by such a metallic coating film.Type: ApplicationFiled: June 5, 1998Publication date: August 16, 2001Inventors: YOSHIYUKI YUKAWA, YUTAKA MASUDA, AKIMASA NAKAHATA
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Patent number: 6255367Abstract: Novel modifying agents contain a sharply-melting crystalline polymer ingredient, preferably a side chain crystalline (SCC) ingredient, and an active chemical ingredient. Such modifying agents, especially when in the form of particles, can be placed in contact with a matrix, will not modify the mix below the crystalline melting point Tp, but will rapidly modify the matrix above Tp. The active chemical ingredient can react with the matrix, catalyze a reaction of the matrix, or inhibit a reaction of the matrix. Particularly useful compositions are polymer precursors which are storage-stable at low temperatures but which are rapidly converted to crosslinked resins when heated to temperatures above Tp, optionally in the presence of light.Type: GrantFiled: December 16, 1998Date of Patent: July 3, 2001Assignee: Landec CorporationInventors: Steven P. Bitler, Ray F. Stewart
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Patent number: 6051633Abstract: This invention relates to high solids, low VOC, low viscosity, filterable, non-gritty non-aqueous dispersions, and coating compositions containing said non-aqueous dispersions.Type: GrantFiled: November 25, 1997Date of Patent: April 18, 2000Assignee: The Sherwin-Williams CompanyInventors: Richard F. Tomko, Madhukar Rao, Mohamad D. Shalati, John D. Kraan
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Patent number: 5972272Abstract: An unsaturated polyester resin composition for molding comprising (A) an unsaturated polyester resin, (B) a thickening agent containing powder of a thermoplastic resin as the effective component thereof in an amount of 20 to 120 parts by weight per 100 parts by weight of the unsaturated polyester resin, (C) a liquid polymerizable monomer in an amount of 30 to 120 parts by weight per 100 parts by weight of the unsaturated polyester resin, and (D) a curing agent; SMC and BMC prepared by adding (E) a reinforcing material to the composition; and a process for molding the SMC and the BMC at a low temperature under a low pressure. The unsaturated polyester resin composition of the present invention can be converted into SMC in a short time. The obtained SMC has an excellent storage stability, can be molded at a low temperature under a low pressure, and provides a molded product exhibiting low shrinkage, excellent surface smoothness, a large strength, and a large modulus.Type: GrantFiled: December 26, 1996Date of Patent: October 26, 1999Assignee: Nippon Zeon Co., Ltd.Inventors: Toshio Nagase, Takeo Kobayashi, Atsushi Tsukamoto
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Patent number: 5962401Abstract: A detergent builder is composed of a maleic acid copolymer having a weight-average molecular weight in a range of from 5,000 to 100,000, wherein a molar ratio of a maleic acid (salt) monomer to total monomers used in a process is in a range of from 0.1 to 0.9. The detergent builder is obtained by a copolymerization reaction of the monomers using a hydrogen peroxide and a persulfate as a polymerization initiator. As such detergent builder has high calcium ion stability constant and desirable property against iron particle deposition, it is suitably used as a detergent composition. The detergent builder may be prepared by granulation with agitation of powders containing the maleic acid copolymer as water-soluble polycarboxylic acid (salt) using a surface active agent.Type: GrantFiled: July 16, 1996Date of Patent: October 5, 1999Assignee: Nippon Shokubai Co., Ltd.Inventors: Shigeru Yamaguchi, Yoshihiro Maeda
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Patent number: 5929142Abstract: A sheet molding composition is disclosed which includes a four component resinous system which comprises (a) an unsaturated polyester comprising a polycondensation product of one or more dihydric alcohols and one or more ethylenically unsaturated polycarboxylic acids; (b) one or more low-profile additives which are thermoplastic polymers which cause phase separation and porosity during the curing reaction; (c) one or more olefinically unsaturated monomers which copolymerize with the unsaturated polyester; and, (d) one or more compatible components comprising at least one polysiloxane polyalkylene copolymer. The compatible components are compatible with the reacted unsaturated polyester and monomer during cure and impart improved surface characteristics when added to low-profile resin systems.Type: GrantFiled: January 8, 1993Date of Patent: July 27, 1999Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Louis R. Ross, Edward L. Wilson
