Aryl-oh Patents (Class 524/194)
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Patent number: 9908989Abstract: A composition for recyclate verification is produced by adding a predetermined quantity of one or more verification compounds to a base resin. Each of the verification compounds is thermally stable over a range of temperatures that includes the maximum processing temperature of the base resin but is less than the degradation temperature of the base resin. In some embodiments, a thermoplastic material provided for verification as a recyclate is analyzed to detect the presence (and, optionally, the loading level) of one or more verification compounds associated with the base resin of the thermoplastic material. In some embodiments, a computer-implemented method for recyclate verification is performed using a computer program product. In some embodiments, a thermoplastic material verified as a recyclate is heated to drive off the verification compound(s), then a known quantity of the verification compound(s) is added to the recyclate, which is then blended with virgin base resin material.Type: GrantFiled: April 9, 2015Date of Patent: March 6, 2018Assignee: International Business Machines CorporationInventors: Travis R. Hebig, Joseph Kuczynski, Steven R. Nickel
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Patent number: 9156964Abstract: A difunctional weather-resistant stabilizer having one terminal semicarbazide functional moiety and one terminal hindered phenol functional moiety is disclosed. The difunctional weather-resistant stabilizer is represented by: wherein R1 represents a C1-C8 alkyl group; each R2 is independently selected from the group consisting of hydrogen and a C1-C8 alkyl group; and Z is a divalent organic group.Type: GrantFiled: April 30, 2014Date of Patent: October 13, 2015Assignees: FDC LEES CHEMICAL INDUSTRY CO., LTD., NEW NETWORK LIMITEDInventors: Eric Lee, Ching-Yie Su, Nai-Mou Hsu
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Patent number: 8883881Abstract: The invention relates to absorptive, crosslinked polymers which are based on partly neutralized, monoethylenically unsaturated monomers carrying acid groups wherein the absorptive crosslinked polymer may be coated with a thermoplastic polymer, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which has a high gel bed permeability and high centrifuge retention capacity.Type: GrantFiled: July 11, 2013Date of Patent: November 11, 2014Assignee: Evonik CorporationInventors: Scott J. Smith, Stan McIntosh, Heinz Bremus, Frank Loeker
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Patent number: 8815003Abstract: Crosslinking systems suitable for use in a polymer melt composition wherein the polymer melt composition comprises a hydroxyl polymer; polymeric structures made from such polymer melt compositions; and processes/methods related thereto are provided.Type: GrantFiled: November 20, 2013Date of Patent: August 26, 2014Assignee: The Procter & Gamble CompanyInventors: Stephen Wayne Heinzman, Linda Evers Smith, Gregory Charles Gordon, Larry Neil Mackey, John Gerhard Michael, Mark Ryan Richards
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Patent number: 7691929Abstract: The present invention is directed a method of flame retarding a polymeric substrate using a specific group of azo and peroxide derivatives as flame retardants, to flame retardant compositions as well as to novel azo compounds usable as flame retarding compounds.Type: GrantFiled: January 9, 2009Date of Patent: April 6, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Nicolas Ronan, Carl-Eric Magnus Wilën
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Patent number: 6794446Abstract: An object of the present invention is to provide a water-borne urethane resin composition for forming a microporous layer, which is suited for use in a fibrous material substrate, especially an artificial leather, and which has well-defined heat-sensitive coagulation properties and is capable of being uniformly filled into a fibrous material substrate without causing migration, forming a micrporous layer after drying and imparting a feel equivalent to that obtained in a solvent-based urethane resin composition, i.e., an elastic and genuine feel, by impregnating or coating the fibrous material substrate with the water-borne urethane resin composition; a method of producing a fibrous sheet-like composite using the water-borne urethane resin composition; and an artificial leather obtained by the method. The water-borne urethane resin composition of the present invention comprises (1) a water-borne urethane resin having a heat-sensitive coagulation temperature of 40 to 90° C.Type: GrantFiled: July 30, 2001Date of Patent: September 21, 2004Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Shingo Takeda, Hideyuki Takeuchi, Eiji Satake, Toshifumi Tamaki
