Carbocyclic Group, E.g., Aryl, Etc. Patents (Class 524/396)
  • Patent number: 7879933
    Abstract: Certain thermoplastic additives that induce simultaneous good material properties and high nucleation efficacy are provided. Such additives include combinations of a phosphate salt and a dicarboxylate salt. This combination or blend may be provided in various ratios. A method for applying such a combination in a thermoplastic formulation is also disclosed. A thermoplastic formulation, which may or may not include polypropylene, is also disclosed in connection with the combination.
    Type: Grant
    Filed: October 14, 2008
    Date of Patent: February 1, 2011
    Assignee: Milliken & Company
    Inventor: Rob Hanssen
  • Publication number: 20110008636
    Abstract: There is provided a curable resin composition comprising a cycloolefin polymer and a cyclic peroxide which has a cyclic structure and a peroxy structure in the cyclic structure. There is also provided a laminate obtained by using a molded article which is obtained by forming the curable resin composition into a sheet shape or a prepreg which is obtained by impregnating the curable resin composition into a reinforcing fiber.
    Type: Application
    Filed: March 2, 2009
    Publication date: January 13, 2011
    Inventors: Takashi Kiuchi, Kiyoshige Kojima
  • Publication number: 20100317779
    Abstract: Disclosed are scratch resistant polypropylene molded parts comprising a) a polypropylene substrate and incorporated therein a combination of b) an alpha, beta-unsaturated carboxylic reagent functionalized olefin polymer or copolymer, c) a primary or secondary fatty acid amide and d) a nucleating agent selected from the group consisting of sodium benzoate, 2,2?-methylene-bis(4,6-di-tert-butylphenyl)phosphate, zinc glycerolate, calcium salt of 1,2-dicarboxylic acid cyclohexane and sodium salt of 1,2-dicarboxylic acid norbornane. Also disclosed is a method for providing scratch resistance to a polypropylene molded part by incorporating said additives. The polypropylene substrate is for instance polypropylene homopolymer or thermoplastic polyolefin (TPO). Component b) is for instance maleated polypropylene or the reaction product of an alpha-olefin and maleic anhydride. The fatty acid amide is for instance stearyl erucamide or oleyl palmitamide. The molded parts are suitable for automotive parts.
    Type: Application
    Filed: May 18, 2010
    Publication date: December 16, 2010
    Inventors: Hung Pham, Nikolas Kaprinidis, Ralph Dieter Maier, Johanne Wilson
  • Patent number: 7820756
    Abstract: A polymeric composition suitable for manufacturing heat sealable films or sheets comprising, polyethylene terephthalate (PET) to the extent of about 80% to 95% by mass of the total composition; a polymer additive for lowering the melting point of the composition selected from Polyethylene Naphthalate (PEN), Polytrimethylene Naphthalate (PTN), in-situ formed Polyethylene Naphthalate (PEN) and in situ formed Polytrimethylene Naphthalate (PTN) to the extent of about 20% to 5% by mass of the total composition; a nucleating agent to the extent of about 200 to 1500 ppm by mass of the composition; a polycondensation catalyst to the extent of about 30 to 300 ppm by mass of the composition; a clear fast reheat (CFRH) additive to the extent of about 10 to 30 ppm by mass of the composition; a color toner to the extent of about 0.75 to 25 ppm by mass of the composition; and a heat stabilizer to the extent of about 20 to 55 ppm by mass of the composition.
    Type: Grant
    Filed: September 19, 2008
    Date of Patent: October 26, 2010
    Assignee: Futura Polyesters Limited
    Inventors: Kulkarni Sanjay Tammaji, Palaniandavar Santhana Gopala Krishnan, Dilly Raj Balasundaram
  • Publication number: 20100267877
    Abstract: The present invention relates to a polymer composition, comprising (i) a polypropylene homopolymer, (ii) a polypropylene random copolymer, prepared by copolymerization of propylene with an olefin comonomer and having an amount of olefin comonomer units of 0.2 to 5 wt %, and (iii) an elastomeric copolymer of propylene and at least one olefin comonomer, the polymer composition having a tensile modulus, determined according to ISO 527-2/1B at 1 mm/min. and 23° C., of at least 1200 MPa.
