Silicon Containing Sicp Or Solid Polymer Patents (Class 524/268)
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Patent number: 5679734Abstract: The present invention relates more specifically to silicone compositions which can be crosslinked into an adhesive gel by hydrosilylation at room temperature, as well as to the gels thus obtained. One of the objects of the invention is to produce, easily and rapidly, gels having viscoelastic qualities, low-temperature physical stability and adhesion properties.This objective is achieved by virtue of the compositions comprising:a polyorganosiloxane POS (I) of the SiVi type (Vi=vinyl);a POS (II) of the SiH type;an extender POS (III) of the .alpha.,.omega.-hydrogen, SiH type; and, optionally, a diluent POS (IV) of the polydimethylsiloxane type; where ##EQU1## Application: protection of electronic equipment (potting), adhesives, prostheses.Type: GrantFiled: April 12, 1996Date of Patent: October 21, 1997Assignee: Rhone-Poulenc ChimieInventors: Pierre-Michel Peccoux, Christian Pusineri
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Patent number: 5668205Abstract: A silicone rubber composition of the addition curing type containing an organopolysiloxane having at least two aliphatic unsaturated hydrocarbon groups in a molecule, silica, an organohydrogenpolysiloxane, a platinum catalyst, and a liquid organopolysiloxane blocked with a (CH.sub.3).sub.3 SiO.sub.1/2 unit at either end, having a monovalent hydrocarbon group (exclusive of an aliphatic unsaturated hydrocarbon group) attached to a silicon atom, provides a composition heat curable to a silicone rubber having improved weathering and tracking resistance and thus useful for high-voltage electrical insulators. Also, a silicone rubber composition containing an organopolysiloxane, an inorganic filler and an organic peroxide is improved by using as the organopolysiloxane one or more organopolysiloxanes of the formula: R.sup.6.sub.f SiO.sub.(4-f)/2, and blending therein aluminum hydroxide.Type: GrantFiled: July 3, 1996Date of Patent: September 16, 1997Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takeo Yoshida, Azechi Shuuichi
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Patent number: 5668225Abstract: An oil-bleeding waterproof sealer for a connector comprising a vulcanized and molded article of a composition comprising: (A) 100 parts by weight of a diorganopolysiloxane green rubber containing at least two alkenyl groups bonded to silicon atoms per molecule thereof, (B) from 10 to 100 parts by weight of a reinforcing filler, (C) from 0.1 to 10 parts by weight of an organohydrogenopolysiloxane having at least two hydrogen atoms bonded to silicon atoms per molecule thereof, (D) from 1 to 30 parts by weight of a phenyl-containing diorganopolysiloxane having a viscosity of 1 to 3,000 cSt at 25.degree. C., and (E) a catalytic amount of a catalyst for hydrosilylation having a particle size of 0.01 to 20 .mu.m, which comprises a platinum catalyst and a non-silicone series thermoplastic resin having a glass transition point of 50.degree. to 200.degree. C., with the proportion of metallic platinum in the catalyst for hydrosilylation being 0.01 to 5% by weight.Type: GrantFiled: December 30, 1996Date of Patent: September 16, 1997Assignee: Yazaki CorporationInventors: Kiyotaka Okazaki, Sinichi Kogure, Masahiro Kanda, Shiroh Kobayashi
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Patent number: 5665804Abstract: The viscosity of a solvent is modified by thickening the solvent with a silicone latex. A silicone latex having a plurality of crosslinked polysiloxane particles is first prepared by mixing the siloxane polymer, a surfactant, and water; emulsifying the mixture to a gel phase; diluting the emulsion with water; adding a cure package (i.e., a catalyst, a crosslinker, or both, or a self catalytic crosslinker); and then without removing the water from the latex and after the particles of siloxane polymer in the latex have been cured, mixing the latex and solvent to thicken the solvent, forming viscous liquids, gels, and pastes. These latex thickened solvent compositions have beneficial properties such as clarity, shelf stability, and ease of preparation; and therefore have wide areas of application, especially as additives in antiperspirants, deodorants, and other personal care applications.Type: GrantFiled: February 5, 1996Date of Patent: September 9, 1997Assignee: Dow Corning CorporationInventors: Michael Philip Louis Hill, Eric Jude Joffre, Linda Moy Madore
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Patent number: 5658975Abstract: The instant invention pertains to a hot-melt pressure sensitive adhesive composition wherein the composition is comprised of a silicone pressure sensitive adhesive selected from the group consisting of a mixture of (i) a silicone resin and (ii) a silicone fluid and a condensed product of (i) and (ii); the silicone pressure sensitive adhesive exhibiting tackiness and adhesiveness; the silicone pressure sensitive adhesive being blended with (iii) from about 1 to 20 weight percent, based on the total weight of (i) and (ii), of a siloxylated polyether wax. The instant invention also encompasses method of using the composition, methods of making hot-melt silicone pressure sensitive adhesive-coated substrates, and devices made using the composition.Type: GrantFiled: May 15, 1995Date of Patent: August 19, 1997Assignee: Dow Corning CorporationInventors: Katherine Lynn Ulman, Randall Paul Sweet, Loren Dean Durfee
