Phosphorus Bonded Directly To Three Chalcogen Atoms And Having Only One P-c Linkage, E.g., Phosphonate, Etc. Patents (Class 524/123)
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Patent number: 10214627Abstract: The invention is directed to a resin composition that has both high heat resistance and high resistance against ultraviolet radiation. The invention is further directed to an article comprising said composition, and to the use of a combination of compounds for stabilising a resin composition. The resin composition of the invention comprises (A) a polypropylene resin, (B) an optionally substituted linear or branched alkyl ester of 3-(alkylated 4?-hydroxyphenyl) propionic acid having a molecular weight of 750 g/mol or less, (C) a hindered amine light stabiliser, having a molecular weight of 1250 g/mol or more, wherein the hindered amine is comprised in the backbone of the hindered amine light stabiliser molecule, and (D) a thiosynergist.Type: GrantFiled: May 13, 2015Date of Patent: February 26, 2019Assignee: SABIC Global Technologies B.V.Inventors: Sarah Van Mierloo, Jacques Theodorus Elisabeth Hubertina Sampers
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Patent number: 10105871Abstract: According to one embodiment, a system for manufacturing a polymethyl methacrylate (PMMA) prepreg includes a mechanism for continuously moving a fabric or mat and a resin application component that applies a methyl methacrylate (MMA) resin to the fabric or mat. The system also includes a press mechanism that presses the fabric or mat during the continuous movement subsequent to the application of the MMA resin to ensure that the MMA resin fully saturates the fabric or mat. The system further includes a curing oven through which the fabric or mat is continuously moved. The curing oven is maintained at a temperature of between 40° C. and 100° C. to polymerize the MMA resin and thereby form PMMA so that upon exiting the curing oven, the fabric or mat is fully impregnated with PMMA.Type: GrantFiled: September 3, 2015Date of Patent: October 23, 2018Assignee: Johns ManvilleInventors: Mingfu Zhang, Klaus Friedrich Gleich, Asheber Yohannes, Michael John Block, Jawed Asrar, Derek Cooper Bristol, Christopher P Sandoval
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Patent number: 9745449Abstract: Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants.Type: GrantFiled: July 22, 2014Date of Patent: August 29, 2017Assignee: LANXESS Solutions US Inc.Inventors: Zachary D. Stockdale, Mark V. Hanson, Larry D. Timberlake, Subramaniam Narayan, William R. Fielding
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Patent number: 9688816Abstract: This disclosure relates to polyetherimide compositions whose residual phenolic monomers exhibit little or no estradiol binding activity. Also disclosed are methods for making the disclosed polyetherimides and articles of manufacture comprising the disclosed polyetherimides.Type: GrantFiled: January 20, 2015Date of Patent: June 27, 2017Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Robert R. Gallucci, James A. Mahood, Roy R. Odle, Steve Dimond
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Publication number: 20150141556Abstract: Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. Various methods for preparing flame retardant materials from more than one phosphonic acid salts are provided, wherein each method can generate different flame retardant materials from the same mixture of starting phosphonic acids. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants.Type: ApplicationFiled: January 8, 2015Publication date: May 21, 2015Inventors: Zachary Stockdale, Mark V. Hanson, Larry D. Timberlake, Subramaniam Narayan, William R. Fielding
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Patent number: 9034958Abstract: A polymer complex is disclosed which is the reaction product of one or more polymers having a terminal or pendant hydroxyl group, or a terminal or pendent carboxyl group, or combinations thereof, with at least one metal complex and one alkyl phosphate. This polymer complex acts as an adhesion promotion agent as well as a viscosity stabilizer when formulated in a printing ink or coating.Type: GrantFiled: November 16, 2004Date of Patent: May 19, 2015Assignee: Sun Chemical CorporationInventors: Mark Andreas Mielke, Mathew Charles Mathew, William P. Keaveney, Richard John Czarnecki, William Ford Wilson, Mark John Lindsey, Ralph Francis Arcurio
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Publication number: 20150040800Abstract: The present invention relates to a method for preparing an aqueous calcium carbonate containing suspension, a suspension comprising a calcium carbonate containing material obtainable by said method as well as a calcium carbonate containing material obtainable by drying said suspension and to the use of the suspension or calcium carbonate containing material in paper, paper coating, plastic and/or paint applications and to the use of the suspension for stabilizing the rheology of a sodium silicate and/or sodium hydroxide containing coating formulations for paper applications.Type: ApplicationFiled: March 26, 2013Publication date: February 12, 2015Applicant: Omya International AGInventors: Patrick A.C. Gane, Daniel Gantenbein
