Phosphorus Bonded To Only Two Chalcogen Atoms And Having At Least One P-c Linkage Patents (Class 524/133)
  • Patent number: 11384201
    Abstract: A non-halogenated flame retardant polyamide composition is disclosed which comprises a polyamide, a non-halogenated flame retardant, and a synergist. The polyamide may have a ratio of carboxylic acid to amine end groups of greater than 1.8. Products formed from the composition are also disclosed. The polyamide may comprise nylon 6,6.
    Type: Grant
    Filed: January 7, 2020
    Date of Patent: July 12, 2022
    Assignee: Ascend Performance Materials Operations LLC
    Inventor: Kimberly M. White
  • Patent number: 11001710
    Abstract: A thermoplastic composition includes a poly(phthalamide), a poly(etherimide-siloxane), and optionally, an additive composition. The respective amounts of each component are further described herein. A method for the manufacture of the composition includes melt-mixing the components of the composition, and optionally, extruding the composition. Articles including the thermoplastic composition are also described.
    Type: Grant
    Filed: July 10, 2017
    Date of Patent: May 11, 2021
    Assignee: SHPP GLOBAL TECHNOLOGIES B.V.
    Inventors: Mian Dai, Liang Shen
  • Patent number: 10920026
    Abstract: The present invention relates to a polymer composition, consisting of (A) 30-90 wt. % of at least one thermoplastic polymer comprising at least a semi-crystalline semi-aromatic polyamide (SSPA-1) in an amount in the range of 30-90 wt. %; (B) 10-70 wt. % of at least one reinforcing agent, and (C) 0-25 wt. % of one or more other components; wherein the SSPA-1 consists of (A-1-a) 90-100 wt. % of repeat units derived from (i) an aromatic dicarboxylic acid and (ii) diamines, and (A-1-b) 0-10 wt. % of repeat units derived from other monomers; the diamines (ii) consist of 80-95 mole % of a linear aliphatic diamine, 5-20 mole % of 2-methyl-pentamethylene diamine, and 0-10 mole % of other diamines; and the SSPA-1 has a melting temperature (Tm) of at least 300° C. The invention further relates to a molded part made of the composition, a process for making the composition and a process for making the molded part.
    Type: Grant
    Filed: September 27, 2017
    Date of Patent: February 16, 2021
    Assignee: DSM IP ASSETS B.V.
    Inventor: Zhujuan Wang
  • Patent number: 10836904
    Abstract: The present invention relates to a low-halogen flame retardant thermoplastic polyamide composition that provides improved mechanical and electrical stability at elevated temperatures, where the thermoplastic composition comprises a polyamide resin; a non-halogen, nitrogen-containing flame retardant; a heat stabilizer containing a copper halide and an organophosphorus compound; an optional lubricant and/or mold release agent; and an optional colorant.
    Type: Grant
    Filed: October 17, 2017
    Date of Patent: November 17, 2020
    Assignee: Ascend Performance Materials Operations LLC
    Inventors: Shawn J. Osborn, Christopher M. Carter
  • Patent number: 10815376
    Abstract: The present invention relates to compositions comprising at least one thermoplastic polyurethane, at least melamine cyanurate, at least one first phosphorus-containing flame retardant (F1) selected from the group consisting of alkyl esters of phosphoric acid and alkyl esters of phosphonic acid, where the alkyl radicals are selected from C1 to C12 alkyl radicals, and at least one further phosphorus-containing flame retardant (F2) selected from the group consisting of derivatives of phosphinic acid, and to the use of such a composition for production of cable sheaths.
    Type: Grant
    Filed: August 17, 2016
    Date of Patent: October 27, 2020
    Assignee: BASF SE
    Inventors: Oliver Steffen Henze, Oliver Muehren
  • Patent number: 10662312
    Abstract: Disclosed herein is a flame retardant composition comprising 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a halogenated phenoxyphosphazene flame retardant, where all weight percents are based on a total weight of the flame retardant composition. Disclosed herein too is a method comprising blending a 20 to 80 weight percent of a polycarbonate; and 1 to 20 weight percent of a halogenated phenoxyphosphazene flame retardant to produce a flame retardant composition, where all weight percents are based on a total weight of the flame retardant composition.
    Type: Grant
    Filed: April 27, 2016
    Date of Patent: May 26, 2020
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Lin Chen, Hongtao Shi, Yun Zheng, Chunjie Zhang
  • Patent number: 10147516
    Abstract: An extruded flexible flat cable, which has a superior formability, flexibility, adhesiveness, and fire-retardancy, with a low manufacturing cost, is adapted for sliding door of a motor vehicle and also other parts, and has a conductor covered with an insulation layer extrude-formed with an extrusion molding method, and the insulation layer formed from a fire-retardant resin composition containing a modified polybutylene terephthalate and a fire-retardant additive, where the fire-retardant resin composition has a melting point of 170-215 degrees C. measured in reference to JIS K7121 with a differential thermal analysis at a rate of temperature increase of 10 degrees C. per minute.
