Carbon Bonded To Three N Atoms, -c=nh, Or C=n-c Group Patents (Class 524/237)
  • Patent number: 11905391
    Abstract: The present invention provides a rubber composition comprising: a guanidine fatty acid salt (A), which is a salt of guanidine and a fatty acid; natural rubber and/or synthetic rubber (B); and an inorganic filler (C).
    Type: Grant
    Filed: July 11, 2019
    Date of Patent: February 20, 2024
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takuya Kageyama, Maya Okaniwa, Susumu Innan
  • Patent number: 11866336
    Abstract: An embodiment of the present disclosure provides a method of producing a reduced graphene oxide, the method including arranging a carbon material; arranging a substrate adjacent to the arranged carbon material; heating the arranged carbon material to a temperature of about 600° C. or higher, and depositing the heated carbon material on the substrate to form a reduced graphene oxide thin film, wherein the arranged carbon material is solid seedlac.
    Type: Grant
    Filed: August 26, 2019
    Date of Patent: January 9, 2024
    Assignee: UNIST(ULSAN NATIONAL INSTITUTE OF SCIENCE AND TECHNOLOGY)
    Inventor: Gun Ho Kim
  • Patent number: 11261329
    Abstract: The present invention provides a tin-free, room temperature curable silicone elastomer composition, wherein the uncured composition is a putty.
    Type: Grant
    Filed: December 15, 2017
    Date of Patent: March 1, 2022
    Assignee: TESA SE
    Inventors: Priti Ariscrisna, Tom Dowden, Jude Pullen, Mark Buckingham, Åsa Jerlhagen, Reya Shamsah, Paraskevi Christogianni, Julien Gautrot, Steve Westall, Khai Duong Quang Nguyen, Winnie Mac
  • Patent number: 10696867
    Abstract: A method of forming a thermal insulation porous film includes mixing 100 parts by weight of polysilsesquioxane-containing polymer, 20 to 75 parts by weight of surfactant, and 20 to 2000 parts by weight of solvent to form a thermal insulation coating material, wherein the polysilsesquioxane-containing polymer in the thermal insulation coating material is tube-shaped or sheet-shaped. The thermal insulation coating material is coated on a substrate, and then dried and sintered to form a thermal insulation porous film.
    Type: Grant
    Filed: January 15, 2020
    Date of Patent: June 30, 2020
    Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Yuan-Chang Huang, Yi-Che Su, Shu-Yun Chien, Hong-Yuan Lian, Huai-Kuang Fu, Pang-Hung Liu
  • Patent number: 10676645
    Abstract: A method of forming a thermal insulation porous film includes mixing 100 parts by weight of polysilsesquioxane-containing polymer, 20 to 75 parts by weight of surfactant, and 20 to 2000 parts by weight of solvent to form a thermal insulation coating material, wherein the polysilsesquioxane-containing polymer in the thermal insulation coating material is tube-shaped or sheet-shaped. The thermal insulation coating material is coated on a substrate, and then dried and sintered to form a thermal insulation porous film.
    Type: Grant
    Filed: July 26, 2018
    Date of Patent: June 9, 2020
    Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Yuan-Chang Huang, Yi-Che Su, Shu-Yun Chien, Hong-Yuan Lian, Huai-Kuang Fu, Pang-Hung Liu
  • Patent number: 10619055
    Abstract: A hydroxyl graphene-modified plating sealant and a preparation method thereof are disclosed. The plating sealant comprises a film-forming material, a resist, a defoaming agent, a levelling agent, and deionized water; the resist is a nanoscale hydroxyl graphene aqueous solution comprising hydroxyl graphene having a mass fraction of 3.5% to 4% and a pH of 8.0 to 9.5. Nanoscale hydroxyl graphene is used as a resist in the plating sealant of the disclosure, then the hydroxyl groups on hydroxyl graphene can react with the hydroxyl groups of the film-forming material, i.e. silica sol and the silane polymer, by dehydration condensation, thereby significantly improving the performance of the sealing film. The sealing film has higher corrosion resistance and abrasion resistance compared with that prepared by graphene or reduced graphene oxide sealant.
    Type: Grant
    Filed: April 17, 2019
    Date of Patent: April 14, 2020
    Assignee: GUANGZHOU ULTRA UNION CHEMICALS LTD.
    Inventors: Chongwu Guo, Lai Fon Voon, Xiaohua Li
  • Patent number: 9663633
    Abstract: A reinforced rubber composition based at least on an elastomeric matrix comprising natural rubber, on a reinforcing filler and on a polyaldimine compound of general formula (I), in which the R1, R2 and A elements are variable groups. This composition is intended in particular for the manufacture of semi-finished products for tires.
