At Least One Solid Polymer Derived From Nitrile-containing Ethylenic Reactant Patents (Class 524/235)
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Patent number: 8921460Abstract: Polyamide-filled acrylate copolymer compositions comprising a continuous acrylate copolymer phase and a discontinuous polyamide phase are produced by a melt mixing process. When crosslinked with diamine curatives the polyamide-filled acrylate copolymer compositions exhibit enhanced resistance to heat aging compared to carbon black-reinforced acrylate copolymer compositions.Type: GrantFiled: June 21, 2012Date of Patent: December 30, 2014Assignee: E. I. du Pont de Nemours and CompanyInventor: Steven R Oriani
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Publication number: 20140018480Abstract: The present disclosure relates to a carbon fiber composition and a fabrication method for high-performance carbon fiber using the same. The method can fabricate high-performance carbon fiber (or graphite fiber) with lowering a graphitization temperature by using graphene carbon fiber composition including nano-sized graphene.Type: ApplicationFiled: July 11, 2013Publication date: January 16, 2014Inventors: Jae Kap LEE, Won Kook CHOI
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Patent number: 8450605Abstract: The present disclosure relates to a method for making a conjugated polymer. In the method, polyacrylonitrile, a solvent, and a catalyst are provided. The polyacrylonitrile is dissolved in the solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed into the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a conjugated polymer solution with the conjugated polymer dissolved therein.Type: GrantFiled: March 18, 2011Date of Patent: May 28, 2013Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Xiang-Ming He, Li Wang, Wei-Hua Pu, Wen-Ting Sun, Jian-Jun Li
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Patent number: 8273829Abstract: The present disclosure relates to a method for making a conjugated polymer. In the method, polyacrylonitrile, a solvent, and a catalyst are provided. The polyacrylonitrile is dissolved in the solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed into the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a conjugated polymer solution with conjugated polymer.Type: GrantFiled: March 18, 2011Date of Patent: September 25, 2012Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Xiang-Ming He, Li Wang, Wei-Hua Pu, Wen-Ting Sun, Jian-Jun Li
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Patent number: 8168705Abstract: The invention relates to novel organic/inorganic hybrid membranes which have the following composition: a polymer acid containing —SO3H, PO3H2, —COOH or B(OH)2 groups, a polymeric ease (optional), which contains primary, secondary or tertiary amino groups, pyridine groups, imidazole, benzimidazole, triazole, benzotriazole, pyrazole or benzopyrazole groups, either in the side chain or in the main chain; an additional polymeric base (optional) containing the aforementioned basic groups; an element or metal oxide or hydroxide, which has been obtained by hydrolysis and/or sol-gel reaction of an elementalorganic and/or metalorganic compound during the membrane forming process and/or by a re-treatment of the membrane in aqueous acidic, alkaline or neutral electrolytes. The invention also relates to methods for producing said membranes and to various uses for membranes of this type.Type: GrantFiled: August 4, 2010Date of Patent: May 1, 2012Inventor: Jochen Kerres
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Publication number: 20120059085Abstract: The present disclosure relates to a method for making a conjugated polymer. In the method, polyacrylonitrile, a solvent, and a catalyst are provided. The polyacrylonitrile is dissolved in the solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed into the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a conjugated polymer solution with conjugated polymer.Type: ApplicationFiled: March 18, 2011Publication date: March 8, 2012Applicants: HON HAI PRECISION INDUSTRY CO., LTD., TSINGHUA UNIVERSITYInventors: XIANG-MING HE, LI WANG, WEI-HUA PU, WEN-TING SUN, JIAN-JUN LI
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Patent number: 6737453Abstract: The present invention relates to a flame retardant thermoplastic resin composition comprising: (A) 100 parts by weight of a rubber-reinforced thermoplastic resin comprising: a graft copolymer (A1) produced by graft-polymerizing a monomer component (b) containing an aromatic vinyl compound, a cyanided vinyl compound and, if required, the other copolymerizable monomer in the presence of a rubber polymer (a) containing polymer particles having a particle size of not more than 150 nm in an amount of 0 to 15% by weight, polymer particles having a particle size of from more than 150 to less than 350 nm in an amount of 60 to 100% by weight and polymer particles having a particle size of not less than 350 nm in an amount of 0 to 40% by weight, or a mixture of the graft copolymer (A1) and a copolymer (A2) of monomer component (b′), said rubber-reinforced thermoplastic resin (A) having a graft ratio of 20 to 150% and a rubber polymer content of 8 to 20% by weight; and (B) 5 to 20 parts by weight of a phosphorType: GrantFiled: December 6, 2000Date of Patent: May 18, 2004Assignee: Techno Polymer Co., Ltd.Inventors: Norifumi Sumimoto, Masahiko Noro, Kunio Matsusaka
