Solid Polymer Derived From Ethylenic Reactants Only Patents (Class 524/32)
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Patent number: 10472499Abstract: A resin composition includes a cellulose ester compound (A); polylactic acid (B); and a poly(meth)acrylate-based compound (C) having a weight-average molecular weight (Mw) of less than 50,000.Type: GrantFiled: February 28, 2018Date of Patent: November 12, 2019Assignee: FUJI XEROX CO., LTD.Inventors: Ryo Tanaka, Kana Miyazaki, Masahiro Moriyama, Kenji Yao
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Patent number: 9085097Abstract: A reinforced catheter or sheath includes an inner tube manufactured via an extrusion process from a mixture of thermoplastic and hollow glass beads. The resultant tube exhibits an inner goose bump surface that defines a central lumen. A reinforcement, such as a braid and/or coil is attached to at least a segment of the outer surface of the inner tube. A second tube of thermoplastic is extruded over at least a portion of the reinforcement. The inner goose bump surface exhibits a net low coefficient of friction comparable to that of polytetrafluoroethylene (PTFE).Type: GrantFiled: March 1, 2010Date of Patent: July 21, 2015Assignee: Cook Medical Technologies LLCInventors: David Christian Lentz, David A. Drewes, Jr.
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Patent number: 8802763Abstract: A curable organopolysiloxane composition in grease or paste form, which including: (A) an organopolysiloxane having at least two alkenyl groups bonded to silicon atom in one molecule; (B) an organohydrogenpolysiloxane having at least two hydrogen atoms bonded to silicone atom in the molecule; (C) gallium and/or a gallium alloy having a melting point of 0 to 70° C.; (D) a thermally conductive filler having an average particle size of 0.1 to 100 ?m; (E) a platinum-based catalyst; and (F) a polysiloxane of the following general formula (1): wherein R1 may be the same or different and represents a monovalent hydrocarbon group, R2 represents an alkyl group, an alkoxyl group, an alkenyl group or an acyl group, a is an integer of 5 to 100, and b is an integer of 1 to 3.Type: GrantFiled: October 3, 2012Date of Patent: August 12, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kunihiro Yamada, Nobuaki Matsumoto, Kenichi Tsuji
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Patent number: 8765870Abstract: A diluent for a fluorine-containing silicone coating agent, said diluent comprising (A) at least one selected from diisopropyl ether and hexane, and (B) a fluorinated solvent having a boiling point, at atmospheric pressure, which is higher than that of the component (A) by at least 30° C. and is 180° C. or lower, with a weight ratio of the component (A) to the component (B) ranging from 95/5 to 50/50.Type: GrantFiled: December 20, 2007Date of Patent: July 1, 2014Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Koichi Yamaguchi, Hirofumi Kishita
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Patent number: 8530547Abstract: To provide a chloroprene rubber composition with which a vulcanized rubber having further improved heat resistance without impairing mechanical properties, the compression set and the tension fatigue can be obtained, and a rubber member for an automobile, a hose, a rubber molded article and a rubber vibration insulator comprising the vulcanized rubber. A chloroprene rubber composition, which comprises 100 parts by mass of at least one chloroprene rubber selected from the group consisting of a xanthogen-modified chloroprene rubber and a mercaptan-modified chloroprene rubber, and from 15 to 200 parts by mass of carbon black having a number average particle size of from 70 nm to 600 nm and having a DBP oil absorption of from 15 ml/100 g to 60 ml/100 g by oil absorption method A of JIS K6221.Type: GrantFiled: September 12, 2008Date of Patent: September 10, 2013Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Yasushi Abe, Hiroyuki Ishiguro
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Publication number: 20130131221Abstract: A cellulose ester composition is provided comprising at least one cellulose ester and at least one additive selected from the group consisting of a compatibilizer, and a plasticizer. Processes for producing the cellulose ester composition are also provided. In another embodiment, a cellulose ester/elastomer composition is provided comprising at least one elastomer, at least one cellulose ester; and at least one additive; wherein the additive is at least one selected from the group consisting of a compatibilizer and a plasticizer. Processes for producing the cellulose ester/elastomer composition is also provided as well as articles comprising the cellulose ester/elastomer composition.Type: ApplicationFiled: November 30, 2012Publication date: May 23, 2013Applicant: Eastman Chemical CompanyInventor: Eastman Chemical Company
