Six-membered Nitrogen Ring Having Two Or More Ring Nitrogen Atoms Patents (Class 524/100)
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Patent number: 8524812Abstract: N-substituted Macrocyclic Triazine-HALS Stabilizers.Type: GrantFiled: January 26, 2010Date of Patent: September 3, 2013Assignee: BASF SEInventors: Massimiliano Sala, Giulia Cocco, Anna Bassi, Michael Roth, Kai-Uwe Schöning
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Publication number: 20130225734Abstract: The present invention relates to a composition, which comprises (a) a compound of formula (A-1) (b) a compound of formulae (B-1), (B-11), (B-111) or (B-IV) wherein Z1 is linear C12-alkyl or linear C18-alkyl, and (c) a compound, which is a further sterically hindered phenolic antioxidant. The composition is used for stabilization of an organic polymer against degradation by heat, light and/or oxidation. The organic polymer is for example a styrene-butadiene copolymer, a styrene-isoprene copolymers or polybutadiene.Type: ApplicationFiled: November 11, 2011Publication date: August 29, 2013Applicant: BASF SEInventors: Shuang di Shandy Li, Alex Wegmann
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Patent number: 8519024Abstract: Water-based intumescent fireproofing formulations are provided that exhibit excellent fireproofing properties while simultaneously significantly reducing and/or eliminating the potential for VOC release and exhibiting excellent hangability properties. The intumescent fireproofing formulation includes a coalescent that significantly reduces and/or eliminates the potential for VOC release and fiber constituents, e.g., fibers of greater than 0.2 mm in length. Exemplary coalescents have a boiling point of at least 180° C. and include bis(2-ethylhexanoate) triethyleneglycol and 2,2,4-trimethyl-1,3-pentanediolmono(2-methylproponate). Intumescent fireproofing formulations are also provided that include clay to further improve performance.Type: GrantFiled: October 11, 2011Date of Patent: August 27, 2013Assignee: United States Mineral ProductsInventor: Robert Paul Kreh
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Publication number: 20130217812Abstract: Disclosed is a low toxicity aprotic alkyl amide solvent system used for the dissolution and application of polyamideimide and polyamide amic acid polymer resins. The solvent system can be used for the dissolution of polyamideimide and polyamide amic acid resins as an efficient method for incorporating these resins into functional coating compositions with the use of the solvent system.Type: ApplicationFiled: March 15, 2013Publication date: August 22, 2013Inventors: John Sidenstick, Russell Scott Clouston, Kathryn Mullins
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Publication number: 20130209820Abstract: Aqueous coating composition for optical brightening and shading of substrates comprising (a) at least one optical brightener of formula (I) in which the anionic charge on the brightener is balanced by a cationic charge composed of one or more identical or different cations selected from the group consisting of hydrogen, an alkali metal cation, alkaline earth metal, ammonium, ammonium which is mono-, di-, tri- or tetrasubstituted by a C1-C4 linear or branched alkyl radical, ammonium which is mono-, di-, tri- or tetrasubstituted by a C1-C4 linear or branched hydroxyalkyl radical, ammonium which is, di-, tri- or tetrasubstituted by a mixture of C1-C4 linear or branched alkylradical and linear or branched hydroxyalkyl radical or mixtures of said compounds, R1 and R1? may be the same or different, and each is hydrogen, C1-C4 linear or branched alkyl, C2-C4 linear or branched hydroxyalkyl, CH2CO2?, CH2CH2CONH2 or CH2CH2CN, R2 and R2? may be the same or different, and each is C1-C4 linear or branched alkyl, C2-C4Type: ApplicationFiled: June 21, 2011Publication date: August 15, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Heidrun Grether-Schene, Cédric Klein, David Puddiphatt
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Publication number: 20130207043Abstract: A compound of the formula (I), wherein one or two radicals of the radicals R1 are independently of one another C1-C20alkyloxy or C3-C12cycloalkyloxy and the remaining radicals R1 are independently of one another hydrogen, C1-C20alkyl or C3-C12cycloalkyl; the radicals R0 and R2 are independently of one another hydrogen, C1-C20alkyl, C3-C12cycloalkyl or a group of the formula (II-a) with R3 being hydrogen, C1-C20alkyl, C3-C12cycloalkyl, C1-C20alkyloxy or C3-C12cycloalkyloxy; Y is C2-C12alkylene; m is 0 or 1; n is 1, 2 or 3; when n is 1, X is hydrogen, C1-C20alkyl, C3-C12cycloalkyl or a group of the formula (II-a); when n is 2, X is C2-C12alkylene; when n is 3, X is a group N(Z—)3 with Z being C2-C12alkylType: ApplicationFiled: October 17, 2011Publication date: August 15, 2013Applicant: BASF SEInventors: Edoardo Menozzi, Kai-Uwe Schoning
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Publication number: 20130210971Abstract: Spun-dyed aramid fibers, wherein spun-dyeing was performed with a completely organic pigment exhibiting the chemical structure of formula (I): wherein, independently from one another, R1 represents a substituent of formula Xa or a substituent of formula Xb: wherein Xa is linked via the group NH having two bonds in the structure represented by Xa, whilst Xb is linked via the carbon atom, which is in a para relationship with the NH2-group of Xb; and R2 represents H or NH2. The spun-dyed aramid fibers exhibit constant colouristic properties and wash proof properties.Type: ApplicationFiled: October 6, 2011Publication date: August 15, 2013Applicant: TEIJIN ARAMID B.V.Inventor: Robin Winters
