Phosphorus Bonded To Only Two Chalcogen Atoms And Having At Least One P-c Linkage Patents (Class 524/133)
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Patent number: 12234345Abstract: The invention provides a flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20% to 99.7% by weight of phosphinic salt of the formula (I), (I), in which R1 and R2 are each ethyl, M is Al and m is 3; as component B 0.2% to 16% by weight of aluminium salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid; as component C 0.Type: GrantFiled: June 11, 2021Date of Patent: February 25, 2025Assignee: CLARIANT INTERNATIONAL LTDInventors: Sebastian Hoerold, Harald Bauer
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Patent number: 12209175Abstract: Described herein is a flame retardant-stabilizer mixture including as a component A, 5% to 95% by weight of aluminium diethylphosphinate (DEPAL) and/or zinc diethylphosphinate (DEPZN); as a component B, 5% to 95% by weight of titanium phosphinates and/or titanyl phosphinates of the formula (I) (DEPTI) in which x is a number from 0 to 1.9; as a component C, 0% to 10% by weight of aluminium phosphite or zinc phosphite of the formula (II), [HP(?O)O2]2?Zn2+, and formula (III), [HP(?O)O2]2?3Al3+2; as a component D, 0% to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus-containing and/or nitrogen-containing flame retardant; as a component E, 0% to 70% by weight of a filler and reinforcer; as a component F, 0% to 3% by weight of an organic phosphonite and/or an organic phosphite and/or mixtures with phenolic antioxidants; and as a component G, 0% to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) typically having chain lengths of C14 to C40.Type: GrantFiled: April 25, 2022Date of Patent: January 28, 2025Assignee: CLARIANT INTERNATIONAL LTDInventors: Sebastian Hörold, Harald Bauer, Eva Maria Leuschner
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Patent number: 12152129Abstract: The present disclosure provides for the production of non-halogenated phosphorus containing, thermally stable flame retardant materials directly in the form of a powder or small particles. The process generally includes heating one or more phosphonic acid salts in a high boiling, water miscible, acid stable solvent to dehydration reaction temperatures of 200° C. or higher.Type: GrantFiled: December 18, 2019Date of Patent: November 26, 2024Assignee: LANXESS CorporationInventors: Julia Yue Lee, Qingliang He
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Patent number: 12139608Abstract: A non-halogenated flame retardant polyamide composition is disclosed which comprises a polyamide, a non-halogenated flame retardant, a PA-6 homopolymer, and at least one heat stabilizer comprising a copper-containing heat stabilizer, an amine-containing heat stabilizer, or a phenol-containing heat stabilizer. The polyamide may have a ratio of carboxylic acid to amine end groups of greater than 1.8:1. The polyamide composition may comprise less than 900 ppm of bromine. Products formed from the composition are also disclosed.Type: GrantFiled: April 1, 2020Date of Patent: November 12, 2024Assignee: Ascend Performance Materials Operations LLCInventor: Kimberly M. White
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Patent number: 12037495Abstract: A flame retardant low hardness material of the present technology contains: 100 parts by mass of a styrene-based elastomer; from 500 to 807 parts by mass of a process oil composed of a petroleum-based hydrocarbon; from 200 to 494 parts by mass of a melamine polyphosphate-based flame retardant; from 200 to 494 parts by mass of a metal phosphinate-based flame retardant; from 4 to 6 parts by mass of a fluorine-based resin; and from 56 to 93 parts by mass of a carbon filler, wherein an asker C hardness is 30 or less.Type: GrantFiled: May 20, 2019Date of Patent: July 16, 2024Assignee: Kitagawa Industries Co., Ltd.Inventors: Guowei Li, Shinya Washino
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Patent number: 12030979Abstract: The present invention relates to a process for producing translucent polyurethane and polyisocyanurate foams by reaction of a component A, comprising A1 at least one polyol reactive with component B; A2 optionally at least one amine; A3 water and optionally formic acid or at least one physical blowing agent or mixtures thereof; A4 at least one foam stabilizer; A5 optionally auxiliary and/or additive substances; A6 optionally at least one flame retardant; A7 at least one catalyst; and a component B, comprising B1 at least one aliphatic or cycloaliphatic polyisocyanate component or a combination thereof; and B2 optionally at least one hydrophilized isocyanate; and B3 more than or equal to 10 parts by weight and up to 70 parts by weight of an aromatic polyisocyanate component, wherein the parts by weight of B3 are based on the sum of the parts by weight of B1 to B3 which are normalized to 100 parts by weight.Type: GrantFiled: October 1, 2019Date of Patent: July 9, 2024Assignee: Covestro Intellectual Property GmbH & Co. KGInventors: Lutz Böhnke, Dirk Achten, Hans-Josef Laas, Ann-Christin Bijlard