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Patent number: 5652287Abstract: A resin composition which comprises:(A) from about 99.5 to about 70 percent by weight, based on the total weight of components (A) and (B), of a poly(arylene sulfide) having a melt viscosity of from about 300 to about 8,000 poise at 1,200 sec.sup.-1 and 310.degree. C.;(B) from about 0.5 to about 30 percent by weight, based on the total weight of components (A) and (B), of a substantially non-functionalized, emulsion cured silicone rubber which is the condensation product of (i) an organopolysiloxane having at least two active hydrogen functional groups per molecule, and (ii) an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule, said silicone rubber being melt dispersable with the poly(arylene sulfide); and(C) from about 0.1 to about 2.0 parts by weight, based on 100 parts by weight of components (A), (B) and (C) combined, of an aminosilane, wherein said composition has been prepared by combining components B and C with component A in the absence of a dispersion medium.Type: GrantFiled: April 10, 1996Date of Patent: July 29, 1997Assignee: Hoechst Celanese CorporationInventors: Vincent J. Sullivan, Andrew B. Auerbach
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Patent number: 5633302Abstract: A method for the preparation of a non-yellowing one-package room-temperature-curable silicone elastomer composition that prior to its cure is highly workable and that during its cure does not crack or fissure even when deformed by an outside force. The method comprises as step one mixing of silanol-containing polydiorganosiloxane and inorganic filler; as step two admixing vinyltrioximosilane into the mixture of step one; and as step three admixing an alkyltrioximosilane into the mixture of step two.Type: GrantFiled: November 21, 1995Date of Patent: May 27, 1997Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Hiroshi Adachi, Toshio Saruyama
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Patent number: 5633303Abstract: An organopolysiloxane gum emulsion is afforded by the emulsification of an organopolysiloxane gum in water. The organopolysiloxane gum emulsion is useful as a cosmetic base, lustrant, lubricant, antifoam, fiber-treatment agent, and paint additive. The organopolysiloxane gum emulsion includes(A) 100 weight parts organopolysiloxane gum whose plasticity at 25.degree. C. is at least 0.75 mm,(B) 1 to 100 weight parts emulsifying agent, and(C) 3 to 800 weight parts water.Type: GrantFiled: January 11, 1996Date of Patent: May 27, 1997Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Hidetoshi Kondo, Tadashi Hamachi, Hidehiko Hosokawa, Fumitaka Suto, Junichi Maeshima
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Patent number: 5631312Abstract: A floor paint composition superior in resistance to oil and solvents, and in early strength. The composition is mainly composed of a synthetic resin emulsion based on an from anion copolymer obtained from the copolymerization of .alpha.-type hemihydrate gypsum, cement and ethylene unsaturated monomer. The ratio of weight of .alpha.-type hemihydrate gypsum to cement is between 80:20 and 95:5. The ratio of the solid content of the synthetic resin relative to 100 parts by weight of the mixture of .alpha.-type hemihydrate gypsum and cement is between 15 and 35 parts by weight. The anion copolymer contains at least one unit of a monomer selected from the group consisting of ethylene unsaturated carboxylic acid, ethylene unsaturated sulfonic acid and ethylene unsaturated phosphonic acid. The copolymer can include an ethylene unsaturated monomer having at least one organic silicon radical. The synthetic resin emulsion can include epoxy silane.Type: GrantFiled: May 21, 1996Date of Patent: May 20, 1997Assignees: Kikusui Chemical Industries Co., Ltd., Hoechst Industry LimitedInventors: Izumi Takada, Noriyuki Niwa, Ikuo Imaizumi
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Patent number: 5612400Abstract: Silicone pressure sensitive adhesive compositions are provided which are free of volatile organic solvents. Silicone fluids in the form of cyclic or linear organosiloxanes, and having a boiling point at atmospheric pressure of 250.degree. C. or less, are used in combination with an organopolysiloxane gum and an organosiloxane hydrolyzate of SiO.sub.2 units and triorganosiloxy units.Type: GrantFiled: June 6, 1995Date of Patent: March 18, 1997Assignee: General Electric CompanyInventors: David C. Gross, Shaow B. Lin, Peter M. Miranda
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Patent number: 5612438Abstract: Novel curable siloxane polymers having integral ultra-violet light absorbers are disclosed which are useful in preparing a variety of commercial silicone products requiring excellent resistance to loss of UV protection due to external forces.Type: GrantFiled: October 25, 1995Date of Patent: March 18, 1997Assignee: General Electric CompanyInventors: William J. Raleigh, Raymond J. Thimineur, James A. Campagna
