Non C-oh Oxygen Atom, Or Element Other Than C, O, Or H, E.g., Tartaric Acid Metal Salt, Etc. Patents (Class 524/381)
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Patent number: 5182174Abstract: A coating composition is disclosed comprising an organosilane polymer, a polyester or a copolymer thereof, an amino resin crosslinking agent, and a silsesquioxane compound. Such a composition is especially useful for providing a flexible finish on non-metallic parts of automobiles and trucks. This finish has the advantage of superior etch resistance and outstanding weatherability and durability characteristics.Type: GrantFiled: May 13, 1991Date of Patent: January 26, 1993Assignee: E. I. du Pont de Nemours and CompanyInventor: Maurice A. S. Stephenson
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Patent number: 5128392Abstract: The present invention relates to filled elastomers which can be cured at low temperatures utilizing a quinoid/peroxide curing system in the presence of a select polar solvent accelerator. The select solvent accelerators which are utilized have the dual function of acting as both dispersing agents and curing accelerators. The instant invention herein includes the instant curing system, its use in a tire sealant composition, the puncture-sealing layer formed of the cured composition and the puncture-sealing tire.Type: GrantFiled: August 15, 1988Date of Patent: July 7, 1992Assignee: Bridgestone/Firestone, Inc.Inventors: Mario N. DeTrano, William L. Hergenrother, Donald B. Diehl
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Patent number: 5079193Abstract: An encapsulant composition comprising a lead zinc silicoborate glass which forms a crystalline phase of Zn.sub.2 SiO.sub.4 and ZnB.sub.2 O.sub.4 when it is fired at 650.degree.-800.degree. C.Type: GrantFiled: July 31, 1990Date of Patent: January 7, 1992Assignee: E. I. Du Pont de Nemours and CompanyInventor: Paul C. Donohue
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Patent number: 5051311Abstract: A curable coating composition, which provides excellent corrosion protection to metals, is disclosed. The composition comprises (I) a reaction product (or blend) of a resinous copolymeric siloxane solution with a liquid organohydrogenpolysiloxane, (II) a hydroxy-functional diorganopolysiloxane, (III) an organosilane, (IV) a trialkyl orthoformate, (V) an organic titanate and (VI) a condensation catalyst. High solids compositions of the present invention can be applied by conventional siphon cup spray equipment and have an extended bath life relative to prior art formulations of this type.Type: GrantFiled: March 1, 1990Date of Patent: September 24, 1991Assignee: Dow Corning CorporationInventors: Paul J. Popa, Arthur J. Tselepis, Harold L. Vincent
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Patent number: 5037870Abstract: The invention relates to the stabilization of organic polymers against degradation by light by the addition of (a) a light stabilizer of the formula ##STR1## in which R is hydrogen or methyl and A is an alkylene radical, and (b) an oxide, hydroxide, carboxylate, enolate or phenate of magnesium or zinc.Type: GrantFiled: August 20, 1990Date of Patent: August 6, 1991Assignee: Ciba-Geigy CorporationInventor: Francois Gugumus
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Patent number: 4996260Abstract: Compositions, such as caulks, paints, sealants and water barriers have a binder which comprises emulsified and/or dispersed (A) film forming latex, (B) non-forming liquid polysulfide and (C) hydrocarbon resin.Type: GrantFiled: December 7, 1989Date of Patent: February 26, 1991Assignee: Morton International, Inc.Inventor: Daniel O'Connell
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Patent number: 4988749Abstract: Disclosed herein are nitrile polymers which are stabilized against color degradation caused by ionizing radiation by the addition of a stabilizing agent comprising a combination of selected sulfur containing compounds as stabilizers and sulfur containing plasticizers.Type: GrantFiled: November 27, 1989Date of Patent: January 29, 1991Assignee: Monsanto CompanyInventors: Vincent A. Aliberti, James K. Stevens
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Patent number: 4966926Abstract: An encapsulant composition comprising a lead zinc silicoborate glass which forms a crystalline phase of Zn.sub.2 SiO.sub.4 and ZnB.sub.2 O.sub.4 when it is fired at 650.degree.-800.degree. C.Type: GrantFiled: August 11, 1989Date of Patent: October 30, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventor: Paul C. Donohue
