Carbocyclic Ring, E.g., Benzophenone, Etc. Patents (Class 524/359)
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Publication number: 20100201939Abstract: A plastic lens exhibiting excellent ability of absorbing ultraviolet light having a wavelength of about 400 nm, suppressed coloring and excellent transparency and a process for producing the plastic lens are provided. The plastic lens comprises a plastic lens substrate obtained by polymerizing a composition comprising (A) a lens material monomer, (B) a cobalt compound expressed by CoO.Al2O3 and/or Co.Al2O4, (C) fine particles of Au having an average diameter of 1 to 1,000 nm and (D) at least one ultraviolet light absorber selected from benzophenone-based ultraviolet light absorbers and benzotriazole-based ultraviolet light absorbers. The process comprises mixing Component (A), a dispersion of a cobalt compound which comprises Component (B), a dispersion of fine particles of Au which comprises Component (C) and Component (D), and polymerizing the obtained composition to prepare a plastic lens substrate.Type: ApplicationFiled: July 31, 2008Publication date: August 12, 2010Applicant: HOYA CORPORATIONInventors: Shinsuke Itoh, Masahisa Kousaka
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Publication number: 20100152341Abstract: Compacted additive blends, or polymer stabilization agent blends, can be added during the post-polymerization process to enhance the processability performance of polymers. The addition of certain compaction aids, such as high melting or non-melting metallic silicates and others, increases the resistance to friability of the compacted additive pellets. These compaction aids are non-migratory during the compaction process and after introduction into the polymer resin and thus have no deleterious effects. The additive blend can contain a variety of suitable additives in addition to the compaction aids.Type: ApplicationFiled: December 9, 2009Publication date: June 17, 2010Applicant: Ingenia Polymers Inc.Inventors: Ananda M. Chatterjee, Tania M. LaFrance, Salvatore D'Uva
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Publication number: 20100137484Abstract: Disclosed is a compound having high optical anisotropy and high compatibility with a polymer resin, which is represented by Formula 1 and necessarily has at least one meta substituent. Also, a resin composition including the compound and a polymer resin, and an optical member including the resin composition are disclosed. Since the compound represented by Formula 1 is an anisotropic compound having high compatibility with a polymer resin and high optical anisotropy, in the case of an optical member obtained by using a polymer resin composition including the compound represented by Formula 1, there is no phase separation, and it is possible to achieve a required optical characteristic with only a small amount thereof.Type: ApplicationFiled: June 4, 2008Publication date: June 3, 2010Inventors: Jaeho Cheong, Minjin Ko, Kiyoul Lee, Bumgyu Chio, Myungsun Moon, Daeho Kang, YunBong Kim
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Publication number: 20100022691Abstract: The present invention provides a polyacetal resin composition having excellent weather resistance and suppressed surface gloss, and having extremely reduced generation of formaldehyde. Particularly, to 100 parts by weight of (A) a polyacetal resin are blended 0.01 to 5 parts by weight of (B) a weathering (light) stabilizer, 1 to 50 parts by weight of (C) a core-shell polymer having a core of a rubbery polymer and a shell of a glassy polymer composed of a vinyl-based copolymer; and 0.01 to 5 parts by weight of (D) a compound selected from an isocyanate compound, an isothiocyanate compound, and a modified compound thereof.Type: ApplicationFiled: September 20, 2007Publication date: January 28, 2010Inventors: Hirokazu Katsuchi, Hiroyuki Hase
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Patent number: 7638565Abstract: A polyacetal resin composition comprises a polyacetal resin and a hetero atom-containing aliphatic carboxylic acid hydrazide. The proportion of the hetero atom-containing aliphatic carboxylic acid hydrazide may be about 0.001 to 20 parts by weight relative to 100 parts by weight of the polyacetal resin. The polyacetal resin composition may further comprise at least one member selected from the group consisting of an antioxidant, a heat stabilizer, a processing stabilizer, a weather (light)-resistant stabilizer, an impact resistance improver, a gloss control agent, an agent for improving sliding property, a coloring agent, and a filler. Such a resin composition improves stability of the polyacetal resin and inhibits formaldehyde emission.Type: GrantFiled: October 22, 2004Date of Patent: December 29, 2009Assignee: Polyplastics Co., Ltd.Inventor: Hatsuhiko Harashina
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Patent number: 7632883Abstract: An aqueous synthetic resin formulation essentially comprising a synthetic resin A, a metallic cation with a charge number of from 2 to 4, dispersants, water, and finely divided fillers, and also, if desired, acetophenone derivatives or benzophenone derivatives, the resin A being prepared by free-radically initiated aqueous emulsion polymerization of monomers in the presence of from 0.01 to 3 parts by weight of an alien polymer seed per 100 parts by weight of the monomer mixture.Type: GrantFiled: October 29, 2002Date of Patent: December 15, 2009Assignee: BASF AktiengesellschaftInventors: Christian Lach, Michael Melan