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Patent number: 5607993Abstract: The present invention provides a bouncing putty with low density and other desirable properties. The density is preferably between 0.33 and 0.95 g/cc, preferably between about 0.5 and 0.75 g/cc and particularly preferably about 0.6 g/cc. Borosilicone rubber base is mixed with density-reducing filler, preferably in the form of thermoplastic microspheres. Addition of a thinning agent reduces stiffness and addition of a lubricating oil improves the handling characteristics. A moisture scavenger can be added to maintain the characteristics of the bouncing putty even if some moisture is absorbed during use. A polarity modifier such as glycerine can be added to soften the putty. If desired, a colorant can be added as well.Type: GrantFiled: February 28, 1994Date of Patent: March 4, 1997Assignee: North Coast Medical, Inc.Inventor: Michael Christy
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Patent number: 5607721Abstract: The instant invention pertains to a hot-melt pressure sensitive adhesive composition wherein the composition is comprised of a silicone pressure sensitive adhesive selected from the group consisting of a mixture of (i) a silicone resin and (ii) a silicone fluid and a condensed product of (i) and (ii); the silicone pressure sensitive adhesive exhibiting tackiness and adhesiveness; the silicone pressure sensitive adhesive being blended with (iii) from about 1 to 20 weight percent, based on the total weight of (i) and (ii), of a siloxylated polyether wax. The instant invention also encompasses method of using the composition, methods of making hot-melt silicone pressure sensitive adhesive-coated substrates, and devices made using the composition.Type: GrantFiled: May 15, 1995Date of Patent: March 4, 1997Assignee: Dow Corning CorporationInventors: Katherine L. Ulman, Randall P. Sweet, Loren D. Durfee
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Patent number: 5580917Abstract: Hydrostatically damping, shock and vibration energy absorbing, non-vulcanisable silicone elastomer is composed of a methylphenylsilicone polymer in which as on the matrix a condensation of polydimethyl- or/and methylhydrosiloxane diols are condensed with reactive compounds of silicon, boron or nitrogen giving the viscous polymer appropriate elasticity coefficient by forming mobile hydrogen bonds. The elastomer according to the invention contains also fillers and lubricants.Type: GrantFiled: August 25, 1994Date of Patent: December 3, 1996Inventors: Jeremi Maciejewski, Antoni Kubicki
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Patent number: 5576378Abstract: Polymers with a high glass transition temperature are used in cement additives to produce a portland cement mortar or concrete that does not have the initial stickiness typical of prior art polymer-modified portland cement compositions and does not form a crust on the surface when exposed to air drying, thus improving the working time of the mix. This simplifies equipment cleaning and permits the use of transit mixers for field applications of polymer-modified concrete. The properties of the mortar and concrete modified with these materials, both in the plastic and hardened state, are equivalent or superior to those of the currently available products which use film-forming materials. Within the scope of this invention are a redispersible powdered cement additive, a redispersible polymer powder and a ready-to-use portland cement composition, as well as related processes.Type: GrantFiled: February 24, 1994Date of Patent: November 19, 1996Assignee: The Dow Chemical CompanyInventors: Louis A. Kuhlmann, James W. Young, Jr., Daniel Moldovan
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Patent number: 5571853Abstract: A gel-forming silicone composition comprising (A) an organopolysiloxane containing a silicon-bonded alkenyl group or groups in an average amount of from 0.15 to 0.35 mol % based on all silicon-bonded organic groups contained per molecule, (B) a non-functional organopolysiloxane, (C) an organohydrogenpolysiloxane containing an average of 2 silicon-bonded hydrogen atoms per molecule, and (D) an addition reaction catalyst. The silicone composition is able to give a gel-like cured silicone product with low modulus of elasticity while retaining flexibility.Type: GrantFiled: July 20, 1995Date of Patent: November 5, 1996Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masayuki Ikeno, Hironao Fujiki
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Patent number: 5561191Abstract: Method for the production of a thermostable crosslinked PVC copolymer where the crosslinking is carried out in the presence of humidity and after processing of the polymer. The copolymer is a copolymer of vinyl chloride and 0.05-10 weight % of a vinyl containing alkoxysilane compound. Preferably methacryloxy-propyltrimethoxy-silane or methacryloxy-propyltriethoxysilane is used as comonomer. The crosslinking can be carried out independent of the type of stabilizer. A condensation catalyst and also an inhibitor can be used to prevent too early crosslinking.Type: GrantFiled: March 6, 1995Date of Patent: October 1, 1996Assignee: Norsk Hydro A.SInventors: Morten Lundquist, Jan O. Laundal
