Triphenyl Phosphite Per Se Patents (Class 524/153)
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Patent number: 6538056Abstract: What is disclosed are polyolefin compounds, e.g., polyethylene and polypropylene, and articles therefrom made in by conventional solid, melt-phase compounding with oxidized, non-cationized, non-silylated sulfur black pigment, a phenolic antioxidant and a sulfur-containing secondary stabilizer, each in stabilizing amount, specified below, which provide a synergistic improvement in the long term heat aging of polyolefins. Preferably the sulfur black compound is treated by washing, and reduction in the soluble sodium salts. Also disclosed is melt-phase compounded polyolefin and molded articles made therefrom comprising incorporating of carbon black, oxidized, non-cationized, non-silylated sulfur black pigment, a phenolic antioxidant and sulfur-containing secondary stabilizer.Type: GrantFiled: October 10, 2000Date of Patent: March 25, 2003Assignee: Clariant International Ltd.Inventor: Joseph R. Webster
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Patent number: 6531530Abstract: The present invention provides a flame retardant resin composition having excellent impact resistance, heat resistance, dimensional stability, and flame retardance. That is, it provides a flame retardant resin composition made up of: 100 parts by weight of a thermoplastic resin (A) containing: 80 to 10% by weight of (A-1) at least one of an aromatic polyester resin and a polyamide resin, 17 to 85% by weight of at least one of a rubber-containing copolymer of a vinyl cyanide and an aromatic vinyl (A-2) and a copolymer of a vinyl cyanide and an aromatic vinyl (A-3) and 3 to 40% by weight of (A-4) at least one of a polyphenylene ether resin and a polyphenylene sulfide resin, 1 to 60 parts by weight of a non-halogen, organic or inorganic flame retardant (B) and 100 parts by weight or less of a filler (C).Type: GrantFiled: December 21, 2000Date of Patent: March 11, 2003Assignee: Daicel Chemical Industries, Ltd.Inventor: Takayuki Asano
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Patent number: 6528595Abstract: A composition useful as a sealant, coating, a potting agent for a printed circuit board, a prepreg or an adhesive comprises a compound (A) wherein all or a part of the oxirane rings in an epoxy compound is replaced with thiirane rings represented by the following formula (1): or compound (A) and compound (B) which contains oxirane rings and no thiirane ring in the molecule, wherein the ratio of oxirane ring/thiirane ring is from 90/10 to 10/90.Type: GrantFiled: October 6, 2000Date of Patent: March 4, 2003Assignee: The Yokohama Rubber Co., Ltd.Inventors: Masahiro Ikawa, Hiroyuki Okuhira, Keisuke Chino
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Patent number: 6518344Abstract: The present invention provides a new and improved flame retarded polyolefin composition that displays good retained physical properties upon aging. The composition also exhibits excellent moldability and it may be easily colored. In a preferred embodiment the composition includes a polyolefin, a halogen-containing flame retardant additive, from at least about 1.00% by weight to about 2.5% by weight of a stabilizer package, and from about 0% to about 1.0% by weight of an acid/halogen scavenger. The stabilizer package includes by weight from about 20% to about 80% of a hindered phenolic antioxidant, from about 20% to about 80% of a phosphite containing antioxidant, and from about 0% to about 40% of a thio-ester antioxidant. In addition to displaying excellent color and physical property development and retention characteristics, the composition of the present invention displays an improved UL94 vertical burn rating.Type: GrantFiled: August 18, 2000Date of Patent: February 11, 2003Assignee: Ferro CorporationInventors: Deenadayalu Chundury, Ann Mendel, Howard E. Munro, Roy C. Sanford
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Patent number: 6512032Abstract: A vinylidene fluoride resin composition which is stable to heat at molding temperatures and is free from foaming and coloration, and molded products made by forming the vinylidene fluoride resin composition are provided. The vinylidene fluoride resin composition of the present invention comprises 100 parts by weight of a vinylidene fluoride resin, 2-20 parts by weight of a polyester plasticizer, 0.01-0.5 parts by weight of a phosphite compound. The vinylidene fluoride resin composition may further comprises a phenol compound.Type: GrantFiled: February 28, 2000Date of Patent: January 28, 2003Assignee: Kureha Chemical Industry Co., Ltd.Inventors: Seiichi Ohira, Kazuyuki Munakata, Toshiya Mizuno, Nobuyuki Masumura
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Patent number: 6489384Abstract: A composition comprises a polyacrylate for processing from the melt and a stabilizer having at least one phosphite group.Type: GrantFiled: February 5, 2001Date of Patent: December 3, 2002Assignee: BASF AktiengesellschaftInventors: Ralf Fink, Karl-Heinz Schumacher
