Metal Patents (Class 524/166)
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Patent number: 5352720Abstract: An aqueous polymer dispersion with a solids volume concentration of at least 50% by volume is obtainable by polymerizing monomers by the method of free radical aqueous emulsion polymerization with the addition of at least one fine and at least one coarse aqueous starting polymer dispersion.Type: GrantFiled: March 29, 1993Date of Patent: October 4, 1994Assignee: BASF AktiengesellschaftInventors: Oral Aydin, Michael Portugall, Josef Neutzer, Walter Maechtle
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Patent number: 5340860Abstract: Improved liquid fluid loss reducing additives, well cement compositions containing the additives and methods of using the compositions are provided by this invention. The liquid fluid loss reducing additives are basically comprised of water, polyethylene imine, an alkali metal salt of alkylbenzene sulfonic acid and an alkali metal salt of naphthalene sulfonic acid condensed with formaldehyde.Type: GrantFiled: October 30, 1992Date of Patent: August 23, 1994Assignee: Halliburton CompanyInventors: Bobby G. Brake, Jiten Chatterji
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Patent number: 5340861Abstract: A rapidly crystallizing polyphenylene sulfide composition for reducing duration of injection molding cycle which comprises (a) a polyphenylene sulfide represented by the formula: ##STR1## and (b) an organometallic compound represented by the formula:R'--O--M--(Q--R").sub.3wherein M is either titanium or zirconium; R' is a substituted or un-substituted alkyl group having a carbon number of 1 to 30; Q is an SO.sub.3 group and R" is an alkyl group having a carbon number of 1 to 25, or an aryl-alkyl group represented by the following formula: ##STR2## wherein R is an alkyl group having a carbon number of 1 to 25.Type: GrantFiled: May 3, 1993Date of Patent: August 23, 1994Assignee: Industrial Technology Research InstituteInventors: Chi-Hwang Chen, Chih-Cheng Chiang, Bin-Yuan Lin, Rong-Hwa Chang
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Patent number: 5332776Abstract: A blend of from 10 to 90 parts by weight of a basic calcium sulphonate free of calcium carbonate in the calcite form and from 90 to 10 parts by weight of a terpolymer of 80 to 99 wt.% of an olefin containing from 2 to 4 carbon atoms, 1 to 30 wt.% of an unsaturated ester which is a vinyl ester of a carboxylic acid or an ester of acrylic or methacrylic acid and 1 to 20 wt.% of an unsaturated carboxylic acid is particularly useful for car undercoatings for corrosion and chip resistance which may be applied as high solids coatings.Type: GrantFiled: October 7, 1992Date of Patent: July 26, 1994Assignee: Exxon Chemical Patents Inc.Inventors: Robert D. M. Best, Jean F. Brument
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Patent number: 5326800Abstract: The invention relates to use of salts of sulphonic acids, phosphonic acids and/or carboxylic acids in combination with halogenated phthalimides for additional processing of glass fibre-containing polycarbonate moulded members.Type: GrantFiled: March 11, 1993Date of Patent: July 5, 1994Assignee: Bayer AktiengesellschaftInventors: Klaus Horn, Jurgen Kirsch, Richard Weider, Hugo Obermann, Dieter Freitag, Karsten-Josef Idel
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Patent number: 5306746Abstract: The present invention relates to a resin composition which selectively absorbs light of the wavelength band in the vicinity of wavelength 580 nm, as well as to the optical products to be formed from this resin composition. The beads possessing light selective function are formed from a transparent polymer which contains a neodymium compound: these beads are then dispersed in a transparent resin composition. Comparing to the case when the neodymium compound is directly dispersed in the resin composition, a large amount of neodymium compound can be added to the resin composition without decreasing the mechanical and thermal properties of the resin composition.Type: GrantFiled: March 10, 1992Date of Patent: April 26, 1994Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Kozo Ida, Tetsuya Suda
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Patent number: 5283276Abstract: A corrosion protection composition a dispersion or solution of (a) colloidal size amorphous overbased sulfonate, (b) solvent or plasticizer, and (c) polymeric material soluble in the solvent or compatible with the plasticizer is disclosed. The composition comprises at least about 70% solids, by weight, and the particle size if the colloidal overbased sulfonate is up to about 100 A. Preferably, the composition is free from any mineral oil. Metal surfaces having the herein disclosed composition applied thereto, or having the applied thereto the composition from which the solvent has been removed also is disclosed.Type: GrantFiled: February 19, 1992Date of Patent: February 1, 1994Assignee: Exxon Chemical Patents Inc.Inventors: Robert D. M. Best, Pierre H. Fillastre, Edouard M. Mathieu