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Patent number: 5907003Abstract: The invention concerns paint compositions for providing road markings, in particular on wet roadways. The paint compositions essentially comprise: at least one unsaturated polyester; at least one ethylenically unsaturated monomer; at least one polymerization accelerator selected from toluidine derivatives; at least one colored pigment; at least one compound which can exude at the surface of the paint and prevent oxygen in the air from inhibiting polymerization; glass beads and dibenzoyl peroxide.Type: GrantFiled: October 20, 1997Date of Patent: May 25, 1999Assignee: Lafarge Materiaux De SpecialitesInventors: Estelle Blot, Claude Stock
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Patent number: 5880180Abstract: This invention is the addition of an aldimine to enhance the ability of thermoplastic low profile additives to improve the surface quality of cured sheet molding compound vehicle parts.Type: GrantFiled: September 26, 1997Date of Patent: March 9, 1999Assignee: Ashland Inc.Inventor: Cynthia L. Smith
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Patent number: 5880171Abstract: A polymerizable composition for the production of high quality ophthalmic lenses is disclosed that includes:a) between 20 and 90 weight percent, and preferably, at least 50 weight percent, of urethane, epoxy, or polyester oligomers end terminated with acrylate or methacrylate (or mixtures of acrylate and methacrylate);b) between 5 and 50 to 80 percent, preferably between 10 and 40 percent, by weight of an optional diluent, such as a hydrocarbon diol end terminated with acrylate or methacrylate, or mixtures thereof, or a crosslinkable tri-, tetra-, or poly-acrylate or methacrylate, or mixtures thereof; andc) conventional optional additives, including but not limited to free radical initiators, UV absorbers, mold release agents, stabilizers, dyes, antioxidants, and wetting agents.The invention also includes ophthalmic lenses prepared from this composition and an apparatus for the production of lenses using sequential polymerization.Type: GrantFiled: January 11, 1995Date of Patent: March 9, 1999Assignee: 2C Optics, Inc.Inventors: Fredric J. Lim, Young C. Bae, David S. Soane
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Patent number: 5853645Abstract: Improved low pressure molding compositions are disclosed which comprise an unsaturated thermosetting resin, an olefinically unsaturated monomer copolymerizable with the thermosetting resin, a viscosity reducing additive, a thermoplastic additive and a thickener comprising one or more alkaline earth metal oxides or hydroxides which can provide the molding compositions with viscosities of less than 25 MMcps after aging.Type: GrantFiled: February 5, 1996Date of Patent: December 29, 1998Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Robert Lawrence Seats, Kenneth Earl Atkins, Carroll Glenn Reid
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Patent number: 5837770Abstract: A process for producing a flame retardant thermoplastic resin composition which has an excellent flame retardancy while maintaining sufficiently high levels of mechanical properties including tensile property, flexural property and impact resistance which process comprises the following first step and second step:the first step: the step of melt-kneading the following components (A) and (B) to obtain a melt-kneaded composition (AB),the second step: the step of melt-kneading the melt-kneaded composition (AB) and the following component (C) to obtain the flame retardant thermoplastic polyester resin composition:component (A): an impact resistance improver,component (B): a flame retarder,component (C): a thermoplastic polyester resin.Type: GrantFiled: February 13, 1996Date of Patent: November 17, 1998Assignee: Sumitomo Chemicial Company, LimitedInventors: Noboru Yamaguchi, Tohru Fujiki