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Patent number: 6465548Abstract: The present invention relates to a stabilizer composition for organic polymer material containing (a) 6-hydroxychroman compound, a phosphorus antioxidant and (c) phenolic antioxidant, wherein the component (a) is contained in a proportion of 0.5 wt %-10 wt % and the total amount of the component (b) and the component (c) is in a proportion of 99.5 wt %-90 wt %, of the total amount of the components (a), (b) and (c). The present invention also relates to an organic polymer material composition containing an organic polymer and the above-mentioned stabilizer composition for organic polymer material. The use of the stabilizer composition of the present invention as a stabilizer for organic polymer materials affords an industrially extremely useful stabilized organic polymer material composition superior in heat stability during processing.Type: GrantFiled: April 14, 2000Date of Patent: October 15, 2002Assignee: Yoshitomi Fine Chemicals, Ltd.Inventors: Takeshi Inoue, Shoichi Horie
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Patent number: 6441071Abstract: Improved polycarbonate resins are prepared comprising specific amounts of a cyanacrylic acid ester type UV absorber in combination with a synergistic phosphite type stabilizer and, optionally, a hindered phenol type stabilizer and/or a lactone type stabilizer. The polycarbonate compositions according to the invention can be used to prepare molded, shaped or otherwise fabricated articles having improved combinations of protection against UV radiation, color and color stability with reduced plate-out behavior during processing. The compositions are especially suitable for use in extrusion, blow molding, thermoforming, injection molding, injection blow molding, injection compression molding, film blow molding and foaming processes and provide improved parts or articles.Type: GrantFiled: August 8, 2000Date of Patent: August 27, 2002Assignee: Dow Global Technologies Inc.Inventor: Claude T. E. Van Nuffel
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Patent number: 6420462Abstract: A new process is described for the preparation of a compound of the formula I wherein R1, R2, R3 and R4, independently of each other, are C1-C8alkyl or C1-C5hydroxyalkyl, or R1 and R2 together with the carbon atom they are attached to are C5-C12cycloalkyl or R3 and R4 together with the carbon atom they are attached to are C5-C12cycloalkyl; R5, R6, R7, R8 and R9, independently of each other, are H, C1-C8alkyl, C2-C8alkenyl, C5-C12aryl, C1-C4haloalkyl, an electron withdrawing group, or C1-C12aryl which is substituted by a residue selected from C1-C4alkyl, C1-C4alkoxy, halogen; and R7 and R8 together may also form a chemical bond; and R is an organic linking group containing 2-500 carbon atoms and forming, together with the carbon atoms it is directly connected to and the nitrogen atom, a substituted, 5-, 6 or 7-membered cyclic ring structure; characterized in that a compound of the formula II is oxidized.Type: GrantFiled: June 15, 2000Date of Patent: July 16, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Alessandro Zedda, Gianluca Ferri, Massimiliano Sala
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Patent number: 6420463Abstract: Hindered amines substituted on the N-atom with an -O-E-OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal -O-E moieties.Type: GrantFiled: February 21, 2001Date of Patent: July 16, 2002Assignee: Ciba Specialty Chemicals Corp.Inventors: James P. Galbo, Gerald A. Capocci, Nancy N. Cliff, Robert E. Detlefsen, Michael P. DiFazio, Ramanathan Ravichandran, Peter Solera
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Patent number: 6403681Abstract: Hindered amines substituted on the N-atom with an —O—E—OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal —O—E moieties.Type: GrantFiled: February 21, 2001Date of Patent: June 11, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: James P. Galbo, Gerald A. Capocci, Nancy N. Cliff, Robert E. Detlefsen, Michael P. DiFazio, Ramanathan Ravichandran, Peter Solera
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Patent number: 6391949Abstract: Hindered amines substituted on the N-atom with an —O—E—OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal —O—E moieties.Type: GrantFiled: February 22, 2001Date of Patent: May 21, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: James P. Galbo, Gerald A. Capocci, Nancy N. Cliff, Robert E. Detlefsen, Michael P. DiFazio, Ramanathan Ravichandran, Peter Solera
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Patent number: 6376584Abstract: Hindered amines substituted on the N-atom with an hydroxy-substituted alkoxy moiety are particularly effective in stabilizing organic polymer compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not otherwise attainable.Type: GrantFiled: February 27, 2001Date of Patent: April 23, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: James Peter Galbo, Gerald A. Capocci, Nancy N. Cliff, Robert E. Detlefsen, Michael P. DiFazio, Ramanathan Ravichandran, Peter Solera, Christophe Bulliard