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Patent number: 6447905Abstract: Tire bead rubber compositions and tire beads made therewith are provided having good dimensional stability, processability and wire adhesion Tire bead rubber compositions containing crosslinked styrene butadiene rubber are also provided having good dimensional stability, processability and wire adhesion. Methods for manufacturing tire beads and tires using dimensionally stale compositions are further provided.Type: GrantFiled: November 4, 1999Date of Patent: September 10, 2002Assignee: Pirelli Tire LLCInventors: Benfei Hu, Stanley T. Esposito, Ronald E. Evans
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Publication number: 20010049429Abstract: The present invention provides a polymer that can be used as an anti-refelctive coating (ARC) polymer, an ARC composition comprising the same, methods for producing the same, and methods for using the same. The polymer of the present invention is particularly useful in a submicrolithographic process, for example, using KrF (248 nm), ArF (193 nm), or F2 (157 nm) laser as a light source. The polymer of the present invention comprises a chromophore that is capable of absorbing light at the wavelengths used in a submicrolithographic process. Thus, the ARC of the present invention significantly reduces or prevents back reflection of light and the problem of the CD alteration caused by the diffracted and/or reflected light. The ARC of the present invention also significantly reduces or eliminates the standing wave effect and reflective notching.Type: ApplicationFiled: December 22, 2000Publication date: December 6, 2001Inventors: Min-ho Jung, Sung-eun Hong, Jae-chang Jung, Geun-su Lee, Ki-ho Baik
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Patent number: 5965651Abstract: A liquid-absorbing material composition containing a crosslinking agent (component A), N-vinylcarboxamide copolymer (component B) having a functional group capable of crosslinking with the component A, water (component C), a water-soluble organic solvent (component D) and a plasticizer (component E), a molded liquid-absorbing material prepared from the composition, a method of manufacturing the molded liquid-absorbing material, and uses thereof are provided. The liquid-absorbing material composition has a high flowability, and gives a uniform continuous layer so that it can be directly molded readily into film- or sheet-shaped molded liquid-absorbing material without requiring secondary processing as in the case of conventional water-absorbing polymer.Type: GrantFiled: November 22, 1996Date of Patent: October 12, 1999Assignee: Showa Denko K.K.Inventors: Tetsuya Ishii, Tetsuhiko Yamaguchi
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Patent number: 5861442Abstract: Process of mixing a fugitive plasticizer, e.g., ethylene carbonate, with moist particulate polyacrylonitrile then removing the water enabling adjustment of the melt viscosity for extrusion of the polyacrylonitrile into film, fiber, pellets and shaped articles. Stretching and heating the extruded polyacrylonitrile film or fiber causes the fugitive plasticizer to exude and vaporize from the film or fiber, carrying with it any remaining acrylonitrile monomer. The resulting film or fiber exhibits substantially increased molecular weight, thus enhancing the tensile strength and barrier properties of the polyacrylonitrile product. The process also produces polyacrylonitrile foam products. A novel cross-linking agent for polyacrylonitrile, divinyloxybutane, is disclosed. Thermostabilizing agents for polyacrylonitrile, N-maleimides and stilbene derivatives, are also disclosed.Type: GrantFiled: August 8, 1996Date of Patent: January 19, 1999Assignee: Solcar Polymer, Limited PartnershipInventors: Edmund H. Merz, Roy A. White, John P. Fouser, Norman Fishman
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Patent number: 5814674Abstract: A method is disclosed for processing residue-containing packages so as to receive valuable materials, in particular pressure containers for dispensing foams with propellant gases. For that purpose, extraction with a solvent is carried out essentially in atmosphere of propellant gas and/or solvent vapors.Type: GrantFiled: September 3, 1996Date of Patent: September 29, 1998Assignee: Rathor AGInventors: Mathias Pauls, Torsten Kellner
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Patent number: 5672631Abstract: The invention concerns the method and apparatus for processing remnant-holding packagings while recovering substances of value, said method including the following steps: The packagings are inserted into an operational vessel 13, and the residues are extracted using a solvent. The residue-containing solution from the operational vessel 13 is transferred into a sump. The residue-holding solution is concentrated in the sump while the solvent is evaporated in an evaporation station 19. The evaporated solvent is condensed in a condensing station 20. The solvent is recycled from a recycling station 22 into the operational vessel 13. The residues are enriched and then recovered in concentrated form from the sump.Type: GrantFiled: April 2, 1996Date of Patent: September 30, 1997Inventors: Mathias Pauls, Torsten Kellner