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Patent number: 8338507Abstract: The present invention relates to the use of phosphinic acids and/or phosphonic acids and salts thereof for wetting fluorine compounds, in particular fluoropolymers, to the use in coating solutions comprising fluorine compounds, and to polymerisation processes in which fluorine compounds are used and/or formed.Type: GrantFiled: November 22, 2008Date of Patent: December 25, 2012Assignee: Merck Patent Gesellschaft mit Beschränkter HaftungInventors: Wolfgang Hierse, Nikolai (Mykola) Ignatyev
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Patent number: 8263689Abstract: The invention relates to water-based adhesives for industrial applications obtained by mixing water-redispersible polymer powder and water-soluble polymer powder with water, wherein the weight ratio of the water-redispersible polymer powder to the water-soluble polymer powder is from about 0.001:1 to 100:1 and the water-based adhesive has a set speed of less than 300 sec, when measured with a 36 ?m thick layer at 23° C. and 50% relative humidity and 385 ?m thick carton boards with a weight of 275+/?3 g/m2 and Cobb values on one side of 43 g/min/m2 and 27 g/min/m2 on the other side, has a solids content of about 7.5 to 70 wt.-% and a Brookfield viscosity at 23° C. at 20 rpm, measured according to the ASTM D1084 standard, of about 500 to 10,000 mPas. The water-based industrial adhesive has the capability to bond a low surface tension substrate to a cellulosic substrate, in particular with a weight-ratio of water-redispersible polymer powder to water-soluble polymer powder from about 0.Type: GrantFiled: September 5, 2006Date of Patent: September 11, 2012Assignee: Henkel AG & Co. KGaAInventors: Nalini Patel, Rebecca Stopps, Christophe Magnin
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Patent number: 8247478Abstract: A thermoplastic resin composition of the present invention has high impact resistance, not lowering the weather resistance thereof, even though the amount of an impact resistance improver added thereto is small. The thermoplastic resin composition contains 100 parts by weight of (A) a thermoplastic resin and from 0.5 to 20 parts by weight of (B) a graft copolymer, wherein the graft copolymer (B) contains from 70% to 99% by weight of a crosslinked core (b2) prepared through polymerization of a monomer for the core (b2), containing 70% by weight or more of an acrylate, in the presence of from 0.5% to 20% by weight of a non-crosslinked seed (b1) having a weight-average molecular weight of 40,000 or less, and from 0.5% to 10% by weight of a shell (b3) prepared through polymerization of a monomer for the shell (b3) containing 50% by weight or more of a methacrylate, and the thermoplastic composition further contains from 0.01 to 3.Type: GrantFiled: February 7, 2007Date of Patent: August 21, 2012Assignee: Kaneka CorporationInventor: Toru Terada
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Publication number: 20120141747Abstract: Styrene-acrylic dispersants for use in pigment dispersions have lower viscosities than benchmark formulations such as nitrocellulose, dimer-acid based polyamides, and thermoplastic polyurethanes, prepared under otherwise identical conditions. Lower viscosities allow for the preparation of similarly viscous dispersions and inks with the styrene-acrylics when compared to traditional dispersants, at either (a) lower solvent levels, or if solvent levels are to be maintained, (b) higher pigment and solids loadings.Type: ApplicationFiled: July 14, 2010Publication date: June 7, 2012Inventors: Gary A. Deeter, Chien Hsu, Timothy D. Klots
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Publication number: 20120029121Abstract: The present invention relates to aluminium flakes having a thickness between 7 and 9 nm, coating compositions containing them and the use of the coating compositions for forming (security) products. When the compositions of the present invention are used in coating a hologram the obtained products show an extremely bright OVD image and extremely strong rainbow effect, high purity and contrast.Type: ApplicationFiled: December 9, 2009Publication date: February 2, 2012Applicant: BASF SEInventors: Geoff Ian Ormerod, Michelle Richert, Michael Milde, Grégoire Folly