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Patent number: 4880860Abstract: The invention relates to polyester molding compositions, comprising substantially the polyester, preferably polyethylene terephthalate, a nucleating agent, a special imide compound as a further crystallization accelerator and, if appropriate, the conventional reinforcing agents and additives. The special crystallization accelerator according to the invention is virtually unreactive with the polyester and, in particular, is considerably more resistant to migration than relevant crystallization accelerators according to the state of the art. The invention also relates to a process for the preparation of these polyester molding compositions.Type: GrantFiled: August 25, 1988Date of Patent: November 14, 1989Assignee: Hoechst AktiengesellschaftInventor: Erich Blocker
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Patent number: 4837264Abstract: High-impact polyamide molding compositions contain as essential components(X) from 40 to 98% by weight, based on (X)+(Y), of a thermoplastic polyamide,(Y) from 2 to 60% by weight, based on (X)+(Y), of a rubberlike polymer which contains, as copolymerized units, an acrylic or methacrylic ester or an unsaturated carboxylic acid,(Z) from 0.001 to 2% by weight, based on (X)+(Y), of a metal compound selected from the group consisting of(Z.sub.1) salts of divalent, trivalent or tetravalent metals with C.sub.2 -C.sub.4 -carboxylic acids,(Z.sub.2) oxides of germanium or antimony and(Z.sub.3) alkyl orthotitanates and dialkyltin dilaurates.Type: GrantFiled: January 5, 1988Date of Patent: June 6, 1989Assignee: BASF AktiengesellschaftInventors: Franz Zahradnik, Karlheinz Ulmerich, Graham E. McKee, Horst Reimann, Richard Pflueger, Rainer Theysohn
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Patent number: 4829115Abstract: This invention is concerned with the stabilization of organic materials subject to oxidative degradation. The synergists of this invention possess organothioethyl alcohol segmers or moieties which enhance the antioxidative activity of phenolic and amine stabilizers. The invention is also concerned with compounds that contain an organothioethyl alcohol moiety and their use in oxidizable materials in combination with polymerizable and/or conventional antidegradants.Type: GrantFiled: March 3, 1988Date of Patent: May 9, 1989Assignee: The Goodyear Tire & Rubber CompanyInventor: Kirkwood S. Cottman
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Patent number: 4826906Abstract: Disclosed herein is a poly(arylene thioether-ketone) composition improved in melt stability and crystallinity, which comprises (A) 100 parts by weight of a melt-stable poly(arylene thioether-ketone) (PTK) and (B) 0.1-30 parts by weight of at least basic compound selected from the group consisting of the hydroxides, oxides and aromatic carboxylic acid salts of Group IIA metals of the periodic table other than magnesium and the hydrocarbyl oxides, aromatic carboxylic acid salts, carbonates, hydroxides, phosphates and borates of Group IA metals of the periodic table. The phosphates and borates include condensation products. The PTK has predominant recurring units of the formula ##STR1## and having a melting point, Tm of 310.degree.-380.degree. C., a residual melt crystallization enthalpy, .DELTA.Hmc (420.degree. C./10 min) of at least 10 J/g, a melt crystallization peak-temperature, Tmc (420.degree. C./10 min) of at least 210.degree. C. and a reduced viscosity of 0.2-2 dl/g.Type: GrantFiled: June 17, 1988Date of Patent: May 2, 1989Assignee: Kureha Kagaku Kogyo K.K.Inventors: Yoshikatsu Satake, Ken Kashiwadate, Yo Iizuka, Toshitaka Kouyama, Takayuki Katto, Zenya Shiiki
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Patent number: 4789701Abstract: The method of modifying an organic material including rubber and plastics which consists in the steps of embodying in the organic material during manufacture of the glycerato-zinc complex (C.sub.3 H.sub.6 O.sub.3 Zn) which is manufactured by heating a zinc compound and glycerol to a temperature below the boiling point of the glycerol to form crystals having substantial two-dimensional extension but low thickness and orientating the crystals selectively to improve tensile strength and reduce ultraviolet light degradation of the organic material.Type: GrantFiled: April 23, 1987Date of Patent: December 6, 1988Assignee: Glyzinic Pharmaceuticals LimitedInventor: Reginald M. Taylor