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Patent number: 11384201Abstract: A non-halogenated flame retardant polyamide composition is disclosed which comprises a polyamide, a non-halogenated flame retardant, and a synergist. The polyamide may have a ratio of carboxylic acid to amine end groups of greater than 1.8. Products formed from the composition are also disclosed. The polyamide may comprise nylon 6,6.Type: GrantFiled: January 7, 2020Date of Patent: July 12, 2022Assignee: Ascend Performance Materials Operations LLCInventor: Kimberly M. White
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Patent number: 11001710Abstract: A thermoplastic composition includes a poly(phthalamide), a poly(etherimide-siloxane), and optionally, an additive composition. The respective amounts of each component are further described herein. A method for the manufacture of the composition includes melt-mixing the components of the composition, and optionally, extruding the composition. Articles including the thermoplastic composition are also described.Type: GrantFiled: July 10, 2017Date of Patent: May 11, 2021Assignee: SHPP GLOBAL TECHNOLOGIES B.V.Inventors: Mian Dai, Liang Shen
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Patent number: 10920026Abstract: The present invention relates to a polymer composition, consisting of (A) 30-90 wt. % of at least one thermoplastic polymer comprising at least a semi-crystalline semi-aromatic polyamide (SSPA-1) in an amount in the range of 30-90 wt. %; (B) 10-70 wt. % of at least one reinforcing agent, and (C) 0-25 wt. % of one or more other components; wherein the SSPA-1 consists of (A-1-a) 90-100 wt. % of repeat units derived from (i) an aromatic dicarboxylic acid and (ii) diamines, and (A-1-b) 0-10 wt. % of repeat units derived from other monomers; the diamines (ii) consist of 80-95 mole % of a linear aliphatic diamine, 5-20 mole % of 2-methyl-pentamethylene diamine, and 0-10 mole % of other diamines; and the SSPA-1 has a melting temperature (Tm) of at least 300° C. The invention further relates to a molded part made of the composition, a process for making the composition and a process for making the molded part.Type: GrantFiled: September 27, 2017Date of Patent: February 16, 2021Assignee: DSM IP ASSETS B.V.Inventor: Zhujuan Wang
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Patent number: 10836904Abstract: The present invention relates to a low-halogen flame retardant thermoplastic polyamide composition that provides improved mechanical and electrical stability at elevated temperatures, where the thermoplastic composition comprises a polyamide resin; a non-halogen, nitrogen-containing flame retardant; a heat stabilizer containing a copper halide and an organophosphorus compound; an optional lubricant and/or mold release agent; and an optional colorant.Type: GrantFiled: October 17, 2017Date of Patent: November 17, 2020Assignee: Ascend Performance Materials Operations LLCInventors: Shawn J. Osborn, Christopher M. Carter
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Patent number: 10815376Abstract: The present invention relates to compositions comprising at least one thermoplastic polyurethane, at least melamine cyanurate, at least one first phosphorus-containing flame retardant (F1) selected from the group consisting of alkyl esters of phosphoric acid and alkyl esters of phosphonic acid, where the alkyl radicals are selected from C1 to C12 alkyl radicals, and at least one further phosphorus-containing flame retardant (F2) selected from the group consisting of derivatives of phosphinic acid, and to the use of such a composition for production of cable sheaths.Type: GrantFiled: August 17, 2016Date of Patent: October 27, 2020Assignee: BASF SEInventors: Oliver Steffen Henze, Oliver Muehren
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Patent number: 10662312Abstract: Disclosed herein is a flame retardant composition comprising 20 to 80 weight percent of a polycarbonate; 1 to 20 weight percent of a halogenated phenoxyphosphazene flame retardant, where all weight percents are based on a total weight of the flame retardant composition. Disclosed herein too is a method comprising blending a 20 to 80 weight percent of a polycarbonate; and 1 to 20 weight percent of a halogenated phenoxyphosphazene flame retardant to produce a flame retardant composition, where all weight percents are based on a total weight of the flame retardant composition.Type: GrantFiled: April 27, 2016Date of Patent: May 26, 2020Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Lin Chen, Hongtao Shi, Yun Zheng, Chunjie Zhang
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Patent number: 10147516Abstract: An extruded flexible flat cable, which has a superior formability, flexibility, adhesiveness, and fire-retardancy, with a low manufacturing cost, is adapted for sliding door of a motor vehicle and also other parts, and has a conductor covered with an insulation layer extrude-formed with an extrusion molding method, and the insulation layer formed from a fire-retardant resin composition containing a modified polybutylene terephthalate and a fire-retardant additive, where the fire-retardant resin composition has a melting point of 170-215 degrees C. measured in reference to JIS K7121 with a differential thermal analysis at a rate of temperature increase of 10 degrees C. per minute.Type: GrantFiled: January 13, 2017Date of Patent: December 4, 2018Assignee: Yazaki CorporationInventors: Maki Yamada, Kazuya Goshima
