Halogen Patents (Class 524/163)
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Publication number: 20140275321Abstract: Photoactive additives, such as cross-linkable polycarbonate resins, are disclosed. The additive is formed from the reaction of a monohydroxybenzophenone, a dihydroxybenzophenone, a diol chain extender, and one or more linker moieties having functional groups that react with the phenolic groups on the other ingredients. If desired, a secondary linker moiety and/or an end-capping agent can be used. When added to a base polymeric resin, the photoactive additive permits crosslinking when exposed to ultraviolet light.Type: ApplicationFiled: March 13, 2014Publication date: September 18, 2014Applicant: SABIC Innovative Plastics IP B.V.Inventors: Jean-Francois Morizur, Paul Dean Sybert
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Patent number: 7714047Abstract: The present invention provides a method of producing a fluoropolymer aqueous dispersion by which the fluorine-containing emulsifier contained in the fluoropolymer aqueous dispersion as obtained after polymerization can be efficiently removed as well as a fluoropolymer aqueous dispersion low in fluorine-containing emulsifier concentration. The present invention is a method of producing a fluoropolymer aqueous dispersion which comprises carrying out a concentration treatment comprising a concentration operation of a pretreatment fluoropolymer aqueous dispersion, wherein the pretreatment fluoropolymer aqueous dispersion is obtained by carrying out a polymerization in an aqueous medium in the presence of a fluorine-containing surfactant (A), the fluorine-containing surfactant (A) is a fluorine-containing surfactant having an octanol/water partition coefficient of 1.5 to 3.5.Type: GrantFiled: June 1, 2009Date of Patent: May 11, 2010Assignee: Daikin Industries, Ltd.Inventors: Nobuhiko Tsuda, Chie Sawauchi, Yasuhiko Sawada, Tetsuo Shimizu
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Patent number: 7696268Abstract: The present invention provides a method of producing a fluoropolymer aqueous dispersion by which the fluorine-containing emulsifier contained in the fluoropolymer aqueous dispersion as obtained after polymerization can be efficiently removed as well as a fluoropolymer aqueous dispersion low in fluorine-containing emulsifier concentration. The present invention is a method of producing a fluoropolymer aqueous dispersion which comprises carrying out a concentration treatment comprising a concentration operation of a pretreatment fluoropolymer aqueous dispersion, wherein the pretreatment fluoropolymer aqueous dispersion is obtained by carrying out a polymerization in an aqueous medium in the presence of a fluorine-containing surfactant (A), the fluorine-containing surfactant (A) is a fluorine-containing surfactant having an octanol/water partition coefficient of 1.5 to 3.5.Type: GrantFiled: October 29, 2004Date of Patent: April 13, 2010Assignee: Daikin Industries, Ltd.Inventors: Nobuhiko Tsuda, Chie Sawauchi, Yasuhiko Sawada, Tetsuo Shimizu
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Patent number: 7511089Abstract: An alkali metal or alkaline earth metal salt of sulfonic acid of polyphenylene ether oligomer is useful as a modifier for thermoplastic resins, typically as a flame retardant, compatibilizing agent or antistatic agent.Type: GrantFiled: September 8, 2005Date of Patent: March 31, 2009Assignees: Shin-Etsu Chemical Co., Ltd., Mitsubishi Gas Chemical Company, Inc.Inventors: Akinari Itagaki, Masaki Tanaka, Masaaki Yamaya, Takahiro Adachi, Yasumasa Norisue, Satoshi Kanayama
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Patent number: 7390450Abstract: A process for producing a fire resistant polycarbonate composition comprises preparing an aqueous solution of a flame retardant salt; and compounding the aqueous solution of the flame retardant salt with a polycarbonate composition to form the fire resistant polycarbonate composition. The process reduces the level of haze, color and inclusions compared to fire resistant polycarbonate compositions compounded with the same flame retardant salt in solid form.Type: GrantFiled: June 7, 2002Date of Patent: June 24, 2008Assignee: General Electric CompanyInventors: Theodorus Lambertus Hoeks, Adrianus A. M. Kusters