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Publication number: 20090290109Abstract: A photoalignment material includes an alignment polymer, a photoalignment additive including a compound represented by the following Chemical Formula 1 and an organic solvent. In Chemical Formula 1, R1 represents a cyclic compound. A and B independently represent a single bond or —(CnH2n)—. “n” represents an integer in a range of 1 to 12. Each —CH2— of A and/or B may be replaced with R3 represents an alkyl group having 1 to 12 carbon atoms, and each —CH2— of A and/or B may be replaced with —O—. R4 represents In Chemical Formula 1, each hydrogen atom excluding hydrogen atoms of R4 may be replaced with chlorine (Cl) or fluorine (F). Thus, an alignment layer having an orientation may be formed without an alignment polymer having a photoreactive portion, and the density of the alignment layer may be increased.Type: ApplicationFiled: March 20, 2009Publication date: November 26, 2009Inventors: Jun-Woo LEE, Fusayuki Takashita, Baek-Kyun Jeon, Tae-Sung Jung, Hoi-Lim Kim, Jeong-Hye Choi, Sung-Yi Kim
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Patent number: 7622526Abstract: The invention relates to a thermoset plastic material, comprising a three-dimensional matrix containing sulphur atoms and at least one anti-plasticizing additive which is unreactive toward said matrix.Type: GrantFiled: September 29, 2004Date of Patent: November 24, 2009Assignee: Essilor InternationalInventors: Nicolas Droger, Jean-Louis Halary, Gilles Richard, Martin Rickwood
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Publication number: 20090225425Abstract: An optical resin composition with superior impact resistance and a method for producing an optical lens from the composition are disclosed. In one embodiment, the optical resin composition for a plastic optical lens has superior impact resistance as well as light-weight, superior moldability, excellent dyeing ability, a high Abbe number and good transparency. The optical lens produced from the composition exhibits superior impact resistance even after multi-coating. The optical resin composition with superior impact resistance has a solid refractive index (nD) of about 1.53 to about 1.57, an Abbe number of about 35 to about 48, a liquid specific gravity of about 0.97 to about 1.25 and a solid specific gravity of about 1.10 to about 1.35, by which the composition comprises a mixture of isophorone diisocyanate and hexamethylene diisocyanate, pentaerythritol tetrakis(3-mercaptopropionate), a UV absorber, a release agent and a polymerization initiator.Type: ApplicationFiled: March 5, 2009Publication date: September 10, 2009Applicant: SHIN DAE SPECIALTIES CO., LTD.Inventors: Dong Gyu Jang, Jong Hyo Kim
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Publication number: 20090143506Abstract: An aldehyde-inhibiting composition inhibiting an aldehyde from an aldehyde-generating source comprises a carboxylic acid hydrazide and a metal salt of a hydroxy polycarboxylic acid (e.g., a salt of citric acid, malic acid, or tartaric acid with an alkaline earth metal) in a proportion of 0.01 to 100 parts by weight relative to 1 part by weight of the carboxylic acid hydrazide. Moreover, a polyacetal resin composition may comprise a polyacetal resin and the aldehyde-inhibiting composition in a proportion of 0.001 to 20 parts by weight of the aldehyde-inhibiting composition relative to 100 parts by weight of the polyacetal resin. To the resin composition, may be added an antioxidant, a heat stabilizer, a processing stabilizer, a weather (light)-resistant stabilizer, an impact resistance improver, a gloss control agent, a sliding improver, a coloring agent, a filler, and others.Type: ApplicationFiled: October 22, 2004Publication date: June 4, 2009Inventor: Hatsuhiko Harashina
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Publication number: 20090130351Abstract: The present invention provides a production process of a heat shrinkable film which is transparent, excellent in the balance of physical properties such as rigidity, elongation and shrink properties in both MD and TD, especially has a uniform film thickness and good stability in extrusion molding film while utilizing an inflation method; a block copolymer or hydrogenated product thereof, or a composition composed thereof excellent in tensile properties, optical properties, hardness, stretch properties, molding processability, shrink properties and solvent resistance and therefore suited for extrusion, injection molding and foams. The production process of a heat shrinkable film has a first inflation step of forming a tube having a thickness of from 0.05 to 0.5 mm by using a block copolymer having a vinyl aromatic hydrocarbon content of from 65 to 95 wt. % and a conjugated diene content of from 5 to 35 wt.Type: ApplicationFiled: September 12, 2006Publication date: May 21, 2009Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Susumu Hoshi, Ryoko Fukuoka, Yasutaka Nakamura
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Publication number: 20090069466Abstract: A silicone fluid comprising a chromophore-substituted polyorganosiloxane having a formula (2): wherein x is an integer in the range of 60 to 2000; y is an integer in the range of 5 to 100; a ratio x:y is in a range of about 10:1 to about 20:1; and X is a photostabilizing chromophore.Type: ApplicationFiled: September 5, 2008Publication date: March 12, 2009Applicant: HALLSTAR INNOVATIONS CORP.Inventors: Craig A. Bonda, Anna Pavlovic, Anthony J. O'Lenick, JR.