    Type: Grant
    Filed: January 29, 2013
    Date of Patent: May 30, 2017
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Catherine Mougin, Justin Belz, Jose Carlos Araujo Da Silva
  • Patent number: 9566828
    Abstract: Reinforced rubber composition based on, exhibiting a lesser hysteresis degradation over time, based on at least (a) an elastomeric matrix predominantly based on natural rubber, (b) a reinforcing filler and (c) a specific polyimine compound in a content of between 6 and 20 mmol per 100 g of elastomer. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for the tyres of motor vehicles.
    Type: Grant
    Filed: July 8, 2010
    Date of Patent: February 14, 2017
    Assignees: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: José Carlos Araujo Da Silva, Justin Belz
  • Patent number: 9126840
    Abstract: Provided are organosilica composites based on bis(3-triethoxysilylpropyl)tetrasulfide (TESPTS) or bis(3-triethoxysilylpropyl)disulfide (TESPDS) and containing octadecyltrimethoxy silane (C18TMS) and cetyltrimethylammonium bromide (CTAB), and a method for preparing hollow or porous carbon structures and silica structures using the same. According to the present disclosure, it is possible to obtain hollow or porous carbon structures and silica structures in a more simple and cost-efficient manner. Thus, the resultant structures have a high surface area and a large mesopore volume, so that they may serve as catalyst carriers for fuel cells capable of loading metal catalyst particles having a smaller particle size in a larger amount and in a more homogeneously dispersed state.
    Type: Grant
    Filed: May 29, 2013
    Date of Patent: September 8, 2015
    Assignee: Korea University Research and Business Foundation
    Inventor: Jong-Sung Yu
  • Patent number: 9006321
    Abstract: Reinforced rubber composition, exhibiting improved hysteresis, based on at least (a) an elastomeric matrix predominantly based on natural rubber, (b) a reinforcing filler and (c) a specific polyimine compound in a small proportion, preferably ranging from 1 to 5 mmol per 100 g of elastomer. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for the tires of motor vehicles.
    Type: Grant
    Filed: July 8, 2010
    Date of Patent: April 14, 2015
    Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.
    Inventors: José Carlos Araujo Da Silva, Justin Belz, Stéphanie De Landtsheer, Nathalie Simon, Brigitte Chauvin
  • Patent number: 8980957
    Abstract: The subject invention relates to a method of preparing a biocompatible polymer comprising epsilon-linked L-lysine having free alpha-amino and carboxy functions. The invention further encompasses the resulting biocompatible polymer and articles made from the polymer, in particular contact and intraocular lenses.
    Type: Grant
    Filed: January 11, 2011
    Date of Patent: March 17, 2015
    Assignee: CIS Pharma AG
    Inventors: Rolf Schäfer, Hans Hitz
  • Publication number: 20150030845
    Abstract: The present disclosure is directed to a base film having a thickness from 8 to 152 microns, a 60 degree gloss value from 2 to 35, an optical density greater than or equal to 2 and a dielectric strength greater than 1400 V/mil. The base film comprises a chemically converted (partially or wholly aromatic) polyimide in an amount from 63 to 96 weight percent of the base film. The base film further comprises a pigment and a matting agent. The matting agent is present in an amount from 1.6 to 10 weight percent of the base film, has a median particle size from 1.3 to 10 microns, and has a density from 2 to 4.5 g/cc. The pigment is present in an amount from 2 to 35 weight percent of the base film. The present disclosure is also directed to coverlay films comprising the base film in combination with an adhesive layer.
    Type: Application
    Filed: July 26, 2013
    Publication date: January 29, 2015
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: THOMAS EDWARD CARNEY, Jeffrey Michael Bartolin, Meredith L. Dunbar, Scott John Herrmann
  • Patent number: 8815985
    Abstract: An object of the present invention is to provide a curable composition which is made mainly of a polymer having one or more reactive silicon groups, has good curability even when filler is used while a non-organotin catalyst is used, and is further high in industrial practicability. The object is solved by a curable composition, comprising, as constituents, a polymer (A) having one or more reactive silicon groups on average per molecule thereof, the reactive silicon group(s) being (each) a group which can be crosslinked by forming a siloxane bond, a Lewis acid and/or derivative thereof (B), an amine compound (C), a compound (D) having a reactive silicon group, and filler (E), and obtained by mixing the constituents with each other.