    Type: Application
    Filed: July 1, 2010
    Publication date: October 21, 2010
    Inventors: Kauno Alastalo, Carl-Gustaf Ek, Bo Malm, Ulf Torgersen, Olli Tuominen
  • Publication number: 20100234507
    Abstract: A high impact strength random block copolymer including (a) about 65-97 wt. % of a crystalline propylene/ethylene copolymer A containing from about 0.5 wt. % to about 6 wt. % derived from ethylene and from about 94 wt. % to about 99.5 wt. % derived from propylene, and (b) about 3-35 wt. % of a propylene/ethylene copolymer B containing from about 8 wt. % to about 40 wt % derived from ethylene and from about 60 wt % to about 92 wt. % derived from propylene. The crystalline to amorphous ratio Lc/La of the random block copolymer ranges from about 1.00 to about 2.25. The random block copolymer is characterized by both high toughness and low haze.
    Type: Application
    Filed: March 11, 2009
    Publication date: September 16, 2010
    Inventors: Jose Pezzutti, Alberto Benito, Guillermo Cassano, Leandro Roth, Werner Schoene, Hartmut Siebert, Andreas Winter, Anita Dimeska, Vassilios Galiatsatos
  • Publication number: 20100218892
    Abstract: A maleimide terminated polyimide incorporated into a two-part acrylic structural adhesive system. The maleimide terminated polyimide of the various embodiments of the present invention provide improving thermal stability, strength, and toughness.
    Type: Application
    Filed: February 2, 2010
    Publication date: September 2, 2010
    Inventors: JIAN-PING HUANG, Eric N. Wyman
  • Patent number: 7776947
    Abstract: A golf ball composition having a copolymer with an acid content modified by a nucleating agent is described. The nucleating agent modifies the flexural modulus of the acid copolymer.
    Type: Grant
    Filed: October 17, 2008
    Date of Patent: August 17, 2010
    Assignee: Acushnet Company
    Inventor: Michael D. Jordan
  • Publication number: 20100203307
    Abstract: Disclosed is an adhesive tape containing a flux activation compound having a carboxyl group and/or a phenolic hydroxyl group, a thermosetting resin and a film-forming resin. In this adhesive tape, the thermosetting resin may be an epoxy resin, and may contain a curing agent. The curing agent may be an imidazole compound and/or a phosphorus compound. This adhesive tape can be used as an interlayer material for circuit boards or multilayer flexible printed wiring boards.
    Type: Application
    Filed: September 28, 2007
    Publication date: August 12, 2010
    Applicant: Sumitomo Bakelite Co., Ltd.
    Inventors: Toshio Komiyatani, Takashi Hirano, Kenzou Maejima, Satoru Katsurayama, Tomoe Yamashiro
  • Publication number: 20100160518
    Abstract: The present subject matter relates generally to a controlled nucleated polymer composition comprising: (1) a polyolefin resin; (II) a nucleator; and (III) a nucleation regulator.
    Type: Application
    Filed: March 20, 2007
    Publication date: June 24, 2010
    Applicant: Basell Poliolefine Italia s.r.l.
    Inventors: Joseph P. Congdon, Jean-Francois Croteau
  • Publication number: 20100068540
    Abstract: To provide a curable composition and an adhesive which exhibit a temporarily fixing effect very quickly and which are completely cured quickly at room temperature, and a bonding method. A curable composition comprising a component (A): a polymerizable acrylic liquid composition, a component (B): cumene hydroperoxide, a component (C): a reducing agent containing vanadium or copper or a reducing agent comprising ethylene thiourea, and a component (D): a basic compound having a primary, secondary or tertiary amine structure, and a bonding method using it.
    Type: Application
    Filed: February 28, 2008
    Publication date: March 18, 2010
    Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHA
    Inventors: Yuki Hisha, Kimihiko Yoda
  • Publication number: 20100056687
    Abstract: Flame retardant compositions are disclosed which comprise (a) at least one particulate material which expands on the application of heat and (b) at least one particulate nano-filler, together with at least one polymer and/or at least one curable monomer or oligomer. The compositions may also contain certain silicon-based materials. Flame-retardant compositions comprising polyorganosiloxanes containing one or more functional groups selected from amino, hydroxyl, methacrylic, acrylic and epoxy groups, are also disclosed.
    Type: Application
    Filed: November 6, 2009
    Publication date: March 4, 2010
    Applicant: Huntsman Advanced Materials Americas LLC
    Inventors: Constantinos D. Diakoumakos, Dimiter Lubomirov Kotzev
  • Publication number: 20100056684
    Abstract: The present invention has its object to provide a rubber composition for a studless tire that contributes to both good braking force and high handling stability on ice or snow, and a high performance studless tire using the rubber composition. The rubber composition for the studless tire contains: a mixture of a zinc salt of an aliphatic carboxylic acid and a zinc salt of an aromatic carboxylic acid; an oil or a plasticizer; and a rubber component that comprises 40% by mass or more of a butadiene rubber relative to 100% by mass of a total amount of the rubber component.