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Patent number: 8022121Abstract: The present invention provides a rubber composition for a studless tire and a high-performance studless tire produced therefrom, which achieve good braking force and handling stability on ice and snow. The rubber composition for a studless tire includes: a rubber component; a zinc salt of a C4-C12 aliphatic carboxylic acid, or a C4-C12 aliphatic carboxylic acid and zinc oxide; and an oil or a plasticizer. The rubber component contains 40% by mass or more of butadiene rubber per 100% by mass of the rubber component.Type: GrantFiled: June 11, 2010Date of Patent: September 20, 2011Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Takayuki Hattori, Ryoji Kojima
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Patent number: 7960503Abstract: The present invention provides a method for continuously washing poly(vinyl butyral) in which a poly(vinyl butyral) slurry is passed through multiple continuous stirred tank reactors, each of which is adjusted to specific processing parameters that allow for continuous input, washing, and removal of poly(vinyl butyral). The resulting poly(vinyl butyral) can then be dried to form a powder resin that can be used in place of conventional poly(vinyl butyral) resin. In an alternative embodiment, a counter current screw washing unit is provided that passes wash water over the poly(vinyl butyral) in a direction opposite to the flow of the poly(vinyl butyral), thereby allowing the continuous washing of the poly(vinyl butyral) resin.Type: GrantFiled: May 26, 2009Date of Patent: June 14, 2011Assignee: Solutia, Inc.Inventors: Pol D'Haene, Nandan Ukidwe, Paul Van Lierde
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Patent number: 7939585Abstract: Disclosed is a flame-retardant composition comprising (i) 40-66 wt. % alkenyl aromatic resin, (ii) 9-33 wt. % ammonium polyphosphate and (iii) 14-40 wt. % cellulosic material, wherein all weights are based on the total weight of the composition and wherein ammonium polyphosphate and cellulosic material are present in a weight % ratio effective to provide molded articles exhibiting at least V-1 flame rating as determined according to the UL-94 protocol. A process to prepare the composition and articles comprising a composition of the invention and/or made by the process of the invention described herein are also disclosed.Type: GrantFiled: December 30, 2008Date of Patent: May 10, 2011Assignee: SABIC Innovative Plastics IP B.V.Inventors: Satish Kumar Gaggar, Tze Wei Liu, Rakesh Gupta, Sushant Agarwal, Adam Al-Mulla
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Publication number: 20110091771Abstract: This invention relates to a coating formulation, a coating formulation for manufacturing an electrode plate and an undercoating formulation, and their use. These coating formulations are all characterized by containing, in a polar solvent, a hydroxyl-containing resin and an organic acid and/or a derivative thereof. The hydroxyl-containing resin is at least one of (1) a polyvinyl acetal resin, (2) an ethylene-vinyl alcohol copolymer, (3) a modified and/or unmodified polyvinyl alcohol, and (4) a cyanoethyl-containing polymer. According to the present invention, there is provided a coating formulation capable of forming a coating of excellent adhesion and solvent resistance on a surface of a metal material such as an aluminum material.Type: ApplicationFiled: May 28, 2009Publication date: April 21, 2011Applicant: Dainichiseika Color & Chemicals Mfg. Co., Ltd.Inventors: Takanori Sannan, Shinya Tsuchida, Nobuyuki Kobayashi, Shinichiro Aoyagi
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Patent number: 7888412Abstract: The present invention relates to processes utilizing ionic liquids for the dissolution of various polymers and/or copolymers, the formation of resins and blends, and the reconstitution of polymer and/or copolymer solutions, and the dissolution and blending of “functional additives” and/or various polymers and/or copolymers to form advanced composite materials.Type: GrantFiled: March 24, 2005Date of Patent: February 15, 2011Assignee: Board of Trustees of the University of AlabamaInventors: John D. Holbrey, Richard P. Swatloski, Ji Chen, Dan Daly, Robin D. Rogers
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Patent number: 7829611Abstract: A curable binder composition comprising an emulsion polymer, an extender and a hydryoxyamide.Type: GrantFiled: June 19, 2007Date of Patent: November 9, 2010Assignee: Rohm and Haas CompanyInventor: Michael D. Kelly
