Aryl Patents (Class 524/254)
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Patent number: 11459447Abstract: In accordance with the invention a wire coat rubber composition for a tire comprises from 70 phr to 100 phr of cis 1,4-polyisoprene rubber, from 0 phr to 30 phr of solution styrene butadiene rubber, from 65 phr to 95 phr pre-silanized precipitated silica, from 0.1 phr to 5 phr of a cobalt salt, up to 15 phr carbon black, up to 10 phr of a resin, and up to 10 phr oil. Further the present invention is directed to a tire comprising such a wire coat composition.Type: GrantFiled: June 17, 2020Date of Patent: October 4, 2022Inventors: Julia Martine Francoise Claudine Tahon, Robert Anthony Bethea, James Joseph Golden, Carolin Anna Welter, Christian Jean-Marie Kaes
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Patent number: 11127429Abstract: A problem to be solved by the present invention is to provide a magnetic recording medium having a jet-black magnetic stripe which is not tinged with red. The present invention is directed to a magnetic recording medium including: a magnetic recording layer on a substrate; and a protective layer (a) on the magnetic recording layer, wherein the protective layer (a) contains an aniline coloring material. The magnetic recording medium is advantageous in that the magnetic stripe is jet-black and has excellent design properties, and therefore can be widely used for credit cards, bank cards and the like.Type: GrantFiled: April 13, 2017Date of Patent: September 21, 2021Assignee: DIC CORPORATIONInventors: Akira Fukasawa, Toshiaki Adachi, Daisuke Yano
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Patent number: 11084916Abstract: A polymeric material having a multimodal pore size distribution is provided. The material is formed by applying a stress to a thermoplastic composition that contains first and second inclusion additives dispersed within a continuous phase that includes a matrix polymer. Through the use of particular types of inclusion additives and careful control over the manner in which such additives are dispersed within the polymer matrix, the present inventors have discovered that a unique, multimodal porous structure can be achieved.Type: GrantFiled: June 6, 2014Date of Patent: August 10, 2021Assignee: KIMBERLY-CLARK WORLDWIDE, INC.Inventors: Vasily A. Topolkaraev, Ryan J. McEneany, Theodore T. Tower, David Glen Biggs, Neil T. Scholl, Thomas A. Eby, Antonio J. Carrillo
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Patent number: 10883035Abstract: Wellbore fluids, and methods of use thereof, are disclosed. Wellbore fluids may include a non-oleaginous internal phase; an oleaginous external phase; at least one two-dimensional platelet-like material; a first latex-containing copolymer comprising at least one copolymer formed from at least one natural polymer and at least one latex monomer; and a second latex polymer distinct from the first latex polymer.Type: GrantFiled: April 29, 2016Date of Patent: January 5, 2021Assignee: M-I L.L.C.Inventors: Guido De Stefano, Brandi Katherine Price Hoelscher, Aaron Blue, Clint Falgout
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Patent number: 10766305Abstract: The present invention provides a pneumatic tire that achieves a balanced improvement in fuel economy, wet grip performance, handling stability, abrasion resistance, fatigue resistance, and tensile strength. The present invention relates to a pneumatic tire including a tread formed from a rubber composition, the rubber composition having after vulcanization rubber properties satisfying certain values.Type: GrantFiled: November 17, 2015Date of Patent: September 8, 2020Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventor: Tetsuya Kunisawa
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Patent number: 10689558Abstract: Wellbore fluids, and methods of use thereof, are disclosed. Wellbore fluids may include a non-oleaginous internal phase, an oleaginous external phase, a first latex-containing copolymer comprising at least one copolymer formed from at least one natural polymer and at least one latex monomer, and a second latex polymer distinct from the first latex polymer.Type: GrantFiled: April 29, 2016Date of Patent: June 23, 2020Assignee: M-I L.L.C.Inventors: Guido De Stefano, Brandi Katherine Price Hoelscher, Aaron Blue, Clint Falgout
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Patent number: 10669405Abstract: The present invention provides a rubber composition for tires which provides a balanced improvement of physical properties including fuel economy, tensile strength, and abrasion resistance while achieving good processability. Also provided is a pneumatic tire formed from the rubber composition. The rubber composition for tires contains: an isoprene-based rubber; and a polybutadiene rubber mixture consisting of a high molecular weight polybutadiene rubber having a cis content of 95% by mass or more and a peak top molecular weight Mp of 550,000 or more and a low molecular weight polybutadiene rubber having a cis content of 95% by mass or more and a peak top molecular weight Mp of 500,000 or less. The rubber component in the rubber composition includes, based on 100% by mass thereof, 60 to 90% by mass of the isoprene-based rubber and 10 to 40% by mass of the polybutadiene rubber mixture.Type: GrantFiled: April 3, 2018Date of Patent: June 2, 2020Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Satoru Inoue, Norihiro Matsumoto