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Patent number: 5744523Abstract: Polyacrylate esters having an average molecular weight of 1500 to 20,000 and being obtainable by the transesterification of alkyl polyacrylates, obtained by free radical polymerization and containing 1 to 4 carbon atoms in the alkyl group, witha) saturated or unsaturated aliphatic alcohols with 12 to 22 carbon atoms andb) optionally, additionally with dialkylaminoalkanols of the general formula HO--R.sup.1 --NR.sup.2 R.sup.3, wherein R.sup.1 is a divalent alkylene groups with 2 to 4 carbon atoms and are R.sup.2, R.sup.3 are the same or different and represent alkyl groups with 1 to 4 carbon atoms,the molar ratio of the aliphatic alcohols a) to the dialkylaminoalkanols b) being 1:0 to 1:1.5, and the components a) and b) being used in such amounts, that 25 to 70% of the ester groups are transesterified, are used as dispersants for finely divided solids, particularly for fillers and pigments, in organic media.Type: GrantFiled: August 10, 1995Date of Patent: April 28, 1998Assignee: Th. Goldschmidt AGInventors: Michael Barkowsky, Jurgen Fock, Dietmar Schaefer
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Patent number: 5661199Abstract: A non-aqueous dispersion containing, in addition to organic solvents,A) from 15-85% by weight of a dissolved film-forming component of hydroxyl group- and carboxyl-group containing polyesters, (meth)acrylic copolymers or mixtures thereof in which up to half the molecules may be esterified with 1 molecule of maleic acid each, andB) from 15-85% by weight of a disperse phase of uncross-linked (meth)acrylic copolymers having a hydroxyl number of at least 300, obtainable by the radical polymerization ofa) from 80-100% by weight of hydroxyalkyl (meth)acrylates andb) from 0-20% by weight of other .alpha.,.beta.-monounsaturated monomers in the dissolved film-forming component.Type: GrantFiled: May 28, 1996Date of Patent: August 26, 1997Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Klaus Bederke, Hermann Kerber, Ralf Dahm, Friedrich Herrmann, Horst Voss
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Patent number: 5648417Abstract: A color coating composition having excellent appearance, acid resistance and mar resistance is provided. Such excellent properties are achieved by the combination of an aminoplast-curing coating system with a curable coating system comprising a particular half esterified acid anhydrides, hydroxyl groups and epoxy groups.Type: GrantFiled: July 29, 1995Date of Patent: July 15, 1997Assignee: Nippon Paint Co., Ltd.Inventors: Akira Fushimi, Seigo Miyazoe, Atsushi Yamada, Yoshitaka Okude
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Patent number: 5637630Abstract: A molding composition comprises a) an unsaturated polyester resin, b) a copolymerizable olefinically unsaturated monomer, c) a pigment, d) fiber reinforcement and e) a poly(vinyl ether) polymer with a weight average molecular weight of at least 50,000 to control shrinkage and promote the uniform distribution of the pigment in the molding composition.Type: GrantFiled: November 22, 1991Date of Patent: June 10, 1997Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Kenneth E. Atkins
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Patent number: 5552460Abstract: Process for producing composite articles made of polyesters and elastomers. Composite articles made of a thermoplastic polyester and a vulcanizate are to be produced. These articles are obtained by producing the vulcanizate under conventional vulcanization conditions in contact with the hard component by vulcanization of a rubber composition which contains the following components:I. 100 parts by weight of a rubber,II. From 0 to 300 parts by weight of fillers,III. From 1 to 10 parts by weight of peroxidic vulcanization agents,IV. From 0 to 4 parts by weight of vulcanization activators andV. From 0 to 150 parts by weight of plasticizers, wherea) the hard and/or the soft component, as desired, additionally contains from 0.5 to 12 parts by weight of a difunctional or polyfunctional maleimide andb) in the case of the hard component containing no difunctional or polyfunctional maleimide, the rubber possesses carboxyl or acid anhydride groups.A strong composite is obtained by this process.Type: GrantFiled: March 30, 1995Date of Patent: September 3, 1996Assignee: Huels AktiengesellschaftInventors: Friedrich G. Schmidt, Horst Heuer