    Type: Grant
    Filed: February 13, 2008
    Date of Patent: August 26, 2014
    Assignee: Kaneka Corporation
    Inventors: Katsuyu Wakabayashi, Katsuya Ouchi
  • Patent number: 8759428
    Abstract: A polycarbonate composition is disclosed comprising a polycarbonate resin, a 3-hydroxychromone dye, and an ultraviolet absorber selected from the group consisting of cyanoacrylates, malonates, and oxanilides. The combination of the 3-hydroxychromone dye and ultraviolet absorber results in a composition with good color retention and strong initial fluorescent emission intensity.
    Type: Grant
    Filed: August 22, 2007
    Date of Patent: June 24, 2014
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Christopher L. Hein, Cristina Cojocariu, Mohd S. Salleh
  • Publication number: 20140099510
    Abstract: A method of manufacture of a bis(phthalimide) composition includes reacting, in the presence of a solvent and a catalytically active amount of an imidization catalyst selected from quaternary ammonium salts, quaternary phosphonium salts, and combinations thereof, a substituted phthalic anhydride with an organic diamine, wherein conversion to the bis(phthalimide) is 99% complete in less than 6 hours.
    Type: Application
    Filed: October 4, 2012
    Publication date: April 10, 2014
    Inventors: Hendrich Chiong, Surya Prakasha Rao Daliparthi, Hareesh Shamrao Deshpande, Thomas Link Guggenheim, Farid Fouad Khouri, Mahesh Srinivas Kumar, Miguel Angel Navarro De Castro, Roy Ray Odle, Sivakumar P, Dhumal Sunil S, Brennan Alexander Smith, Siva Kumar Sreeramagiri
  • Publication number: 20130221263
    Abstract: The invention relates to the use of a betaine as a foam drainage reducing agent. The invention also relates to the use of betaine in processes involving foam.
    Type: Application
    Filed: April 4, 2013
    Publication date: August 29, 2013
    Applicant: Rhodia Operations
    Inventors: Evelyne PRAT, Sylvie Touzet, Florence Deschaseaux
  • Patent number: 8497337
    Abstract: A process for producing water-absorbing polymer particles, wherein at least one aliphatic aldehyde or reaction product thereof with an aliphatic alcohol, an aliphatic amine, ammonia, a hypophosphite or a phosphite is added.
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: July 30, 2013
    Assignee: BASF SE
    Inventors: Norbert Herfert, Thomas Daniel
  • Patent number: 8455100
    Abstract: The present invention relates to aldimines of the formula (I) which have at least one hydroxyl group, and to curable compositions comprising these aldimines. The aldimines can be prepared in a simple manner and are widely usable. The aldehydes formed in the hydrolysis can be incorporated into a polymer via the hydroxyl groups and have tertiary amino groups which can act catalytically.
    Type: Grant
    Filed: August 29, 2008
    Date of Patent: June 4, 2013
    Assignee: Sika Technology AG
    Inventor: Urs Burckhardt
  • Publication number: 20120277360
    Abstract: Compositions comprising graphene sheets, at least one polymeric binder, and at least one polyalkyleneimine. The compositions may further comprise a liquid carrier. They may be in the form of a coating.
    Type: Application
    Filed: October 28, 2011
    Publication date: November 1, 2012
    Applicant: VORBECK MATERIALS CORP.
    Inventors: Dan Scheffer, Vipin Varma, Sanjay Monie
  • Patent number: 8252859
    Abstract: Aldimines of formula (I) that are particularly suitable as latent hardeners in curable compositions, particularly compositions having one or two-component isocyanate groups. Due to the presence of the reactive group, they can be converted to compounds of formulas (X) and (XII) having aldimine groups. The aldimines, or the aldimine compounds, can be used primarily in adhesive and sealant materials, but also in coatings, and can be produced easily from readily available source materials, and have good thermal stability. The tertiary amino group thereof has a surprisingly low alkalinity and can in some cases have a catalytic effect in chemical reaction systems.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: August 28, 2012
    Assignee: Sika Technology AG
    Inventor: Urs Burckhardt
  • Publication number: 20120165449
    Abstract: Reinforced rubber composition based on, exhibiting a lesser hysteresis degradation over time, based on at least (a) an elastomeric matrix predominantly based on natural rubber, (b) a reinforcing filler and (c) a specific polyimine compound in a content of between 6 and 20 mmol per 100 g of elastomer. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for the tyres of motor vehicles.