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Patent number: 8841369Abstract: A description is given of an aqueous polymer dispersion comprising at least one polyurethane, dispersed in aqueous phase and having one or more uretdione groups, and at least one solid polyamine with a deactivated surface, said dispersion being useful as an adhesive, coating material or sealant or for producing adhesive, coating or sealing compositions. The compositions can be activated thermally or by electromagnetic radiation.Type: GrantFiled: March 30, 2012Date of Patent: September 23, 2014Assignee: BASF SEInventors: Axel Meyer, Maria Teresa Hechavarria Fonseca, Tina Schroeder-Grimonpont, Stefan Dahmen, Christian Beil, Karl-Heinz Schumacher, Thomas Abend
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Publication number: 20130341066Abstract: This application relates to a polyolefin composition comprising a polyolefin and an aromatic compound. The polyolefin composition can be used in producing medium and high voltage cables with improved electrical breakdown strength.Type: ApplicationFiled: August 5, 2013Publication date: December 26, 2013Applicant: Borealis Technology OYInventors: Thomas Hjertberg, Villgot Englund
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Patent number: 8552097Abstract: A new polymer composition comprising (i) a polymer having a main polymer chain derived from (ia) at least 30% by weight to 100% by weight based on the polymer of a first monomer which introduces at least one of a secondary carbon and a tertiary carbon to the main polymer chain, and (ib) in the range of from 0 to 70% by weight based on the polymer of at least one other monomer; (ii) at least one lithium salt; and (iii) at least one antioxidant is provided, as well as a process for producing a polymer vulcanizate comprising the step of vulcanizing the polymer composition mentioned above additionally comprising a vulcanization system. A method for improving the hot air aging and aqueous fluid resistance characteristics of the polymer mentioned above comprises the step of admixing said polymer with at least one lithium salt and at least one antioxidant is also provided.Type: GrantFiled: November 21, 2008Date of Patent: October 8, 2013Assignee: LANXESS Deutschland GmbHInventors: Andreas Roos, Martin Mezger, Hans Magg, Stefan Kelbch, Joachim Haider, Gerd Bergmann
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Patent number: 8450423Abstract: A fluoroelastomer mixture, including: a peroxide-vulcanizable fluoroelastomer (A) containing an iodine atom; and a peroxide-vulcanizable fluoroelastomer (B) containing an iodine atom. The fluoroelastomer (A) is a copolymer (a1) consisting of 50 to 85 mol % of a vinylidene fluoride unit and 15 to 50 mol % of a perfluoro(alkyl vinyl ether) unit, or a copolymer (a2) consisting of 45 to 85 mol % of a vinylidene fluoride unit, 1 to 30 mol % of a tetrafluoroethylene unit, and 14 to 30 mol % of a perfluoro(alkyl vinyl ether) unit. Further the fluoroelastomer (B) has a fluorine content of 70.0% or more. Also disclosed is a composition for peroxide vulcanization containing the above fluoroelastomer composition (i), a polyfunctional unsaturated compound (ii) and a peroxide (iii), as well as a method for producing the fluoroelastomer mixture.Type: GrantFiled: March 30, 2010Date of Patent: May 28, 2013Assignee: Daikin Industries, Ltd.Inventors: Shoji Fukuoka, Keiko Washino, Shuumi Nishii, Daisuke Ota, Mitsuru Kishine
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Publication number: 20130065991Abstract: Disclosed is a vibration-proof rubber composition having improved physical properties such as dynamic ratio, loss factor, etc. without sacrificing, for example, long-term durability. More particularly, the vibration-proof rubber composition, which contains a natural rubber as well as a styrene-butadiene rubber or a butadiene rubber as base rubber together with a filler and suitable additives, provides improved comfort, driving stability and impact shock of an automobile by improving dynamic ratio and loss factor while maintaining long-term durability.Type: ApplicationFiled: November 18, 2011Publication date: March 14, 2013Applicants: KIA MOTORS CORPORATION, HYUNDAI MOTOR COMPANYInventor: Min Soo Kim
