Sulfur Bonded Directly To Four Oxygen Atoms Patents (Class 524/156)
  • Patent number: 5866625
    Abstract: The density of rigid foamed articles made by the thermal decomposition of a blowing agent in a vinyl chloride polymer is reduced by the use of an organotin halide in combination with a mercaptocarboxylic acid ester or a sulfide of such ester or a mixture of the ester and the sulfide to activate the blowing agent.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: February 2, 1999
    Assignee: Morton International, Inc.
    Inventors: George F. Beekman, Lionel R. Price
  • Patent number: 5863466
    Abstract: Thermoplastic compositions are provided which have electrostatic dissipative properties. The thermoplastic composition is prepared by combining at least the following initial ingredients: (i) a thermoplastic polyurethane, which is prepared by reacting a polyalkylene glycol, a diisocyanate and a chain extender having at least two hydroxyl groups, (ii) a thermoplastic polyester, wherein the polyester is a polylactone, and (iii) a quaternary ammonium compound. The composition may additionally include an organic polymer to which is imbued electrostatic dissipative properties as a result of incorporating the three initial ingredients.
    Type: Grant
    Filed: February 6, 1997
    Date of Patent: January 26, 1999
    Inventor: Ebrahim Mor
  • Patent number: 5840789
    Abstract: The present invention relates to aqueous compositions having pH of less than or equal to about 11 and which contain a thickening amount of an acrylate-based rheology modifier, which modifier contains an emulsion which is prepared by single-stage emulsion polymerization of a C.sub.2 -C.sub.6 alkyl ester of acrylic acid and/or a C.sub.1 -C.sub.6 alkyl ester of methacrylic acid, a monomer chosen from a vinyl-substituted heterocyclic compound containing at least one of a nitrogen or sulfur atom, (meth)acrylamide, a mono- or di-(C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylate, a mono or di-(C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylamide, and optionally cross-linking monomers and/or associative monomers, in the presence of water, a first surfactant, a free-radical initiator and an alcohol selected from C.sub.2 -C.sub.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: November 24, 1998
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Daniel W. Verstrat, Milagros C. Barron
  • Patent number: 5827911
    Abstract: Colored thermoplastic resin composition comprising a transparent thermoplastic resin and a black dye contained therein, wherein said black dye is a black dye obtained by reaction of at least one anionic surfactant selected from the group consisting of(a) sulfuric acid ester-series surfactants,(b) phosphoric acid ester-series surfactants,(c) sulfonic acid-series surfactants and(d) carboxylic acid-series surfactants, and nigrosine.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: October 27, 1998
    Assignee: Orient Chemical Industries, Ltd.
    Inventors: Akihiko Hayashi, Masataka Nishikawa
  • Patent number: 5795942
    Abstract: This invention relates to a process for preparing water soluble conductive polyaniline composite represented by the formula(III) which comprises reacting emeraldine base-type polyaniline(EB) representing by the formula(I) with poly(ethyleneglycol) hydrogen sulfate (PEGSF) represented by the formula(II), and to water soluble conductive polyaniline composite synthesized by the said process ##STR1## wherein, x is an integer or fractional number; y is 0 to 1 ##STR2## wherein, n is 4 to 200. ##STR3## wherein, x and n are same as defined above.
    Type: Grant
    Filed: July 29, 1997
    Date of Patent: August 18, 1998
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Suh Bong Rhee, Chang Jin Lee, Xianhong Wang
  • Patent number: 5786399
    Abstract: The density of rigid foamed articles made by the thermal decomposition of a blowing agent in a vinyl chloride polymer is reduced by the use of an organotin mercaptoalkylcarboxylate, alone, or in combination with an organotin halide or carboxylate which activate the blowing agent. Sulfides made from said organotin mercaptoalkylcarboxylate are also superior activators of the blowing agent.
    Type: Grant
    Filed: September 4, 1997
    Date of Patent: July 28, 1998
    Assignee: Morton International, Inc.
    Inventors: George F. Beekman, Lionel R. Price
  • Patent number: 5783613
    Abstract: The density of rigid foamed articles made by the thermal decomposition of a blowing agent in a vinyl chloride polymer is reduced by the use of an organotin halide in combination with a mercaptocarboxylic acid ester or a sulfide of such ester or a mixture of the ester and the sulfide to activate the blowing agent.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: July 21, 1998
    Assignee: Morton International, Inc.