    Type: Application
    Filed: June 15, 2009
    Publication date: March 4, 2010
    Inventors: Takayuki HATTORI, Ryoji Kojima, Naohiko Kikuchi
  • Publication number: 20100056686
    Abstract: Curable elastomer compositions and cured and/or curable articles made therefrom, the curable elastomer composition comprising an essentially unsaturated rubber elastomer, between 0.5 and 25 phr of a metal salt of a carboxylic acid, an effective amount of a peroxide curing agent for curing the elastomer composition and between 0.1 and 10. phr of a hysteresis-decreasing multifunctional curing coagent that decreases the hysteresis of the cured elastomer composition, wherein the hysteresis is measured using a rotorless shear rheometer as a loss tangent at 150° C., 41.85% strain and 10 Hz. The hysteresis of such a cured composition may decrease by at least 15% or alternatively, by at least 25%. The elastomer is useful in tires including, for example, the sidewall supports, the carcass reinforcement and the tread.
    Type: Application
    Filed: December 20, 2006
    Publication date: March 4, 2010
    Applicant: SOCIETE DE TECHNOLOGIE MICHELIN
    Inventor: Brian R. Bergman
  • Publication number: 20100056685
    Abstract: The present invention has its object to provide a high performance studless tire for a passenger vehicle which has both good braking force and high handling stability on ice or snow. The studless tire for a passenger vehicle comprises a tread having a total sulfur content of 0.7% by mass or less and having a crosslink density of 2.0×10?5 mol/cm3 or higher.
    Type: Application
    Filed: June 15, 2009
    Publication date: March 4, 2010
    Inventors: Takayuki Hattori, Ryoji Kojima, Naohiko Kikuchi
  • Patent number: 7659336
    Abstract: A blend of two different compounds may be applied together to form a nucleating agent additive composition. This additive composition is useful as an additive in thermoplastics, polyolefins and/or polymer resins. A blend of a bicyclo[2.2.1]heptane dicarboxylate salt and a dicarboxylate calcium metal salt provide useful and beneficial physical property effects in molded polymeric articles in terms of shrinkage and crystallization temperature of polymer resin compositions.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: February 9, 2010
    Assignee: Milliken & Company
    Inventors: Weihua Sonya Wolters, Rob Hanssen, Thaneerpandal K. Palanisami, Darin L. Dotson
  • Patent number: 7652092
    Abstract: The present invention relates to articles made from plasticized thermoplastic polyolefin compositions comprising a thermoplastic polyolefin, a nucleating agent, and a non-functionalized hydrocarbon plasticizer.
    Type: Grant
    Filed: April 19, 2006
    Date of Patent: January 26, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mun Fu Tse, Chon-Yie Lin, Bryan R. Chapman, Bruce R. Lundmark
  • Publication number: 20090278284
    Abstract: A dip-forming composition is provided, which can give a dip-formed article that exhibits good softness of touch and comfortable fittingness, an excellent tensile strength and a high flexural fatigue resistance, and which is less likely to color even when worn and subjected to working for a long time period. The above problem is solved by the dip-forming composition which is obtained by converting an organic peroxide, which is solid at 30° C. under normal pressure, to an aqueous dispersion in the presence of a surfactant and a polymeric protective colloid, adding the dispersion to a conjugated diene rubber latex, and aging the mixture. The organic peroxide is preferably dibenzoyl peroxide or dilauroyl peroxide.
    Type: Application
    Filed: July 16, 2009
    Publication date: November 12, 2009
    Inventor: Kazumi KODAMA
  • Patent number: 7601770
    Abstract: A multi-functional admixture for concrete, having improved fluidity for providing hardened materials with improved early strength, smaller shrinkage rate, improved resistance against freezing and thawing action and slower carbonation speed, contains a specified kind of graft copolymer and/or its salt, a specified kind of (poly)alkyleneglycol monoalkyl ether and a specified kind of organic phosphate at specified ratios.
    Type: Grant
    Filed: February 24, 2004
    Date of Patent: October 13, 2009
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Kazumasa Inoue, Toshio Yonezawa, Kenrou Mitsui, Masarou Kojima, Mitsuo Kinoshita, Junji Inagaki, Shinji Tamaki, Toyoji Miura
  • Patent number: 7589138
    Abstract: A process for the preparation of a molded article formed of an isotactic ethylene propylene copolymer comprising providing an isotactic ethylene-propylene copolymer having an ethylene content of no more than 5 weight percent produced by the copolymerization of ethylene and propylene in the presence of an isospecific metallocene catalyst; heating the copolymer to a molten state; incorporating a nucleating agent into copolymer in an amount effective to provide a uniform shrinkage of the molded article at 48 hours molding of the at least 85% as determined by the differential in transverse and longitudinal shrinkage at the 48 hour mark; extruding the molten copolymer into a mold cavity; cooling the copolymer within the confines of the mold cavity to solidify the copolymer and form the molded article which is then retrieved from the mold cavity.
