Two Or More Chalcogen Rings Patents (Class 524/109)
  • Patent number: 4451594
    Abstract: A method of emulsifying an unsaturated diallylphthalate-based resin to form a continuous water phase emulsion which involves mixing a diallylphthalate-based resin with a specified emulsifying agent, adding water and agitating to form an emulsion in which the aqueous phase is the continuous phase.
    Type: Grant
    Filed: March 10, 1983
    Date of Patent: May 29, 1984
    Assignee: Owens-Corning Fiberglas Corporation
    Inventor: Leslie E. Campbell
  • Patent number: 4447569
    Abstract: Polyvinyl chloride resin compositions are provided, suitable for use as electrical insulation material, having a high volume resistivity and a high resistance to deterioration when heated at temperatures above 100.degree. C., comprising as the essential ingredients a polyvinyl chloride resin and, in the amounts indicated, in parts per one hundred of resin, from about 30 to about 100 parts mono or poly carboxylic acid ester plasticizer; from about 5 to about 25 parts filler; from about 1 to about 20 parts epoxy compound, and from about 1 to about 20 parts lead alkyl phenolate.
    Type: Grant
    Filed: October 8, 1982
    Date of Patent: May 8, 1984
    Assignee: Argus Chemical Corporation
    Inventors: Lawrence R. Brecker, Charles Keeley, Stuart D. Brilliant
  • Patent number: 4446264
    Abstract: Compounds prepared by reacting maleic anhydride, maleic acid or their esters with thiols; which exhibit a synergistic effect when combined with a phenolic antioxidant in the stabilization of organic materials such as natural and synthetic polymers, rubbers, lubricants and oil, etc. are disclosed.
    Type: Grant
    Filed: April 15, 1982
    Date of Patent: May 1, 1984
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Kirkwood S. Cottman
  • Patent number: 4438228
    Abstract: Filled thermoplastic compositions useful, e.g., as sound-deadening sheeting for automotive carpet are obtained by blending about 5-55% by weight of ethylene/.alpha.-olefin copolymer, the .alpha.-olefin containing from 4 to 10 carbon atoms; about 2-12% by weight of plasticizer selected from the group consisting of processing oils, epoxidized oils, polyesters, polyethers and polyether esters; about 40-90% by weight of filler; and optionally elastomeric polymers.
    Type: Grant
    Filed: June 15, 1981
    Date of Patent: March 20, 1984
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Timothy T. Schenck
  • Patent number: 4438229
    Abstract: A thermoplastic composition which comprises a blend comprising 20 to 80% by weight of a polycarbonate resin and 80 to 20% by weight of a graft polymer obtained by grafting at least one aromatic vinyl compound and at least one of vinyl cyanides and alkyl unsaturated carboxylates onto a conjugated diene rubber or its mixture with a copolymer of at least one aromatic vinyl compound and at least one of vinyl cyanides and alky unsaturated carboxylates in an amount of not more than 90% by weight on the basis of the combined amount of the graft polymer and the copolymer, and a polyolefin or a plasticizer having a light transmission of not less than 70% when determined on the film of 20 microns in thickness prepared by the use of a solution of the plasticizer (0.25 g) and acrylonitrile-styrene copolymer (weight ratio of acrylonitrile and styrene, 30:70; 0.75 g) in acetone (10 ml), the weight proportion of the blend and the polyolefin or the plasticizer being 100:0.2-20.
    Type: Grant
    Filed: September 8, 1982
    Date of Patent: March 20, 1984
    Assignees: Sumitomo Naugatuck Co., Ltd., Honda Motor Co., Ltd.