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Patent number: 7825181Abstract: The present invention relates to modified layered fillers made from layered fillers and modifying agents and processes to produce the same. The invention also relates to nanocomposite compositions made from these modified layered fillers and elastomers, and processes to produce the same, and their use in articles.Type: GrantFiled: October 7, 2005Date of Patent: November 2, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Caiguo Gong, Weiqing Weng, Mun Fu Tse, Anthony J. Dias, James P. Stokes, Alan A. Galuska, Beverly J. Poole, Carmen Neagu, Kriss R. Karp, Molly W. Johnston
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Patent number: 7241820Abstract: A process for producing an absorbing polymer structure (Pa) including the steps of obtaining a treated absorbing polymer structure (Pb) by increasing the absorption under load at a load of 0.3 or 0.9 psi (AUL) compared to an untreated absorbing polymer structure (Pu) by a first treatment of an outer region of the untreated absorbing polymer structure (Pu) and reducing the AUL compared to the treated polymer structure (Pb) by a second treatment of an outer region of the treated absorbing polymer structure (Pb). Such absorbing polymer structure (Pa) may be used in a composite and may be used in foams, moulded articles, fibers, sheets, films, cables, sealing materials, liquid-absorbing hygiene articles, carriers for plant growth-regulating and fungal growth-regulating agents, packaging materials and soil additives or building materials.Type: GrantFiled: April 30, 2003Date of Patent: July 10, 2007Assignee: Stockhausen GmbHInventors: Scott Smith, Bernfried Messner, Markus Frank
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Patent number: 6962643Abstract: A sealing method wherein sealing agent composition comprises: (A) organopolysiloxane having at least two silicon atom bonded alkenyl groups in one molecule; (B) organohydrogen polysiloxane having at least two silicon atom bonded hydrogen atoms in one molecule; (C) fumed silica of a specified amount with respect to the components (A) and (B); and (D) an inorganic filler of a specified amount with respect to the components (A) and (B), in which the rocker and the cylinder block are pressed such that a hardness of the sealing agent in a cured state is 60 to 80 with a type A durometer of JIS K 6253 and a compression rate of the sealing agent becomes 20 to 40%.Type: GrantFiled: March 6, 2001Date of Patent: November 8, 2005Assignees: Mitsubishi Jidosha Kogyo Kabushiki Kaisha, Three Bond Co., Ltd.Inventors: Takeshi Kondo, Isamu Terasawa, Takafumi Shigemori, Yasunori Sakamoto
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Patent number: 6951895Abstract: Disclosed is an absorbent composition comprising each of an acidic and a basic material, wherein the absorbent composition exhibits desirable absorbent properties. Specifically, the present invention relates to an absorbent composition comprising either an acidic water-swellable, water-insoluble polymer having a pKa between about 2 to about 12 or a basic water-swellable, water-insoluble polymer having a pKb between about 2 to about 12 and either a basic or an acidic second material. The absorbent composition has the ability to slowly absorb a large quantity of liquid, particularly while under an external pressure. The absorbent composition is useful in disposable absorbent products, such as those disposable absorbent products that are used to absorb bodily liquids.Type: GrantFiled: December 2, 1996Date of Patent: October 4, 2005Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Jian Qin, Palani Raj Ramaswami Wallajapet
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Patent number: 6780918Abstract: Process for the preparation of protective colloid-stabilized aqueous dispersions.Type: GrantFiled: February 14, 2003Date of Patent: August 24, 2004Assignee: PolymerLatex GmbH & Co.KG.Inventor: Davide Brizzolara
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Publication number: 20030171458Abstract: The invention relates to methods of making carbohydrate and polyol esters suitable for use as plasticizers for polymer compositions. The invention also relates to plasticized polymer compositions comprising such carbohydrate and polyol esters. The invention also relates to articles prepared from such plasticized polymer compositions. The invention further relates to methods of using these compositions.Type: ApplicationFiled: January 10, 2003Publication date: September 11, 2003Inventors: Charles M. Buchanan, Norma L. Buchanan, Kevin J. Edgar, Juanelle L. Lambert