    Type: Grant
    Filed: December 5, 2006
    Date of Patent: September 15, 2009
    Assignee: Fina Technology, Inc.
    Inventor: Frank Li
  • Publication number: 20090103239
    Abstract: A dielectric fluid that provides improved resistance to device failure in capacitors comprising combinations of certain anthraquinone compounds and scavengers. Capacitors including the dielectric fluid can have a higher discharge inception voltage and can have increased failure threshold voltages in comparison to capacitors made without the combination. Therefore, these capacitors are more resistant to failures.
    Type: Application
    Filed: October 17, 2008
    Publication date: April 23, 2009
    Inventors: Clay Lynwood Fellers, Marco James Mason, Alan Paul Yerges, Lisa Carol Sletson, Gary Arden Gauger
  • Publication number: 20090087635
    Abstract: An object of the invention is to yield a highly transparent cured article wherein bubbles are less generated when a catalyst and others are added to a curable composition that contains an organic polymer having a silicon-containing group which can be crosslinked by the formation of a siloxane bond and then the resultant mixture is stirred. Another object thereof is to provide a cured article which is small in surface stickiness, slightly gets dirty over a long term, and has a practical adhesiveness. These objects are attained by a curable composition which comprises (A) an organic polymer having a silicon-containing group that can be crosslinked by the formation of a siloxane bond, (B) a bivalent tin carboxylate and (C) an amine compound having no reactive silicon group, and which turns transparent when cured; or a transparent cured article obtained by curing the composition.
    Type: Application
    Filed: April 12, 2006
    Publication date: April 2, 2009
    Applicant: KANEKA CORPORATION
    Inventor: Ayako Yano
  • Publication number: 20090082496
    Abstract: A polymeric composition suitable for manufacturing heat sealable films or sheets comprising, polyethylene terephthalate (PET) to the extent of about 80% to 95% by mass of the total composition; a polymer additive for lowering the melting point of the composition selected from Polyethylene Naphthalate (PEN), Polytrimethylene Naphthalate (PTN), in-situ formed Polyethylene Naphthalate (PEN) and in situ formed Polytrimethylene Naphthalate (PTN) to the extent of about 20% to 5% by mass of the total composition; a nucleating agent to the extent of about 200 to 1500 ppm by mass of the composition; a polycondensation catalyst to the extent of about 30 to 300 ppm by mass of the composition; a clear fast reheat (CFRH) additive to the extent of about 10 to 30 ppm by mass of the composition; a color toner to the extent of about 0.75 to 25 ppm by mass of the composition; and a heat stabilizer to the extent of about 20 to 55 ppm by mass of the composition.
    Type: Application
    Filed: September 19, 2008
    Publication date: March 26, 2009
    Inventors: Kulkarni Sanjay Tammaji, Palaniandavar Santhana Gopala Krishnan, Dilly Raj Balasundaram
  • Patent number: 7491762
    Abstract: Compositions comprising hexahydrophthalate (HHPA) metal salts may be useful as nucleating agents in polyolefins. Masterbatch compositions containing such salts and silica and/or hydrotalcite are particularly useful in reducing haze and improving properties of manufactured polyolefin articles or film. Such compositions may be dispersed effectively and efficiently into resin during manufacturing operations in the form of a masterbatch, thereby providing excellent polymer crystallization temperatures, improved polymer physical properties, improved dimensional stability, and improved transparency.
    Type: Grant
    Filed: July 3, 2006
    Date of Patent: February 17, 2009
    Assignee: Milliken & Company
    Inventors: Weihua Sonya Wolters, Kemper David Lake, Jr.
  • Publication number: 20090032773
    Abstract: The present invention provides polymeric compositions comprising an hydrogenated anthraquinone derivative and/or its enol/enolate tautomer. Methods of scavenging oxygen and preventing transmission of oxygen into a package using said compositions are also provided.
