Two Or More Nitrogen Rings Patents (Class 524/102)
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Patent number: 4829111Abstract: A stabilizer composition for synthetic resin is described comprising a piperazine derivative represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents an alkyl group having from 12 to 20 carbon atoms or a 2,2,6,6-tetramethyl-4-piperidyl group; R.sub.3 and R.sub.4 each represents a hydrogen atom or a methyl group; and n and m each represents 2 or 3.A synthetic resin composition is also described comprising polyolefin and the aforesaid piperazine derivative.Type: GrantFiled: February 2, 1988Date of Patent: May 9, 1989Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Kazuyuki Iida, Hiroyuki Omori, Akiyoshi Oonishi, Masami Takahashi
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Patent number: 4822833Abstract: Rigid polyvinyl chloride stabilized against the adverse effects of ultraviolet radiation by the addition thereto of effective amounts of 2,2,6,6-tetraalkylpiperidine compound and an organotin carboxylate thermal stabilizer, optionally with reduced amounts of titanium dioxide, organotin mercapto esters and/or organotin mercaptide thermal stabilizers.Type: GrantFiled: February 3, 1988Date of Patent: April 18, 1989Assignee: Ciba-Geigy CorporationInventors: Jean M. Zappia, Gerald A. Capocci
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Patent number: 4812499Abstract: Compositions of thermoplastic polymers comprising, in mixture, a thermoplastic polymer and a mixture of self-extinguishability-conferring additives, formed by:ammonium phosphate or ammonium polyphosphate: ##STR1## (wherein p is preferably equal to or greater than 50); phosphorus-containing compound definable by means of the general formula: ##STR2## (wherein R.sub.1, R.sub.2 and R.sub.3 have the meaning as indicated in the disclosure).Type: GrantFiled: March 20, 1986Date of Patent: March 14, 1989Assignee: Enichem Sintesi S.p.A.Inventors: Gioacchino Cipriani, Gianluigi Landoni
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Patent number: 4812501Abstract: 1,3,2-oxazaphospholidine derivatives of the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants.Type: GrantFiled: March 16, 1988Date of Patent: March 14, 1989Assignee: Ciba-Geigy CorporationInventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun
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Patent number: 4812498Abstract: Polycarbonate resin compositions are provided having improved light stability and comprising an alkylidene bis(benzotriazolyl phenol)having the formula: ##STR1## wherein: R.sub.1 is selected from the group consisting of hydrogen and alkyl having from one to about eleven carbon atoms;R.sub.2 is selected from the group consisting of alkyl having from one to about twelve carbon atoms; and arylalkyl having from seven to about eighteen carbon atoms; andX is selected from the group consisting of hydrogen; halogen; alkyl having from one to about twelve carbon atoms; aryl alkyl having from seven to about eighteen carbon atoms; alkoxy having from one to about twelve carbon atoms; phenoxy; arylalkoxy having from seven to about eighteen carbon atoms; and phenyl.Type: GrantFiled: December 22, 1986Date of Patent: March 14, 1989Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Yutaka Nakahara, Atsushi Nishimura, Toshio Nakajima
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Patent number: 4812500Abstract: An improved polyolefin pipe or wire and coating composition having improved resistance to deterioration in the presence of chlorinated and nonchlorinated water and having improved resistance to temperatures in the range of about 0.degree. C., as well as in cool water consisting of a blend of:(a) about 93 to about 99.5 percent by weight of an isotactic poly-1-butene polymer;(b) about 0.05 to about 0.50 percent by weight of a hindered amine UV stabilizer;(c) about 0.05 to about 1.1 by weight of a hindered phenolic thermal stabilizer having a molecular weight above 530;(d) about zero to about 0.5 percent by weight of a nucleating agent;(e) about zero to about 4 percent by weight of a pigment;(f) about zero to about 3.0 percent by weight of a filler; and(g) up to about 3.0 percent by weight of a chelating agent.Type: GrantFiled: September 30, 1987Date of Patent: March 14, 1989Assignee: Shell Oil CompanyInventor: Earl E. Hayden
