Oxygen Atom Other Than As Si-o-si And At Least One Si-c Or Si-h Group Patents (Class 524/265)
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Patent number: 4952621Abstract: Polyurethane sealant and coating compositions made from blocked isocyanate-terminated prepolymers have improved shelf stability when an effective amount of a carbodiimide is utilized therewith. Such compositions and coating materials can be stored in sealed containers or cartridges for relatively long periods of time, for example in excess of five or six months, without significant loss of curability which adversely affects physical properties upon cure. One part as well as two part polyurethane sealant and coating compositions are stabilized by the addition of the carbodiimide stabilizing agent whereas the addition of an organosilane abates viscosity increase during storage.Type: GrantFiled: October 10, 1989Date of Patent: August 28, 1990Assignee: The B. F. Goodrich CompanyInventor: Baldev K. Bandlish
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Patent number: 4948820Abstract: Selective thermodegradation of homo- and copolymers of propylene, without encountering thermo-oxidation phenomena, by treating the polymer at 250.degree.-350.degree. C. in the presence of primary and/or secondary antioxidant and of a derivative of benzopinacol having formula (I): ##STR1## wherein n=1, or=0, and when n=1, X may be=1, and in this case Z.sub.1 and Z.sub.2 form together with each other ##STR2## groups, ##STR3## wherein R.sub.1, R.sub.2, R.sub.3, which may be the same or different, are alkyl or aryl radicals;or X ranges from 3 to 20 and in this case Z.sub.1 and Z.sub.2 are aryl radicals, A and B are R.sub.1 -Si-R.sub.2 groups that are part of an oligomer having formula: ##STR4## and when n=0, X is=1, Z.sub.1 and Z.sub.Type: GrantFiled: January 27, 1989Date of Patent: August 14, 1990Assignee: Montedipe S.p.A.Inventors: Antonio Addeo, Annibale Vezzoli, Stefano Saccardi, Corrado Brichta
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Patent number: 4946883Abstract: Curable fluororubber compositions comprising an organic fluororubber, an organopolysiloxane gum and an epoxy-containing organoalkoxysilane or partial hydrolyzate thereof, a reinforcing filler and an organoperoxide are characterized by excellent roll workability during roll milling and can be cured to yield a fluororubber which undergoes little deterioration in its mechanical properties at low temperatures.Type: GrantFiled: December 20, 1989Date of Patent: August 7, 1990Assignee: Toray Dow Corning SiliconeInventors: Kaoru Kunimatsu, Atsushi Komatsu
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Patent number: 4943601Abstract: A latent curable electronic coating composition is described which comprises:a. a linear dimethylvinyl chainstopped polydimethylsiloxane fluid having a viscosity of about 500 to 5000 centipoise at 25.degree. C.;b. an organohydrogenpolysiloxane;c. an amount of a platinum catalyst sufficient to cause the co-reaction of (a) and (b);d. a combination of inhibiting agents comprised of (i) an ethylenically unsaturated isocyanurate and (ii) a dialkyl acetylenedicarboxylate; ande. a silanol-containing dimethyl siloxane hydrolyzate having a silanol content from about 0.5% to about 1.5% and a viscosity from about 4 to about 40 centipoise at 25.degree. C.Type: GrantFiled: April 3, 1989Date of Patent: July 24, 1990Assignee: General Electric CompanyInventor: Anthony J. Dinallo, Sr.