    Type: Application
    Filed: June 28, 2005
    Publication date: February 5, 2009
    Inventors: Mark Andrew Horsham, Andrew David Scully, James Keith Gerard Murphy, Ross Anthony Santangelo, Michael McNally
  • Publication number: 20090035502
    Abstract: A polymeric composition suitable for manufacturing pasteurizable containers comprising, polyethylene terephthalate (PET) in the ratio of about 80 to about 95 mass % by mass of the total composition; polyethylene naphthalate (PEN) in the ratio of about 20 to about 5 mass % by mass of the total composition; tungsten trioxide in the range of 10 to 100 ppm by mass of the composition and particle size of 2 to 20 microns; and optionally a nucleating agent and a polycondensation catalyst.
    Type: Application
    Filed: July 28, 2008
    Publication date: February 5, 2009
    Inventors: Kulkarni Sanjay Tammaji, Palaniandavar Santhana Krishnan, Dillyraj Balasundaram
  • Publication number: 20090029098
    Abstract: Slit films and processes of forming the same are generally described herein. In one embodiment, the slit films include an impact copolymer (ICP) formed of polypropylene and less than about 8 wt. % total ethylene, wherein the slit film exhibits less shrinkage and higher tenacity than a slit film formed from an ICP having greater than 10 wt. % ethylene. In one embodiment, the slit films include an impact copolymer including propylene and ethylene, wherein the slit film is absent another polymer.
    Type: Application
    Filed: July 18, 2008
    Publication date: January 29, 2009
    Applicant: Fina Technology, Inc.
    Inventors: John Ashbaugh, William R. Wheat
  • Patent number: 7439297
    Abstract: A composition comprising: A) 50-99.9% by weight of at least a copolymer (1) of ethylene (E) with chlorotrifluoroethylene (CTFE) wherein CTFE is comprised between 53 and 70% by moles, having a crystallinity in the range 5-45%; B) 0.1-50% by weight of a fine powder of a nucleating agent, having an average particle size lower than 50 micron and a melting temperature higher than 300° C.
    Type: Grant
    Filed: September 24, 2004
    Date of Patent: October 21, 2008
    Assignee: Solvay Solexis S.p.A.
    Inventors: Julio A. Abusleme, Claudia Manzoni
  • Publication number: 20080227900
    Abstract: Disclosed is a method for improving the barrier properties of polyethylene films. The method comprises mixing a substantially linear, high density polyethylene with a nucleating agent and converting the mixture into a film. The film made by the method of the invention has at least a 15% improvement on the water vapor barrier property and/or in the oxygen barrier property compared with the control film made from the same substantially linear, high density polyethylene but does not contain the nucleating agent.
    Type: Application
    Filed: March 14, 2007
    Publication date: September 18, 2008
    Inventors: Jeffrey S. Borke, Douglas C. McFaddin, Stephen M. Imfeld
  • Publication number: 20080214704
    Abstract: The present invention relates to a polymer composition, comprising (i) a polypropylene-based matrix which comprises a polypropylene random copolymer prepared by copolymerization of propylene with an olefin comonomer, wherein the amount of olefin comonomer units is within the range of (0.2) wt % to (5) wt %, based on the weight of the polypropylene-based matrix, and (ii) an elastomeric copolymer of propylene and at least one olefin comonomer, the polymer composition having a storage modulus G1 at a loss modulus G?=5 kPa of G?(5 kPa)<(3100) Pa, measured at (220° C.).
    Type: Application
    Filed: May 11, 2006
    Publication date: September 4, 2008
    Inventors: Jarmo Harjuntausta, Carl-Gustaf Ek, Kauno Alastalo, Kenneth Lund
  • Publication number: 20080206468
    Abstract: A thermoplastic composition includes particular amounts of a poly(arylene ether), a hydrogenated block copolymer, a copolymer of ethylene and an alpha-olefin, a plasticizer, a white pigment, and an ultraviolet radiation stabilizer. The composition exhibits excellent light stability, and it is particularly useful for forming white or off-white cable insulation.
    Type: Application
    Filed: February 28, 2007
    Publication date: August 28, 2008
    Inventors: Steven Raymond Klei, James Edward Pickett, James Jun Xu
  • Publication number: 20080139718
    Abstract: Compositions comprising hexahydrophthalate (HHPA) metal salts may be useful as nucleating agents in polyolefins. Masterbatch compositions containing such salts and with additives may be useful in reducing haze and improving properties of manufactured polyolefin articles or film.
    Type: Application
    Filed: December 11, 2006
    Publication date: June 12, 2008
    Inventors: Wouter Reyntjens, Martin Horrocks, Diederik Goyvaerts, Rob Hanssen
  • Patent number: 7332536
    Abstract: Compounds and compositions comprising specific metal salts of hexahydrophthalic acid (HHPA) in order to provide highly desirable properties within thermoplastic articles are provided. The inventive HHPA derivatives are useful as nucleating and/or clarifying agents for such thermoplastics, are practical and easy to handle. Such compounds provide excellent crystallization temperatures, stiffness, and acid scavenger compatibility within target polyolefins. Also, such compounds exhibit very low hygroscopicity and therefore excellent shelf stability as powdered or granular formulations. Thermoplastic additive compositions and methods of producing polymers with such compounds are also contemplated within this invention.