    Type: Grant
    Filed: January 13, 2017
    Date of Patent: December 4, 2018
    Assignee: Yazaki Corporation
    Inventors: Maki Yamada, Kazuya Goshima
  • Patent number: 9765183
    Abstract: A process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and having a number average molecular weight of at least 10,000 (as determined by GPC based on polystyrene standards) includes a first step wherein a prepolymer is made having the 2,5-furandicarboxylate moiety within the polymer backbone, followed in a second step by a polycondensation reaction. In the first step a 2,5-furandicarboxylate ester is transesterified with a compound or mixture of compounds containing two or more hydroxyl groups, in the presence of a tin(IV) based transesterification catalyst. In the second step at reduced pressure and under melt conditions the prepolymer prepared in the first step is polycondensed in the presence of a tin (II) based polycondensation catalyst until the polymer is obtained. This polymer may then be subjected to Solid State Polycondensation.
    Type: Grant
    Filed: July 7, 2016
    Date of Patent: September 19, 2017
    Assignee: Furanix Technologies B.V.
    Inventor: Laszlo Sipos
  • Patent number: 9296897
    Abstract: A polyamide molding composition for the production of a stain-resistant article, the staining tendency (ST) of the article being at most 15. The composition contains 30-100% by weight of a polyamide mixture, consisting of more than 50 and up to 98% by weight of at least one semi-aromatic polyamide comprising 2 to up to 50% by weight of amorphous and/or microcrystalline polyamides having a glass transition temperature of at least 100° C., based on: 20-100 mol % of at least one cycloaliphatic diamine; and 0-80 mol % of at least one other aliphatic and/or aromatic diamine; and also aromatic and/or aliphatic dicarboxylic acids comprising at least 6 carbon atoms. In addition, the composition comprises inorganic white pigments, fibrous or particulate additives, impact toughness modifier and/or polymers different from (A), 0-25% by weight of a flame retardant.
    Type: Grant
    Filed: December 20, 2013
    Date of Patent: March 29, 2016
    Assignee: EMS-PATENT AG
    Inventors: Mark Pfleghar, Etienne Aepli, Heinz Hoff, Botho Hoffmann
  • Patent number: 9139714
    Abstract: The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkyl phosphonic acid, salt, salt or ester (II) thereof is reacted with compounds of formula (V) and/or (VI?) to yield mono-functionalized dialkylphosphinic acid derivatives (VI) and/or (VI?) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivatives (VI) and/or (VI?) are reacted to yield a mono-carboxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst C, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H1 C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X and Y are the same or different and stand independently o
    Type: Grant
    Filed: October 6, 2009
    Date of Patent: September 22, 2015
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Michael Hill, Werner Krause, Martin Sicken
  • Patent number: 9034958
    Abstract: A polymer complex is disclosed which is the reaction product of one or more polymers having a terminal or pendant hydroxyl group, or a terminal or pendent carboxyl group, or combinations thereof, with at least one metal complex and one alkyl phosphate. This polymer complex acts as an adhesion promotion agent as well as a viscosity stabilizer when formulated in a printing ink or coating.
    Type: Grant
    Filed: November 16, 2004
    Date of Patent: May 19, 2015
    Assignee: Sun Chemical Corporation
    Inventors: Mark Andreas Mielke, Mathew Charles Mathew, William P. Keaveney, Richard John Czarnecki, William Ford Wilson, Mark John Lindsey, Ralph Francis Arcurio
  • Patent number: 9029443
    Abstract: Flame retardant thermoplastic polyurethane (TPU) compositions are disclosed having a flame retardant package comprising an organo-phosphinate component, an organo-phosphate component, and a polyhydric alcohol. The flame retardant components may be present in an amount from about 5 to about 40 weight percent of the phosphinate compound; from about 5 to about 20 weight percent of the phosphate compound, and from about 0.1 to about 15 weight percent of the polyhydric alcohol, based on the total weight of the TPU composition. Processes are disclosed to make the TPU compositions and to make wire and cable constructions employing the TPU compositions as the jacket of the wire and cable constructions. The TPU compositions exhibit excellent flame retardant capabilities as measured by Limited Oxygen Index testing and/or UL 94 Vertical Burn tests.