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Patent number: 4940765Abstract: 3-Benzylidenecamphor-substituted diorganopolysiloxanes, well adopted for incorporation into coating and lubricant compositions (notably as a lubricant for PVC), have the structural formulae (1) and (2) ##STR1## wherein A and/or B is a 3-benzylidenecamphor moiety.Type: GrantFiled: December 29, 1988Date of Patent: July 10, 1990Assignee: Rhone-Poulenc ChimieInventors: Edith Canivenc, Serge Forestier, Michel Gay, Gerard Lang, Herve Richard
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Patent number: 4935458Abstract: A release agent comprising a polyfunctional alkoxysiloxane and an organic compound which is solid at room temperature and contains a functional group capable of reacting with said polyfunctional alkoxysiloxane, and a composite material comprising a substrate and a cured film of the release agent are disclosed. The cured film of the release agent exhibits high strength and excellent release properties without causing blocking or contamination on an adherent.Type: GrantFiled: January 18, 1989Date of Patent: June 19, 1990Assignee: Nitto Denko CorporationInventors: Kihachi Suzuki, Makoto Sunakawa, Hiroshi Yamamoto
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Patent number: 4931492Abstract: The present invention relates to olefin polymer compositions which can be extruded into film material characterized by improved stability and optical properties. In particular, this application is directed olefin polymer compositions containing specific polyorganosiloxanes bearing a hydroxyl functionality.Type: GrantFiled: March 17, 1989Date of Patent: June 5, 1990Assignee: Union Carbide Chemicals and Plastics Company Inc.Inventors: George N. Foster, Herbert E. Petty, Charles H. Blevins, II, Roswell E. King, III
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Patent number: 4929702Abstract: Organopolysiloxane compositions curable into elastomeric state, whether in single- or two-component form, comprise an .alpha., .omega.-dihydroxypolydiorganopolysiloxane oil, a crosslinking agent therefor, optionally, inorganic fillers and an adhesion promoter, and a catalytically effective amount of a pentacoordinated tin monochelate produced by reacting a tin bischelate with an organic carboxylic acid.Type: GrantFiled: June 27, 1988Date of Patent: May 29, 1990Assignee: Rhone-Poulenc ChimieInventors: Jacques Cavezzan, Jean-Marc Frances, Pierre Lancelin
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Patent number: 4925890Abstract: A process for enhancing the fabrication of thermoplastic polymers entailing the addition of from 0.01 to 1 part, per hundred parts of thermoplastic polymer, of a processing aid, said processing aid comprising a processing additive, such as a silicon or a polyol, and a processing adjuvant, such as a phosphate.Type: GrantFiled: May 24, 1989Date of Patent: May 15, 1990Assignee: Union Carbide Chemicals and Plastics Company Inc.Inventors: Pak S. Leung, Errol D. Goddard, Fred H. Ancker
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Cosmetic application of polysiloxanes containing a .beta.-keto ester group and compositions employed
Patent number: 4925659Abstract: Use in cosmetics of diorganopolysiloxanes containing a .beta.-keto ester group, corresponding to the formula: ##STR1## in which: the groups R, which may be identical or different, denote, independently of one another, a C.sub.1 -C.sub.4 alkyl, 3,3,3-trifluoropropyl, vinyl or phenyl groups, at least 80%, in numerical terms of the groups R being methyl radicals;the groups Y, which may be identical or different, denote, independently of one another, a C.sub.1 -C.sub.18 linear or branched alkylene link, optionally extended by a polyether chain;the groups X, which may be identical or different, denote, independently of one another, a radical Y--OH or Y--OCOR', Y having the meaning stated above and R' being chosen from C.sub.1 -C.sub.Type: GrantFiled: February 2, 1989Date of Patent: May 15, 1990Assignee: L'OrealInventors: Jean F. Grollier, Claude Dubief -
Patent number: 4923914Abstract: A surface-segregatable, melt-extrudable thermoplastic composition suitable for processing by melt extrusion to form a fiber or film having a differential, increasing concentration of an additive from the center of the fiber or film to the surface thereof, which differential, increasing concentration imparts to the surface of the fiber or film at least one desired characteristic which otherwise would not be present, which composition includes at least one thermoplastic polymer and at least one defined additive. During formation of the fiber or film, the additive rapidly segregates in a controllable manner toward the newly-formed surface of the fiber or film, thereby resulting in a controllable differential concentration of the polymeric material, which concentration increases with increasing distance from the center of the fiber or film to its surface. The weight ratio of the polymer to the additive is in the range of from about 1 to about 1,000.Type: GrantFiled: April 14, 1988Date of Patent: May 8, 1990Assignee: Kimberly-Clark CorporationInventors: Ronald S. Nohr, J. Gavin MacDonald
