At Least One Solid Polymer Derived From Ethylenic Reactants Only Patents (Class 524/40)
  • Patent number: 10829620
    Abstract: A resin composition contains cellulose acylate (A), a polyester resin (B), at least one compound (C) selected from the group consisting of cardanol compounds and ester compounds having a molecular weight of about 250 or more and about 2000 less, and a water-absorbing compound (D).
    Type: Grant
    Filed: August 19, 2018
    Date of Patent: November 10, 2020
    Assignee: Eastman Chemical Company
    Inventors: Kana Miyazaki, Ryo Tanaka, Masahiro Moriyama, Kenji Yao
  • Patent number: 10822474
    Abstract: Provided is a resin composition containing: a cellulose acetate in which the weight average polymerization degree is 120-330 and the degree of substitution of an acetyl group is 2.10-2.60; a (meth)acrylic polymer having a weight average molecular weight of 1000-30000; and a plasticizer.
    Type: Grant
    Filed: January 24, 2019
    Date of Patent: November 3, 2020
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Masahiro Moriyama, Kenji Yao
  • Patent number: 10689506
    Abstract: A resin composition contains cellulose acetate (A) having a degree of substitution of about 2.1 or more and about 2.6 or less, a plasticizer (B), a polyhydroxyalkanoate (C), and an olefin-(meth)acrylate copolymer (D).
    Type: Grant
    Filed: April 11, 2018
    Date of Patent: June 23, 2020
    Assignee: EASTMAN CHEMICAL COMPANY
    Inventors: Masahiro Moriyama, Kenji Yao
  • Patent number: 10308790
    Abstract: A resin composition includes: a cellulose acetate having a weight-average molecular weight of 30,000 to 90,000 and a substitution degree of 2.1 to 2.6; and a polyhydroxyalkanoate.
    Type: Grant
    Filed: July 5, 2017
    Date of Patent: June 4, 2019
    Assignee: FUJI XEROX CO., LTD.
    Inventor: Kenji Yao
  • Patent number: 10246581
    Abstract: The present disclosure is directed to rubber compositions comprising a butyl rubber or a halogenated butyl rubber, at least one filler, and a whey protein component. The whey protein component is present in an amount sufficient to provide about 0.1 to about 10 phr whey protein in the rubber composition. The present disclosure is also directed to methods of preparing such rubber compositions and to a tire innerliner or innertube containing the rubber compositions disclosed herein.
    Type: Grant
    Filed: June 11, 2015
    Date of Patent: April 2, 2019
    Assignee: Bridgestone Americas Tire Operations, LLC
    Inventors: Benjamin C. Galizio, Amy M. Randall, Melissa M. Clark
  • Patent number: 10233319
    Abstract: The present disclosure is directed to rubber compositions comprising a conjugated diene rubber, a reinforcing silica filler, and a whey protein component. The whey protein component is in an amount sufficient to provide about 0.1 to about 10 phr whey protein. The present disclosure is also directed to methods of preparing such rubber compositions and to tire components containing the rubber compositions disclosed herein.
    Type: Grant
    Filed: June 11, 2015
    Date of Patent: March 19, 2019
    Assignee: Bridgestone Americas Tire Operations, LLC
    Inventors: Benjamin C. Galizio, Amy M. Randall, Melissa M. Clark
  • Patent number: 9259959
    Abstract: A method for manufacturing panels of the type which is at least composed of a substrate and a top layer provided on the substrate, the top layer includes at least two material layers, amongst which a print, the method may involve applying the two material layers, such that the print is performed directly on the substrate and the print forms at least a portion of a printed decor. At least one of the two material layers may include a mixture having at least a thermally curing component and a radiation-curing component.
