Abstract: The present invention relates to an organopolysiloxane composition that can be vulcanized at room temperature into an elastomer that is crosslinked by polycondensation and that does not contain alkyltin-based catalysts which exhibit toxicity problems. The invention also relates to novel polycondensation catalysts having a guanidine structure, in silicone chemistry, and to the uses thereof as catalysts for the organopolysiloxane polycondensation reaction.

Abstract: An object of the present invention is to provide a two-component curing type urethane-based aqueous golf ball paint, which is excellent in gloss of a paint film and evenness of the film thickness. Another object of the present invention is to provide a two-component curing type urethane-based aqueous golf ball paint, which is excellent in adhesion to the surface of a golf ball body. The present invention provides a two-component curing type urethane-based aqueous golf ball paint containing (A) an aqueous polyol composition and (B) an aqueous polyisocyanate, wherein the aqueous paint has a contact angle of 45° or less to a resin component constituting an outermost layer of a golf ball body and a paint film has reflectivity of 70% or more at an incident angle of 20°.

Abstract: White particles for display including at least one of a chain or cyclic polysilane compound having a polysilane structure represented by the following Formula (I) or a halogen-substituted compound thereof: wherein in Formula (I), A represents a phenyl group, B represents an alkyl group or a phenyl group, and n represents an integer of from 5 to 1000.

Abstract: This is to provide a curable polyorganosiloxane composition which gives a cured product excellent in cold resistance. This relates to a curable polyorganosiloxane composition which comprises (A) an alkenyl group-containing polyorganosiloxane comprising (A1) a linear polyorganosiloxane represented by the formula (1) (wherein Rs independently represent R1 or R2, and among Rs, at least two of which are R1s, R1s independently represent a C2-C6 alkenyl group, R2s independently represent a C1-C6 alkyl group, n is a number which makes a viscosity at 23° C.

Abstract: A composition for forming a silicon-containing resist underlayer film that contains: a component (A) including at least one or more compounds selected from the group consisting of a polymer having repeating units shown by the following general formulae (1-1a) and (1-1b) and being capable of generating a phenolic hydroxyl group, a hydrolysate of the polymer, and a hydrolysis-condensate of the polymer, and a component (B) which is a silicon-containing compound obtained by hydrolysis-condensation of a mixture containing, at least, one or more hydrolysable silicon compounds represented by the following general formula (2) and one or more hydrolysable silicon compounds represented by the following general formula (3).

Abstract: Superior defoamer compositions contain a low viscosity linear organopolysiloxane, a higher viscosity, optionally branched organopolysiloxane, a polyethersiloxane with a low cloud point, and both colloidal silica and fumed silica.

Abstract: Disclosed is a curable silicone composition for preparing release layers and pressure sensitive adhesives, and to substrates bearing a layer of the cured composition. More specifically, this invention relates to a silicone composition, curable in the absence of both catalysts and actinic radiation comprising a cyclic anhydride copolymer and an amine-terminated polysiloxane.

Abstract: An antifouling condensation curing organopolysiloxane composition is prepared by premixing a part or all of (A) a diorganopolysiloxane free of a reactive group with a part or all of (B) silica to form a premix, then mixing the premix with the remainder of (A) and (B), (C) a base diorganopolysiloxane, and (D) a silane. The composition has a good balance of low viscosity and high thixotropy, can be thickly coated in a single pass, and cures into a coating having rubber strength and surface smoothness and exhibiting satisfactory antifouling property over a long period of time.

Abstract: A one-component moisture-curing adhesive containing at least one flowable polyoxyalkylene or polyacrylate prepolymer with at least one hydrolyzable silane group, at least one inert additive solid at room temperature selected from hydrocarbon resins, polyesters or polyamides with a softening point of 40 to 150° C., together with auxiliary substances and additives.