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Patent number: 8933153Abstract: The present invention relates to impact-modified polycarbonate molding compositions, the use thereof for producing shaped bodies and moldings, as well as shaped bodies and molding produced therefrom themselves. Compositions of the present invention comprise mixtures of graft polymers prepared in the emulsion polymerization process and in the bulk, solution and/or suspension polymerization process having a defined grafted particle size distribution. Compositions of the present invention, on the one hand are suitable for producing, over a wide processing window, (i.e. also at high processing temperatures), non-lacquered components having a high gloss surface, and on the other hand, are also capable of precise imaging of fine-grained or surface-etched mold surfaces.Type: GrantFiled: March 28, 2013Date of Patent: January 13, 2015Assignee: Bayer Intellectual PropertyInventor: Andreas Seidel
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Patent number: 8927654Abstract: Provided are a water-treating agent which includes a specific nonionic polymer and a phosphorus compound and can exhibit the ability to inhibit the deposition of silica-based scale under wide ranges of water quality conditions and temperature conditions; and a method of treating water. The inhibitor for silica-based scale includes a nonionic polymer and a phosphorus compound, the nonionic polymer being: a polymer formed by the reaction of an unsaturated double bond and including units derived from at least one monomer selected from the group consisting of (meth)acrylamide, N-substituted (meth)acrylamide and N-vinyl lactam; and/or one or more polymers having an ether group and selected from the group consisting of alkyl alcohol/polyalkylene oxide adducts, aliphatic monocarboxylic acid/polyalkylene oxide adducts, and polyvinyl alcohol/polyalkylene oxide adducts.Type: GrantFiled: January 14, 2010Date of Patent: January 6, 2015Assignee: Kurita Water Industries Ltd.Inventor: Ikuko Nishida
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Patent number: 8889773Abstract: There is provided herein an aluminum methyl methylphosphonate in crystalline form wherein 90% of the aluminum methyl methylphoshponate has a particle size of less than 10 microns, and wherein the aluminum methyl methylphosphonate is obtained by the process of reacting aluminum hydroxide with dimethyl methylphosphonate in the presence of a catalyst.Type: GrantFiled: June 21, 2011Date of Patent: November 18, 2014Assignee: ICL-IP America Inc.Inventors: Joseph Zilberman, Sergei V. Levchik, Andrew Gregor, Pierre Georlette, Yoav Bar Yaakov, Gideon Shikolski
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Patent number: 8841366Abstract: This disclosure relates to thermoplastic compositions comprising a polycarbonate copolymer, the polycarbonate copolymer comprising first repeating carbonate units and second repeating units selected from carbonate units that are different from the first carbonate units, polysiloxane units, and a combination comprising at least one of the foregoing unit; and an organophosphorus flame retardant in an amount effective to provide 0.1 to 1.0 wt % phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after 4 minutes (Ds-4) of less than or equal to 600 determined according to ISO 5659-2 on a 3 mm thick plaque, and a material heat release of less than or equal to 160 kW/m2 determined according to ISO 5660-1 on a 3 mm thick plaque.Type: GrantFiled: February 28, 2013Date of Patent: September 23, 2014Assignee: Sabic Innovative Plastics IP B.V.Inventors: Mark Adrianus Johannes van der Mee, Robert Dirk van de Grampel, Roland Sebastian Assink, Paul Dean Sybert
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Patent number: 8779038Abstract: The invention relates to a flame retardant composition comprising at least one polymer precursor, at least one flame retardant (A) selected from cyclic phosphonate esters responding to formula (I) and at least one flame retardant (B) selected from phosphorus derivatives different from the cyclic phosphonates of formula (I) and their use to make fire resistant glass laminates.Type: GrantFiled: August 3, 2009Date of Patent: July 15, 2014Assignee: Allnex Belgium S.A.Inventor: Hugues Van Den Bergen