    Inventors: Yoshitugu Fujimori, Yasuo Takabori, Hajime Sakano, Akitoshi Ito
  • Patent number: 4434261
    Abstract: Extrudable, self-supporting, nonblocking hot melt adhesive sheet is obtained by blending about 10-50% by weight of an ethylene interpolymer, such as ethylene/vinyl ester, ethylene/unsaturated mono- or dicarboxylic acids or esters of said unsaturated acids, etc.; 2-30% by weight of a plasticizer selected from the group consisting of processing oils, epoxidized oils, polyesters, polyethers, polyether esters and combinations thereof; about 20-80% by weight of filler; from 0 to about 10% by weight of at least one additive, such as organic acids, organic acid derivatives and surface active agents.
    Type: Grant
    Filed: August 6, 1982
    Date of Patent: February 28, 1984
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Edward G. Brugel, Walter Yllo
  • Patent number: 4434258
    Abstract: Filled thermoplastic compositions having enhanced elongation and useful, e.g., as sound-deadening sheeting for automotive carpet, are obtained by blending about 0-50% by weight of an ethylene interpolymer, such as ethylene/vinyl ester, ethylene/unsaturated mono- or dicarboxylic acids or esters of said unsaturated acids, etc.; 0-20% by weight of a plasticizer selected from the group consisting of processing oils, epoxidized oils, polyesters, polyethers, polyether esters and combinations thereof; about 40-90% by weight of filler; from about 0.05 to about 5.
    Type: Grant
    Filed: January 15, 1982
    Date of Patent: February 28, 1984
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Frederick G. Schumacher, Walter Yllo
  • Patent number: 4431762
    Abstract: A resin composition containing at least one compound (A) selected from compounds of formulas ##STR1## wherein R.sub.1 and R.sub.2 each denote a hydrogen atom, halogen atom, or alkyl or alkoxy group having 1 to 10 carbon atoms, ##STR2## R.sub.3 denotes a hydrogen atom, alkyl group containing 1 to 10 carbon atoms, naphthyl group or substituent of formula ##STR3## wherein R.sub.4 to R.sub.8, which may be the same or different, each denote a hydrogen atom, halogen atom, nitro group and alkyl or alkoxy group having 1 to 10 carbon atoms.
    Type: Grant
    Filed: July 21, 1982
    Date of Patent: February 14, 1984
    Assignee: Dainippon Ink & Chemicals Inc.
    Inventors: Shingo Araki, Keizo Asai, Seibei Ono
  • Patent number: 4430468
    Abstract: Filled thermoplastic compositions having enhanced elongation and useful, e.g., as sound-deadening sheeting for automotive carpet, are obtained by blending about 0-50% by weight of an ethylene interpolymer, such as ethylene/vinyl ester, ethylene/unsaturated mono- or dicarboxylic acids or esters of said unsaturated acids, etc.; 0-20% by weight of a plasticizer selected from the group consisting of processing oils, epoxidized oils, polyesters, polyethers, polyether esters and combinations thereof; about 40-90% by weight of filler; from about 0.05 to about 5.0% by weight of at least one surface active agent such as sulfonates, sulfates, phosphates, etc.; and optionally, modifying resins, such as tackifiers and certain ethylene and propylene homo- and copolymers.
    Type: Grant
    Filed: July 21, 1982
    Date of Patent: February 7, 1984
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Frederick G. Schumacher
  • Patent number: 4418168
    Abstract: Improved stability is imparted to suspension and emulsion polymerized dry particulate vinylidene chloride resin by adding thereto a dispersion of an oil insoluble inorganic particulate stabilizing additive in a liquid plasticizer/stabilizer medium with sufficient mixing to ensure generally uniform distribution of the dispersion onto the resin particles. Optionally, a hindered phenol may be incorporated into the dispersion.