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Patent number: 4804699Abstract: Monomeric and oligomeric derivatives of the dialkyl esters of polyalkyl 1,5-dioxa-9-azaspiro-[5.5]undecane-3,3-diacetic acid are useful light stabilizers for synthetic polymer resins such as polyolefins, and in particular, polypropylene.Type: GrantFiled: May 15, 1987Date of Patent: February 14, 1989Assignee: ICI Americas Inc.Inventors: Richard V. Nelson, John F. Stephen
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Patent number: 4798836Abstract: Bis-(2,2,6,6-tetramethyl-piperidyl)diimides are provided, having the formula: ##STR1## in which R is selected from the group consisting of hydrogen; oxyl; alkyl and alkenyl having from one to about eighteen carbon atoms; epoxy and hydroxyalkyl having from two to about eight carbon atoms; acyl having from two to about eight carbon atoms; and phenalkyl having from seven to about twelve carbon atoms; and Z is a tetravalent aliphatic or cycloaliphatic hydrocarbon group having from two to about eighteen carbon atoms; and stabilizer and synthetic polymer compositions containing such diimides having improved resistance to deterioration when exposed to light.Type: GrantFiled: October 26, 1987Date of Patent: January 17, 1989Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Motonobu Minagawa, Yutaka Nakahara, Bunji Hirai, Kazuo Sugibuchi
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Patent number: 4785034Abstract: A stabilized polyolefin resin composition in which (a) 0.005-5% by weight of at least one monofunctional or polyfunctional cyanate ester compound having at least one cyanato group in its molecule, (b) 0.01-5% by weight of at least one hindered amine ultraviolet absorber and (c) 0.005-2% by weight of at least one hindered phenolic antioxidant are incorporated into a polyolefin resin is disclosed. The resin composition has excellent heat stability and resistance to weathering.Type: GrantFiled: March 3, 1987Date of Patent: November 15, 1988Assignees: Mitsubishi Gas Chemical Company, Inc., Dainichiseika Color & Chemicals Mfg. Co. Ltd.Inventors: Morio Gaku, Hidenori Kimbara, Akira Yahagi, Takaaki Osanai
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Patent number: 4780494Abstract: An aqueous dispersion comprising one or more 2,2,6,6-tetraalkylpiperidine compounds having a molecular weight 2000 or less than 2000 and a melting point of 100.degree. C. or more, one or more cationic, non-ionic and/or anionic dispersing agents and an aqueous medium. These dispersions are suitable for use as light stabilizers in aqueous systems.Type: GrantFiled: April 11, 1985Date of Patent: October 25, 1988Assignee: Sandoz Ltd.Inventors: Erwin Hess, Rainer Wolf
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Patent number: 4780492Abstract: A liquid concentrate comprising an oxamide and a 2,2,6,6-tetraalkylpiperidine compound dissolved in an organic solvent is useful for the UV-stabilization of hardenable liquid finishes, particularly automotive finishes.Type: GrantFiled: December 22, 1986Date of Patent: October 25, 1988Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4780493Abstract: Novel piperidine compounds of the general formula (I) ##STR1## in which m is an integer from 1 to 4, R.sub.1 and R.sub.2 are as defined in claim 1 and at least one 2,2,6,6-tetramethylpiperidinyl group, being present in R.sub.1 or R.sub.2 are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic material, especially for synthetic polymers.Type: GrantFiled: April 22, 1986Date of Patent: October 25, 1988Assignee: Ciba-Geigy CorporationInventors: Giuseppe Cantatore, Valerio Borzatta
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Patent number: 4778837Abstract: A method of stabilizing an acid cured coating formulation against photo and/or thermal degradation without adverse effect on acid cure is disclosed. The method discloses incorporating a stabilizingly effective amount of a hindered amine light stabilizer (HALS) represented by Formula I: ##STR1## wherein R is a saturated or unsaturated, optionally alkyl- or alkenyl-substituted alkylene or cycloalkylene radical having 2-20 C-atoms and R' is selected from the group consisting of:hydrogen;an alkyl radical having 1-20 C-atoms;an alkenyl radical having 3-5 C-atoms;an aralkyl radical having 7-12 C-atoms;--CH.sub.2 --CH.sub.2 --CN;--CH.sub.2 --COO--alkyl;--CH.sub.2 --CH(CH.sub.3)--COO--alkyl; an acyl radical; and--(CH.sub.2 --CH.sub.2 O).sub.n H, wherein n can be 1-10.Also disclosed is an acid cured coating composition stabilized against photo and/or thermal degradation. The composition comprises: a stabilizingly effective amount of HALS represented by Formula I above.Type: GrantFiled: December 24, 1986Date of Patent: October 18, 1988Assignee: American Cyanamid CompanyInventors: Paul S. Waterman, Frank F. Loffelman