    Type: Grant
    Filed: April 30, 2014
    Date of Patent: May 12, 2015
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Sridhar K. Siddhamalli, Carl A. Brown
  • Publication number: 20150125696
    Abstract: A melt blowing process comprising: (a) providing a thermoplastic polymer material that includes at least one or a plurality of polyester polymers and at least one or a combination of different meltable metal phosphinates; and (b) melt blowing the thermoplastic polymer material into at least one fiber or a plurality of fibers, with each fiber having a diameter or thickness that is less than about 10 microns. The metal phosphinate is in an amount that (a) reduces the viscosity of the polyester polymer and (b) functions as a crystallizing agent, which at least promotes crystallization of the polyester polymer, when the thermoplastic polymer material is melt blown into the at least one fiber. Non-woven and woven fibrous structures can be made using fibers made from this process.
    Type: Application
    Filed: December 20, 2012
    Publication date: May 7, 2015
    Inventors: Nataliya V. Fedorova, Eric M. Moore, Sehyun Nam, Pamela A. Percha, Sachin Talwar
  • Publication number: 20150112004
    Abstract: Disclosed are a halogen-free fire-retardant polyamide composition, and a preparation method and application thereof. The halogen-free fire-retardant polyamide composition is prepared from 35 to 71.5% of a semi-aromatic polyamide, 10 to 35% of a fire retardant and 0 to 50% of an inorganic reinforcing filler, the terminal amino group content of the semi-aromatic polyamide being 80 to 150 mol/t. The halogen-free fire-retardant polyamide composition of the present invention has good heat stability and releases only a small amount of gas in production; mold dirt is not easily formed, and the halogen-free fire-retardant polyamide composition can be produced continuously.
    Type: Application
    Filed: January 9, 2012
    Publication date: April 23, 2015
    Applicants: SHANGHAI KINGFA SCI., & TECH. CO., LTD., KINGFA SCI & TECH. CO., LTD.
    Inventors: Jieming Long, Sujun Jiang, Qingfeng Yi, Xia Yan, Jiehong Mai, Jian Chen, Kaijun Ning, Tongmin Cai
  • Patent number: 9012546
    Abstract: This invention relates to a process for producing compounds derived from 9,10-Dihydro-9-Oxa-10-Phosphaphenantrene-10-oxide (DOPO). In particular, the invention relates to producing DOPO-derived compounds by reacting DOPO with diol compounds in the presence of a catalyst. This invention also relates to DOPO derived composition containing a high melting point diastereomer. The DOPO derived compounds may be useful as flame-retardants.
    Type: Grant
    Filed: March 28, 2011
    Date of Patent: April 21, 2015
    Assignee: Albemarle Corporation
    Inventors: Qiang Yao, Junzuo Wang, Arthur G. Mack
  • Publication number: 20150105484
    Abstract: Disclosed are new compositions consisting of mixtures of flame retardants for thermoplastic elastomers with the addition of phosphinate salt and phosphonate oligomers, polymers or copolymers, and optionally additional flame retardants. The compositions exhibit an excellent combination of processing characteristics, thermal and mechanical properties, and are flame retardant. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, wires, and cables including these compositions, or any combination thereof.
    Type: Application
    Filed: October 14, 2014
    Publication date: April 16, 2015
    Inventors: Xiudong SUN, Zhiyuan LAN, Jan-Pleun LENS
  • Patent number: 8987359
    Abstract: A flame retardant polyamide resin composition includes (A) about 40 to about 60% by weight of a crystalline polyamide resin, (B) about 10 to about 20% by weight of polyphenylene sulfide resin, (C) about 5 to about 15% by weight of flame retardant containing phosphinic acid metal slat compound, (D) about 20 to about 40% by weight of glass fiber and (E) about 0.1 to about 1% by weight of phosphite antioxidant. The flame retardancy polyamide resin composition can have excellent mechanical properties such as impact strength, flexural modulus, flexural strength and/or tensile strength and can exhibit reduced gas blistering on a surface of a specimen thereof.
    Type: Grant
    Filed: June 10, 2013
    Date of Patent: March 24, 2015
    Assignee: Cheil Industries Inc.