    Inventors: George F. Beekman, Lionel R. Price
  • Patent number: 5746814
    Abstract: Disclosed is a curl preventing/minimizing fluid composition containing a hydrophilic solvent, a polymeric binder, a water soluble/dispersible paper desizing agent, a water soluble/dispersible paper anticurl agent, a defoamer, a biocide, an antistatic agent, a lightfastness promoting agent, and a filler.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: May 5, 1998
    Assignee: Xerox Corporation
    Inventors: Shadi L. Malhotra, Diane M. Foley
  • Patent number: 5744520
    Abstract: A process for the preparation of polymer compositions which comprises mixing a conductive component with an anionic polymeric latex containing a polymer; adding a cationic surfactant, or flocculant whereby the aggregation of the latex particles and the conductive component particles results; subsequently adding colloidal stabilizer, followed by the addition of a base to obtain a pH of from about 7 to about 12; heating above about the polymer glass transition temperature thereby enabling the severage, or breakage of the formed aggregated particles; further heating above about the polymer glass transition temperature enabling the coalescence of the polymer and conductive component particles; and optionally washing and drying the resulting coalesced product.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: April 28, 1998
    Assignee: Xerox Corporation
    Inventors: Grazyna E. Kmiecik-Lawrynowicz, Richard P. N. Veregin, Raj D. Patel, Michael A. Hopper, Maria V. McDougall
  • Patent number: 5714534
    Abstract: A resin composition having excellent antistatic properties is provided which comprises (A) 100 parts by weight of a styrene resin, (B) 3 to 35 parts by weight of a polyethylene oxide, (C) 0.1 to 10 parts by weight of a styrene-acrylonitrile-hydroxyalkyl acrylate copolymer and/or a styrene-acrylonitrile-hydroxyalkyl methacrylate copolymer, (D) 4 to 100 parts by weight of a (meth)acrylic ester polymer, and/or an oxide selected from the group consisting of titanium oxide, zinc oxide and magnesium oxide, the oxide being present in an amount of 0.7 to 5 parts by weight per 100 parts by weight of the combined amount of components (A) and (B), and (E) a surface-active agent comprising a specified sulfonic acid salt or alkylsulfuric acid salt, the surface-active agent being present in an amount of 0.4 to 5 parts by weight per 100 parts by weight of the combined amount of components (A), (B), (C) and (D). This resin composition can be used for general household articles including, for example, wardrobe cases.
    Type: Grant
    Filed: October 5, 1995
    Date of Patent: February 3, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Nobumoto Kojima, Kouzo Ichikawa, Hideo Amemiya, Shinji Okajima, Takayoshi Sekido, Mitsuyoshi Kato
  • Patent number: 5710188
    Abstract: The density of rigid foamed articles made by the thermal decomposition of a blowing agent in a vinyl chloride polymer is reduced by the use of an organotin halide in combination with a mercaptocarboxylic acid ester or a sulfide of such ester or a mixture of the ester and the sulfide to activate the blowing agent.
    Type: Grant
    Filed: March 19, 1997
    Date of Patent: January 20, 1998
    Assignee: Morton International, Inc.
    Inventors: George F. Beekman, Lionel R. Price
  • Patent number: 5668202
    Abstract: A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfonates group sulfonic acid anhydride group or a sulfate group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: September 16, 1997
    Assignee: Teijin Limited
    Inventors: Masumi Hirata, Wataru Funakoshi, Katsushi Sasaki
  • Patent number: 5648411
    Abstract: Thermoplastic compositions exhibiting enhanced melt stability are provided. The compositions contain a blend of resins and an organosulfate salt. The resin blends are preferably selected from (a) a blend of a polyester resin, such as polybutylene terephthalate, and aromatic polycarbonate resin, and (b) a blend of a low molecular weight polyester resin and a high molecular weight polyester resin. The compositions exhibit enhanced retentions of cystallinity and related properties, during melt processing.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 15, 1997
    Assignee: General Electric Company
    Inventors: Robert Russell Gallucci, Paul Joseph Hans
  • Patent number: 5610212
    Abstract: A means for stabilizing a deproteinized natural rubber latex is disclosed, comprising adding a stabilizer selected from the group consisting of (a) an anionic surfactant, (b) an amphoteric surfactant, (c) a nonionic surfactant, (d) a nonionic or amphoteric oligomer or polymer, and (e) an anionic oligomer or polymer. By adding the stabilizer, the mechanical stability of a deproteinized natural rubber latex can be markedly improved.