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Patent number: 6362261Abstract: A method of preparing a modified cationic layer compound which includes providing a layer compound of the general formula (I): [EeZzDdVv(OH−)x](An−)a.qH2O (I) wherein E represents one or more monovalent alkali metal cations, e represents a number of from 0 to about 2, Z represents one or more divalent metal cations, z represents a number of from 0 to about 6, D represents one or more trivalent metal cations, d represents a number of from 0 to about 3, V represents one or more tetravalent metal cations, v represents a number of from 0 to about 1, (An−) represents an acid anion wherein n represents an integer of from 1 to 3, q represents a number of from about 1 to about 10, and wherein x>a and e+2z+3d+4v=x+na; subjecting the layer compound to crystallization to provide a resultant material; and subjecting the resultant material to steam drying at a temperature of from about 200° C. to about 260° C.Type: GrantFiled: October 2, 2000Date of Patent: March 26, 2002Assignee: Cognis Deutschland GmbHInventors: Ilona Lange, Joerg-Dieter Klamann, Peter Daute, Juergen Foell, Peter Wedl, Stefan Kuepper
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Patent number: 6362258Abstract: A thermoplastic polymer composition includes a polyolefin polymer, silica; a phosphorus-containing antioxidant compound; and a co-additive that includes one or more of (i) a polyalkylene glycol having a number average molecular weight of greater than or equal to 3,000, (ii) a polyalkylene oxide, (iii) a sterically hindered amine compound.Type: GrantFiled: December 29, 1995Date of Patent: March 26, 2002Assignee: General Electric CompanyInventors: Roger W. Avakian, Henry C. Ashton
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Patent number: 6342549Abstract: Cycloolefin resin pellets of the present invention comprises a cycloolefin resin pellet and a powdery coating material and/or a liquid coating material, the melting point or the glass transition point of the coating material being 200° C. or lower, and the coating material being adhered onto the surface of the cycloolefin resin pellets, so that the molded product thereof is excellent in transparency.Type: GrantFiled: January 5, 1996Date of Patent: January 29, 2002Assignees: Mitsui Chemicals, Inc., Ticona GmbHInventors: Toshiyuki Hirose, Yohzoh Yamamoto, Toshio Kimura, Shinji Osato
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Patent number: 6284822Abstract: Disclosed is a film or sheet of a polypropylene resin composition comprising the following components (A), (B) and (C): (A) 100 parts by weight of a polypropylene resin, (B) from 0.001 to 1 part by weight of a phenolic antioxidant such as 1,3,5-tris(4-t-butyl-3-hydroxy-2,6-dimethylbenzyl)isocyanurate or the like, and (C) from 0.05 to 5 parts by weight of a hindered amine-based light stabilizer. Provided are filmy or sheet moldings of the polypropylene resin composition which color little even when stored indoors at relatively high temperatures; and also the polypropylene resin composition for the moldings.Type: GrantFiled: April 23, 1999Date of Patent: September 4, 2001Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Satoshi Tamura, Yutaka Azuma
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Patent number: 6277905Abstract: This invention relates to a process for improving the toughness of a polymer composition comprising blending: (A) a polyester comprising: (1) terephthalic acid in the amount of 85 to 100 mole % based on the mole percentages of the dicarboxylic acid component equaling a total of 100 mole %. (2) a glycol component comprising from about 60 to 100 mole % 1,4-cyclohexanedimethanol based on the total percentages of the glycol component equaling a total of 100 mole %; (B) one or more rubber impact modifiers; (C) one or more halogenated organic compounds containing at least one imide group having a melting point of greater than 240° C.; and (D) reinforcing fiber.Type: GrantFiled: November 30, 1999Date of Patent: August 21, 2001Assignee: Eastman Chemical CompanyInventor: Gerald Timothy Keep
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Patent number: 6225385Abstract: The present invention relates to a stabilizer mixture prepared by partially condensing PCl3 with 2,2′-dimethyl-4,4′-dihydroxy-5,5′-di-tert-butyldiphenyl sulfide, where the phosphorus content is from 2 to 4% by weight and the content of 2,2′-dimethyl-4,4′-dihydroxy-5,5′-di-tert-butyldiphenyl sulfide is from 0.5 to 50% by weight. The stabilizer mixture has very good solubility in organic solvents and in the polymer and has very good stabilizing action.Type: GrantFiled: March 19, 1999Date of Patent: May 1, 2001Assignee: Clariant GmbHInventors: Thomas Stährfeldt, Alexander Lichtblau, Gerhard Pfahler, Karl Gaa
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Patent number: 6221494Abstract: The invention is directed to a two-pack solvent-based ambient curable coating composition comprising a binder of a hydroxyl and crosslinking components. The hydroxyl component includes a linear or branched cycloaliphatic moiety-containing reactive oligomer or blend of oligomers with a weight average molecular weight not exceeding 3,000, a polydispersity not exceeding about 1.7 with at least 2 hydroxyl groups, at least 1, on average, being a primary hydroxyl group. The reactive oligomer is formed by the reaction of an oligomeric acid with monofunctional epoxy. The crosslinking component includes one or more of an oligomeric crosslinker containing at least 2 isocyanate groups. The coating composition of the invention is particularly suited in automotive refinish coatings.Type: GrantFiled: March 18, 1999Date of Patent: April 24, 2001Assignee: E.I. du Pont de Nemours and CompanyInventors: Robert J. Barsotti, Patrick Henry Corcoran, Gary Delmar Jaycox, Laura Ann Lewin