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Patent number: 8258218Abstract: A method of fabricating a composite insulator with a protective housing made of a polymer material incorporating an antioxidant and an antiozonant includes the step consisting in incorporating said antiozonant at a final concentration by weight lying in the range 0.005% to 1%, and said antioxidant at a final concentration by weight lying in the range 0.005% to 1%, said antiozonant being selected from the family of phenylenediamines, and said antioxidant being selected from the family of multifunctional phenolic antioxidants.Type: GrantFiled: February 13, 2009Date of Patent: September 4, 2012Assignee: Sediver Societe Europeenne d'Isolateurs en Verre et CompositeInventor: Guy Thevenet
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Publication number: 20120196963Abstract: A compound having formula (I) wherein R1, R2, R3, R4, R5 and R6 independently are hydrogen, C1-C10 alkyl, C5-C10 cycloalkyl, C6-C10 aryl or C7-C20 aralkyl; X is a difunctional group selected from the group consisting of C2-C20 alkyl, C5-C20 cycloalkyl, C6-C10 aryl, C8-C20 aryl alkyl, C4-C20 heteroalkyl or C10-C20 aryl heteroalkyl.Type: ApplicationFiled: October 8, 2010Publication date: August 2, 2012Applicant: Angus Chemical CompanyInventor: Raymond John Swedo
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Publication number: 20120147724Abstract: An optical data storage medium is provided. The optical data storage medium includes a polymer matrix; a reactant capable of undergoing a change upon triplet excitation, thereby causing a refractive index change; and a non-linear sensitizer capable of absorbing actinic radiation to cause upper triplet energy transfer to said reactant. The refractive index change capacity of the medium is at least about 0.005. The non-linear sensitizer comprises a triarylmethane dye.Type: ApplicationFiled: December 14, 2010Publication date: June 14, 2012Applicant: GENERAL ELECTRIC COMPANYInventors: Arunkumar Natarajan, Patrick Joseph McCloskey, Eugene Pauling Boden, Kwok Pong Chan, Matthew Jeremiah Misner, Evgenia Mikhailovna Kim
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Publication number: 20120065303Abstract: Disclose is a polyamide resin composition having excellent heat resistance, heat aging resistance and mechanical physical properties, which is produced by incorporating a specified aromatic secondary amine compound and a specified organic sulfur based compound into a polyamide composed of a diamine unit containing a paraxylylenediamine unit as a major component and a dicarboxylic acid unit containing a linear aliphatic dicarboxylic acid unit having from 6 to 18 carbon atoms as a major component.Type: ApplicationFiled: May 28, 2010Publication date: March 15, 2012Applicant: MITSUBISHI GAS CHEMICAL COMPANY INCInventors: Shun Ogawa, Takahiko Sumino
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Publication number: 20120031495Abstract: A polyolefinic moulding composition is suitable for producing pipes with improved resistance to thermo-oxidative degradation when these pipes are in extended contact with liquids which contain disinfectants with an oxidative action. Beside thermoplastic polyolefins, the moulding composition additionally contains specific aromatic amines which are liquid under standard conditions as an additive. The invention also relates to a pipe made from the moulding composition and to a process for improving the long-term resistance of water pipework made of plastics to damage by disinfectants with an oxidative action from the water by the use of this moulding composition.Type: ApplicationFiled: April 23, 2010Publication date: February 9, 2012Applicant: Basell Polyolefine GmbHInventors: Heinz Vogt, Hansjörg Nitz
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Patent number: 8026268Abstract: The invention relates to antioxidants or radical scavengers and their reaction products. The invention provides compounds and compositions for use in methods for scavenging radicals or for modulating the immune response comprising urocanic acid or salts, derivatives, functional equivalents and analogues thereof.Type: GrantFiled: November 29, 2005Date of Patent: September 27, 2011Assignee: Academisch Ziekenhuis bij de Universiteit van AmsterdamInventors: Arthur Kammeijer, Joannes Dositheus Bos
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Patent number: 7915339Abstract: Novel additive systems for metallocene based filled cable insulation are disclosed. These systems provide excellent protection against thermal degradation, better cure state and reduced dissipation factor after prolonged heat exposure. The additives may contain one or more hindered amine light stabilizers and amine antioxidants.Type: GrantFiled: July 22, 2005Date of Patent: March 29, 2011Assignee: General Cable Technologies CorporationInventor: Mark R. Easter