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Patent number: 9765183Abstract: A process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and having a number average molecular weight of at least 10,000 (as determined by GPC based on polystyrene standards) includes a first step wherein a prepolymer is made having the 2,5-furandicarboxylate moiety within the polymer backbone, followed in a second step by a polycondensation reaction. In the first step a 2,5-furandicarboxylate ester is transesterified with a compound or mixture of compounds containing two or more hydroxyl groups, in the presence of a tin(IV) based transesterification catalyst. In the second step at reduced pressure and under melt conditions the prepolymer prepared in the first step is polycondensed in the presence of a tin (II) based polycondensation catalyst until the polymer is obtained. This polymer may then be subjected to Solid State Polycondensation.Type: GrantFiled: July 7, 2016Date of Patent: September 19, 2017Assignee: Furanix Technologies B.V.Inventor: Laszlo Sipos
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Patent number: 9296897Abstract: A polyamide molding composition for the production of a stain-resistant article, the staining tendency (ST) of the article being at most 15. The composition contains 30-100% by weight of a polyamide mixture, consisting of more than 50 and up to 98% by weight of at least one semi-aromatic polyamide comprising 2 to up to 50% by weight of amorphous and/or microcrystalline polyamides having a glass transition temperature of at least 100° C., based on: 20-100 mol % of at least one cycloaliphatic diamine; and 0-80 mol % of at least one other aliphatic and/or aromatic diamine; and also aromatic and/or aliphatic dicarboxylic acids comprising at least 6 carbon atoms. In addition, the composition comprises inorganic white pigments, fibrous or particulate additives, impact toughness modifier and/or polymers different from (A), 0-25% by weight of a flame retardant.Type: GrantFiled: December 20, 2013Date of Patent: March 29, 2016Assignee: EMS-PATENT AGInventors: Mark Pfleghar, Etienne Aepli, Heinz Hoff, Botho Hoffmann
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Patent number: 9139714Abstract: The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkyl phosphonic acid, salt, salt or ester (II) thereof is reacted with compounds of formula (V) and/or (VI?) to yield mono-functionalized dialkylphosphinic acid derivatives (VI) and/or (VI?) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivatives (VI) and/or (VI?) are reacted to yield a mono-carboxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst C, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H1 C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X and Y are the same or different and stand independently oType: GrantFiled: October 6, 2009Date of Patent: September 22, 2015Assignee: Clariant Finance (BVI) LimitedInventors: Michael Hill, Werner Krause, Martin Sicken
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Patent number: 9034958Abstract: A polymer complex is disclosed which is the reaction product of one or more polymers having a terminal or pendant hydroxyl group, or a terminal or pendent carboxyl group, or combinations thereof, with at least one metal complex and one alkyl phosphate. This polymer complex acts as an adhesion promotion agent as well as a viscosity stabilizer when formulated in a printing ink or coating.Type: GrantFiled: November 16, 2004Date of Patent: May 19, 2015Assignee: Sun Chemical CorporationInventors: Mark Andreas Mielke, Mathew Charles Mathew, William P. Keaveney, Richard John Czarnecki, William Ford Wilson, Mark John Lindsey, Ralph Francis Arcurio
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Patent number: 9029443Abstract: Flame retardant thermoplastic polyurethane (TPU) compositions are disclosed having a flame retardant package comprising an organo-phosphinate component, an organo-phosphate component, and a polyhydric alcohol. The flame retardant components may be present in an amount from about 5 to about 40 weight percent of the phosphinate compound; from about 5 to about 20 weight percent of the phosphate compound, and from about 0.1 to about 15 weight percent of the polyhydric alcohol, based on the total weight of the TPU composition. Processes are disclosed to make the TPU compositions and to make wire and cable constructions employing the TPU compositions as the jacket of the wire and cable constructions. The TPU compositions exhibit excellent flame retardant capabilities as measured by Limited Oxygen Index testing and/or UL 94 Vertical Burn tests.Type: GrantFiled: April 30, 2014Date of Patent: May 12, 2015Assignee: Lubrizol Advanced Materials, Inc.Inventors: Sridhar K. Siddhamalli, Carl A. Brown