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Patent number: 5274018Abstract: The invention relates to a novel absorbent composition and manner of using the same. The absorbent has at least the following two components:(a) a swellable hydrophobic polymer being capable of absorbing a quantity of water which is at least about 10 times the dry weight of said polymer; and(b) an amount of an ionizable surfactant sufficient to form at least a monolayer of said surfactant about said polymer.The novel absorbent is substantially tolerant to an aqueous solution having a soluble salt, such as sodium chloride.Type: GrantFiled: May 24, 1991Date of Patent: December 28, 1993Assignee: Massachusetts Institute of TechnologyInventors: Toyoichi Tanaka, Yong-Qing Zhang
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Patent number: 5252644Abstract: An acrylic resin is provided which has excellent weatherability, outstanding transparency and improved heat and solvent resistance, as well as improved impact strength. The acrylic resin comprises an intimate blend of a polymerization syrup and a catalytic amount of a polymerization catalyst capable of effecting polymerization of the syrup. The polymerization syrup, which has an improved shelf life and can be stored at ambient temperature and atmospheric pressure, consists essentially of:(a) from about 300 to about 1000 parts per volume of an acrylic monomer represented by the formula ##STR1## wherein R is an alkyl moiety containing 1 to about 18 carbon atoms; (b) from about 0.1 to about 1000 parts by volume of a non-peroxide oxygen donator, such as 2,2-bis(allyloxymethyl)-butan-1-ol or diallylphtha1ate;(c) from about 0.5 to about 5 parts by volume of a mercaptan; and(d) from about 0.3 to about 40 parts by volume of a crosslinking agent compatible with the acrylic monomer.Type: GrantFiled: July 27, 1992Date of Patent: October 12, 1993Inventor: Bill R. Edwards
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Patent number: 5250596Abstract: An acrylic resin is provided which has excellent weatherability, outstanding transparency and improved heat and solvent resistance, as well as improved impact strength. The acrylic resin comprises an intimate blend of a polymerization syrup and a catalytic amount of a polymerization catalyst capable of effecting polymerization of the syrup. The polymerization syrup, which has an improved shelf life and can be stored at ambient temperature and atmospheric pressure, consists essentially of:(a) from about 300 to about 1000 parts per volume of an acrylic monomer represented by the formula ##STR1## wherein R is an alkyl moiety containing 1 to about 18 carbon atoms; (b) from about 0.1 to about 1000 parts by volume of a non-peroxide oxygen donator, such as 2,2-bis(allyloxymethyl)-butan-1-ol or diallylphthalate;(c) from about 0.5 to about 5 parts by volume of a mercaptan; and(d) from about 0.3 to about 40 parts by volume of a crosslinking agent compatible with the acrylic monomer.Type: GrantFiled: April 15, 1993Date of Patent: October 5, 1993Inventor: Bill R. Edwards
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Patent number: 5221706Abstract: An emulsified pressure sensitive adhesive is provided which is based on a polymer containing from about 95 to 97.5% by weight of an alkyl ester of acrylic acid and from about 2.5 to 5% by weight of a mixture of carboxylic acids and a three component anionic surfactant system. The polymer is preferably tackified.Type: GrantFiled: July 29, 1991Date of Patent: June 22, 1993Assignee: Avery Dennison CorporationInventors: Ivan S. P. Lee, Paul Keller, Richard J. Norman, Robert S. Dordick, Mary E. Zawadzki
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Patent number: 5194469Abstract: This invention relates to the synthesis of a latex which can be formulated into coatings having improved flexibility and good water resistance. Coatings of this type are particularly useful in roof coating applications because they offer excellent flexibility, excellent ultra-violet light resistance, and good water resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises:(1) free radical aqueous emulsion polymerizing, at a pH of less than about 3.5, a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 30 to about 70 weight percent vinyl aromatic monomers, (b) from about 25 to about 65 weight percent of at least one alkyl acrylate monomer, (c) from about 1 to about 5 weight percent of acrylic acid, and (d) about 0.4 to about 3 weight percent methacrylic acid, in the presence of about 0.2 to 0.Type: GrantFiled: February 28, 1991Date of Patent: March 16, 1993Assignee: The Goodyear Tire & Rubber CompanyInventors: Richard E. Srail, Gary L. Burroway