    Type: Grant
    Filed: May 28, 2004
    Date of Patent: February 19, 2008
    Assignee: Milliken & Company
    Inventors: Darin L. Dotson, X. Edward Zhao
  • Patent number: 7323508
    Abstract: The invention relates to carbonated alkaline earth metal carboxylates that are neutral, meaning they have a base value of less than 10 mg KOH/g, and that are derived from a mixture of, preferably branched, optionally cyclic, C4-C40 alk(en)yl carboxylic acids and C6-C30 alkaryl or aralkyl carboxylic acids. Also a process to make such products is claimed, as well as the use of the products to stabilize PVC.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: January 29, 2008
    Assignee: Akzo Nobel N.V.
    Inventors: Jack James Angus Orchison, Malcolm Thomas John Mellor
  • Publication number: 20070213439
    Abstract: A blend of two different compounds may be applied together to form a nucleating agent additive composition. This additive composition is useful as an additive in thermoplastics, polyolefins and/or polymer resins. A blend of a bicyclo[2.2.1]heptane dicarboxylate salt and a dicarboxylate calcium metal salt provide useful and beneficial physical property effects in molded polymeric articles in terms of shrinkage and crystallization temperature of polymer resin compositions.
    Type: Application
    Filed: September 29, 2006
    Publication date: September 13, 2007
    Inventors: Weihua Sonya Wolters, Rob Hanssen, Thaneerpandal K. Palanisami, Darin L. Dotson
  • Patent number: 7144939
    Abstract: The use of organic based nucleating agents to induce certain specific polymer orientations into the molded polypropylene articles such that the resultant part has improved stiffness-impact properties without sacrificing other attributes of the polypropylene is provided. Such results have been obtained through the utilization of low amount of organic nucleating compounds, including, without limitation, specific metal salts of hexahydrophthalic acid (hereinafter HHPA). Furthermore, such nucleating compounds have been found to impart, again in such low added amounts, heretofore unforeseen levels of b-axis crystalline orientation which translates into improved physical properties as well.
    Type: Grant
    Filed: July 29, 2003
    Date of Patent: December 5, 2006
    Assignee: Milliken & Company
    Inventors: Darin L. Dotson, Brian M. Burkhart
  • Patent number: 7129323
    Abstract: Specific methods of inducing high nucleation rates in thermoplastics, such as polyolefins, and particularly, though not necessarily, polypropylenes, through the introduction of two different compounds that are substantially soluble within the target molten thermoplastic resin (such as, as one non-limiting example, an added compound including at least one acid group and an added organic salt) are provided. Such introduced components react to form a nucleating agent in situ within such a target molten thermoplastic resin which is then allowed to cool. Preferably, one compound is an acid, preferably bicyclic (i.e., two cyclic systems sharing at least three carbon atoms) or monocycloaliphatic (i.e., a single, saturated ring system) in nature, such as, without limitation, bicyclo[2.2.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: October 31, 2006
    Assignee: Milliken & Company
    Inventors: Darin L. Dotson, Nathan A. Mehl, Brian M. Burkhart, Jiannong Xu
  • Patent number: 7070865
    Abstract: A coating composition for the linerboard of corrugated paperboard provides water and grease resistance but is water vapor permeable, and thus permits a different mode of manufacture of corrugated paperboard when aqueous adhesives are employed in the assembly of the linerboards and corrugated medium; in particular the linerboards may be coated with the coating composition prior to assembly of the corrugated paperboard because the water vapor permeable coating permits escape of the water of the aqueous adhesive, during drying of the assembled components of the corrugated paperboard; the coating composition employs a styrene-acrylate copolymer and a C14-C18 fatty acid complex of a metal ion having an oxidation state of at least 3, such as chromium.
    Type: Grant
    Filed: January 27, 2003
    Date of Patent: July 4, 2006
    Assignee: Le Groupe Recherche I.D. Inc.