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Publication number: 20150125696Abstract: A melt blowing process comprising: (a) providing a thermoplastic polymer material that includes at least one or a plurality of polyester polymers and at least one or a combination of different meltable metal phosphinates; and (b) melt blowing the thermoplastic polymer material into at least one fiber or a plurality of fibers, with each fiber having a diameter or thickness that is less than about 10 microns. The metal phosphinate is in an amount that (a) reduces the viscosity of the polyester polymer and (b) functions as a crystallizing agent, which at least promotes crystallization of the polyester polymer, when the thermoplastic polymer material is melt blown into the at least one fiber. Non-woven and woven fibrous structures can be made using fibers made from this process.Type: ApplicationFiled: December 20, 2012Publication date: May 7, 2015Inventors: Nataliya V. Fedorova, Eric M. Moore, Sehyun Nam, Pamela A. Percha, Sachin Talwar
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Publication number: 20150112004Abstract: Disclosed are a halogen-free fire-retardant polyamide composition, and a preparation method and application thereof. The halogen-free fire-retardant polyamide composition is prepared from 35 to 71.5% of a semi-aromatic polyamide, 10 to 35% of a fire retardant and 0 to 50% of an inorganic reinforcing filler, the terminal amino group content of the semi-aromatic polyamide being 80 to 150 mol/t. The halogen-free fire-retardant polyamide composition of the present invention has good heat stability and releases only a small amount of gas in production; mold dirt is not easily formed, and the halogen-free fire-retardant polyamide composition can be produced continuously.Type: ApplicationFiled: January 9, 2012Publication date: April 23, 2015Applicants: SHANGHAI KINGFA SCI., & TECH. CO., LTD., KINGFA SCI & TECH. CO., LTD.Inventors: Jieming Long, Sujun Jiang, Qingfeng Yi, Xia Yan, Jiehong Mai, Jian Chen, Kaijun Ning, Tongmin Cai
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Patent number: 9012546Abstract: This invention relates to a process for producing compounds derived from 9,10-Dihydro-9-Oxa-10-Phosphaphenantrene-10-oxide (DOPO). In particular, the invention relates to producing DOPO-derived compounds by reacting DOPO with diol compounds in the presence of a catalyst. This invention also relates to DOPO derived composition containing a high melting point diastereomer. The DOPO derived compounds may be useful as flame-retardants.Type: GrantFiled: March 28, 2011Date of Patent: April 21, 2015Assignee: Albemarle CorporationInventors: Qiang Yao, Junzuo Wang, Arthur G. Mack
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Publication number: 20150105484Abstract: Disclosed are new compositions consisting of mixtures of flame retardants for thermoplastic elastomers with the addition of phosphinate salt and phosphonate oligomers, polymers or copolymers, and optionally additional flame retardants. The compositions exhibit an excellent combination of processing characteristics, thermal and mechanical properties, and are flame retardant. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, wires, and cables including these compositions, or any combination thereof.Type: ApplicationFiled: October 14, 2014Publication date: April 16, 2015Inventors: Xiudong SUN, Zhiyuan LAN, Jan-Pleun LENS
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Patent number: 8987359Abstract: A flame retardant polyamide resin composition includes (A) about 40 to about 60% by weight of a crystalline polyamide resin, (B) about 10 to about 20% by weight of polyphenylene sulfide resin, (C) about 5 to about 15% by weight of flame retardant containing phosphinic acid metal slat compound, (D) about 20 to about 40% by weight of glass fiber and (E) about 0.1 to about 1% by weight of phosphite antioxidant. The flame retardancy polyamide resin composition can have excellent mechanical properties such as impact strength, flexural modulus, flexural strength and/or tensile strength and can exhibit reduced gas blistering on a surface of a specimen thereof.Type: GrantFiled: June 10, 2013Date of Patent: March 24, 2015Assignee: Cheil Industries Inc.Inventors: Hyoung Taek Kang, Eun Joo Lee, Sang Hyun Hong, Jong Cheol Lim
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Patent number: 8987357Abstract: The present invention relates to a thermoplastic molding composition comprising the following components: A) 20 to 98.99% by weight of at least one polyamide, B) 0.01 to 40% by weight of at least one branched polyimide selected from condensates of either b1) at least one polyisocyanate having an average of more than two isocyanate groups per molecule or b2) at least one polyamine having an average of more than two amino groups per molecule and b3) at least one polycarboxylic acid having at least three COOH groups per molecule or its anhydride C) 1 to 59% by weight of at least one flame retardant selected from the group of c1) phosphorus-containing flame retardants c2) nitrogen-containing flame retardants and mixtures of these, D) 0 to 50% by weight of further additives, where the total of the proportions by weight is 100% by weight based on the molding composition.Type: GrantFiled: May 25, 2012Date of Patent: March 24, 2015Assignee: BASF SEInventors: Anna Cristadoro, Alexander König, Michael Roth