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Patent number: 4761448Abstract: The melting point and the apparent degree of crystallinity of a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against undue lowering during melt processing by inclusion within the polymer of an aluminum tri-alkoxide or hydrolysis product thereof.Type: GrantFiled: September 29, 1987Date of Patent: August 2, 1988Assignee: Shell Oil CompanyInventors: Robert Q. Kluttz, Richard A. Kemp, Robert C. Ryan
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Patent number: 4711796Abstract: A poly(arylene sulfide) coating composition, method of preparing the composition, and method of coating are disclosed. The composition comprises a finely-divided poly(arylene sulfide) having from about 75 to about 99 mole percent para-polymerized aromatic units and from about 1 to about 25 mole percent ortho- or meta- polymerized aromatic units and, optionally, from about 0.1 to about 2 mole percent trifunctionally-polymerization aromatic units. The coating resin can be prepared in a polymerization reaction medium containing a molar excess of base, with respect to sulfur present, and can be washed with water at at least about 100.degree. C. to lower the curing temperature of the coating composition. The compositions are particularly suited for application in which curing temperatures of 350.degree. C. or lower are desired.Type: GrantFiled: June 30, 1986Date of Patent: December 8, 1987Assignee: Phillips Petroleum CompanyInventors: Michael C. Yu, Roy F. Wright
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Patent number: 4711921Abstract: The invention provides an improved heat stabilization of post-chlorinated vinyl chloride polymers utilizing barium carbonate or cadmium carbonate that has a surface area greater than 2M.sup.2 /g.Type: GrantFiled: October 10, 1986Date of Patent: December 8, 1987Assignee: The B. F. Goodrich CompanyInventor: Marvin H. Lehr
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Patent number: 4705820Abstract: A surgical suture coating comprising a random copolymer is disclosed. The copolymer has about 25 to 75 weight percent of glycolic acid ester linkages. The remaining linkages comprise at least trimethylene carbonate. The copolymer has a glass transition temperature at or below ambient temperature.Type: GrantFiled: September 5, 1986Date of Patent: November 10, 1987Assignee: American Cyanamid CompanyInventors: David W. Wang, Donald J. Casey, Leonard T. Lehmann
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Patent number: 4670498Abstract: A polyester block copolymer composition comprising 100 parts by weight of a polyester block copolymer and 0.05 to 10 parts by weight of a metal alcoholate of the formula: M(OR).sub.n, wherein M is a metal of the groups I to III in periodic table, R is a hydrocarbon group having 1 to 20 carbon atoms, and n is 1 to 3, said polyester block copolymer composition having improved melt properties and being suitable for producing various shaped articles by extrusion molding.Type: GrantFiled: November 5, 1985Date of Patent: June 2, 1987Assignee: Toyo Boseki Kabushiki KaishaInventors: Hironobu Furusawa, Tadao Taika
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Patent number: 4656216Abstract: In order to preserve the solubility of films and moldings of polyvinyl alcohol in cold water even under the action of an aggressive atmosphere, in particular a strongly acidic atmosphere, the thermoplastically processable polyvinyl alcohol composition used for the preparation of the films and moldings is stabilized by the addition of a water-soluble polymer or copolymer which is composed to the extent of at least 70% by weight of monomer units which are carboxylic acid amides at least monosubstituted on the amido nitrogen. N-vinylpyrrolidine, N-vinyl-N-methylacetamide and the alkali metal salts or the ammonium salts of 2-acrylamido-2-methylpropanesulfonic acid have proved to be particularly suitable representatives of this group of compounds.Type: GrantFiled: March 19, 1985Date of Patent: April 7, 1987Inventors: Albrecht Muller, Wolfgang Zimmermann
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Patent number: 4649171Abstract: A polyolefin molding composition which contains a very small amount of a metal salt of citric acid brings about only very slight corrosion to the machines during processing.Type: GrantFiled: July 2, 1985Date of Patent: March 10, 1987Assignee: Hoechst AktiengesellschaftInventors: Martin Bonnke, Lothar Bothe