    Type: Application
    Filed: July 8, 2010
    Publication date: June 28, 2012
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., SOCIETE DE TECHNOLOGIE MICHELIN
    Inventors: José Carlos Araujo Da Silva, Justin Belz
  • Publication number: 20110218277
    Abstract: A pressurized ball point pen ink composition comprising 30-65% of organic solvent, 15-50% of resin, 0.1-3% of viscosity imparting agent, 0.01 to 1% of polyvinyl pyrrolidone, 2 to 20% of lubricant, 5-25% of colorant; and 0.1-5% of amines and/or 0.1 to 20% diols or polyols; amines and/or diols or polyols capable of forming temporary bridging between silica particles at the same time forming associative coupling between amines itself and diols or polyol itself to obtain the ink composition having viscosity of about 10K to 45K cps. The pressurized ball point pen ink composition further comprising higher alcohol as anti-leakage and plasticizing additive in the ink composition to reduce the viscosity of the ink composition from 13K to 15K cps to below 1 0000 cps. The ink composition prevents leakage, bobbling and other defects associated with the prior art at the same time gives pleasure while writing. The pen comprising, the above ink compositions, which are manufactured by the process of the invention.
    Type: Application
    Filed: January 6, 2009
    Publication date: September 8, 2011
    Inventors: Manish Babulal Shah, Manish Swetal Shah, Vinod Chintamani Malshe
  • Publication number: 20110065851
    Abstract: A nonaqueous ink composition for an ink jet and a method of manufacturing ink comprising the same are provided. The nonaqueous ink composition for the ink jet includes: a glycol ether acetate solvent represented by a specific chemical formula; and a polypropylene glycol binder represented by a specific chemical formula. The nonaqueous ink composition for an ink jet has dynamic viscoelasticity obtained by a chemical interaction between the solvent and the binder, exhibits excellent print quality and is capable of high-speed printing.
    Type: Application
    Filed: February 22, 2010
    Publication date: March 17, 2011
    Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.
    Inventors: Jun Young Kim, Jae Woo Joung, Sung Nam Cho, Ha Yoon Song
  • Patent number: 7851541
    Abstract: A composition containing an anti-microbial agent that comprises a polymeric biguanide, either alone or in combination with at least one other microbiologically active component. The composition also includes an amphoteric co-polymer of the Formula (1): (i) group consisting of quaternary ammonium compounds, [A]m-[B]n-[C]v-[D]yq.
    Type: Grant
    Filed: April 27, 2007
    Date of Patent: December 14, 2010
    Assignee: Arch UK Biocides Limited
    Inventors: David John Hodge, David Alan Pears, John Jeffrey Gerrard, Paula Louise McGeechan
  • Publication number: 20100277884
    Abstract: The circuit-connecting material of the invention is a circuit-connecting material for connection between a first circuit member having a first circuit electrode formed on the main side of a first board, and a second circuit member having a second circuit electrode formed on the main side of a second board, with the first circuit electrode and the second circuit electrode laid facing each other, the circuit-connecting material comprising a film-forming material, a curing agent that generates free radicals upon heating, a radical-polymerizing substance, an isocyanate group-containing compound and a ketimine group-containing compound represented by the following general formula (I), wherein the isocyanate group-containing compound content is 0.1-5 parts by weight and the ketimine group-containing compound content is 0.1-5 parts by weight with respect to 100 parts by weight as the total of the film-forming material and radical-polymerizing substance.
    Type: Application
    Filed: September 29, 2008
    Publication date: November 4, 2010
    Applicant: HITACHI CHEMICAL COMPANY, LTD.
    Inventors: Motohiro Arifuku, Kouji Kobayashi, Kazuyoshi Kojima, Nichiomi Mochizuki, Sunao Kudou
  • Publication number: 20100255215
    Abstract: The present invention is a method which erase information printed on a recording medium if necessary and thus reuse the recording medium, and includes 1) decolorable ink compositions which are not erased during the use but erased by a dye readily decolorable by a decolorant, 2) a decolorant composition including a thermal initiator or photoinitiator, and 3) a method for coating the decolorant and applying heat or irradiating UV to erase the dye. According to the present invention, it is possible to prepare various writing inks, and particularly, when applied to recording medium with a magnetic stripe as well as the general purpose papers, it is possible to reduce the production cost significantly, obtain a large import substitution effect of the magnetic ink all of which are imported, and largely reduce the environmental pollution.