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Patent number: 6136902Abstract: To provide a polyacetal resin composition having an excellent corrosion inhibiting effect on metals, particularly reduced in the adverse effect on magnetic tapes or the like, and suitable for use in producing component parts of a magnetic tape cassette such as a reel hub or tape guide, 100 parts by weight of a polyacetal resin (A) is blended with 0.05 to 5 parts by weight of an antioxidant (B), 0.001 to 5 parts by weight of a specified nitrogen-containing compound (C), and 0.001 to 3 parts by weight of a boric acid compound.Type: GrantFiled: June 18, 1997Date of Patent: October 24, 2000Assignee: Polyplastics Co., Ltd.Inventors: Yoshihito Fukasawa, Sachio Anada
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Patent number: 6107375Abstract: A thermoplastic composition featuring an improved resistance to hydrolysis is disclosed. The composition comprises (i) thermoplastic polycarbonate resin (ii) about 0.01 to 3 percent of a compound selected from the group consisting of phosphite and phosphonite and (iii) an additive amount of an oligomer or polymer the structure of which features at least one pendant cyclic iminoether group per molecular chain. The additive amount is that which is sufficient to improve the resistance of the polycarbonate resin to hydrolysis.Type: GrantFiled: October 8, 1998Date of Patent: August 22, 2000Assignee: Bayer CorporationInventors: Sivaram Krishnan, James B. Johnson, Donald K. Booher
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Patent number: 6107377Abstract: A propylene resin composition containing a phenolic antioxidant, and a phosphorus-containing antioxidant which has a differential melt index (.DELTA.MI) calculated from a melt index (MIi) as measured at a propylene temperature of 230.degree. C. and under a load of 2,160 g and a melt index (MIe) as measured at a propylene temperature of 230.degree. C. and under a load of 2,160 g after five repetitions of a 100% recycle test is not greater than 0.5 g/10 min, and MIe is not greater than 1.2 g/10 min. This propylene resin composition enables manufacture of large-sized blow-molded articles featuring light weight, excellent rigidity, dimensional stability, heat resistance and showing good drawdown resistance, suitable for continuous blow molding. Blow moldings are advantageously used as automobile bumpers, bumper beams, or like parts.Type: GrantFiled: September 17, 1998Date of Patent: August 22, 2000Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Tetsuya Nakamura, Masaya Tsubokawa
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Patent number: 6107376Abstract: An acrylic rubber composition which forms a phosphorous inert coating on the surface of a metal member when in contact with the metal member under high temperature contains the acrylic rubber, a phosphite-based material and an acid acceptor which reacts with an acid substance in the composition. The acrylic rubber composition particularly exhibits its effect when used as a sealing member 10 for an oil filter 1 which filters engine oil. In such cases, the content of the phosphite-based material is preferably 8-20 parts by weight and that of the acid acceptor is preferably 1-10 parts by weight to 100 parts by weight of the acrylic rubber.Type: GrantFiled: November 4, 1996Date of Patent: August 22, 2000Assignee: Denso CorporationInventors: Norio Tanaka, Tokuhide Aoyama
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Patent number: 6103796Abstract: A homogeneous blended additive useful as a processing stabilizer for polymers which is a blend of Component (a), a defined phosphite or phosphonite; and Component (b) which is micronized zinc oxide. Component (b) is preferably in an amount of 5 to 10% based on the weight of component (a). This additive composition improves the resistance of phosphites and phosphonites against hydrolysis in the presence of moisture, by providing Component (b) as a hydrolysis stabilizer for Component (a).Type: GrantFiled: October 3, 1997Date of Patent: August 15, 2000Assignee: Clariant Finance (BVI) LimitedInventors: Peter Staniek, Klaus Stoll, Rainer Wolf
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Patent number: 6093757Abstract: A composition and method for encapsulating a photovoltaic device which minimizes discoloration of the encapsulant. The composition includes an ethylene-vinyl acetate encapsulant, a curing agent, an optional ultraviolet light stabilizer, and/or an optional antioxidant. The curing agent is preferably 1,1-di-(t-butylperoxy)-3,3,5-trimethylcyclohexane; the ultraviolet light stabilizer is bis-(N-octyloxy-tetramethyl) piperidinyl sebacate and the antioxidant is selected from the group consisting of tris (2,4-di-tert-butylphenyl) phosphite, tetrakis methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, and 2,2'-ethylidene bis(4,6-di-t-butylphenyl) fluorophosponite. The composition is applied to a solar cell then cured. The cured product contains a minimal concentration of curing-generated chromophores and resists UV-induced degradation.Type: GrantFiled: November 24, 1997Date of Patent: July 25, 2000Assignee: Midwest Research InstituteInventor: Fu-Jann Pern
