N=c=x Group Wherein X Is A Chalcogen, E.g., Isocyanate, Etc. Patents (Class 524/196)
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Publication number: 20090011361Abstract: Novel, poison-blocking compositions and methods of using those compositions to form poison-blocking layers are provided. The compositions comprise a typical composition used in microlithographic processes, but with a poison-blocking additive included in that composition. The preferred additive is a compound comprising one or more blocked isocyanates. Upon heating to certain temperatures, the blocking group is released from the isocyanate, leaving behind a moiety that is highly reactive with the poisonous amines generated by typical dielectric layers.Type: ApplicationFiled: March 6, 2008Publication date: January 8, 2009Inventor: Marc W. Weimer
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Publication number: 20080300347Abstract: The invention relates to an adhesive formulation for the treatment of reinforcing layers which are provided for the production of reinforced polymer products, the adhesive formulation containing dissolved epoxide.Type: ApplicationFiled: October 26, 2006Publication date: December 4, 2008Applicant: EMS-CHEMIE AGInventors: Gunter Kurz, Manuel Senn
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Patent number: 7456233Abstract: An adhesive formulation comprising at least a reinforcing phase, a liquid phase and an adsorbent phase. The adsorbent phase, in particle form, has a surface coating which renders the adsorbent phase non-interactive and non-reactive with at least the reinforcing phase and liquid phase.Type: GrantFiled: February 16, 2005Date of Patent: November 25, 2008Assignee: Nordson CorporationInventor: Laurence B. Saidman
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Publication number: 20080234070Abstract: A golf ball including a core; an outer cover layer; and an inner cover layer disposed between the core and outer cover layer, the inner cover layer being formed from a polymer blend including a microgel having a Tg of 20° C. or greater formed from a monomer, a co-monomer, and an initiator; and a thermoplastic material.Type: ApplicationFiled: March 23, 2007Publication date: September 25, 2008Inventors: Brian Comeau, Murali Rajagopalan, Michael J. Sullivan
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Publication number: 20080227897Abstract: One embodiment of the invention includes a product including a coating comprising (a) a primary resin and a blocked isocyanate, and (b) at least one bio-diesel fuel degradation product neutralizing material.Type: ApplicationFiled: March 10, 2008Publication date: September 18, 2008Applicant: Magni Industries, Inc.Inventors: Paul Badyrka, Thomas T. Haig, Warren E. Knape, Gregory Lee Tarrance
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Publication number: 20080171818Abstract: A treated pigment comprising: (a) an inorganic pigment; (b) an organic compound comprises a fluoroalkyl group and a hydrocarbon group and having the structure: RH-L-RF, wherein RF is a fluorochemical component containing at least one Zerewitinoff hydrogen; RH is an aliphatic group of 1-30 carbons, cycloaliphatic group of 3-30 carbons, an aromatic group of 6-30 carbons, or a group having the structure: R?—(OCH2CHR?)x?—(OCH2CH2)y?—O—, wherein R? is H or an aliphatic group of 1-20 carbons, R? is H or methyl; and x? and y? are the same or different integers ranging from 0-20 except that the sum of x? and y? is at least 1 when R? is H; and L is selected from the group CO, isocyanate, and a mixture of polyisocyanates containing at least three isocyanate groups per RH-L-RF structure. Plastic articles containing a pigment and the organic compound have improved cleanability with all the other needed properties and without the negative property of chaulking.Type: ApplicationFiled: March 16, 2006Publication date: July 17, 2008Inventor: Donald Douglas May
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Patent number: 7396395Abstract: A composition of a water-repellent agent has a solvent and a solute. The solvent is water. The solute is dissolved in water and has isocyanate-acryl, non-ionic fluoro-acryl, 4,4-dipheylmethane diisocyanate, zinc acetate and polyethylene wax. Isocyanate-acryl has a concentration in a range of 10˜40 gram in per liter of the water-repellent agent (i.e. 10˜40%). Non-ionic fluoroacryl has a concentration in a range of 80˜150% t. 4,4-dipheylmethane diisocyanate has a concentration in a range of 5˜12%. Zinc acetate has a concentration in a range of 1˜20%. Polyethylene wax emulsion has a concentration in a range of 1˜40%. Therefore, a fabric treated with the present invention has good waterproof ability, widely enhanced color fastness in light and improved tear-resistance strength at the same time.Type: GrantFiled: May 8, 2007Date of Patent: July 8, 2008Assignee: Everest Textile Co., Ltd.Inventors: Min-Tze Chen, Pi-Hsun Chang, I-Ling Cheng, Wen-Hsin Lin