    Inventor: Serge Berube
  • Patent number: 6835328
    Abstract: A metal carbonate/carboxylate microemulsion imparting static and dynamic thermal stability to a halogen-containing polymer is provided which comprises (a) a metal carbonate/carboxylate obtained from the reaction of an oxide and/or hydroxide of a metal selected from the group consisting of sodium, potassium, calcium, magnesium, zinc and mixtures thereof and an aliphatic acid in which the aliphatic moiety contains up to about 30 carbon atoms and carbon dioxide in an oil; b) one or more non-phenolic compounds having about two or about three hydroxyl groups; and, c) one or more polyols, alcohol ethoxylates and/or alcohol propoxylates having from about 6 to about 24 carbon atoms in the alcohol and/or 0 to 3 ethylene oxide units and/or 0 to 3 propylene oxide units.
    Type: Grant
    Filed: September 24, 2003
    Date of Patent: December 28, 2004
    Assignee: Crompton Corporation
    Inventors: Julius Fakinlede, Michael H. Fisch, Ulrich Stewen, Radu Bacaloglu, Shah Mukund, Ilze Bacaloglu, Wahib I. Farahat
  • Patent number: 6794433
    Abstract: Compounds and compositions comprising specific metal salts of hexahydrophthalic acid (HHPA) in order to provide highly desirable properties within thermoplastic articles are provided. The inventive HHPA derivatives are useful as nucleating and/or clarifying agents for such thermoplastics, are practical and easy to handle. Such compounds provide excellent crystallization temperatures, stiffness, and acid scavenger compatibility within target polyolefins. Also, such compounds exhibit very low hygroscopicity and therefore excellent shelf stability as powdered or granular formulations. Thermoplastic additive compositions and methods of producing polymers with such compounds are also contemplated within this invention.
    Type: Grant
    Filed: December 28, 2002
    Date of Patent: September 21, 2004
    Assignee: Milliken & Company
    Inventors: Darin L. Dotson, X. Edward Zhao
  • Patent number: 6787067
    Abstract: The present invention provides a multi-component granular additive for polyolefins which has a strength and a function which enable the additive to be dust-free and be of components-in-granule type. It comprises 10 parts by mass of a nucleating agent comprising an alkali metal salt or hydroxyaluminum salt of an aromatic monocarboxlylic acid or comprising an alkali metal salt or hydroxyaluminum salt of an acid aromatic phosphoric ester compound, 1 to 50 parts by mass of a phenolic antioxidant, 5 to 50 parts by mass of polyproylene, and 0 to 500 parts by mass of one or more optional additive components other than the nucleating agent and the phenolic antioxidant.
    Type: Grant
    Filed: August 16, 2002
    Date of Patent: September 7, 2004
    Assignee: Asahi Denka Kogyo K.K.
    Inventors: Toshinori Yukino, Takashi Takeuchi, Naoko Tanji, Etsuo Tobita
  • Publication number: 20030236334
    Abstract: An extrudable polypropylene blend combined with resins in precise amounts so that the resultant extruded film is easier to glue and is useable with hot melt adhesives. Mixtures of polypropylene and low density polyethylene are normally considered incompatible, but the contemplated blends which include 10-30% low-density polyethylene mixed with polypropylene give resin combinations runnable on a coater extruder and they produce a film having the advantages of polypropylene but which are no more difficult to glue than a film of low-density polyethylene.
    Type: Application
    Filed: May 1, 2003
    Publication date: December 25, 2003
    Inventors: Steven J. Gatewood, William J. Culhane
  • Patent number: 6653381
    Abstract: Novel compounds derived from traditional semi- drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10 ° C. and cure to above ambient glass transition (Tg polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: November 25, 2003
    Assignee: University of Southern Mississippi
    Inventors: Shelby Freland Thames, Kamlesh Gopichand Panjnani, Rajan Hariharan, Zhiyu Wang
  • Publication number: 20030216499
    Abstract: Disclosed is a polypropylene resin composition comprising (A) 100 parts by weight of polypropylene resin and the following components (B) to (D):
    Type: Application
    Filed: February 11, 2003
    Publication date: November 20, 2003
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventor: Yoshiaki Oobayashi
  • Patent number: 6585819
    Abstract: Certain thermoplastic additives (combinations of clarifying and nucleating compounds) that induce simultaneously low clarity and high nucleation efficacy are provided. Such additives include combinations of certain bicyclic salts (which by themselves induce very high nucleation efficacy) and thermoplastic clarifying agents, including certain dibenzylidene sorbitol acetals and derivatives (hereinafter collectively referred to as “DBSs”)(which alone provide very low haze measurements and thus highly desirable clarity characteristics). In comparison, other types of standard thermoplastic nucleators, such as sodium benzoate and sodium 2,2′-methylene-bis-(4,6-di-tert-butylphenyl) phosphate provide relatively high peak crystallization temperatures, but do not combine synergistically with clarifiers, such as DBSs, to provide the same results as for the inventive combination of bicyclic salts and DBSs.