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Patent number: 6077890Abstract: A stabilizer formulation particularly well suited for improving the properties of thermoplastic polymers is disclosed. The stabilizer formulation contains a combination of stabilizers that improves the process stability of a polymer, prevents the polymer from yellowing, increases the thermal aging stability of the polymer and inhibits the polymer from generating smoke during melt processing. Of particular advantage, the stabilizer formulation improves the stability of a polymer without significantly adversely affecting any other properties of the polymer. In one embodiment, the stabilizer formulation includes a hindered amine, a hydroxyl amine, and one or more hydrolytically resistant phosphites. In one embodiment, the formulation can further contain an acid scavenger for preventing an acid contained within the polymer or produced during processing from harming the polymer.Type: GrantFiled: December 4, 1997Date of Patent: June 20, 2000Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Robert L. Hudson, Mary Lou Delucia
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Patent number: 6043332Abstract: The present invention relates to a process for the production of polyisocyanates containing uretdione groups bya) oligomerizing a portion of the isocyanate groups of diisocyanates having aliphatically and/or cycloaliphatically bound isocyanate groups in the presence of catalysts or catalyst systems which accelerate the dimerization of isocyanate groups and in the presence of trisubstituted phosphite stabilizers corresponding to formula (I) ##STR1## b) optionally termination of the oligomerization reaction at a degree of oligomerization of 10 to 60% by adding a catalyst poison andc) optionally removing unreacted diisocyanate by extraction or thin-layer distillation.The present invention also relates to the use of the resulting uretdione polyisocyanates as a starting component for polyurethane plastics, particularly as an isocyanate component for the production of uretdione hardeners for powder coating compositions.Type: GrantFiled: August 5, 1998Date of Patent: March 28, 2000Assignee: Bayer AktiengesellschaftInventors: Hans-Josef Laas, Reinhard Halpaap, Hans-Ulrich Meier-Westhues, Ulrich Freudenberg
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Patent number: 6022914Abstract: The present invention relates to a pressure-sensitive adhesive composition containing a non-halogen, non-intumescent flame-retardant system comprising at least one flame-retardant agent with the provisos that the flame-retardant system does not comprise Sb.sub.2 O.sub.3 or does not consist only of alumina trihydrate.Type: GrantFiled: November 27, 1995Date of Patent: February 8, 2000Assignee: 3M Innovative Properties CompanyInventors: Petra Nowak, Robert D. Waid, William D. Coggio
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Patent number: 6010760Abstract: A thermoplastic resin composition comprising a thermoplastic resin (A) not forming an anisotropic melt phase and a liquid crystal polymer (B) capable of forming an anisotropic melt phase, an injection molding method thereof and an injection molded article capable of providing a thin molded article having excellent mechanical strength. A thermoplastic resin composition (C) comprises 99 to 50 wt. % of the thermoplastic resin (A) and 1 to 50 wt. % of the liquid crystal polymer (B). The liquid crystal polymer (B) is microscopically dispersed in an island form in the matrix phase of the thermoplastic resin (A) so that when the composition (C) is heat-treated at a temperature not lower than the melting point of the liquid crystal polymer (B) under a non-load state and is then cooled, the liquid crystal polymer (B) has a weight average particle diameter within the range of 10 to 40 micrometers and at least 80 wt. % thereof has a particle diameter within the range of 0.5 to 60 micrometers.Type: GrantFiled: June 17, 1997Date of Patent: January 4, 2000Assignee: Polyplastics Co., Ltd.Inventors: Hirotaka Miyazaki, Tomoyuki Aketa, Haruji Murakami, Takayuki Ishikawa, Kazuhito Kobayashi, Ayako Migita
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Patent number: 6004678Abstract: A polycarbonate composition comprising a polycarbonate, a substituted aryl phosphite and a substituted triazine is extruded as a cap layer with sudstantially no fuming or plate out and is additionally useful in profile or molded products.Type: GrantFiled: August 16, 1996Date of Patent: December 21, 1999Assignee: General Electric CompanyInventors: Marja Jaatinen, Douglas Meldrum