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Patent number: 8779040Abstract: The present invention is directed to a composition comprising: (a) a polyethylene terephthalate; (b) a copolycarbonate of 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP) and another bisphenol; (c) a polycarbonate-polysiloxane copolymer; and (d) a non-halogenated flame retardant. The invention is also directed to processes for making such compositions as well as articles derived therefrom.Type: GrantFiled: October 16, 2012Date of Patent: July 15, 2014Assignee: SABIC Global Technologies B.V.Inventors: Chris van der Weele, Johannes Hubertus Gabriel Marie Lohmeijer, Andries J. P. van Zyl
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Publication number: 20140155527Abstract: There is provided herein a flame retarded polyolefin composition comprising a thermoplastic polyolefin polymer, an inorganic flame retardant and a synergist comprising a metal phosphonate represented by the formula: There is also provided a method for making a flame retarded polyolefin composition comprising contacting at least one thermoplastic polyolefin polymer with at least one inorganic flame retardant and at least one metal phosphonate and heating the mixture of thermoplastic polyolefin polymer, at least one inorganic flame retardant and at least one metal phosphonate above the melting temperature of the thermoplastic polyolefin polymer.Type: ApplicationFiled: June 12, 2013Publication date: June 5, 2014Applicant: ICL-IP America Inc.Inventors: Sergei V. Levchik, Gerald R. Alessio, Yankai Yang
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Patent number: 8716378Abstract: A thermoplastic polyester composition comprising, based on the total weight of the composition, a chlorine- and bromine-free combination of: from 40 to 60 wt % of a polyester; from 25 to 35 wt % of a reinforcing filler; from 2 to 8 wt % of a flame retardant synergist selected from the group consisting of melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, melamine phosphate, and combinations thereof; from 5 to 15 wt % of a phosphinate salt flame retardant; from more than 0 to less than 5 wt % of an impact modifier component comprising a poly(ether-ester) elastomer and a (meth)acrylate impact modifier; from more than 0 to 5 wt % poly(tetrafluoroethylene) encapsulated by a styrene-acrylonitrile copolymer; from more than 0 to 2 wt % of a stabilizer; wherein the thermoplastic polyester composition contains less than 5 wt % of a polyetherimide.Type: GrantFiled: June 29, 2010Date of Patent: May 6, 2014Assignee: Sabic Innovative Plastics IP B.V.Inventors: Tianhua Ding, Rodney Fonseca, Sung Dug Kim, Chris van der Weele
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Patent number: 8710126Abstract: Flame-proofed thermoplastic compositions include organophosphorus compounds as flame retardants; thermoplastic articles shaped therefrom do not experience deterioration of the appearance of the surfaces thereof by corrosion or deposition.Type: GrantFiled: June 17, 2008Date of Patent: April 29, 2014Assignee: Rhodia OperationsInventors: Silvia Angeli, Xavier Couillens, Michelangelo Amorese
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Publication number: 20140107264Abstract: The present invention is directed to a composition comprising: (a) a polyethylene terephthalate; (b) a copolycarbonate of 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP) and another bisphenol; (c) a polycarbonate-polysiloxane copolymer; and (d) a non-halogenated flame retardant. The invention is also directed to processes for making such compositions as well as articles derived therefrom.Type: ApplicationFiled: October 16, 2012Publication date: April 17, 2014Applicant: Sabic Innovative PlasticsInventor: Sabic Innovative Plastics
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Publication number: 20140099459Abstract: A shaped part that is formed from a polymer composition that contains a liquid crystalline polymer and a metallic pigment is provided. By selectively controlling the type and relative concentration of these components, the polymer composition and shaped parts formed therefrom can have a metallic-like appearance. In addition to possessing an aesthetically pleasing appearance similar to stainless steel articles, the metallic-like appearance can also provide a signal to a user that the foodstuff article can be safely heated in an oven or stove.Type: ApplicationFiled: September 19, 2013Publication date: April 10, 2014Applicant: Ticona LLCInventors: Mark Allen Tyler, Bruce Michael Mulholland
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Patent number: 8686072Abstract: A thermoplastic polyester composition comprising, based on the total weight of the composition, a chlorine- and bromine-free combination of: from 40 to 60 wt % of a modified poly(1,4-butylene terephthalate); from 25 to 35 wt % of a reinforcing filler; from 2 to 8 wt % of a flame retardant synergist selected from the group consisting of melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, melamine phosphate, and combinations thereof; from 5 to 15 wt % of a phosphinate salt flame retardant; from more than 0 to less than 5 wt % of an impact modifier component comprising a poly(ether-ester) elastomer and a (meth)acrylate impact modifier; from more than 0 to 5 wt % poly(tetrafluoroethylene) encapsulated by a styrene-acrylonitrile copolymer; from more than 0 to 2 wt % of a stabilizer; wherein the thermoplastic polyester composition contains less than 5 wt % of a polyetherimide.Type: GrantFiled: June 29, 2010Date of Patent: April 1, 2014Assignee: Sabic Innovative Plastics IP B.V.Inventors: Tianhua Ding, Rodney Fonseca, Sung Dug Kim, Chris van der Weele