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Publication number: 20110071242Abstract: A method of fabricating a composite insulator with a protective housing made of a polymer material incorporating an antioxidant and an antiozonant includes the step consisting in incorporating said antiozonant at a final concentration by weight lying in the range 0.005% to 1%, and said antioxidant at a final concentration by weight lying in the range 0.005% to 1%, said antiozonant being selected from the family of phenylenediamines, and said antioxidant being selected from the family of multifunctional phenolic antioxidants.Type: ApplicationFiled: February 13, 2009Publication date: March 24, 2011Applicant: SEDIVER SOCIETE EUROPEENNE D'ISOLATEURS EN VERRE ET COMPOSITEInventor: Guy Thevenet
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Patent number: 7879934Abstract: A rubber composition is disclosed wherein the rubber composition contains at least an effective amount of at least one substituted or unsubstituted diaryl amine-containing compound having at least one substituted or unsubstituted, saturated or partially saturated C5-C30 ring structure optionally containing one or more heteroatoms fused to at least one of the aryl rings.Type: GrantFiled: August 16, 2007Date of Patent: February 1, 2011Assignee: Chemtura CorporationInventors: Theodore E. Nalesnik, John Kounavis, Joseph Stieber
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Publication number: 20100190624Abstract: The present invention relates to a method for producing a roller shell or roller covering of a roller from a PPDI-based polyurethane. To avoid stress cracks, the intention is to overcome the inadequacy in green strength as quickly as possible by the hardener that is added to the polyurethane bringing the pot time down to 5 to 60 seconds. The present invention also relates to a PPDI polyurethane for producing a roller shell or roller covering of a roller formed by mixing a PPDI prepolymer with a hardener, in particular for carrying out the method, wherein 60 to 99% by weight of the hardener is 1,4-butane diol, at most 40% by weight is diamine and at most 1% by weight is a catalyst.Type: ApplicationFiled: March 5, 2010Publication date: July 29, 2010Inventors: Michael Wokurek, Martin Breineder
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Patent number: 7683113Abstract: Novel additive systems for metallocene based filled cable insulation are disclosed. These systems provide excellent protection against thermal degradation, better cure state and reduced dissipation factor after prolonged heat exposure. The additives may contain one or more hindered amine light stabilizers and amine antioxidants.Type: GrantFiled: November 24, 2004Date of Patent: March 23, 2010Assignee: General Cable Technologies CorporationInventor: Mark R. Easter
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Patent number: 7572850Abstract: A rubber composition comprising the following compound: R1—NH-phenyl-NH—R2 where the amino moieties occupy the 1 and 4 positions of the phenyl ring, and R1 and R2 are selected from the group consisting of H, C1 to C3 straight chain or branched alkyl groups, and wherein R1 and R2 may be the same or different; and where the t90, isothermal at 125° C. is within thirty percent of the t90, after 28 days aging at forty degrees Celsius (40° C.), as the unaged green rubber composition. In another embodiment, R1 and R2 are selected from C4 to C5 straight chain or branched alkyl groups. In another embodiment of the invention, R1 and R2 are selected from C6 to C15 straight chain or branched alkyl groups. In another embodiment of the invention, the rubber compound is greater than 5 parts by weight per hundred parts of the rubber composition.Type: GrantFiled: December 15, 2006Date of Patent: August 11, 2009Assignee: Michelin Recherche et Technique S.A.Inventors: Peter Hetzel, Jean-Michel Douarre
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Patent number: 7312264Abstract: A process for obtaining a grafted diene elastomer having functional groups along the chain, a rubber composition containing this grafted elastomer and having in particular improved hysteresis properties in the cross-linked state, a preparation process for this composition, a tire tread made from this composition and a tire of reduced rolling resistance which incorporates this tread. A process for obtaining this grafted elastomer includes a radical grafting reaction carried out in solution or without a solvent by means of a reagent of the mercaptan type to graft functional groups on to the chain of a starting elastomer. The starting elastomer is treated with an antioxidant having at least one aromatic amine function before the grafting reaction, so that the grafted elastomer has a macrostructure which is practically identical to that of the starting elastomer.Type: GrantFiled: October 25, 2005Date of Patent: December 25, 2007Assignee: Michelin Recherche et Technique S.A.Inventor: Sylvie Gandon-Pain