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Patent number: 5559180Abstract: A polyacetal composition is provided for use in plastic-plastic wear applications, said composition containing about 85 to 99 weight percent polyacetal, about 0 to 5 weight percent polytetrafluoroethylene fibers, about 0.5 to 5 weight percent ethylene methyl acrylate copolymer, and about 0.5 to 5 weight percent of at least one lubricant. The compositions are particularly useful in forming shaped articles for use especially in conveyor chain applications and gear applications.Type: GrantFiled: April 3, 1995Date of Patent: September 24, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Tatsuhiro Takahashi, Edmund A. Flexman, Robert J. Kassal
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Patent number: 5556902Abstract: The present invention provides a silicone antifoaming agent composition excellent in the persistence of the foam controlling effect. The silicone antifoaming agent composition comprises a polydiorganosiloxane and silica, which form an antifoaming agent to be improved, and 4 to 2,500 parts by weight per 100 parts by weight of the sum total of the polydiorganosiloxane plus silica of a modified silicone oil having at least one organic group bonded to a silicon atom and having at least one functional group selected from among epoxy, amino, amide, carboxyl, alkoxyl and hydroxyl groups and at least one substituted or unsubstituted polyoxyalkylene group bonded to a silicon atom.Type: GrantFiled: November 6, 1990Date of Patent: September 17, 1996Assignee: Dow Corning K.K.Inventors: Hiroaki Shouji, Koichi Aizawa
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Patent number: 5554681Abstract: The present invention comprises multi-color textured powder coatings comprising solid silicone resin and a mixture of polyacrylate and silica for application to exterior surfaces of a metal substrate, such as the metal substrate of cookware, bakeware, kitchen appliances, or barbecue grill, to improve the heat resistance characteristics at elevated temperatures of at least 150.degree. F.Type: GrantFiled: August 4, 1995Date of Patent: September 10, 1996Assignee: Coatings America Inc.Inventor: Rajendra Patel
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Patent number: 5534560Abstract: The compound for the correct taking of dental impressions is in a liquid solution and includes a surface-active substance, compatible with silicone materials, combined with a solvent. A very light color and a flavoring agent are advantageously added.Type: GrantFiled: March 12, 1993Date of Patent: July 9, 1996Assignee: Zhermack S.p.A.Inventors: Tiziano Busin, Enrico Faccio
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Patent number: 5525660Abstract: An organopolysiloxane composition contains (A) a both end hydroxyl-blocked diorganopolysiloxane, (B) an inert diorganopolysiloxane, (C) a silane or siloxane having at least three hydrolyzable functional groups, (D) an organosilane having at least two alkoxy groups each attached to a silicon atom and one mercapto group separated from a silicon atom by an alkylene group or a partial hydrolyzate thereof, (E) an organosilane having at least two alkoxy groups each attached to a silicon atom and one amino group separated from a silicon atom by an alkylene group or a partial hydrolyzate thereof, (F) a condensation catalyst, and (G) a fine powder, typically of polycarbonate, having a mean particle size of 0.1-50 .mu.m. The composition is useful as a surface treating agent for cured rubber moldings for imparting non-tackiness, water repellency and lubricity to the rubber surface and forming a long-lasting abrasion resistant coating.Type: GrantFiled: December 6, 1994Date of Patent: June 11, 1996Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Mikio Shiono, Kazumi Okada
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Patent number: 5519080Abstract: An insulator includes a housing portion. The housing portion is composed a silicone rubber obtained by curing a composition containing diorganopolysiloxane (A) and a fine silicon powder (B) by heating, and a methylalkylpolysiloxane oil (C). The diorganopolysiloxane has at least two silicon atom-bonded alkenyl groups in one molecule. The methylalkyl-polysiloxane oil (C) has each of both terminal ends of each molecular chain blocked with a trialkysiloxy group and possessing a viscosity at 25.degree. C. being 1 to 1,000 centistokes, and is incorporated into the above composition in an amount of 1-100 parts by weight per 100 parts by weight of the component (A).Type: GrantFiled: August 10, 1994Date of Patent: May 21, 1996Assignees: Dow Corning Toray Silicone Co., Ltd., NGK Insulators Ltd.Inventors: Takao Matsushita, Katsuya Baba, Kazuo Hirai, Isao Nakajima, Takayuki Takeda
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Patent number: 5516823Abstract: Adhesion-promoting additives for use in curable organosiloxane compositions comprise 1) at least one organosiloxane comprising a) silicon bonded hydrogen atoms and/or ethylenically unsaturated substituents bonded to silicon through carbon and b) at least one silicon atom containing three hydrolyzable groups, and 2) at least one silane containing four alkoxy or enoloxy groups or three of these groups and a hydrocarbon radical containing an epoxy or ethylenically unsaturated group as a substituent.Type: GrantFiled: May 10, 1994Date of Patent: May 14, 1996Assignee: Dow Corning CorporationInventors: Theresa E. Gentle, Michael A. Lutz