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Patent number: 4920168Abstract: A stabilized surface-segregatable, melt-extrudable thermoplastic composition suitable for processing by melt extrusion to form a fiber or film having a differential, increasing concentration of a siloxane-containing primary additive from the center of the fiber or film to the surface thereof, which differential, increasing concentration imparts hydrophilicity to the surface of the fiber or film, which composition includes at least one thermoplastic polymer, at least one siloxane-containing primary additive, and at least one siloxane-containing stabilizing additive. During formation of the fiber or film, the primary additive rapidly segregates in a controllable manner toward the newly-formed surface of the fiber or film, thereby resulting in a controllable differential concentration of the primary additive, which concentration increases with increasing distance from the center of the fiber or film to its surface. The weight ratio of the polymer to the additive is in the range of from about 1 to about 1,000.Type: GrantFiled: April 14, 1988Date of Patent: April 24, 1990Assignee: Kimberly-Clark CorporationInventors: Ronald S. Nohr, J. Gavin MacDonald
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Patent number: 4917957Abstract: A molded article useful for electrical parts, such as connectors, has at least one weld portion and is obtained by injection molding of a polyarylene sulfide composition comprising a polyarylene sulfide and an alkoxysilane such as aminoalkoxysilanes, epoxyalkoxysilanes, mercaptoalkoxysilanes and vinylalkoxysilanes, and optionally an inorganic filler.Type: GrantFiled: July 29, 1988Date of Patent: April 17, 1990Assignee: Polyplastics Co., Ltd.Inventors: Toshikatsu Nitoh, Toshifumi Nonaka
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Patent number: 4918126Abstract: Silicone rubber adhesive films or sheets are obtained by sheeting a composition comprising 100 parts by weight of organopolysiloxane gum, 30 to 150 parts by weight of wet-process hydrophobic reinforcing silica, a curing agent, and 0.1 to 10 parts by weight of an organoalkoxysilane. These uncured sheets have a tensile strength at break of from 1.5 to 5 kg/cm.sup.2. The adhesive films are characterized by simplicity in handling and an excellent workability combined with excellent tensile adhesive strength. They tightly bond and unify adherend pairs and are particularly suitable for bonding flat surface, such as fabrics, glass, and rubber sheets.Type: GrantFiled: January 23, 1989Date of Patent: April 17, 1990Assignee: Toray Silicone Company, Ltd.Inventors: Takao Matsushita, Kanzuo Hirai
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Patent number: 4912157Abstract: A composition useful in printing inks exemplified as comprising:(1) from about 4 to about 80% by weight of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from about 1.0 to about 60% by weight of pigment material;(3) from about 0.05 to about 30% by weight of a nonionic, polyether type property modifier; and(4) from substantially none to about 90% by weight of water.Type: GrantFiled: April 29, 1988Date of Patent: March 27, 1990Assignee: Eastman Kodak CompanyInventors: Gary T. Clark, John N. Rasar, Rebecca R. Stockl
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Patent number: 4908399Abstract: An encapsulating composition for electronic devices comprises a curable material such as an epoxy resin and an ion scavenger compound selected from certain calixarene or oxycalixarene compounds in which at least half of the phenolic groups have been substituted by specific groups and certain silacrown compounds. Exemplary ion scavenger compounds include ##STR1## the tetraethyl acetate of 7, 13, 19, 25-tetra-tertbutyl-27, 28, 29, 30-tetrahydroxy-2,3-dihomo-3-oxacalix-4-arene and 1,1-dimethasila-17-crown-6.Type: GrantFiled: November 14, 1988Date of Patent: March 13, 1990Assignee: Loctite (Ireland) Ltd.Inventors: Stephen J. Harris, Maureen G. MacManus, John Guthrie
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Patent number: 4906686Abstract: The addition-curable composition of the present invention, because it comprises a special component as component (D), is characterized by an excellent bonding to any of various substrates with which it is in contact during curing. Component (D) is a mixture, or reaction product, of (a) a silicon-free compound which contains at least 1 alcoholic hydroxyl group and at least 1 alkenyl group in each molecule, and (b) an organosilane having in each molecule at least 1 alkoxy group and at least 1 epoxy or methacryloxy or acryloxy group.Type: GrantFiled: December 28, 1988Date of Patent: March 6, 1990Assignee: Toray Silicone Company, Ltd.Inventors: Toshio Suzuki, Akira Kasuya