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Patent number: 8581107Abstract: Disclosed is a halogen-free flame-retardant epoxy resin composition for printed circuit board, which includes (A) a halogen-free epoxy resin; (B) a copolymer of styrene and maleic anhydride used as a first curing agent; (C) poly(1,3-phenylene methylphosphonate) used as a second curing agent; (D) a curing accelerator; and (E) an inorganic filler.Type: GrantFiled: August 13, 2010Date of Patent: November 12, 2013Assignee: Taiwan Union Technology CorporationInventor: Hsuan Hao Hsu
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Patent number: 8550162Abstract: A retarder aid increases the applicable temperature range of phosphonate/borate cement-retarder systems to at least 302° C. (575° F.), and 207 MPa (30,000 psi). The retarder aid comprises a terpolymer of styrene sulfonate, maleic anhydride and acrylate of ethylene oxide. Cement slurries containing the retarder and retarder aid may be used for both primary-cementing and remedial-cementing applications.Type: GrantFiled: June 28, 2011Date of Patent: October 8, 2013Assignee: Schlumberger Technology CorporationInventors: Michel Michaux, Jean-Philippe Caritey
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Patent number: 8524814Abstract: The present invention provides for compounds comprising at least one phosphonate or phosphinate moiety; and at least one moiety selected from an aromatic nitroso or an aromatic nitroso precursor and combinations thereof. Adhesive compositions comprising the compounds may find utility in bonding polymers to metal and or hydroxylated surfaces such as glass. Suitable polymers include natural and synthetic rubbers. The aromatic nitroso precursor may be a nitrosobenzene precursor such as at least one of a quinone dioxime or a quinone oxime.Type: GrantFiled: April 13, 2012Date of Patent: September 3, 2013Assignee: Henkel Ireland LimitedInventors: Nigel Fay, Eimear M. Fleming, Darren Nolan, Brendan J. Kneafsey
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Patent number: 8487043Abstract: A phosphorous flame retardant primarily includes hexachlorotriphosphazene (HCP) having poly(oxyalkylene)amine substitutes. The poly(oxyalkylene)amine includes at least two end groups. The phosphorous flame retardant can further include layered silicate clay. The layered silicate clay can be intercalated and modified with the poly(oxyalkylene)amine substitutes of HCP to effectively promote thermal stability. The flame retardant, phosphazene-poly(oxyalkylene)amine adducts, can be applied to a polymer. By the cross-linking between them, the flame-retarding property of the polymer can be improved. Also provided is a method for producing the flame retardant of phosphazene-poly(oxyalkylene)amine adducts and application thereof to a polymer.Type: GrantFiled: March 31, 2010Date of Patent: July 16, 2013Assignee: National Taiwan UniversityInventors: Jiang-Jen Lin, Yu-Min Chen, Yi-Lin Liao
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Publication number: 20130109791Abstract: The present invention relates to a flame retardant plexifilamentary film-fibril strand comprising at least one polyolefin and at least one flame retardant selected from the group consisting of: phosphate esters, phosphonate esters, phosphinate esters, polyphosphazines, nitrogen-containing polyphosphates, hindered amines and mixtures thereof. The present invention also relates to flame retardant sheet made from the flame retardant plexifilamentary film-fibril strands. The sheet can be made into a flame retardant building substrate, garment, banner, light reflector and cover.Type: ApplicationFiled: April 17, 2012Publication date: May 2, 2013Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: SABINE GABRIEL, LAKSHMI KRISHNAMURTHY, MIECZYSLAW (MICHEL) STACHNIK, MARK GARY WEINBERG
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Patent number: 8378012Abstract: A flame retardant composition is provided which contains at least one phosphate ester containing at least one acidic substance resulting from the process of its manufacture, at least one acidity-reducing hydrotalcite and, optionally, at least one acidity-reducing oxetane. The flame retardant composition is especially useful for addition to resins that are susceptible to hydrolytic degradation such as polyesters and polycarbonates, and to resin blends (alloys) containing one or more of such resins, e.g., a blend of polycarbonate and acrylonitrile butadiene-styrene terpolymer.Type: GrantFiled: November 7, 2006Date of Patent: February 19, 2013Assignee: ICL-IP America Inc.Inventors: Paul Y. Moy, Leslie Bright