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Publication number: 20080143083Abstract: An article is formed in a mold having a mold cavity, has a periphery, and defines a score line having a tensile heal strength of less than 200 ppi along the score line. The article includes a cured urethane composition including the reaction product of an isocyanate component and a resin composition. The cured urethane composition is used in a method of forming the article. The method includes the steps of determining a theoretical tensile heal strength along the score line and applying the isocyanate component into the mold cavity in response to the determining of the theoretical tensile heal strength. The method also includes the steps of applying the resin composition into the mold cavity, reacting the isocyanate component and the resin composition to form a urethane composition, curing the urethane composition, and de-molding the article from the mold cavity.Type: ApplicationFiled: November 9, 2007Publication date: June 19, 2008Inventor: ROBERT B. STEARNS
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Publication number: 20080125525Abstract: Provided is a thioether-functional, oligomeric polythiol having pendant hydroxyl functional groups, prepared by reacting together: (a) a compound having at least two thiol functional groups; and (b) a hydroxyl functional compound having triple bond functionality. Also provided are optical articles prepared from the reaction product of: (A) a reactive compound having functional groups that are reactive with active hydrogens; (B) a thioether-functional, oligomeric polythiol; and, optionally, (C) a compound different from (B) containing active hydrogens.Type: ApplicationFiled: May 4, 2007Publication date: May 29, 2008Applicant: PPG INDUSTRIES OHIO, INC.Inventor: Nina V. Bojkova
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Patent number: 7368494Abstract: The present invention provides an emulsion composition for vibration damping materials which is capable of giving water-based vibration damping materials exhibiting very satisfactory thermal drying characteristics and vibration damping properties through improved dispersibility and stability and an emulsion composition for chipping-resistant materials which is capable of giving water-based chipping-resistant materials exhibiting satisfactory thermal drying characteristics and chipping-resistant properties. It also is directed to an emulsion composition for vibration damping materials which comprises an emulsion obtained by polymerizing a monomer composition containing an unsaturated carboxylic acid monomer as an essential component and a crosslinking agent.Type: GrantFiled: October 18, 2002Date of Patent: May 6, 2008Assignee: Nippon Shokubai Co., Ltd.Inventors: Shigeyasu Morihiro, Yukihiro Miyawaki
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Patent number: 7351476Abstract: The present invention aims to give a two package curing type polyurethane coating composition which can form a film having soft, wet and dry feelings simultaneously and which maintains general properties such as designing property, film strength, pot life, resistance to scratching and discoloration, resistance to stains with fats and oils and the like, and to provide a coated article with the coating composition. The two package curing type polyurethane coating composition comprises a resin solution containing an acrylic polyol and a curing agent solution containing a polyisocyanate. The resin solution contains urethane resin beads (A) in the amount of 25 to 50 parts by weight and an organic matting agent (B) in the amount of 3 to 10 parts by weight, and the total of (A) and (B) is at least 30 parts by weight in 100 parts by weight of solid contents of the resin solution. And the equivalent ratio of OH groups/NCO groups of the acrylic polyol and the polyisocyanate is in the range of 4.5:1 to 1.5:1.Type: GrantFiled: November 4, 2004Date of Patent: April 1, 2008Assignees: Toyota Jidosha Kabushiki Kaisha, Nippon Bee Chemical Co., Ltd.Inventors: Kenji Kawazu, Mika Kai, Hirokazu Yoshida, Yasuhiro Nakano
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Patent number: 7334974Abstract: A composition for use as a self-locking agent is provided which comprises an aqueous dispersion of the following ingredients dissolved and dispersed in water: (a) a polyamide powder insoluble or slightly soluble in water, (b) an isocyanate compound, (c) a surfactant and (d) a water-soluble polyamide. The composition permits a polyamide resin layer of a smooth surface to be formed on a screw surface of a to-be-coated member. With use of the composition, it is possible to prevent slippage and sagging of the resin layer coated on the screw surface and improve the precision in resin coating processing.Type: GrantFiled: October 25, 2002Date of Patent: February 26, 2008Assignee: Three Bond Co. Ltd.Inventors: Satoshi Matsuo, Hidenori Kanazawa
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Patent number: 7094812Abstract: Disclosed are colorant compounds of the formula wherein R, R1, R2, R3, and R4 each, independently of the others, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and wherein R, R1, R2, R3, and R4 each can be joined to a phenyl moiety to form a ring, each R?a, R?b, and R?c, independently of the others, is a halogen atom, an alkyl group, an alkoxy group, a nitrile group, a nitro group, an amide group, or a sulfonamide group, z1, z2, and z3 each, independently of the others, is an integer of 0, 1, 2, 3, or 4, n is an integer representing the number of carbon atoms in each repeat alkylene oxide unit, x is an integer representing the number of repeat alkylene oxide units, D is an anion, and g is the charge on the anion, wherein said colorant has no more than one —OH, —SH, or primary or secondary amino group per molecule.Type: GrantFiled: April 24, 2003Date of Patent: August 22, 2006Assignee: Xerox CorporationsInventors: Jeffery H. Banning, Donald R. Titterington, Clifford R. King