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Patent number: 6825253Abstract: Novel additive systems for metallocene based filled cable insulation are disclosed. These systems provide excellent protection against thermal degradation, better cure state and reduced dissipation factor after prolonged heat exposure. The additives may contain one or more hindered amine light stabilizers and amine antioxidants.Type: GrantFiled: February 24, 2003Date of Patent: November 30, 2004Assignee: General Cable Technologies CorporationInventor: Mark R. Easter
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Patent number: 6756451Abstract: Process for the hydrogenation of a polymer composed of conjugated diene monomer units and a nitrile group-containing monomer units, in which hydrogenation is carried out in the presence of hydrazine, and an oxidizing compound, with the hydrogenation being carried out in the presence of a antioxidant. It is preferred for NBR to be used as polymer.Type: GrantFiled: January 7, 2002Date of Patent: June 29, 2004Assignee: DSM IP Assets B.V.Inventors: Johannes W. Belt, Olav M. Aagaard
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Patent number: 6706216Abstract: Liquid antiozonant mixtures obtained from the process comprising simultaneously reacting at least one unsubstituted and/or substituted paraphenylenediamine compound with a carbonyl compound mixture comprising acetone and at least one other carbonyl compound selected from the group consisting of ketones containing from 4 to about 12 carbon atoms, aldehydes containing from 1 to about 12 carbon atoms and mixtures thereof in the presence of a reductive alkylation catalyst is provided. Rubber compositions containing the liquid antiozonant mixtures is also provided.Type: GrantFiled: April 19, 2000Date of Patent: March 16, 2004Assignee: Uniroyal Chemical Company, Inc.Inventors: Russell E. Malz, Jr., Michael P. Reynolds, Richard A. Gencarelli
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Patent number: 6706217Abstract: Liquid antiozonant mixtures obtained from the process comprising simultaneously reacting at least one unsubstituted and/or substituted paraphenylenediamine compound with a carbonyl compound mixture comprising acetone and at least one other carbonyl compound selected from the group consisting of ketones containing from 4 to about 12 carbon atoms, aldehydes containing from 1 to about 12 carbon atoms and mixtures thereof in the presence of a reductive alkylation catalyst is provided. Rubber compositions containing the liquid antiozonant mixtures is also provided.Type: GrantFiled: October 22, 2001Date of Patent: March 16, 2004Assignee: Uniroyal Chemical Company, Inc.Inventors: Russell E. Malz, Jr., Michael P. Reynolds, Richard A. Gencarelli
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Patent number: 6706790Abstract: The present invention relates to a polyamide-based composition used for the manufacture of moulded components exhibiting high resistance to attack by light and/or weathering. The invention more particularly relates to compositions comprising a thermoplastic matrix based on semi-crystalline polyamide, a black pigment and optionally reinforcing fillers. This composition is characterized by the presence of thermally stabilizing additives, in combination with a black pigment comprising at least one black pigment of inorganic origin and with at least additives which decrease the effect of radiation on the degradation of the polymeric matrix. The compositions of the invention exhibit improved stability in their properties under the effect of light and/or weathering, for example similar to that of polyester.Type: GrantFiled: March 26, 1999Date of Patent: March 16, 2004Assignee: Nyltech FranceInventor: Jérôme Berliet
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Publication number: 20040006162Abstract: A composition comprising alkylthio- or aryl(heteroyl)thio-substituted p-phenylenediamine, its method of preparation, and its use as an antidegradant in natural or synthetic rubber.Type: ApplicationFiled: May 20, 2003Publication date: January 8, 2004Inventors: Otto William Maender, Charles John Rostek, Alan Roy Katritzky, Herman Howard Odens, Michael Victor Voronkov
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Patent number: 6613818Abstract: The invention relates to a coating composition for preparing a back coating film of a mirror. This mirror serving as an anticorrosive mirror has a glass substrate, a silver mirror film that comprises silver and is formed on a back surface of the glass substrate, a metallic protective film that comprises a first metal and is formed on the silver mirror film, and the back coating film formed on the metallic protective film. The coating composition is substantially free of a lead component and comprises (a) a vehicle containing a synthetic resin, (b) a first salt formed by a neutralization of an acid with a base containing a second metal having an ionization tendency that is greater than the silver and the first metal, and (c) a basic compound selected from the group consisting of azoles and diamines. The acid is one compound selected from the group consisting of organic acids each containing an azole ring and unsubstituted and substituted carbamic acids.Type: GrantFiled: March 27, 1997Date of Patent: September 2, 2003Assignee: Central Glass Company, LimitedInventors: Motoyuki Sakatoku, Kenichi Hayashi, Yoshihisa Tamura, Yutaka Mori