    Inventors: Hyoung Taek Kang, Eun Joo Lee, Sang Hyun Hong, Jong Cheol Lim
  • Patent number: 8987357
    Abstract: The present invention relates to a thermoplastic molding composition comprising the following components: A) 20 to 98.99% by weight of at least one polyamide, B) 0.01 to 40% by weight of at least one branched polyimide selected from condensates of either b1) at least one polyisocyanate having an average of more than two isocyanate groups per molecule or b2) at least one polyamine having an average of more than two amino groups per molecule and b3) at least one polycarboxylic acid having at least three COOH groups per molecule or its anhydride C) 1 to 59% by weight of at least one flame retardant selected from the group of c1) phosphorus-containing flame retardants c2) nitrogen-containing flame retardants and mixtures of these, D) 0 to 50% by weight of further additives, where the total of the proportions by weight is 100% by weight based on the molding composition.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: March 24, 2015
    Assignee: BASF SE
    Inventors: Anna Cristadoro, Alexander König, Michael Roth
  • Patent number: 8969443
    Abstract: The present invention relates to the combination of halogen-free flame retardant additives in a copolyester to improve the flame retardant properties of the copolyester composition while retaining impact properties, methods of making the copolyester composition and articles made from the copolyester composition. More specifically, the present invention relates to the use of a nitrogen containing flame retardant and a metal phosphorous-containing compound in copolyester compositions to improve the flame retardant properties while retaining impact properties, methods of making said copolyester compositions and articles therefrom.
    Type: Grant
    Filed: August 20, 2013
    Date of Patent: March 3, 2015
    Assignee: Eastman Chemical Company
    Inventor: Robert Erik Young
  • Patent number: 8957144
    Abstract: A polycarbonate resin composition having improved chemical resistance and solvent resistance while maintaining the impact resistance, heat resistance, thermal stability, and the like inherent to the polycarbonate resin which comprises 100 parts by weight of polycarbonate resin and 0.01 to 20 parts by weight of a specific alkyl ketene dimer, and inhibits problems such as cracking, and the like, even when solvents or various chemicals such as hand creams and detergents adhere to the molded article obtained from the resin composition.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: February 17, 2015
    Assignee: Styron Europe GmbH
    Inventors: Tadashi Shinomiya, Keiko Sakaguchi
  • Publication number: 20150031805
    Abstract: Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants.
    Type: Application
    Filed: July 22, 2014
    Publication date: January 29, 2015
    Applicant: CHEMTURA CORPORATION
    Inventors: Zachary D. Stockdale, Mark V. Hanson, Larry D. Timberlake, Subramaniam Narayan, William R. Fielding
  • Patent number: 8940834
    Abstract: An unreinforced, halogen-free polyamide moulding composition having the following composition: (A) 62-87% by weight of a partially aromatic, partially crystalline copolyamide having a melting point of 270° C. to 320° C. and made up of 100% by weight of diacid fraction composed of: 50-100% by weight of terephthalic acid (TPA) and/or naphthalenedicarboxylic acid; 0-50% by weight of isophthalic acid (IPA), and 100% by weight of diamine fraction; (B) 5-15% by weight of ionomer; (C) 8-18% by weight of flame retardants; (D) 0-5% by weight of additives; where the components (A)-(D) add up to 100% by weight.
    Type: Grant
    Filed: July 8, 2011
    Date of Patent: January 27, 2015
    Assignee: EMS-Patent AG
    Inventors: Andreas Bayer, Manfred Hewel
  • Publication number: 20150018464
    Abstract: The invention relates to mixed alkali-aluminum phosphites of the formula (I) Al2.00Mz(HPO3)y(OH)vx(H2O)w??(I) in which M represents alkali metal ions, z is 0.01 to 1.5, y is 2.63 to 3.5, v is 0 to 2, w is 0 to 4; to a process for preparation thereof and to the use thereof.
    Type: Application
    Filed: November 28, 2012
    Publication date: January 15, 2015
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Harald Bauer, Sebastian Hoerold, Martin Sicken
  • Patent number: 8921465
    Abstract: To provide a polybutylene terephthalate resin composition having excellent tracking resistance, mechanical strength, and low-hygroscopicity, and being flame-retarded by a non-halogen-containing flame retardant. A polybutylene terephthalate resin composition is prepared by compounding polyamide resin, an organic phosphorous flame retardant, and a nitrogen-containing flame retardant assistant into polybutylene terephthalate resin, wherein the content of the polyamide resin is not less than 1 part by mass and not more than 15 parts by mass to 100 parts by mass of the polybutylene terephthalate resin.
    Type: Grant
    Filed: May 13, 2011
    Date of Patent: December 30, 2014
    Assignee: Wintech Polymer Ltd.
    Inventors: Takakazu Hirakawa, Nobuyuki Sueyasu
  • Publication number: 20140370301
    Abstract: According to a resin composition for a pigment-containing insulating film which resin composition contains at least a (A) binder polymer and (B) pigment-containing cross-linked polymer particles, it is possible to provide a resin composition for a pigment-containing insulating film which resin composition is excellent in tack property after drying and allows a resultant pigment-containing insulating film to be excellent in flexibility and electrical insulation reliability and to be small in warpage after curing, a resin film for a pigment-containing insulating film, a pigment-containing insulating film, and a printed wiring board provided with a pigment-containing insulating film.