    Type: Application
    Filed: October 6, 2008
    Publication date: October 7, 2010
    Inventors: Jong-Soo Han, Woon Chang Paik, Hyun-Man Shin, Yeong-Gweon Lim, Yong-Hwan Choi
  • Patent number: 7795356
    Abstract: A rubber composition containing 100 parts by weight of a diene-based rubber, 20 to 120 parts by weight of silica, 3 to 15% by weight, based upon the weight of silica, of a sulfur-containing silane coupling agent and (A) 1,5-diazabicyclo[4,3,0]nonene-5 (DBN) having the formula (I): and/or a salt thereof or (B) 0.1 to 3.0 parts by weight of a compound having a piperidine skeleton having the formula (II) or a salt thereof and/or formula (III): wherein n indicates 3 or 5, R1 indicates CH or N and R2 indicates H or OH when R1 is CH, or H when R1 is N, and a melamine derivative of formula (IV): wherein R3 is a methoxymethyl group (—CH2OCH3) or methylol group (—CH2OH), the number of methoxymethyl groups is 3 to 6, and the number of methylol groups is 0 to 3, and/or polymer or copolymer resins of the same and a pneumatic tire using the same.
    Type: Grant
    Filed: April 15, 2009
    Date of Patent: September 14, 2010
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Satoshi Mihara, Yoshihiro Kameda
  • Publication number: 20100190014
    Abstract: The present invention relates to aldimines of the formula (I) which have at least one hydroxyl group, and to curable compositions comprising these aldimines. The aldimines can be prepared in a simple manner and are widely usable. The aldehydes formed in the hydrolysis can be incorporated into a polymer via the hydroxyl groups and have tertiary amino groups which can act catalytically.
    Type: Application
    Filed: August 29, 2008
    Publication date: July 29, 2010
    Applicant: SIKA TECHNOLOGY AG
    Inventor: Urs Burckhardt
  • Patent number: 7718722
    Abstract: A composition comprising alkylthio- or aryl(heteroyl)thio-substituted p-phenylenediamine, its method of preparation, and its use as an antidegradant in natural or synthetic rubber.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: May 18, 2010
    Assignee: Flexsys America L.P.
    Inventors: Otto William Maender, Charles John Rostek, Alan Roy Katritzky, Herman Howard Odens, Michael Victor Voronkov
  • Publication number: 20100081745
    Abstract: The present invention relates to a method for preparing paints and/or inks in which a particle composition consisting of pigment dyestuff, an aldehyde, ketone and/or acrylic resin and optionally excipients and/or adjuvants are mixed into at least one organic solvent, water or a mixture thereof. The invention also relates to paints and/or inks obtainable using said preparation method and to manufactured items painted and/or treated with such paints and/or inks.
    Type: Application
    Filed: September 29, 2009
    Publication date: April 1, 2010
    Applicant: INXEL TRADEMARK & PATENTS SAGL
    Inventor: GIOVANNI BROGGI
  • Patent number: 7598306
    Abstract: An acrylic rubber composition in which the base material is an acrylic rubber comprising monomer units of ethyl acrylate, n-butyl acrylate, and cure site monomer, with a ratio (B/A) of the amount of n-butyl acrylate (B) with respect to ethyl acrylate (A) of 1.0 or less by weight. A heat-resistant hose having a layer of this acrylic rubber composition as the innermost layer. The above constitution of the invention provides the acrylic rubber composition effective for preventing aluminum fixing while retaining the material properties of acrylic rubber and its excellent characteristics. The present invention also provides a heat-resistant hose using this acrylic rubber composition at the surface which is to be fitted with an aluminum member.
    Type: Grant
    Filed: June 16, 2006
    Date of Patent: October 6, 2009
    Assignee: Tokai Rubber Industries, Ltd.
    Inventors: Masashi Noda, Shinobu Kanbe, Hiroyoshi Mori, Motohide Nishimura
  • Patent number: 7521492
    Abstract: A composition is described comprising an organic polymer or a polymerizable monomer, having dispersed therein an azido polymer surface-modified particle phase, in an amount sufficient to reduce the flammability of the polymer.
    Type: Grant
    Filed: June 1, 2005
    Date of Patent: April 21, 2009
    Assignee: 3M Innovative Properties Company
    Inventors: Jimmie R. Baran, Jr., Anthony P. Manzara
  • Publication number: 20090076203
    Abstract: The present invention provides a nanocomposite of an isobutylene-based elastomer and a phosphate nanofiller. Also disclosed is a nanocomposite embodiment wherein the elastomer is BIMSM and high aspect ratio, partially intercalated, partially exfoliated alpha-zirconium phosphate treated with amine or amide. A dispersion aid can include a low molecular weight polymer or oligomer, optionally functionalized with a polar group. The nanocomposite is suitable for use as an air barrier.