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Publication number: 20130210968Abstract: The invention relates to flame-retardant polyester compounds comprising as component A 40% to 89.9% by weight of thermoplastic polyesters, as component B 5% to 25% by weight of phosphinic salt of the formula (V) and/or diphosphinic salt of the formula (VI) and/or polymers thereof, in which R1 and R2 are H or C1-C6-alkyl and/or aryl; R3 is C1-C10-alkylene, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; and x is 1 to 4, and as component C 5% to 25% by weight of a phosphazene, as component D 0% to 15% by weight of reaction products of melamine with phosphoric acid and/or condensed phosphoric acids, as component E 0% to 45% by weight of reinforcing agents, and as component F 0.1% to 3% by weight of further additives, the sum of the components by weight being 100% by weight.Type: ApplicationFiled: October 25, 2011Publication date: August 15, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Sebastian Hoerold, Wolfgang Wanzke, Elke Schlosser, Bernd Nass
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Publication number: 20130210970Abstract: The invention relates to a method for producing a free flowing flame retardant material, comprising steps of i. preparing an aqueous slurry from a freshly prepared moist melam having a water content of at least 8 wt. %, relative to the total weight of the moist melam, the slurry comprising water, melam and a water soluble polymeric binding agent, wherein the melam is present in an amount of 5-35 wt. % relative to the total weight of the slurry, and the water soluble polymeric binding agent is present in an amount of 0.5-8 wt. % relative to the total amount of melam and the water soluble polymeric binding agent; ii. drying the slurry in a fluid bed to form a granulate material; and iii. collecting the resulting granulate material. The invention also relates to a melam granulate material, obtainable by said process.Type: ApplicationFiled: June 7, 2011Publication date: August 15, 2013Applicant: DSM IP ASSETS B.V.Inventors: Gerard Jan Kwant, Christiaan Johannes Cornelis Stoelwinder, Bas van Laarhoven
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Patent number: 8506854Abstract: The present invention relates to a stabilizer system for halogenated polymers comprising, as component (A), calcium monocarbonatohydroxodialuminate of the formula (A) CamAl2(OH)6+2(m-1)CO3*nH2O??(A), where m=from 3.8 to 4.2, and n=from 0 to 3, and, as component (B), a catena-2,2?,2?-nitrilotrisethanolperchloratolithium or -sodium coordination polymer (B1) with a monomer unit of the formula where Mt=Li or Na, An=OClO3 and q=1, and/or a quaternary or ternary ammonium or phosphonium perchlorate (B2). The present invention further relates to compositions and articles comprising these stabilizer systems, and to the use of the systems and compositions.Type: GrantFiled: August 4, 2008Date of Patent: August 13, 2013Assignee: Nabaltec AGInventors: Trupti Dave, Wolfgang Wehner
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Publication number: 20130203904Abstract: The present invention relates to polypiperidine compounds of polymeric type which are capable of conferring to the polymeric materials, particularly to polyolefins, a high stability against photodegradation and oxidative action of air, belong to the HALS category and have general formula (I): wherein p is from 3 to 20; n is from 2 to 12; R and R1, which are the same or different, are selected in the group consisting of hydrogen, linear and branched C1-C12 alkyl groups, alkenyl groups having 3 to 8 carbon atoms and aralkyl groups having 7 to 19 carbon atoms; X and X1, which are the same or different, are selected in the group consisting oxygen and groups of formula (II) wherein R2 is selected in the group consisting of hydrogen, linear and branched C1-C12 alkyl groups, cycloalkyl groups having, 5 to 12 carbon atoms and aralkyl groups having 7 to 12 carbon atoms; A represents a —(CH2)a— group wherein a is from 2 to 12, with the proviso that a is different from n; Z is selected in the group consistType: ApplicationFiled: October 27, 2011Publication date: August 8, 2013Applicant: 3V SIGMA S.P.A.Inventors: Francesco Maestri, Simone Del Sordo, Ferruccio Berte
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Patent number: 8501846Abstract: Stabilizer compositions comprise phosphate of the formula I or II, a phosphite of the formula III, and a phenol of the formula IV as these formulas are defined herein. The stabilizer compositions are useful for stabilizing polymers. Methods for making stabilized polymer compositions involve intermixing the stabilizer compositions and the polymers, e.g., by extruding, pelletizing, and/or molding.Type: GrantFiled: June 15, 2010Date of Patent: August 6, 2013Assignee: Cytec Technology Corp.Inventors: John Mathew Zenner, Brent Sanders
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Publication number: 20130190432Abstract: A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(?O)O2]2?Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carboType: ApplicationFiled: September 30, 2011Publication date: July 25, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Werner Krause, Harald Bauer, Martin Sicken, Sebastian Hoerold, Wolfgang Wanzke, Elke Schlosser