    Type: Grant
    Filed: August 11, 2001
    Date of Patent: July 1, 2003
    Assignee: Milliken & Company
    Inventor: Xiaodong Edward Zhao
  • Patent number: 6583206
    Abstract: Compounds of and compositions comprising specific salts of saturated [2.2.2] dicarboxylate in order to provide highly desirable properties within thermoplastic (e.g., polyolefin) articles are provided. The inventive salts and derivatives thereof are useful as nucleating and/or clarifying agents for such thermoplastics, are easy to produce and handle, and relatively inexpensive to manufacture. Such compounds induce high peak crystallization and improved stiffness within thermoplastics. Also, thermoplastic compositions comprising such novel nucleating agents exhibit improved heat distortion properties and clarity levels in comparison with the closest unsaturated salt nucleating agents. Thermoplastic additive compositions and methods of producing thermoplastics with such compounds are also contemplated within this invention.
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: June 24, 2003
    Assignee: Milliken & Company
    Inventor: Xiaodong Edward Zhao
  • Publication number: 20030096895
    Abstract: Bicyclic nucleator compounds that provide highly versatile nucleation benefits for different polyolefins are provided. Such nucleator compounds provide very high peak crystallization temperatures and significantly reduced crystallization cycle time for certain thermoplastic formulations with or without the presence of other calcium stearate and/or peroxide components within the same type of formulation. Furthermore, such inventive nucleator compounds exhibits very little if any fugitivity from such thermoplastic formulations thereby providing excellent processing characteristics as well as excellent nucleation capabilities for a variety of different thermoplastic resins, independent of the presence of different, potentially necessary, additives (such as calcium stearate). Thermoplastic compositions as well as thermoplastic additive packages comprising such inventive nucleator compounds are also contemplated within this invention.
    Type: Application
    Filed: November 5, 2002
    Publication date: May 22, 2003
    Inventors: Xiaodong Edward Zhao, Darin L. Dotson
  • Patent number: 6562890
    Abstract: Compositions comprising specific disodium hexahydrophthalate(HHPA) salts in combination with acid scavengers (such as organic calcium salts or dihydrotalcite complexes) that provide highly desirable and effective nucleating properties within polymer articles (such as polyolefins) are provided. Surprisingly, such a combination of HHPA salt and acid scavenger provides high crystallization temperatures, low haze, and/or high flexural modulus to the finished polymer product. Other sodium salt polymer nucleators (such as sodium benzoate) deleteriously react with calcium organic salt acid scavengers such that characteristically high crystallization temperatures are drastically reduced when in combination with calcium salts (such as calcium stearate). Also, sodium benzoate when combined with dihydrotalcite acid scavengers produce extremely high haze levels in the finished target polymer article, whereas the inventive compositions surprisingly reduce haze.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: May 13, 2003
    Assignee: Milliken & Company
    Inventor: Darinl L. Dotson
  • Publication number: 20030083416
    Abstract: A thermoplastic moulding composition that contains an aliphatic thermoplastic polyurethane (TPU) resin is disclosed. The TPU is the product of a reaction of A) a diisocyanate reactant that contains predominantly hexamethylene diisocyanate, and B) a polyol reactant that contains polytetramethylene glycol and C) a chain extending reactant that contains primarily 1,6-hexanediol. The TPU that is further characterized in the equivalence ratio of A to B and NCO index exhibits improved properties.
    Type: Application
    Filed: September 10, 2002
    Publication date: May 1, 2003
    Inventors: Wolfgang Kaufhold, Henricus Peerlings, Hans-Georg Hoppe
  • Patent number: 6534574
    Abstract: Compounds and compositions comprising specific metal salts of bicyclo[2.2.1 ]heptane dicarboxylate salts in order to provide highly desirable properties within polyolefin articles are provided. The inventive salts and derivatives thereof are useful as nucleating and/or clarifying agents for such polyolefin, provide excellent crystallization temperatures, stiffness, and calcium stearate compatibility within target polyolefin. Also, such compounds exhibit very low hygroscopicity and therefore excellent shelf stability as powdered or granular formulations. Polyolefin additive compositions and methods of producing polyolefin with such compounds are also contemplated within this invention.
    Type: Grant
    Filed: November 27, 2001
    Date of Patent: March 18, 2003
    Assignee: Milliken & Company
    Inventors: Xiaodong Edward Zhao, Darin L. Dotson, Brian G. Morin, Brian M. Burkhart, Martin E. Cowan, Jeffrey R. Jones