    Type: Application
    Filed: August 2, 2006
    Publication date: March 19, 2009
    Inventors: Yves Fernand de Puydt, Herman Robberechts, Andy H. Tsou
  • Publication number: 20090002620
    Abstract: An adhesive layer attaining, in a single layer, both adhesiveness permitting direct attachment to a glass plate disposed on the front face of a display device and desired optical filter functions and hardly undergoing the change in spectral characteristics attributable to deterioration in a light absorbing agent, even during long-time use, particularly at high temperature under high humidity, as well as a composite filter using this adhesive layer. The adhesive layer has optical filter functions, containing a block copolymer having at least a specific triblock structure in its molecule and having a weight-average molecular weight of 50,000 or more and a molecular-weight distribution (Mw/Mn) of less than 1.5 and one or more light absorbing agents each having light absorption in a predetermined wavelength region, as well as a composite filter using this adhesive layer.
    Type: Application
    Filed: June 28, 2007
    Publication date: January 1, 2009
    Inventors: Yudai Yamashita, Hideki Imamura, Yuka Hiwatashi, Toshio Yoshihara
  • Patent number: 7271208
    Abstract: Improved tensile mechanical and dynamic viscoelastic properties of silica-reinforced sulfur vulcanized rubbers can be achieved by compounding elastomers with silica in the presence of an alkoxysilane and a catalytic amount of a strong organic base. The strong organic base acts as a catalyst to accelerate the alkoxysilane-silica reaction, especially at high compounding temperatures, resulting in rubber compounds that exhibit reduced compound viscosity, improved dispersion of silica, and reduced filler flocculation after compounding, and reduced hysteresis and improved abrasion resistance in the vulcanized product, compared to similar compounds prepared at the temperature without the strong organic base catalyst.
    Type: Grant
    Filed: May 2, 2006
    Date of Patent: September 18, 2007
    Assignee: Bridgestone Corporation
    Inventors: Chenchy Jeffrey Lin, William L. Hergenrother, Terrence E. Hogan
  • Patent number: 7256231
    Abstract: The invention provides a sulfur vulcanizable silica-reinforced elastomeric compound having improved tensile mechanical and dynamic viscoelastic properties. The compounds are formed by mixing an elastomer optionally having an alkoxysilane terminal group, with silica in the presence of an alkyl alkoxysilane and a blocked mercaptosilane. In particular, the mercaptosilane moiety of the blocked mercaptosilane and the alkyl alkoxysilane are present in a weight ratio of about 0.001:1 to about 0.20:1. Preferably, the blocked mercaptosilane and the alkyl alkoxysilane are compounded with the elastomer and the silica at high temperature to facilitate the silica-silane reaction. A deblocking agent is added at any desired mixing stage, optionally with the cure package, to allow binding of the mercaptosilane to the polymer.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: August 14, 2007
    Assignee: Bridgestone Corporation
    Inventors: Chenchy Jeffrey Lin, William L. Hergenrother
  • Patent number: 7226968
    Abstract: A composition containing (i) an anti-microbial agent that comprises a polymeric biguanide, either alone or in combination with at least one other microbiologically active component and (ii) a basic co-polymer of the Formula (1): [A]m-[B]n-[D]yq.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: June 5, 2007
    Assignee: Arch UK Biocides Limited
    Inventors: David John Hodge, David Alan Pears, John Jeffrey Gerrard, Paula Louise McGeechan
  • Patent number: 7217759
    Abstract: A composition containing (i) an anti-microbial agent that comprises a polymeric biguanide, either alone or in combination with at least one other microbiologically active component and (ii) an amphoteric co-polymer of the Formula (1):
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: May 15, 2007
    Assignee: Arch UK Biocides Limited
    Inventors: David John Hodge, David Alan Pears, John Jeffrey Gerrard, Paula Louise McGeechan
  • Patent number: 7169839
    Abstract: An acrylic rubber composition in which the base material is an acrylic rubber comprising monomer units of ethyl acrylate, n-butyl acrylate, and cure site monomer, with a ratio (B/A) of the amount of n-butyl acrylate (B) with respect to ethyl acrylate (A) of 1.0 or less by weight. A heat-resistant hose having a layer of this acrylic rubber composition as the innermost layer. The above constitution of the invention provides the acrylic rubber composition effective for preventing aluminum fixing while retaining the material properties of acrylic rubber and its excellent characteristics. The present invention also provides a heat-resistant hose using this acrylic rubber composition at the surface which is to be fitted with an aluminum member.