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Patent number: 5543440Abstract: A process for producing a powdered carboxyl-containing polymer comprising mixing a solution of a water-insoluble polymer containing a carboxyl group per molecule in a hydrophilic organic solvent (e.g., ethanol) and an aqueous solution of a dispersant comprising a neutralized copolymer of a carboxyl-containing unsaturated monomer and a (meth)acrylic ester to precipitate the water-insoluble polymer. Fine polymer particles free from adhesion or agglomeration are obtained efficiently. Since any residual unreacted carboxyl-containing monomers are dissolved out in water as a precipitating solvent, the resulting powdered polymer has a reduced residual content of the unreacted monomers which may be poisonous and is therefore useful as a base resin of cosmetics or a coating resin for applications involving contact with the skin.Type: GrantFiled: January 26, 1995Date of Patent: August 6, 1996Assignee: Mitsubishi Chemical CorporationInventors: Kazuhide Hayama, Yukio Saitoh, Yasuo Kitani, Katsuhiko Yamada
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Patent number: 5516820Abstract: Novel, non-aqueous dispersions and coatings made therefrom particularly suited for use as automotive primers, sealers, topcoats and as industrial coatings.Type: GrantFiled: June 7, 1995Date of Patent: May 14, 1996Inventors: John R. Babjak, Liza A. Capino, John D. Kraan, Mohamad D. Shalati, Susan L. Smith, Demetri L. Vallion, Richard S. Valpey, Thomas W. Yokoyama
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Patent number: 5473032Abstract: Coating composition containing one or several (meth)acrylic copolymers having hydroxyl groups, as well as one or several solvents and, optionally, water, special-effect pigments and/or coloring pigments, fillers and/or conventional lacquering additives, whereby the (meth)acrylic copolymer is essentially constructed from units based on the following monomers:a) 0.5-10.0% by weight of amides and/or N-substituted amides of acrylic acid and/or methacrylic acid,b) 5.0-30.0% by weight of phenylalkyl esters of acrylic acid and/or methacrylic acid,c) 10.0-30.0% by weight of hydroxyalkyl esters of acrylic acid and/or methacrylic acid having 2-8 C-atoms in the hydroxyalkyl residue,d) 0.6-7.5% by weight of acrylic acid and/or methacrylic acid, ande) 30.0-83.9% by weight of alkyl esters of acrylic acid and/or methacrylic acid having 1-18 C-atoms in the alkyl residue, andwhereby the sum of components a) to e) amounts in each case to 100.Type: GrantFiled: May 24, 1993Date of Patent: December 5, 1995Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Klaus Bederke, Hermann Kerber, Olaf Ley, Michael Prescher, Petra Kochert-Muhlenbeck
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Patent number: 5420179Abstract: Liquid resinous compositions suitable for the moulding of objects reinforced with glass fibres and capable of being pigmented, comprising an unsaturated polyester, a copolymerisable monomer and a partially hydroxylated alkyl methacrylate polymer.A hydroxylated alkyl methacrylate polymer which is soluble in the monomer and miscible with the unsaturated polyester is chosen.Application to the manufacture of objects moulded by bulk, sheet and injection moulding.Type: GrantFiled: December 22, 1992Date of Patent: May 30, 1995Assignee: Cray Valley, S.A.Inventors: Dominique Fourquier, Laurent Suspene
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Patent number: 5395865Abstract: Quickly curable unsaturated polyester composition with improved surface characteristics and stability in storage contains 20-40 weight parts of unsaturated polyester, 20-60 weight parts of vinyl monomer, 0.01-1.0 weight parts of BHT (ditertiary butyl hydroxy toluene), and 10-40 weight parts of thermoplastic resin such that the total is 100 weight parts. In addition, 0.001-0.1 weight parts of compound with effect of inhibiting polymerization at temperatures over 100.degree. C. are contained against the total of 100 weight parts. Molding materials are obtained by impregnating glass fibers with such compositions and products are obtained by curing such molding materials.Type: GrantFiled: November 6, 1992Date of Patent: March 7, 1995Assignee: Takeda Chemical Industries, Ltd.Inventors: Koichi Akiyama, Takashi Shibata, Hiroma Miyashita, Sanji Aoki, Ken Hatta, Takashi Ino, Yasuhiro Mishima
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Patent number: 5393808Abstract: A composition of matter especially for the formation and development of wear surfaces of decorative or aesthetic character is provided which comprehends a matrix and discrete reforcing elements embedded in the matrix. The matrix is resin-based with the resin being hydrogenated bis-phenol A which is mixed with a suitable low profile additive, a catalystic agent, a flame retardant, an extender, and a inhibitor while the reinforcer is constituted of glass fiber particles.Type: GrantFiled: June 9, 1994Date of Patent: February 28, 1995Assignee: The Swan CorporationInventors: Anthony Buonaura, John W. Moore