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Publication number: 20130184384Abstract: The invention provides hot melt adhesives that comprise a templating agent, a polymer and a wax. It has been discovered that hot melt adhesives with an effective amount of templating agent have improved heat resistance than adhesives. The adhesives find particular use as case, carton, and tray forming, and as sealing adhesives, including heat sealing applications, for example in the packaging of cereals, cracker and beer products.Type: ApplicationFiled: March 5, 2013Publication date: July 18, 2013Applicant: HENKEL CORPORATIONInventor: HENKEL CORPORATION
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Patent number: 8487025Abstract: The present invention relates to an aromatic branched polycarbonate, produced via melt transesterification of a bisphenol with a diaryl carbonate in the presence of a branching agent, wherein the aromatic branched polycarbonate comprises branching point structures and structures of formula (D) wherein X is a single bond, C1- to C6-alkylene, C2- to C5-alkylidene or C5- to C6-cycloalkylidene, optionally substituted by C1- to C6-alkyl; wherein the amount of D in the aromatic branched polycarbonate is in the range of from 5 to 450 mg per kg of the aromatic branched polycarbonate; and wherein the ratio of the total branching point structures to the total structures of the formula D in the aromatic branched polycarbonate is in the range of from 8 to 200.Type: GrantFiled: April 7, 2011Date of Patent: July 16, 2013Assignee: Bayer Material Science AGInventors: Stephan Konrad, Helmut-Werner Heuer, Karl-Heinz Köhler, Christian Münnich, Rolf Wehrmann
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Patent number: 8487018Abstract: Heavy metal-free compostable polymers, composites and articles anaerobically biodegrade in landfills in a relatively short time. Heavy metal-free composite polymeric articles and sheets such as indoor or outdoor signs, billboards, banners, images, protective barriers, backdrops and wall coverings have very useful service durations and yet are landfill biodegradable.Type: GrantFiled: February 21, 2011Date of Patent: July 16, 2013Assignee: Biotech Products, LLCInventor: Richard F. Grossman
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Publication number: 20130175070Abstract: Disclosed are polymeric compositions with improved breakdown strength. The polymeric compositions contain a polyolefin and a voltage stabilizing agent. The voltage stabilizing agent contains a triazine. The triazine may include a substituent that enables keto-enol tautomerism, which provides the voltage stabilizing agent with additional energy dissipation capacity. The present polymeric compositions exhibit improved breakdown strength when applied as an insulating layer for power cable.Type: ApplicationFiled: September 23, 2011Publication date: July 11, 2013Inventors: Timothy J. Person, Jeffrey M. Cogen
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Patent number: 8481621Abstract: Disclosed embodiments concern using at least one triazine, typically an amine or polyamine triazine (referred to as amino triazines), in combination with at least one ionomer or ionomer precursor to form compositions useful for making sporting equipment, such as golf ball components. The ionomer or ionomer precursor typically includes plural acid functional groups, such as carboxyl or carboxylate groups, that react or form salts with the amino triazine. Specific examples, without limitation, of suitable amino triazines include guanamine, 6-methyl-1,3,5-triazine-2,4-diamine(acetoguanamine), 6-nonyl-1,3,5-triazine-2,4-diamine(nonylguanamine), 6-phenyl-1,3,5-triazine-2,4-diamine(benzoguanamine) and 2,4,6-triamino-triazine(melamine).Type: GrantFiled: July 6, 2012Date of Patent: July 9, 2013Assignee: Taylor Made Golf Company, Inc.Inventors: Hyun J. Kim, Hong G. Jeon
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Patent number: 8481620Abstract: A method for producing a resin composition, including the steps of melt-kneading a raw material A containing a polylactic acid resin, a crystal nucleating agent, and a plasticizer containing an ester compound formed between a polycarboxylic acid having a hydrocarbon group having 1 to 7 carbon atoms and a mono-alcohol having a hydrocarbon group having 1 to 7 carbon atoms, to prepare a polylactic acid-containing melt-kneaded mixture having a relative crystallinity of 70% or more (step A); and further melt-kneading the polylactic acid-containing melt-kneaded mixture obtained by the step A and a raw material B containing a polypropylene resin and a compatibilizing agent (step B). The resin composition obtainable by the method of the present invention can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.Type: GrantFiled: October 22, 2009Date of Patent: July 9, 2013Assignee: Kao CorporationInventors: Taiki Yoshino, Masahiro Mori, Akira Takenaka
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Publication number: 20130172453Abstract: A polyamide resin composition comprises (A) about 10 to about 70% by weight of a crystalline polyamide resin, (B) about 10 to about 70% by weight of an amorphous polyamide resin, (C) about 5 to about 30% by weight of an inorganic filler, and (D) about 10 to about 50% by weight of a white pigment. The polyamide resin composition can have good thin-wall moldability, light reflectance, yellowing resistance, impact strength and heat resistance.Type: ApplicationFiled: December 27, 2012Publication date: July 4, 2013Applicant: CHEIL INDUSTRIES INC.Inventor: CHEIL INDUSTRIES INC.