    Type: Grant
    Filed: March 18, 1982
    Date of Patent: November 29, 1983
    Assignee: The Dow Chemical Company
    Inventor: Earl H. Johnson
  • Patent number: 4401774
    Abstract: A thermosetting binder composition for coating, comprising:(I) (1) A non-acidic resinous saturated compound having a molecular weight of at least 900, and an alcoholic hydroxyl content of at least 0.2 eq./100 g;(2) A non-acidic polyester of a polycarboxylic acid crosslinking agent having more than one .beta.-hydroxyl ester group per molecule, and at least one of components (1) and (2) having an alcoholic hydroxyl functionality of more than 2, and(II) A transesterification-promoting metal salt or complex curing catalyst which is soluble in liquid hydrocarbons.For aqueous compositions, component (I) (1) is preferably a neutralized epoxy resin/amine adduct and component (II) should be insoluble in water; they can be used for cathodic electrodeposition.
    Type: Grant
    Filed: February 16, 1982
    Date of Patent: August 30, 1983
    Assignee: Shell Oil Company
    Inventors: Petrus G. Kooymans, Johannes J. M. H. Wintraecken, Werner T. Raudenbusch, Josepha M. E. Seelen-Kruijssen, Gerardus C. M. Schreurs
  • Patent number: 4397972
    Abstract: Flame retarded compositions of styrene or para-methylstyrene polymers and containing octahalobiphthalyl, such as octabromobiphthalyl, and inorganic flame retardant, such as antimony trioxide.
    Type: Grant
    Filed: December 30, 1982
    Date of Patent: August 9, 1983
    Assignee: Mobil Oil Corporation
    Inventor: Bruce A. Marien
  • Patent number: 4384055
    Abstract: A hard vinyl chloride resin composition for information signal recording media, said composition consisting essentially of(A) 100 parts by weight of a copolymer having a specific viscosity of 0.16 to 0.31 and composed of 75 to 99% by weight of vinyl chloride, 1 to 10% by weight of ethylene and 0 to 15% by weight of another monomer copolymerizable with said monomers, and/or a polymer mixture having a specific viscosity of 0.16 to 0.31 and composed of at least two polymers selected so that the proportions of monomer components are the same as above, and(B) 15 to 30 parts by weight of carbon black having an oil absorption of 300 to 400 ml/100g and a surface area of at least 900 m.sup.2 /g.
    Type: Grant
    Filed: September 16, 1981
    Date of Patent: May 17, 1983
    Assignee: Nippon Zeon Co. Ltd.
    Inventors: Takao Okuda, Nobuhide Hada
  • Patent number: 4380597
    Abstract: A stabilized thermoplastic composition comprised of polyvinyl chloride or mixed polymers containing mainly vinyl chloride units together with stabilizers and other conventional additives employed in thermoplastic compositions, which have as major stabilizer component, a content of 0.02 to 5 parts by weight of aliphatic polyhydroxyl compounds containing 4 to 6 OH-groups per 100 parts by weight of polymer. These polyhydroxyl compounds should contain at least one carboxyl and/or carbonyl group and/or double bond. Suitable compounds are gluconic acid, glucuronic acid, ketogluconic acid, ascorbic acid or the alkali metal salts or alkaline earth salts of the mentioned acids.Other conventional processing additives may be present. The invention concerns also a process for the manufacture of pipes, profiles, foils, hollow parts by hot forming, with the use of the mentioned additives, and the additional use of paraffin, free fatty acid, epoxidized soybean oil or higher molecular weight ester wax.
    Type: Grant
    Filed: October 21, 1981
    Date of Patent: April 19, 1983
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Werner Erwied, Bernd Wegemund
  • Patent number: 4379876
    Abstract: Methyl methacrylate-butadiene-styrene polymer impact modifiers are improved by mixing them with about 0.01 to 5 percent by weight of a compound of the formula ##STR1## wherein R.sub.1 and R.sub.2 are C.sub.1 to C.sub.4 alkyl, R.sub.3 and R.sub.4 are H, C.sub.1 to C.sub.4 alkyl, or 4'-hydroxy-2'-R.sub.2 -5'-R.sub.1 -phenyl. Polyvinyl chloride (PVC) is mixed with the improved impact modifiers and has improved dispersion and resistance to discoloration.