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Patent number: 8969443Abstract: The present invention relates to the combination of halogen-free flame retardant additives in a copolyester to improve the flame retardant properties of the copolyester composition while retaining impact properties, methods of making the copolyester composition and articles made from the copolyester composition. More specifically, the present invention relates to the use of a nitrogen containing flame retardant and a metal phosphorous-containing compound in copolyester compositions to improve the flame retardant properties while retaining impact properties, methods of making said copolyester compositions and articles therefrom.Type: GrantFiled: August 20, 2013Date of Patent: March 3, 2015Assignee: Eastman Chemical CompanyInventor: Robert Erik Young
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Patent number: 8957144Abstract: A polycarbonate resin composition having improved chemical resistance and solvent resistance while maintaining the impact resistance, heat resistance, thermal stability, and the like inherent to the polycarbonate resin which comprises 100 parts by weight of polycarbonate resin and 0.01 to 20 parts by weight of a specific alkyl ketene dimer, and inhibits problems such as cracking, and the like, even when solvents or various chemicals such as hand creams and detergents adhere to the molded article obtained from the resin composition.Type: GrantFiled: December 19, 2013Date of Patent: February 17, 2015Assignee: Styron Europe GmbHInventors: Tadashi Shinomiya, Keiko Sakaguchi
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Publication number: 20150031805Abstract: Certain phosphonic acid salts heated at temperatures over 200° C. generate thermally stable, highly efficient flame retardant materials well suited for use as flame retardant additives in polymers. The flame retardants of the invention can be used as the sole flame retardant in a composition or in combination with other flame retardants, synergists or adjuvants.Type: ApplicationFiled: July 22, 2014Publication date: January 29, 2015Applicant: CHEMTURA CORPORATIONInventors: Zachary D. Stockdale, Mark V. Hanson, Larry D. Timberlake, Subramaniam Narayan, William R. Fielding
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Patent number: 8940834Abstract: An unreinforced, halogen-free polyamide moulding composition having the following composition: (A) 62-87% by weight of a partially aromatic, partially crystalline copolyamide having a melting point of 270° C. to 320° C. and made up of 100% by weight of diacid fraction composed of: 50-100% by weight of terephthalic acid (TPA) and/or naphthalenedicarboxylic acid; 0-50% by weight of isophthalic acid (IPA), and 100% by weight of diamine fraction; (B) 5-15% by weight of ionomer; (C) 8-18% by weight of flame retardants; (D) 0-5% by weight of additives; where the components (A)-(D) add up to 100% by weight.Type: GrantFiled: July 8, 2011Date of Patent: January 27, 2015Assignee: EMS-Patent AGInventors: Andreas Bayer, Manfred Hewel
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Publication number: 20150018464Abstract: The invention relates to mixed alkali-aluminum phosphites of the formula (I) Al2.00Mz(HPO3)y(OH)vx(H2O)w??(I) in which M represents alkali metal ions, z is 0.01 to 1.5, y is 2.63 to 3.5, v is 0 to 2, w is 0 to 4; to a process for preparation thereof and to the use thereof.Type: ApplicationFiled: November 28, 2012Publication date: January 15, 2015Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Harald Bauer, Sebastian Hoerold, Martin Sicken
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Patent number: 8921465Abstract: To provide a polybutylene terephthalate resin composition having excellent tracking resistance, mechanical strength, and low-hygroscopicity, and being flame-retarded by a non-halogen-containing flame retardant. A polybutylene terephthalate resin composition is prepared by compounding polyamide resin, an organic phosphorous flame retardant, and a nitrogen-containing flame retardant assistant into polybutylene terephthalate resin, wherein the content of the polyamide resin is not less than 1 part by mass and not more than 15 parts by mass to 100 parts by mass of the polybutylene terephthalate resin.Type: GrantFiled: May 13, 2011Date of Patent: December 30, 2014Assignee: Wintech Polymer Ltd.Inventors: Takakazu Hirakawa, Nobuyuki Sueyasu
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Publication number: 20140371361Abstract: The invention relates to aluminum hydrogenphosphites of the formula (I) Al2.00(HPO3)v(H2PO3)y×(H2O)??(I) in which v is 2 to 2.99, y is 2 to 0.01 and z 0 to 4; to a process for preparation thereof and to the use thereof.Type: ApplicationFiled: November 28, 2012Publication date: December 18, 2014Applicant: Clariant Finance (BVI) LimitedInventors: Harald Bauer, Sebastian Hoerold, Martin Sicken