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Publication number: 20130165557Abstract: It is an object of the present invention to provide a laminate having excellent weatherability and abrasion resistance as well as adhesion. The present invention relates to a laminate comprising a base, a first layer formed by thermally curing an acrylic resin composition and a second layer formed by thermally curing an organosiloxane resin composition, all of which are formed in the mentioned order, wherein the acrylic resin composition comprises: (A) an acrylic copolymer which contains at least 70 mol % of a recurring unit represented by the following formula (A): wherein X is a hydrogen atom or methyl group, and Y is a methyl group, ethyl group, cycloalkyl group, hydroxyalkyl group having 2 to 5 carbon atoms or triazine-based ultraviolet absorber residue; (B) a blocked polyisocyanate compound; (C) a curing catalyst; and (D) a triazine-based ultraviolet absorber, and the organosiloxane resin composition comprises: (E) colloidal silica and (F) a hydrolysis condensate of an alkoxysilane.Type: ApplicationFiled: February 8, 2013Publication date: June 27, 2013Applicant: TEIJIN CHEMICALS, LTD.Inventor: Teijin Chemicals, Ltd.
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Publication number: 20130165558Abstract: The invention relates to flame retardant compositions that contain mixtures of melamine polyphosphates with layered silicates added to the polymer substrates, particularly polyamides.Type: ApplicationFiled: February 25, 2013Publication date: June 27, 2013Applicant: BASF SEInventor: BASF SE
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Publication number: 20130153643Abstract: A polyamide composition for surface-mounted components is described. Also described are compositions for surface-mounted components (SMCs) including a semiaromatic polyamide modified by a hydroxyaromatic compound, reinforcing fillers, and a flame retardant. Further, the compositions have many advantages linked to the uses thereof in lead-free reflow soldering processes, in particular a good dimensional stability and a blistering resistance during the use of articles produced from these compositions.Type: ApplicationFiled: June 21, 2011Publication date: June 20, 2013Applicant: RHODIA OPERATIONSInventor: Stéphane Jeol
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Patent number: 8466221Abstract: Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of a thermoplastic polyamide, B) from 0.01 to 20% by weight of a highly branched melamine polymer or melamine-urea polymer, or a mixture of these, C) from 0 to 70% by weight of further additives, where the total of the percentages by weight of components A) to C) is 100%.Type: GrantFiled: March 8, 2011Date of Patent: June 18, 2013Assignee: BASF SEInventors: Manoranjan Prusty, Maxim Peretolchin, Martin Baumert
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Publication number: 20130150502Abstract: Stabilized photoactive composition comprising at least one photoactive organic polymer; at least one light stabilizer selected from hindered amines; at least one UV absorber selected from triazines, benzoxazinones, benzotriazoles, benzophenones, benzoates, formamidines, cinnamates or propenoates, aromatic propanediones, benzoimidazoles, cycloaliphatic ketones, formanilides including oxamides, cyanoacrylates, benzopyranones, salicylates, or mixtures thereof. Said photoactive composition can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both rigid and flexible supports.Type: ApplicationFiled: February 5, 2013Publication date: June 13, 2013Applicant: Eni S.P.A.Inventor: Eni S.P.A.
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Publication number: 20130143051Abstract: The instant invention relates to novel hydroxyphenyl triazine UV-absorbers with an aromatic carbocyclic fused ring system having a long wavelength shifted absorption spectrum with significant absorbance up to 420 nm. Further aspects of the invention are a process for their preparation, a UV stabilized composition containing the new UV-absorbers, a process for the stabilization of organic materials and the use of the new compounds as UV-light stabilizers for organic materials.Type: ApplicationFiled: January 23, 2013Publication date: June 6, 2013Applicant: Ciba Specialty Chemicals Holding Inc.Inventor: Ciba Specialty Chemicals Holding Inc.