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Patent number: 4778838Abstract: Siliconic compounds, stabilizer for organic polymers, containing in their molecule the aromatic phosphite or phosphonite function and the sterically hindered aminic function, are obtained by making a 2,2,6,6-tetramethyl-piperidinyl-4-oxyalkylene-.gamma.-alkyl-di(alkyloxy)si lane, an aliphatic glycol, an aromatic phosphite, phosphonite or diphosphite and possibly an aliphatic mono-hydroxy alcohol interact with each other.Type: GrantFiled: May 1, 1987Date of Patent: October 18, 1988Assignee: Enichem Sintesi S.p.A.Inventors: Alberto Greco, Carlo Busetto
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Patent number: 4774332Abstract: A compopund containing one or more units of formula I ##STR1## in which R.sub.1 is --CH.sub.2 C.sub.1-4 alkyl or --CH.sub.3 or both groups R.sub.1 form --(CH.sub.2).sub.5 --;R.sub.2 is --CH.sub.2 C.sub.1-4 alkyl or --CH.sub.3 or both groups R.sub.2 form --(CH.sub.2).sub.5 --;R.sub.3 is furylmethyl, unsubstituted C.sub.1-18 alkyl; C.sub.1-4 alkyl monosubstituted by phenyl, the phenyl group of which is unsubstituted or substituted by 1 to 3 groups selected from --OH and C.sub.1-8 alkyl; C.sub.2-8 alkyl monosubstituted by C.sub.1-4 alkoxy; phenyl, unsubstituted or substituted by 1 to 3 groups selected from C.sub.1-8 alkyl and --OH; or cyclohexy, unsubstituted or monosubstituted by C.sub.1-8 alkyl or --OH.These compounds are useful as light stabilizers for polymeric material.Type: GrantFiled: July 11, 1986Date of Patent: September 27, 1988Assignee: Sandoz, Ltd.Inventor: Lajos Avar
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Patent number: 4772708Abstract: Derivatives of 4-hydroxy-methyl-piperidine having general formula: ##STR1## wherein: R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be alkyl or may form, with the carbon they are bound to, a cycloalkyl group or the group ##STR2## with R.sub.6, R.sub.7, R.sub.8 and R.sub.9 being hydrogen or alkyl; R.sub.5 may be H, alkyl, aryl, alkenyl, etc.; Y may be an organic or inorganic group or atom having a valence from 1 to 4 and n is an integer from 1 to 4.The use of the derivatives of the alkyl-substituted 4-hydroxy-methyl-piperidine of formula (I) as stabilizers of polymeric substances, and polymeric compositions stabilized with said piperdine derivatives.This invention relates to new derivatives of alkyl-substituted 4-hydroxy-methyl-piperidine, to the use thereof as stabilizers of polymeric substances usually subject to worsening owing to thermal and/or photo-oxidation, and to the polymeric compositions stabilized with said derivatives.Type: GrantFiled: March 20, 1987Date of Patent: September 20, 1988Assignee: Ausimont S.p.A.Inventors: Piero Di Battista, Gilberto Nucida
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Patent number: 4769177Abstract: Electrically conductive or antistatic polymers containing charge transfer complexes corresponding to general formula ID A.sub.n (I)wherein D represents an electron donor; A represents an electron acceptor; and n represents an integer of from 1 to 5; wherein the charge transfer complexes are in the form of fibre- or needle-like crystals having a diameter-to-length ratio of from 1:20 to 1:500, preferably from 1:20 to 1:200, and a process for the production of these polymers wherein a solution of the donor or a donor salt in a suitable solvent and a solution of the acceptor or an acceptor salt are successively added in this order or in the reverse order to a monomer, a soluble polymer preliminary stage or a polymer solution and the solid charge transfer complexes thus produced in the polymer or its preliminary stage.Type: GrantFiled: May 13, 1982Date of Patent: September 6, 1988Assignee: Bayer AktiengesellschaftInventors: Jurgen Hocker, Rolf Dhein, Rudolf Merten