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Patent number: 5177131Abstract: The present room temperature curing composition comprises an organopolysilethylenesiloxane represented by the following general formula: ##STR1## wherein R.sup.1 to R.sup.4 each represent an alkyl having up to 8 carbon atoms or a phenyl group and n is an integer of 10 or above, and an organosilane or an organosiloxane having two or more hydrolyzable groups such as alkoxy groups in the molecule. The composition can form a cured product high in rubber strength and excellent in chemical resistance.Type: GrantFiled: July 9, 1991Date of Patent: January 5, 1993Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Toshio Takago, Hiroshi Inomata, Hirofumi Kishita, Shinichi Sato, Hitoshi Kinami, Koichi Yamaguchi, Takashi Matsuda, Hirokazu Yamada
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Patent number: 5157062Abstract: A thermoplastic resin composition containing (A) 100 parts by weight of a glutarimide copolymer having 5 to 100% by mole of glutarimide units and 95 to 0% by mole of ethylenically .alpha.,.beta.-unsaturated monomer units, and (B) 0.3 to 10 parts by weight of an alkali metal alkylsulfonate of the following formula:R--SO.sub.3 X (I)wherein R represents a C.sub.8 -C.sub.22 alkyl group, and X represents an alkali metal, which has good antistatic properties as well as improved heat resistance.Type: GrantFiled: October 2, 1991Date of Patent: October 20, 1992Assignee: Sumitomo Chemical Company, LimitedInventors: Teruhisa Koyama, Shinji Date
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Patent number: 5140056Abstract: The invention relates to the use of salts of sulfosuccinic acid esters as internal antistatic agents, take-off and winding aids for transparent cast films of polycarbonates, to a process for the production of cast polycarbonate films and to the cast polycarbonate films themselves containing salts of sulfosuccinic acids and also to the use of the new cast polycarbonate films in the electrical field and optical field.Type: GrantFiled: February 21, 1990Date of Patent: August 18, 1992Assignee: Bayer AktiengesellschaftInventors: Volker Wiskamp, Dittmar Nerger, Bernhard Schulte, Werner Waldenrath
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Patent number: 5130358Abstract: A cationic polymer composition suitable for use as a flocculating agent and as a retention aid in paper making consists of a mixture ofa) a hydrophilic cationic polymer,b) an anionic surfactant,optionally c) a water-immeriscible oil in which the polymer a) is insoluble,and, if c) is present,optionally d) a lipophilic non-ionic surfactant,optionally e) waterand optionally f) an oil-miscible polar solvent.The compositions may be prepared by water-in-oil emulsion polymerisation and are readily diluted with water.Type: GrantFiled: March 22, 1989Date of Patent: July 14, 1992Assignee: Sandoz Ltd.Inventor: Bernard Danner
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Patent number: 5118738Abstract: The specification describes and claims filled compositions, e.g. moisture curable sealant compositions which comprise 100 parts by weight of polymeric material comprising a mixture and/or a reaction product of a polydiorganosiloxane having silicon-bonded hydroxyl groups with a compound containing silicon-bonded alkoxy or alkoxyalkoxy groups, 50 to 200 parts by weight of finely divided filler and an additive which is a reaction product of an organic amine, an oxide, hydroxide, carbonate, bicarbonate or a mixture thereof with a sulphonic acid of the formula RSO.sub.3 H in which R represents a hydrocarbon group which may be halogenated. The additive is preferably a reaction product of the sulphonic acid and an oxide, hydroxide, carbonate or bicarbonate of magnesium, or calcium and the acid is preferably one in which R represents a group R'C.sub.6 H.sub.4 wherein R' represents an alkyl group having 6 to 18 carbon atoms, for example dodecylbenzenesulphonic acid.Type: GrantFiled: April 20, 1990Date of Patent: June 2, 1992Assignee: Dow Corning S.A.Inventors: Michelle M. N. C. Berthet, Brian R. Trego, Hans-Juergen Wessely