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Patent number: 8455576Abstract: A halogen-free, flame retardant composition comprises thermoplastic polyurethane, olefin block copolymer, carbonyl-containing olefin polymer compatibilizer, and flame retardant package comprising bisphenol-A bis(diphenyl phosphate) and/or resorcinol bis(diphenyl phosphate), a nitrogen/phosphorus based, halogen-free flame retardant, and epoxidized novolac. The composition that will not only be processed easily to make a wire or cable sheath but also pass both the VW-1 flame retardancy test and the UL1581 heat deformation test at 150° C. exhibits good tensile and flexibility properties.Type: GrantFiled: December 18, 2009Date of Patent: June 4, 2013Assignee: Dow Global Technologies LLCInventors: Given Jing Chen, Wilson Xiao Wei Yan, Lan Lu, Bin Li, David Hong Fei Guo, Lotus Hua Huang
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Publication number: 20130137800Abstract: The invention relates to flame retardant compositions, wherein a phosphinic acid hydrazide is present in a polymer substrate. The combination with >NOR-compounds improves the flame retardant properties.Type: ApplicationFiled: July 26, 2011Publication date: May 30, 2013Applicant: BASF SEInventors: Rainer Xalter, Simon Kniesel
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Patent number: 8450399Abstract: The invention relates to a polymer composition which is characterized in that it comprises a mixture (A) consisting of formula (A1) and/or formula (A2), phenolic resin (B) and a stabilizer (C) in the form of a HALS compound.Type: GrantFiled: April 2, 2009Date of Patent: May 28, 2013Assignee: Evonik Degussa GmbHInventors: Marianne Omeis, Kathrin Salwiczek, Elke Fiebig-Bauer
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Patent number: 8450409Abstract: Disclosed is a method comprising: (a) mixing in a first mixing step ingredients comprising (i) first polymer, (ii) a low molecular weight polymer having a number average molecular weight of about 5,000 to about 100,000, and (iii) a filler, and (b) mixing in a second mixing step ingredients comprising (i) the mixture obtained in step (a), (ii) a second polymer that is different from said first polymer, and (iii) optionally a filler. In one embodiment, the method further comprises mixing sulfur and vulcanization accelerator(s) into the composition, forming the rubber composition into a sidewall for a tire, and vulcanizing the rubber composition.Type: GrantFiled: August 27, 2010Date of Patent: May 28, 2013Assignee: Bridgestone CorporationInventors: Zhong-Ren Chen, Joseph M. Lanzarotta, Yuichi Nagai, Tomohiro Kusano
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Publication number: 20130131235Abstract: The invention relates to a flameproof agent stabiliser combination containing, as component A 40-99 wt. % of a phosphinic acid salt of formula (I) and/or a diphosphinic acid salt of formula (II) and/or polymers thereof, wherein R1, R2 are the same or different and represent C1-C18-alkyl linear, branched or cyclic, C6-C18-aryl, C7-C18-arylalkyl and/or C7-C18-alkylaryl; R3 represents C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C18-alkylarylene or C7-C18-arylalkylene; M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protoned nitrogen base; m represents 1-4; n represents 1-4; x represents 1-4, as component B 1-60 wt. % of a phosphinic acid salt of general formula (III) wherein R4 represents C1-C18-alkyl linear, branched or cyclic, C6-C18-aryl, C7-C18-arylalkyl or C7-C18-alkylaryl and M represents Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base, as component C 0-50 wt.Type: ApplicationFiled: April 20, 2011Publication date: May 23, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Sebastian Hoerold, Harald Bauer
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Patent number: 8444879Abstract: Disclosed are triazine derivatives of formula wherein X1 is a bivalent radical of formula A and A? independently from each other are unsubstituted or substituted, straight-chain or branched C1-C12alkylene, which is optionally interrupted by C5-C12cycloalkylene, N, O or S; C5-C12cycloalkylene; biphenylene; C6-C10arylene; or C5-C10arylene-(C1-C12alkylene); R1 is a radical of formula R2 and R3 independently from each other are hydrogen; C1-C12alkyl; OR7; NR7R8; C6-C10aryl; X2 is O, or NH; W1 is C1-C20alkyl; or a group Sp-Sil; Sp is a straight-chain or branched saturated or single or multiple unsaturated C3-C12 hydrocarbon; Sil is a silane; an oligosiloxane; or a polysiloxane moiety; and R4, R5 R6, R7, R8 and R9 independently from each other are hydrogen; C1-C12alkyl; or C3-C12cycloalkyl.Type: GrantFiled: May 2, 2007Date of Patent: May 21, 2013Assignee: BASF SEInventors: Thomas Ehlis, Elek Borsos
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Patent number: 8445566Abstract: The invention relates to a continuous process for producing a reactive polymer based on compounds according to the structures (A1) and/or (A2) and phenolic resin in an extruder and to the reactive polymer produced according to said process and the use thereof for producing composite materials.Type: GrantFiled: April 2, 2009Date of Patent: May 21, 2013Assignee: Evonik Degussa GmbHInventors: Marianne Omeis, Thomas Weihrauch, Silvia Herda, Elke Fiebig-Bauer