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Patent number: 6534155Abstract: An inkjet printing coating compositions and recording sheets having printable coating compositions on substrates which are suitable for photographic quality prints by inkjet printing technology, such as thermal and piezo. The recording sheet which comprises a substrate and a dried coating composition on the substrate, which coating composition comprises either (i) a hydrophilic or amphiphilic polyether polyurethane plus one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers or (ii) cellulose acetate trimellitate plus optionally one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers; a quaternary ammonium compound; a metal salt chelating agent; and a microcrystalline filler drying agent.Type: GrantFiled: March 27, 2000Date of Patent: March 18, 2003Assignee: Honeywell International Inc.Inventors: Jyoti Sharma, David James Gibboni, Elizabeth Joyce Lanigan
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Patent number: 6310121Abstract: Compositions including fibers, fillers, reinforcing agents or other property-enhancing agents added to a polymeric matrix formed from DCPD monomer or related compounds such as norbornene and norbornadiene are disclosed. The composition has a mechanically forgiving matrix due to the polymer with the inherent strength and other physical properties of the enhancement agent according to the invention. Enhancement agents according to the invention generally include inorganic, organic and metallic substances in a variety of forms.Type: GrantFiled: August 7, 1998Date of Patent: October 30, 2001Assignee: Cymetech, LLCInventors: Charles S. Woodson, Jr, Robert H. Grubbs
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Publication number: 20010003778Abstract: A recording paper coated or impregnated with a sizing agent containing a water-soluble soybean polysaccharide as an indispensable component, and optionally a cationic polymer and a surfactant, preferably a nonionic surfactant having HLB of 5-15. The water-soluble soybean polysaccharide is a water-soluble polysaccharide extracted from soybean or soybean extraction residue and subjected to desalinating purification.Type: ApplicationFiled: November 29, 2000Publication date: June 14, 2001Inventors: Toshikatsu Furunaga, Yoshiyuki Kondo
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Patent number: 6225381Abstract: An inkjet printing coating compositions and recording sheets having printable coating compositions on substrates which are suitable for photographic quality prints by inkjet printing technology, such as thermal and piezo. The recording sheet which comprises a substrate and a dried coating composition on the substrate, which coating composition comprises either (i) a hydrophilic or amphiphilic polyether polyurethane plus one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers or (ii) cellulose acetate trimellitate plus optionally one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers; a quaternary ammonium compound; a metal salt chelating agent; and a microcrystalline filler drying agent.Type: GrantFiled: April 9, 1999Date of Patent: May 1, 2001Assignee: AlliedSignal Inc.Inventors: Jyoti Sharma, David James Gibboni, Elizabeth Joyce Lanigan
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Patent number: 6218448Abstract: The invention pertains to mixtures or pastes comprising a cellulose ester, a binder resin, water, and optionally a plasticiser, an organic solvent, an emulsifier, and/or a thickener, wherein in that at least a portion of the binder resin is functionalized with an amino-functional acetal. The mixtures can be cured at ambient temperature. The mixtures or pastes can be used for, for example, varnishing wood, metal, synthetic material, paper, leather, glass, and plastic films, and in particular on surfaces where great value is placed on solventless coating compositions.Type: GrantFiled: March 26, 1999Date of Patent: April 17, 2001Assignee: Akzo Nobel N.V.Inventors: Paulus T. F. M. Kraaijevanger, Klaas J. H. Kruithof, Jörgen E. Raasing, Reinhold Heicht, Lutz Hoppe
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Patent number: 6172775Abstract: The present invention is a composition for removing scratches from photographic elements. The composition includes a solvent, an abrasive particle, a petroleum distillate, hard wax and water.Type: GrantFiled: December 8, 1998Date of Patent: January 9, 2001Assignee: Eastman Kodak CompanyInventors: Yongcai Wang, Jeffrey A. Trest, Alfred B. Fant