Abstract: A metal particle dispersion structure characteristically comprising (B) 0.005 to 100 weight parts of metal nanoparticles dispersed in (A) 100 weight parts of polymerized polymer, wherein the metal nanoparticles are metal particles obtained by mixing (b1) organohydrogenpolysiloxane and (b2) at least one metal compound which is soluble in component (b3) to uniformity in (b3) cyclic or chain dimethylpolysiloxane or at least one organic solvent.

Abstract: A method of controlling oil-absorbing properties of a silicone rubber powder characterized by keeping a silicone rubber powder in hot storage at a temperature in the range of 40° C. to 150° C. or in cold storage at a temperature in the range of 0° C. to 10° C.

Abstract: A thermoplastic polyurethane composition includes thermoplastic polyurethane (TPU), a polysiloxane, an acetal polymer, and an acrylonitrile-butadiene-styrene (ABS) copolymer. A method of forming the TPU composition includes the step of combining the TPU, the polysiloxane, the acetal polymer, and the ABS copolymer. The thermoplastic polyurethane composition is also used to form an article. The TPU composition has an increased abrasion resistance and decreased coefficient of friction as compared to existing TPUs.

Abstract: This disclosure relates to compositions containing a) a silicone resin, b) a first silicone fluid having a viscosity from about 1 to about 15,000 centistokes at 25° C.; c) a second silicone fluid having a viscosity from about 1 to about 30,000 centistokes at 25° C.; d) an acrylic polymer; e) a hydrocarbon solvent; and f) water. The compositions of this disclosure provide long lasting hydrophobic coatings with high water contact angles for automotive surfaces, in which the hydrophobic automotive surfaces possess self-cleaning functions, e.g., water and dirt repellency. This disclosure also relates to methods for treating automotive surfaces and to automotive surfaces coated with the compositions.

Abstract: Gel compositions are disclosed containing a silicone polyether elastomer from the reaction of an organohydrogensiloxane having at least two SiH containing cyclosiloxane rings in its molecule, a compound or mixture of compounds having at least two aliphatic unsaturated groups in its molecule, and a hydrosilylation catalyst. The silicone polyether elastomer reaction product may itself be a gelled composition, or optionally may be contained in a carrier fluid to form a gel. The gel compositions may further contain a personal or healthcare active.

Abstract: An emulsion of a silicone oil that contains cross-linked silicone particles in droplets of a silicone oil which are dispersed in water, wherein the aforementioned silicone oil is an organopolysiloxane having in its molecule at least two alkenyl groups, and wherein the cross-linked silicone particles are formed by a hydrosilation reaction; and a cross-linkable silicone composition comprising (I) a silicone composition obtained by removing water from the aforementioned emulsion, (II) an organopolysiloxane that contains in its molecule at least two silicon-bonded hydrogen atoms; and (III) a hydrosilation catalyst.

Abstract: The present invention relates to silicone compounds which have photoprotective properties and personal care compositions comprising the same. The present inventors, in developing a sunscreen that gives protection against both UV radiation and visible radiation, found that when certain moieties generally occurring in nature e.g. curcuminoids, polyphenols or flavonoids having uv-visible absorption activity are attached to cross-linked silicone polymers, they provide not only the desired photoprotection but also excellent spreadability on skin.

Abstract: Gel compositions are disclosed comprising a silicone elastomer from the reaction of an SiH containing organopolysiloxane resin and an organic compound having at least two aliphatic unsaturated groups in its molecule.

Abstract: A polycarbonate resin composition includes about 100 parts by weight of a base resin including a polycarbonate resin (A) and a polycarbonate-polysiloxane copolymer (B); and about 0.1 to about 10 parts by weight of polyalkylaryl siloxane (C) having a refractive index of about 1.42 to about 1.59. The composition can exhibit high gloss and blackness and can have excellent impact resistance, heat resistance, light resistance, and mar resistance (resistance to fine scratches).