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Publication number: 20130123398Abstract: The invention relates to a flame-proofed polymer composition that can be obtained from one or more ?-olefin/vinyl acetate copolymers, having a vinyl acetate content of 40 to 90 wt %, relative to the total weight of the ?-olefin/vinyl acetate copolymers, and from a synergistic flame-proofing material combination, containing, as component A, a phosphinic acid salt of the formula (I), where R1, R2 are C1-C6-alkyl, preferably C1-C4-alkyl, linear or branched; M is calcium, aluminum, zinc ions; m is 2 or 3; and as component B, a metal hydroxide, preferably aluminum hydroxide (ATH); and, as component C, a melamine compound.Type: ApplicationFiled: December 21, 2010Publication date: May 16, 2013Applicant: LANXESS DEUTSCHLAND GMBHInventors: Andreas Roos, Gerd Bergmann, Manuel La Rosa, Oriane Cerin, Gaëlle Fontaine, Sophie Duquesne, Serge Bourbigot
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Patent number: 8440748Abstract: Provided is a thermoplastic resin composition comprising 1 to 100 parts by weight of a flame retardant (B) containing any one or more flame retardants (B-1) selected from melamine phosphate, melamine pyrophosphate, and melamine polyphosphate and any one or more flame retardants (B-2) selected from piperazine phosphate, piperazine pyrophosphate, and piperazine polyphosphate, based on 100 parts by weight of a thermoplastic resin (A) comprising polylactide resin, wherein, according to transmission electronic microscopy, the major axis of the largest particle of the flame retardant (B) in the composition is not more than 10 ?m, and the ratio of the number of particles of the flame retardant (B) having a major axis of not more than 3 ?m relative to the number of particles of the flame retardant (B) per an area of 1,000 ?m2 is 70% or more.Type: GrantFiled: September 13, 2011Date of Patent: May 14, 2013Assignee: Toray Industries, Inc.Inventors: Daisuke Sato, Yosuke Onoue, Sadanori Kumazawa
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Publication number: 20130115472Abstract: The halogen-free resin composition comprises (A) 100 parts by weight of cyanate ester resin; (B) 5 to 50 parts by weight of styrene-maleic anhydride; (C) 5 to 100 parts by weight of polyphenylene oxide resin; (D) 10 to 150 parts by weight of phosphazene; and (E) 10 to 1000 parts by weight of inorganic filler. By using specific components at specific proportions, the halogen-free resin composition offers the features of low dielectric constant, low dissipation factor, high heat resistance and high flame retardancy, and can be made into prepreg or resin film, and thereby used in copper clad laminate or printed circuit board.Type: ApplicationFiled: November 19, 2012Publication date: May 9, 2013Applicant: ELITE MATERIAL CO., LTD.Inventor: Elite Material Co., Ltd.
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Publication number: 20130109792Abstract: Flame retardant-stabilizer combination for thermoplastic polymers The invention relates to a flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 30 to 79.9% by weight of a phosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each H, C1-C18-alkyl, C6-C18-aryl, C7-C18-arylalkyl and/or C7-C18-alkylaryl; R3 is linear or branched C1-C10-alkylene, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 20 to 50% by weight of a nitrogen-containing synergist or of a phosphorus/nitrogen flame retardant and as component C 0.Type: ApplicationFiled: July 6, 2011Publication date: May 2, 2013Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Sebastian Hoerold, Wolfgang Wanzke, Elke Schlosser
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Publication number: 20130109791Abstract: The present invention relates to a flame retardant plexifilamentary film-fibril strand comprising at least one polyolefin and at least one flame retardant selected from the group consisting of: phosphate esters, phosphonate esters, phosphinate esters, polyphosphazines, nitrogen-containing polyphosphates, hindered amines and mixtures thereof. The present invention also relates to flame retardant sheet made from the flame retardant plexifilamentary film-fibril strands. The sheet can be made into a flame retardant building substrate, garment, banner, light reflector and cover.Type: ApplicationFiled: April 17, 2012Publication date: May 2, 2013Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: SABINE GABRIEL, LAKSHMI KRISHNAMURTHY, MIECZYSLAW (MICHEL) STACHNIK, MARK GARY WEINBERG
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Publication number: 20130109786Abstract: The present invention provides an epoxy resin composition comprising epoxy resin, phenolic resin, a cure accelerator and an inorganic filler; said epoxy resin comprises: (1) 20-50% of Formula I; (2) 10-40% of Formula II; and (3) 0-30% of Formula III and/or 0-40% of Formula IV, wherein Formula III and Formula IV are not 0% simultaneously; and wherein, R1 and R2 are independently hydrogen or alkyl of C1-C6; n is an integer from 0 to 50 in Formula I; the ratio of the number of phenolic hydroxyls in said phenolic resin to the number of epoxy groups in the epoxy resin mixture is 0.8-1.3; all said percentages are percentages relative to the total mass of the epoxy resin mixture. The present invention provides a green, environmentally friendly epoxy resin composition with high reliability and low warpage properties that can satisfy the requirement of lead-free high temperature reflux process.Type: ApplicationFiled: December 18, 2012Publication date: May 2, 2013Applicant: Henkel (China) Investment Company Ltd.Inventor: Henkel (China) Investment Company Ltd.