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Patent number: 6777502Abstract: Coupled polymers are prepared by a process comprising heating an admixture containing (1) at least one polyolefin comprising ethylene and optionally at least one comonomer and (2) a coupling amount at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide) for a period sufficient for decomposition of at least 80 weight percent of the poly(sulfonyl azide) and sufficient to result in a coupled polymer; particularly where the polyolefin is the product of polymerization of ethylene and optionally at least one other alpha-olefin in the presence of a single site catalyst.Type: GrantFiled: January 21, 2003Date of Patent: August 17, 2004Assignee: Dow Global Technologies Inc.Inventors: Thoi H. Ho, Wendy D. Hoenig, Che-l Kao, Michael E. Rowland, Clark H. Cummins, Michael J. Mullins, H. Craig Silvis
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Publication number: 20040094859Abstract: Polyisocyanurate systems, pultrusion of those systems to produce reinforced polyisocyanurate matrix composites, and to composites produced thereby. The polyisocyanurate systems include a polyol component, an optional chain extender, and an isocyanate. The polyisocyanurate systems have extended initiation times of about 5 minutes to about 30 minutes at room temperature, and can be snap cured.Type: ApplicationFiled: November 17, 2003Publication date: May 20, 2004Inventors: Evan H. Cheolas, Berend Eling, Ravi R. Joshi, Alan McClelland, Ajay Padsalgikar, Andreas H. Rothacker
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Patent number: 6696233Abstract: The present invention provides a silver halide photographic photosensitive material in which a silver halide photosensitive layer is disposed on a transparent polyethylene terephthalate (PET) film into which an ultraviolet light absorber has been kneaded, wherein the ultraviolet light absorber is at least one kind of ultraviolet light absorber characterized in that (i) a loss of mass is not greater than 10% when heated to 300° C. at a heating rate of 10° C./minute in a nitrogen gas atmosphere, and/or (ii) a difference between a b-value of a sheet having a thickness of 1.5 mm formed after heating for 1 minute at 300° C., a PET resin including an amount of 0.4% by mass of the ultraviolet light absorber and having a water content of not greater than 50 ppm, and a b-value of a sheet having a thickness of 1.5 mm formed after heating the PET resin for 8 minutes at 300° C., is not greater than 3.0.Type: GrantFiled: December 18, 2001Date of Patent: February 24, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Tatsuya Nomura, Takanori Sato, Hideki Takaki
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Patent number: 6541547Abstract: Polyolefin mouldings which have excellent stability on permanent contact with extracting media comprise, as stabilizers, a selected mixture comprising an organic phosphite or phosphonite and a specially selected group of sterically hindered phenols or a certain group of sterically hindered amines. In addition, a selected three-component mixture comprising a phosphite or phosphonite, a phenolic antioxidant and a certain group of sterically hindered amines is particularly suitable as stabilizer for polyolefin moldings which are in permanent contact with extracting media.Type: GrantFiled: September 9, 1996Date of Patent: April 1, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Thomas Schmutz, Erich Kramer, Hans Zweifel, Bruno Rotzinger
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Patent number: 6528136Abstract: The invention includes a process of preparing a coupled polymer comprising heating an admixture containing (1) at least one polyolefin comprising ethylene and optionally at least one comonomer which is selected from alpha olefins having at least 3 carbon atoms, dienes and combinations thereof said polyolefin having a molecular weight distribution of less than or equal to about 3 and (2) a coupling amount at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide) for a period sufficient for decomposition of at least about 80 weight percent of the poly(sulfonyl azide) and sufficient to result in a coupled polymer; particularly where the polyolefin is the product of polymerization of ethylene and optionally at least one other alpha-olefin in the presence of a single site catalyst (transition metal like Va or Cr, metallocene or constrained geometry). The amount of poly(sulfonyl azide) is preferably from about 0.01 to about 5 weight percent of the polyolefin.Type: GrantFiled: August 26, 1998Date of Patent: March 4, 2003Assignee: Dow Global Technologies Inc.Inventors: Thoi H. Ho, Wendy D. Hoenig, Che-I Kao, Michael E. Rowland, Clark H. Cummins, Michael J. Mullins, H. Craig Silvis
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Patent number: 6521306Abstract: The invention includes a process of preparing a coupled polymer characterized by heating an admixture containing (1) at least one ethylene polymer or blend of ethylene polymers having a density of at least about 0.89 g/mL and less than about 0.935 g/mL and a comonomer content between about 0.5 and 50 weight percent of an alpha olefin having greater than 2 and less than 20 carbon atoms per molecule and (2) a coupling amount of at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide) for a period sufficient for decomposition of at least about 80 weight percent of the poly(sulfonyl azide) and sufficient to result in a coupled polymer. The amount of poly(sulfonyl azide) is preferably from about 0.01 to about 5 weight percent of polymers in the admixture. The invention also includes any composition which is the product of any of the processes of the invention and articles made from those compositions, particularly any film of any composition of the invention.Type: GrantFiled: August 5, 1998Date of Patent: February 18, 2003Assignee: Dow Global Technologies Inc.Inventors: Wendy D. Hoenig, Teresa Karjala, Li-Min Tau, Clark H. Cummins, Michael J. Mullins, H. Craig Silvis, Thoi H. Ho