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Patent number: 6569927Abstract: A composition is disclosed comprising: (A) a thermoplastic resin; and (B) a stabilizing amount of a blend of at least one sterically hindered phenol antioxidant, at least one aromatic amine and/or N,N′-substituted oxamide antioxidant, and at least one lactone antioxidant having a 3-phenylbenzofuran-2-one structure. A method is also disclosed for stabilizing a thermoplastic resin, wherein the method comprises adding thereto a stabilizing amount of a blend of at least one sterically hindered phenol antioxidant, at least one aromatic amines and/or N,N′-substituted oxamide antioxidant, and at least one lactone antioxidant having a 3-phenylbenzofuran-2-one structure.Type: GrantFiled: October 6, 2000Date of Patent: May 27, 2003Assignee: Uniroyal Chemical Company, Inc.Inventor: Michael E. Gelbin
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Publication number: 20020165302Abstract: Improved carbon black and method for producing improved carbon black by combining one or more additives with carbon black in the absence of a solvent or carrier resulting in an additive carbon black (ACB). The additive may include p-phenylenediamine (PPD) and related compounds. The invention also relates to improved polymer compositions and articles of-manufacture comprised of the improved carbon black and methods for making same. Advantages provided by the improved carbon blacks made in accordance with the invention may include reduced processing time for polymer, such as rubber, compositions and articles, as well as reduced cost and environmental impact from the production of the improved carbon blacks themselves.Type: ApplicationFiled: December 10, 2001Publication date: November 7, 2002Inventors: Rakshit Lamba, Grady Franklin Bradley, Rodney Taylor
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Publication number: 20020132888Abstract: A composition comprising 2-alkylthio- or 2-aryl(heteroyl)thio-substituted p-phenylenediamine, its method of preparation, and its use as an antidegradant in natural or synthetic rubber.Type: ApplicationFiled: November 20, 2001Publication date: September 19, 2002Inventors: Otto William Maender, Charles John Rostek, Alan Roy Katritzky, Herman Howard Odens, Michael Victor Voronkov
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Patent number: 6417253Abstract: The color stability of thermoplastic polymers comprising structural units derived from at least one 1,3-dihydroxybenzene and at least one organodicarboxylic acid is enhanced by combination with at least one photobleachable 4-aminocinnamic compound such as 4-dimethylaminocinnamaldehyde. The latter absorbs radiation in the range between about 360 nanometers and about 390 nanometers, balancing the radiation absorbed by hydroxybenzophenone moieties formed in the polymer.Type: GrantFiled: March 22, 2001Date of Patent: July 9, 2002Assignee: General Electric CompanyInventor: Alexander Isaakovich Shakhnovich
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Patent number: 6410620Abstract: The color stability of thermoplastic polymers comprising structural units derived from at least one 1,3-dihydroxybenzene and at least one organodicarboxylic acid is enhanced by combination with at least one photobleachable 4-aminocinnamic compound such as 4-dimethylaminocinnamaldehyde. The latter absorbs radiation in the range between about 360 nanometers and about 390 nanometers, balancing the radiation absorbed by hydroxybenzophenone moieties formed in the polymer.Type: GrantFiled: March 22, 2001Date of Patent: June 25, 2002Assignee: General Electric CompanyInventor: Alexander Isaakovich Shakhnovich
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Patent number: 6235819Abstract: A method for scavenging amines within polymeric compositions of matter comprising the step of adding to a polymeric composition of matter at least one triazine compound, wherein said triazine compound is defined according to the formula: where X is selected from the group consisting of hydrogen, halides, amines, and organic groups having from 1 to about 20 carbon atoms, Y is selected from the group consisting of halides, alkoxy derivatives, amine derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Y is displacable by a reaction with a secondary amine, and Z is selected from the group consisting of alkoxy derivatives, amino derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Z is displacable by a reaction with a secondary amine.Type: GrantFiled: December 31, 1997Date of Patent: May 22, 2001Assignee: Bridgestone CorporationInventors: David F. Lawson, Ashley S. Hilton, John R. Schreffler, Roderic P. Quirk