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Patent number: 7067075Abstract: The object of the present invention is to provide a flame-retardant thermoplastic resin composition, which comprises: 100 parts by weight of a thermoplastic resin (A), 0.1 to 30 parts by weight of a polyorganosiloxane-containing graft copolymer (B) obtained by polymerizing, in at least one stage, a monomer (B-3) comprising a polyfunctional monomer (B-2) containing at least two polymerizable unsaturated bonds within the molecule thereof, and/or a vinyl monomer (B-4) in the presence of polyorganosiloxane particles (B-1), 0.0005 to 5 parts by weight of at least one metal salt (C) selected from the group consisting of alkali metal salts and bivalent or further polyvalent metal salts, and 0.05 to 2 parts by weight of a fluororesin (D).Type: GrantFiled: April 25, 2003Date of Patent: June 27, 2006Assignee: Kaneka CorporationInventors: Kazunori Saegusa, Tomomichi Hashimoto, Hiroshi Tsuneishi, Nobuo Miyatake, Hiroshi Tone, Akira Takaki
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Patent number: 6489042Abstract: An electronic circuit device comprising at least one substrate having a photoimageable covercoat, comprising at least 95 weight percent of at least one epoxy-modified aromatic vinyl-conjugated diene block copolymer and a catalyst comprising an onium salt selected from a triarylsulfonium salt and a diaryliodonium salt, wherein the covercoat is formed by solvent coating or extrusion and then heat laminated onto at least a portion of the substrate.Type: GrantFiled: October 18, 2001Date of Patent: December 3, 2002Assignee: 3M Innovative Properties CompanyInventors: Ronald L. Imken, Robert S. Clough
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Patent number: 6423367Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: July 27, 2001Date of Patent: July 23, 2002Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
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Patent number: 6294270Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: December 23, 1998Date of Patent: September 25, 2001Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
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Patent number: 6031036Abstract: Disclosed are aromatic brominated polycarbonate/polyester carbonate/silicone polyimide compositions having improved flame resistance and reduced drippage and heat release rate, comprising by weight:(A) from about 20 to about 77 parts of an aromatic brominated polycarbonate resin;(B) from about 20 to about 77 parts of a polyester carbonate resin;(C) from about 0.5 to about 10 parts of a silicone-polyimide resin;(D) from about 0 to about 25 parts of an aromatic polycarbonate having a molecular weight of from about 40,000 to about 90,000; the sum of (A)-(D) being 100 parts by weight;(E) from about 0.05 to about 2.0 parts of a metal salt of a halogenated monomeric or polymeric aromatic sulfonic acid or mixtures thereof, wherein the metal salt is selected from the group consisting of alkali metal salts, alkaline earth metal salts, and mixtures of the metal salts; and(F) from about 0.1 to about 5.0 parts by weight of filler or a pigment.Type: GrantFiled: December 10, 1993Date of Patent: February 29, 2000Assignee: General Electric CompanyInventors: Niles Richard Rosenquist, Angelika Howard Clark
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Patent number: 5698618Abstract: A coating composition is formed from an acid-set coating varnish and a pigment composition. The pigment composition includes a specific organic dyestuff derivative and a specific basic-group-containing resin-type pigment dispersant. The coating composition excels in pigment dispersibility, nonflocculation properties, noncrystallizability and fluidity. When used as a coating, the coating composition has excellent color tone, gloss, hardness, weather resistance, and solvent resistance.Type: GrantFiled: July 18, 1996Date of Patent: December 16, 1997Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Takashi Kamikubo, Tadashi Itabashi, Masami Kuwahara
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Patent number: 5659058Abstract: A process for rendering polymer compositions antistatic and the products of such process are described. The polymeric material is treated with a combination of selected trineoalkoxy amino zirconates and trineoalkoxy sulfonyl zirconates. These latter materials are soluble in the polyolefins, polyesters, polyamides, polyethers, polycarbonates, and polystyrenes and remain stable during the processing of these polymers. Furthermore, the antistatic agents of the invention are thermally stable to temperatures up to 825.degree. F., do not "bloom" during the polymer processing, and are colorless, permanent, non-blooming and non-moisture dependent.Type: GrantFiled: May 31, 1995Date of Patent: August 19, 1997Assignee: Kenrich Petrochemicals, Inc.Inventor: Salvatore Joseph Monte