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Patent number: 4757102Abstract: Various substituted aminoxy alkylamine derivatives are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants and/or metal salts of fatty acids and/or hindered amine light stabilizers and/or organic phosphorus compounds; and certain of said derivatives as new compounds.Type: GrantFiled: May 12, 1986Date of Patent: July 12, 1988Assignee: Ciba-Geigy CorporationInventors: Ramanathan Ravichandran, Stephen D. Pastor, Thomas E. Snead
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Patent number: 4757103Abstract: Self-extinguishing polycarbonates consisting of mixtures of polycarbonates with at least one salt of particular carboxylic organic compounds, said salt being of metals of Group I A and/or B, and/or Group II A and/or B of the Periodic Table of elements, and/or of ammonium.Type: GrantFiled: October 23, 1986Date of Patent: July 12, 1988Assignee: Anic, S.p.A.Inventors: Giovanni Dozzi, Salvatore Cucinella, Giorgio Della Fortuna
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Patent number: 4753979Abstract: Compounds of the formula (T).sub.g -E where T is a substituted 4-acyl-2-piperazinone group, g is 1 or 2 and E is a selected terminal or linking group, are effective light stabilizers for polyolefins and other organic polymers, particularly thermoset acrylic or alkyd acrylic resins.Type: GrantFiled: November 12, 1986Date of Patent: June 28, 1988Assignee: Ciba-Geigy CorporationInventors: Thomas E. Conetta, Roger F. Malherbe, Roland A. E. Winter
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Patent number: 4751073Abstract: 2,2,6,6-tetraalkyl-4-piperidinyl derivatives and, more specifically, the N,N'-bis(2,2,6,6-tetraalkyl-4-piperidene)2,2'-diamino-2,2'-dihydrocarbyl divinyl ketones wherein the alkyl groups have independently from one to about eight carbon atoms and said hydrocarbyl moieties are selected from the group consisting of alkyls having between one and about eight carbon atoms, aryl, alkaryl, and aralkyl groups having between one and about twenty carbon atoms.These compounds are useful as UV light stabilizers in plastics and cosmetics (e.g. sunscreens).Type: GrantFiled: June 3, 1987Date of Patent: June 14, 1988Assignee: Olin CorporationInventor: Robert J. Raynor
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Patent number: 4749734Abstract: The present invention relates generally to semi-crystalline polymers which are suitable for stabilization by irradiation sterilization. More particularly, the present invention relates to improved additives for semi-crystalline polymers, such as propylene polymer compositions, to improve the properties of the polymer when subject to irradiation.Type: GrantFiled: January 31, 1985Date of Patent: June 7, 1988Assignee: Becton, Dickinson and CompanyInventors: Joel L. Williams, Terry S. Dunn
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Patent number: 4740542Abstract: A method of stabilizing a polymer film coating or molded article against the action of light, moisture, and oxygen is disclosed. The method comprises incorporating in said polymer a stabilizingly and synergistically effective amount of:(A) A 2,2,6,6-tetraalkylpiperidine compound, or the acid addition salts or complexes with metal compounds thereof; and(B) A tris-aryl-s-triazine compound represented by the formula: ##STR1## wherein X, Y and Z are each aromatic, carbocylic radicals of less than three 6-membered rings, and at least one of X, Y and Z is substituted by a hydroxy group ortho to the point of attachment to the triazine ring; and each of R.sup.1 through R.sup.9 is selected from the group consisting of hydrogen, hydroxy, alkyl, alkoxy, sulfonic, carboxy, halo, haloalkyl and acylamino.Type: GrantFiled: August 11, 1986Date of Patent: April 26, 1988Assignee: American Cyanamid CompanyInventor: Peter V. Susi
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Patent number: 4731393Abstract: s-Triazine compounds, the molecule of which contains at least one ethylenically unsaturated group and at least one 2,2,6,6-tetramethylpiperidine group can be grafted onto organic polymers, in particular onto polyolefines, in the presence of free-radical formers or by means of irradiation. Examples of free-radical formers are peroxy or azo compounds. If polyunsaturated piperidine-triazine compounds are used, it is also possible to achieve crosslinking of the polymer, particularly in the case of polyethylene.Type: GrantFiled: June 11, 1986Date of Patent: March 15, 1988Assignee: Ciba-Geigy CorporationInventors: Friedrich Karrer, Peter Hofmann