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Patent number: 6515055Abstract: Provided is a rubber composition comprising 100 parts by weight of a rubber component comprising at least one selected from the group consisting of natural rubber and synthetic rubbers and 0.Type: GrantFiled: November 17, 2000Date of Patent: February 4, 2003Assignees: Bridgestone Corporation, Otsuka Chemical Co., Ltd.Inventors: Daisuke Nohara, Jingo Shirasaka, Akinori Oka, Ken Sonogi, Hiroaki Tokuda
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Patent number: 6469088Abstract: Improved stabilizer compositions which impart superior oxidative stability to polyolefins used for wire and cable insulation are provided. The stabilizer compositions are a mixture of a diacyl hydrazine compound and an alkylenebisacylamide compound. The stabilizer combinations are particularly useful for propylene polymer insulation compositions used in filled cable constructions. Polyolefin compositions stabilized with the stabilizer combinations of the invention and jacketed constructions utilizing same are also disclosed.Type: GrantFiled: November 2, 2000Date of Patent: October 22, 2002Assignee: Equistar Chemicals, LPInventor: Chun D. Lee
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Patent number: 6409937Abstract: The invention relates to a process for the preparation of melt processable liquid crystalline terpolyesters of the general formula I by the in situ acetylation of a monomer selected from (4-hydroxyphenyl) acetic acid/ 3(4-hydroxyphenyl)propionic acid and hydroquinone/4,4′-biphenol/2,6-naphthylene diol followed by acidolysis polycondensation with or without a solvent and a catalyst, under reduced pressure for the efficient removal of acetic acid to effect higher molecular weight formation. Post polymerisation is effected at higher temperatures below the decomposition temperature purification by soxhlet extraction using solvent mixtures selected from acetone-alcohol, acetone-methylethyl ketone.Type: GrantFiled: March 28, 2000Date of Patent: June 25, 2002Assignees: Council of Scientific & Industrial Research, Department of Science and TechnologyInventors: Vadakkethonippurathu Sivankutty Nair Prasad, Chennakkattu Krishna Sadasivan Pillai, Marayil Ravindranathan
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Publication number: 20020045690Abstract: The invention relates to polyisocyanurate systems, pultrusion of those systems to produce reinforced polyisocyanurate matrix composites, and to composites produced thereby. The polyisocyanurate systems include a polyol component, an optional chain extender, and an isocyanate. The polyisocyanurate systems have extended initiation times of about 5 minutes to about 30 minutes at room temperature, and can be snap cured.Type: ApplicationFiled: May 16, 2001Publication date: April 18, 2002Inventors: Evan H. Cheolas, Berend Eling, Ravi R. Joshi
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Publication number: 20010041760Abstract: A process for producing a succinimide resin composition is provided which comprises reacting a maleic anhydride-olefin type copolymer constituted of 40-60 mol % of maleic anhydride units, 60-40 mol % of olefin units, and 0-20 mol % of a copolymerizable monomer units with one or more amine compounds for imide formation in the presence of a second polymer other than the succinimide resin. This process improves the productivity by lowering the torque in the extrusion reaction, giving a succinimide copolymer resin composition having low yellowness and high transparency with high production efficiency.Type: ApplicationFiled: April 16, 2001Publication date: November 15, 2001Inventors: Takeshi Harunari, Yoshiki Uchida, Toru Doi
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Patent number: 6159649Abstract: The use of an azo pigment of the formula (1) ##STR1## as a colorant in electrophotographic toners, electrophotographic developers, powders and powder coatings, and electret materials, wherein said azo pigment is prepared in the presence of 20 to 50% by weight of an auxiliary selected from the group consisting of a rosin, a salt of a rosin, an abietic acid, and a salt of an abietic acid, wherein said weight is based on the overall weight of the azo pigment including said auxiliary, and wherein the azo pigment has a specific surface area of more than 70 m.sup.2 /g and the azo pigment particles comprising the azo pigment have a length-to-width ratio of on average less than 2.8:1 and a mean particle size d.sub.50 of less than 130 nm.Type: GrantFiled: September 18, 1998Date of Patent: December 12, 2000Assignee: Clariant GmbHInventors: Hans-Tobias Macholdt, Dieter Baumgart, Rudiger Baur