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Patent number: 5516812Abstract: A radiation and moisture curable silicone conformal coating composition comprises a silicone fluid of a monovalent ethylenically unsaturated functional group endcapped silicone and at least one (meth)acryl-functionalized silicone; and a photoinitiator effective for radiation curing of the silicone composition. The encapped silicone is the product of a reaction between a silanol terminated silicone and a silane cross linker having joined directly to a silicon atom thereof a monovalent ethylenically unsaturated functional group and at least 2 hydrolyzable groups.Type: GrantFiled: August 1, 1994Date of Patent: May 14, 1996Assignee: Loctite CorporationInventors: Hsien K. Chu, Robert P. Cross, Lester D. Bennington
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Patent number: 5512376Abstract: A reactive component, which is curable to form a nonpolar polymer containing silicon and carbon atoms, and having a glass transition temperature of at least 20.degree. C., is mixed with an antiplasticizer. The resulting mixture, a curable composition, is cured to form a composition having an increased modulus. The reactive component preferably comprises a polyene having at least two hydrosilation reactive carbon-carbon double bonds (e.g., dicyclopentadiene), and a silicon compound having at least two hydrosilation reactive .ident.SiH groups. Preferably the silicon compound comprising at least one member selected from the group consisting of cyclic polysiloxanes, tetrahedral siloxysilanes, and linear polysiloxanes. Preferably the resulting cured composition is crosslinked, due to at least one member selected from the group consisting of the polyene and the silicon compound having more than two hydrosilation reactive sites. Preferably the curable composition further comprises a hydrosilation catalyst.Type: GrantFiled: June 20, 1994Date of Patent: April 30, 1996Assignee: Hercules IncorporatedInventors: Richard L. Brady, Samuel A. Thompson
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Patent number: 5508321Abstract: An intumescent silicone rubber composition is provided having an expandable intumescent material present in the composition by up to 20% by weight, a polyorganosiloxane oil present in an amount from about 10% to about 40% by weight of the composition, a hydrated alkali metal silicate present in an amount of up to 80% by weight of the composition and a silicone elastomer binder present in an amount from about 4% to about 30% by weight of the composition. The result is a very effective and relatively inexpensive composition which when used as firestop material around combustible pipe, such as PVC or ABS, readily meets the test criteria set forth under ASTM Standard E-814.Type: GrantFiled: October 5, 1994Date of Patent: April 16, 1996Inventor: Keith I. Brebner
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Patent number: 5489482Abstract: A film forming composition, comprising an amine-modified highly polymerized polysiloxane represented by the general formula (1): ##STR1## wherein R, which are the same or different, each represent a monovalent hydrocarbon group having 1 to 6 carbon atoms, a hydroxyl group, or a hydrogen atom, R' each represent an amino-group-containing organic group, a is an integer of 0 to 3, m is an integer of 1 or more, and n is an integer of 5 or more, provided that m+n is an integer of 2,000 or more, and dissolved in an organic solvent, which film forming composition can give a smooth soft film that is excellent in water repellency, water resistance, touch, and durability in comparison with the conventional film forming compositions.Type: GrantFiled: November 10, 1994Date of Patent: February 6, 1996Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masahiko Minemura, Osamu Uchida
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Patent number: 5482988Abstract: The instant invention pertains to a hot-melt pressure sensitive adhesive composition wherein the composition is comprised of a silicone pressure sensitive adhesive selected from the group consisting of a mixture of (i) a silicone resin and (ii) a silicone fluid and a condensed product of (i) and (ii); the silicone pressure sensitive adhesive exhibiting tackiness and adhesiveness; the silicone pressure sensitive adhesive being blended with (iii) from about 1 to 20 weight percent, based on the total weight of (i) and (ii), of a siloxylated polyether wax. The instant invention also encompasses method of using the composition, methods of making hot-melt silicone pressure sensitive adhesive-coated substrates, and devices made using the composition.Type: GrantFiled: January 14, 1994Date of Patent: January 9, 1996Assignee: Dow Corning CorporationInventors: Katherine L. Ulman, Randall P. Sweet, Loren D. Durfee