    Type: Grant
    Filed: September 10, 2002
    Date of Patent: January 30, 2007
    Assignee: Tokai Rubber Industries, Ltd.
    Inventors: Masashi Noda, Shinobu Kanbe, Hiroyoshi Mori, Motohide Nishimura
  • Patent number: 6951896
    Abstract: The invention relates to a flame-retardant thermoplastic composition which comprises at least (A) a thermoplastic polymer and (B) a flame-retardant system and which also contains (C) an n-alkanelactam-substituted polymer. Such a composition shows both a good flame retardancy, in particular a short afterflame time and little dripping, and also excellent mechanical properties. In particular, the n-alkanelactam-substituted polymer is a polyolefine, substituted with n-alkanelactam groups, with n being chosen from between 2 and 12. More in particular, the n-alkanelactam is polyvinyl pyrrolidone. Preferably, the thermoplastic polymer is a polycondensation polymer, in particular a polyamide, a polyester or a polycarbonate. Particularly suitable for use as the polyamide are PA-6, PA-6,6, PA-4,6 and semi-aromatic polyamides. The flame-retardant system may be both a halogen-containing and a halogen-free system.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: October 4, 2005
    Assignee: DSM IP Assets B.V.
    Inventor: Johannes H. G. Ottenheijm
  • Patent number: 6951897
    Abstract: The present invention is directed to a rubber composition that is useful for the manufacture of tires, where the composition is based on a diene elastomer, a reinforcing inorganic filler, and a coupling system. The coupling system comprises a polysulfurized alkoxysilane (“PSAS”) coupling agent (inorganic filler/diene elastomer) associated with an aldimine having the general formula R—CH?N—R and a guanidine derivative. The present invention is further directed to tires and semi-finished products for tires comprising a rubber composition according to the invention. The invention is also directed to a coupling system (inorganic filler/diene elastomer) for a rubber composition based on a diene elastomer reinforced by an inorganic filler, where the coupling system comprises a polysulfurized alkoxysilane (PSAS) coupling agent in association with an aldimine having the general formula R—CH?N—R and a guanidine derivative.
    Type: Grant
    Filed: July 23, 2002
    Date of Patent: October 4, 2005
    Assignee: Michelin Recherche et Technique S.A.
    Inventor: Christophe Penot
  • Patent number: 6890969
    Abstract: This invention is directed to a method of preserving colloid-stabilized polymer emulsions against microbial attack and spoilage using selected cationic compounds. It is also directed to compositions containing colloid-stabilized polymer emulsions and cationic compounds that are resistant to contamination with biodeteriogenic microbes. It has been discovered that specific cationic compounds are particularly effective against biodeteriogenic microbes in preserving polymer emulsions that have been stabilized with protective colloids, such as poly(vinyl alcohol). Examples of suitable microbicidal cationic compounds are: substituted pyridinium salts, substituted guanidine salts, tetrasubstituted ammonium salts, and polymeric cationic compounds.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: May 10, 2005
    Assignee: Air Products Polymers, L.P.
    Inventors: John Joseph Rabasco, Dennis Sagl
  • Publication number: 20040266922
    Abstract: An ethylene-acrylic copolymer rubber composition, which comprises (A) a carboxyl group-containing ethylene-acrylic copolymer rubber, (B) at least one monoamine compound selected from the group consisting of a primary amine, a secondary amine and a tertiary amine, (C) a guanidine type compound, and (D) at least one of an aromatic diamine compound expressed by the following structural formula (1),
    Type: Application
    Filed: April 29, 2004
    Publication date: December 30, 2004
    Applicant: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yasuhiro Kanba, Yasushi Abe, Shogo Hagiwara, Masao Koga
  • Patent number: 6765045
    Abstract: Rubber composition vulcanizable with sulfur and tire tread and tire casing comprising the composition, characterized in that the composition comprises: a) at least one polymer selected from the group consisting of diene polymers, olefin/monomeric diene copolymers and isoolefin/halogenated para-alkylstyrene copolymers; b) silica as filler; c) at least one agent of the sulfur-containing silane type promoting the linkage between silica and polymer; d) at least one substituted guanidine; and in that it has at least one of the following characteristics: It has at least one diene polymer which comprises at least one terminal amino group of an aliphatic or cycloaliphatic amine which is bonded thereto at the end of the chain, the polymer then being devoid of the alkoxysilane and silanol group; the composition comprises at least one free aliphatic or cycloaliphatic amine.