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Patent number: 6143860Abstract: A polymer composition made by combining a polyketone polymer and a phenolic alkylene dicarboxylate of the general formula: ##STR1## each R.sup.1 independently is hydrogen or alkyl with 1-6 carbon atoms, each R.sup.2 independently is alkyl with 1-6 carbon atoms,each m is an integer of 0-4, andn is an integer of 2-12; anda process for preparing these compositions.Type: GrantFiled: September 29, 1998Date of Patent: November 7, 2000Assignee: Shell Oil CompanyInventors: Abraham Adriaan Smaardijk, Hendrik De Wit
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Patent number: 5990259Abstract: Polymer composition made by combining a polyketone polymer and a monophenolic compound of the general formula: ##STR1## R.sup.1 and R.sup.2, independently, are hydrogen or alkyl groups with 1-6 carbon atoms,Y is an organic group from 3 up to 15 carbon atoms.Type: GrantFiled: September 29, 1998Date of Patent: November 23, 1999Assignee: Shell Oil CompanyInventors: Abraham Adriaan Smaardijk, Hendrik De Wit
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Patent number: 5880183Abstract: A composition of a hydroxyl functional polymer, an acetate functional polymer and a carboxyl functional polymer, which are crosslinked by a polyfunctional aziridine. Preferably, PVOH, polyvinylacetate and a carboxylated styrene/butadiene are used as the polymers. The aziridine can be held separate from the polymers prior to crosslinking. The composition is useful as a wood adhesive or coating composition.Type: GrantFiled: November 24, 1997Date of Patent: March 9, 1999Inventor: Siew Puat Yeo
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Patent number: 5705549Abstract: A rubber composition comprises a particular copolymer containing isobutylene unit, a paramethylstyrene unit and a parabromomethylstyrene unit; natural rubber and/or diene synthetic rubber; carbon black; and at least one hydrazide compound, and has a low value of tan .delta. at 60.degree. C. with maintaining tan .delta. at 0.degree. C. at a high level.Type: GrantFiled: April 15, 1996Date of Patent: January 6, 1998Assignee: Bridgestone CorporationInventor: Masahiro Hojo
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Patent number: 5534569Abstract: Heat generation of a rubber composition can be lowered by incorporating to the composition a compound of the formula, (I), (II) or (III), ##STR1## where A is an aromatic group, hydantoin ring or C.sub.0-18 straight chain hydrocarbon group, B is an aromatic group, X is hydroxy or amino, Y is pyridyl or hydrozino.Type: GrantFiled: March 8, 1995Date of Patent: July 9, 1996Assignee: Bridgestone CorporationInventor: Akiko Etoh
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Patent number: 5216054Abstract: A polymer composition comprising resin components comprising (a) 5-95 weight % of a polyamide resin, and (b) 5-95 weight % of polyolefin + unsaturated carboxylic acid-modified polyolefin, and (c) additives comprising the following compounds in amounts per 100 parts by weight of the total composition: (1) 0.1-2 parts by weight of a substituted hydrazine: (2) 0.05-2 parts by weight of a hindered phenol compound; (3) 0.05-0.5 parts by weight of a phosphite or phosphonite; and (4) 0.15-1 parts by weight of a thiodipropionate.Type: GrantFiled: February 27, 1992Date of Patent: June 1, 1993Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Kunio Iwanami, Kissho Kitano, Yukihiko Yagi, Takashi Mikami
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Patent number: 5194456Abstract: The novel compound of the formula ##STR1## has been found to be useful as a UV absorber. A novel PMMA material has incorporated therein a UV absorbing amount of the novel UV absorber. Intraocular lenses and contact lenses are produced from PMMA having incorporated therein a UV absorbing amount of the novel UV absorber.Eyeglasses are produced having lenses of a polycarbonate material which has incorporated therein a UV absorbing amount of the novel UV absorbed.Type: GrantFiled: May 22, 1990Date of Patent: March 16, 1993Assignee: Ioptex Research, Inc.Inventor: Amitava Gupta
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Patent number: 5175200Abstract: The present invention provides: a novel poly(arylene sulfide) (PAS) composition having an increased comparative tracking index (CTI) rating; a novel method wherein the inventive composition is formed and molded to produce a useful article; a novel article produced by the inventive molding method; a novel method wherein the inventive composition is formed and used to encapsulate an article; and a novel encapsulated article produced by the inventive encapsulation method. The inventive PAS composition comprises: poly(arylene sulfide) resin; talc; and an amount of hindered phenol sufficient to increase the composition's CTI rating.Type: GrantFiled: November 6, 1991Date of Patent: December 29, 1992Assignee: Phillips Petroleum CompanyInventor: Nathaniel Harry, Sr.