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Patent number: 5476892Abstract: Polyols are conditioned and stabilized by mixing them at 0 to 150.degree. C. with from about 0.0001 to about 1% by weight, based on the quantity of polyol, of a silylated acid corresponding to the formula:X--[Si(CH.sub.3).sub.3 ].sub.nin whichX represents a neutral acid residue obtained by removal of the acidic hydrogen atoms from an n-basic acid having a maximum pKa value of 3, provided that the n-basic acid is not a hydrohalic acid andn represents an integer of from 1 to 3.The resultant polyol is characterized by good color and activity properties. The stabilized polyols are particularly useful in the production of polyurethanes, particularly polyurethane foams.Type: GrantFiled: December 9, 1993Date of Patent: December 19, 1995Assignee: Bayer AktiengesellschaftInventors: Hans J. Scholl, Hartmut Nefzger, Helmut Reiff, Bernd Quiring
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Patent number: 5475044Abstract: Addition-curable platinum group metal catalyzed silicone compositions are provided which utilize a bis(trialkyloxysilyl)alpha-amino ester as an adhesion promoter. Cohesive bonding is effected on both plastic and metal substrates at temperatures of about 100.degree. C. in an hour or less.Type: GrantFiled: December 29, 1994Date of Patent: December 12, 1995Assignee: General Electric CompanyInventor: Judith Stein
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Patent number: 5432218Abstract: The introduction of a room-temperature-curable organopolysiloxane composition that cures at room temperature to give a rubber whose surface is easily coated with paint and from which the resulting paint film does not delaminate readily and that after curing is free from staining of the surface of the rubber and any substrates in contact with the rubber.Type: GrantFiled: May 20, 1994Date of Patent: July 11, 1995Assignee: Dow Corning Toray Silicon Co., Ltd.Inventors: Ryuzo Mikami, Hisataka Nakashima, Tadashi Okawa, Shigeki Sugiyama
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Patent number: 5430082Abstract: An elastomer-forming silicone composition comprising (A) a vinyl-organopolysiloxane, (B) an organosilicon compound, (C) a noble metal catalyst and (D) an adhesion promoter characterised in that the adhesion promotor is the product of the mixture or reaction of (1) an organosiloxane compound having at least two trialkoxysilyl groups, (2) an unsaturated alcohol having at least one .alpha.,.beta.-unsaturated alkenyl group and has improved adhesion without the toxic disadvantages of the prior art.Type: GrantFiled: December 20, 1993Date of Patent: July 4, 1995Assignee: Dow Corning GmbHInventor: Peter O. Bentz
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Patent number: 5418280Abstract: A sealant or mastic composition comprises a dispersion of a finely divided particulate solid in a silicone resin formulation which contains a dispersant containing at least one group of the formula--(O--A--CO).sub.n --.The dispersant may be derived from a hydroxycarboxylic acid and preferably has a --COOH end group. The dispersant modifies the shear properties of the sealant.Type: GrantFiled: August 25, 1989Date of Patent: May 23, 1995Assignee: Imperial Chemical Industries PLCInventor: Kevin L. Birkett
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Patent number: 5409963Abstract: A silicone composition capable of being cured by both a moisture-curing mechanism and an ultraviolet (UV) curing mechanism is provided. The silicone composition comprises:1 a reactive organosiloxane prepared by a condensation reaction of a silicone (1) represented by the general formula ##STR1## where R.sup.1 and R.sup.2 are each an organo group, and a is a number corresponding to a kinematic viscosity of 25-50,000 cSt, measured at 25.degree. C., with a vinyl ether silane compound represented by the general formula: ##STR2## where m and n are each an integer of 1 to 5, R.sup.3 and R.sup.4 are each an alkyl group having 1 to 3 carbon atoms or allyl, and b is 0 or 1;2 0-70 parts by weight of a silicone oil having trimethylsilyl group as an end group;3 a catalytic amount of a photopolymerization catalyst; and4 a catalytic amount of a silicone moisture-curing catalyst.Type: GrantFiled: December 28, 1993Date of Patent: April 25, 1995Assignee: Three Bond Co., Ltd.Inventor: Toru Takfoka
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Patent number: 5405908Abstract: An improvement is proposed for an acrylic rubber composition to decrease the stickiness of the rubber composition under processing and shaped and vulcanized articles of the composition to a metallic surface with which the rubber article is kept in contact at an elevated temperature under compression as is the case in packings, gaskets and O-rings as automobile parts. The improvement can be obtained by compounding the rubber composition consisting of an acrylic rubbery polymer, which can be substituted by organosilicon groups, and a reinforcing filler with a limited amount of a specific diorganopolysiloxane, e.g., dimethyl polysiloxane, of which from 5 to 50% in number of the organic groups bonded to the silicon atoms are phenyl groups.Type: GrantFiled: January 7, 1994Date of Patent: April 11, 1995Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masaharu Takahashi, Naoki Omura
