Aryl Group Patents (Class 524/132)
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Patent number: 5061743Abstract: Certain hydroxy alkanoate polymers, such as 3-hydroxybutyrate polymers, when obtained by solvent extraction from fermentation masses, can have long cycle times during thermal processing due to a low rate of crystallization. A combination of (a) an organophosphonic or organophosphoric acid or ester with (b) an oxide, hydroxide, or carboxylate of a metal of Groups I to V is an effective nucleating agent.Type: GrantFiled: May 30, 1990Date of Patent: October 29, 1991Assignee: Imperial Chemical Industries plcInventors: John M. Herring, Andrew Webb
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Patent number: 5030675Abstract: Flame-resistant molding compounds of polycarbonate, polyalkylene terephthalate, graft polymer, fluorinated polyolefine and phosphorus compound can be worked up into moulded products which have a particularly advantageous combination of joint line strength, dimensional stability under heat and toughness.Type: GrantFiled: December 13, 1989Date of Patent: July 9, 1991Assignee: Bayer AktiengesellschaftInventors: Dieter Wittmann, Hans-Jurgen Kress, Horst Peters, Josef Buekers, Christian Lindner
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Patent number: 4946882Abstract: Compositions comprising a polyphenylene ether and, optionally, a styrene resin, an aromatic phosphate, phosphonate or phospine oxide, an aromatic halogen compound and an impact modifier comprising a diene polymer have excellent flame retardant properties during large scale flammability tests. The compositions will tolerate large amounts of aromatic halogen compound without discoloration and processing difficulties. In comparison with compositions of the present state of the art, peak burn temperatures are reduced, smoke is less dense, and flaming drips are eliminated in large as well as small scale burn tests.Type: GrantFiled: September 25, 1981Date of Patent: August 7, 1990Assignee: General Electric CompanyInventors: William R. Haaf, Gim F. Lee, Jr.
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Patent number: 4925888Abstract: A mixture for stabilizing polyurethanes contains(a) an amine of the formula I ##STR1## (b) a mixture of the benzotriazoles II and III ##STR2## in which n is chosen so that the mean molecular weight of the mixture is greater than 600, and(c) .alpha.-tocopherol, if necessary mixed with tris-(nonylphenyl) phosphite, and polyurethanes contain from 0.005 to 5.0% by weight, based on the material to be stabilized, of this mixture.Type: GrantFiled: October 21, 1988Date of Patent: May 15, 1990Assignee: BASF AktiengesellschaftInventors: Alexander Aumueller, Peter Neumann, Peter Spang, Guenter Matzke, Hubert Trauth
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Patent number: 4889879Abstract: Coherent thermoplastic aggregates with very high content of pulverized mineral materials, composed of the said materials, of polyolefin polymers and/or copolymers, and possibly also of various familiar adjuvants, characterized by the fact that, in order for them to have both a volumetric mass close to or at most equal to the theoretical volumetric mass of the pulverized mineral substances entering into their composition and an excellent compatibility with redispersion polymers, the polymers and/or copolymers entering into the composition of the said aggregates in presence of a fluidizing agent are chosen within the group of thermoplastics with melting and/or softening point at least equal to 60.degree. C. and index of fluidity at least 50 (measured according to the standard ASTM D 1238) of the polyolefin type, other than those containing a polar monomer.Type: GrantFiled: July 24, 1987Date of Patent: December 26, 1989Assignee: Pluess Staufer AGInventors: Henry Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
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Patent number: 4888370Abstract: Flame-resistant, thermoplastic polyamide moulding materials which contain 0.01-4% by weight of polyphenylene oxides as flameproofing agent and which are prepared by mixing the components in the melt.Type: GrantFiled: September 7, 1988Date of Patent: December 19, 1989Assignee: Bayer AktiengesellschaftInventors: Dieter Freitag, Thomas Joswig, Karsten Idel, Heinz-Josef Fullmann, Friedemann Muller