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Patent number: 6849676Abstract: Inorganic salts are generated in the production process of metal salts, such as sulfonates, sulfates and phosphates. When such metal salts containing inorganic salts are added as an antistatic agent to a polymer for producing polyurethane fiber, the inorganic salts cause fiber breakage or pack choking in fiber extrusion process. In addition, such antistatic agents are highly hygroscopic and contain trace of water. When such an antistatic agent is added to the material for polymerizing polyurethane, the alcohol and water in the agent react with isocyanate to result in lowered degree of polymerization and generation of oligomer. Such polyurethane polymer is spun into fiber of low elongation and tenacity. The material for polyurethane elastic fibers of the present invention comprises a mixture of 5 to 95 weight percent of at least one of the above-mentioned antistatic agents and 95 to 5 weight percent of a isocyanate-free starting material for elastic fibers, and eliminates the above troubles.Type: GrantFiled: January 8, 1999Date of Patent: February 1, 2005Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Michihiro Shibano, Yoji Mizuhiro, Masayoshi Yamanaka
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Patent number: 6814882Abstract: A fabric coating composition with latent heat effects and a method for fabricating the same are provided. The composition at least includes 1 part of the polymer binder, the hydrophilic microcapsule aqueous solution and the thickener, wherein the hydrophilic microcapsule aqueous solution contains 1 to 40 parts of microcapsules and the weight percentage of the thickener is about between about 2% and 12% based on the weight of the microcapsules. The water percentage of the composition is about between about 30% and 70%. The method for fabricating the composition comprises mixing the polymer binder, the hydrophilic microcapsule aqueous solution and thickener together and then stirring the composition mixture until the viscosity of the composition exceeding 6000 cps. The solution is allowed to set for between about 6 minutes and 10 hours, prior to application in fabric coating.Type: GrantFiled: July 7, 2003Date of Patent: November 9, 2004Assignee: China Textile InstituteInventors: Yen-Hsi Lin, Chun-Hung Lin, Lien-Hua Chiu, Shu-Lan Yao, Cheng-Chu Lin
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Patent number: 6797746Abstract: An ultraviolet radiation curable organic ink composition, comprising 80% to 95% by weight of an epoxy-polyurethane-based ink; 0.5% to 8% by weight of an additive including a mixture of polyethylenic waxes and polythetrafluoroethylenic waxes; 1% to 8% by weight of a blocked aliphatic polyisocyanate catalyst; and an adhesion promoter primer including 0.15% to 3% by weight of a silane, which can be directly included in the ultraviolet radiation curable organic ink composition or independently applied to a substrate, in order that the blocked aliphatic polyisocyanate catalyst promote a polymerization reaction and a crosslinking reaction between the epoxy-polyurethane-based ink and the adhesion promoter, when heated to 160 to 200° C., forming an interpenetration network.Type: GrantFiled: August 9, 2001Date of Patent: September 28, 2004Assignee: Vidriera Monterrey, S.A. de C.V.Inventor: Rodrigo Cavazos-Gutierrez
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Patent number: 6766739Abstract: The invention provides an improved golf ball printing method which is capable of efficient printing control in the production of golf balls and provides a colorful or lustrous mark on the ball surface. The printing method uses a two-component reacting ink comprising a resin having a hydroxyl group, an isocyanate, a coloring agent containing a metal, and a &bgr;-diketone. The ink ensures pot life more than eight hours and does not need to replace with newly prepared ink all day long.Type: GrantFiled: December 21, 2001Date of Patent: July 27, 2004Assignee: Sumitomo Rubber Industries LimitedInventors: Kazuhiko Isogawa, Seiichiro Endo
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Patent number: 6767946Abstract: A water and oil repellent composition comprising a compound of the following formula (1) and a thermoplastic polymer, as essential components: where the symbols in the formula (1) have the following meanings: Rf: a C1-20 polyfluoroalkyl group, X: (CH2)m, wherein m is an integer of from 1 to 10, A, A1, A2: each independently, O, S or N(Z3), wherein Z3 is a hydrogen atom or an alkyl group, Z1: an octadecyl group, Z2: an alkyl group, or an alkyl group having at least one hydrogen atom substituted, W: a trivalent organic group, and a, b: each independently, 1 or 2, provided that a+b is 2 or 3.Type: GrantFiled: September 24, 2002Date of Patent: July 27, 2004Assignee: Asahi Glass Company, LimitedInventors: Toyomichi Shimada, Masako Tada, Takashige Maekawa