    Type: Grant
    Filed: May 13, 1994
    Date of Patent: March 11, 1997
    Assignees: Kao Corporation, Sumitomo Rubber Industries, Ltd.
    Inventors: Yasuyuki Tanaka, Yuichi Hioki, Masaharu Hayashi, Naoya Ichikawa, Toshiaki Sakaki
  • Patent number: 5587411
    Abstract: This invention presents a rubber composition wherein a determined amount of protein is mixed with unvulcanized rubber. Rubber products made of this rubber composition have sufficient strength for practical use and are harmless to human bodies. The rubber composition of the invention not requiring vulcanizing process is advantageous in eliminating the need of large-scale vulcanizing equipment. Combined use of a curing agent and protein will increase modulus higher than using the curing agent alone.
    Type: Grant
    Filed: November 30, 1993
    Date of Patent: December 24, 1996
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Toshiaki Sakaki, Shinichi Nakade
  • Patent number: 5548017
    Abstract: This invention relates to a release coating for pressure sensitive adhesive designed primarily for use on paper and textile substrates. The basic release coating comprises a latex containing polymer material and a release additive. The improvement in the basic release coating comprises the incorporation of a polyamide resin having a softening point of less than 70.degree. C. as a release additive. Preferably, the polyamide resin is a dimer fatty acid reacted with an aliphatic or cycloaliphatic amine.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: August 20, 1996
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Frank V. DiStefano
  • Patent number: 5543448
    Abstract: Blends of polycarbonate and polyester are admixed in compositions with poly(phenylene ether), and/or with a poly(phenylene ether) concentrate containing poly(phenylene ether), polystyrene, a vinyl aromatic copolymer, polyamide, polycarbonate, polyester, poly(alkyl acrylate), and/or poly(alkyl methacrylate).
    Type: Grant
    Filed: January 26, 1995
    Date of Patent: August 6, 1996
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5514772
    Abstract: A method for producing a powdery and granular polymer by two coagulation steps comprising coagulating a latex of the polymer, the latex containing a sulfuric acid ester series and/or sulfonic acid series anionic surface active agents, with an acid to an amount of the polymer of 40 to 80 wt. % at a first coagulation step, and then bringing coagulation to completion with an acid or salt at a second coagulation step. According to the present invention, a powdery and granular polymer having a sharp particle size distribution and a high bulk specific gravity can be obtained.
    Type: Grant
    Filed: February 16, 1994
    Date of Patent: May 7, 1996
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Fumio Suzuki, Haruki Sato, Masaki Sugihara, Wataru Hadano
  • Patent number: 5494952
    Abstract: A process for the production of a stabilized polycarbonate which comprises melt-polycondensing an aromatic dihydroxy compound and a carbonic acid diester in the presence of a polycondensation catalyst and then, after the reaction mixture shows an intrinsic viscosity of at least 0.1, adding at least one stabilizer selected from the group consisting of specific compounds having a sulfanate group and a sulfonic acid anhydride group in an amount of 0.01 to 500 ppm of a polycarbonate to be formed, to form a polycarbonate having a desired intrinsic viscosity.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: February 27, 1996
    Assignee: Teijin Limited
    Inventors: Masumi Hirata, Wataru Funakoshi, Katsushi Sasaki
  • Patent number: 5492950
    Abstract: There is provided a mixture of acrylic emulsion polymers based on 70 to 95 parts by weight of a first polymer containing from about 95 to 97.5% by weight of an alkyl ester of acrylic acid and from about 2.5 to 5% by weight of a mixture of carboxylic acids tackified by a second acrylic emulsion polymer containing 10 to 20% by weight of carboxylic acid or hydroxyethyl methacrylate.