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Patent number: 6022913Abstract: The present invention provides a container for retort packaging comprising a laminated film having an outermost layer comprising a layer formed of a cross-linked structure containing ester bonds between poly(meth)acrylic acid (A) and polyalcoholic polymer (B); a resin composition having at least the chemical structures (X) [poly(meth)acrylic acid (A) residue], (Y) [poly(meth)acrylic acid (A)-polyalcoholic polymer (B) residue] and (Z) [metal cross-linked ionic residues], wherein the degree of esterification defined by the equation: degree of esterification=c/(b+c+d) is from 0.01 to 0.5 and the degree of ionization defined by the equation: degree of ionization=c/(b+c+d) is from 0.01 to 0.9 (wherein b, c and d represent the molar ratios of the carbon-oxygen double bond in the chemical structure of the resin composition; and a gas barrier film comprising the same.Type: GrantFiled: May 6, 1998Date of Patent: February 8, 2000Assignee: Kureha Chemical Industry Co. Ltd.Inventors: Hideaki Tanaka, Hiroyuki Ohba, Tomoaki Sato, Tomohisa Hasegawa
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Patent number: 6020405Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of the above-described inks.Type: GrantFiled: May 8, 1998Date of Patent: February 1, 2000Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 6007610Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Also, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks. Furthermore, the disclosed phase change inks inhibit corrosion of metallic internal printer parts.Type: GrantFiled: May 8, 1998Date of Patent: December 28, 1999Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 6001904Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks.Type: GrantFiled: May 8, 1998Date of Patent: December 14, 1999Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 5973036Abstract: Phase-change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibilty, offset and pick resistance, adhesion, and other desired properties. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks.Type: GrantFiled: May 8, 1998Date of Patent: October 26, 1999Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 5847030Abstract: A process for the preparation of polymer latex particles by conducting a pre-reaction emulsification with monomer, polar comonomer, water, surfactant, chain transfer agent, and initiator; and which pre-reaction emulsification is effected at a low temperature of from about 3.degree. C. to about 35.degree. C., for example, and thereafter, effecting emulsion polymerization by heating the aforementioned emulsified mixture in a reactor at a temperature of from about 25.degree. C. to about 125.degree. C. The aforementioned reactor contents are retained at this temperature, that is 25.degree. C. to 125.degree. C. for an effective time period. Thereafter, the reaction mixture is cooled.Type: GrantFiled: August 2, 1996Date of Patent: December 8, 1998Assignee: Xerox CorporationInventors: Hadi K. Mahabadi, Grazyna E. Kmiecik-Lawrynowicz, T. Hwee Ng
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Patent number: 5725942Abstract: A water-expandable, sealant article of manufacture comprising a water swellable smectite clay dispersed in an organic liquid consisting of C2-C6 aliphatic polyhydric alcohols and a binder comprising a copolymer of acrylic ester of lower alkyl alcohols. The composition is used for the manufacture by extrusion of highly flexible and elastic strip-shaped or sheet-shaped products for waterproofing works in the field of building.Type: GrantFiled: December 24, 1996Date of Patent: March 10, 1998Assignee: Laviosa Chimica Mineraria S.p.A.Inventors: Piero Starita, Paolo Gasperini
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Patent number: 5708117Abstract: The description relates to coating agents for use as primers and fillers in the manufacture of multilayer lacquer coatings, more particularly in the motor-vehicle sector.The coating agent contains a binder mixture ofA) 60-75 wt. % of a hydroxy-functional copolymer with an OH number of 110 to 170 mg KOH/g, obtainable froma) 5-60 wt. %, preferably 10-30 wt. % of at least one diester of an alpha, beta-olefinically unsaturated dicarboxylic acid with saturated monohydric alcohols containing 1-8 carbon atoms,b) 10-70 wt. %, preferably 35-60 wt. % of one or more vinyl aromatic hydrocarbons,c) 0-30 wt. %, preferably 0-15 wt. % of one or more glycidyl esters of aliphatic saturated monocarboxylic acids branched in the alpha position,d) 25-50 wt. % of at least one hydroxy alkyl ester or a mixture of at least one alkyl ester and one hydroxyl alkyl ester of an alpha, beta-olefinically unsaturated monocarboxylic acid, ande) 0-10 wt. % of one or more alpha, beta-unsaturated monocarboxylic acids,B) 1-6 wt.Type: GrantFiled: March 11, 1996Date of Patent: January 13, 1998Assignee: Herberts Gesellschaft mit Beschrankter HaftungInventors: Heinz Dietholf Becker, Gerhard Bremer, Fritz Sadowski, Werner Stephan