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Publication number: 20090061248Abstract: An object of the invention is to provide a block copolymer hydrogenation product suitable for a sheet and a heat shrinkable film which are excellent in solvent resistance, rigidity, elongation and transparency, which is excellent in a balance of physical properties such as solvent resistance, natural shrinkability, low-temperature shrinkability, rigidity, transparency and low-temperature elongation, and a composition thereof.Type: ApplicationFiled: April 7, 2006Publication date: March 5, 2009Inventors: Susumu Hoshi, Yukio Yamaura
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Patent number: 7468406Abstract: A durable colored article having fluorescent properties comprises a substantially solventless polyvinyl chloride matrix, a thioxanthene fluorescent dye, and a secondary or tertiary hindered amine light stabilizer having a molecular weight less than about 1000 grams/mole. The invention has the advantage in that it provides a flexible polyvinyl chloride film that exhibits durable fluorescent colors.Type: GrantFiled: August 24, 2006Date of Patent: December 23, 2008Assignee: 3M Innovative Properties CompanyInventors: Kenneth M. White, Lee A. Pavelka, Vera L. Lightle, James C. Coderre
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Publication number: 20080311372Abstract: The present invention relates to the use of a blend of UV absorbers and a naphthalate containing polymer for enhancing the stability of fibers and fabrics. According to the present invention, preferred UV absorbers include but are not limited to benzophenones, benzotriazoles, triazines and benzoxazinone chemistries and preferred naphthalate containing polymers include but are not limited to polyethylene naphthalate (PEN), polyethylene naphthalate terephthalate (PENT), polybutylene naphthalate (PBN), polytrimethylene naphthalate (PTN) and copolymers and blends there of.Type: ApplicationFiled: June 18, 2008Publication date: December 18, 2008Inventor: Vaman G. Kulkarni
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Publication number: 20080188584Abstract: An autoxidisable architectural coating composition suitable for application to surfaces found in and around buildings at ambient temperatures and in natural daylight wherein surface autoxidation of the composition is promoted by a combination of low concentrations of metal ions (especially manganese or vanadium) and 2,2-dimethoxy 1,2-diphenylethan-1-one as photoinitiator. The composition avoids the need to use more than trace amounts cobalt ions which are rumoured to be carcinogenic yet achieves adequately fast rates of autoxidation. Preferably the use of cobalt is a avoided altogether. The use of the low concentrations of the other metal ions reduces discolouration of the compositions often to levels below what is achieved using conventional cobalt promoters. Also a modification in which surface autoxidation is promoted by a combination of 2,2-dimethoxy-1,2-diphenylethan-1-one and trace amounts of cobalt ions in the absence of other surface autoxidation promoting metal ions.Type: ApplicationFiled: June 11, 2006Publication date: August 7, 2008Inventor: Philip Louis Taylor
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Patent number: 7407992Abstract: High refractive index and optically clear copoly(carbosilane and siloxane) elastomers and ophthalmic lenses made therefrom are provided. The elastomers are comprised of copolymers having carbosilane repeat units and siloxane repeat units. The copolymers and ophthalmic lenses of the present invention have a high refractive index and excellent folding recoverability.Type: GrantFiled: June 30, 2006Date of Patent: August 5, 2008Assignee: STAAR Surgical CompanyInventor: Xiugao Liao
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Publication number: 20080132625Abstract: A hot melt adhesive that contains fragrances is provided. The hot melt adhesive can be used to adhere packaging materials to one another and, upon exposure of the adhesive surface, releases a fragrance, in particular at low temperatures. A method for manufacturing such a hot melt adhesive is also provided, wherein the thermal stress from manufacture is kept low.Type: ApplicationFiled: December 27, 2007Publication date: June 5, 2008Inventors: Erik Niehaus, Petra Padurschel, Marcel Roth, Gunter Hoffmann, Rolf Tenhaef, Georg Meine, Andreas Bauer
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Patent number: 7351757Abstract: The invention relates to vibration-damping engineering plastics which can be used in a wide variety of fields such as electronic equipments, electronic materials, household appliances, automobile/other transport instruments, industrial machine parts, precision instruments, building materials, sporting/leisure goods, and articles for daily use, and which includes thermoplastic engineering plastics as a base polymer and an organic vibration-damping agent incorporated into the base polymer, the organic vibration damping agent has one or more members selected from a compound having a benzothiazyl group, a compound having a benzotriazole group, a compound having a diphenyl acrylate group and a compound having a benzophenone group.Type: GrantFiled: June 3, 2005Date of Patent: April 1, 2008Assignee: Shishiai-KabushikigaishaInventors: Yasuyuki Ohira, Tatsuya Aoki