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Patent number: 4906676Abstract: A resin composition suitable for various optical uses, which comprises a base resin and 0.1 to 60% based on the weight of said resin composition, of fine silica or glass particles, said fine silica or glass particles having an average particle diameter of 0.05 to 50 .mu.m and having their surface treated with at least one silane compound selected from those represented by the following general formulae (I) to (IV): ##STR1## wherein n is an integer of from 1 to 3, R.sup.1 is an alkyl group having 1 to 3 carbon atoms, and R is a saturated or unsaturated hydrocarbon group having 1 to 22 carbon atoms or a halogen-substituted, saturated or unsaturated hydrocarbon group having 1 to 22 carbon atoms, wherien the silane does not couple the particle and the resin.Type: GrantFiled: January 30, 1987Date of Patent: March 6, 1990Assignee: Mitsubishi Rayon Co., Ltd.Inventor: Kozo Ida
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Patent number: 4904720Abstract: A process for improving properties of a synthetic resin powder which comprises: subjecting a latex of a graft-copolymer whose back bone is a rubber to coagulation, and adding a silicone oil to the graft-copolymer in an amount of 0.01 to 10 parts by weight based on 100 parts by weight of said graft-copolymer. According to the present invention, the bulk specific gravity of a synthetic resin powder can be made large, the flowability and blocking resistance can be remarkably improved in comparison with known methods. Accordingly, the blocking during storage can be prevented, a line for transport is not packed with the resin powder, it is possible to automatically weigh the resin powder, and it is applicable to the tendency to grow larger in transport.Type: GrantFiled: May 25, 1988Date of Patent: February 27, 1990Assignee: Kanegafuchi Kagaku Koyo Kabushiki KaishaInventors: Atsushi Kawakatsu, Ryuichi Takagi, Takeshi Nagano
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Patent number: 4904721Abstract: A coating composition comprising:(a) 100 parts by weight (in terms of organoalkoxysilane) of at least one compound selected from the group consisting of (a') an organoalkoxysilane represented by the general formula (I):RSi(OR.sup.1).sub.3 (I)wherein R is an organic group having 1-8 carbon atoms and R.sup.1 is an alkyl group having 1-5 carbon atoms or an acyl group having 1-4 carbon atoms, (a") a hydrolyzate of (a') and (a'") a partial condensate of (a'),(b) 5-50 parts by weight (as solids) of colloidal alumina, and(c.sub.1) 2-200 parts by weight of at least one organopolysiloxane having at least one reactive functional group in the polymer molecule and/or(c.sub.2) 3-6,000 parts by weight of at least one silyl group-containing vinyl polymer having, at the terminal(s) or side chain(s) of the polymer molecule, at least one silyl group having a silicon atom having bonded thereto a hydrolyzable group, and(d) an organic solvent.Type: GrantFiled: January 5, 1988Date of Patent: February 27, 1990Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Hideyuki Hanaoka, Kazuo Yamamoto, Toshiyuki Suzuki
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Patent number: 4897312Abstract: Insulated electrical conductor and electrical insulation which includes a polyolefin as polymeric base material and a voltage stabilizer included in the polyolefin and comprised of at least one hydrolyzable alkoxy compound, which at least one hydrolyzable alkoxy compound is a liquid at a temperature ranging from about -25.degree. C. to about 140.degree. C. and has a formula:(R.sup.a O).sub.y R.sub.3--y.sup.b X-[R-X'(OR.sup.c).sub.z R.sub.2-z.sup.d ].sub.n -OR.sup.e,where R.sup.a, R.sup.c and R.sup.e are hydrocarbon groups having 1 to 18 carbon atoms; R.sup.b and R.sup.d are saturated or unsaturated, substituted or unsubstituted aliphatic hydrocarbon groups or aromatic hydrocarbon groups having from 1 to 30 carbon atoms; R is a group having a carbon skeleton including at least one heteroatom Y; O is oxygen; X and X' are elements having a valence of four; n varies from 1 to 10, y varies form 0 to 3, z varies from 0 to 2, and where R, R.sup.a, R.sup.b, R.sup.c and R.sub.Type: GrantFiled: January 26, 1988Date of Patent: January 30, 1990Assignee: Licentia Patent-Verwaltungs-GmbHInventors: Johann Wartusch, Werner Golz, Holger Andress
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Patent number: 4895887Abstract: A coating composition comprising a colloidal silica, a partial condensate of organoalkoxysilane hydrolyzate, a polymer or a copolymer of unsaturated ethylenic monomers, a surface active agent and glycol derivatives, which is coated on a wheel for vehicles shows excellent properties such as adhesive property, filiform corrosion resistance, stain resistance, weather-resistance and impact resistance. A wheel coated with the coating composition for vehicles also shows excellent properties such as filiform corrosion resistance, stain resistance, weather-resistance and impact resistance.Type: GrantFiled: August 4, 1988Date of Patent: January 23, 1990Assignees: Osaka Yuki Kagaku Kogyo Kabushiki Kaisha, Asahi Malleable Iron Co., Ltd.Inventors: Yasuo Daimon, Takashi Ban, Akio Fujinaka, Kimio Ochiai