Abstract: A core-shell particle is formed by a method that includes forming a crosslinked polyorganosiloxane core, reacting a graftlinking agent with the crosslinked polyorganosiloxane core, and polymerizing a poly(alkenyl aromatic) shell around the graftlinking agent-functionalized polyorganosiloxane core. The method produces a core-shell particle with improved adhesion between shell and core. The core-shell particle is useful as an impact modifier in thermoplastic compositions.

Abstract: A non-stick coating composition comprising a waterborne phenoxy resin, a crosslinker, a silicone compound, and a Fluoropolymer. An article, such as aluminum, may be coated with the composition. The composition may be multi-layers, but only the layers other than the first layer includes the silicone compound. The invention includes the method for applying the coating or coatings.

Abstract: Disclosed is a formed article comprising an ion-implanted layer obtained by implanting ions of a silicon compound into a polymer layer. Also disclosed are: a method of producing the formed article, the method comprising implanting ions of a silicon compound into a surface of a polymer layer of a formed body that includes the polymer layer in its surface; an electronic device member comprising the formed article; an electronic device comprising the electronic device member. Consequently, the present invention provides: a formed article which has excellent gas barrier capability, bendability and surface flatness; a method of producing the formed article, an electronic device member comprising the formed article; an electronic device comprising the electronic device member.

Abstract: Novel particles and composite particles, their uses and a novel process for producing them from alkoxysilyl-group-carrying alkoxylation products.

Abstract: A method for the preparation of hydrophilic elastomers involves the synthesis of polydimethylsiloxane with tunable hydrophilic surface properties. An elastomeric monolith with desired hydrophilic properties is produced by combining a polyethylene oxide polymeric surfactant additive with a PDMS base and curing agent during polymerization. The surfactant chain segment lengths are varied to control the hydrophobic/hydrophilic balance.

Abstract: Disclosed is a thermoplastic resin composition that includes: (A) about 55 to about 95 wt % of a polycarbonate resin; (B) about 1 to about 40 wt % of a polyalkyl(meth)acrylate resin having a weight average molecular weight of about 1,000,000 g/mol or more; and (C) about 0.001 to about 10 wt % of a polysiloxane resin, and a molded product made using the same.

Abstract: A cement mold-making silicone rubber composition is provided comprising (A) 100 parts by weight of a polyorganosiloxane having at least two silicon-bonded monovalent aliphatic unsaturated hydrocarbon groups in a molecule, (B) a polyorganohydrogensiloxane having at least three silicon-bonded hydrogen atoms in a molecule, in such an amount as to provide 0.1-5 silicon-bonded hydrogen atoms per monovalent aliphatic unsaturated hydrocarbon group in component (A), (C) a platinum base compound in such an amount as to provide 1-100 ppm of platinum atoms based on the weight of component (A), (D) 5-60 parts by weight of finely divided silica having a specific surface area of at least 50 m2/g, and (E) 0.1-100 parts by weight of coal ash and/or pozzolan powder.

Abstract: Present invention provides a fluorine-containing organopolysiloxane composition comprising a fluorine-containing silicone polymer having a three-dimensional, cross-linked structure, prepared by addition polymerizing the following (A), (B) and (C) and containing 10 to 30 mass % of the fluorine atoms, relative to a total mass of (A) to (C), (A) a vinyl group-containing organopolysiloxane represented by the following formula (1): (B) an organohydrogenpolysiloxane represented by the following formula (2): and (C) an organopolysiloxane having a reactive group on one end alone and represented by the following formula (3), and further comprising (D) a low viscosity silicone oil with a dynamic viscosity of 50 mm2/s or less at 25 degrees C.

Abstract: A process for producing a room temperature vulcanizable organopolysiloxane composition comprising: (A) 100 parts by weight of a diorganopolysiloxane having in one molecule at least two hydroxyl groups and/or hydrolyzable groups connecting to silicon atoms; (B) 0.2 to 10 parts by weight of an alkylene oxide compound having silicon atoms in a molecule; (C) 0.5 to 100 parts by weight of a silica; and (D) 0.5 to 30 parts by weight of a silane and/or condensate of partial hydrolyzate thereof, wherein said process comprises steps of hot-mixing component (A), component (B), and component (C) together, and subsequently mixing component (D) thereto.