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Patent number: 7348373Abstract: Water absorption resistant polyimide pastes (or solutions), are particularly useful to make electronic screen printable pastes and the electronic components made from these pastes. A group of soluble polyimides and their solvents were discovered to be particularly resistant to moisture absorption. These polyimide solutions optionally contain polyimides also containing cross-linkable monomers and/or thermal cross-linking agents. In addition, these polyimide pastes may optionally contain adhesion promoting agents, blocked isocyanates, metals, metal oxides, and other inorganic fillers. The polyimide pastes (or solutions) of the present invention have a polyimide with a glass transition temperature greater than 250° C., have a water absorption factor of less than 2%, and a have a positive solubility measurement.Type: GrantFiled: February 19, 2004Date of Patent: March 25, 2008Assignee: E.I. du Pont de Nemours and CompanyInventors: Thomas E. Dueber, John D. Summers, Xin Fang
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Patent number: 7326740Abstract: Disclosed are natural products composites protected against the deleterious effects of microorganisms comprising at least one natural product, at least one thermoplastic resin, and an effective amount of an antifungal agent. The composites are further advantageously protected against weathering and color formation by the incorporation therein of at least one light stabilizer and at least one compound selected from the group consisting of the oxides, hydroxides or silicates of Ca, Mg, Al and Zn. The light stabilizers are selected from the group consisting of the ultraviolet light absorbers and the sterically hindered amines. The metal oxide is for example CaO. The natural products are for example wood flour, flax, hemp, jute, kenaf, or rice husk. The thermoplastic resin is for example polyethylene or polypropylene. The antifungal agent and potential coadditives are incorporated via melt processing such as extrusion, co-kneading, pultrusion and injection molding.Type: GrantFiled: April 20, 2004Date of Patent: February 5, 2008Assignee: Ciba Specialty Chemicals CorporationInventors: Urs Stadler, Gerry Capocci, Shing Li, Melinda Reyes, Heinz Herbst
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Patent number: 7317049Abstract: A sheet molding compound used for the preparation of enclosures comprising a base resin in a range from 20.0 to 28.0% by weight; a thermoplastic resin in a range from 3.0 to 7.0% by weight; a styrene monomer in a range from 0.01 to 2.5% by weight; a first catalyst in a range from 0.1 to 0.7% by weight; a second catalyst in a range from 0.01 to 0.3 % by weight; a catalyst modifier in a range from 0.01 to 0.25% by weight; an inhibitor in a range from 0.01 to 0.25% by weight; a UV absorber in a range from 0.01 to 0.25% by weight; a wetting agent in a range from 0.1 to 1.00% by weight; a zinc stearate in a range from 1.0 to 2.0% by weight; optionally, at least one pigment in a range from 1.0 to 8.0% by weight; a flame retardant in a range from 30.0 to 73.0% by weight; a thickener in a range from 0.1 to 1.0% by weight; a glass fiber in a range from 10.0 to 30.0% by weight; and a thermoplastic powder in a range of 0.1 to 2.5% by weight.Type: GrantFiled: September 10, 2002Date of Patent: January 8, 2008Assignee: Robroy Industries-Stahlin EnclosuresInventors: John M. Maxel, Mike Jackson
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Patent number: 7198844Abstract: Microporous particles for stabilizing thermoplastic compositions comprising comprising a stabilizer are provided. Each of the porous microparticles has a plurality of preformed pores into which the stabilizing agent is loaded and from which the stabilizing is subsequently released to the processing environment of use.Type: GrantFiled: January 17, 2003Date of Patent: April 3, 2007Assignee: Crompton CorporationInventors: Vaikunth S. Prabhu, Marshall D. Moore
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Patent number: 7186464Abstract: Herein is disclosed an oxygen barrier composition comprising an oxygen barrier polymer and an oxygen scavenging polymer. The composition can be in the form of a physical blend or a cross-linked blend, and can further comprise a compatibilizer, a transesterification catalyst, or both. Preferably, the oxygen barrier polymer is poly(ethylene/vinyl alcohol) (EVOH), polyethylene terephthalate (PET), or polyamide other than MXD6. Preferably, the oxygen scavenging polymer comprises an ethylenic backbone and a pendant cyclic olefinic group, or the oxygen scavenging polymer is a polyamide derived at least in part from a xylene diamine-based monomer. The oxygen barrier composition can be formed into an oxygen barrier layer of a packaging article. Such layers and articles, and methods for making same, are also disclosed.Type: GrantFiled: March 6, 2001Date of Patent: March 6, 2007Assignee: Chevron Phillips Chemical Co. LPInventors: Raymond Laplante, Hu Yang, Ta Yen Ching, Gangfeng Cai