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Publication number: 20040072931Abstract: Use of a compound according to one of the formulae I to III 1Type: ApplicationFiled: June 20, 2003Publication date: April 15, 2004Inventors: Christoph Thiebes, Christian Fussel, Reinhard Halpaap, Beate Baumbach, Joachim Petzoldt, Karsten Danielmeier
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Patent number: 6706842Abstract: A glycol-organosilane composition and a process for producing the composition are disclosed. The composition comprises or is produced by combining (a) a glycol and (b) an organosilane. This composition is preferably substantially soluble in glycol and water. Also disclosed is a polyester composition and a process to produce the composition. The composition comprises repeat units derived from (a) a carbonyl compound or its oligomer, (b) a glycol, (c) a crosslinker, and (d) optionally a comonomer. The crosslinker can be the glycol-organosilane, a carbonyl compound containing 3 or more carboxyl groups, or an alcohol containing 3 or more hydroxyl groups. The comonomer is a dicarboxylic compound, a diol compound, or a carbonyl alcohol. The polyester composition can be used to increase the rate of polymerization, to increase pilling resistance and strength of polyester, to decrease crystallization rate and improve object forming process such as fibers and containers.Type: GrantFiled: February 6, 2003Date of Patent: March 16, 2004Inventor: Jiwen F. Duan
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Patent number: 6649706Abstract: A thixotroping agent comprising a reaction product of a isocyanto-containing compound and an amine. The isocyanto-containing compound comprises at least one of Ia) at least one isocyanate with at least one diisocyanate structural unit that has an unsaturated/aromatic or non-aromatic ring structure with 5-10 ring atoms and two isocyanate groups that are bound to the ring structure; Ib) at least one oligomer of the isocyanate Ia) with 2 to 10 isocyanate units; and Ic) at least one partially blocked isocyanate Ia) and/or at least one partially blocked oligomer Ib).Type: GrantFiled: November 14, 2001Date of Patent: November 18, 2003Assignee: BASF Coatings AGInventors: Ingrid Heid, Helmut Kleine Beckmann, Ulrike Röckrath, Hubert Baumgart
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Patent number: 6642291Abstract: A viscoelasticity improving agent for rubber obtained by reacting an alkyllithium compound with a free radical compound having an isocyanate group in the molecule thereof and existing stably at room temperature in the presence of oxygen and a rubber composition.Type: GrantFiled: May 18, 2001Date of Patent: November 4, 2003Assignee: The Yokohama Rubber Co., Ltd.Inventors: Keisuke Chino, Naoshi Miyashita, Makoto Ashiura, Tetsuji Kawazura
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Patent number: 6544445Abstract: A fire-resistant composite substrate for use in making structural openings fire-resistant, the substrate containing: (a) elastically compressible particles; (b) at least one heat-activated expanding agent; (c) at least one heat-activated binder; and (d) a diisocyanate adhesive.Type: GrantFiled: August 6, 1999Date of Patent: April 8, 2003Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Robert Graf, Maria-Elisabeth Kaiser
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Patent number: 6486239Abstract: This invention relates to a polyester based coating composition for anti-stain PCM outside panel and more particularly, to the polyester based coating composition for anti-stain PCM outside panel having the excellent combination of physical properties such as surface compactness, anti-contamination effect, acid resistance and self-cleaning effect, wherein the polyester based coating composition comprises: a) hydroxy unsaturated polyester resin and a melamine curing agent as main ingredients, b) sulfonic acid blocked with a secondary amine or epoxy resin, c) sulfonic acid blocked with a tertiary amine, d) an isocyanate compound blocked with malonate, e) a tin based curing catalyst, f) polyalkyl silicate, and g) an alkoxy compound; further, the polyester based coating composition for anti-stain PCM outside panel can demonstrate excellent properties of a film of paint such as appearance and workability even without the addition of any defoaming agent and leveling agent by adjusting the compatibility of both hydType: GrantFiled: December 28, 2000Date of Patent: November 26, 2002Assignee: Kumgang Korea Chemical Co., Ltd.Inventors: Joon Ho Lee, Jin Hyung Lee, Sung Uk Park, Chang Il Jin, Joo Lak Sohn
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Publication number: 20020123545Abstract: The present invention relates to polyurethane polyol compositions comprising the reaction product of a polyisocyanate, a polyol, and a Guerbet alcohol having at least 12 carbon atoms or a Guerbet alcohol mixture having an average of at least 12 carbon atoms. Preferred polyols are &agr;,&bgr; diols and &agr;,&ggr; diols. The polyurethane polyol compositions exhibit very low viscosity and are particularly useful in very low VOC coating compositions. The resulting cured coating provides surprisingly improved properties.Type: ApplicationFiled: December 12, 2001Publication date: September 5, 2002Inventors: Alexander Leo Yahkind, Robert Brian Feisel, Michael Todd Render, Dhruv Vrajlal Parekh