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Patent number: 8420747Abstract: A thermosetting polymer material capable of being used in powder coatings. The thermosetting polymer material includes at least one hydroxyl functional aliphatic polycarbonates that is formulated and crosslinked with isocyanates to yield a thermoset organic coating material. These materials provide improved weatherability as compared to prior art powder coating materials while also being less expensive than prior art materials utilizing fluorinated polymers.Type: GrantFiled: July 17, 2008Date of Patent: April 16, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventors: Jon M Malinoski, Paul D Sybert, Christopher Michael Eastman, Sumeet Jain, Rainer Koeniger, Michael Todd Luttrell, Glen David Merfeld, James Edward Pickett, Jason Joseph Testa
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Patent number: 8415470Abstract: The present invention deals with a novel aromatic di-isoimide chemical compound that has utility as a catalyst and as a curing agent in epoxy compositions. The di-isoimide serves effectively as a thermally activated latent catalyst in epoxy curing, thereby increasing shelf life, and avoids premature cross-linking. Novel laminated articles and printed wiring boards, including encapsulated printed wiring boards are also disclosed. The composition hereof also can be used as a flame retardant in thermoplastic and thermoset polymers.Type: GrantFiled: June 24, 2011Date of Patent: April 9, 2013Assignee: E I du Pont de Nemours and CompanyInventor: George Elias Zahr
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Publication number: 20130085215Abstract: The present invention realizes a display device or input device having excellent ultraviolet protection property for the touch panel, display element or the like, while retaining optical characteristics, even when a small amount of or no optical film is used. The pressure-sensitive adhesive sheet of the present invention has a total light transmittance of 85% or more, a light transmittance at a wavelength of 380 nm of 5% or less, and a haze of 3% or less. The pressure-sensitive adhesive sheet preferably includes a pressure-sensitive adhesive layer containing an acrylic polymer and a triazine-based ultraviolet absorber.Type: ApplicationFiled: September 27, 2012Publication date: April 4, 2013Applicant: NITTO DENKO CORPORATIONInventor: Nitto Denko Corporation
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Patent number: 8410227Abstract: Thermoplastic molding compositions comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of a hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.Type: GrantFiled: May 29, 2012Date of Patent: April 2, 2013Assignee: BASF SEInventors: Andreas Eipper, Bernd Bruchmann, Dietrich Scherzer, Jean-Francois Stumbe, Carsten Weiβ, Freddy Gruber
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Patent number: 8404349Abstract: It is an object of the present invention to provide a laminate having excellent weatherability and abrasion resistance as well as adhesion. The present invention relates to a laminate comprising a base, a first layer formed by thermally curing an acrylic resin composition and a second layer formed by thermally curing an organosiloxane resin composition, all of which are formed in the mentioned order, wherein the acrylic resin composition comprises: (A) an acrylic copolymer which contains at least 70 mol % of a recurring unit represented by the following formula (A): wherein X is a hydrogen atom or methyl group, and Y is a methyl group, ethyl group, cycloalkyl group, hydroxyalkyl group having 2 to 5 carbon atoms or triazine-based ultraviolet absorber residue; (B) a blocked polyisocyanate compound; (C) a curing catalyst; and (D) a triazine-based ultraviolet absorber, and the organosiloxane resin composition comprises: (E) colloidal silica and (F) a hydrolysis condensate of an alkoxysilane.Type: GrantFiled: March 7, 2007Date of Patent: March 26, 2013Assignee: Teijin Chemicals, Ltd.Inventors: Toshio Kita, Shunsuke Kajiwara, Ryou Niimi, Takehiro Suga, Tatsuya Ekinaka, Nobuaki Takaoka
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Patent number: 8404765Abstract: The present invention relates to polypiperidine compounds capable of conferring to polymeric materials, particularly polyolefins, a high stability against photodegradation and oxidative action of air, which belong to the HALS category and have the following general formula (I) in which x can be zero or 1; y is between 1 and 10; m and n, which may be different or equal to each other, range from 2 to 8; A represents a NPiR1 group or a NR2R3 group; and Pi represents the group of formula (II) wherein R1 is selected from the group consisting of H, C1-C4 straight-chain and branched-chain alkyl groups; R2 and R3 can be the same or different and are selected in the group consisting of H, C1-C8 straight-chain and branched-chain alkyl groups, cyclic alkyl groups having from 5 to 12 carbon atoms, or form together with the nitrogen atom a heterocyclic ring having from 5 to 7 members, comprising other heteroatoms such as O, R4 is selected from the group consisting of H, C1-C4 straight-chain and branched-Type: GrantFiled: February 8, 2010Date of Patent: March 26, 2013Assignee: 3V Sigma S.p.A.Inventors: Luca Bemporad, Ferruccio Berte, Carlo Seccomandi