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Patent number: 7183340Abstract: About 0.001 to 5 parts by weight of an antioxidant and about 0.001 to 10 parts by weight of a guanamine compound having at least one unit represented by the following formula (1) or a salt thereof relative to 100 parts by weight of a polyacetal resin are mixed and constitute a resin composition. The resin composition may further comprise a processing stabilizer, a heat stabilizer, a weather-resistant stabilizer, a coloring agent, a gloss control agent, an impact resistance improver, a slide improver, a filler, and/or the like. Wherein R1 and R2 are the same or different and each represents a hydrogen atom or an alkyl group, and “m” denotes an integer of not less than 2.Type: GrantFiled: December 24, 2003Date of Patent: February 27, 2007Assignee: Polyplastics Co., Ltd.Inventors: Hatsuhiko Harashina, Hayato Kurita
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Patent number: 7166659Abstract: Compounds of formula I or II where R is an aryl moiety, such as phenyl, naphthyl or biphenylyl, or is phenyl substituted by one or more trifluoromethyl, bromo or cyano, and E1 and E2 are independently hydrogen, alkyl, aralkyl and the like are prepared by reaction of a benzotriazole substituted on the 5-position of the benzo ring by a halogen atom with a arylboronic acid or ester in the presence of a transition-metal catalyst, such as palladium (II) diacetate. The benzotriazole compounds of formula I are particularly efficacious as stabilizers for automotive coatings and candle wax.Type: GrantFiled: March 30, 2004Date of Patent: January 23, 2007Assignee: Ciba Specialty Chemicals CorporationInventors: Stephen D. Pastor, Andrew B. Naughton, Robert Detlefsen, Mervin G. Wood, Joseph Suhadolnik, Anthony DeBellis, Deborah DeHessa
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Patent number: 7148274Abstract: where R is an aryl moiety, such as phenyl, naphthyl or biphenylyl, or is phenyl substituted by one or more trifluoromethyl, bromo or cyano, and E1 and E2 are independently hydrogen, alkyl, aralkyl and the like are prepared by reaction of a benzotriazole substituted on the 5-position of the benzo ring by a halogen atom with a arylboronic acid or ester in the presence of a transition-metal catalyst, such as palladium (II) diacetate. The benzotriazole compounds of formula I are particularly efficacious as stabilizers for automotive coatings and candle wax.Type: GrantFiled: January 26, 2004Date of Patent: December 12, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Stephen D. Pastor, Andrew B. Naughton, Robert Detlefsen, Mervin G. Wood, Joseph Suhadolnik, Anthony DeBellis, Deborah DeHessa
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Patent number: 7071244Abstract: High refractive index and optically clear copoly(carbosilane and siloxane) elastomers and ophthalmic lenses made therefrom are provided. The elastomers are comprised of copolymers having carbosilane repeat units and siloxane repeat units. The copolymers and ophthalmic lenses of the present invention have a high refractive index and excellent folding recoverability.Type: GrantFiled: December 3, 2002Date of Patent: July 4, 2006Assignee: STAAR Surgical CompanyInventor: Xiugao Liao
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Patent number: 7071279Abstract: High refractive index and optically clear copoly(carbosilane and siloxane) elastomers and ophthalmic lenses made therefrom are provided. The elastomers are comprised of copolymers having carbosilane repeat units and siloxane repeat units. The copolymers and ophthalmic lenses of the present invention have a high refractive index and excellent folding recoverability.Type: GrantFiled: April 16, 2004Date of Patent: July 4, 2006Assignee: STAAR Surgical CompanyInventor: Xiugao Liao
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Patent number: 7037962Abstract: The instant invention relates to a thermoplastic polymer composition useful in greenhouse films to enhance plant growth or in general bio-mass production. Further aspects of the invention are a process for enhancing plant growth in greenhouses by incorporating a photoactive additive together with light stabilizers into the greenhouse film and the use of the condensation product of dialkylamino benzaldehyde and barbituric acid together with light stabilizers as a plant growth enhancing additive in polymeric greenhouse films.Type: GrantFiled: October 20, 2003Date of Patent: May 2, 2006Assignee: Ciba Specialty Chemicals Corp.Inventors: Mara Destro, Michela Bonora, Galileo Magnani
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Patent number: 7026380Abstract: A stabilizer mixture containing A) either (A1) at least one compound of the formula in which R1 is for example hydrogen or C1–C8alkyl; R2, R3, R5 and R6 are for example hydrogen, C1–C30alkyl or phenyl; R4 is for example C1–C30alkyl or 2,2,6,6-tetramethyl-4-piperidyl; and n1 is a number from 1 to 50; or (A2) at least one compound of the formulae wherein n2 and n2* are a number from 2 to 50; B) magnesium oxide, magnesium hydroxide, zinc oxide, zinc hydroxide or an organic salt of zinc or magnesium; and C) either (C1) an UV absorber or (C2) a pigment or (C3) an UV absorber and a pigment; with the proviso that, when component A) is at least one compound of the formulae (IIIa) and (IIIb), component B) is magnesium oxide, magnesium hydroxide or an organic salt of zinc or magnesium. Such a stabilizer mixture is particularly useful for stabilizing a polyolefin against light-induced degradation.Type: GrantFiled: March 24, 2003Date of Patent: April 11, 2006Assignee: Ciba Specialty Chemicals CorporationInventor: François Gugumus