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Patent number: 6407194Abstract: A process for increasing the pill resistance of a polyester polymer wherein the polyester polymer is produced by polymerizing a polymerization mixture comprising (a) a carbonyl compound or an oligomer of the carbonyl compound and (b) a glycol. The process comprises contacting the polymerization mixture with a cross-linker comprising (RO)mSi(X)nZp, wherein: R is hydrogen, a hydrocarbon, or a hydrocarbon oxygen; X is a hydrocarbon or a hydrocarbon oxygen; Z is a hydrophilic group; m is 1 to 3; n is 1 to 3; and p is 1 to 30.Type: GrantFiled: July 17, 2001Date of Patent: June 18, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Jiwen F. Duan
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Patent number: 6403699Abstract: The invention relates to nonaqueous coatings containing a polyacrylate resin and a urea group-containing thixotropic agent and having improved surface properties. The polyacrylate resin is prepared by polymerizing (a) from 16 to 51% by weight of a hydroxyl group-containing ester of acrylic acid or methacrylic acid or of a mixture of such monomers; (b)from 32 to 84% by weight of an aliphatic or cycloaliphatic ester of acrylic acid or methacrylic acid which is different from (a) and has at least 4 carbon atoms in the alcohol radical or of a mixture of such monomers; (c) from 0 to 2% by weight of an ethylenically unsaturated carboxylic acid or of a mixture of ethylenically unsaturated carboxylic acids, and (d)from 0 to 30% by weight of an ethylenically unsaturated monomer which is different from (a), (b) and (c) or of a mixture of such monomers.Type: GrantFiled: September 28, 1995Date of Patent: June 11, 2002Assignee: BASF Coatings AGInventors: Ulrike Röckrath, Ulrich Poth
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Patent number: 6384097Abstract: An amine catalyst for production of a polyurethane and a polyisocyanurate is provided which comprises a quaternary ammonium compound represented by General Formula (1): where R1 to R6 are independently a linear or branched saturated hydrocarbon group of 1 to 4 carbon atoms; R7 and R8 are independently a linear or branched, saturated or unsaturated hydrocarbon group of 2 to 12 carbon atoms; n is a number of 0 to 3, provided that at n=0 any one of R1, R2 and R3, and R5 and/or R6 may be linked together to form a heterocycle, or at n=1, 2, or 3, R5 or R6 and R4 may be linked together to form a heterocycle; A is a carbonate group or an organic acid group; and X is number of 1 to 2. The catalyst has high activity in formation of polyurethane foams and polyisocyanurate foams, having less odor, and producing foams of high fire retardance, having high curability, high retarding effect, and low corrosiveness.Type: GrantFiled: August 27, 2001Date of Patent: May 7, 2002Assignee: Tosoh CorporationInventors: Katsumi Tokumoto, Yutaka Tamano, Shuichi Okuzono
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Patent number: 6384177Abstract: An amine catalyst for production of a polyurethane and a polyisocyanurate is provided which comprises a quaternary ammonium compound represented by General Formula (1): where R1 to R6 are independently a linear or branched saturated hydrocarbon group of 1 to 4 carbon atoms; R7 and R8 are independently a linear or branched, saturated or unsaturated hydrocarbon group of 2 to 12 carbon atoms; n is a number of 0 to 3, provided that at n=o any one of R1, R2 and R3, and R5 and/or R6 may be linked together to form a heterocycle, or at n=1, 2, or 3, R5 or R6 and R4 may be linked together to form a heterocycle; A is a carbonate group or an organic acid group; and X is number of 1 to 2. The catalyst has high activity in formation of polyurethane foams and polyisocyanurate foams, having less odor, and producing foams of high fire retardance, having high curability, high retarding effect, and low corrosiveness.Type: GrantFiled: August 27, 2001Date of Patent: May 7, 2002Assignee: Tosoh CorporationInventors: Katsumi Tokumoto, Yutaka Tamano, Shuichi Okuzono
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Publication number: 20020016391Abstract: A viscoelasticity improving agent for rubber obtained by reacting an alkyllithium compound with a free radical compound having an isocyanate group in the molecule thereof and existing stably at room temperature in the presence of oxygen and a rubber composition.Type: ApplicationFiled: May 18, 2001Publication date: February 7, 2002Applicant: THE YOKOHAMA RUBBER CO., LTD.Inventors: Keisuke Chino, Naoshi Miyashita, Makoto Ashiura, Tetsuji Kawazura
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Patent number: 6277907Abstract: A method is disclosed for stabilizing a thermoplastic resin, which may also contain carbon black and/or glass, wherein the method comprises adding to the resin a stabilizing amount of at least one sterically hindered phenol antioxidant, at least one secondary amine antioxidant and/or at least one N,N′-substituted oxamide antioxidant, and at least one thioether antioxidant.Type: GrantFiled: November 9, 1998Date of Patent: August 21, 2001Assignee: Uniroyal Chemical Company, Inc.Inventor: Michael E. Gelbin