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Patent number: 4730017Abstract: A compound useful as a light-stabilizer for polymeric material of formula I ##STR1## in which R is hydrogen, oxygen, C.sub.1-8 alkyl or --CO--R.sub.5, where R.sub.5 is --C(R.sub.10).dbd.CH.sub.2, C.sub.1-6 alkyl, phenyl, --CO--O--C.sub.1-4 alkyl or --NR.sub.7 R.sub.8 and where R.sub.7 is hydrogen, C.sub.1-12 alkyl, C.sub.5-6 -cycloalkyl, phenyl, phenylC.sub.1-4 alkyl or C.sub.1-12 alkylphenyl and R.sub.8 is C.sub.1-12 alkyl or hydrogen;each R.sub.1, independently, is --CH.sub.3 or --CH.sub.2 (C.sub.1-4 alkyl) or both groups R.sub.1 form a group --(CH.sub.2).sub.5 --;each R.sub.2, independently, is --CH.sub.3 or --CH.sub.2 (C.sub.1-4 alkyl) or both groups R.sub.2 form a group --(CH.sub.2).sub.5);R.sub.10 is hydrogen or C.sub.1-4 alkyl; andR.sub.4 is an amide- or ester-forming group.Type: GrantFiled: September 12, 1986Date of Patent: March 8, 1988Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4730015Abstract: A polyacetal resin composition comprises a polyacetal resin as the matrix, (A) 0.01 to 2.0 percent by weight of a stabilizer selected from a benzotriazole compound, a benzophenone compound and an aromatic benzoate compound and (B) 0.01 to 2.0 percent by weight of a hindered amine compound and is improved in whetherability.Type: GrantFiled: July 22, 1985Date of Patent: March 8, 1988Assignee: Polyplastics Co., Ltd.Inventors: Yukio Ikenaga, Masami Yamawaki, Kunio Suzuki
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Patent number: 4727100Abstract: A coating composition useful as an exterior for automobiles and trucks and as a refinish composition containing a film forming binder and a carrier for the binder; wherein the binder contains(1) a reactive component of the formula ##STR1## where R is a divalent or trivalent aliphatic or cycloaliphatic group,R.sup.1 is an alkyl group having 1-4 carbon atomsn is 2-3(2) a hydroxy containing acrylic polymer having drying oil fatty acid moieties and a hydroxyl number of 20-500 and(3) an organo metallic alkylate selected from the group of an aluminum, titanium, zirconium alkylate, or mixtures thereof.The composition can be applied by conventional techniques such as spraying and cures at ambient temperatures or can be baked at relatively low temperatures.Type: GrantFiled: August 15, 1986Date of Patent: February 23, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Joseph A. Vasta
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Patent number: 4727099Abstract: A coating composition containing a film forming binder and a carrier for the binder; wherein the binder consists essentially of(1) a reactive polyurethane of the formula ##STR1## where R is a divalent or trivalent aliphatic or cycloaliphatic group,R.sup.1 is an alkyl group having 1-4 carbon atoms, n is 2-3;(2) a hydroxy containing polymer having a hydroxyl number of 50-200 and having pendent ester groups;(3) an organo metallic alkylate catalyst selected from the group of an aluminum alkylate, zirconium alkylate, titanium alkylate or mixtures thereof.The composition can be applied by conventional techniques such as spraying and can be cured at relatively low baking temperatures.Type: GrantFiled: August 15, 1986Date of Patent: February 23, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Joseph A. Vasta
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Patent number: 4721744Abstract: Polyurethanes are stabilized against yellowing by incorporating a phenolic type compound represented by the general formula (I) ##STR1## wherein R.sub.1 represents a C.sub.1 -C.sub.3 alkyl group and at least one member selected from a benzotriazole type light stabilizer and a hindered amine type stabilizer.Type: GrantFiled: March 31, 1986Date of Patent: January 26, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Tamaki Ishii, Shinichi Yachigo, Manji Sasaki, Haruki Okamura, Masahisa Shionoya
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Patent number: 4717745Abstract: Polyacetal resin compositions are stabilized to heat, oxygen and light by incorporation a phenolic type compound represented by the formula ##STR1##Type: GrantFiled: April 4, 1986Date of Patent: January 5, 1988Assignee: Sumitomo Chemical Company, Ltd.Inventors: Tamaki Ishii, Shinichi Yachigo, Manji Sasaki, Haruki Okamura, Masahisa Shionoya