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Patent number: 5109042Abstract: An additive for reducing water loss from cement comprising a tetrapolymer, base, an electrolyte, at least one surfactant, and water is disclosed. A process for producing cement slurries with improved water loss properties, as well as an improved method for cementing gas and oil wells is also disclosed.Type: GrantFiled: December 22, 1989Date of Patent: April 28, 1992Assignee: Phillips Petroleum CompanyInventor: Michael Stephens
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Patent number: 5106903Abstract: Monodisperse latexes of at least 2-30 microns particle size are prepared from an emulsion recipe comprising a monodisperse seed latex polymer on the order of 2 microns or less particle size, a polymerizable monomer, an initiator, at least one inhibitor, and a water-soluble polymeric emulsifier of 10.sup.4 -10.sup.7 molecular weight. Optional ingredients are crosslinking monomer, oil-soluble inhibitor if the mixture is to be stored before polymerization, and one or more additional emulsifiers selected from a water-soluble comonomer or polymer of 0.3.times.10.sup.3 -5.times.10.sup.3 molecular weight and a non-polymeric anionic emulsifier. Additional particle size growth and monodisperse latex yield are realized by polymerization in a microgravity environment.Type: GrantFiled: August 19, 1988Date of Patent: April 21, 1992Assignee: Lehigh UniversityInventors: John W. Vanderhoff, Fortunato J. Micale, Mohamed S. El-Aasser, Chi-Ming Tseng
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Patent number: 5073587Abstract: An acrylic-based particulate filled polymeric composition is provided which is curable at atmospheric pressure and ambient temperature and has a pour to pull time of less than about 4 hours. The acrylic-based particulate filled polymeric composition comprises an intimate blend of a polymerization syrup, a filler, and minor effective amount of crosslinking agent, a polymerization catalyst, a quaternary compound and a polymerization initiator. To enhance and reduce the pour to pull time of articles molded or cast from the acrylic-based particular filled polymeric composition, an effective miner amount of a reaction modifier, such as trimethylpropane triacrylate, can be incorporated into the polymeric composition. The polymerization syrup employed in formulating an acrylic-based particulate filled polymeric composition consist essentially of from about 300 to about 1,000 parts by volume of an acrylic monomer, from about 0.01 to about 1 part by volume of peroxide-free oxygen donator, from about 0.Type: GrantFiled: January 16, 1990Date of Patent: December 17, 1991Inventor: Bill R. Edwards
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Patent number: 5073586Abstract: The specification discloses a curable composition comprising 100 parts by weight of polysiloxane, 50 to 200 parts by weight of finely divided filler having an average particle size greater than 0.05 micron and not less than 0.5 parts by weight per 100 parts by weight of the filler of an additive which is a reaction product of an organic amine, or an oxide, hydroxide, carbonate, or bicarbonate or a mixture thereof with a sulphonic acid of the formula RSO.sub.3 H in which R represents a hydrocarbon group which may have halogen or amino substituents and which contains not less than six carbon atoms. Preferred additives are reaction products of the sulphonic acid and an oxide, hydroxide, carbonate or bicarbonate of sodium, magnesium, zinc, calcium, barium, aluminium or a mixture thereof. The group R of the sulphonic acid may be R'C.sub.6 H.sub.4 where R' represents an alkyl group having 6 to 18 carbon atoms and a preferred acid is dodecylbenzenesulphonic acid.Type: GrantFiled: April 20, 1990Date of Patent: December 17, 1991Assignee: Dow Corning S.A.Inventors: Michelle M. N. C. Berthet, Brian R. Trego, Hans-Juergen Wessely
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Patent number: 5068273Abstract: A thermosetting composition comprising a mixture of a thermosettable polyester and an aminoplast resin together with an alkali metal sulfonate. The composition may also contain a pigment and a reactive diluent. The composition is useful as a coating or ink.Type: GrantFiled: June 27, 1990Date of Patent: November 26, 1991Assignee: Sun Chemical CorporationInventors: Narendra M. Patel, Leonard Di Leo
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Patent number: 5045580Abstract: A thermoplastic polyester resin composition exhibiting improved antistatic properties including a thermoplastic polyester resin, between about 0.02 to about 10 wt. %, based on the total weight of the composition, of a sulfonate-type anionic antistatic agent, and between about 0.005 to about 10 wt. %, based on the total weight of the composition, of one or more compounds selected from organophosphorus compounds, and organic chelating agents.Type: GrantFiled: November 30, 1989Date of Patent: September 3, 1991Assignee: Polyplastics Co., Ltd.Inventor: Hiroshi Kitamura