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Patent number: 4894405Abstract: A concrete and masonry waterproofing composition comprises a major amount of a polyurethane and a minor amount of a penetrant. The polyurethane is desirably made from a polyether polyol or a polyester polyol intermediate, wherein the polyol is a diol or a triol. Such intermediates are reacted with a polyisocyanate. Cure, that is, chain extension occurs upon contact with moisture in the air. The penetrant is an organosilane having the formula: ##STR1## where R.sup.1 is an aliphatic having from 1 to 18 carbon atoms and wherein R.sup.2, R.sup.3, and R.sup.4, independently, is an alkyl having from 1 to 6 carbon atoms, or an organosiloxane having the formula: ##STR2## wherein R.sup.7 is an aliphatic having from 1 to 18 carbon atoms and R.sup.5 and R.sup.6, independently, is an alkyl having from 1 to 6 carbon atoms, and wherein n is 2 to 20.Type: GrantFiled: November 25, 1988Date of Patent: January 16, 1990Assignee: Tremco IncorporatedInventor: Larry R. Barron
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Patent number: 4891402Abstract: Organic silicon-nitrogen compositions are prepared by the reaction of approximately equimolar amounts of a glycidoxyalkyltrialkoxysilane and a primary amine such as isobutylamine. They are useful as adhesion promoters in room temperature vulcanizable compositions comprising polyalkoxysilyl-terminated polydiorganosiloxanes.Type: GrantFiled: May 9, 1988Date of Patent: January 2, 1990Assignee: General Electric CompanyInventors: Jeffrey H. Wengrovius, Virginia M. VanValkenburgh, Steven J. Valenty
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Patent number: 4888375Abstract: Reactive antioxidant compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered phenolic group and a hydrolysable silyl function. In stabilizing organic polymers, said reactive antioxidant compounds can be hydrolysed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to be stabilized. According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized. According to a further embodiment, the reactive antioxidant compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups.Type: GrantFiled: September 28, 1987Date of Patent: December 19, 1989Assignee: Enichem Sintesi S.p.A.Inventors: Alberto Greco, Luigi Cassar, Silvestro Costanzi, Carlo Neri
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Patent number: 4883832Abstract: Fluid polymer/polyol dispersions are prepared from novel polyether polyols.Type: GrantFiled: June 24, 1987Date of Patent: November 28, 1989Assignee: BP Chemicals LimitedInventors: Rudolpha C. Cloetens, Werner A. Lidy, Huy P. Thanh
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Patent number: 4874805Abstract: Compounds of the general formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is a group of the formula --CH.sub.2 OR.sup.7 (II) in which R.sup.7 is C.sub.1- C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is --C(O)--R.sup.8, and R.sup.8 is C.sub.1 -C.sub.12 -alkyl, and also not more than two of the radicals R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are one or two groups of the formula --CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (III), --CH.Type: GrantFiled: June 29, 1988Date of Patent: October 17, 1989Assignee: Ciba-Geigy CorporationInventors: Rolf Mulhaupt, Hubert Simon
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Patent number: 4857593Abstract: A process for enhancing the fabrication of thermoplastic polymers entailing the addition of from 0.01 to 1 part, per hundred parts of thermoplastic polymer, of a processing aid, said processing aid comprising a processing additive, such as a silicone or a polyol, and a processing adjuvant, such as a phosphate.Type: GrantFiled: March 8, 1988Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: Pak S. Leung, Errol D. Goddard, Fred H. Ancker
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Patent number: 4857564Abstract: The presence of an incompatible liquid, polydiorganosiloxane wherein from 1 to 30 percent of the siloxane units contain an ethylenically unsaturated hydrocarbon radical in high-consistency organosiloxane compositions that cure by a platinum-catalyzed hydrosilation reaction substantially improves the tear strength and elongation of cured elastomers prepared from these compositions.Type: GrantFiled: September 29, 1988Date of Patent: August 15, 1989Assignee: Dow Corning CorporationInventor: Myron T. Maxson