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Patent number: 5942556Abstract: Disclosed is a radiation curable composition which includes: (a) an unsaturated ester compound, and (b) a pulverizable vinyl ether compound. The unsaturated ester compound is characterized as having a plurality of unsaturated ester groups per molecule. The pulverizable vinyl ether compound is characterized as including at least one of the following: (a) a compound having an average of greater than 1.0 reactive vinyl ether groups per molecule, and (b) a vinyl ether-containing group bonded to the unsaturated ester compound such that there is an average of at least 1.0 reactive vinyl ether group per molecule. The unsaturated ester compound, the vinyl ether compound and/or a mixture thereof is treated with a reducing agent so as to decompose destabilizing agents present therein that would initiate premature polymerization of the vinyl ether compound.Type: GrantFiled: November 27, 1996Date of Patent: August 24, 1999Assignee: PPG Industries Ohio, Inc.Inventors: Charles B. Friedlander, Ronald R. Ambrose, David A. Diehl, Alan B. Weissberg, Carolyn A. Novak
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Patent number: 5929148Abstract: The present invention provides polyhexamethylene adipamide fibers significantly excellent in thermal yellowing resistance, and a process for producing the same. The improved polyhexamethylene adipamide fibers have adaptability to fibers for clothing which adaptability is comparable to that of poly-.epsilon.-capramide fibers and polyester fibers. The improved polyhexamethylene adipamide fibers can be obtained by either (1) melt spinning a polyhexamethylene adipamide simultaneously containing 2,4-bis(alkylthio)-6-(3,5 -dialkyl-4-hydroxyanilino)-1,3,5-triazine and a compound selected from the group consisting of phosphorous acid, hypophosphorous acid and derivatives of these acids, or (2) melt spinning the fibers having the sum of an amino end group concentration (?--NH.sub.2)!) and a carboxyl end group concentration (?--COOH!) of 70 to 200 meq/kg, satisfying the condition: ?--COOH!.ltoreq.60 meq/kg, and containing from 0.005 to 0.Type: GrantFiled: November 25, 1996Date of Patent: July 27, 1999Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Katsuya Shimizu, Hiroshi Tomiyama
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Patent number: 5929133Abstract: Anti-bacterial film according to the present invention is suitable for use as food packaging wrap, and is given with the properties required for such film, such as a clinging property, transparency, and an anti-fogging property, as well as a high anti-bacterial property. The anti-bacterial film according to the present invention comprises, for 100 weight parts of PVC resin, 5 to 50 weight parts of a plasticizer, 0.3 to 3.0 weight parts of a stabilizer, 0.02 to 1.0 weight parts of hydrotalcite, 0.5 to 5.0 weight parts of an anti-fogging agent, and 0.02 to 2.0 weight parts of an anti-bacterial compound. The anti-bacterial compound may consist of a compound obtained by ion exchanging metallic ions of inorganic oxo-acid salt in the form of irregular particles having a particle diameter no more than 0.5 .mu.Type: GrantFiled: July 21, 1997Date of Patent: July 27, 1999Assignee: Hitachi Chemical Filtec, Inc.Inventors: Takayoshi Watanabe, Satoru Aoki, Shinichi Ohta, Katsuhiro Shirono, Atsushi Tanaka
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Patent number: 5919849Abstract: The invention relates to improved polyacetal compositions composed of polyoxymethylene (component A) and a stabilized MBS core shell graft copolymer (component B) formed from a rubber-elastic core based on polybutadiene, and a hard graft shell.The stabilized MBS core shell graft copolymer (component B) contains a special stabilization formulation of at least one hindered phenol, a phosphite, a sulfide, and a pH buffer system.The shaped articles produced from these mixtures are particularly distinguished by an excellent low-temperature impact strength and a good heat aging performance.Type: GrantFiled: September 9, 1996Date of Patent: July 6, 1999Assignees: Rohm and Haas Company, Hoechst AktiengesellschaftInventors: Nazir Ahmed Memon, Richard Henry Weese, Ursula Elisabeth Ziegler
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Patent number: 5912289Abstract: Disclosed is a thermally stable aromatic polycarbonate composition comprising an aromatic polycarbonate, which is substantially free of a chlorine-containing compound, and a thermal stabilizer, the aromatic polycarbonate comprising a plurality of aromatic polycarbonate chains, each comprising recurring aromatic carbonate units and having a terminal aryl carbonate group and a terminal hydroxyl group, wherein each recurring unit has a divalent aromatic or pyridylene group comprising one or more divalent constituent aromatic or pyridylene groups, and wherein the plurality of aromatic polycarbonate chains collectively contain at least one constituent aromatic or pyridylene group substituted with at least one methyl group in an amount of 0.0001 or less in terms of the molar ratio of the methyl group substituted constituent group or groups relative to all constituent groups in the aromatic polycarbonate chains.Type: GrantFiled: January 24, 1997Date of Patent: June 15, 1999Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kyosuke Komiya, Hiroshi Hachiya