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Publication number: 20140370301Abstract: According to a resin composition for a pigment-containing insulating film which resin composition contains at least a (A) binder polymer and (B) pigment-containing cross-linked polymer particles, it is possible to provide a resin composition for a pigment-containing insulating film which resin composition is excellent in tack property after drying and allows a resultant pigment-containing insulating film to be excellent in flexibility and electrical insulation reliability and to be small in warpage after curing, a resin film for a pigment-containing insulating film, a pigment-containing insulating film, and a printed wiring board provided with a pigment-containing insulating film.Type: ApplicationFiled: December 19, 2012Publication date: December 18, 2014Applicant: Kaneka CorporationInventor: Yoshihide Sekito
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Publication number: 20140363654Abstract: The present invention relates to a flame-retardant polyamide moulding composition with good mechanical properties with the following constitution: (A) from 25 to 90% by weight of at least one polyamide, (B) from 5 to 60% by weight of glass fibres, where the arithmetic average of the length of these in the polyamide moulding composition is from 100 to 220 ?m, (C) from 5 to 25% by weight of at least one phosphinic salt and/or one diphosphinic salt, (D) from 0 to 20% by weight of at least one additive, where the entirety of components (A) to (D) gives 100% by weight. The invention also relates to processes for the production of moulding compositions of this type, to mouldings produced therefrom, and also to uses.Type: ApplicationFiled: June 6, 2014Publication date: December 11, 2014Applicant: EMS-PATENT AGInventors: Mark D. ROTH, Nikolai LAMBERTS, Pierre DUBON, Gion Antoni TUOR
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Publication number: 20140363639Abstract: The present invention provides a resin composition for an insulating film which resin composition is excellent in tack property after drying and allows a resultant insulating film to be excellent in flexibility and electrical insulation reliability and to be small in warpage after curing, a resin film for an insulating film, an insulating film, and a printed wiring board provided with an insulating film. The resin composition for an insulating film contains at least: a (A) binder polymer; and (B) cross-linked polymer particles, whose polymer has a urethane bond and a carbonate skeleton in its molecule.Type: ApplicationFiled: December 19, 2012Publication date: December 11, 2014Inventor: Yoshihide Sekito
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Patent number: 8901214Abstract: The present invention provides a resin composition that simultaneously (1) supports high productivities, (2) is resistant to bleed out by the flame retardant present in the composition, (3) is resistant to migration of its components to another resin, (4) exhibits a high flame retardancy, and (5) exhibits high flexibility. The resin composition includes components (A) a polyphenylene ether, (B) a hydrogenated copolymer, (C) a styrene resin and/or olefin resin, and (D) a metal phosphinate, wherein the component (B) includes (B1) a polymer block principally comprising an aromatic vinyl monomer unit, and (B2) a hydrogenated copolymer block principally comprising an aromatic vinyl monomer unit and a conjugated diene monomer unit, and a content of the aromatic vinyl monomer unit in the (B2) is 20 to 95% by weight, and a content of the aromatic vinyl monomer unit in the (B) is 35 to 80% by weight.Type: GrantFiled: September 23, 2011Date of Patent: December 2, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshifumi Araki, Takashi Sato, Takahiro Hisasue
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Publication number: 20140350149Abstract: The invention relates to a mixture of at least one dialkylphosphinic acid of the formula (I) in which R1, R2 are the same or different and are each C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl, with at least one different dialkylphosphinic acid of the formula (II) in which R3, R4 are the same or different and are each C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl and/or C7-C18-alkylaryl, with the proviso that at least one of the R3 and R4 radicals is different than R1 and R2.Type: ApplicationFiled: December 13, 2012Publication date: November 27, 2014Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Fabian Schneider, Frank Osterod, Harald Bauer, Martin Sicken
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Publication number: 20140350147Abstract: A method of producing metal flakes (72?) is provided. The method includes: applying a layer of ionic liquid (70) to a substrate (24); forming a layer of metal (70) on the substrate (24) over the ionic liquid (70); and removing the layer of metal (70) from the substrate (24).Type: ApplicationFiled: August 24, 2012Publication date: November 27, 2014Applicant: ECKART AMERICA CORPORATIONInventor: John Moffatt