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Patent number: 5589520Abstract: Process of mixing a fugitive plasticizer, e.g., ethylene carbonate, with moist particulate polyacrylonitrile then removing the water enabling adjustment of the melt viscosity for extrusion of the polyacrylonitrile into film, fiber, pellets and shaped articles. Stretching and heating the extruded polyacrylonitrile film or fiber causes the fugitive plasticizer to exude and vaporize from the film or fiber, carrying with it any remaining acrylonitrile monomer. The resulting film or fiber exhibits substantially increased molecular weight, thus enhancing the tensile strength and barrier properties of the polyacrylonitrile product. The process also produces polyacrylonitrile foam products. A novel cross-linking agent for polyacrylonitrile, divinyloxybutane, is disclosed. Thermostabilizing agents for polyacrylonitrile, N-maleimides and stilbene derivatives, are also disclosed.Type: GrantFiled: February 3, 1995Date of Patent: December 31, 1996Assignee: Solcas Polymer, Limited PartnershipInventors: Edmund H. Merz, Roy A. White, John P. Fouser, Norman Fishman
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Patent number: 5434205Abstract: A process for providing extrudable polyacrylonitrile compositions. Dry, particulate polyacrylonitrile having a moisture content of less than about 1.5 percent is mixed with a liquid plasticizer such as ethylene carbonate or propylene carbonate at a mixing temperature of about 140.degree. C. to about 180.degree. C. This process produces an extrudable polyacrylonitrileplasticizer composition which can be extruded to form film, fiber or other extruded or co-extruded products.Type: GrantFiled: August 4, 1993Date of Patent: July 18, 1995Assignee: Solcas Polymer Limited PartnershipInventor: Norman Fishman
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Patent number: 5304590Abstract: Process of mixing a fugitive plasticizer, e.g., ethylene carbonate, with moist particulate polyacrylonitrile then removing the water enabling adjustment of the melt viscosity for extrusion of the polyacrylonitrile into film, fiber, pellets and shaped articles. Stretching and heating the extruded polyacrylonitrile film or fiber causes the fugitive plasticizer to exude and vaporize from the film or fiber, carrying with it any remaining acrylonitrile monomer. The resulting film or fiber exhibits substantially increased molecular weight, thus enhancing the tensile strength and barrier properties of the polyacrylonitrile product. The process also produces polyacrylonitrile foam products. A novel cross-linking agent for polyacrylonitrile, divinyloxybutane, is disclosed. Thermostabilizing agents for polyacrylonitrile, N-maleimides and stilbene derivatives, are also disclosed.Type: GrantFiled: January 21, 1992Date of Patent: April 19, 1994Assignee: Solcas Polymer, Inc.Inventors: Edmund H. Merz, Roy A. White, John P. Fouser, Norman Fishman
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Patent number: 4988749Abstract: Disclosed herein are nitrile polymers which are stabilized against color degradation caused by ionizing radiation by the addition of a stabilizing agent comprising a combination of selected sulfur containing compounds as stabilizers and sulfur containing plasticizers.Type: GrantFiled: November 27, 1989Date of Patent: January 29, 1991Assignee: Monsanto CompanyInventors: Vincent A. Aliberti, James K. Stevens
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Patent number: 4841016Abstract: An additive composition for enhancing curing and color clarity properties of polyester resins. The additive comprises from about 50 to 75 parts by weight of a mercaptan, and from about 50 to about 25 parts by weight of a quaternary ammonium salt. From about 0.5 to about 25 parts by weight of a polymerization initiator can be incorporated into the additive when the polyester resin is utilized as a gel coat. Resinous compositions formulated with the additive consist essentially of from about 50 to about 99.5 parts by weight of a polyester resin, from about 0.5 to about 35 parts by weight of the mercaptan, from about 0.1 to about 15 parts by weight of the quaternary ammonium salt, and a minor effective amount of an oxidizing agent for the polyester resin.Type: GrantFiled: March 16, 1988Date of Patent: June 20, 1989Inventor: Bill R. Edwards
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Patent number: 4444932Abstract: Moldable compositions which comprise a high molecular weight nonequimolar copolymer of an ethylenically unsaturated dicarboxylic acid or its derivative, and at least one copolymerizable monomer and, a surface gloss enhancing agent selected from the group consisting of amides or N,N-dimethylamides of linear and saturated or unsaturated fatty acids containing 16 or more carbon atoms and low molecular weight copolymers of styrene and maleic anhydride, facilitate the production of molded articles exhibiting improved surface gloss.Type: GrantFiled: June 1, 1982Date of Patent: April 24, 1984Assignee: Atlantic Richfield CompanyInventor: Peter S. Francis
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Patent number: 4387174Abstract: This invention relates to hot melt adhesive compositions which include an elastomeric co- or terpolymer, about 5 to about 100 parts by weight of a neutralized sulfonated co- or terpolymer per 100 parts by weight of the highly unsaturated hydrocarbon rubber, wherein the neutralized sulfonated elastomeric polymer has about 0.2 to about 5 weight percent of chemically combined sulfur and about 25 to about 200 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, aliphatic dienes and mono and diolefins, cyclic olefins of 5 to 6 carbon atoms and hydrogenated poly cyclics per 100 parts by weight of the neutralized sulfonated co- or terpolymer rubber.Type: GrantFiled: September 28, 1981Date of Patent: June 7, 1983Assignee: Exxon Research and Engineering Co.Inventors: Robert D. Lundberg, Pawan K. Agarwal, Robert A. Weiss