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Patent number: 7019053Abstract: A stabilizer mixture containing A) for example at least one compound of the formula (I) wherein the radicals R1, independently of one another, are hydrogen, C1–C8alkyl, —O?, —CH2CN, C3–C6alkenyl, C7–C9phenylalkyl, C7–C9phenylalkyl which is substituted on the phenyl radical by C1–C4alkyl; or C1–C8acyl; and B) magnesium oxide, magnesium hydroxide, zinc oxide, zinc hydroxide or an organic salt of zinc or magnesium, or a hydrotalcite; and C) either (C1) an UV absorber or (C2) a pigment or (C3) an UV absorber and a pigment. Such a stabilizer mixture is particularly useful for stabilizing a polyolefin against light-induced degradation.Type: GrantFiled: January 21, 2003Date of Patent: March 28, 2006Assignee: Ciba Specialty Chemicals CorporationInventor: François Gugumus
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Patent number: 6913712Abstract: Mixtures of compounds comprising a compound G2 and at least one further compound from the group G0, G1, G3, G4, G5, G6, the compounds G0-G6 corresponding to formula (I) in which, in the compound G0, the radicals R1, R2, R3, R4, R5 and R6 are each hydrogen; G1, the radical R1 is Q and R2, R3, R4, R5 and R6 are each hydrogen; G2, the radicals R1 and R2 independently of one another are each Q and R3, R4, R5 and R6 are each hydrogen; G3 the radicals R1, R2 and R3 independently of one another are each Q and R4, R5 and R6 are each hydrogen; G4, the radicals R1, R2, R3 and R4 independently of one another are each Q and R5 and R6 are each hydrogen; G5, the radicals R1, R2, R3, R4 and R5 independently of one another are each Q and R6 is hydrogen; G6, the radicals R1, R2, R3, R4, R5 and R6 independently of one another are each Q; and Q and the other symbols are as defined in claim 1, are effective as stabilizers for organic material with respect to damaging exposure to light, oxygen and/or heat.Type: GrantFiled: December 14, 2000Date of Patent: July 5, 2005Assignee: CIBA Specialty Chemicals Corp.Inventor: Pascal Hayoz
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Patent number: 6899952Abstract: A polysulfone-based resin solution composition which is stable, contains no undissolved resin left in the liquid, shows neither thickening nor gelation, gives a smooth coating layer when spread on a base film and does not generate any harmful component, and a laminate which is produced by spreading and drying the same polysulfone-based resin solution composition on a base film surface. More specifically, a polysulfone-based resin solution composition prepared by dissolving at least one type of polysulfone-based resin in a mixed solvent composed of a lactone (A) or ketone (B) having an aromatic ring, and cycloketone (C) and aliphatic ketone (D) having a boiling point of 150° C. or lower, and a laminate which is produced by spreading and drying the same polysulfone-based resin solution composition on a base film surface.Type: GrantFiled: May 16, 2003Date of Patent: May 31, 2005Assignee: Daicel Chemical Industries, Ltd.Inventor: Kiyoshi Shimizu
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Patent number: 6872766Abstract: Ultraviolet light absorbing polymer film, coating, or molded article UV filter elements are described which comprise a polymer phase having molecularly dispersed therein a) a first ultraviolet absorbing dibenzoylmethane compound of formula (I) where R1 through R5 are each independently hydrogen, halogen, nitro, or hydroyxl, or further substituted or unsubstituted alkyl, alkenyl, aryl, alkoxy, acyloxy, ester, carboxyl, alkyl thio, aryl thio, alkyl amine, aryl amine, alkyl nitrile, aryl nitrile, arylsulfonyl, or 5-6 member heterocylce ring groups, and b) a second ultraviolet light absorbing compound which absorbs ultraviolet light at a wavelength for which the first compound is deficient at absorbing. In particular embodiments, the second ultraviolet light absorbing compound may comprise a hydroxyphenyl-s-triazine, hydroxyphenylbenzotriazole, formamidine, benzoxazinone, or benzophenone compound.Type: GrantFiled: May 17, 2002Date of Patent: March 29, 2005Assignee: Eastman Kodak CompanyInventors: Timothy C. Schunk, Kurt M. Schroeder, Charles H. Appell, Daniel T. Linehan
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Patent number: 6852793Abstract: Optically transparent, relatively high refractive index polymeric compositions and ophthalmic devices such as intraocular lenses and corneal inlays made therefrom are described herein. The preferred polymeric compositions are produced through the polymerization of one or more copolymers with one or more hydrophilic monomers and optionally one or more aromatic-based monomers, hydrophobic monomers or a combination thereof.Type: GrantFiled: June 19, 2002Date of Patent: February 8, 2005Assignee: Bausch & Lomb IncorporatedInventors: Joseph C. Salamone, Jay F. Kunzler, Richard M. Ozark, David E. Seelye
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Patent number: 6815482Abstract: The present invention is directed to a thin packaging film made out of a thermoplastic material with anti-UV properties, characterized in that its composition further comprises a combination of at least one organic compound with at least one inorganic UV-absorbent compound, for improved barrier against UV rays, and improved transparency. Preferably, the organic compound is a benzotriazole, and the inorganic compound is micronized zinc oxide. More preferably, the material for the film further comprises a binder compound, for example a benzophenone, in order to improve the compatibility between the organic component and the base-resin. Preferably, the film thickness is below 80 &mgr;m, more preferably below 35 &mgr;m.Type: GrantFiled: May 10, 2001Date of Patent: November 9, 2004Assignee: The Procter & Gamble CompanyInventors: Thomas Wolfgang Friedrich Hirn, Rached Menif