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Patent number: 8378007Abstract: The invention relates to a colored polymer dispersion containing, as main ingredients: (a) a colored polymer produced by polymerization of monomer A with monomer B, monomer A being a pigment B which is coated with a polymerizable wax D wherein the polymerizable function is an ethylenically unsaturated group, monomer B being a ethylenically unsaturated compound; (b) at least one non-ionic surface-active additive E based on polyethers and/or polyglycerines; (c) at least one anionic surface-active additive F based on sulfonates, sulfates, phosphonates, phosphates or carboxylates; and (d) water.Type: GrantFiled: March 16, 2012Date of Patent: February 19, 2013Assignee: Clariant Finance (BVI) LimitedInventors: Franz-Leo Heinrichs, Anais Bialy, Klaus Saitmacher, Josef Ritter
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Patent number: 8329792Abstract: The present invention provides a phosphonate based compound represented by the following Chemical Formula 1 and a flameproof thermoplastic resin composition comprising (A) a thermoplastic resin and (B) a phosphonate based compound represented by the following Chemical Formula 1. The flameproof thermoplastic resin composition can exhibit good flame retardancy and impact strength. Further, the composition does not include a halogenated flame retardant and thus can provide environmental and safety benefits. wherein R1 and R2 are each independently C1-C4 alkylene and X is a cyano group.Type: GrantFiled: December 10, 2010Date of Patent: December 11, 2012Assignee: Cheil Industries Inc.Inventors: Woo Joong Kim, Seung Shik Shin, Jin Hwan Choi
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Patent number: 8278375Abstract: Mixtures of three types of linear, branched or cyclic phosphates are useful flame retardants, especially for thermoplastic resins or as functional additives in polymer matrices.Type: GrantFiled: July 5, 2006Date of Patent: October 2, 2012Assignee: Rhodia UK LimitedInventors: Vincent Schanen, Dwight Shamblee, Gleb Priimov, Julie Ann Salter
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Patent number: 8188171Abstract: The invention relates to the use of additived (poly)isocyanate compositions for producing coatings, especially paints or varnishes for car bodywork parts, said compositions having excellent impact-resistant properties, especially grit-resistant properties.Type: GrantFiled: December 20, 2005Date of Patent: May 29, 2012Assignee: Rhodia ChimieInventors: Jean-Marie Bernard, Mathias Dubecq
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Publication number: 20120121459Abstract: This invention relates to an aqueous polymer composition and to films formed from this aqueous composition. The aqueous composition may be used in a method for removing contaminate material from a substrate. The aqueous polymer composition may comprise: water; and at least one water-soluble film forming polymer. In one embodiment, the aqueous composition may further comprise at least one chelating agent and/or at least one surfactant. The aqueous polymer composition may be applied to a contaminated substrate or to a clean substrate which is subjected to subsequent contamination. The aqueous composition may be dehydrated and/or the polymer may be crosslinked to form a film. When applied to a contaminated substrate, the film may combine with the contaminates. When applied to a clean substrate, the contaminate material may subsequently contact and adhere to the film.Type: ApplicationFiled: February 28, 2007Publication date: May 17, 2012Inventors: Garry Edgington, Shaosheng Dong, Ge Ming Lui, Hank Wuh, Stephen L. Sherman
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Patent number: 8163818Abstract: The invention relates to a colored polymer dispersion containing, as main ingredients: (a) a colored polymer produced by polymerization of monomer A with monomer B, monomer A being a pigment B which is coated with a polymerizable wax D wherein the polymerizable function is an ethylenically unsaturated group, monomer B being a ethylenically unsaturated compound; (b) at least one non-ionic surface-active additive E based on polyethers and/or polyglycerines; (c) at least one anionic surface-active additive F based on sulfonates, sulfates, phosphonates, phosphates or carboxylates; and (d) water.Type: GrantFiled: June 30, 2007Date of Patent: April 24, 2012Assignee: Clariant Finance (BVI) LimitedInventors: Franz-Leo Heinrichs, Anais Bialy, Klaus Saitmacher, Josef Ritter