    Type: Application
    Filed: December 19, 2012
    Publication date: December 18, 2014
    Applicant: Kaneka Corporation
    Inventor: Yoshihide Sekito
  • Publication number: 20140371361
    Abstract: The invention relates to aluminum hydrogenphosphites of the formula (I) Al2.00(HPO3)v(H2PO3)y×(H2O)??(I) in which v is 2 to 2.99, y is 2 to 0.01 and z 0 to 4; to a process for preparation thereof and to the use thereof.
    Type: Application
    Filed: November 28, 2012
    Publication date: December 18, 2014
    Applicant: Clariant Finance (BVI) Limited
    Inventors: Harald Bauer, Sebastian Hoerold, Martin Sicken
  • Publication number: 20140363639
    Abstract: The present invention provides a resin composition for an insulating film which resin composition is excellent in tack property after drying and allows a resultant insulating film to be excellent in flexibility and electrical insulation reliability and to be small in warpage after curing, a resin film for an insulating film, an insulating film, and a printed wiring board provided with an insulating film. The resin composition for an insulating film contains at least: a (A) binder polymer; and (B) cross-linked polymer particles, whose polymer has a urethane bond and a carbonate skeleton in its molecule.
    Type: Application
    Filed: December 19, 2012
    Publication date: December 11, 2014
    Inventor: Yoshihide Sekito
  • Publication number: 20140363654
    Abstract: The present invention relates to a flame-retardant polyamide moulding composition with good mechanical properties with the following constitution: (A) from 25 to 90% by weight of at least one polyamide, (B) from 5 to 60% by weight of glass fibres, where the arithmetic average of the length of these in the polyamide moulding composition is from 100 to 220 ?m, (C) from 5 to 25% by weight of at least one phosphinic salt and/or one diphosphinic salt, (D) from 0 to 20% by weight of at least one additive, where the entirety of components (A) to (D) gives 100% by weight. The invention also relates to processes for the production of moulding compositions of this type, to mouldings produced therefrom, and also to uses.
    Type: Application
    Filed: June 6, 2014
    Publication date: December 11, 2014
    Applicant: EMS-PATENT AG
    Inventors: Mark D. ROTH, Nikolai LAMBERTS, Pierre DUBON, Gion Antoni TUOR
  • Patent number: 8901214
    Abstract: The present invention provides a resin composition that simultaneously (1) supports high productivities, (2) is resistant to bleed out by the flame retardant present in the composition, (3) is resistant to migration of its components to another resin, (4) exhibits a high flame retardancy, and (5) exhibits high flexibility. The resin composition includes components (A) a polyphenylene ether, (B) a hydrogenated copolymer, (C) a styrene resin and/or olefin resin, and (D) a metal phosphinate, wherein the component (B) includes (B1) a polymer block principally comprising an aromatic vinyl monomer unit, and (B2) a hydrogenated copolymer block principally comprising an aromatic vinyl monomer unit and a conjugated diene monomer unit, and a content of the aromatic vinyl monomer unit in the (B2) is 20 to 95% by weight, and a content of the aromatic vinyl monomer unit in the (B) is 35 to 80% by weight.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: December 2, 2014
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Yoshifumi Araki, Takashi Sato, Takahiro Hisasue
  • Publication number: 20140350149
    Abstract: The invention relates to a mixture of at least one dialkylphosphinic acid of the formula (I) in which R1, R2 are the same or different and are each C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl, with at least one different dialkylphosphinic acid of the formula (II) in which R3, R4 are the same or different and are each C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl and/or C7-C18-alkylaryl, with the proviso that at least one of the R3 and R4 radicals is different than R1 and R2.
    Type: Application
    Filed: December 13, 2012
    Publication date: November 27, 2014
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Fabian Schneider, Frank Osterod, Harald Bauer, Martin Sicken
  • Publication number: 20140350147
    Abstract: A method of producing metal flakes (72?) is provided. The method includes: applying a layer of ionic liquid (70) to a substrate (24); forming a layer of metal (70) on the substrate (24) over the ionic liquid (70); and removing the layer of metal (70) from the substrate (24).