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Patent number: 5405888Abstract: A photocurable and moisture-curable silione composition comprising a reactive organosilane which has acryldialkoxysilyl or acryldiallyloxysilyl groups at both ends, a silicone oil, a photosensitizer and a moisture-curing catalyst.Type: GrantFiled: December 28, 1993Date of Patent: April 11, 1995Assignee: Three Bond Co, Ltd.Inventor: Toru Takeoka
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Patent number: 5405896Abstract: An adhesive silicone rubber composition of addition reaction curing type comprising (a) an organopolysiloxane containing an alkenyl group; (b) an organohydrogenpolysiloxane having at least one hydrogen atom directly attached to a silicon atom in a molecule; (c) an addition reaction catalyst; and (d) an adhesive agent selected from compounds of the following formulae (I), (II) and (III):A-(D-B).sub.x -D-A (I)C-(B-D).sub.Type: GrantFiled: December 9, 1993Date of Patent: April 11, 1995Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hironao Fujiki, Shigeki Shudo, Akira Matsuda
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Patent number: 5403891Abstract: A composition useful in the fabrication of extruded articles contains a thermoplastic resin such as polyethylene and from 100-3,000 parts per million of a lubricant which is (i) an organosilicon resinous copolymer having a number average molecular weight of between 1,200-10,000 and R.sub.3 SiO.sub.1/2, R.sub.2 SiO.sub.2/2, RSiO.sub.3/2 and SiO.sub.4/2 units, wherein R is a C.sub.1 -C.sub.6 alkyl, aryl, alkenyl and/or trifluoropropyl radical(s); or (ii) the organosilicon resinous copolymer and a siloxane polymer R.sub.3 SiO(R.sub.2 SiO).sub.n SiR.sub.3 wherein R is as defined heretofore and n is 1-100,000; or (iii) the organosilicon resinous copolymer and an absorbing filler such as silica; or (iv) the organosilicon resinous copolymer, the siloxane polymer and an absorbing filler.Type: GrantFiled: April 8, 1994Date of Patent: April 4, 1995Assignee: Dow Corning CorporationInventor: David J. Romenesko
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Patent number: 5403881Abstract: A room-temperature-curable composition is very storage stable under seal at room temperature, cures to give a rubbery elastic material with excellent physical properties, and is useful as a sealant composition when polyoxyalkylene has at the terminals groups of the formula ##STR1## of which one example of a organosiloxane-modified polyoxyalkylene is ##STR2## in which Me is methyl.Type: GrantFiled: October 22, 1993Date of Patent: April 4, 1995Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Tadashi Okawa, Shigeki Sugiyama, Shuji Yamada
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Patent number: 5399602Abstract: The composition of the present invention comprises an oil-resistant silicone rubber composition that undergoes little swelling even when used in regular or continuous contact with mineral oil-based lubricating oil such as engine oil and so forth. The oil-resistant silicone rubber composition comprises:(A) a dimethylsiloxane-3,3,3-trifluoropropylmethylsiloxane-methylvinylsiloxane copolymer gum that contains 0.001 to 5 mole percent methylvinylsiloxane unit,(B) a hydrocarbon oil or diorganopolysiloxane oil wherein the total in each diorganopolysiloxane oil molecule of the number of silicon-bonded hydrogen atoms and the number of functional groups reactive with component (A) or (C) is less than two,(C) a reinforcing filler, and(D) a curing agent in a quantity sufficient to cure the composition.Type: GrantFiled: August 1, 1994Date of Patent: March 21, 1995Assignee: Dow Corning Toray Silicone, Co. Ltd.Inventors: Takao Matsushita, Yasumichi Shigehisa
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Patent number: 5391691Abstract: A process for producing an aromatic polycarbonate with improved heat resistance comprising melt polycondensing an aromatic diol compound and a carbonic acid diester compound in the presence of an interesterification catalyst and in the co-presence of an organosilicon compound.Type: GrantFiled: October 22, 1993Date of Patent: February 21, 1995Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Masuzo Yokoyama, Kazuhide Takakura, Junji Takano
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Patent number: 5384075Abstract: An addition-curable type organopolysiloxane composition having a volume resistivity of 10.sup.7 .OMEGA.cm or below, comprising (A) an organopolysiloxane having at least two alkenyl group in its molecule and a viscosity at 25.degree. C. of from 100 to 200,000 cSt, (B) an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms in its molecule, (C) a platinum group metal catalyst, (D) an organosilicon compound which has at least one silicon-bonded hydrogen atom in its molecule and in which at least one member selected from the group consisting of epoxy group-containing organic groups and alkoxy groups is attached to a silicon atom, and (E) an electrically conductive filler. This composition can be cured by an ultra high frequency heating system to form an adhesive cured product. It is therefore possible to obtain cured products with stable physical properties under constantly fixed conditions irrespective of the heat capacity of adherends.Type: GrantFiled: March 26, 1993Date of Patent: January 24, 1995Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Takehide Okami