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Patent number: 6015851Abstract: The present invention relates to rubber compositions containing an elastomer containing olefinic unsaturation and a bis anil compound of the formula ##STR1## where R.sup.1 and R.sup.2 may be the same or different and are independently selected from alkyls having from 1 to 5 carbon atoms and X is selected from the group consisting of H; OH; OAlk where Alk is an alkyl having from 1 to 3 carbon atoms; COOH and; COO.sup.- M.sup.+ where M is a metal selected from the group consisting of Zn, Na, Ca and Mg; and y is 0 to 2.Type: GrantFiled: June 17, 1998Date of Patent: January 18, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Neil Arthur Maly, Lawson Gibson Wideman, Lewis Timothy Lukich
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Patent number: 5760114Abstract: This invention relates to the discovery that aminobenzylamine, when used as a replacement in whole or in part of conventional cobalt materials, improves the rubber-to-wire adhesion properties.Type: GrantFiled: August 26, 1996Date of Patent: June 2, 1998Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, William Paul Francik, Adel Farhan Halasa
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Patent number: 5708055Abstract: What is disclosed is an improved thermoplastic composition for use in wire and cable manufacturing processes, which features the use of from about 15 to 45 percentage by weight of a modified furnace carbon black having a specific surface area of from about 35 to 250 m.sup.2 /g, preferably 35 to 60 m.sup.2 /g, as measured by the nitrogen adsorption surface area method. The modified carbon black is prepared by combining the carbon black with a specified amount of amine, under certain conditions, and heating the reactive mixture for an extended period.Type: GrantFiled: February 16, 1996Date of Patent: January 13, 1998Assignee: Columbian Chemicals CompanyInventors: George Alfred Joyce, Edward Lester Little
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Patent number: 5684073Abstract: The cap tread portion composed of a rubber composition having a tan.delta. (0.degree. C.) of at least 0.45 and a tan.delta. (60.degree. C.) of at least 0.25 comprising (i) a p-phenylenediamine type antioxidant, 2,2,4-trimethyl-1,2-dihydroquinoline etc, and carbon black having a nitrogen specific surface area of at least 70 m.sup.2 /g and a 24M4DBP of at least 80 ml/100 g or (ii) a p-phenylenediamine based antioxidant, a 2,2,4-trimethyl-1,2-dihydroquinoline or other polymer mixture of a specific polymer content, and carbon black having a nitrogen specific surface area of at least 70 m.sup.2 /g and a 24M4DBP of at least 80 ml/100 g, blended with a rubber.Type: GrantFiled: May 1, 1995Date of Patent: November 4, 1997Assignee: The Yokohama Rubber Co., Ltd.Inventors: Shingo Midorikawa, Kinya Kawakami, Yasushi Kikuchi, Motoji Fujita
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Patent number: 5492954Abstract: N,N,N',N'-Tetrasubstituted 1,4-diamino-2-butenes where the substituents are alkyl, cycloalkyl, aralkyl, aryl or mixtures thereof provide effective antioxidant protection to lubricants and/or synthetic polymers.Type: GrantFiled: November 18, 1994Date of Patent: February 20, 1996Assignee: Ciba-Geigy CorporationInventors: Joseph E. Babiarz, Glen T. Cunkle, Werner Rutsch
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Patent number: 5476891Abstract: A flexible, fire-retardant, intumescent composition comprising:a) an intumescent material;b) an effective amount of a stabilizing agent; andc) an organic binder throughout which the intumescent material and stabilizing agent are dispersed, the elastomeric binder being at least partially crosslinked, wherein the stabilizing agent consists essentially of a compound selected from the group consisting of compounds within general formula I ##STR1## wherein R.sup.1 -R.sup.4 inclusive are independently selected from the group consisting of hydrogen and alkyl groups having from 1 to about 5 carbon atoms, with the provisos that:i) either both of R.sup.1 and R.sup.2, or both R.sup.3 and R.sup.4 are alkyl groups having from 1 to about 5 carbon atoms; andii) the stabilizing agent has a melting point ranging from about 105.degree. C. to about 125.degree. C.Type: GrantFiled: August 11, 1994Date of Patent: December 19, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventor: Walton W. Welna