    Type: Grant
    Filed: March 23, 1993
    Date of Patent: February 20, 1996
    Assignee: Avery Dennison Corporation
    Inventors: Ian Brown, Stuart A. Harris
  • Patent number: 5478874
    Abstract: A flame-retardant aromatic polycarbonate resin composition has excellent flame retardancy and high transparency without impairing excellent properties inherent to an aromatic polycarbonate resin, and is free from corroding a molding machine or a processing machine, the flame-retardant resin composition comprising 100 parts by weight of an aromatic polycarbonate resin, 0.01 to 1 part by weight of (a) a perfluoroalkane-sulfonic acid alkali salt and 0.02 to 2 parts by weight of (b) a halogenated triaryl phosphate of the formula [1], ##STR1## wherein each of Ar.sup.1, Ar.sup.2 and Ar.sup.3 is independently an aromatic hydrocarbon, and at least one halogen atom is substituted on ring-forming carbon of each aromatic hydrocarbon group.
    Type: Grant
    Filed: March 3, 1995
    Date of Patent: December 26, 1995
    Assignee: Teijin Chemicals Ltd.
    Inventors: Masahiro Miyouga, Shinichi Souda
  • Patent number: 5426142
    Abstract: The present invention relates to the preparation of aqueous based polymers bearing reactive functional groups. More particularly, this invention relates to waterborne or water dispersed polymers that are equivalent in performance in applications formerly dominated by solvent based polymers.Polymers of the present invention have many uses including adhesives, saturant applications, solutions or dispersions in water or water-cosolvent mixtures, and are most useful as coatings and sealants for wood, glass, metal, concrete and binders for mortars and non-wovens.More specifically, surface coatings produced from polymers of the present invention exhibit improved properties such as: for example, durability, toughness, solvent resistance, dirt pickup resistance, print and block resistance and mar resistance.
    Type: Grant
    Filed: August 25, 1993
    Date of Patent: June 20, 1995
    Assignee: Rohm and Haas Company
    Inventors: William J. Rosano, Frederick J. Schindler
  • Patent number: 5425806
    Abstract: A pourable liquid thickening composition for aqueous systems including latex coatings is described. The composition comprises in specified ratios an associative thickener polymer, water and one or more surfactants. Associate thickener polymers include polyurethanes, polyesters, polyacrylamides, modified hydroxyethyl celluloses, alkali soluble emulsions and other chemicals. Specific surfactants include dialkyl sulfosuccinates, alkyl sulfates, alpha olefin sulfonates and sulfates of ethoxylated alcohols.
    Type: Grant
    Filed: May 12, 1994
    Date of Patent: June 20, 1995
    Assignee: Rheox, Inc.
    Inventors: Joseph G. Doolan, Charles A. Cody
  • Patent number: 5424344
    Abstract: A flame retardant polymer composition comprising at least one polymer selected from the group consisting of a polyamide, polyolefin, polyester, polyacrylic, polystyrene, polyurethane and polycarbonate, a flame retardant effective amount of an additive comprising at least one(a) hexavalent oxygenated sulfur compound and optionally at least one of(b) a char forming agent,(c) a metal compound,(d) a filler or reinforcing agent, and(e) a flow modifier.By excluding halogens and phosphorus beneficial results are achieved without the negative consequences attending their presence.
    Type: Grant
    Filed: January 5, 1994
    Date of Patent: June 13, 1995
    Assignee: E. I. DuPont de Nemours and Company
    Inventor: Menachem Lewin
  • Patent number: 5360851
    Abstract: Aqueous silicone dispersions crosslinkable into elastomeric state on removal of water therefrom under ambient conditions, well adapted, e.g., for the production of elastomeric silicone seals in the construction industry, include an oil-in-water base emulsion (A) of an .alpha.,.omega.-(dihydroxy)polydiorganosiloxane stabilized with at least one anionic or nonionic surface-active agent, or mixture thereof, (B) an aqueous latex of an organic (co)polymer having a particle size ranging from 0.01 to 0.5 .mu.m and a solids content ranging from 20% to 70% by weight, (C) an effective crosslinking amount of at least one crosslinking agent, (D) an effective amount of at least one nonsiliceous filler material, and (E), optionally, a catalytically effective amount of a metal curing catalyst, such aqueous dispersions further having a solids content of at least 40% by weight.