    Type: Grant
    Filed: July 11, 1980
    Date of Patent: April 12, 1983
    Assignee: Rohm and Haas Company
    Inventors: Richard R. Clikeman, Donald H. Jones, Thomas J. Shortridge, Edward J. Troy
  • Patent number: 4375521
    Abstract: A vegetable oil extended polyurethane system comprising the reaction product of an isocyanate terminated polyisocyanate with a polyol in the presence of a vegetable oil and, optionally, a plasticizer, said polyurethane systems being applicable for use as reenterable encapsulants for sealing insulated electrical devices, as hard, permanent encapsulants and as general polyurethane elastomers.
    Type: Grant
    Filed: June 1, 1981
    Date of Patent: March 1, 1983
    Assignee: Communications Technology Corporation
    Inventor: James M. Arnold
  • Patent number: 4375525
    Abstract: The present invention relates to stable and bright thermoplastic aromatic polycarbonate compositions characterized in the absence of phosphites and boric acid esters and in that they comprise an additive amount of an organic-silicon compound having on its silicon atom three or four organo-oxy radicals.
    Type: Grant
    Filed: May 12, 1980
    Date of Patent: March 1, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karsten Idel, Wolfgang Cohnen, Dieter Freitag, Ottfried Schlak
  • Patent number: 4375520
    Abstract: A procedure is provided for the production of clean, dustless particulate granules from dusty, dirty particles by treatment with a composition comprising a liquid polymeric substance, illustratively, epoxidized soybean oil, and a solid, low molecular weight polymer having a melting point in the range of about 95.degree. to 105.degree. C., illustratively, a polyethylene vinyl acetate copolymer in the proportions of from 1 part of solid polymer to 1 part of liquid polymeric substance to 2 parts of solid polymer to 1 part of liquid polymeric substance. In one modification of the procedure, the ingredients were charged to a Papenmeir mixer and the mixer was run at 1500 RPM until a temperature of 95.degree. C. was reached. The resulting product comprised clean, dustless uniform beads.
    Type: Grant
    Filed: April 10, 1981
    Date of Patent: March 1, 1983
    Assignee: Dart Industries Inc.
    Inventors: Thomas W. Pennie, Sunil S. Parikh, Charles Lowe
  • Patent number: 4371656
    Abstract: A stabilizer for use in a halogen-containing resin is described comprising a crystalline aluminosilicate substituted with ions of a metallic element belonging to Group II or Group IVA of the Periodic Table for Group I (M) metal ion contained in said aluminosilicate and containing 10% by weight of less, as M.sub.2 O, of residual Group I metal ions.
    Type: Grant
    Filed: December 8, 1980
    Date of Patent: February 1, 1983
    Assignees: Nippon Chemical Industrial Co., Ltd., Kosei Co., Ltd.
    Inventors: Kohji Kashiwase, Yasuo Machino, Muneo Mita, Tsunenosuke Hiramatsu, Toshihiko Morishita, Mitsuo Taniguchi
  • Patent number: 4371651
    Abstract: Stabilizer compositions and polyvinyl halide resin compositions containing 1,3-dicarbonyl compounds having the formula: ##STR1## as well as metal and organotin enolate salts thereof, effective in enhancing the resistance to deterioration by heat and light of polyvinyl halide resins.