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Patent number: 5681877Abstract: Block copolymers denoted by AB from acrylic or methacrylic acid, the corresponding blocks being denoted by A, and from alkyl acrylate or methacrylate with the alkyl chain being C.sub.1 -C.sub.10, the corresponding blocks being denoted by B. Said copolymer blocks are used as wetting and/or dispersing agents for solid particles in an essentially organic medium consisting of a solvent or a mixture of solvents solubilizing the block B.The invention also concerns solid particle dispersions using the above-defined block copolymers.It also concerns compositions, in particular cosmetic compositions, containing said dispersions.Type: GrantFiled: March 27, 1996Date of Patent: October 28, 1997Assignee: LVMH RechercheInventors: Claude Hosotte-Filbert, Carole Tondeur, Henri-Gerard Riess, Alain Meybeck, Jean-Fran.cedilla.ois Tranchant
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Patent number: 5681889Abstract: The present invention provides hydrophilic crosslinked polymer fine particles made of a copolymer composed of:2-50% by weight of (a) a monoethylenic monomer having a polyoxyalkylene or polyvinylpyrrolidone chain,20-97% by weight of (b) a (meth)acrylamide type monoethylenic monomer,1-30% by weight of (c) a crosslinkable unsaturated monomer selected from the group consisting of compounds having, in the molecule, at least two polymerizable double bonds, and compounds having, in the molecule, at least one functional group selected from hydrolyzable silyl groups and 1,2-epoxy groups and one polymerizable double bond, and0-50% by weight of (d) other monoethylenic monomer. Said polymer fine particles are superior in polymerization stability as well as in dispersion stability during storage, undergoes no adverse effect by dispersion stabilizer owing to no use of said stabilizer, and are suitably used for formation of a hydrophilic film.Type: GrantFiled: December 15, 1995Date of Patent: October 28, 1997Assignee: Kansai Paint Co., LtdInventors: Masahiro Kondo, Hiroshi Inoue
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Patent number: 5656646Abstract: Mixtures of(I)polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and(II)(1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising(a) from 10 to 70% by weight of monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acids or the salts thereof and(b) from 30 to 90% by weight of monoethylenically unsaturated C.sub.3 -C.sub.10 -monocarboxylic acids and/or the salts thereof,(2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of(A) monoethylenically unsaturated C.sub.3 -C.sub.10 -carboxylic acids or the anhydrides and/or the salts thereof in the presence of(B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or(3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groupscontain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.Type: GrantFiled: May 22, 1995Date of Patent: August 12, 1997Assignee: BASF AktiengesellschaftInventors: Johannes Perner, Paul Diessel, Helmut Guembel, Walter Denzinger, Heinrich Hartmann, Matthias Kroner
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Patent number: 5618858Abstract: A polymer material for manufacturing arcing chambers for low-voltage switchgear is characterized by a thermoplastic polymer matrix of polyamide or polyolefin which contains a cellulose material sheathed by cured melamine-formaldehyde resin.Type: GrantFiled: January 5, 1996Date of Patent: April 8, 1997Assignee: Siemens AktiengesellschaftInventors: Hans-Georg Hauschildt, Wilfried Haas, Heinz Hacker
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Patent number: 5580910Abstract: The present invention is directed toward a water vapor responsive self sealing thin film which is formed from a blend of at least about 75 weight percent of a water dispersible polymer; from about 0.5 to about 5 weight percent of a xerogellant; and from about 7.5 to about 20 weight percent of a plasticizing agent.Type: GrantFiled: April 12, 1993Date of Patent: December 3, 1996Assignee: Kimberly-Clark CorporationInventors: Robert L. Isaac, Bernard Cohen, Lee K. Jameson
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Patent number: 5414028Abstract: Carbohydrate substituted dibenzo[d,f][1,3,2]dioxaphosphepin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.Type: GrantFiled: February 17, 1994Date of Patent: May 9, 1995Assignee: Ciba-Geigy CorporationInventors: Stephen D. Pastor, Joseph E. Babiarz
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Patent number: 5356962Abstract: Carbohydrate substituted dibenzo[d,g][1,3,2]dioxaphosphocin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.Type: GrantFiled: February 17, 1994Date of Patent: October 18, 1994Assignee: Ciba-Geigy CorporationInventors: Stephen D. Pastor, Joseph E. Babiarz