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Patent number: 4855351Abstract: Cyclic aminoalkylsilane compositions are prepared by the reaction of approximately equimolar amounts of an aminoalkyltrialkoxysilane such as 3-aminopropyltrimethoxy-silane and a glycidyl ether such as methyl glycidyl ether. They are useful as adhesion promotors in room temperature vulcanizable compositions comprising polyalkoxysilyl-terminated polydiorganosiloxanes.Type: GrantFiled: August 22, 1988Date of Patent: August 8, 1989Assignee: General Electric CompanyInventor: Judith Stein
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Patent number: 4847319Abstract: A sealant or coating composition admixture contains a blocked isocyanate-terminated prepolymer in which generally all of the NCO groups are blocked, a curing agent such as a polyamine or a polyimine, and a functional silane or siloxane nonreactive with blocked isocyanates. The sealants or coating compositions when cured have improved properties such as adhesion.Type: GrantFiled: May 23, 1988Date of Patent: July 11, 1989Assignee: The B. F. Goodrich CompanyInventor: Baldev K. Bandlish
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Patent number: 4842934Abstract: A high tenacity fiber for reinforcing plastic composites, the fiber being selected from the group consisting of polyester, aliphatic polyamide, and combinations thereof. The fiber is treated with a composition consisting essentially of an organofunctional silane in an amount sufficient to achieve 0.02 to 1.0 weight percent of the silane on the fiber, and a diluent which provides for the hydrolysis of the silane to a silanol. The fiber is used to reinforce a plastic composite additionally comprising a resin matrix.Type: GrantFiled: October 30, 1987Date of Patent: June 27, 1989Assignee: Allied-Signal Inc.Inventors: David S. Cordova, David R. Coffin, Stanley D. Lazarus, Hugh H. Rowan, Robert M. Marshall
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Patent number: 4840983Abstract: An organosilane of the general formula ##STR1## where R denotes a hydrogen or alkyl radical, n is 2 to 5, Ph denotes an aryl radical, and R' denotes an alkyl radical, and the hydrolysis product, a disiloxane, of said organosilanes with water, where said compounds are useful as anit-treeing additives to polyolefin.Type: GrantFiled: May 23, 1986Date of Patent: June 20, 1989Assignee: Dow Corning CorporationInventor: Gary A. Vincent
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Patent number: 4837274Abstract: A curable composition comprising (A) an organic polymer containing at least one reactive silicon functional group crosslinkable to produce an elastomer by the formation of a siloxane bond in its molecule and (B) an organic silicon compound having a molecular weight of not less than 140 and represented by the formula (1):[(CH.sub.3).sub.3 SiO].sub.n R.sup.1 (1)wherein R.sup.1 is a residue of an alcohol or a weak acid which has a valency of n, and n is a positive integer. The composition of the invention can give cured product having excellent modulus and elongation as well as has excellent storage stability.Type: GrantFiled: September 29, 1987Date of Patent: June 6, 1989Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Fumio Kawakubo, Sadao Yukimoto, Michihide Homma
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Patent number: 4833187Abstract: Silicone containing paint compositions containing aqueous dispersions of(a) organopolysiloxanes; and(b) an ethylene-vinyl chloride copolymer which does not exceed the weight of the organopolysiloxanes.Type: GrantFiled: March 28, 1988Date of Patent: May 23, 1989Assignee: Wacker-Chemie GmbHInventors: Wilhelm Sittenthaler, Klaus Marquardt, Bernward Deubzer, Anton Eglseder
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Patent number: 4831070Abstract: A composition and method for forming elastomeric pressure sensitive adhesives comprising a mixture of (A) a xylene-soluble resin copolymer of 0.6 to 0.9 triorganosiloxy units per SiO.sub.4/2 unit and having less than 0.7 weight % silicon-bonded hydroxyl units. (B) a polydiorganosiloxane fluid endcapped with silicon-bonded hydroxyl groups and having a viscosity of from about 50 to 300,000 cP. at 25.degree. C., an organosilicon compound containing an average of more than two silicon-bonded alkoxy groups per molecule, and a condensation catalyst. The cured elastomeric pressure sensitive adhesives formed from these compositions are useful as medical adhesives, such as those used for ostomy seals.Type: GrantFiled: November 2, 1987Date of Patent: May 16, 1989Assignee: Dow Corning CorporationInventors: Linda J. McInally, John T. Woodard
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Patent number: 4816506Abstract: Aqueous silicone dispersions containing (a) polydiorganosiloxanes having hydroxyl groups in the terminal units, (b) (organo)metallic compound(s), (c) a siliconate, and optionally, (d) a silicone resin.These aqueous silicone dispersions will cure to form elastomeric coatings or sealants when the water is removed by evaporation.Type: GrantFiled: October 30, 1987Date of Patent: March 28, 1989Assignee: Wacker-Chemie GmbHInventors: Norbert Gamon, Karl Braunsperger, Otto Schneider