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Patent number: 5393606Abstract: Charge-transfer complexes of formula I(A.sup..crclbar.).sub.n B.sup.n.sym. (I)whereina) n is 1 or 2,b) A is the radical anion of a compound of formula II or of a mixture of compounds of formula II ##STR1## wherein the substituents R are the same and are H or C.sub.1 -C.sub.4 alkyl, or adjacent substituents R together form --(CH.sub.2).sub.3 -- or --(CH.sub.2).sub.4 --;R.sub.1 is H or C.sub.1 -C.sub.4 alkyl;X.sub.1 is .dbd.N--CN;and X.sub.2, X.sub.3 and X.sub.4 are .dbd.O or .dbd.N--CN, andc) when n=1, B is the monovalent radical cation and when n=2, B is the divalent radical cation of an N-aromatic compound having a total of from 1 to 5 aromatic rings that are unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl or by C.sub.1 -C.sub.4 alkoxy, at least one ring containing at least one group --NR.sub.2 -- or [.dbd.N.sup.+ R.sub.2 --] I.sup.- wherein R.sub.2 is C.sub.1 -C.sub.4 alkyl or benzyl.Type: GrantFiled: May 25, 1993Date of Patent: February 28, 1995Assignee: Ciba-Geigy CorporationInventor: Peter Chetcuti
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Patent number: 5358987Abstract: A new polysilane composition usable as an organic semiconductor which contains a specific polysilane compound of 6000 to 200000 in a weight average molecular weight in which all the substitutional groups and end groups being substituted by specific organic groups not containing oxygen atom, said polysilane compound not containing chlorine atom, and an acceptor level forming material or/and a donor level forming material.Type: GrantFiled: June 12, 1992Date of Patent: October 25, 1994Assignee: Canon Kabushiki KaishaInventors: Masahiro Kanai, Hisami Tanaka, Harumi Sakou, Tatuyuki Aoike, Kouichi Matuda, Keishi Saitou, Mituyuki Niwa, Masahumi Sano
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Patent number: 5344861Abstract: A chlorosulfonated polyethylene polymer composition is disclosed, comprising a chlorosulfonated polyethylene polymer having incorporated therein (a) from 0.1 to 20 parts by weight of a metal salt of an organic acid, (b) from 0.1 to 10 parts by weight of a phenylamine and/or a phenylenediamine, (c) from 1 to 30 parts by weight of an acid acceptor, and (d) from 0.1 to 10 parts by weight of a vulcanizing agent, per 100 parts by weight of the chlorosulfonated polyethylene polymer. The composition provides a vulcanized product excellent in ozone resistance as well as mechanical strength.Type: GrantFiled: April 2, 1993Date of Patent: September 6, 1994Assignee: Tosoh CorporationInventors: Hideyoshi Nakamura, Katsumi Sando
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Patent number: 5319010Abstract: The instant invention pertains to viscous fluid coupling organopolysiloxane compositions comprised of (A) at least one organopolysiloxane fluid that has the general formula R.sup.1.sub.a R.sup.2.sub.b SiO.sub.[4-(a+b)]/2 wherein R.sup.1 is an alkyl group, R.sup.2 is an aryl group, a+b has the value of 1.95 to 2.05, and b/(a+b) has the value of 0.05 to 0.30; and (B) 0.01 to 5 weight parts by weight per 100 parts by weight of component (A) of a compound with the general formula ##STR1## wherein each R.sup.3 is independently selected from an alkyl group and C has the value of 0 to 2. The viscous fluid coupling organopolysiloxane compositions of the instant invention are capable of withstanding long-term use and under high-temperature, high-shear conditions with little increase or decrease in viscosity and almost no torque fluctuation.Type: GrantFiled: December 4, 1992Date of Patent: June 7, 1994Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Osamu Mitani, Ichiro Murakami
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Patent number: 5272196Abstract: A method is disclosed for increasing the surface energy of a surface of an organic polymeric material, particularly polyolefins. The method is comprised of blending from about 99.5% to about 90.0% by weight of the polymeric material with from about 0.5% to about 10.0% by weight of an amphiphile having the formula:RA(CHR.sup.2 [CH.sub.2 ].sub.n A.sup.1).sub.m R.sup.1where R and R.sup.1 are selected from the group consisting of the alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of an aliphatic or aliphatic/aromatic mono-acid with a molecular weight of from about 150 to about 500 daltons, A and A.sup.1 are polar atoms or groups, R.sup.2 is selected from the group consisting of H, CH.sub.3 and C.sub.2 H.sub.5, n is from 0 to 3 and m is from 2 to 20.Type: GrantFiled: March 24, 1993Date of Patent: December 21, 1993Assignee: Arizona Chemical CompanyInventor: Eric S. Gardiner
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Patent number: 5240976Abstract: Elastomers are very effectively stabilized against thermal and oxidative degradation at elevated temperatures with a blend of an N,N,N',N'-tetrasubstituted 1,4-diamino-2-butene, where the substituents are alkyl, cycloalkyl, aralkyl, aryl or mixtures thereof, in combination with a mercaptoimidazole of formula IV ##STR1## where E is hydrogen, alkyl, cycloalkyl, aryl or phenylalkyl.Type: GrantFiled: August 21, 1992Date of Patent: August 31, 1993Assignee: Ciba-Geigy CorporationInventors: Douglas W. Horsey, Ambelal R. Patel