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Patent number: 4618457Abstract: Sulfonated polyoxyalkylene ethers of the formulaR.sup.1 CH.sub.2 O--(C.sub.2 H.sub.4 O--).sub.n (C.sub.3 H.sub.6 O--).sub.m CH.sub.2 CHR.sup.3 CH.sub.2 --SO.sub.3 Xin which R.sup.1 is ##STR1## R2 is CH.sub.3 --, C.sub.2 H.sub.5 --, or C.sub.3 H.sub.7 --, R.sup.3 is H-- or CH.sub.3 --, X is H--, alkali metal or ammonium ion, n is 0 to 100, m is 0 to 50, and n+m is not less than 1. The compounds are prepared by adding a compound of formula HSO.sub.3 X in a known manner by a free radical reaction in the presence of catalysts and optionally at an elevated temperature to compounds of the formulaR.sup.1 CH.sub.2 O--(C.sub.2 H.sub.4 O--).sub.n (C.sub.3 H.sub.6 O--).sub.m CH.sub.2 CHR.sup.3 .dbd.CH.sub.2.The inventive compounds can be used as the only or a partial polyol component for the preparation of curable, polyurethane-based adhesives and increase the combined tensile and shear strength and the floating roller peel strength of the adhesive bonds.Type: GrantFiled: March 1, 1985Date of Patent: October 21, 1986Assignee: Th. Goldschmidt AGInventors: Eberhard Esselborn, Jurgen Fock
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Patent number: 4616055Abstract: A mixture of virgin crumb rubber sized to between 30 mesh and 100 mesh containing less than 5%+100 fines and thermoplastic binder, such as carbon black filled polyethylene containing a coating promoter, such as a citrate salt and lubricant, such as a calcium stearate, is mixed in a vented Banburg mixer heated to at least 350.degree. F. to remove volatiles through vent before extrusion. The mixture is formed into sheet in the nip of a two roll assembly and cooled in air before diced into pellets by a dicer.The pellets are formed into porous pipe by extrusion in a pipe extruder having the feeding, transition and metering zones separately heated to temperatures from 320.degree. F. to 400.degree. F. (T.sub.1, T.sub.2, T.sub.3). The die has a separate jacket receiving heat exchange fluid for heating the die to a temperature from 290.degree. F. to 380.degree. F. to form a porous pipe having more uniformly spaced and sized pores and a smoother inner wall surface.Type: GrantFiled: May 13, 1985Date of Patent: October 7, 1986Assignee: Dasurat Enterprises PTE, Ltd.Inventor: James W. Mason
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Patent number: 4585815Abstract: A stencil printing ink is described, comprising 0.5 to 20% by weight pigment, 5 to 30% by weight extender pigment, 0.5 to 5% by weight water-soluble polymer (the viscosity of its 10% aqueous solution is at least 40 cps), 3 to 15% by weight (calculated as solids) o/w type resin emulsion, 5 to 20% by weight polyhydric alcohol and water. This ink can produce printed images without being affected by printing conditions such as temperature and application pressure. Thus, it is suitably used in stencil printing for non-professional or unskilled people.Type: GrantFiled: December 12, 1983Date of Patent: April 29, 1986Assignee: Pilot Ink Co., Ltd.Inventors: Yoshiaki Ono, Takeshi Teranishi
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Patent number: 4574111Abstract: The invention relates to electric insulation of polyolefin suitable for medium and high voltage from about 10 kV which resists the formation of so-called water trees. For this purpose, the insulation contains as an additive at least one alcoholate of magnesium, calcium or aluminum. The electric insulation according to the invention is particularly suitable for use in cables and wires.Type: GrantFiled: June 28, 1985Date of Patent: March 4, 1986Assignee: Siemens AktiengesellschaftInventors: Hans-Joachim Henkel, Norbert Muller
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Patent number: 4485140Abstract: Melt-fusible polyimides based on pyromellitic dianhydride and 2,2-bis[3,5-dichloro-4-(4-aminophenoxy)phenyl]propane, alone or in combination with other defined diamines, are useful in making low-void composites and thermoplastic tapes, which can be fabricated into articles such as, for example, aircraft and autobody panels, printed circuit boards, etc.Type: GrantFiled: January 27, 1984Date of Patent: November 27, 1984Assignee: E. I. Du Pont de Nemours and CompanyInventors: Thomas P. Gannett, Hugh H. Gibbs, Robert J. Kassal