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Patent number: 4808649Abstract: Diorganopolysiloxanes having the formula: ##STR1## are especially useful for the stabilization of polyvinyl chloride-based polymers.Type: GrantFiled: August 12, 1987Date of Patent: February 28, 1989Assignee: Rhone-Poulenc ChimieInventors: Michel Gay, Edith Canivenc
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Patent number: 4804692Abstract: The invention relates to thermoplastic polycarbonate molding compositions which are rendered resistant to gamma-radiation by incorporating therewith about 0.05 to about 10 percent by weight of a stabilizing agent selected from the group consisting of ##STR1## wherein R is a hydrogen or a halogen atom or a C.sub.1 -C.sub.10 alkyl, a C.sub.6 -C.sub.10 aryl, C.sub.1 -C.sub.22 acyl, C.sub.6 -C.sub.18 alkylaryl or a C.sub.4 -C.sub.10 cycloalkyl radical, m is 1 or 3 to 6, n is an integer of about 20 to 70 and Y is a radical conforming to ##STR2## wherein R, R' and R" independently one of the others are selected from C.sub.1 -C.sub.10 alkyl and C.sub.6 -C.sub.12 aryl radicals preferably C.sub.1 -C.sub.4 alkyl radical.Type: GrantFiled: April 28, 1988Date of Patent: February 14, 1989Assignee: Mobay CorporationInventors: Charles E. Lundy, Winfried G. Paul, Sivaram Krishnan
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Patent number: 4804720Abstract: Disclosed herein is a polyamide resin composition comprising a polyamide resin, from 0.1 to 1% by weight of fine silica based on the polyamide resin and from 1 to 99% by weight of a silane coupling agent based on the fine silica. The packaging material obtained from the polyamide resin composition of the present invention has uniform and satisfactory transparency and is excellent in the blocking resistance.Type: GrantFiled: April 6, 1988Date of Patent: February 14, 1989Assignee: Mitsubishi Chemical Industries LimitedInventors: Mitsuhiko Tamura, Masaaki Miyamoto, Masaya Ueda, Eiichi Kamoshida
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Patent number: 4786660Abstract: A method for making curable casting resins having a high content of finely divided inorganic fillers and comprising esters of acrylic or methacrylic acid and organosilicon compounds used as adhesion promoters, which method involves mixing the liquid polymer precursor comprising acrylic or methacrylic esters with the organosilicon compound and with an alkylamine as a catalyst for the organosilicon compound, the finely divided inorganic fillers being incorporated into the resulting mixture in such amounts that the viscosity of the mixture does not exceed 10 Pa.sec, the resulting thixotropic suspension then being transformed into a completely deflocculated low viscosity suspension by being allowed to stand for a sufficient length of time at room temperature or by short term heating.Type: GrantFiled: September 2, 1986Date of Patent: November 22, 1988Assignee: Rohm GmbHInventors: Guenther Ittmann, Manfred Krieg
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Patent number: 4785041Abstract: Thixotropic, silica-filled coating compositions wherein the curable film-forming material is an organosiloxane copolymer resin include a liquid polydiorganosiloxane containing hydroxyl-terminated polyoxypropylene units as the flow control agent. The compositions are particularly useful as screen printable passivation coatings for semiconductor devices.Type: GrantFiled: December 31, 1987Date of Patent: November 15, 1988Assignee: Dow Corning CorporationInventors: Robert C. Antonen, Diane M. Rasch, David A. Sierawski, David J. Romenesko
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Patent number: 4783495Abstract: ((Hydroxyphenyl)silane derivatives of the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as process stabilizers in organic materials containing phenolic antioxidants.Type: GrantFiled: November 20, 1987Date of Patent: November 8, 1988Assignee: Ciba-Geigy CorporationInventors: Stephen D. Pastor, Edward T. Hessell
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Patent number: 4764576Abstract: The inventive silicon-based coating composition provides an antistatic surface-releasing coating layer on a plastic film without the need of any antistatic undercoating. The coating composition comprises, in addition to the conventional ingredients in similar coating compositions including a vinyl-containing organopolysiloxane, an organohydrogenpolysiloxane and a platinum catalyst, a salt, e.g. nitrate and perchlorate, of a metal of the Ist, IInd or VIIIth Group of the Periodic Table and a specific organopolysiloxane having at least one per molecule of alkanolic pendant groups of the formula HO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 CH.sub.2 --, in which n is 1 to 9.Type: GrantFiled: August 25, 1987Date of Patent: August 16, 1988Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masahiko Ogawa, Yasuaki Hara