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Patent number: 5370936Abstract: The release film-forming organopolysiloxane composition in accordance with the present invention is characterized by its ability to cure rapidly at relatively low temperatures not exceeding 100.degree. C. to yield a cured film that is strongly adherent for the surface of various types of substrates (e.g., synthetic films, paper, polyethylene-laminated paper, etc.) and that also exhibits excellent release properties for tacky substances.Type: GrantFiled: July 21, 1993Date of Patent: December 6, 1994Assignee: Dow Corning Toray Silicone Co., Ltd.Inventor: Nobuo Kaiya
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Patent number: 5364899Abstract: A flame-retardant resin composition comprising the following components:(A) 100 parts by weight of a polycarbonate resin,(B) from 0.0001 to 1 part by weight of a salt of a carboxylic acid with zinc,(C) at least one member selected from the group consisting of from 1 to 200 parts by weight of a filler, from 0.01 to 5 parts by weight of a fluorine-containing resin and from 0.01 to 5 parts by weight of a silicone.Type: GrantFiled: January 22, 1993Date of Patent: November 15, 1994Assignee: Denki Kagaku Koguo Kabushiki KaishaInventors: Jyun Watanabe, Noriak Kudo
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Patent number: 5360852Abstract: Organic pressure-sensitive adhesive and silicone pressure-sensitive adhesive composites have improved shear strength upon the addition of a silicone cross-linking agent.Type: GrantFiled: May 18, 1993Date of Patent: November 1, 1994Assignee: General Electric CompanyInventors: Frank J. Traver, Duane F. Merrill
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Patent number: 5352722Abstract: Hot-melt silicone pressure sensitive adhesive compositions containing alkylmethylsiloxane waxes and methods of using the compositions are disclosed. The hot-melt silicone pressure sensitive adhesive compositions include a mixture of (i) a silicate resin, (ii) a silicone fluid, and (iii) an alkylmethylsiloxane wax having a melting point of between 30.degree. C. and 70.degree. C. The alkylmethylsiloxane wax decreases dynamic viscosity of the adhesive compositions at temperatures ranging from about 50.degree. C. to about 200.degree. C.Type: GrantFiled: November 8, 1993Date of Patent: October 4, 1994Assignee: Dow Corning CorporationInventors: Randall P. Sweet, Loren Durfee, Katherine L. Ulman, Ross A. Noel
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Patent number: 5346932Abstract: The invention provides a silicone rubber composition which is efficiently curable by exposure to microwaves but, different from conventional microwave-curable silicone rubber compositions compounded with a deep-colored energy-absorbing agent, is still capable of being colored in any desired color because the energy-absorbing agent compounded therein is not colored. The energy-absorbing agent used here is a silica or polyorganosilsesquioxane powder having cyanoalkyl or fluoroalkyl groups bonded to the silicon atoms.Type: GrantFiled: August 19, 1992Date of Patent: September 13, 1994Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masaharu Takahashi, Jun Hatakeyama
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Patent number: 5346941Abstract: A siloxane powder composition which can impart improved lubricity character to a thermoplastic resin is disclosed, said composition being prepared by mixing(A) 100 parts by weight of a liquid polydiorganosiloxane and(B) 40 to 200 parts by weight of a silica powder that has a specific surface of at least 50 m.sub.2 /g using sufficient shear to prepare a powder in which the surface of component (B) is coated with component (A), and then mixing this powder with(C) 10 to 50 parts by weight of a polyorganosiloxane resin which is a solid at room temperature, said resin consisting essentially of (R.sub.3 SiO.sub.1/2) siloxane units and (SiO.sub.2) siloxane units in the molar ratio of 1:4 to 1:1,where R is selected from the group consisting of alkyl radicals and phenyl radical.Type: GrantFiled: May 17, 1993Date of Patent: September 13, 1994Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Haruhiko Furukawa, Akihiko Shirahata
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Patent number: 5346737Abstract: Incorporation of at least one lubricant and an ethylene-based polymer of the formula E/X/Y wherein E is ethylene, X is methyl acrylate, butyl acrylate, or ethyl acrylate, and Y is glycidyl methacrylate, glycidyl acrylate, or glycidyl vinyl ether into polyacetal compositions results in compositions having good wear resistance and good melt processing thermal stability. The compositions are useful, for example, when molded into parts to be used in sliding applications, such as gears, cams, and conveyor chains.Type: GrantFiled: July 16, 1993Date of Patent: September 13, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventors: Tatsu-Hiro Takahashi, Toshikazu Kobayashi