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Patent number: 8889772Abstract: The invention relates to a method for producing mixtures of alkylphosphonous acid and dialkylphosphinic acid salts, characterized in that a) a phosphinic acid source (I) is reacted with olefins (II) in the presence of a catalyst A to obtain a mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or salts or esters thereof, and b) the thus obtained mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or the salts or esters thereof is reacted with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base to obtain the corresponding mixtures of alkylphosphonous acid salt (V) and dialkylphosphinic acid salt (VI) of said metals and/or a nitrogen compound, (V) (VI), wherein Y represents Mg, Ca, AI, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na; K and/or a nitrogen compound and n represents ¼, ?, ½, 1.Type: GrantFiled: April 20, 2011Date of Patent: November 18, 2014Assignee: Clariant Finance (BVI) LimitedInventors: Michael Hill, Sebastian Hoerold, Werner Krause, Martin Sicken
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Patent number: 8883894Abstract: The present invention provides an insulating film including: a (A) binder polymer; (B) spherical organic beads; and (C) fine particles containing at least one element selected from the group consisting of phosphorus, aluminum, and magnesium, both the (B) spherical organic bead and the (C) fine particles being dispersed in a predetermined state in the insulating film.Type: GrantFiled: February 22, 2012Date of Patent: November 11, 2014Assignee: Kaneka CorporationInventor: Yoshihide Sekito
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Publication number: 20140329944Abstract: A polyamide molding material is proposed, which comprises at least one partially crystalline, partially aromatic polyamide (A) and at least one amorphous polyamide (B). The polyamides (A) and (B) together make up 30-60 wt.-% of the polyamide molding material. Furthermore, the polyamide molding material comprises 40-70 wt.-% glass fibers (C) having flat cross section, 0-15 wt.-% of at least one nonhalogenated flame retardant (D), and 0-10 wt.-% further additives (E), the components (A) to (E) adding up to 100 wt.-% of the polyamide molding material. The at least one partially crystalline, partially aromatic polyamide (A) has a glass transition temperature of at least 105° C. The polyamide molding material according to the invention is preferably distinguished in an injection-molding burr formation test in that, at a melt temperature of 320° C. and a tool temperature of 90° C.Type: ApplicationFiled: December 23, 2011Publication date: November 6, 2014Applicant: EMS-PATENT AGInventors: Philipp Harder, Herbert Mossauer
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Patent number: 8865804Abstract: The present invention provides a resin composition that simultaneously (1) supports high productivities, (2) is resistant to bleed out by the flame retardant present in the composition, (3) is resistant to migration of its components to another resin, (4) exhibits a high flame retardancy, and (5) exhibits high flexibility. The resin composition includes components (A) a polyphenylene ether, (B) a hydrogenated copolymer, (C) a styrene resin and/or olefin resin, and (D) a metal phosphinate, wherein the component (B) includes (B1) a polymer block principally comprising an aromatic vinyl monomer unit, and (B2) a hydrogenated copolymer block principally comprising an aromatic vinyl monomer unit and a conjugated diene monomer unit, and a content of the aromatic vinyl monomer unit in the (B2) is 20 to 95% by weight, and a content of the aromatic vinyl monomer unit in the (B) is 35 to 80% by weight.Type: GrantFiled: September 23, 2011Date of Patent: October 21, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshifumi Araki, Takashi Sato, Takahiro Hisasue
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Publication number: 20140296396Abstract: Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety.Type: ApplicationFiled: October 31, 2012Publication date: October 2, 2014Inventors: John Ta-Yuan Lai, Ti Chou
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Publication number: 20140288220Abstract: Disclosed are heat resistant polyamide compositions including a) one or more polyamide resins, b) one or more reinforcing agents, c) a zinc compound; d) a copper heat stabilizer; and optionally, e) a polyhydric alcohol.Type: ApplicationFiled: March 25, 2013Publication date: September 25, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Andrew Jay Duncan, Benjamin Weaver Messmore, Jennifer Leigh Thompson
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Patent number: 8841366Abstract: This disclosure relates to thermoplastic compositions comprising a polycarbonate copolymer, the polycarbonate copolymer comprising first repeating carbonate units and second repeating units selected from carbonate units that are different from the first carbonate units, polysiloxane units, and a combination comprising at least one of the foregoing unit; and an organophosphorus flame retardant in an amount effective to provide 0.1 to 1.0 wt % phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after 4 minutes (Ds-4) of less than or equal to 600 determined according to ISO 5659-2 on a 3 mm thick plaque, and a material heat release of less than or equal to 160 kW/m2 determined according to ISO 5660-1 on a 3 mm thick plaque.Type: GrantFiled: February 28, 2013Date of Patent: September 23, 2014Assignee: Sabic Innovative Plastics IP B.V.Inventors: Mark Adrianus Johannes van der Mee, Robert Dirk van de Grampel, Roland Sebastian Assink, Paul Dean Sybert