    Type: Grant
    Filed: January 21, 1981
    Date of Patent: February 1, 1983
    Assignee: Phoenix Chemical Corporation
    Inventors: William E. Leistner, Motonobu Minagawa, Kouji Tsuruga, Masashi Harada
  • Patent number: 4369276
    Abstract: Chlorine-containing thermoplastics, containing a pyrrole of the formula I ##STR1## in which R.sub.1 is hydrogen, alkyl, cycloalkyl, aryl, alkoxycarbonylmethyl, free or esterified .alpha.-hydroxyalkyl, free or esterified .alpha.-hydroxycycloalkylmethyl, free or esterified .alpha.-hydroxyaralkyl, alkoxymethyl, alkylthiomethyl, aryloxymethyl, arylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, aralkylthiomethyl, alkoxy, alkylthio, cycloalkoxy, cycloalkylthio, aralkoxy, arylalkylthio, aryloxy, arylthic, halogen, mercapto, mercaptomethyl or hydroxyl, R.sub.2 is hydrogen, alkyl, cycloalkyl, aryl, free or esterified .alpha.-hydroxyalkyl, in which the alkyl moiety together with R.sub.1 can be alkylene, or free or esterified .alpha.-hydroxycycloalkylmethyl, free or esterified .alpha.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: January 18, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Hermann O. Wirth, Jurgen Bussing, Hans-Helmut Friedrich
  • Patent number: 4368283
    Abstract: Reinforced resin compositions exhibiting excellent heat resistance and appearance, and containing by weight: (a) at least 30% of a polyethylene terephthalate-type resin, (b) 5 to 60% glass fiber, (c) 0.03 to 5% of one or more salts of organic carboxylic acids with metals of the Groups Ia and IIa of the Periodic Table, and (d) 0.1 to 20% of a sorbitan derivative are disclosed. Optionally liquid or solid paraffin or polyethylene wax is incorporated in an amount of 0.3 to 5% based on the total composition may be incorporated if a white article is desired.Molded articles prepared from these compositions, high in heat resistance and uniform appearance, even if the thickness of the molded article is small or uneven or the molding operation is carried out at a relatively low mold temperature, are also disclosed. Molding temperature dependence and thickness dependence on the heat distortion temperature of the molded article are remarkably improved as well.
    Type: Grant
    Filed: June 30, 1981
    Date of Patent: January 11, 1983
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Kazuo Kishida, Isao Sasaki, Hiroshi Mori
  • Patent number: 4367303
    Abstract: Certain solutions of phosphines in oxetane compounds impart oxidative stability to aromatic thermoplastic polycarbonates in which such solutions are admixed.
    Type: Grant
    Filed: June 25, 1981
    Date of Patent: January 4, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Erich Eimers, Rolf Dhein, Wolfgang Cohnen, Engelbert Kuhle, Gerhard Heywang
  • Patent number: 4352903
    Abstract: The invention relates to thermoplastic moulding compositions based on polymers of vinyl chloride and containing 0.1 to 5% by weight of a 2-thio-6-aminouracil of the formula I ##STR1## wherein each of R.sup.1 and R.sup.2 independently is a hydrocarbon radical of 1 to 24 carbon atoms which can be substituted by --OH, --COOR.sup.4, --O(C.dbd.O)R.sup.4, --(C.dbd.O)R.sup.4, halogen or amino, and R.sup.3 is hydrogen, acyl of 2 to 24 carbon atoms or --(C.dbd.O)NHR.sup.4, while R.sup.4 is a hydrocarbon radical of 1 to 24 carbon atoms.
    Type: Grant
    Filed: June 1, 1981
    Date of Patent: October 5, 1982
    Assignee: Ciba-Geigy Corporation
    Inventor: Gerd Abeler
  • Patent number: 4348494
    Abstract: Liquid, solvent-free, non-toxic stabilizers for vinyl chloride resin compositions comprise a major amount of a liquid epoxy compound and minor amounts of magnesium, zinc, and calcium salts of alkanoic acids having 6 to 26 carbon atoms, an organosulfur compound, and an organic phosphite. Vinyl chloride resin compositions that contain these stabilizers are characterized by excellent heat and light stability, color, and clarity.
    Type: Grant
    Filed: June 10, 1980
    Date of Patent: September 7, 1982
    Assignee: Tenneco Chemicals, Inc.