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Patent number: 4710527Abstract: Malonate-based spiroacetals of polyalkylpiperidin-4-ones are useful light stabilizers for synthetic polymer resins such as polyolefins, and in particular, polypropylene.Type: GrantFiled: August 29, 1986Date of Patent: December 1, 1987Assignee: ICI Americas Inc.Inventors: Richard V. Nelson, John F. Stephen
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Patent number: 4703073Abstract: Alkylated N,N-dibenzylhydroxylamine derivatives are effective in stabilizing polyolefin compositions containing a stabilizer or mixture of stabilizers selected from the group consisting of the phenolic antioxidants, the hindered amine light stabilizers, the alkylated hydroxybenzoate light stabilizers, the ultraviolet light absorbers, the organic phosphorus compounds, the alkaline metal salts of fatty acids and the thiosyner-gists, against degradation upon high temperature extrusion, exposure to the combustion products of natural gas, gamma irradiation or upon storage for extended periods.Type: GrantFiled: September 15, 1986Date of Patent: October 27, 1987Assignee: Ciba-Geigy CorporationInventors: Roland A. E. Winter, Ramanathan Ravichandran, Raymond Seltzer
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Patent number: 4701485Abstract: Malonate-derived acetal esters and amides possessing the polyalkyl piperidin-4-yl moiety are useful light stabilizers with synthetic polymer resins such as polyolefins and, in particular, polypropylene.Type: GrantFiled: August 6, 1986Date of Patent: October 20, 1987Assignee: ICI Americas Inc.Inventors: Richard V. Nelson, John F. Stephen
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Patent number: 4696959Abstract: A composition of matter contains as a principal component a material which acts as an ultraviolet light stabilizer. The ultraviolet light stabilizer is formed from the reaction of (a) a methylol or alkoxy alkyl-containing material, and (b) an alkyl substituted piperidine containing material which is represented by the following structural formula: ##STR1## R" is hydrogen or C.sub.1 to C.sub.6 alkyl, R.sub.10 is hydrogen or methyl,Y is a radical derived from a material selected from the group consisting of amino substituted triazines, ureas, glycolurils, phenols, and amides of the formula ##STR2## R' is hydrogen or C.sub.1 to C.sub.12 alkyl and R is an aliphatic, cycloaliphatic, or olefinic radical, or an acrylic polymer moiety having at least one group selected from hydroxyl, carboxyl, amido, and ureido, said reaction proceeding between a methylol or alkoxy alkyl group of (a) and the group selected from hydroxyl, carboxyl, amido and ureido of (b).Type: GrantFiled: September 26, 1983Date of Patent: September 29, 1987Assignee: PPG Industries, Inc.Inventors: Wen-Hsuan Chang, Michael M. Chau, Robert Piccirilli
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Patent number: 4692486Abstract: Low-molecular and high-molecular polyalkylpiperidines are suitable as a synergistic mixture for stabilizing organic material, in particular organic polymers. The compounds are substances known per se. Thus, for example, the mixture of ##STR1## is distinguished by a pronounced synergism.Type: GrantFiled: July 21, 1986Date of Patent: September 8, 1987Assignee: Ciba-Geigy CorporationInventor: Francois Gugumus
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Patent number: 4690963Abstract: Monomeric and oligomeric derivatives of the diethyl ester of polyalkyl 1,4-dioxa-8-azaspiro-[4.5]-decane-2,3-dicarboxylic acid are useful light stabilizers for synthetic polymer resins such as polyolefins, and in particular, polypropylene.Type: GrantFiled: September 2, 1986Date of Patent: September 1, 1987Assignee: ICI Americas Inc.Inventors: Richard V. Nelson, John F. Stephen
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Patent number: 4691015Abstract: Hydroxylamines derived from hindered amines are effective in stabilizing polyolefin compositions containing a stabilizer or mixture of stabilizers selected from the group consisting of the phenolic antioxidants, the hindered amine light stabilizers, the alkylated hydroxybenzoate light stabilizers, the ultraviolet light absorbers, the organic phosphorus compounds, the alkaline metal salts of fatty acids and the thiosynergists, against degradation upon high temperature extrusion, exposure to the combustion products of natural gas, gamma irradiation or upon storage for extended periods.Type: GrantFiled: March 21, 1985Date of Patent: September 1, 1987Assignee: Ciba-Geigy CorporationInventors: Rudolf A. Behrens, Raymond Seltzer