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Patent number: 8129455Abstract: A flame retardant thermoplastic molding composition containing a thermoplastic copolymer A, a graft copolymer B, and a flame retardant component C, wherein the molding composition contains: A: from 40 to 80% by weight of a thermoplastic copolymer A, obtainable e.g. from acrylonitrile and styrene; B: from 15 to 50% by weight of a graft ABS copolymer B, and C: from 15 to 30% by weight of the flame retardant component C, comprising at least an expandable graphite component (C1) and a phosphorous flame retardant component (C2) and a perfluorinated polymer (C3); has a high fire protection and improved mechanical properties.Type: GrantFiled: July 8, 2008Date of Patent: March 6, 2012Assignee: Styrolution GmbHInventors: Piyada Charoensirisomboon, Maarten Staal, Michel Pepers, Christoph Link
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Publication number: 20120022192Abstract: Provided are a water-treating agent which includes a specific nonionic polymer and a phosphorus compound and can exhibit the ability to inhibit the deposition of silica-based scale under wide ranges of water quality conditions and temperature conditions; and a method of treating water. The inhibitor for silica-based scale includes a nonionic polymer and a phosphorus compound, the nonionic polymer being: a polymer formed by the reaction of an unsaturated double bond and including units derived from at least one monomer selected from the group consisting of (meth)acrylamide, N-substituted (meth)acrylamide and N-vinyl lactam; and/or one or more polymers having an ether group and selected from the group consisting of alkyl alcohol/polyalkylene oxide adducts, aliphatic monocarboxylic acid/polyalkylene oxide adducts, and polyvinyl alcohol/polyalkylene oxide adducts.Type: ApplicationFiled: January 14, 2010Publication date: January 26, 2012Applicant: KURITA WATER INDUSTRIES LTD.Inventor: Ikuko Nishida
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Patent number: 8051947Abstract: The present invention relates to a method for vibration damping and noise reduction by using thermoplastic vulcanizate compositions and to multilayer structures for use in vibration damping and noise reduction applications comprising at least one polymeric layer made of a thermoplastic vulcanizate composition.Type: GrantFiled: December 1, 2009Date of Patent: November 8, 2011Assignee: E.I. du Pont de Nemours and CompanyInventor: Eleni Karayianni
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Patent number: 8044126Abstract: The present invention relates to a polyarylene sulfide resin composition, which comprises polyarylene sulfide (A) and polyamide (B) as essential components, and further includes an organic phosphorus compound (C), which is selected from the group consisting of an aromatic phosphite compound and an aromatic phosphonate compound, and an inorganic phosphorus compound (D), which is selected from the group consisting from a metal salt of phosphorous acid and a metal salt of hypophosphoric acid as essential components, in addition to the polyarylene sulfide (A) and the polyamide (B); a manufacturing method thereof; and a surface mount electronic component. The polyarylene sulfide resin composition has excellent heat resistance, does not decrease mechanical properties such as bending strength even if heating treatment is performed under the high temperature condition by passing through a reflow furnace, and has excellent flame retardance.Type: GrantFiled: January 28, 2009Date of Patent: October 25, 2011Assignee: DIC CorporationInventors: Yasuyuki Yoshino, Hirokiyo Nakase, Hiroaki Negishi, Yohei Yamaguchi, Shinya Gibo
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Patent number: 7977415Abstract: A thermoplastic molding composition characterized by its flame retardance and impact strength is disclosed. The composition contains (A) linear aromatic (co)polycarbonate, (B) a graft (co)polymer having core-shell morphology, the shell containing polymerized alkyl(meth)acrylate and the core containing interpenetrated and inseparable polyorganosiloxane and poly(meth)alkyl acrylate components, (C) a phosphorous-containing flame retardant compound, (D) fluorinated polyolefin and (E) a boron compound, and optionally SAN. The composition is further characterized in that it contains no polyalkylene terephthalate.Type: GrantFiled: November 30, 2007Date of Patent: July 12, 2011Assignee: Bayer MaterialScience LLCInventor: Marina Rogunova
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Patent number: 7973109Abstract: A process for producing a crosslinked type or non-crosslinked type layered metal phosphonate compound including a reaction step of reacting two or more members selected from organic diphosphonic acids or monophosphonic acids, or derivatives thereof having predetermined conditions and a metal source capable of forming an ion of a hexacoordinate metal atom as a central atom (M) of a metal oxide octahedron upon reaction under the presence of a sulfuric acid catalyst, a crosslinked or non-crosslinked metal phosphonate compound obtained by the process, as well as a stock solution used for the synthesis of the crosslinked or non-crosslinked type layered metal phosphonate compound described above.Type: GrantFiled: March 24, 2008Date of Patent: July 5, 2011Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Shin-ichi Ogata, Yoshiaki Fukushima, Masaya Kawasumi