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Patent number: 6187844Abstract: A plastic lens is formed using a plastic lens composition which contains, as its main components, a resin material having a urethane-based resin, and at least one kind of UV absorbent selected from the group comprising 2-(5-methyl-2-hydroxyphenyl) benzotriazole, 2-(5-t-butyl-2-hydroxyphenyl) benzotriazole, 2-(5-t-octyl-2-hydroxyphenyl) benzotriazole, 2-(3, 5-di-t-butyl-2-hydroxyphenyl)-5-chlorobenzotriazole, 2-(3-t-butyl-5-methyl-2-hydroxyphenyl)-5-chlorobenzotriazole, 2-(3, 5-di-t-amyl-2-hydroxyphenyl) benzotriazole, and 2-(3, 5-di-t-butyl-2-hydroxyphenyl) benzotriazole. The total amount of addition of the UV absorbants is preferably in the range of 0.02 to 2.0 wt % relative to 100 wt % of the resin material.Type: GrantFiled: February 10, 1999Date of Patent: February 13, 2001Assignee: Asahi Kogaku Kogyo Kabushiki KaishaInventor: Naoki Murata
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Patent number: 6150441Abstract: This invention provides a composition for double glazing use which satiskfies the requirement of both low moisture permeability and weather-resistant adhesiveness and also has rapid hardenability by addition type curing, can be produced by a line process and is able to be used as a one-pack sealant having excellent shelf stability and mechanical properties, and the composition for double glazing use of this invention comprises (A) a hydrocarbon polymer having at least one alkenyl group in its molecule and a molecular weight of 500 to 300,000, (B) a curing agent having at least two hydrosilyl groups in its molecule, (C) a hydrosilylation catalyst and (D) a tackifier as essential components. When the composition for double glazing use requires one-pack adhesive property, shelf stability improving agent (E) is further used in addition to the components (A) to (D). An isobutylene polymer is desirable as the component (A), and a polyorgano hydrogen siloxane as the component (B).Type: GrantFiled: July 8, 1997Date of Patent: November 21, 2000Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Makoto Chiba, Masashi Sakaguchi
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Patent number: 6130267Abstract: The invention provides a fire retardant composition comprising a dispersion of a solid fire retardant such as melamine, ammonium polyphosphate or guanidine carbonate in a liquid organic polyisocyanate which contains dispersed polymer particles. The preferred content of solid fire retardant is from 10 to 100% by weight and the preferred content of polymer particles is from 2 to 30% by weight. The compositions of the invention are suitable for the preparation of flexible and rigid polyurethane foams.Type: GrantFiled: July 13, 1992Date of Patent: October 10, 2000Assignee: Imperial Chemical Industries PLCInventors: Ernst Otto Dueber, Louis Muller
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Patent number: 6043300Abstract: A liquid, pourable 100% active rheological additive especially useful for thickening non-aqueous compositions is described. The additive, which exists in a pourable form at up to a 100% as a rheologically active composition, exhibits excellent thickening efficiency for systems including inks, epoxies, polyesters, paints, greases and other systems, including ease of dispersibility, without adversely affecting gloss. The additive may operate by both an associative and a reaction mechanism to provide rheological viscosity properties to such systems, and is also similarly useful for aqueous systems.Type: GrantFiled: February 13, 1998Date of Patent: March 28, 2000Assignee: Rheox, Inc.Inventor: Mahalingam Santhanam
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Patent number: 5863657Abstract: An adhesive for bonding together a first substrate made of vinylidene fluoride resin and a second substrate comprises an elastic fluorohydrocarbon resin, a polyisocyanate, and an organic solvent. This elastic fluorohydrocarbon resin is obtained by graft copolymerization of a fluorine-containing copolymer with a vinylidene fluoride monomer. This copolymer is prepared by copolymerizing at least one first fluorine-containing monomer with at least one unsaturated monomer that has peroxy bond. The adhesive itself is superior in durability, and bond strength between the first and second substrates is also superior.Type: GrantFiled: December 27, 1995Date of Patent: January 26, 1999Assignee: Central Glass Company, LimitedInventors: Chikashi Kawashima, Katunori Kawamura
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Patent number: 5852111Abstract: Disclosed is a polyisocyanate composition which comprises: (a) a hydrophilic polyisocyanate comprising at least one base polyisocyanate selected from an aliphatic and/or an alicyclic diisocyanate, and a polyisocyanate derived therefrom, and a nonionic hydrophilic group, bonded to the polyisocyanate, containing therein 5 to 50 repeating ethylene oxide units in terms of the average number of the units, wherein the hydrophilic group is present in an amount of from 2 to 50% by weight, based on the total weight of the base polyisocyanate and the hydrophilic group; and (b) 0.5 to 20% by weight, based on the total weight of components (a) and (b), of a substantially water-free ionic surfactant. The polyisocyanate composition exhibits not only excellent dispersibility in water, but also exhibits high stability in the form of an aqueous dispersion thereof, since a reaction between the terminal isocyanate groups and water is suppressed.Type: GrantFiled: October 10, 1997Date of Patent: December 22, 1998Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Shinichiro Watanabe, Ichiro Ibuki