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Patent number: 5023313Abstract: An acrylic resin is provided which has excellent weatherability, outstanding transparency and improved heat and solvent resistance, as well as improved impact strength. The acrylic resin comprises an intimate blend of a polymerization syrup and a catalytic amount of a polymerization catalyst capable of effecting polymerization of the syrup. The polymerization syrup, which has an improved shelf life and can be stored at ambient temperature and atmospheric pressure, consists essentially of:(a) from about 300 to about 1000 parts per volume of an acrylic monomer represented by the formula ##STR1## wherein R is an alkyl moiety containing 1 to about 18 carbon atoms; (b) from about 0.1 to about 1 parts by volume of 2,2-bis(allyl-oxymethyl)-butan-1-ol;(c) from about 0.5 to about 5 parts by volume of a mercaptan; and(d) from about 0.3 to about 40 parts by volume of a crosslinking agent compatible with the acrylic monomer.Type: GrantFiled: May 23, 1990Date of Patent: June 11, 1991Inventor: Bill R. Edwards
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Patent number: 5021489Abstract: This invention relates to corrosion-inhibiting compositions and particula to compositions capable of forming films on metal substrates to protect said metal from corrosion. The film-forming compositions which are capable of displacing moisture from the metal surface comprises effective amounts of an acrylic resin, a silicone resin and a copolymer derived from a silicone and alkyd monomers. These resins together with effective amounts of an organic phosphate and a sulfonate are used in combination with lower molecular weight alcohols and at least one solvent.Type: GrantFiled: March 1, 1990Date of Patent: June 4, 1991Assignee: The United States of America as represented by the Secretary of the NavyInventors: Walter E. Knight, Kenneth G. Clark, David L. Gauntt
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Patent number: 4945122Abstract: An acrylic resin is provided which has excellent weatherability, outstanding transparency and improved heat and solvent resistance, as well as improved impact strength. The acrylic resin comprises an intimate blend of a polymerization syrup and a catalytic amount of a polymerization catalyst capable of effecting polymerization of the syrup. The polymerization syrup, which has an improved shelf life and can be stored at ambient temperature and atmospheric pressure, consists essentially of:(a) from about 300 to about 1000 parts per volume of an acrylic monomer represented by the formula ##STR1## wherein R is an alkyl moiety containing 1 to about 18 carbon atoms; (b) from about 0.1 to about 1 parts by volume of 2,2-bis(allyl-oxymethyl)-butan-1-ol;(c) from about 0.5 to about 5 parts by volume of a mercaptan; and(d) from about 0.3 to about 40 parts by volume of a crosslinking agent compatible with the acrylic monomer.Type: GrantFiled: July 27, 1989Date of Patent: July 31, 1990Inventor: Bill R. Edwards
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Patent number: 4929652Abstract: The invention relates to polyolefines stabilized against damage caused by light and containing(A) at least one polyalkylpiperidine light stabilizer,(B) an organic salt of zinc or magnesium and(C) either(C.sub.1) a UV absorber or(C.sub.2) a pigment or(C.sub.3) a UV absorber and a pigment.Type: GrantFiled: April 27, 1988Date of Patent: May 29, 1990Assignee: Ciba-Geigy CorporationInventor: Francois Gugumus
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Patent number: 4882376Abstract: The vinyl chloride polymers forming part of the composition of the plastisols result from the polymerization of vinyl chloride in aqueous medium with the aid of sulphosuccinamate(s). After gelling at 120.degree.-140.degree. C., the plastisols based on such polymers have an excellent adhesiveness to metal. They are more particularly suitable for coating sheet metal processed by electrostatic spraying.Type: GrantFiled: April 18, 1989Date of Patent: November 21, 1989Assignee: Solvay & CieInventors: Serge Dusoleil, Jean-Luc Preat, Odon Barthelemy
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Patent number: 4882375Abstract: The melt viscosity of polyesters is modified by adding thereto a minor amount of a sulfonated salt of a carboxylic acid.Type: GrantFiled: September 1, 1988Date of Patent: November 21, 1989Assignee: General Electric CompanyInventors: John A. Tyrell, Lawrence R. Wallace