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Patent number: 7960455Abstract: Use of copolymers comprising alkylene oxide units, which copolymers comprise incorporated randomly or blockwise by polymerization (a) 50 to 93 mol % of acrylic acid and/or a water-soluble salt of acrylic acid, (b) 5 to 30 mol % of methacrylic acid and/or a water-soluble salt of methacrylic acid and (c) 2 to 20 mol % of at least one nonionic monomer of the formula I where the variables have the following meaning: R1 hydrogen or methyl; R2 a chemical bond or unbranched or branched C1-C6-alkylene; R3 identical or different unbranched or branched C2-C4-alkylene radicals; R4 unbranched or branched C1-C6-alkyl; n 3 to 50, as additive to phosphate- and/or phosphonate-comprising aqueous systems in industrial technical plants.Type: GrantFiled: June 14, 2006Date of Patent: June 14, 2011Assignee: BASF AktiengesellschaftInventors: Stephan Nied, Karl-Heinz Buechner, Marcus Guzmann
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Patent number: 7951860Abstract: Polymer composite materials having improved gas barrier properties are generally disclosed, along with process of making the same. The polymer composite materials can include phosphonate particles, oxide particles, and combinations thereof. For example, the particles can be metal phosphonate particles, synthetic oxide particles, or combinations thereof.Type: GrantFiled: July 22, 2005Date of Patent: May 31, 2011Assignee: University of South CarolinaInventors: Hans-Conrad zur Loye, Tara Hansen, Baolong Zhang, John W. Stone
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Patent number: 7893135Abstract: The present invention relates to compositions comprising A) aromatic polycarbonate, B) polyalkylene terephthalate and C) a concentrate comprising polyalkylene terephthalate and at least one compound selected from the group consisting of ortho-phosphoric acid, phosphorous acid, carboxylic acid esters of ortho-phosphoric acid and carboxylic acid esters of phosphorous acid, Compositions of the present invention are distinguished by high melt stability. The present invention also relates to a process for the preparation of impact-modified polyalkylene terephthalate/polycarbonate compositions, wherein a concentrate of polyalkylene terephthalate with a phosphorus-containing additive is used.Type: GrantFiled: March 20, 2009Date of Patent: February 22, 2011Assignee: Bayer MaterialScience AGInventors: Pierre Moulinie, Ralf Hufen, Stephan Konrad, Dieter Wittmann
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Patent number: 7868070Abstract: A thermoplastic molding composition that features improved thermal stability and a relatively low maximum rate of decomposition in the event of fire is disclosed. The composition contains an aromatic polycarbonate and/or polyester carbonate, and a modified layered compound, the modification with organic polymer by means of a solvent-free melt process. Optional additional components include an impact modifier, a thermoplastic (co)copolymer, and a phosphorus compound.Type: GrantFiled: December 11, 2006Date of Patent: January 11, 2011Assignee: Bayer MaterialScience AGInventors: Eckhard Wenz, Uwe Peucker, Thomas Eckel, Dieter Wittmann, Arno Nennemann, Vera Buchholz
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Publication number: 20100317776Abstract: The invention relates to the use of alkylphenols for adjusting the molecular weight of polycarbonates and compositions of these polycarbonates with additives chosen from the group of heat stabilizers, mould release agents and light stabilizers, the use thereof for the production of mouldings and mouldings obtainable therefrom.Type: ApplicationFiled: January 31, 2009Publication date: December 16, 2010Applicant: Bayer MaterialScience AGInventors: Rolf Wehrmann, Helmut-Werner Heuer, Bert Ruytinx
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Patent number: 7799848Abstract: A thermoplastic molding composition characterized by its flame retardance and impact strength is disclosed. The composition contains (A) linear aromatic (co)polycarbonate, (B) a graft (co)polymer having core-shell morphology, the shell containing polymerized alkyl(meth)acrylate and the core containing interpenetrated and inseparable polyorganosiloxane and poly(meth)alkyl acrylate components, (C) a phosphorous-containing flame retardant compound, (D) fluorinated polyolefin and (E) a boron compound, and optionally SAN. The composition is further characterized in that it contains no polyalkylene terephthalate.Type: GrantFiled: February 6, 2008Date of Patent: September 21, 2010Assignee: Bayer Materialscience LLCInventor: Marina Rogunova