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Patent number: 5804648Abstract: A TDI residue generated from the phosgenation of toluene diamine having an ortho-isomer content of less than 0.5% is used to produce a urethane-filled hydroxyl compound. The TDI residues useful in this invention must contain at least 10% monomeric TDI and have a total NCO content of at least 20%. These TDI residues are reacted with a monofunctional alcohol in an amount such that the equivalent ratio of isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. The resultant composition may then be dissolved in a polyhydroxyl compound to produce a urethane-filled polyhydroxyl compound. This urethane-filled polyhydroxyl compound may then be reacted with a polyisocyanate to produce a polyurethane.Type: GrantFiled: December 27, 1996Date of Patent: September 8, 1998Assignee: Bayer CorporationInventor: William E. Slack
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Patent number: 5753750Abstract: TDI residue-based urethane-filled isocyanate compositions are produced by reacting a TDI residue satisfying specified criteria with a monofunctional alcohol in amounts such that the equivalent ratio of isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. This reaction product is then dissolved in a diisocyanate or polyisocyanate. These TDI residue-based urethane-filled isocyanate compositions are particularly useful in the production of polyurethanes.Type: GrantFiled: December 27, 1996Date of Patent: May 19, 1998Assignee: Bayer CorporationInventors: William E. Slack, Jyothi S. Pisipati
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Patent number: 5753749Abstract: Urethane-filled compositions are produced by reacting a dicyclohexylmethane diisocyanate residue or a dicyclohexylmethane diisocyanate residue containing mixture with a monofunctional alcohol containing at least one ether group in an amount such that the equivalent ratio isocyanate groups to hydroxyl groups is from about 0.9:1 to about 1:0.9. The diisocyanate residue or residue-containing mixture must contain at least 20% by weight monomeric diisocyanate and have a total NCO content of at least 10%. The diisocyanate residue is produced by phosgenating dicyclohexylmethane diamine in which less than 20% polymeric diamine is present. The urethane filled compositions produced in this manner may then be dissolved in either a polyol or a polyisocyanate and subsequently used to produce polyurethanes in known manner.Type: GrantFiled: December 27, 1996Date of Patent: May 19, 1998Assignee: Bayer CorporationInventor: William E. Slack
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Patent number: 5739207Abstract: Urethane-filled polyisocyanates are produced by (a) reacting a hexamethylene diisocyanate-containing residue having less than 10% by weight monomeric hexamethylene diisocyanate and a total NCO content of at least 25% with an alcohol containing at least one ether linkage in an equivalent ratio of isocyanate to hydroxyl groups of from about 0.9:1 to about 1.0:0.9 and (b) dissolving the product of (a) in a polyisocyanate. These urethane-filled polyisocyanates are particularly useful in the production of polyurethanes.Type: GrantFiled: December 27, 1996Date of Patent: April 14, 1998Assignee: Bayer CorporationInventor: William E. Slack
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Patent number: 5696182Abstract: An ink comprising water, a water-soluble organic solvent, a coloring material and a water-soluble oligomer, wherein said water-soluble oligomer is a polymer comprising at least one of monomers represented by the formulae (I), (II) and (III):CH.sub.2 .dbd.C (R)-COO-(CH.sub.2 CH.sub.2 O).sub.m (CH.sub.2).sub.p H(I)CH.sub.2 .dbd.C(R)--COO--(CH.sub.2 CH.sub.2 O).sub.q --phenyl--(CH.sub.2).sub.r H (II)CH.sub.2 .dbd.C(X)--COO--R.sub.Type: GrantFiled: March 14, 1994Date of Patent: December 9, 1997Assignee: Canon Kabushiki KaishaInventors: Akio Kashiwazaki, Yuko Suga, Katsuhiro Shirota, Hiromichi Noguchi, Aya Takaide
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Patent number: 5594046Abstract: The invention relates to an intumescent one-component sealant based on polyurethane and containing an intumescent agent and a vitreous fusible filler. The intumescent agent and the vitreous filler have been pretreated by reaction with an isocyanate having a functionality of at least 2. The sealant is stable in storage and is an effective fire barrier in the event of fire.Type: GrantFiled: May 30, 1995Date of Patent: January 14, 1997Assignee: Bostik, Inc.Inventor: Roland Joachimi
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Patent number: 5530035Abstract: Closed cell polyurethane foams, useful as thermal insulation for refrigerators and the like, are prepared by blending a polyisocyanate, a polyol and a suspension of at least one solid alkaline reagent, preferably sodium hydroxide, in an inert carrier liquid having a suitable viscosity. Preferred carrier liquids include polyepoxides and polyoxyalkylenediamines. The alkaline reagent reacts with and removes the carbon dioxide employed as a blowing agent, thus decreasing the thermal conductivity of the foam.Type: GrantFiled: June 15, 1994Date of Patent: June 25, 1996Assignee: General Electric CompanyInventors: Monica A. Ferrero-Heredia, James Day, George L. Gaines, Jr.