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Patent number: 5897959Abstract: A biaxially extended polyester film which comprises a polyester resin having ethylene A biaxially oriented polyester film comprises a polyester resin having ethylene terephthalate and ethylene isophthalate repeating units in a weight ratio of 90:10 to 75:25; 0.02 to 0.06 weight % of an organic phosphite or phosphate ester; and 0.01 to 0.05 weight % of a hindered phenol compound, wherein the film possesses good thermal stability, processability, and thermal adhesive strength to a metal surface and is useful in forming the inner laminate layer of a metal container.Type: GrantFiled: November 20, 1996Date of Patent: April 27, 1999Assignee: SKC LimitedInventors: Sang-Il Kim, Byoung-Ho Cho
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Patent number: 5880189Abstract: Disclosed is a stabilizer composition effective to protect PVC resin against heat-mediated deterioration, comprising a mixture of barium and zinc salts of aliphatic C.sub.6 -C.sub.20 carboxylates and aromatic C.sub.7 -C.sub.12 carboxylates, organic triphosphites of the formula R.sub.1 OP(OR.sub.3)OR.sub.2 wherein each of R.sub.1, R.sub.2 and R.sub.3 is C.sub.6 -C.sub.12 alkyl or phenyl, and organic acid phosphites of the formula R.sub.4 OP(OH)OR.sub.5 wherein each of R.sub.4 and R.sub.5 is C.sub.6 -C.sub.12 alkyl or phenyl, or R.sub.4 can be hydrogen. PVC film compounded with this stabilizer composition also exhibits improved wettability and adherence to water-based inks applied to such films.Type: GrantFiled: May 2, 1997Date of Patent: March 9, 1999Assignee: Witco CorporationInventors: Michael A. Croce, Kook Jin Bae, Otto Loeffler
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Patent number: 5859102Abstract: Plastic mixtures, in particular recycled plastic mixtures, comprising predominantly polyolefins and 0.05-20% by weight of PVDC can be stabilized against thermo-oxidative degradation by addition of a combination of an organic phosphite or phosphonite and a metal salt of a fatty acid.Type: GrantFiled: June 20, 1996Date of Patent: January 12, 1999Assignee: Ciba Speciality Chemicals CorporationInventors: Rudolf Pfaendner, Heinz Herbst, Kurt Hoffmann
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Patent number: 5844026Abstract: A mixture of the compounds identified in the title, their pure isomers and alkane-bridged derivatives are particularly effective in stabilizing polymer compositions, particularly polyolefin compositions.Type: GrantFiled: June 30, 1997Date of Patent: December 1, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: James P. Galbo, Henry C. Grace, Douglas W. Horsey, Peter Solera, Rangarajan Srinivasan
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Patent number: 5837759Abstract: The stabilizer mixture comprises(a) one or more chroman derivatives of the formula I ##STR1## where R.sup.1 is ##STR2## in which Z is C.sub.7 - to C.sub.30 -alkyl, --CH.sub.2 CH.sub.2 --S--(C.sub.1 - to C.sub.30 -alkyl) or ##STR3## and (b) an inert organic solvent for the chroman derivatives I from the group consisting of aliphatic, cycloaliphatic or aromatic hydrocarbons or halogenated hydrocarbons, silicone oils and vegetable and animal fats,where components (a) and (b) are in a weight ratio of from 99:1 to 1:99.Type: GrantFiled: July 16, 1997Date of Patent: November 17, 1998Assignee: BASF AktiengesellschaftInventors: Hubert Trauth, Jurgen Krockenberger, Ekkehard Jahns, Ralf Biastoch
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Patent number: 5804623Abstract: Recycled plastics, predominandy thermoplastics, from domestic, commercial and industrial waste can be stabilized against thermooxidative degradation by adding a combination of a sterically hindered phenol with an organic phosphite or phosphonite and a metal salt of a fatty acid.Type: GrantFiled: November 25, 1996Date of Patent: September 8, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Kurt Hoffmann, Heinz Herbst, Rudolf Pfaendner, Hans-Jurgen Sander, Franciszek Sitek
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Patent number: 5770644Abstract: A fire retardant polyester resin composition comprising (A) 95 to 30 parts by weight of a polyester resin and (B) 5.0 to 70 parts by weight of a polyphenylene ether resin and/or polyphenylene sulfide resin, and, for 100 parts by weight in total of the components (A) and (B), (C) 0.05 to 10 parts by weight of a compatibilizing agent, (D) 2.0 to 45 parts by weight of a phosphoric ester compound or phosphonitrile compound, (E) 0 to 150 parts by weight of a reinforcing filler, (F) 0.001 to 15 parts by weight of an anti-dripping agent, (G) 0 to 45 parts by weight of a melamine cyanurate, and (H) 0 to 15 parts by weight of a polystyrene resin having epoxy group, provided that the amount of the component (G) is from 0.5 to 45 parts by weight for 100 parts by weight in total of the components (A) and (B) when the amount of the component (B) is less than 35 parts by weight. The polyester resin composition scarcely corrodes a metal mold when it is molded, and is excellent in fire retardancy.Type: GrantFiled: February 26, 1997Date of Patent: June 23, 1998Assignee: Mitsubishi Engineering Plastics CorporationInventors: Masanori Yamamoto, Shintarou Kishimoto