    Type: Grant
    Filed: April 19, 2000
    Date of Patent: July 20, 2004
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Marc Daniel, Gérard Labauze
  • Patent number: 6756435
    Abstract: The invention relates to a silica-filled, sulfur-vulcanizable rubber composition comprising an unsaturated rubber, 20 to 100 phr of a silica, 1.6 to 8 phr of a silica coupling agent, 0.05 to 5 phr of an antidegradant, 0.1 to 5 phr of a vulcanization accelerator, 0.1 to 10 phr of sulfur, and 0.5 to 5 phr of a quinone diimine, with the proviso that the antidegradant is not a quinone diimine. The invention also relates to a vulcanization process comprising mixing and heating said rubber composition and to rubber articles, such as pneumatic tires, comprising the rubber vulcanizate obtained by said process.
    Type: Grant
    Filed: December 11, 2001
    Date of Patent: June 29, 2004
    Assignee: Akzo Nobel NV
    Inventors: Rabindra Nath Datta, Nicolaas Maria Huntink, Auke Gerardus Talma
  • Publication number: 20040097623
    Abstract: A method of producing a toner composition, including stirring and mixing toner particles comprising a binder resin, a colorant and a release agent with a charge controlling agent in a fluidizing and stirring mixer comprising a rotor having a stirring blade to fix the charge controlling agent on a surface of the toner particles, wherein the stirring and mixing comprises rotating the rotor at a peripheral speed of from 65 to 120 m/s at an environmental temperature (T) in the fluidizing and stirring mixer, satisfying the relationship,Tg-10>T>Tg-35(° C.), where the Tg represents a glass transition temperature of the binder resin.
    Type: Application
    Filed: August 12, 2003
    Publication date: May 20, 2004
    Inventors: Junya Koeda, Kenichi Uehara, Hiroyuki Yoshikawa, Osamu Kouzu
  • Patent number: 6696233
    Abstract: The present invention provides a silver halide photographic photosensitive material in which a silver halide photosensitive layer is disposed on a transparent polyethylene terephthalate (PET) film into which an ultraviolet light absorber has been kneaded, wherein the ultraviolet light absorber is at least one kind of ultraviolet light absorber characterized in that (i) a loss of mass is not greater than 10% when heated to 300° C. at a heating rate of 10° C./minute in a nitrogen gas atmosphere, and/or (ii) a difference between a b-value of a sheet having a thickness of 1.5 mm formed after heating for 1 minute at 300° C., a PET resin including an amount of 0.4% by mass of the ultraviolet light absorber and having a water content of not greater than 50 ppm, and a b-value of a sheet having a thickness of 1.5 mm formed after heating the PET resin for 8 minutes at 300° C., is not greater than 3.0.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: February 24, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tatsuya Nomura, Takanori Sato, Hideki Takaki
  • Patent number: 6689829
    Abstract: Hydroxyalkylamines can, in addition to imparting antistatic properties, significantly improve the color, i.e., the whiteness, of polyolefin resins produced with chromium-based catalysts and metallocene catalysts. Additionally, such compounds can impart improved whiteness at a loading significantly lower than that required to impart antistatic properties. Surprisingly, the discovered improvement in whiteness is not, however, observed in resins produced using other types of catalysts.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: February 10, 2004
    Assignee: Phillips Petroleum Company
    Inventor: Mark K. Russell
  • Patent number: 6680349
    Abstract: An organohybrid-based damping material for controlling unwanted vibration and noise, an organic damping improver exhibiting piezoelectric, dielectric and electroconductive effects, and their producing methods, are provided. The damping material comprises a polymer matrix having a polar side chain and a damping improver composed of a compound containing basic nitrogen and a phenol-based compound. The damping material shows an excellent damping properties, alleviates the functional deterioration, and is applicable to different application temperature regions and wide areas.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: January 20, 2004
    Assignee: Masao Sumita
    Inventors: Cheng Zhang, Tadashi Miura, Masao Sumita
  • Publication number: 20030105215
    Abstract: A coating composition containing an emulsion polymer prepared with up to about 20% by weight, based on total polymerizable monomers, of addition polymerizable esters of the glycidyl esters of tertiary acids having 9 or more carbon atoms, preferably up to 18 carbon atoms, and particularly having 9 to 11 carbon atoms has improved application properties and produces coatings with better appearance and less water sensitivity. The emulsion polymerization process of the invention produces less coagulum without having to increase the amount of surfactant.
    Type: Application
    Filed: October 26, 2001
    Publication date: June 5, 2003
    Inventor: Sunitha Grandhee