    Type: Application
    Filed: August 24, 2012
    Publication date: November 27, 2014
    Applicant: ECKART AMERICA CORPORATION
    Inventor: John Moffatt
  • Patent number: 8889772
    Abstract: The invention relates to a method for producing mixtures of alkylphosphonous acid and dialkylphosphinic acid salts, characterized in that a) a phosphinic acid source (I) is reacted with olefins (II) in the presence of a catalyst A to obtain a mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or salts or esters thereof, and b) the thus obtained mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or the salts or esters thereof is reacted with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base to obtain the corresponding mixtures of alkylphosphonous acid salt (V) and dialkylphosphinic acid salt (VI) of said metals and/or a nitrogen compound, (V) (VI), wherein Y represents Mg, Ca, AI, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na; K and/or a nitrogen compound and n represents ¼, ?, ½, 1.
    Type: Grant
    Filed: April 20, 2011
    Date of Patent: November 18, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Michael Hill, Sebastian Hoerold, Werner Krause, Martin Sicken
  • Patent number: 8883894
    Abstract: The present invention provides an insulating film including: a (A) binder polymer; (B) spherical organic beads; and (C) fine particles containing at least one element selected from the group consisting of phosphorus, aluminum, and magnesium, both the (B) spherical organic bead and the (C) fine particles being dispersed in a predetermined state in the insulating film.
    Type: Grant
    Filed: February 22, 2012
    Date of Patent: November 11, 2014
    Assignee: Kaneka Corporation
    Inventor: Yoshihide Sekito
  • Publication number: 20140329944
    Abstract: A polyamide molding material is proposed, which comprises at least one partially crystalline, partially aromatic polyamide (A) and at least one amorphous polyamide (B). The polyamides (A) and (B) together make up 30-60 wt.-% of the polyamide molding material. Furthermore, the polyamide molding material comprises 40-70 wt.-% glass fibers (C) having flat cross section, 0-15 wt.-% of at least one nonhalogenated flame retardant (D), and 0-10 wt.-% further additives (E), the components (A) to (E) adding up to 100 wt.-% of the polyamide molding material. The at least one partially crystalline, partially aromatic polyamide (A) has a glass transition temperature of at least 105° C. The polyamide molding material according to the invention is preferably distinguished in an injection-molding burr formation test in that, at a melt temperature of 320° C. and a tool temperature of 90° C.
    Type: Application
    Filed: December 23, 2011
    Publication date: November 6, 2014
    Applicant: EMS-PATENT AG
    Inventors: Philipp Harder, Herbert Mossauer
  • Patent number: 8865804
    Abstract: The present invention provides a resin composition that simultaneously (1) supports high productivities, (2) is resistant to bleed out by the flame retardant present in the composition, (3) is resistant to migration of its components to another resin, (4) exhibits a high flame retardancy, and (5) exhibits high flexibility. The resin composition includes components (A) a polyphenylene ether, (B) a hydrogenated copolymer, (C) a styrene resin and/or olefin resin, and (D) a metal phosphinate, wherein the component (B) includes (B1) a polymer block principally comprising an aromatic vinyl monomer unit, and (B2) a hydrogenated copolymer block principally comprising an aromatic vinyl monomer unit and a conjugated diene monomer unit, and a content of the aromatic vinyl monomer unit in the (B2) is 20 to 95% by weight, and a content of the aromatic vinyl monomer unit in the (B) is 35 to 80% by weight.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: October 21, 2014
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Yoshifumi Araki, Takashi Sato, Takahiro Hisasue
  • Publication number: 20140296396
    Abstract: Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety.
    Type: Application
    Filed: October 31, 2012
    Publication date: October 2, 2014
    Inventors: John Ta-Yuan Lai, Ti Chou
  • Publication number: 20140288220
    Abstract: Disclosed are heat resistant polyamide compositions including a) one or more polyamide resins, b) one or more reinforcing agents, c) a zinc compound; d) a copper heat stabilizer; and optionally, e) a polyhydric alcohol.
    Type: Application
    Filed: March 25, 2013
    Publication date: September 25, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Andrew Jay Duncan, Benjamin Weaver Messmore, Jennifer Leigh Thompson
  • Patent number: 8841366
    Abstract: This disclosure relates to thermoplastic compositions comprising a polycarbonate copolymer, the polycarbonate copolymer comprising first repeating carbonate units and second repeating units selected from carbonate units that are different from the first carbonate units, polysiloxane units, and a combination comprising at least one of the foregoing unit; and an organophosphorus flame retardant in an amount effective to provide 0.1 to 1.0 wt % phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after 4 minutes (Ds-4) of less than or equal to 600 determined according to ISO 5659-2 on a 3 mm thick plaque, and a material heat release of less than or equal to 160 kW/m2 determined according to ISO 5660-1 on a 3 mm thick plaque.