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Patent number: 6787591Abstract: The invention relates to synergistic stabilizer compositions comprising Hindered Amine Stabilizers (HAS), phenolic antioxidants, and, if appropriate, UV-absorbers, for thermoplastic polymers, especially for polyolefin pipes and other polyolefin molding materials, which are in prolonged contact with water. These mixtures show superior long term performance as measured by standard test methods such as oxidation induction time (OIT).Type: GrantFiled: August 22, 2002Date of Patent: September 7, 2004Assignee: Clariant Finance (BVI) LimitedInventors: Harald Koch, Christoph Kröhnke, Alexander Lichtblau, Matthias Zäh
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Patent number: 6767937Abstract: Polymer film, coating, and molded article elements for use in a display device are described which comprise a polymer phase having molecularly dispersed therein an acid scavenger compound, a hindered amine light stabilizer compound and a hindered phenol antioxidant compound, wherein the hindered amine light stabilizer compound and the hindered phenol antioxidant compound are present at a weight ratio of from 20:1 to 1:20, and the weight ratio of the acid scavenger compound to the total concentration of hindered amine light stabilizer compound and hindered phenol antioxidant compound is from 10:1 to 1:10. Use of a combination of an acid scavenger and a combination of two radical scavenger antioxidants dispersed in a polymer phase in accordance with the invention enables enhanced stabilization of the polymer when exposed to high heat and/or humidity condition, which has been found to be especially desirable when applied to polymer layers laminated into displays (e.g., polarizers in liquid crystal displays).Type: GrantFiled: May 17, 2002Date of Patent: July 27, 2004Assignee: Eastman Kodak CompanyInventors: Timothy C. Schunk, Kurt M. Schroeder, Charles H. Appell, Daniel T. Linehan
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Patent number: 6749898Abstract: There are disclosed a casting film which is used for producing a ceramic green sheet and which comprises a substrate film and a cured layer formed thereon of an addition reaction type silicone composition containing a photosensitizer, in which the cured layer is formed by heat-treating a layer of a photosensitizer-containing addition reaction type silicone composition in a coating amount expressed in terms of solid content in the range of 0.01 to 0.2 g/m2 at a temperature in the range of 40 to 120° C., followed by a treatment with ultraviolet ray irradiation. The casting film is excellent in coatability of ceramic slurry and releasability of ceramic green sheet, and is imparted with high flatness which has heretofore never been realizable by any of conventional casting films.Type: GrantFiled: September 7, 2001Date of Patent: June 15, 2004Assignee: Lintec CorporationInventors: Toru Nakamura, Tomishi Shibano
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Patent number: 6734235Abstract: An extended life fluorescent polyvinyl chloride sheeting and a method for forming the sheeting are disclosed. The sheeting includes a polyvinyl chloride film having a fluorescent colorant incorporated therein. A protective polymer layer is attached to the polyvinyl chloride film. A light filtering agent is incorporated into the protective layer, wherein the filter agent blocks the 425 nm and lower wavelengths of the visible spectrum.Type: GrantFiled: March 21, 2003Date of Patent: May 11, 2004Assignee: Reflexite CorporationInventor: Edward D. Phillips
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Publication number: 20040082694Abstract: Disclosed is a PPS member having an excellent fastness to lights such as ultraviolet light, and of which color does not change even when the member is used outdoors, while retaining the characteristics of PPS. The polyphenylene sulfide member according to the present invention is characterized by having a light-fastness rating of Class 1 or higher, against light from an ultraviolet carbon arc lamp, which rating is measured in accordance with JIS L-0842.Type: ApplicationFiled: August 19, 2003Publication date: April 29, 2004Inventors: Kenzo Kubo, Makoto Nakahara, Taizo Horiike, Hideyuki Yamamoto, Ryutaro Ito, Koji Sumi
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Patent number: 6696233Abstract: The present invention provides a silver halide photographic photosensitive material in which a silver halide photosensitive layer is disposed on a transparent polyethylene terephthalate (PET) film into which an ultraviolet light absorber has been kneaded, wherein the ultraviolet light absorber is at least one kind of ultraviolet light absorber characterized in that (i) a loss of mass is not greater than 10% when heated to 300° C. at a heating rate of 10° C./minute in a nitrogen gas atmosphere, and/or (ii) a difference between a b-value of a sheet having a thickness of 1.5 mm formed after heating for 1 minute at 300° C., a PET resin including an amount of 0.4% by mass of the ultraviolet light absorber and having a water content of not greater than 50 ppm, and a b-value of a sheet having a thickness of 1.5 mm formed after heating the PET resin for 8 minutes at 300° C., is not greater than 3.0.Type: GrantFiled: December 18, 2001Date of Patent: February 24, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Tatsuya Nomura, Takanori Sato, Hideki Takaki