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Patent number: 4873277Abstract: An aromatic carbonate resin composition exhibiting improved impact properties comprised of:(i) at least one aromatic carbonate resin;(ii) at least one effective amount of at least one impact modifier; and(iii) an amount effective to improve the impact properties of (i) and (ii) but insufficient to substantially deleteriously affect, to a substantial degree, most of the advantageous properties thereof of at least one aliphatic sulphonate.Type: GrantFiled: October 31, 1986Date of Patent: October 10, 1989Assignee: General Electric CompanyInventor: Omar M. Boutni
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Patent number: 4873279Abstract: A resinous composition comprising:(i) at least one copolyester-carbonate resin;(ii) at least one polyester resin; and(iii) a minor amount of a mixture of at least one polyol and at least one epoxide.Type: GrantFiled: December 22, 1986Date of Patent: October 10, 1989Assignee: General Electric CompanyInventor: Linda H. Nelson
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Patent number: 4843126Abstract: Aminoplast compositions are cured using a sulfur and phosphorus containing catalyst.Type: GrantFiled: December 30, 1987Date of Patent: June 27, 1989Assignee: The Lubrizol CorporationInventor: Robert E. Quinn
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Patent number: 4804720Abstract: Disclosed herein is a polyamide resin composition comprising a polyamide resin, from 0.1 to 1% by weight of fine silica based on the polyamide resin and from 1 to 99% by weight of a silane coupling agent based on the fine silica. The packaging material obtained from the polyamide resin composition of the present invention has uniform and satisfactory transparency and is excellent in the blocking resistance.Type: GrantFiled: April 6, 1988Date of Patent: February 14, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Mitsuhiko Tamura, Masaaki Miyamoto, Masaya Ueda, Eiichi Kamoshida
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Patent number: 4804700Abstract: Resinous composition comprised of, in physical admixture: (i) at least one copolyester-carbonate resin, (ii) at least one polyarylate resin, and (iii) at least one resin selected from polyphenylene ether resins, polystyrene resins, and mixtures thereof.Type: GrantFiled: July 11, 1985Date of Patent: February 14, 1989Assignee: General Electric CompanyInventor: Deborah L. Allen
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Patent number: 4791158Abstract: Thermoplastic molding materials contain, as essential components,(A) from 10 to 89.99% by weight of a polyester,(B) from 10 to 89.99% by weight of a polycarbonate and(C.sub.1) from 0.01 to 1% by weight of a low molecular weight organic compound of not more than 70 carbon atoms which contains (--SO.sub.3).sub.m Q groups where Q is hydrogen, NH.sub.4 or an alkali or alkaline earth metal and m is an integer equal to the valency of Q, and/or(C.sub.2) from 0.01 to 30% by weight of a polymer containing sulfo groups and having a weight average molecular weight of not less than 1000,and, as a further component,(D) from 0 to 30% by weight of a rubber impact modifier.Type: GrantFiled: July 10, 1987Date of Patent: December 13, 1988Assignee: BASF AktiengesellschaftInventors: Dietrich Lausberg, Graham E. McKee, Christof Taubitz, Georg Wassmuth, Manfred Knoll
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Patent number: 4776981Abstract: The present invention relates to phthalimide compounds of the formula (I) ##STR1## wherein X denotes H or halogen, for example chlorine or bromine,a and b independently of one another denote 0 or 1 andR denotes a C.sub.1 -C.sub.4 -alkyl radical,which, in combination with alkali metal salts, are suitable as flameproofing agent combinations for thermoplastic, branched, aromatic polycarbonates, and the preparation of these compounds.Type: GrantFiled: August 24, 1987Date of Patent: October 11, 1988Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Klaus Kircher
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Patent number: 4777198Abstract: A self-emulsifiable resin powder can be dispersed in water without utilizing additional surfactants or expending large amounts of mechanical energy. Such self-emulsifiable resin powders offer numerous distinct advantages over conventional latices. One of the most important benefits that is realized by utilizing self-emulsifiable resin powders is that they can be shipped dry which is the equivalent to shipping a latex with a 100 percent solids content. In other words, such self-emulsifiable resin powders eliminate the necessity for shipping water in latices. The self-emulsifiable resin powders disclosed herein also have the advantage of having low carboxyl contents and of being dispersible into aqueous systems which contain virtually no surfactants. These self-emulsifiable resins contain a relatively small proportion of repeat units which are derived from both acrylic acid and methacrylic acid.Type: GrantFiled: May 22, 1987Date of Patent: October 11, 1988Assignee: The Goodyear Tire & Rubber CompanyInventor: Mariano Salazar