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Patent number: 5744526Abstract: An aromatic polycarbonate composition having improved color stability and improved hydrolytic stability, while maintaining good processing properties, which composition consists of an aromatic polycarbonate and a stabilizer system consisting of at least one organic phosphorous containing additive and hexamethylene tetra amine.Type: GrantFiled: May 14, 1997Date of Patent: April 28, 1998Assignee: General Electric CompanyInventors: Johanes M.D. Goossens, Theodours L. Hoeks
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Patent number: 5717014Abstract: A polyphenylene ether resin composition containing the following Components (A) to (D) according at the following formulation ratio.(A) 50 to 99.5 parts by weight of a polyphenylene ether(B) 0.5 to 50 parts by weight of a partially hydrogenated aromatic alkenyl compound-conjugated diene block copolymer having a hydroxy group and based on 100 parts by weight of the above resin composition,(C) 0 to 950 parts by weight of a thermoplastic resin and(D) 0 to 10 parts by weight of a phosphorous acid triester.Type: GrantFiled: November 25, 1996Date of Patent: February 10, 1998Assignee: Mitsubishi Chemical CorporationInventors: Ichiro Ohkawachi, Kiyoji Takagi, Koji Nishida
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Patent number: 5714531Abstract: A propylene resin extruded article comprising 100 parts by weight of a propylene resin, 0.03 to 2 parts by weight of a metal salt of a rosin compound, 0.01 to 1 part by weight of a tertiary amine light stabilizer, and 0.01 to 0.5 part by weight of an aromatic phosphite and/or phosphonite antioxidant, and a propylene resin extruded article further comprising 0.01 to 0.5 part by weight of an antistatic agent in addition to the above components. The resin compound comprising the above components does not contaminate extrusion equipment, and the extruded articles are excellent in transparency, hue, thermal aging resistance and, when the antistatic agent is used, are excellent in antistatic property.Type: GrantFiled: January 21, 1997Date of Patent: February 3, 1998Assignee: Japan Polychem CorporationInventors: Kazumasa Fujimura, Hitoshi Inagaki
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Patent number: 5695869Abstract: Melt-blown microfiber webs are prepared from polyarylene sulfide polymers, particularly polyphenylene sulfide. A small amount of a phosphite or phosphonite compound is added to the extruder feedstock. The additive essentially eliminates spurious polymer particle formation at the extruder die openings, even over sustained production periods. The polyarylene sulfide microfiber webs so produced are thus essentially free of spurious particulates, and the web defects which may be caused by such particulates.Type: GrantFiled: August 21, 1995Date of Patent: December 9, 1997Assignee: Hoechst Celanese CorporationInventors: Andrew Bernard Auerbach, Warren Stephen Harmon
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Patent number: 5674927Abstract: A solid amorphous phosphite stabilizer composition is provided which exhibits enhanced hydrolytic stability. The stabilizer composition preferably contains from 10 to 99.9 percent by weight of a phosphorous compound selected from phosphites and phosphonites, and preferably contains from 0.1 to 10 percent by weight of an aliphatic polyamine. The stabilizer composition exhibits enhanced hydrolytic stability, and is preferably in the form of powders or flakes. The stabilizer composition is useful as an additive to polymeric resins as an antioxidant stabilizer.Type: GrantFiled: November 16, 1995Date of Patent: October 7, 1997Assignee: General Electric Co.Inventor: James A. Mahood
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Patent number: 5599860Abstract: The invention relates to improved polyacetal compositions composed of polyoxymethylene (component A) and a stabilized MBS core shell graft copolymer (component B) formed from a rubber-elastic core based on polybutadiene, and a hard graft shell.The stabilized MBS core shell graft copolymer (component B) contains a special stabilization formulation of at least one hindered phenol, a phosphite, a sulfide, and a pH buffer system.The shaped articles produced from these mixtures are particularly distinguished by an excellent low-temperature impact strength and a good heat aging performance.Type: GrantFiled: June 7, 1995Date of Patent: February 4, 1997Inventors: Nazir A. Memon, Richard H. Weese, Ursula E. Ziegler
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Patent number: RE35509Abstract: Compatiblized mixtures of a polyphenylene ether, a polyamide and a compatibilizer are described. The mixtures have improved physical properties as a result of using in the mixtures a polyamide having a terminal amine group to terminal carboxyl group ratio of greater than 1.Type: GrantFiled: July 15, 1994Date of Patent: May 13, 1997Assignee: General Electrical CompanyInventors: Susumi Fujii, Hiromi Ishida, Masataka Morioka, Akihiro Saito, Roelof van der Meer