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Patent number: 5338784Abstract: A article of manufacture and composition for preventing a tear, hole or run in hosiery from expanding, wherein the composition comprises:(a) nitrocellulose,(b) resin,(c) dioctylphthalate, and(d) a solvent or solvent mixture.Type: GrantFiled: September 23, 1992Date of Patent: August 16, 1994Assignee: Carole L. KentInventors: Carole L. Kent, Dieter Frank
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Patent number: 5143970Abstract: Water wet nitrocellulose, butyl acrylate/methyl methacrylate monomers and phosphate surfactant are emulsified into an oil-in-water emulsion and polymerized to produce a nitrocellulose/acrylic latex emulsion with a particle size below 0.25 microns. Wood finishing lacquers produced from this latex emulsion are equivalent in performance to solvent lacquers while lowering VOC to below 2.3 lb/gal.Type: GrantFiled: June 3, 1991Date of Patent: September 1, 1992Assignee: Aqualon CompanyInventor: Syed M. Ahmed
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Patent number: 5104915Abstract: A sprayable metallic-tone lacquer composition comprising a tinted polymer-solvent system containing approximately 5% to about 15% by weight of a transparent film-forming resin consisting of a mixture of an acrylic copolymer and nitrocellulose, and about 1-5% by weight of a metal-simulating dye dissolved in about 80-90% by weight of an organic solvent blend. The solvent blend preferably comprises about 25-35% by weight of acetone; 5-15% by weight each of propylene glycol methyl ether acetate, toluene, and methyl isobutyl ketone; and 5-10% by weight each of butyl benzyl phthalate, isobutyl acetate and isopropyl alcohol. The lacquer composition are particularly adapted for aerosol application and are prepared by dissolving appropriate amounts of the clear resin mixture in the solvent blend and adding the soluble dye, then pressurizing the resulting tinted resinous solution with a mutually compatible aerosol propellant in a suitable aerosol dispensing container.Type: GrantFiled: September 5, 1990Date of Patent: April 14, 1992Inventor: Laercio Paci
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Patent number: 5070121Abstract: The invention concerns a solvent-free, polymerizing hotmelt substance free of, or low in monomers, for corrosion- and/or abrasion proofing and/or forming a protective film with barrier properties on a real substrates and molded bodies made of metal, plastic, cellulose materials and/or inorganic materials, in particular for wrapping purposes, and consisting of(a) one or more polymerizing polymers containing hydroxyls with an average molecular weight (M.sub.w) between 1,000 and 500,000 and with a glass transition temperature (T.sub.g).gtoreq.20.degree. C., and/or(b) one or more polymerizing, linear, unbranched and/or unbranched polyesters and/or their copolymers with an average molecular weight (M.sub.w) between 900 and 50,000 and with a glass transition temperature (T.sub.g).gtoreq.-50.degree. C.Type: GrantFiled: April 25, 1989Date of Patent: December 3, 1991Assignee: Schmalbach Lubeca AGInventors: Rudolf Hinterwaldner, Georg Bolte
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Patent number: 5032682Abstract: Silated polysaccharides having 0.005 to 2.0 silyl molar substitution per anhydrosaccharide unit form water resistant films when cast from aqueous solution and dried in the presence of atmospheric carbon dioxide. These films are soluble in aqueous caustic. A preferred water soluble polymer is a cellulose ether with 0.005 to 1.0 silyl substitution.Type: GrantFiled: September 28, 1990Date of Patent: July 16, 1991Assignee: Aqualon CompanyInventor: Arjun C. Sau
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Patent number: 5000029Abstract: Resilient, crosslinked silicone elastomers shaped as elastoforming dies or form blocks for the stamping of sheet material workpieces, e.g., ultra-thin sheet metal, and well adopted for applications in the automotive industry, comprise a crosslinked fluid organopolysiloxane including at least one silicone-compatible organic or inorganic plasticizer within the crosslinked network thereof, said at least one plasticizer being stable and nonmigrating under elastoforming stamping conditions, and said at least one plasticizer being present in such amount that said plasticized silicone elastomer has a Shore 00 hardness of less than about 40.Type: GrantFiled: March 5, 1990Date of Patent: March 19, 1991Assignee: Rhone-Poulenc ChimieInventors: Claude Laurent, Paul Rostaing, Rene Lyobard