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Patent number: 5326800Abstract: The invention relates to use of salts of sulphonic acids, phosphonic acids and/or carboxylic acids in combination with halogenated phthalimides for additional processing of glass fibre-containing polycarbonate moulded members.Type: GrantFiled: March 11, 1993Date of Patent: July 5, 1994Assignee: Bayer AktiengesellschaftInventors: Klaus Horn, Jurgen Kirsch, Richard Weider, Hugo Obermann, Dieter Freitag, Karsten-Josef Idel
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Patent number: 5274017Abstract: Aromatic carbonate polymers are flame retarded by an effective amount of a metal oxide of aluminum, magnesium, lithium, lanthanum, bismuth or yttrium. Colloidal aluminum oxide on silica is particularly effective.Type: GrantFiled: November 24, 1989Date of Patent: December 28, 1993Assignee: General Electric CompanyInventor: Wie-Hin Pan
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Patent number: 5118739Abstract: A novel flame retardant formulation comprising a flammable macromolecular material and a metal salt of a polybrominated sulfonic acid and having improved flame retardancy and enhanced U.V. stability.Type: GrantFiled: June 20, 1990Date of Patent: June 2, 1992Assignee: Ethyl CorporationInventors: Burton J. Sutker, Saadat Hussain
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Patent number: 4735978Abstract: A flame retardant polycarbonate composition, comprising in admixture:an aromatic polycarbonate resin, an ortho-methyl substituted aromatic dihydroxy compound, and an additional flame retardant additive, said ortho-methyl substituted aromatic dihydroxy compound and said additional flame retardant additive being present in an amount sufficient to improve the flame retardant properties of said aromatic polycarbonate resin.Type: GrantFiled: December 24, 1986Date of Patent: April 5, 1988Assignee: General Electric CompanyInventor: Toshio Ishihara
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Patent number: 4579896Abstract: Flame retardant and drip retardant polycarbonate composition comprised of:(i) at least one aromatic carbonate resin;(ii) a flame retardant amount of at least one flame retardant compound; and(iii) a drip retardant amount of at least one bis cyclic carbonate represented by the general formula ##STR1## wherein X, Y, X' and Y' are the same or different and are hydrogen or alkyl of one to about six carbon atoms, inclusive; W, W', Z and Z' are the same or different and are alkyl of one to about six carbon atoms, inclusive, and E is alkylene or alkylidene of two to about twelve carbon atoms, inclusive.Type: GrantFiled: January 2, 1985Date of Patent: April 1, 1986Assignee: General Electric CompanyInventor: Niles R. Rosenquist
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Patent number: 4469833Abstract: Improved non-opque flame retardant compositions comprised of, in admixture:(i) at least one aromatic polycarbonate resin derived from (a) at least one halogen-free and sulfur-free dihydric phenol, (b) a minor amount of at least one halogen-free thiodiphenol, and (c) a carbonate precursor; and(ii) a minor amount of at least one organic alkali or alkaline earth metal salt of sulfonic acid.Type: GrantFiled: May 27, 1983Date of Patent: September 4, 1984Assignee: General Electric CompanyInventor: Victor Mark
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Patent number: 4440890Abstract: Described herein is a flame retardant molding composition comprising a particular poly(aryl ketone) and a flame retardant additive which is a metal salt of an aromatic sulfonic acid.Type: GrantFiled: June 21, 1983Date of Patent: April 3, 1984Assignee: Union Carbide CorporationInventor: Lloyd M. Robeson
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Patent number: 4380598Abstract: Described herein are flame retardant molding compositions comprising a blend of a polyarylate derived from a dihydric phenol and an aromatic dicarboxylic acid and a flame retardant additive which is a metal salt of an aromatic sulfonic acid. The composition may additionally contain one or more thermoplastic polymers.Type: GrantFiled: February 12, 1981Date of Patent: April 19, 1983Assignee: Union Carbide CorporationInventors: Lloyd M. Robeson, Markus Matzner