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Patent number: 4835200Abstract: A hot melt adhesive composition possessing color stability and resistance to heat degradation, oxidation and skin formation. The adhesive composition contains a block copolymer prepared using a bromide based coupling agent, a tackifying resin, and an effective amount of a stabilizer composition. The stabilizer composition contains a thio compound, a phenolic antioxidant, a tris-(nonylated phenyl) phosphite, and an aliphatic compatible epoxy compound. Optionally, the adhesive composition may also contain a plasticizer and/or a petroleum derived wax.Type: GrantFiled: December 19, 1986Date of Patent: May 30, 1989Assignee: Shell Oil CompanyInventor: David J. St. Clair
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Patent number: 4788238Abstract: The present invention provides thermoplastic flame-retardant moulding compositions containing halogen-containing copolycarbonates, styrene/maleic anhydride copolymers, phosphorus compounds of the formula (I) ##STR1## and tetrafluoroethylene polymers and, if desired, further known additives.Type: GrantFiled: September 21, 1987Date of Patent: November 29, 1988Assignee: Bayer AktiengesellschaftInventors: Gert Todtemann, Klaus Reinking, Otto Koch, Kress Hans-Jurgen, Lindner Christian, Friedemann Muller, Horst Peters, Josef Buekers
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Patent number: 4786581Abstract: A gumming solution is disclosed for use in the burning-in of irradiated and developed offset-printing plates. The gumming solution contains (a) water, (b) at least one hydrophilic polymer, and (c) at least one component derived from an organic acid. Component (b) comprises, for example, N-polyvinyl-pyrrolidone-(2) or polyacrylic acid, and component (c) comprises a water-soluble organic carboxylic acid, sulfonic acid, or phosphonic acid which has at least two acid functions and which is selected from the group consisting of benzene carboxylic acids, benzene sulfonic acids, benzene phosphonic acids, and alkane phosphonic acids, or one of the salts thereof (for example, disodium-benzene-1,3-disulfonate, mellitic acid, or methane-diphosphonic acid.) A process for the production of an offset-printing plate, using the aforesaid gumming solution in the burning-in of the plate, is also disclosed.Type: GrantFiled: February 9, 1987Date of Patent: November 22, 1988Assignee: Hoechst AktiengesellschaftInventors: Paul Stahlhofen, Loni Schell
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Patent number: 4756881Abstract: A composition and method for inhibiting corrosion in industrial cooling waters which contain hardness and have a pH of at least 8, which composition comprises a water-soluble organic phosphonate capable of inhibiting corrosion in an aqueous alkaliine environment and a hydrocarbon polymer containing an N-substituted acrylamide polymer with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, and combinations thereof.Type: GrantFiled: May 9, 1986Date of Patent: July 12, 1988Assignee: Nalco Chemical CompanyInventors: John E. Hoots, Donald A. Johnson, Dodd W. Fong
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Patent number: 4751260Abstract: The present invention relates to flame-retarding, thermoplastic polycarbonate moulding materials of high impact strength consisting of halogen-containing polycarbonates, copolymers formed from styrenes and (meth)acrylonitrile, phosphorus compounds of the formula (I) ##STR1## tetrafluoroethylene polymers and small amounts of graft polymers and, if appropriate, effective amounts of stabilizers, pigments, lubricants, mould release agents and/or antistatic agents, and to a process for the preparation thereof.Type: GrantFiled: April 30, 1986Date of Patent: June 14, 1988Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Friedemann Muller, Christian Lindner, Horst Peters, Josef Buekers
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Patent number: 4690954Abstract: A method for improving a production characteristic of flame-retardant polyurethanes. The characteristic may be selected from the group consisting of(1) processability;(2) scorch;(3) odor; and(4) flame-retardant efficiency.The method comprises incorporation into a polyurethane an amount effective to reduce combustibility of a haloether phosphorate flame-retardant under conditions sufficient to improve said characteristic. Also, the flame-retardant polyurethane composition such as prepared by said method. Preferably, the polyurethane is a foam, especially a flexible foam and most especially flexible slabstock foam.Type: GrantFiled: April 28, 1986Date of Patent: September 1, 1987Assignee: The Dow Chemical CompanyInventors: David J. Wampfler, Donna J. Fielding, Chester E. Pawloski