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Patent number: 5032632Abstract: A composition of a copolymer of ethylene and vinyl alcohol, 0.01 to 0.5 weight percent of a monovalent or divalent metal salt of an aliphatic carboxylic acid having 3 to 9 carbon atoms and 0.05 to 0.5 weight percent of a hindered phenolic antioxidant exhibits improved stability toward oxidative gel formation at elevated temperatures.Type: GrantFiled: May 15, 1990Date of Patent: July 16, 1991Assignee: E. I. du Pont de Nemours and CompanyInventor: Ronald L. Saxton
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Patent number: 4992499Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of a stabilizing amount of a combination of a phenolic compound and an aromatic amine.Type: GrantFiled: November 30, 1989Date of Patent: February 12, 1991Assignee: Shell Oil CompanyInventors: Johannes L. M. Syrier, Hendrik Van De Weg, Robert Q. Kluttz
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Patent number: 4960808Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of certain phenolic compounds.Type: GrantFiled: March 30, 1988Date of Patent: October 2, 1990Assignee: Shell Oil CompanyInventor: Andre Schmitter
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Patent number: 4954548Abstract: Compositions comprising linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against degradation caused by exposure to UV light by the inclusion therein of an aromatic diamine and a certain type of carbon black.Type: GrantFiled: April 27, 1989Date of Patent: September 4, 1990Assignee: Shell Oil CompanyInventor: George B. Klingensmith
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Patent number: 4699939Abstract: Compounds of formula I ##STR1## wherein R.sub.1, R.sub.2 and A are essentially hydrocarbyl or substituted hydrocarbyl groups with at least one of R.sub.1 and R.sub.2 being cyclohexyl, n is 0, 1 or 2, m is an integer of 1 to 4 and X is oxygen or --N(R.sub.3)-- wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl.Type: GrantFiled: October 8, 1986Date of Patent: October 13, 1987Assignee: Ciba-Geigy CorporationInventors: Ivan Orban, Hans-Rudolf Meier, Paul Dubs, Samuel Evans, Peter Hofmann
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Patent number: 4536527Abstract: There is provided an improved molding resin capable of being molded into an article exhibiting reduced tendency to corrode a copper surface when the molded resin and the copper surface are placed in spaced relationship in a common unventilated atmosphere at elevated temperatures, as measured by the Bell Telephone Laboratories Copper Corrosion Test at temperatures within the range of from 150.degree. to 175.degree. C., wherein the molding resin comprises the combination of (a) a butyleneterephthalate polyester comprising a brominated copolyester as a polymeric flame retardant comprising aromatic halogen groups in a flame retardant amount, and (b) an alkylhydroxyphenylalkanoyl-hydrazine in an amount that is within the range of from 0.05 to 0.3% by weight.Type: GrantFiled: May 7, 1984Date of Patent: August 20, 1985Assignee: Celanese CorporationInventors: Wilfred L. Shearer, Stephen M. Sinker, Richard A. Wolf
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Patent number: 4447571Abstract: A process for providing water based anionic polyurethanes having improved thermal oxidation color stability. Water dispersed amine salts of anionic prepolymers prepared from the reaction of polyhydroxy compounds and dihydroxy carboxylic acids with diisocyanates are chain-extended with hydrazine or hydrazide and thereafter optionally with a diamine, when cured at temperatures in excess of 150.degree. C., form polyurethane products having substantially no discoloration and good mechanical properties. Alternately, the hydrazide may be employed as an additive rather than as a chain-extender. The process is particularly useful when employing cross-linking agents which react only at high temperatures.Type: GrantFiled: October 15, 1981Date of Patent: May 8, 1984Assignee: Witco Chemical CorporationInventors: Shmuel Dabi, Peter Loewrigkeit
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Patent number: 4334932Abstract: Pigment formulations which contain(1) 10-90% by weight, based on the whole formulation, of a pigment mixture of(a) 99.5-90 mol %, based on the pigment mixture, of at least one monoazo pigment of the general formulaA--N=N--Band(b) 0.5-10 mol %, based on the pigment mixture, of at least one monoazo pigment of the formula(A'-N=N-B'--(X).sub.mcharacterized by the presence of at least one --COOH, --SO.sub.3 H, metal carboxylate or metal sulfonate group per pigment molecule, and(2) 90-10% by weight, based on the whole preparation, of a polyacrylate resin containing carboxylic acid groups.The novel pigment formulations are outstandingly suitable for pigmenting aqueous, alcoholic and aqueous-alcoholic printing ink systems and colored lacquer systems and are distinguished in particularlby good shelf life.The substituents A, B, A', B', X and m are as defined in claim 1.Type: GrantFiled: April 6, 1981Date of Patent: June 15, 1982Assignee: Ciba-Geigy CorporationInventor: Armand Roueche