    Type: Grant
    Filed: February 28, 2013
    Date of Patent: September 23, 2014
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Mark Adrianus Johannes van der Mee, Robert Dirk van de Grampel, Roland Sebastian Assink, Paul Dean Sybert
  • Publication number: 20140275367
    Abstract: A flame retardant polyamide resin composition includes (A) about 40 to about 60% by weight of a crystalline polyamide resin, (B) about 10 to about 20% by weight of polyphenylene sulfide resin, (C) about 5 to about 15% by weight of flame retardant containing phosphinic acid metal slat compound, (D) about 20 to about 40% by weight of glass fiber and (E) about 0.1 to about 1% by weight of phosphite antioxidant. The flame retardancy polyamide resin composition can have excellent mechanical properties such as impact strength, flexural modulus, flexural strength and/or tensile strength and can exhibit reduced gas blistering on a surface of a specimen thereof.
    Type: Application
    Filed: June 10, 2013
    Publication date: September 18, 2014
    Inventors: Hyoung Taek Kang, Eun Joo Lee, Sang Hyun Hong, Jong Cheol Lim
  • Patent number: 8795557
    Abstract: Disclosed herein is a flame resistant composition comprising a compatibilized blend of a polyphthalamide and a poly(arylene ether); and a phosphinate, wherein the composition is substantially free of linear aliphatic polyamides.
    Type: Grant
    Filed: November 4, 2008
    Date of Patent: August 5, 2014
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventor: Mark Elkovitch
  • Patent number: 8791189
    Abstract: A thermoplastic composition comprises, based on the total weight of the composition: 51-90 wt % polyester, 10-49 wt % ABS impact modifier; 0-20 wt % of multifunctional epoxy compound; 0-40 wt % filler; 0-2 wt % fibrillated fluoropolymer; and more than 0 to 5 wt % of a stabilizer composition. An article blow molded or injection molded from the composition has a multi-axial impact total energy from 30-100 Joules at ?30° C. and a ductility of more than 90%; a permeability of more than 0 and less than or equal to 1.5 g/m2-day to ASTM D 471-98 Fuel C, measured after exposure to ASTM D 471-98 Fuel C vapor for 20 weeks at 40° C.; an MVR of 1-20 cc/10 min., measured at 265° C.; a flexural modulus of greater than 1300 MPa; and retains at least 75% of its initial tensile elongation at break, after exposure to Fuel E85 for 28 days at 70° C.
    Type: Grant
    Filed: August 7, 2008
    Date of Patent: July 29, 2014
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Parminder Agarwal, Donald Howard Ellington, Robert Russell Gallucci, Josephus Gerardus M. van Gisbergen, Vishvajit Chandrakant Juikar, Ihab Odeh, Sathish Kumar Ranganathan, Kenneth Frederick Miller, Veeraraghavan Srinivasan
  • Patent number: 8779040
    Abstract: The present invention is directed to a composition comprising: (a) a polyethylene terephthalate; (b) a copolycarbonate of 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP) and another bisphenol; (c) a polycarbonate-polysiloxane copolymer; and (d) a non-halogenated flame retardant. The invention is also directed to processes for making such compositions as well as articles derived therefrom.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: July 15, 2014
    Assignee: SABIC Global Technologies B.V.
    Inventors: Chris van der Weele, Johannes Hubertus Gabriel Marie Lohmeijer, Andries J. P. van Zyl
  • Publication number: 20140187691
    Abstract: A flame retardant includes a polymer including a unit represented by Formula 1: wherein A and B are each independently a single bond, C1 to C5 alkylene, C1 to C5 alkylidene, C5 to C6 cycloalkylidene, —S— or —SO2—, provided that A and B are different from each other; R1 and R4 are each independently substituted or unsubstituted C1 to C6 alkyl, substituted or unsubstituted C6 to C20 aryl, or substituted or unsubstituted C6 to C20 aryloxy; R2, R3, R5 and R6 are each independently substituted or unsubstituted C1 to C6 alkyl, substituted or unsubstituted C3 to C6 cycloalkyl, substituted or unsubstituted C6 to C12 aryl, or halogen; a, b, c and d are each independently an integer from 0 to 4; m is an integer from 0 to 500; and n is an integer from 1 to 500. The flame retardant polyamide resin composition can have excellent flame retardancy and can maintain crystallinity.
    Type: Application
    Filed: December 12, 2013
    Publication date: July 3, 2014
    Applicant: Cheil Industries Inc.