    Inventors: Mahmoud Kheidr, Irene A. E. Fraser
  • Patent number: 4343727
    Abstract: This invention covers a shoe sole composition compounded from polyvinyl chloride and organic cellulosic flock, and the shoe sole product produced therefrom.
    Type: Grant
    Filed: October 24, 1979
    Date of Patent: August 10, 1982
    Assignee: Reichhold Chemicals Incorporated
    Inventor: Arnold Cohen
  • Patent number: 4340514
    Abstract: A non-toxic liquid stabilizer comprising, (a) from about 5 to about 35 percent of zinc resinate, (b) from about 5 to about 35 percent of calcium resinate, (c) from about 10 to about 40 percent of non-toxic plasticizer, (d) from about 1 to about 10 percent of a non-toxic antioxidant, and (e) from about 25 to about 75 percent of a non-toxic phosphite, said stabilizer containing from about 0.1 to about 3.5 percent zinc, and from about 0.025 to about 2.28 percent calcium, all weights being based upon the total weight of the stabilizer, is disclosed. Also disclosed is a similar stabilizer which does not contain phosphite and contains from about 25 to about 90 percent of the plasticizer. A method for stabilizing halogenated hydrocarbon resins utilizing the stabilizers of the present invention is also disclosed.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: July 20, 1982
    Assignee: Interstab Chemicals Inc.
    Inventor: David S. Housel
  • Patent number: 4338244
    Abstract: The present invention relates to a process for stabilizing organic polymeric materials comprising incorporating therein a benzofuran(2)one compound or indolin(2)one compound containing at least two benzofuran(2)one or indolin(2)one nuclei.
    Type: Grant
    Filed: February 4, 1980
    Date of Patent: July 6, 1982
    Assignee: Sandoz Ltd.
    Inventors: Hans Hinsken, Horst Mayerhoefer, Wolfgang Mueller, Hermann Schneider
  • Patent number: 4332711
    Abstract: A thermosetting binder composition for coating, comprising:(I)(1) A non-acidic resinous saturated compound having a molecular weight of at least 900, and an alcoholic hydroxyl content of at least 0.2 eq./100 g;(2) A non-acidic polyester of a polycarboxylic acid crosslinking agent having more than one .beta.-hydroxyl ester group per molecule, and at least one of components (1) and (2) having an alcoholic hydroxyl functionality of more than 2, and(II) A transesterification-promoting metal salt or complex curing catalyst which is soluble in liquid hydrocarbons.For aqueous compositions, component (I) (1) is preferably a neutralized epoxy resin/amine adduct and component (II) should be insoluble in water; they can be used for cathodic electrodeposition.
    Type: Grant
    Filed: December 3, 1979
    Date of Patent: June 1, 1982
    Assignee: Shell Oil Company
    Inventors: Petrus G. Kooymans, Johannes J. M. H. Wintraecken, Werner T. Raudenbusch, Josepha M. E. Seelen-Kruijssen, Gerardus C. M. Schreurs
  • Patent number: 4332716
    Abstract: Novel polymer/polyisocyanate compositions made by polymerizing at least one ethylenically unsaturated monomer in situ in a blend of a first organic polyisocyanate and a stabilizer. The stabilizer comprises a polyoxyalkylene polyol having a number average molecular weight of at least 4000; an isocyanato terminated prepolymer formed by reacting the polyoxyalkylene polyol and a second organic polyisocyanate with the proviso that the isocyanato terminated prepolymer and the first organic polyisocyanate provide greater than 25 equivalents of isocyanato groups per equivalent of hydroxyl groups; a polymer/polyol formed using the polyoxyalkylene polyol; a polymer/prepolymer formed using the polyoxyalkylene polyol with the proviso indicated for the prepolymer above; or a modified polyol containing an ester group formed using the polyoxyalkylene polyol.
    Type: Grant
    Filed: December 10, 1980
    Date of Patent: June 1, 1982
    Assignee: Union Carbide Corporation
    Inventor: Naresh R. Shah