    Type: Grant
    Filed: June 18, 1990
    Date of Patent: November 1, 1994
    Assignee: Rhone-Poulenc Chimie
    Inventors: Michel Feder, Jean-Pierre Jaubert, Jean-Marie Pouchol
  • Patent number: 5324765
    Abstract: A copolymer produced by the copolymerization of a monomer mixture comprising at least 30 weight percent of at least one organic ethylenically unsaturated carboxylic acid, at least 30 weight percent of at least one N-alkyl acrylamide the alkyl group of which contains 8 to 30 carbon atoms in the alkyl chain and 0 to 40 weight percent of at least one hydrophilic unsaturated monomer as well as a corresponding copolymer the carboxylic groups of which are completely or partially salified. The preparation and the use of the copolymer as a thickening agent in compositions having a high amount of a surfactant such as a shampoo are also disclosed.
    Type: Grant
    Filed: May 4, 1993
    Date of Patent: June 28, 1994
    Assignee: L'Oreal
    Inventors: Jean Mondet, Bertrand Lion
  • Patent number: 5296533
    Abstract: A resin composition having improved resistance to discoloration by sunlight comprising (A) a polymer mixture which comprises a polyphenylene ether, a polyamide and optionally a polystyrene and/or an agent to improve the impact resistance, and (B) an inorganic powder whose mean particle size is less than or equql to 5 micrometer, in an amount of more than or equal to 15 parts by weight based on 100 parts by weight of the polyphenylene ether in the polymer mixture (A), which is selected from the group consisting of titanium oxide, mica coated with titanium oxide, barium sulphate, zinc oxide and zinc sulfide.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: March 22, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kenji Nagaoka, Hiroshi Hagimori, Yasurou Suzuki, Takashi Sanada, Etsuji Okumura
  • Patent number: 5277978
    Abstract: The process of producing a stable polymer dispersion by aqueous emulsion polymerization of an ethylenically unsaturated monomer in the presence of a stabilizer selected from a polyester or polyamide containing a sulfate or sulfonate group.
    Type: Grant
    Filed: June 2, 1992
    Date of Patent: January 11, 1994
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Dieter Feustel, Karl-Heinz Stritzke
  • Patent number: 5223340
    Abstract: A stain resistant composition for fibers having polyamide linkages prepared by polymerizing an .alpha.-substituted acrylic acid or ester in the presence of a sulfonated aromatic formaldehyde condensation polymer, or by polymerization of a sulfonated hydroxyaromatic ester of an .alpha.-substituted acrylic acid or acrylic acid, and methods for making and applying the composition.
    Type: Grant
    Filed: July 16, 1991
    Date of Patent: June 29, 1993
    Assignee: Peach State Labs, Inc.
    Inventors: Thomas H. Moss, III, Ralph R. Sargent, Michael S. Williams
  • Patent number: 5221706
    Abstract: An emulsified pressure sensitive adhesive is provided which is based on a polymer containing from about 95 to 97.5% by weight of an alkyl ester of acrylic acid and from about 2.5 to 5% by weight of a mixture of carboxylic acids and a three component anionic surfactant system. The polymer is preferably tackified.
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: June 22, 1993
    Assignee: Avery Dennison Corporation
    Inventors: Ivan S. P. Lee, Paul Keller, Richard J. Norman, Robert S. Dordick, Mary E. Zawadzki
  • Patent number: 5130356
    Abstract: A novel, optically transparent, isotropic molding for optical purposes which is free of orientation birefringence consists of a mixture of polyphenylene ethers, vinylaromatic polymers and additives. The novel molding contains traces of novel diphenoquinone and/or diphenohydroquinone derivatives as additives and may also contain novel ammonium salts of sulfuric acid half esters of diphenohydroquinones as further additives. The novel molding has a yellowness index (YI) of from 40 to 90. It can be produced in a simple manner by injection molding processes. The novel molding in the form of a circular disk having a central hole is very useful as a dimensionally stable substrate of audio compact disks (CD), audiovisual compact disks (CDV), laser-optical computer disks and magneto-optical computer disks, and data media of this type which contain these novel dimensionally stable substrates have particularly advantageous performance characteristics.