    Inventors: Seung Woo JANG, Chang Hong KO, Min Soo LEE, Sung Hee AHN
  • Patent number: 8765849
    Abstract: The invention relates to a composition comprising, relative to the total weight of the composition: between 25% and 52% by weight of at least one semi-crystalline or amorphous polyamide, having an amine chain-end content of less than 0.040 meq/g, between 24% and 40% by weight of at least one reinforcer, and between 24% and 35% by weight of at least one metal salt, optionally contained in a polymer, chosen from a metal salt of phosphinic acid, a metal salt of diphosphinic acid, and a mixture thereof. The invention also relates to the process for preparing this composition and its use.
    Type: Grant
    Filed: January 27, 2010
    Date of Patent: July 1, 2014
    Assignee: Arkema France
    Inventors: Philippe Blondel, Eric Gamache, Benjamin Saillard, Barbara Ramfel
  • Patent number: 8759429
    Abstract: Disclosed herein is a flame-retardant copolyetherester composition comprising: (a) at least one copolyetherester; (b) about 5-35 wt % of at least one halogen-free flame retardant; (c) about 0.1-20 wt % of at least one nitrogen-containing compound; (d) about 0.1-10 wt % of at least one aromatic phosphate and (e) about 0.1-10 wt % of at least at least one novolac resin. Further disclosed herein are articles comprising component parts formed of the flame-retardant copolyetherester composition.
    Type: Grant
    Filed: December 6, 2012
    Date of Patent: June 24, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Yong Ni
  • Patent number: 8735477
    Abstract: The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (H) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with compounds of formula (V) to yield mono-functionalized dialkylphosphinic acid derivatives (VI) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivatives (VI) are reacted to yield a mono-carboxyfunctionalized diakylphosphinic acid derivative (III) in the presence of a catalyst C, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X and Y are the same or different and stand independently of each for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 a
    Type: Grant
    Filed: October 6, 2009
    Date of Patent: May 27, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Michael Hill, Werner Krause, Martin Sicken
  • Patent number: 8735474
    Abstract: The invention relates to a flame retardant composition, wherein the following components: a) At least one flame retardant component selected from the group consisting of phosphinic acid salts and nitrogen containing compounds; and b) At least one polymeric dispersing agent selected from the group consisting of styrenemaleic acid anhydride copolymers, long chain carboxylic acid salts and aliphatic polyether substituted by acidic groups; and c) A polymer substrate; are present.
    Type: Grant
    Filed: August 20, 2009
    Date of Patent: May 27, 2014
    Assignee: BASF SE
    Inventors: Simon Kniesel, Rudolf Pfaendner
  • Patent number: 8716379
    Abstract: Flame retardant thermoplastic polyurethane (TPU) compositions are disclosed having a flame retardant package comprising an organo-phosphinate component, an organo-phosphate component, and a polyhydric alcohol. The flame retardant components may be present in an amount from about 5 to about 40 weight percent of the phosphinate compound; from about 5 to about 20 weight percent of the phosphate compound, and from about 0.1 to about 15 weight percent of the polyhydric alcohol, based on the total weight of the TPU composition. Processes are disclosed to make the TPU compositions and to make wire and cable constructions employing the TPU compositions as the jacket of the wire and cable constructions. The TPU compositions exhibit excellent flame retardant capabilities as measured by Limited Oxygen Index testing and/or UL 94 Vertical Burn tests.
    Type: Grant
    Filed: August 1, 2013
    Date of Patent: May 6, 2014
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Sridhar K. Siddhamalli, Carl A. Brown
  • Patent number: 8703876
    Abstract: A process for producing water-absorbing polymer particles, wherein at least one inorganic phosphoric acid and/or salt thereof and at least one organic 2-hydroxy acid and/or salt thereof is added, where the phosphorus in the inorganic phosphoric acid has an oxidation number of less than +V and the organic 2-hydroxy acid does not have any ethylenically unsaturated groups, and also the water-absorbing polymer particles obtainable by the process according to the invention.
    Type: Grant
    Filed: March 4, 2011
    Date of Patent: April 22, 2014
    Assignee: BASF SE
    Inventors: Norbert Herfert, Thomas Daniel, Bootsara Parchana
  • Publication number: 20140088230
    Abstract: A composition is prepared by melt blending specific amounts of polyamide, acid-functionalized poly(phenylene ether), polyimide-polysiloxane block copolymer, and metal dialkylphosphinate. The composition, which exhibits improved flame retardancy and tensile modulus relative to known blends of poly(phenylene ether), polyamide, and polyimide, is useful for forming electrical components, such as photovoltaic junction boxes and connectors, inverter housings, automotive electrical connectors, electrical relays, and charge couplers.
    Type: Application
    Filed: September 25, 2012
    Publication date: March 27, 2014
    Inventor: Snezana Grcev