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Patent number: 4455402Abstract: Two stage film-forming polymers having a soft first and a hard second stage are prepared by emulsion polymerizing the first stage and then, in the presence of a coalescent, the second stage. The polymers combine low MFT with superior early block resistance and high temperature hardness.Type: GrantFiled: January 5, 1983Date of Patent: June 19, 1984Assignee: Rohm and Haas CompanyInventors: David R. Amick, Sidney Melamed, Ronald W. Novak
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Patent number: 4421889Abstract: Dispersion paints with high wet adhesion are obtained if, as the binder thereof, an aqueous plastics dispersion is used, the polymer content of which includes monomeric units of an acetoacetic acid ester of an unsaturated alcohol, especially vinyl or allyl alcohol or a diester of a dihydroxy compound in which one acyl radical is acetoacetyl and the other acyl radical is an acrylic or methacrylic radical. The preparation of paints with a low pigment content is especially facilitated by the use of such a dispersion.Type: GrantFiled: May 13, 1983Date of Patent: December 20, 1983Assignee: Hoechst AktiengesellschaftInventors: Helmut Braun, Helmut Rinno, Werner Stelzel
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Patent number: 4404331Abstract: Improved enamels and insulated electrical articles produced therefrom are described. The enamels are composed of solutions of curable resin which have been modified to contain nylon polymer. This polymer facilitates application of the enamel to a metallic conductor so as to produce an especially smooth and desirable insulation coating.Type: GrantFiled: May 21, 1982Date of Patent: September 13, 1983Assignee: General Electric CompanyInventor: Denis R. Pauze
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Synthetic resin composition, process for its preparation, its use and sheet made of said composition
Patent number: 4385139Abstract: A synthetic resin composition is prepared by mixing various polymers which differ, above all, in their second order transition temperature; the composition can also contain a filler, an epoxide resin and an alcoholate. The composition is preferably obtained in the form of granules, the particle diameter being within the range from 1 to 10 mm. It is used as a starting material for the production of vibration-damping sheets.Type: GrantFiled: October 9, 1981Date of Patent: May 24, 1983Assignee: Hoechst AktiengesellschaftInventors: Manfred Kuchler, Gunther Duve, Joachim Ebigt -
Patent number: 4369289Abstract: Relatively stable masterbatch compositions are provided comprising a matrix having a polysiloxane dispersed therein, prepared by admixing a solid or liquid matrix, a monomeric silane and a silane condensation catalyst with the result that the monomeric silane condenses to a polysiloxane which is dispersed throughout the matrix per se or as a reactant therein. The masterbatch composition can be admixed with alkylene-alkyl acrylate copolymers in the presence of an organic titanate, to produce water-curable compositions, containing water-curable, silane modified alkylene-alkyl acrylate copolymers, which are useful as extrudates about wires and cables providing protective coatings thereon.Type: GrantFiled: August 20, 1981Date of Patent: January 18, 1983Assignee: Union Carbide CorporationInventor: Michael J. Keogh
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Patent number: 4361665Abstract: Heat-stable vinyl halide resin compositions comprise (a) a vinyl halide resin prepared by the polymerization of a vinyl halide-containing monomer component in an aqueous medium in the presence of a free radical generating polymerization initiator and a chain-terminating agent that is an ortho-dihydric phenol and (b) a liquid antimony stabilizer composition.Type: GrantFiled: June 15, 1981Date of Patent: November 30, 1982Assignee: Tenneco Chemicals, Inc.Inventors: Robert S. Miller, Samuel Hoch, Mario Q. Ceprini
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Patent number: 4360619Abstract: This invention relates to stabilizer compositions for polymers comprising (1) an organotin compound, or mixture of organotin compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and, optionally, (3) a halogen-containing tin compound or mixture of halogen-containing tin compounds, said stabilizers having a total halogen content of about 0.1% to about 10% by weight based on the weight of the stabilizer composition. This invention also relates to polymer compositions containing said stabilizers, to a process for stabilizing polymer by adding thereto said stabilizers, and to articles of manufacture, e.g. pipe, comprising a polymer and said stabilizers.Type: GrantFiled: February 26, 1981Date of Patent: November 23, 1982Assignee: Carstab CorporationInventors: Thomas G. Kugele, Keith A. Mesch, Karl R. Wursthorn