    Type: Grant
    Filed: February 1, 1990
    Date of Patent: July 14, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Feuerherd, Carola Hedtmann-Rein, Ludger Leber
  • Patent number: 5130358
    Abstract: A cationic polymer composition suitable for use as a flocculating agent and as a retention aid in paper making consists of a mixture ofa) a hydrophilic cationic polymer,b) an anionic surfactant,optionally c) a water-immeriscible oil in which the polymer a) is insoluble,and, if c) is present,optionally d) a lipophilic non-ionic surfactant,optionally e) waterand optionally f) an oil-miscible polar solvent.The compositions may be prepared by water-in-oil emulsion polymerisation and are readily diluted with water.
    Type: Grant
    Filed: March 22, 1989
    Date of Patent: July 14, 1992
    Assignee: Sandoz Ltd.
    Inventor: Bernard Danner
  • Patent number: 5116895
    Abstract: Polyamines having at least two amine groups are incorporated into a polymer system comprising an anionic surfactant and a polymer having at least one anionic pendant group. The resulting polymer system typically exhibits at least one improved physical property.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: May 26, 1992
    Assignee: Union Oil Company of California
    Inventor: Gaylen M. Knutson
  • Patent number: 5091452
    Abstract: Quaternary ammonium salt antistatic agents having an organic chain of ten to twenty-five atoms plasticize the vinyl resin of a static charge dissipative surface covering. Such antistatic agents minimize migration and therefore retain their charge dissipative properties for a longer period of time. The class of plasticizing quaternary ammonium salt antistatic agents includes derivatives of unsaturated organic acids and alkyl ethers having a chain length of six to eighteen carbon atoms and a hydroxyl functionality.
    Type: Grant
    Filed: January 30, 1989
    Date of Patent: February 25, 1992
    Assignee: Armstrong World Industries, Inc.
    Inventors: Kenneth K. Ko, Jesse D. Miller, Jr., Susan M. Von Stetten
  • Patent number: 5075363
    Abstract: A matte thermoplastic resin composition consisting essentially of:(A) 70-97% by weight of a rubber-modified alkenyl a romatic thermoplastic resin and(B) 30-3% by weight of a graft copolymer as a high polymer modifier for matting, obtained by polymerizting an ethylenically unsaturated carboxylic acid and at least one monomer selected from the group consisting of an alkenyl aromatic compound, an alkenyl cyanide compound and other copolymerizable alkenyl monomer in the presence of a rubbery polymer latex, wherein the content of the ethylenically unsaturated carboxylic acid component in the graft copolymer (B) is 1-30% by weight and the content of the rubbery polymer in the graft copolymer (B) is 10-60% by weight. Said composition has an excellent matte effect especially when the rubbery polymer latex gives a percentage coagulation of 20% by weight or less based on the total solids of the latex when 15% by weight, based on the total solids, of methacrylic acid is added to the latex.
    Type: Grant
    Filed: November 3, 1988
    Date of Patent: December 24, 1991
    Assignee: Japan Synthetic Rubber Company, Ltd.
    Inventors: Yusuke Tsuda, Kengi Tagami, Kazuyoshi Nakazawa, Yuji Yamamoto
  • Patent number: 5061763
    Abstract: A stain resistant composition for fibers having polyamide linkages prepared by polymerizing an .alpha.-substituted acrylic acid or ester in the presence of a sulfonated aromatic formaldehyde condensation plymer, or by polymerization of a sulfonated hydroxyaromatic ester of an .alpha.-substituted acrylic acid or acrylic acid, and methods for making and applying the composition.
    Type: Grant
    Filed: December 27, 1989
    Date of Patent: October 29, 1991
    Assignee: Peach State Labs, Inc.
    Inventors: Thomas H. Moss, III, Ralph R. Sargent, Michael S. Williams
  • Patent number: 5055506
    Abstract: Polyamines having at least two amine groups are incorporated into a polymer system comprising an anionic surfactant and a polymer having at least one anionic pendant group. The resulting polymer system typically exhibits at least one improved physical property.