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Patent number: 4681902Abstract: This invention relates to flame retardant phenol aldehyde foams which have a k value below 0.020 W/mk. The foams have as flame retardants a blend of a halosubstituted diphenyl oxide and an organic phosphorus compound. The feature of the invention is that unlike conventional flame retardants, the blend now used does not adversely affect the low k value i.e. the low thermal conductivity of the foam.Type: GrantFiled: November 3, 1986Date of Patent: July 21, 1987Assignee: BP Chemicals LimitedInventors: Alexander W. S. Duncan, David G. Summers, Kenneth C. Thomas
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Patent number: 4666967Abstract: The invention provides polyurethanes and polyisocyanurate having incorporated therein a flame retardant amount of a salt formed by reaction between dimethyl methyl phosphonate, monomethyl methyl phosphonate or methyl phosphonic acid, and a compound of the general formula (I). ##STR1## in which X is O, S or NH, R.sup.1 is H, alkyl with 1 to 4 carbon atoms, alkenyl of up to 4 carbon atoms, CN, CONH.sub.2 or NH.sub.2, R.sup.2 is H, alkyl with 1 to 4 carbon atoms or alkenyl of up to 4 carbon atoms or R.sup.1 and R.sup.2 together with the nitrogen atom to which they are attached form a heterocyclic ring of up to 6 carbon atoms which may optionally contain another hetero atom and R is H, an alkyl group with 1 to 8 carbon atoms, an aryl group with 6 to 10 carbon atoms, a cycloalkyl group with 5 to 12 carbon atoms or a heterocyclic group with up to 9 ring carbon atoms, or, together with R.sup.1 forms an alkylene chain of 3 to 10 carbon atoms, or R is a group NHR.sup.3 wherein R.sup.Type: GrantFiled: January 22, 1986Date of Patent: May 19, 1987Assignee: Ciba-Geigy CorporationInventors: Norman Richardson, deceased, Brian G. Clubley, Richard J. Dellar
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Patent number: 4656200Abstract: The invention provides salts of methyl phosphonic acid and its mono- or di-methyl ester with certain amines. The salts are useful flame retardant additives for polyurethanes and polyisocyanurates.Type: GrantFiled: January 14, 1985Date of Patent: April 7, 1987Assignee: Ciba-Geigy AGInventors: Brian G. Clubley, Richard J. Dellar, David L. Buszard, Norman Richardson
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Patent number: 4649168Abstract: The present invention relates to a process for the preparation of flame-resistant polycarbonate moulding compositions, which is characterized in that, besides the addition of alkali metal salts, there is incorporation of tetrafluoroethylene polymers as an intimate mixture with halogen-free graft polymers, these intimate mixtures being prepared by coagulation of the appropriate emulsion mixtures, and to the polycarbonate moulding compositions obtainable by the process according to the invention.Type: GrantFiled: November 13, 1985Date of Patent: March 10, 1987Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Ludwig Bottenbruch, Mark Witman, Klaus Kircher, Christian Lindner, Karl-Heinz Ott
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Patent number: 4611019Abstract: The addition of small amounts of selected polyamides or polyesters to plasticized, melt extrudable polyvinyl alcohol homopolymer provides a composition with lower permeability to oxygen and other fixed gases.Type: GrantFiled: June 17, 1985Date of Patent: September 9, 1986Inventors: H. Harald Lutzmann, Gerald W. Miller
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Patent number: 4555540Abstract: Blends of an aromatic polycarbonate a polyester, a halogenated flame retardant agent and a metal oxide synergist for the flame retardant are made more stable against transesterification reactions during high temperature processing by the inclusion of minor amounts of selected phosphorus-containing compounds, such as phosphorous acid or acid salt.Type: GrantFiled: December 28, 1984Date of Patent: November 26, 1985Assignee: General Electric CompanyInventor: Roger W. Avakian
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Patent number: 4526916Abstract: A composition particularly adapted for use in a rotational moulding process is disclosed. The composition comprises polyethylene having a density of 0.920-0.970 g/cm.sup.3 and a melt index of 10-35 dg/min., 0.3-1.3% by weight of a bis(tert. alkyl peroxyalkyl) benzene, 0.2-1.5% by weight of a co-curing agent selected from triallyl cyanurate, triallyl isocyanurate and 1,2-polybutadiene, 0.01-0.05% by weight of a hindered phenolic antioxidant and 0.01-0.2% by weight of a secondary antioxidant. The preferred secondary antioxidant is tris di(tert.-butyl phenyl) phosphite. The composition may be used in for example, the moulding of tanks, barrels, containers and the like.Type: GrantFiled: January 31, 1983Date of Patent: July 2, 1985Assignee: Du Pont Canada Inc.Inventor: George White