Abstract: A thermoconductive silicone elastomer comprising a silicone elastomer being a cured body of a hydrosilation-curable organopolysiloxane composition, a reinforcing fine powder silica, a thermoconductive inorganic powder, and a non-reactive organopolysiloxane that is liquid at room temperature which are dispersed in the aforementioned silicone elastomer; a thermoconductive medium comprising the aforementioned thermoconductive silicone elastomer; a hydrosilation-curable thermoconductive silicone elastomer composition comprising a hydrosilation-curable organopolysiloxane composition, a reinforcing fine powder silica, a thermoconductive inorganic powder, and a non-reactive organopolysiloxane that is liquid at room temperature.

Abstract: The invention relates to architectural elements possessing at least two components bonded together employing a silicone rubber composition possessing rapid development of strength and deep-section cure, which is useful for application as a bedding sealant in the manufacture of such architectural elements as window assemblies, door assemblies, structural glazing, curtainwall applications, and the like.

Abstract: A thermosetting composition containing an aluminosiloxane, a silicone oil containing silanol groups at both ends, an epoxy silicone, and a silicone elastomer. The thermosetting composition of the present invention can be used for, for example, encapsulating materials, coating materials, molding materials, surface-protecting materials, adhesive agents, bonding agents, and the like. Especially, in a case where the thermosetting composition of the present invention is used as an encapsulating material, the thermosetting composition is suitably used for, for example, photosemiconductor devices mounted with blue or white LED elements (backlights for liquid crystal displays, traffic lights, outdoor big displays, advertisement sign boards, and the like).

Abstract: Electrical insulation system, which optionally contains a filler material and/or further additives, wherein said electrical insulation system comprises poly(dicyclopentadiene) as the main component, and method of making said electrical insulation system.

Abstract: The present invention relates to coating and printing ink compositions possessing silicone surfactants compositions comprising fluorine-free organomodified trisiloxanes which are resistant to hydrolysis between a pH of about 3 to a pH of about 12. The coatings and printing ink composition of the present invention exhibit enhanced wetting, flow and leveling properties.

Abstract: An article comprises a weatherable surface exposed to precipitation or airborne debris; and a weather resistant coating disposed on the weatherable surface, wherein the coating comprises component A, a one- or two-part room temperature vulcanizable polyorganosiloxane composition; and component B, an ice release-enhancing proportion of at least one polyorganosiloxane comprising one or more silanol or alkoxy-silyl groups and comprising from about 10 weight percent to about 85 weight percent of at least one hydroxy-terminated or alkoxy-terminated polyoxyalkylenealkyl radical; and any reaction products thereof.

Abstract: Hydrophobicizing additives are water-redispersible powders or aqueous dispersions containing: a) water-insoluble, film-forming base polymer(s) based on homopolymers or copolymers of one or more vinyl esters of optionally branched C1-15 alkylcarboxylic, (meth)acrylic esters of C1-15 alcohols, vinylaromatics, olefins, dienes and vinyl halides, b) one or more hydrophobic organosilicon compounds, fatty acids, or derivatives thereof, or hydrocarbon waxes, and c) one or more protective colloids, wherein the proportion of the component b) based on the total weight of the component a) is more than 30% by weight.

Abstract: A thermoconductive silicone elastomer comprising a silicone elastomer being a cured body of a hydrosilation-curable organopolysiloxane composition, a reinforcement fine silica powder, a thermoconductive inorganic powder, and an alkylphenylpolysiloxane that is liquid at room temperature. A hydrosilation-curable thermoconductive silicone elastomer composition comprising: a hydrosilation-curable organopolysiloxane composition, a reinforcement fine silica powder, a thermoconductive inorganic powder, and an alkylphenylpolysiloxane that is liquid at room temperature. A thermoconductive medium comprising the aforementioned thermoconductive silicone elastomer.