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Patent number: 5378743Abstract: This invention relates to a stable, low level styrene emission vinyl ester or unsaturated polyester resin composition containing a nonionic surfactant or a copolymer of maleic acid half ester of a polyethylene glycol and a monoalkenyl aromatic monomer as stabilizing agents.Type: GrantFiled: September 24, 1993Date of Patent: January 3, 1995Assignee: The Dow Chemical CompanyInventor: Rolf F. Liedtke
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Patent number: 5356953Abstract: Disclosed are a resin composition for artificial marble comprising:(I) an unsaturated polyester obtained by using a divalent alcohol containing hydrogenated hisphenol A as an essential component and an .alpha.,.beta.Type: GrantFiled: January 13, 1994Date of Patent: October 18, 1994Assignee: Hitachi Chemical Company LimitedInventors: Koki Harada, Yasuhisa Odagawa
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Patent number: 5348992Abstract: This invention relates to aerosol paint and coating compositions comprising non-aqueous dispersions.Type: GrantFiled: January 29, 1993Date of Patent: September 20, 1994Assignee: The Sherwin-Williams CompanyInventors: Paul D. Pearson, Madhukar Rao, Richard F. Tomko
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Patent number: 5342554Abstract: Vinyl-terminated polyesters and vinyl-terminated aliphatic polycarbonates are described which improve the flexibility and elongation at failure of cured samples of unsaturated polyesters or vinyl ester resins both at room temperature and at high temperatures, and without significant loss of surface quality or other mechanical properties. Further, these polymers do not phase separate from uncured polyester resin/styrene solutions, do not significantly increase the initial viscosity of molding compositions in which they have been incorporated, and do not negate the effect of low shrinkage additives during cure.Type: GrantFiled: January 7, 1993Date of Patent: August 30, 1994Assignee: GenCorp Inc.Inventors: Douglas S. McBain, Kevin P. LaJudice, Earl G. Melby
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Patent number: 5331025Abstract: This invention relates to a non-aqueous coating composition and a method for reducing the drying time of a non-aqueous coating composition by incorporating composite polymer particles having a softer, insoluble first stage and a hard second stage without adversely affecting the viscosity and pot life of the liquid coating composition and without degrading the properties of the final dry coating, including color, flexibility, impact resistance, gasoline resistance, salt spray resistance and humidity resistance.Type: GrantFiled: November 4, 1992Date of Patent: July 19, 1994Assignee: Rohm and Haas CompanyInventors: Alvin C. Lavoie, Jen-Chi Chen, Chao-Jen Chung, Dennis P. Lorah, Peter R. Sperry, Andrew W. Gross
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Patent number: 5319003Abstract: A process for making a composite article having improved mechanical properties such as fatigue life, which process comprises contacting at least one continuous filament with a mixture comprising a resin and a strain relieving polymer.Type: GrantFiled: September 30, 1992Date of Patent: June 7, 1994Assignees: Union Carbide Chemicals & Plastics Technology Corporation, Owens-Corning Fiberglas Technology Inc.Inventors: Jaime A. Gomez, Glenn R. Magrum, Eric R. Pohl, Frederick D. Osterholtz, Joshua B. Sweeney, Leonard J. Adzima, Martin C. Flautt, Paul R. Krumlauf
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Patent number: 5314729Abstract: An artificial marble formed by molding a material, in which said material comprises an unsaturated polyester, an unsaturated polymerizable monomer, and a filler. The unsaturated polyester consists essentially of an acid component and an alcohol component, wherein said alcohol component contains at least a glycol selected from a group consisting of 2-methylpropane-1,3-diol, 3-methylpentane-1,5-diol, 3-methyl-2-pentene-1,5-diol, 2-isopropylidene-1,3-propanediol, 2-isopropyl-1,3-propanediol, and 2-methylene-1,3-propanediol.Type: GrantFiled: July 29, 1991Date of Patent: May 24, 1994Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Mitsunori Ikezoe, Shigeru Motomiya