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Patent number: 4689360Abstract: Oligomeric derivatives of the dialkyl esters of polyalkyl 1,5-dioxa-9-azaspiro-[5.5]undecane-3,3-dicarboxylic acid are useful light stabilizers for synthetic polymer resins such as polyolefins, and in particular, polypropylene.Type: GrantFiled: September 4, 1986Date of Patent: August 25, 1987Assignee: ICI Americas Inc.Inventors: Richard V. Nelson, John F. Stephen
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Patent number: 4687800Abstract: Tartrate-derived acetal esters and amides possessing the polyalkyl piperidin-4-yl moiety are useful light stabilizers with synthetic polymer resins such as polyolefins and, in particular, polypropylene.Type: GrantFiled: September 2, 1986Date of Patent: August 18, 1987Assignee: ICI Americas Inc.Inventors: Richard V. Nelson, John F. Stephen
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Patent number: 4681905Abstract: Stabilizer compositions for synthetic resins are provided, improving the resistance of the resin to deterioration when exposed to ultraviolet light, comprising a 2,2,6,6-tetramethylpiperidyl compound and an alkylidene-bis-(benzotriazolyl phenol) having the formula: ##STR1## wherein: R.sub.1 is hydrogen or alkyl having from one to about twelve carbon atoms;R.sub.2 is alkyl having from one to about twelve carbon atoms or arylalkyl having from seven to about sixteen carbon atoms;X is selected from the group consisting of hydrogen, halogen, alkyl having from one to about twelve carbon atoms, aryl having from six to ten carbon atoms, arylalkyl having from seven to about sixteen carbon atoms, alkoxy having from one to about twelve carbon atoms, aryloxy having from six to ten carbon atoms; and arylalkoxy having from seven to about sixteen carbon atoms; as well as synthetic resin compositions containing such stabilizers.Type: GrantFiled: November 6, 1985Date of Patent: July 21, 1987Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Naohiro Kubota, Atsushi Nishimura
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Patent number: 4670488Abstract: The present invention relates to a piperidine derivative represented by the general formula (I), ##STR1## wherein R.sub.1 and R.sub.2 independently represent a hydrogen atom or a C.sub.1 -C.sub.3 alkyl or C.sub.2 -C.sub.20 acyl group, R.sub.3 represents a hydrogen atom or a C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.20 aryl, C.sub.7 -C.sub.20 aralkyl or C.sub.2 -C.sub.20 acyl group, and l represents 1 to 3, and a stabilizer for organic substances containing said piperidine derivative as an effective ingredient.Type: GrantFiled: December 4, 1985Date of Patent: June 2, 1987Assignee: Sumitomo Chemical Co., Ltd.Inventors: Yuzo Maegawa, Yukoh Takahashi, Eizo Okino, Tatsuo Kaneoya, Haruki Okamura, Shinichi Yachigo, Tamaki Ishii
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Patent number: 4670493Abstract: Stabilized against degradation by oxidizing liquids, based on polymers of alpha-olefins such as propylene, containing a phenolic antioxidant, a phosphonite and a sulfur-containing stabilizer chosen from the esters derived from aliphatic polyols and alkylthiodipropionic acids and from combinations of a metal sulfide with one of these esters or with an organic polysulfide and optionally also containing an organic phosphite and an anti-acid agent. These compositions exhibit outstanding resistance to the phenomenon of oxidative degradation produced particularly by the contact with hot washing products of all kinds.Type: GrantFiled: January 4, 1985Date of Patent: June 2, 1987Assignee: Solvay & Cie (Societe Anonyme)Inventors: Roger Van Asbroeck, Serge Blanc
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Patent number: 4670489Abstract: The present invention relates to a piperidine derivative represented by the general formula (I), ##STR1## wherein R.sub.1 is a uni- or divalent carboxylic acid residue, R.sub.2 is a hydrogen atom or a C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.18 acyl group, l is an integer of 1 to 3 and n is 1 or 2,its production and a stabilizer for organic substances containing it as an effective ingredient.Type: GrantFiled: December 5, 1985Date of Patent: June 2, 1987Assignee: Sumitomo Chemical Company, Ltd.Inventors: Yukoh Takahashi, Tatsuo Kaneoya, Eizo Okino, Yuzo Maegawa, Haruki Okamura, Shinichi Yachigo, Tamaki Ishii