Abstract: A composition for forming a silica-based coating film includes a siloxane polymer and an alkali metal compound. The siloxane polymer is preferably a hydrolysis-condensation product of a silane compound having a hydrolyzable group. Sodium, lithium, potassium, rubidium, or cesium, or the like is used as the alkali metal of the alkali metal compound. Furthermore, the alkali metal compound is preferably a nitrate, sulfate, carbonate, oxide, chloride, bromide, fluoride, iodide, or hydroxide of the above alkali metal. This composition for forming a silica-based coating film may also include a pore-forming material. At least one material selected from amongst polyalkylene glycols and alkyl-terminated derivatives thereof is used as the pore-forming material.

Abstract: Process for preparing surface-modified silicon dioxide particles with a mean particle diameter of at most 100 nm, comprising the steps of: a) providing a predispersion b) high-pressure grinding of the predispersion to form a dispersion c) removing the liquid phase of the dispersion, the predispersion comprising a1) surface-modified silicon dioxide particles which are at least partly aggregated, are bonded to the surface-modifying component via Si—O—Si bonds and still have reactive groups on their surface, a2) one or more organosilicon compounds which have at least one silicon-carbon bond and at least one functional group which can react with the reactive groups to form a covalent Si—O—Si bond, and a3) one or more solvents. Redispersible, surface-modified silicon dioxide particles obtainable by this process. Use of these in toner powders, silicone rubber, adhesives and scratch-resistance surface coatings.

Abstract: The present invention is a release liner including a film formed of a thermoplastic polymer and a non-migratory silicone additive. The additive is formed with a siloxane polymer that can be added directly to the thermoplastic polymer prior to compounding the thermoplastic polymer into an extrudable release liner film. The additive provides the desired release properties to the film, and due to bonds formed between the siloxane polymer and a binding component added to the siloxane polymer during formation of the additive, as well as the high molecular weight of the siloxane polymer, is non-migratory.

Abstract: A method of controlling oil-absorbing properties of a silicone rubber powder characterized by keeping a silicone rubber powder in hot storage at a temperature in the range of 40° C. to 150° C. or in cold storage at a temperature in the range of 0° C. to 10° C.

Abstract: There is provided herein, in one specific embodiment, silicone composition(s) comprising unique combination(s) of silicone polymer and alkyltrisiloxane(s) which can produce silicone composition(s) with lower solids content than silicone compositions that use other than alkyltrisiloxane(s); while still maintaining a desirable viscosity.

Abstract: Disclosed is a nanocomposite composition, comprising transparent nanoparticles, a matrix polymer including a polydimethylsiloxane resin and an epoxy group-containing polydimethylsiloxane resin, and a siloxane dispersant including a head part having an affinity for the transparent nanoparticles and a tail part having an affinity for the polydimethylsiloxane resin. The nanocomposite composition of this invention can be effectively used in the encapsulation layer of a light emitting diode or in an optical film.

Abstract: The invention provides a process for preparing SiOC-bonded polyorganosiloxanes by reacting, by processes known per se, hydroxyl-containing compounds with a stoichiometric excess of polyorganosiloxanes which contain —Si(H) units and are of the general formula (I) in the presence of one or more element compounds of main group III and/or of transition group 3 as a catalyst, wherein the reaction, on completion of conversion of the compounds containing hydroxyl groups, is continued until no further ?Si—H groups are detectable by gas volumetric means, and also the compounds prepared in this way and their use.

Abstract: A core-shell particle is formed by a method that includes forming a crosslinked polyorganosiloxane core, reacting a graftlinking agent with the crosslinked polyorganosiloxane core, and polymerizing a poly(alkenyl aromatic) shell around the graftlinking agent-functionalized polyorganosiloxane core. The method produces a core-shell particle with improved adhesion between shell and core. The core-shell particle is useful as an impact modifier in thermoplastic compositions.