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Patent number: 4769406Abstract: A hot melt adhesive suitable for bonding plastic, metal, and glass together has been developed by blending together into a homogenous mixture 10 to 20 weight percent of ethylene/vinyl acetate/acid functional terpolymer resin of low acid number, 15 to 50 weight percent of ethylene/vinyl acetate/acrylic acid terpolymer resin of high acid number and 30 to 60 weight percent of tackifying resins based on alpha-methylstyrene, rosin, or a terpene resin. Additionally, suitable antioxidants and surfactants are added to control the aging and application of the composition.Type: GrantFiled: March 2, 1987Date of Patent: September 6, 1988Assignee: Essex Specialty Products, Inc.Inventor: Robert J. Keithley
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Patent number: 4749506Abstract: A microgel dispersion characterized by that an oil-soluble surface active agent is adsorbed or adhered onto a gel consisting of a fine particle substance and a polymer, and said gel is dispersed in a non-aqueous organic solvent.Type: GrantFiled: September 19, 1985Date of Patent: June 7, 1988Assignee: Ricoh Co., Ltd.Inventors: Ayao Kitahara, Kijiro Konno
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Patent number: 4745142Abstract: A polyester fiber having a superior stainproof property comprises at least one fiber-forming polyester copolymer comprising a backbone polyester polymer and at least one type of terminal substituent which blocks at least some of the terminals of the molecules of the backbone polyester polymer and which substituent consists of a polyoxyalkyleneglycol monoether group of the formula (I):R.sup.1 -O--R.sup.2 -O.sub.n (I)wherein R.sup.1 is a monovalent organic radical free from active hydrogen atom, R.sup.2 is an alkylene radical, and n is an integer of 2 or more.Type: GrantFiled: October 10, 1986Date of Patent: May 17, 1988Assignee: Teijin LimitedInventors: Shinji Ohwaki, Togi Suzuki, Shigenobu Kobayashi
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Patent number: 4742099Abstract: A new polyimide film which contains 30 to 800 ppm of titanium based on the weight of the film, and a process for producing a new polyimide film which comprises introducing an organic titanium compound substance into the film-forming polyimide resin prior to the casting step. This process enables one to control the film surface forming process and improve directly the adhesive properties of the film.Type: GrantFiled: December 1, 1986Date of Patent: May 3, 1988Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Hirosaku Nagano, Junji Takase, Hideki Kawai, Hitoshi Nojiri, Tsuneo Yamamoto
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Patent number: 4729791Abstract: Coating compositions for metals effective to inhibit corrosion of ferrous and nonferrous metals susceptible to corrosion, said compositions comprising an inorganic-organic complex in the form of a thixotropic overbased alkaline earth metal sulfonate, particularly calcium, organic sulfonate, complexed with an alkaline earth metal, particularly calcium, carbonate; and linseed oil or a drying oil having drying properties generally similar to linseed oil, said linseed oil constituting at least 15% and, particularly, higher percentages up to about 50%, by weight of the coating compositions; and a drier, preferably of the paint drier type; and particularly advantageously also containing an epoxidized oil, particularly an epoxidized drying oil; and, also, such ingredients as mineral oils, waxes, petrolatums and resins.Type: GrantFiled: February 25, 1985Date of Patent: March 8, 1988Assignee: Witco CorporationInventors: Paul E. Laura, Paul W. Niemczura, Harold H. Christhilf, Paul E. Morrison
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Patent number: 4713408Abstract: A polybutylene terephthalate resin composition comprises polybutylene terephthalate, a sulfonate anionic antistatic agent and an oxidized polyolefin wax. It is improved in the antistatic property and useful as a part for an electric instrument.Type: GrantFiled: December 20, 1985Date of Patent: December 15, 1987Assignee: Polyplastics Co., Ltd.Inventors: Katsuhiko Takahashi, Yoshihisa Tajima