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Patent number: 6673405Abstract: About 0.001 to 5 parts by weight of a hindered phenol-series compound, about 0.01 to 5 parts by weight of a weather (light)-resistant stabilizer, and about 0.001 to 10 parts by weight of a spiro-compound having a triazine ring are added to 100 parts by weight of a polyacetal resin. The spiro-compound may be a compound represented by the following formula (1). The polyacetal resin composition may further comprise a coloring agent, a processing stabilizer, a heat stabilizer, and others. wherein R1 and R2 are the same or different, each representing an alkylene group, an arylene group, or an aralkylene group.Type: GrantFiled: May 13, 2002Date of Patent: January 6, 2004Assignee: Polyplastics Co., Ltd.Inventor: Hatsuhiko Harashina
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Publication number: 20030236375Abstract: Optically transparent, relatively high refractive index polymeric compositions and ophthalmic devices such as intraocular lenses and corneal inlays made therefrom are described herein. The preferred polymeric compositions are produced through the polymerization of one or more copolymers with one or more hydrophilic monomers and optionally one or more aromatic-based monomers, hydrophobic monomers or a combination thereof.Type: ApplicationFiled: June 19, 2002Publication date: December 25, 2003Inventors: Joseph C. Salamone, Jay F. Kunzler, Richard M. Ozark, David E. Seelye
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Patent number: 6653420Abstract: The present invention relates to a process for the manufacture of a porous polymer, wherein a composition comprising a polymerizable component, a porogen having an inverse temperature dependent solubility and a solvent are polymerized at a temperature around the cloud point temperature of the composition. The porous polymers obtainable according to the process of the invention are useful, for example, as materials for the manufacture of biomedical devices and prostheses, including ophthalmic devices such as contact lenses or artificial corneas.Type: GrantFiled: January 5, 2001Date of Patent: November 25, 2003Assignee: Novartis AGInventors: Angelika Maria Domschke, Vimala Mary Francis
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Patent number: 6586507Abstract: Hindered amines substituted on the N-atom with an —O—E—OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal —O—E moieties.Type: GrantFiled: October 3, 2001Date of Patent: July 1, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: James Peter Galbo, Gerald A. Capocci, Nancy N. Cliff, Robert E. Detlefsen, Michael P. DiFazio, Ramanathan Ravichandran, Peter Solera, Christophe Bulliard
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Patent number: 6583203Abstract: To offer a resin material in which various properties such as excellent appearance and rigidity inherent to a polyacetal resin are maintained and a weather (light) resistance is improved. That is, a branched polyacetal resin composition comprising 100 parts by weight of a branched polyacetal copolymer (A) having an oxymethylene group as the main repeating unit and having a branching unit represented by the following formula (I), 0.01 to 5 parts by weight of a weather (light) resistant stabilizer (B) and 0.01 to 5 parts by weight of a hindered amine substance (C): wherein m and n each is an integer of 0 to 5; the sum of m+n is 1 to 5; and R is a monovalent organic group having a molecular weight of 40 to 1000.Type: GrantFiled: July 5, 2001Date of Patent: June 24, 2003Assignee: Polyplastics Co., Ltd.Inventors: Kuniaki Kawaguchi, Hidetoshi Okawa, Yoshihisa Tajima
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Patent number: 6552106Abstract: An extended life fluorescent polyvinyl chloride sheeting and a method for forming the sheeting are disclosed. The sheeting includes a polyvinyl chloride film having a fluorescent colorant incorporated therein. A protective polymer layer is attached to the polyvinyl chloride film. A light filtering agent is incorporated into the protective layer, wherein the filter agent blocks the 425 nm and lower wavelengths of the visible spectrum.Type: GrantFiled: September 26, 2001Date of Patent: April 22, 2003Assignee: Reflexite CorporationInventor: Edward D. Phillips
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Publication number: 20030069360Abstract: A graded-refractive-index optical plastic material composed of an amorphous fluoropolymer and at least one material which differs from the polymer in refractive index by at least 0.001, wherein the material is so distributed as to have a concentration gradient in a specific direction, and a method for its production.Type: ApplicationFiled: October 3, 2002Publication date: April 10, 2003Applicant: Yasuhiro KOIKEInventors: Yasuhiro Koike, Masaki Naritomi