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Patent number: 4668721Abstract: N,N-Dibenzylhydroxylamine and other selected hydroxylamine derivatives are effective in stabilizing polyolefin compositions containing a stabilizer or mixture of stabilizers selected from the group consisting of the phenolic antioxidants, the hindered amine light stabilizers, the ultraviolet light absorbers, the organic phosphorus compounds, the alkaline metal salts of fatty acids and the thiosynergists, against degradation upon high temperature extrusion, exposure to the combustion products of natural gas, gamma irradiation or upon storage for extended periods.Type: GrantFiled: February 3, 1986Date of Patent: May 26, 1987Assignee: Ciba-Geigy CorporationInventors: Raymond Seltzer, Ambelal R. Patel, Peter W. Stewart, Charlene White
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Patent number: 4668722Abstract: New hindered piperidinoalcohol 1,1,1-trioxyalkanes are disclosed. In the 1,1,1-trioxyalkanes, at least on 1,1,1-trioxyalkane group is linked to the residue of an alcohol linked to the 4-position of a 2,2,6,6-tetraalkylpiperidine compound having 12 to 75 carbon atoms. For each 1,1,1-trioxalkane group, there are 1 to 3 tetraalkylpiperidine groups. The alkyl groups linked to the piperidine ring have from one to five carbon atoms each. The fourth substituent on the carbon atom of the 1,1,1-trioxyalkane is a hydrogen atom or an aliphatic group having one to five carbon atoms.The disclosed 1,1,1-trioxyalkanes protect a variety of synthetic resins against the deteriorative effects of exposure to actinic light.Stabilizer compositions comprising a disclosed 1,1,1-trioxyalkane and a known polymer stabilizer, as well as synthetic resin compositions stabilized with such stabilizer compositions, are also disclosed.Type: GrantFiled: December 13, 1985Date of Patent: May 26, 1987Inventor: Gerry P. Mack
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Patent number: 4666962Abstract: Substituted aminoxy propanoate derivatives corresponding to the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants and/or metal salts of fatty acids and/or hindered amine light stabilizers and/or organic phosphorus compounds; and certain of said derivatives as new compounds.Type: GrantFiled: April 4, 1986Date of Patent: May 19, 1987Assignee: Ciba-Geigy CorporationInventors: Ramanathan Ravichandran, Thomas E. Snead
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Patent number: 4666959Abstract: A propylene polymer molding composition which is resistant to discoloration and losses in physical properties upon sterilization by high energy radiation is comprised of a blend of a propylene polymer with small amounts of a polymeric hindered amine, an alkyl phosphite and a specific hindered phenolic antioxidant as necessary additives.Type: GrantFiled: December 10, 1985Date of Patent: May 19, 1987Assignee: El Paso Products CompanyInventors: Paula S. Weissberger, Bennie M. Lucas
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Patent number: 4665112Abstract: Polyphenylene ether resins can be stabilized against the adverse influence of ultraviolet light by incorporating into the resin an effective amount of a benzofuran UV absorber.Type: GrantFiled: January 2, 1986Date of Patent: May 12, 1987Assignee: General Electric CompanyInventor: Donald R. Berdahl
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Patent number: 4650870Abstract: Compounds of the formula (T).sub.g -E where T is a substituted 4-acyl-2-piperazinone group, g is 1 or 2 and E is a selected terminal or linking group, are effective light stabilizers for polyolefins and other organic polymers.Type: GrantFiled: March 12, 1984Date of Patent: March 17, 1987Assignee: Ciba-Geigy CorporationInventors: Thomas E. Conetta, Roger F. Malherbe, Roland A. E. Winter
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Patent number: 4649167Abstract: Compounds having the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 are independently selected from hydrocarbons, n is an integer of 1 to 15, and Y is H, OH, O, R where R is a hydrocarbon are useful as stabilizers for polymers against the detrimental effects produced by exposure to actinic radiation, such as visible or ultraviolet light rays.Type: GrantFiled: November 14, 1985Date of Patent: March 10, 1987Assignee: Pennwalt CorporationInventors: Ludwig K. Huber, James L. Reilly