Abstract: The liquid, polymer-containing coating materials of this invention comprise a polymer of a polymerizable, nitrogen-containing, hydrophilic monomer, which may give thermoresponsive properties, and which is copolymerized with a hydrophobic, polymerizable siloxy-containing monomer, in a solvent system of a volatile hydrophobic (non-polar) liquid that is non-stinging to a user. The material forms a coating or bandage in the form of a film when applied to a surface or the skin of a user.

Abstract: An anti-smudge agent which is added to a coating composition for imparting smudge proof property with the coating composition, comprising a silicone resin containing a fluorine atom-containing organic group, which has a number average molecular weight of at least 1,000 and a molar ratio of the fluorine atom to the silicon atom (F/Si) of 3 to 50, said silicone resin being produced by hydrolyzing or condensing an organosilicon compound having a fluorine atom-containing organic group represented by the following general formula (I): R1R2mSiX3?m??(I) wherein R1 is a fluorine atom-containing organic substituent, R2 is a substituted or unsubstituted alkyl group or phenyl group containing 1 to 10 carbon atoms, X is a hydrolyzable group or OH group, and m is 0 or 1; or a hydrolysate or a partial condensate thereof.

Abstract: An anti-fouling coating composition comprising (i) a curable polymer and (ii) an organosilicone polymer. This anti-fouling coating composition has a low surface energy, has suitable elastomeric properties, decreases the settlement of fouling organisms and their adhesion strength, and can be used as a clear coat without a misty or milky appearance.

Abstract: A curable organopolysiloxane composition is provided, which includes (A) an organopolysiloxane containing at least one silicon atom-bonded alkenyl group within each molecule, (B) an organohydrogenpolysiloxane, which contains, within each molecule, at least one silicon atom-bonded hydrogen atom at a molecular chain terminal, and at least two silicon atom-bonded hydrogen atoms at non-terminal positions within the molecular chain, and which satisfies the formula shown below: 0<?/?0.25 (wherein, ? represents the number of silicon atom-bonded hydrogen atoms at non-terminal positions within the molecular chain, and ? represents the total number of silicon atoms within the component (B)), in sufficient quantity to provide from 0.1 to 5 silicon atom-bonded hydrogen atoms per silicon atom-bonded alkenyl group within the component (A), and (C) a platinum-based catalyst.

Abstract: It is an object of the present invention to provide a rubber composition which has been improved in mechanical properties with maintaining excellent various properties and is favorably used for a fuel cell sealing member, a hard disc drive top cover gasket member and an electric wire connector sealing member. It is another object of the present invention to provide main bodies mounted with the above respective members obtained by the use of the rubber composition. The rubber composition of the invention comprises a specific ethylene/?-olefin/non-conjugated polyene copolymer in which the non-conjugated polyene is a norbornene-based compound, a specific SiH group-containing compound, and if necessary, an organopolysiloxane. Such a rubber composition of the invention is excellent in mechanical properties and can be particularly favorably used for a fuel cell sealing member, a hard disc drive top cover gasket, an electric wire connector sealing member, etc.

Abstract: A method of making silicone-based foam control agents comprising: i) preparing a polysiloxane containing polymer by the polymerisation of siloxane containing monomers and/or oligomers in the presence of an inert organopolysiloxane and/or an organic fluid, a suitable catalyst and optionally an end-blocking agent; ii) where required quenching the polymerisation process; wherein the inert organopolysiloxane and/or organic fluid is substantially retained within the resulting diluted polysiloxane containing polymer; iii) introducing from 0.1 to 10% by weight of a suitable filler prior to during or subsequent to step (i); iv) optionally introducing up to 5% by weight of a suitable silicone resin during or subsequent to step (i) and v) where required, adapting the foam control agent produced in steps (i) to (iv) into a suitable form of delivery therefor.

Abstract: Pressure sensitive adhesives and methods, wherein the adhesives include a silicone tackifying resin and a polydiorganosiloxane polyurea copolymer. The tack of these adhesives is improved by the use of a processing aid, such as a plasticizer.