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Patent number: 4761445Abstract: The subject invention relates to polytetramethylene adipamide resin compositions containing 100 parts by weight of the polyamide and 2 to 20 parts by weight of a silicon oil. Objects produced from the composition possess good surface appearance, excellent sliding properties and high heat resistance and rigidity.Type: GrantFiled: July 15, 1986Date of Patent: August 2, 1988Assignee: Stamicarbon, B.V.Inventor: Kazumasa Chiba
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Patent number: 4751114Abstract: A solvent soluble fluorine-containing polymer according to the present invention is a copolymer characterized by(i) consisting substantially of(a) fluoroolefin,(b) vinyl ether, and(c) an organosilicon compound having an olefinically unsaturated bond and a hydrohyzable group,(ii) said copolymer comprising, based on the total mole number of said (a)-(c) in the copolymer, 30-70 mol % of (a), 20-60 mol % of (b) and 1-25 mol % of (c) and(iii) said copolymer having a number average molecular weight (Mn) of 3000-200000 as measured by gel permeation chromatography.Further, according to the present invention, a coating composition having excellent weathering resistance and solvent resistance comprising the above-mentioned solvent soluble fluorine-containing polymer and organic solvent is also provided. In addition a coating process of said coating composition is also provided.Type: GrantFiled: August 6, 1987Date of Patent: June 14, 1988Assignee: Mitsui Sekiyu Kagaku Kogyo Kabushiki KaishaInventors: Shirou Homma, Takashi Izumi, Sakae Murakami
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Patent number: 4748197Abstract: A high tenacity fiber for reinforcing plastic composites, the fiber being selected from the group consisting of polyester, aliphatic polyamide, and combinations thereof. The fiber is treated with a composition consisting essentially of an organofunctional silane in an amount sufficient to achieve 0.02 to 1.0 weight percent of the silane on the fiber, and a diluent which provides for the hydrolysis of the silane to a silanol. The fiber is used to reinforce a plastic composite additionally comprising a resin matrix.Type: GrantFiled: June 27, 1984Date of Patent: May 31, 1988Assignee: Allied CorporationInventors: David S. Cordova, David R. Coffin, Stanley D. Lazarus, Hugh H. Rowan, Robert M. Marshall
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Patent number: 4745142Abstract: A polyester fiber having a superior stainproof property comprises at least one fiber-forming polyester copolymer comprising a backbone polyester polymer and at least one type of terminal substituent which blocks at least some of the terminals of the molecules of the backbone polyester polymer and which substituent consists of a polyoxyalkyleneglycol monoether group of the formula (I):R.sup.1 -O--R.sup.2 -O.sub.n (I)wherein R.sup.1 is a monovalent organic radical free from active hydrogen atom, R.sup.2 is an alkylene radical, and n is an integer of 2 or more.Type: GrantFiled: October 10, 1986Date of Patent: May 17, 1988Assignee: Teijin LimitedInventors: Shinji Ohwaki, Togi Suzuki, Shigenobu Kobayashi
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Patent number: 4743639Abstract: A polymer composition is provided comprising at least one poly(arylene sulfide), at least one polysiloxane, at least one trialkoxysilane, and at least one solid, resinous polyolefin. Molded objects made of this polymer composition have greater impact strength than those made of poly(arylene sulfide), preferably poly(phenylene sulfide). In one embodiment, an additive composition comprising at least one polysiloxane, at least one trialkoxysilane and at least one solid, resinous polyolefin is provided. The additives can be blended with poly(arylene sulfide) so as to improve its impact strength. In another embodiment, a polymer composition is provided comprising at least one poly(arylene sulfide), at least one polysiloxane having molecular in the range of from about 100,000 to about 4000,000, and optionally at least one trialkoxysilane.Type: GrantFiled: June 2, 1987Date of Patent: May 10, 1988Assignee: Phillips Petroleum CompanyInventor: Yeon F. Liang
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Patent number: 4732932Abstract: Organopolysiloxane compositions comprising a polyorganosiloxane having olefinic unsaturation, an organohydrogen polysiloxane and a catalyst, exhibit improved adhesion to a number of substrates when it also comprises an organosilane of the general formula R'(RO).sub.2 SiR", wherein R denotes a monovalent hydrocarbon group, R' denotes an aliphatically unsaturated hydrocarbon or hydrocarbonoxy group and R" denotes an epoxy functional group. The organopolysiloxane compositions also exhibit reduced thixotropy over prior art compositions especially when a reinforcing silica filler is also present.Type: GrantFiled: December 8, 1986Date of Patent: March 22, 1988Assignee: Dow Corning S.A.Inventor: Alan M. Waldern