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Patent number: 7786198Abstract: The present invention relates to substances, crosslinkable by attachment of an Si-bonded hydrogen atom to an aliphatic multiple bond, which comprise at least one compound of the formula R3P(O) (OH)2??(III) and/or the derivatives thereof, R3 being an optionally substituted hydrocarbon radical which can be interrupted by heteroatoms.Type: GrantFiled: April 3, 2007Date of Patent: August 31, 2010Assignee: Wacker Chemie AGInventors: Torsten Sixt, Franz Neuhauser
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Patent number: 7754794Abstract: A composition for treating a keratin based substrate that includes a cosmetically acceptable medium containing a water-soluble interjacent complex. The water-soluble interjacent complex includes a first water-soluble polymer and a second water-soluble polymer formed by polymerizing one or more water-soluble monomers in the presence of the first water-soluble polymer. The water-soluble interjacent complex is characterized in that it forms a solution in water that is free of insoluble polymer particles. The water-soluble interjacent complex is used in a method of treating a keratin based substrate, whereby a cosmetically acceptable medium is applied to the substrate and contains from 0.1-20% by weight of the water-soluble interjacent complex.Type: GrantFiled: August 9, 2005Date of Patent: July 13, 2010Assignee: WSP Chemical & Technology, LLCInventors: Shih-Ruey T Chen, Valentino L. DeVito, Kevin W. Frederick
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Patent number: 7705080Abstract: The invention relates to an adhesive according to a conventional formulation, comprising additives capable of binding metal ions in the sense of chemical interactions, electrochemical interactions and/or physical interactions.Type: GrantFiled: December 7, 2007Date of Patent: April 27, 2010Assignee: tesa SEInventors: Kai Ellringmann, Stefan Wulf, Philipp Preuβ
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Patent number: 7678852Abstract: Polymer compositions are afforded flame retardancy with the incorporation of a combination of melamine polyphosphate and poly(m-phenylene methylphosphonate). The polymer compositions are for instance epoxy resins for prepegs, laminates and printed circuit boards. The epoxy resins are for example for coating electronic parts. The polymer compositions are also thermoplastics such as polyolefins or polystyrenics, useful as fibers, films or molded parts. The melamine polyphosphate may be of a fine particle size.Type: GrantFiled: June 12, 2008Date of Patent: March 16, 2010Assignee: Ciba CorporationInventor: Nikolas Kaprinidis
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Patent number: 7666932Abstract: Disclosed are new compositions consisting of polyphosphonates and specific additive compositions that exhibit superior resistance to degradation due to exposure to air, high temperature and air, moisture or combinations thereof. Also disclosed are polymer mixtures or blends comprising these polyphosphonates/additive compositions and commodity and engineering plastics and articles produced therefrom. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.Type: GrantFiled: October 16, 2006Date of Patent: February 23, 2010Assignee: FRX Polymers, Inc.Inventors: Dieter Freitag, Pin Go, Gad Stahl
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Patent number: 7658791Abstract: It is an object of the present invention to provide an anticorrosive coating composition which uses a pollution-free (heavy metal-free) rust preventive pigment and exhibits anticorrosive performances equal or superior to those of lead compounds or chromic acid compounds even if the pigment is blended in various binder resins and also to provide an anticorrosive coating composition having excellent storage stability. The present invention relates to an anticorrosive coating composition comprising a binder resin and a pollution-free (heavy metal-free) rust preventive pigment containing a condensed calcium phosphate produced by baking a single substance or mixture of a calcium component and a phosphorous component in the following atomic ratio (Ca/P=m): 0.50<m<1.00, at 180 to 350° C.Type: GrantFiled: November 16, 2005Date of Patent: February 9, 2010Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Masanori Nagai, Tsuyoshi Matsumoto, Takashi Matsuda, Osamu Ogawa
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Patent number: 7632880Abstract: The invention provides a single phase, essentially solvent-free polymerizable liquid composition comprising a polymerizable liquid with dissolved therein an organogroup 4, 5 or 6 compound selected from the group consisting of organolead, organophosphorus, organoarsenic, organoantimony, organobismuth and organselenium compounds, said position being polymerizable under the action of an externally applied influence.Type: GrantFiled: February 20, 2004Date of Patent: December 15, 2009Assignee: Microsharp Corporation Ltd.Inventors: Zhi Li, Rifat Iqbal, Jun Wang