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Patent number: 4704334Abstract: The bond strength between a sulphur-vulcanisable rubber and a metal, especially brass, is increased by using as bonding promoter an organic substance containing one or more groups of the formula --S--SO.sub.2 R where R represents (a) a radical --OM where M is a monovalent metal, the equivalent of a multivalent metal, a monovalent ion derived by the addition of a proton to a nitrogeneous base or the equivalent of a multivalent ion derived by the addition of two or more protons to a nitrogeneous base, or (b) an organic radical. Preferred promoters include sodium, zinc, nickel and cobalt organothiosulphates.Type: GrantFiled: April 12, 1985Date of Patent: November 3, 1987Assignee: Monsanto Europe, S.A.Inventors: Jean-Marc Delseth, Daniel E. Mauer, Philippe G. Moniotte
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Patent number: 4696962Abstract: A cationic polymer composition suitable for use as a flocculating agent and as a retention aid and dewatering agent in paper making consists of a mixture of(a) a hydrophilic cationic polymer of(a.sub.1) acrylamide and/or methacrylamide and(a.sub.2) dialkylamino-C.sub.2-3 alkylene-(meth)acrylamidethe molar quantity of cationic monomer units (a.sub.2) being from 0.2 to 9 mol % of the total(b) an anionic surfactant(c) a water-immiscible oil in which the polymer (a) is insoluble, andoptionally (d) a lipophilic non-ionic surfactant,optionally (e) waterand optionally (f) an oil-miscible polar solvent.The compositions may be prepared by water-in-oil emulsion copolymerization and are readily diluted with water.Type: GrantFiled: July 24, 1984Date of Patent: September 29, 1987Assignee: Sandoz Ltd.Inventors: Bernard Danner, James R. Ruynon
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Patent number: 4681906Abstract: Polyphenylene ether resin compositions exhibiting improved melt behavior without degradation of other thermal properties are provided by combining a polyphenylene ether polymer and an alkyl or aralkyl sulfonate of an alkali metal, where the alkyl or aralkyl radical has 5 to 25 carbon atoms.Type: GrantFiled: November 1, 1985Date of Patent: July 21, 1987Assignee: General Electric CompanyInventors: Visvaldis Abolins, Thomas A. Morelli
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Patent number: 4665113Abstract: The joint agglomeration of PTFE and metal-containing fillers belonging to the group comprising copper, tin and alloys thereof with one another and with other metals is improved if an alkylsulfate or an alkanesulfonate having 10 to 18 carbon atoms is added to the liquid agglomeration medium.Type: GrantFiled: April 10, 1986Date of Patent: May 12, 1987Assignee: Hoechst AktiengesellschaftInventor: Karl Eberl
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Patent number: 4661543Abstract: The present invention relates to phthalimide compounds of the formula (I) ##STR1## wherein X denotes H or halogen, for example chlorine or bromine,a and b independently of one another denote 0 or 1 andR denotes a C.sub.1 -C.sub.4 -alkyl radical,which, in combination with alkali metal salts, are suitable as flameproofing agent combinations for thermoplastic, branched, aromatic polycarbonates, and the preparation of these compounds.Type: GrantFiled: October 17, 1984Date of Patent: April 28, 1987Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Klaus Kircher
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Patent number: 4657955Abstract: The present invention relates to new phthalimides of the formula (I) ##STR1## wherein n is an integer of from 1 to 12, preferably 1 to 4 and especially 1 to 2 andR is H or F,and their preparation, these phthalimides being suitable, in combination with alkali metal salts, as flameproofing agent combinations for thermoplastic, branched, aromatic polycarbonates.Type: GrantFiled: June 11, 1986Date of Patent: April 14, 1987Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Klaus Kircher
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Patent number: 4649168Abstract: The present invention relates to a process for the preparation of flame-resistant polycarbonate moulding compositions, which is characterized in that, besides the addition of alkali metal salts, there is incorporation of tetrafluoroethylene polymers as an intimate mixture with halogen-free graft polymers, these intimate mixtures being prepared by coagulation of the appropriate emulsion mixtures, and to the polycarbonate moulding compositions obtainable by the process according to the invention.Type: GrantFiled: November 13, 1985Date of Patent: March 10, 1987Assignee: Bayer AktiengesellschaftInventors: Hans-Jurgen Kress, Ludwig Bottenbruch, Mark Witman, Klaus Kircher, Christian Lindner, Karl-Heinz Ott