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Publication number: 20140275367Abstract: A flame retardant polyamide resin composition includes (A) about 40 to about 60% by weight of a crystalline polyamide resin, (B) about 10 to about 20% by weight of polyphenylene sulfide resin, (C) about 5 to about 15% by weight of flame retardant containing phosphinic acid metal slat compound, (D) about 20 to about 40% by weight of glass fiber and (E) about 0.1 to about 1% by weight of phosphite antioxidant. The flame retardancy polyamide resin composition can have excellent mechanical properties such as impact strength, flexural modulus, flexural strength and/or tensile strength and can exhibit reduced gas blistering on a surface of a specimen thereof.Type: ApplicationFiled: June 10, 2013Publication date: September 18, 2014Inventors: Hyoung Taek Kang, Eun Joo Lee, Sang Hyun Hong, Jong Cheol Lim
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Patent number: 8795557Abstract: Disclosed herein is a flame resistant composition comprising a compatibilized blend of a polyphthalamide and a poly(arylene ether); and a phosphinate, wherein the composition is substantially free of linear aliphatic polyamides.Type: GrantFiled: November 4, 2008Date of Patent: August 5, 2014Assignee: Sabic Innovative Plastics IP B.V.Inventor: Mark Elkovitch
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Patent number: 8791189Abstract: A thermoplastic composition comprises, based on the total weight of the composition: 51-90 wt % polyester, 10-49 wt % ABS impact modifier; 0-20 wt % of multifunctional epoxy compound; 0-40 wt % filler; 0-2 wt % fibrillated fluoropolymer; and more than 0 to 5 wt % of a stabilizer composition. An article blow molded or injection molded from the composition has a multi-axial impact total energy from 30-100 Joules at ?30° C. and a ductility of more than 90%; a permeability of more than 0 and less than or equal to 1.5 g/m2-day to ASTM D 471-98 Fuel C, measured after exposure to ASTM D 471-98 Fuel C vapor for 20 weeks at 40° C.; an MVR of 1-20 cc/10 min., measured at 265° C.; a flexural modulus of greater than 1300 MPa; and retains at least 75% of its initial tensile elongation at break, after exposure to Fuel E85 for 28 days at 70° C.Type: GrantFiled: August 7, 2008Date of Patent: July 29, 2014Assignee: SABIC Innovative Plastics IP B.V.Inventors: Parminder Agarwal, Donald Howard Ellington, Robert Russell Gallucci, Josephus Gerardus M. van Gisbergen, Vishvajit Chandrakant Juikar, Ihab Odeh, Sathish Kumar Ranganathan, Kenneth Frederick Miller, Veeraraghavan Srinivasan
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Patent number: 8779040Abstract: The present invention is directed to a composition comprising: (a) a polyethylene terephthalate; (b) a copolycarbonate of 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP) and another bisphenol; (c) a polycarbonate-polysiloxane copolymer; and (d) a non-halogenated flame retardant. The invention is also directed to processes for making such compositions as well as articles derived therefrom.Type: GrantFiled: October 16, 2012Date of Patent: July 15, 2014Assignee: SABIC Global Technologies B.V.Inventors: Chris van der Weele, Johannes Hubertus Gabriel Marie Lohmeijer, Andries J. P. van Zyl
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Publication number: 20140187691Abstract: A flame retardant includes a polymer including a unit represented by Formula 1: wherein A and B are each independently a single bond, C1 to C5 alkylene, C1 to C5 alkylidene, C5 to C6 cycloalkylidene, —S— or —SO2—, provided that A and B are different from each other; R1 and R4 are each independently substituted or unsubstituted C1 to C6 alkyl, substituted or unsubstituted C6 to C20 aryl, or substituted or unsubstituted C6 to C20 aryloxy; R2, R3, R5 and R6 are each independently substituted or unsubstituted C1 to C6 alkyl, substituted or unsubstituted C3 to C6 cycloalkyl, substituted or unsubstituted C6 to C12 aryl, or halogen; a, b, c and d are each independently an integer from 0 to 4; m is an integer from 0 to 500; and n is an integer from 1 to 500. The flame retardant polyamide resin composition can have excellent flame retardancy and can maintain crystallinity.Type: ApplicationFiled: December 12, 2013Publication date: July 3, 2014Applicant: Cheil Industries Inc.Inventors: Seung Woo JANG, Chang Hong KO, Min Soo LEE, Sung Hee AHN
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Patent number: 8765849Abstract: The invention relates to a composition comprising, relative to the total weight of the composition: between 25% and 52% by weight of at least one semi-crystalline or amorphous polyamide, having an amine chain-end content of less than 0.040 meq/g, between 24% and 40% by weight of at least one reinforcer, and between 24% and 35% by weight of at least one metal salt, optionally contained in a polymer, chosen from a metal salt of phosphinic acid, a metal salt of diphosphinic acid, and a mixture thereof. The invention also relates to the process for preparing this composition and its use.Type: GrantFiled: January 27, 2010Date of Patent: July 1, 2014Assignee: Arkema FranceInventors: Philippe Blondel, Eric Gamache, Benjamin Saillard, Barbara Ramfel