    Type: Grant
    Filed: December 30, 1988
    Date of Patent: October 8, 1991
    Assignee: Union Oil Company of California
    Inventor: Gaylen M. Knutson
  • Patent number: 5055495
    Abstract: An improvement in the method for the foaming of polyvinylchloride resins by the use of a blowing agent and an activator therefor which uses as the activator a mixture of at least one organotin mercapto acid ester and a diorganotin oxide complex with an ester of an oxygen-containing acid.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: October 8, 1991
    Assignee: Witco Corporation
    Inventors: Michael R. Croce, Stuart D. Brilliant
  • Patent number: 5045582
    Abstract: A fire-retardant polycarbonate resin composition comprising 100 parts by weight of a halogen atom-free conventional polycarbonate resin having a viscosity-average molecular weight of 10,000 to 30,000, a fire retardant in an amount necessary for imparting fire retardance, and 5 to 60 parts by weight of a halogen atom-free ultrahigh-molecular-weight polycarbonate resin having a viscosity-average molecular weight of 100,000 to 250,000, said composition showing a flow value of 0.01 to 0.3 cm.sup.3 /sec when measured at 280.degree. C. under a load of 180 kg/cm.sup.2 using a die having a hold diameter of 1 mm and a length of 10 mm and performance rated at class V-0 when conducting a burning test in accordance with a UL-94 test about a test piece having a thickness of 1 mm.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: September 3, 1991
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Kouji Hashimoto, Noboru Yamanishi
  • Patent number: 5013865
    Abstract: An improved process for preparing a compound selected from among 2,4,6-triiodo-5-amino-N-alkylisophthalamic acid, salts thereof, esters thereof, 2,4,6-triiodo-5-amino-isophthalamide, 2,4,6-triiodo-5-amino-N-hydroxyalkyl-isophthalamide and 2,4,6-triiodo-5-amino-N,N'-bishydroxyalkyl-isophthalamide. A substrate selected from among 5-amino-N-alkylisophthalamic acid, salts thereof, esters thereof 5-amino-isophthalamide, 5-amino-N-hydroxyalkyl-isophthalamide and 5-amino-N,N'-bishydroxyalkylisophthalamide is reacted with an iodine halide in an aqueous reaction medium.
    Type: Grant
    Filed: July 24, 1989
    Date of Patent: May 7, 1991
    Assignee: Mallinckrodt, Inc.
    Inventors: Gregory D. Cross, Robert C. Chapman
  • Patent number: 4996249
    Abstract: A process for improving the flowability of resin coated sand which comprises the use of a fluorosurfactant with the mixture of sand and resin. Also provided is a resin binder containing a fluorosurfactant and a foundry mix comprising foundry sand, a resin binder and a fluorosurfactant. The resins used are alkaline phenolic resole resins and acid-curable resins.
    Type: Grant
    Filed: April 27, 1989
    Date of Patent: February 26, 1991
    Assignee: Acme Resin Corporation
    Inventors: Calvin K. Johnson, Richard C. Cooke, Kwok-Tuen Tse
  • Patent number: 4978700
    Abstract: Extrudable anti-static polyvinyl chloride (PVC) compositions include a quaternary ammonium compound as an anti-static agent, and a barium-cadmium-zinc component as a stablizing agent. The barium-cadmium-zinc component has been found to be critically required in order for the compositions to be processable (e.g., via extrusion) while retaining their desired anti-static characteristics. Shaped articles (e.g., floor mats, door strippings, and the like) may be formed from the compositions of this invention, and use in environments where static-charge dissipation is desired (e.g., computer rooms, hospitals, and the like).
    Type: Grant
    Filed: March 15, 1989
    Date of Patent: December 18, 1990
    Assignee: Edward S. Robbins, III
    Inventor: David L. Haygood
  • Patent number: 4977193
    Abstract: An improvement in the method for the foaming of polyvinylchloride resins by the use of a blowing agent and an activator therefor which uses as the activator a mixture of at least one organotin mercapto acid ester and a diorganotin oxide complex with an ester of an oxygen-containing acid.
    Type: Grant
    Filed: May 4, 1990
    Date of Patent: December 11, 1990
    Assignee: Witco Corporation
    Inventors: Michael R. Croce, Stuart D. Brilliant
  • Patent number: 4940757
    Abstract: A stain resistant composition for fibers having polyamide linkages prepared by polymerizing an .alpha.-substituted acrylic acid or ester in the presence of a sulfonated aromatic formaldehyde condensation polymer, and methods for making and applying the composition.