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Publication number: 20130071658Abstract: The present invention aims to provide an adhesive composition having high adhesive strength, as well as being easily detachable and having excellent heat resistance, an adhesive tape comprising the adhesive composition, a method for treating a semiconductor wafer using the adhesive tape, and a method for producing a TSV wafer. The present invention relates to an adhesive composition comprising: an adhesive component; and a tetrazole compound represented by the following formula (1), formula (2), or formula (3), or its salt: wherein R1 and R2 each may be hydrogen, a hydroxy group, an amino group, or a C1-C7 alkyl group, alkylene group, phenyl group, or mercapto group; and the C1-C7 alkyl group, alkylene group, phenyl group, and mercapto group may be substituted.Type: ApplicationFiled: March 17, 2011Publication date: March 21, 2013Applicant: Sekisui Chemical Co., Ltd.Inventors: Shigeru Nomura, Daihei Sugita, Toru Tonegawa
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Publication number: 20130065051Abstract: Halogen-free, flame-retardant thermoplastic compositions that include a styrenic block copolymer, a low-melting, phosphorus-based flame retardant having a melting temperature no higher than 170° C., and a blend of solid intumescent phosphorus and nitrogen-containing flame retardants. The blend of solid intumescent flame retardants include at least two phosphorous and nitrogen-containing phosphoric acid salts that synergistically enhance the flame-retardant properties of the compositions relative to compositions that include other flame-retardant packages.Type: ApplicationFiled: April 14, 2010Publication date: March 14, 2013Inventors: Given Jing Chen, Bin Li, Geoffrey D. Brown, Xiangyang Tai, Tong Wu, Kawai Peter Pang, Yongyong Yang, Robert F. Eaton, Manish Mundra
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Publication number: 20130059072Abstract: A two part non-sag polyurethane construction sealant or adhesive is provided with the properties of low modulus, high elongation, good paint adhesion, and primerless adhesion to concrete surfaces. The sealant or adhesive is prepared using a polyol, and optionally an epoxy silane and/or a melamine compound, in the base component of the formulation; and a prepolymer reaction product including the residues of xylenol or xylenol and an additional polyol, and a polymeric isocyanate, an aromatic diisocyanate, or a polymeric isocyanate and an aromatic diisocyanate, and optionally an epoxy silane and/or a melamine compound, in the activator component of the formulation.Type: ApplicationFiled: July 26, 2012Publication date: March 7, 2013Applicant: Construction Research & Technology GmbHInventors: Chia L. Wang, John M. Davis, Bryan Lienke
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Patent number: 8389639Abstract: A proton exchange membrane comprising modified hyper-branched polymer is disclosed. The proton exchange membrane includes 85-90 wt % of sulfonated tetrafluorethylene copolymer and 15-10 wt % of modified hyper-branched polymer. The modified hyper-branched polymer comprises the bismaleimide (BMI)-based hyper-branched polymer, and parts of the chain ends of the hyper-branched polymer are sulfonated by the sulfonic compound. Also, the modified hyper-branched polymer and sulfonated tetrafluorethylene copolymer are interpenetrated to form an interpenetrating polymer. Furthermore, the modification step could be performed before or after forming the interpenetrating polymer. For example, the sulfonation is proceeded after forming the interpenetrating polymer. Alternatively, the sulfonation of the hyper-branched polymer could be proceeded before the formation of the interpenetrating polymer.Type: GrantFiled: November 23, 2009Date of Patent: March 5, 2013Assignee: Industrial Technology Research InstituteInventors: Chung-Liang Chang, Ya-Ting Hsu, Jing-Pin Pan
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Patent number: 8389719Abstract: The instant invention relates to novel hydroxyphenyl triazine UV-absorbers with an aromatic carbocyclic fused ring system having a long wavelength shifted absorption spectrum with significant absorbance up to 420 nm. Further aspects of the invention are a process for their preparation, a UV stabilized composition containing the new UV-absorbers, a process for the stabilization of organic materials and the use of the new compounds as UV-light stabilizers for organic materials.Type: GrantFiled: May 31, 2006Date of Patent: March 5, 2013Assignee: Ciba Specialty Chemicals Corp.Inventors: Thomas Vogel, Adalbert Braig, Thomas Schäfer, Rachel Kohli Steck, Valerie Stutz