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Patent number: 4357434Abstract: Stabilized halogen-containing resin compositions comprising a halogen-containing resin, at least one organo tetravelent tin stabilizer selected from the group consisting of an alkyl tin laurate and an alkyl tin maleate and as a stabilizer assistant a hydroxymercaptan compound having the following the general formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and are each hydrogen atom, substituted or unsubstituted alkyl, alkenyl, aryl, cycloalkyl, hydroxyalkyl, alkoxyalkyl, carboalkoxyalkyl, epoxyalkyl or epoxyalkenyl, with the proviso R.sub.1 and R.sub.3 may form a ring together.Type: GrantFiled: March 16, 1981Date of Patent: November 2, 1982Assignee: Ajinomoto Company IncorporatedInventors: Takeshi Miyoshi, Koji Takeuchi, Tatsuo Nukui, Hidetaka Oshida
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Patent number: 4336168Abstract: Shelf-stable liquid antimony stabilizer compositions for vinyl halide resin compositions comprise a liquid antimony organic sulfur- and/or oxygen-containing compound, such as antimony tris-(isooctyl thioglycolate), and a stabilizing amount of an acidic organic compound that may be a mercaptoacid ester, mercaptan, mercaptoacid, mercaptoalcohol, monocarboxylic acid, or a mixture thereof.Type: GrantFiled: April 28, 1980Date of Patent: June 22, 1982Assignee: Tenneco Chemicals, Inc.Inventors: Samuel Hoch, Mario Q. Ceprini
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Patent number: 4336343Abstract: A polyester based composition comprising sodium citrate as a nucleating agent.Type: GrantFiled: June 25, 1981Date of Patent: June 22, 1982Assignee: Morris Township, Morris CountyInventor: Shaul M. Aharoni
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Patent number: 4331656Abstract: A composition for treating oily hair or skin to reduce the oily appearance thereof comprises in an appropriate vehicle an active compound having the formula, ##STR1## wherein n is a whole number from 1-10 inclusive, p is 0, 1 or 2, and R.sub.1 is ##STR2## wherein R.sub.2 is ##STR3## or --CO.sub.2 H wherein R.sub.3 and R.sub.4 represent hydrogen, 2-hydroxy ethyl, 2-hydroxy propyl or 2,3-dihydroxy propyl; (iii) --(CH.sub.2 --CHR.sub.5) OH wherein R.sub.5 is hydrogen, methyl or hydroxy methyl; ##STR4## wherein R.sub.3 and R.sub.4 have the meanings given above; or (v) ##STR5## wherein q is 1 or 2 and A represents hydrogen, acyl, succinoyl, nictinoyl or thenoyl; with the proviso that p is other than 0 and n is other than 2-4 when R.sub.1 is (iv) or (v).Type: GrantFiled: January 21, 1980Date of Patent: May 25, 1982Assignee: L'OrealInventors: Claude Bouillon, Jean Maignan
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Patent number: 4330456Abstract: Continuous process for producing a finely divided aqueous dispersion of a homogeneous phase of at least one fusible solid ingredient and possibly of at least one liquid ingredient in which an aqueous solution of dispersion additive with a melted homogeneous phase is continuously subjected to a high velocity gradient in an agitation zone. The respective temperatures and flow rates of the aqueous solution and the homogeneous phase are regulated so that the homogeneous phase of the dispersion thusly produced reaches its solidification temperature after the dispersion has been evacuated from the agitation zone and before thermal equilibrium between the aqueous solution and the homogeneous phase is reached.Type: GrantFiled: December 26, 1978Date of Patent: May 18, 1982Assignee: Chloe ChimieInventors: Bernard Bonnaud, Jean-Bernard Pompon
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Patent number: 4317758Abstract: Selected sulfur-containing compounds function as solution viscosity stabilizers in aqueous compositions comprising acrylamide polymers containing a redox couple or components which can produce a redox couple in the presence of the solution. The aqueous compositions are useful in post-primary oil recovery involving the use of thickened fluids as mobility buffers and mobility control agents.Type: GrantFiled: April 28, 1980Date of Patent: March 2, 1982Assignee: Phillips Petroleum CompanyInventor: Donald D. Bruning