    Type: Grant
    Filed: April 20, 1989
    Date of Patent: July 10, 1990
    Assignee: Peach State Labs, Inc.
    Inventors: Thomas H. Moss, III, Ralph R. Sargent, Michael S. Williams
  • Patent number: 4935175
    Abstract: A mold-cleaning composition and sheet comprising an uncured rubber composition comprising an uncured rubber and a curing agent, and at least one removal aid selected from imidazoles and imidazolines, and a method for cleaning a mold using the mold-cleaning sheet, are disclosed. The mold-cleaining sheet is suitably used to clean molding surfaces of a mold or to remove contaminants such as burr formed at peripheries thereof in the continuous production of semiconductor devices by transfer molding.
    Type: Grant
    Filed: December 11, 1987
    Date of Patent: June 19, 1990
    Assignee: Nitto Electric Industrial Co., Ltd.
    Inventors: Toshihiko Kitaura, Akio Nakamura, Masayuki Sakamoto, Kouichi Takashima, Kiyotaka Hirakawa, Matao Mizota
  • Patent number: 4889879
    Abstract: Coherent thermoplastic aggregates with very high content of pulverized mineral materials, composed of the said materials, of polyolefin polymers and/or copolymers, and possibly also of various familiar adjuvants, characterized by the fact that, in order for them to have both a volumetric mass close to or at most equal to the theoretical volumetric mass of the pulverized mineral substances entering into their composition and an excellent compatibility with redispersion polymers, the polymers and/or copolymers entering into the composition of the said aggregates in presence of a fluidizing agent are chosen within the group of thermoplastics with melting and/or softening point at least equal to 60.degree. C. and index of fluidity at least 50 (measured according to the standard ASTM D 1238) of the polyolefin type, other than those containing a polar monomer.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: December 26, 1989
    Assignee: Pluess Staufer AG
    Inventors: Henry Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
  • Patent number: 4888367
    Abstract: High polymer content compositions, containing the neutralized salt of a carboxyl-containing polymer suspended in an organic medium, are made by neutralizing the carboxyl-containing polymer in the presence of a neutralizing agent and an equal quantity of already neutralized polymer in an organic medium. These compositions are useful as thickeners and emulsifiers for aqueous solutions.
    Type: Grant
    Filed: December 1, 1987
    Date of Patent: December 19, 1989
    Assignee: The Standard Oil Company
    Inventors: Vincent P. Quigley, Richard J. Jorkasky, II
  • Patent number: 4857593
    Abstract: A process for enhancing the fabrication of thermoplastic polymers entailing the addition of from 0.01 to 1 part, per hundred parts of thermoplastic polymer, of a processing aid, said processing aid comprising a processing additive, such as a silicone or a polyol, and a processing adjuvant, such as a phosphate.
    Type: Grant
    Filed: March 8, 1988
    Date of Patent: August 15, 1989
    Assignee: Union Carbide Corporation
    Inventors: Pak S. Leung, Errol D. Goddard, Fred H. Ancker
  • Patent number: 4808648
    Abstract: A stable latex composition possessing a viscosity of less than about 50 cp. comprised of an ethylacrylane/methylacrylic acid/acrylic acid polymer and a nonylphenol polyethylene oxide ether sulfate useful for increasing the viscosity of water that is injected into subterranean petroleum bearing formations for the enhanced recovery of the petroleum.
    Type: Grant
    Filed: November 20, 1984
    Date of Patent: February 28, 1989
    Assignee: Union Oil Company of California
    Inventor: Wen-Ching Hsieh
  • Patent number: 4806434
    Abstract: A medium for electrophoresis comprising an aqueous acrylamide gel formed by crosslinking polymerization of an acrylamide compound and an acrylamide copolymer having at least one specifically selected constitutional repeating unit in the presence of water. The medium may contain a water-soluble polymer and agarose. The medium may contain a modifier such as an anionic surfactant or a compound having at least one carbamoyl group.
    Type: Grant
    Filed: July 8, 1985
    Date of Patent: February 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masashi Ogawa