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Patent number: 4496687Abstract: The invention provides a novel organopolysiloxane-containing aqueous emulsion composition which, upon removal of water by drying at room temperature, can give a cured rubbery elastomer having excellent mechanical properties and exhibiting strong adhesion to the substrate on which it has been cured. The inventive composition is prepared by blending (A) an aqueous emulsion of an organopolysiloxane having silicon-bonded hydroxy groups and emulsified in water by use of an anionic surface active agent, (B) a mixture of a reaction product of a carboxylic acid anhydride with an amino-functional organosilane and a colloidal silica in the form of an aqueous suspension and (C) a curing catalyst in limited proportions.Type: GrantFiled: January 27, 1984Date of Patent: January 29, 1985Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Fumio Okada, Toshio Oba, Morizo Nakazato
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Patent number: 4450249Abstract: The present invention relates to polycarbonate articles and films characterized by their antistatic properties comprising polycarbonate resin and alkali, or alkali earth, salts of specific aromatic sulfonic acids, specific aromatic phosphonic acids or aromatic partial phosphoric acid esters.Type: GrantFiled: August 19, 1982Date of Patent: May 22, 1984Assignee: Bayer AktiengesellschaftInventors: Manfred Schmidt, Joachim Wank, Eckart Reese, Dieter Freitag, Klaus Wangermann, Wolfgang Cohnen
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Patent number: 4444930Abstract: The invention relates to a fire-resistant synthetic resin composition containing a polycarbonate, more specifically a bisphenol A derivative, a phosphorous fireproofing additive derived from phosphonic acid, and possibly other additives and/or fillers.The fireproofing additive is a Li, Na or K hemiester of a phosphonic acid derived from an aromatic or cycloaliphatic hydrocarbon, or from a polynuclear aromatic compound, and is added at the rate of 0.01 to 0.4 weight % in relation to polycarbonate. This small amount of additive improves the fire-resistant properties of the polycarbonate, without affecting its mechanical properties.Type: GrantFiled: August 24, 1982Date of Patent: April 24, 1984Assignee: Ato ChimieInventors: Bernard Guerin, Pierre Poisson, Georges Sturtz
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Patent number: 4383066Abstract: A polyphenylene ether resin composition having improved heat stability, said composition comprising a polyphenylene ether resin matrix, and dispersed therein, a phosphonic acid or its derivative of the formula ##STR1## wherein R.sub.1 represents an unsubstituted or substituted phenyl or naphthyl group, or a linear or branched alkyl group with 1 to 18 carbon atoms, or a group of the following formula (a) ##STR2## R.sub.2 and R.sub.3 are identical or different and each represents hydrogen atom, a metal, an unsubstituted or substituted phenyl group, or an alkyl group with 1 to 10 carbon atoms; and R.sub.4 is a divalent hydrocarbon group with 2 to 10 carbon atoms.Type: GrantFiled: April 7, 1981Date of Patent: May 10, 1983Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Akitoshi Sugio, Masanobu Masu, Masao Okabe, Kozo Ishiyama
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Patent number: 4373042Abstract: New N,N'-di-(hydroxy-phenyl) derivatives of piperazine are disclosed. These new compounds are useful for stabilizing thermoplastic polymers, in particular polyolefins, against sunlight, heat and oxidation.A process for producing the new compounds is also disclosed, as well as the polymeric compositions stabilized with said new compounds.Type: GrantFiled: May 9, 1980Date of Patent: February 8, 1983Assignee: Montedison S.p.A.Inventors: Francesco Gratani, Giuseppe Nelli, Piero Di Battista, Osvaldo Cicchetti
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Patent number: 4373044Abstract: The invention relates to plastics moulding compounds which have been flame-proofed with organic chlorine- or bromine-containing compounds, said moulding compounds containing at least one aerosol selected from the group comprising the highly dispersed silicates, highly dispersed alumina, and highly dispersed titanium dioxide, and, optionally, a dibasic or tribasic oxyacid of phosphorus or an ester thereof. These moulding compounds have a reduced corrosive action on contact metals.Type: GrantFiled: November 19, 1980Date of Patent: February 8, 1983Assignee: Ciba-Geigy CorporationInventors: Lothar Buxbaum, Franz Breitenfellner