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Patent number: 5508111Abstract: A polyurethane adhesive formed from (I) an NCO terminated prepolymer with excess of NCO and talc, and (II) a polyol, a urethane catalyst, talc and a minor amount of certain aryl or aromatic polyamines exhibits good sag and thixotropic properties and, also, exhibits good lap shear strength when cured between treatment-free substrates.Type: GrantFiled: March 5, 1993Date of Patent: April 16, 1996Assignee: GenCorpInventor: Arden E. Schmucker
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Patent number: 5446086Abstract: A polyoxymethylene composition which is remarkably improved in heat stability, little stains molds even in long-term continuous molding and little generates formaldehydic stench in molding, and which comprises a polyoxymethylene and, added thereto, 0.01 to 5% by weight of an antioxidant and 0.01 to 10% by weight of a melamine-formaldehyde polycondensate, each based on the polyoxymethylene, characterized in that the melamine-formaldehyde polycondensate used is one which is prepared mainly from melamine and formaldehyde and contains 2.0 to 10 moles of the melamine units on the average per mol of the melamine-formaldehyde polycondensate, wherein the mean mole number of hydrogen bonded to 3 moles of the amino groups contained in 1 mole of melamine is 3.0 moles or above.Type: GrantFiled: March 9, 1994Date of Patent: August 29, 1995Assignee: Polyplastics Co., Ltd.Inventors: Noriyuki Sugiyama, Hiroyuki Miyaji, Makoto Kamiya, Arisa Chisoku, Kaoru Yamamoto
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Patent number: 5378748Abstract: Polyacetal resin compositions capable of providing a molded article having exceptionally reduced surface gloss characteristics but which maintain the inherent mechanical properties and moldability of polyacetal resin include (A) 100 parts by weight of a polyacetal base resin and, incorporated therein, (B) between 1 to 50 parts by weight of a polyalkylene terephthalate copolymer having a melt flow temperature of 210.degree. C. or below, and (C) between 0.1 to 10 parts by weight of an isocyanate or isothiocyanate compound, or a derivative thereof.Type: GrantFiled: December 16, 1992Date of Patent: January 3, 1995Assignee: Polyplastics Co., Ltd.Inventors: Tohru Katsumata, Nobuyuki Matsunaga
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Patent number: 5372731Abstract: Textiles can be finished in a wash- and cleaning-resistant manner by impregnation if aqueous dispersions are employed for this purpose which contain reactive copolymers and/or cocondensates having perfluoroalkyl groups and water-dispersible polyisocyanate mixtures whose NCO groups are not blocked.Type: GrantFiled: March 3, 1993Date of Patent: December 13, 1994Assignee: Bayer AktiengesellschaftInventors: Gisbert Michels, Hans-Albert Ehlert, Hans-Josef Laas, Joachim Probst, Helmut Reiff, Rolf-Volker Meyer
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Patent number: 5310848Abstract: a resin composition for a powder coating comprising a polyester A, which does not substantially set to gel and has a hydroxyl value of at least 1,200 g eq/10.sup.6 g, a polyester B, which does not substantially set to gel and has a hydroxyl value of from 200 to 1,000 g eq/10.sup.6 g, and an inner blocked isocyanate hardener, wherein the weight ratio of polyester A to polyester B is from 70:30 to 10:90 and the difference (absolute value) in gel time between these polyesters A and B is at least 3 minutes.Type: GrantFiled: January 29, 1993Date of Patent: May 10, 1994Assignee: Nippon Ester Co., Ltd.Inventors: Tokuzo Nozaki, Katsuyoshi Atsumi, Makiko Sakai
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Patent number: 5284918Abstract: A reactive plastisol composition includes a one component, solventless, storage stable, low temperature curable polyurethane composition and a thermoplast plastisol. The urethane composition is formed from a blocked isocyanate prepolymer and a curing agent. The isocyanate prepolymer is the reaction product of a polyol, a diisocyanate, and a ketoxime blocking agent. The diisocyanate has the formula ##STR1## in which R.sub.1 -R.sub.4 are each a C.sub.1 -C.sub.6 alkyl which can be linear or branched, R.sub.5 is a phenylene or naphthalene ring which is unsubstituted or substituted by one or more C.sub.1 -C.sub.12 linear or branched chained alkyl groups or halo groups, and m and n are each integers from 0 to 6. A polyurethane curing catalyst can also be used.Type: GrantFiled: May 1, 1991Date of Patent: February 8, 1994Assignee: W. R. Grace & Co.-Conn.Inventors: Truc-Chi T. Huynh-Tran, Felek Jachimowicz, Alexander C. Paton