    Type: Grant
    Filed: September 15, 2010
    Date of Patent: February 16, 2016
    Assignee: FLOORING INDUSTRIES LIMITED, SARL
    Inventors: Benjamin Clement, Christophe Maesen
  • Patent number: 9018283
    Abstract: A resin composition containing: (A) a cellulose ester, (B) a styrene-based resin, and (C) a titanium dioxide, and not containing a compatibilizer between the component (A) and the component (B), in which the content of the component (A) is within a range of 95 to 50% by mass, the content of the component (B) is within a range of 5 to 50% by mass, and the content of the component (C) relative to 100 parts by mass of the sum of the amount of component (A) and the amount of component (B) is within a range of 0.1 to 10 parts by mass.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: April 28, 2015
    Assignees: Daicel Polymer Ltd., Fuji Xerox Co., Ltd.
    Inventors: Shinichiro Imanishi, Hideaki Sakamoto, Masayuki Okoshi, Kenji Yao
  • Patent number: 8993645
    Abstract: Provided by the invention is a compound containing an imido group that is obtained by partial hydrolysis of a polyimide molded article, in which the compound has an absorption peak derived from an imido group at wave number of 1375 cm?1, an absorption peak derived from an amide group at wave number of 1600 cm?1, and an absorption peak derived from a carboxyl group at wave number of 1413 cm?1 in the IR spectrum chart obtained by IR spectroscopic measurement.
    Type: Grant
    Filed: October 31, 2012
    Date of Patent: March 31, 2015
    Assignee: Nakata Coating Co., Ltd.
    Inventors: Takemi Matsuno, Katsuji Kitagawa, Misao Hanazono
  • Publication number: 20150010710
    Abstract: Described is a high solids coating composition having exceptional rheological properties and appearances comprising (a) a thermosetting binder, (b) from about 0.1 to about 10 wt. % based on binder solids of solid polyurea particles prepared by the reaction of a mixture of a polyisocyanate and an amino reactant comprising a primary or secondary monoamine that optionally has a hydroxyl or ether group or both, and (c) from about 5 to about 20 wt. % based on binder solids of a cellulose mixed ester having a number average molecular weight of from about 1000 to about 5600, a polydispersity of from about 1.2 to about 3.5, and a total degree of substitution per anhydroglucose unit of from about 3.08 to about 3.5.
    Type: Application
    Filed: November 16, 2012
    Publication date: January 8, 2015
    Inventors: Timothy S. December, John G. Partyka, Werner-Alfons Jung, Alexandra Steffens
  • Publication number: 20150004424
    Abstract: A coating formed on a substrate is provided which coating comprises (a) an organic NIR-transparent pigment and/or an inorganic NIR-reflective pigment; (b) a dye having a transmittance of at least 75% in the range of from 700 to 2500 nm; and (c) optionally an effect pigment; wherein said coating exhibits a total solar reflectance (TSR) of (i) ?40%, if 60<L*<100, or (ii) ?30%, if 30<L*?60, or (iii) ?20%, if 0<L*?30, wherein L* is the lightness. The coating is suitable for an exterior-use coating like an industrial coating or a coating for vehicles, especially an automotive finish, having improved jetness.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 1, 2015
    Applicant: BASF SE
    Inventors: Juliane Kruesemann, Thomas Frey, Rainer Henning, Annegret Pietsch, Claudia Sierakowski, Tom Landuydt
  • Publication number: 20140335289
    Abstract: A method for producing an optical film of the present invention includes: (1) a step for obtaining a (meth)acrylic resin by copolymerizing methyl methacrylate and a copolymerizable monomer containing an acryloyl morpholine in the presence of a polymerization initiator and a chain transfer agent; and (2) a step for obtaining an optical film by melt extruding a resin composition that contains the thus-obtained (meth)acrylic resin and a cellulose ester resin at a (meth)acrylic resin:cellulose ester resin ratio of from 95:5 to 30:70. The (meth)acrylic resin obtained in step (1) is characterized in that: (a) the weight average molecular weight (Mw) thereof is from 2.0×104 to 5.0×105; (b) the total amount of the remaining methyl methacrylate and the remaining copolymerizable monomer is 0.05-1% by mass; (c) the amount of the remaining polymerization initiator is 0.01-0.5% by mass; and (d) the amount of the remaining chain transfer agent is 0.01-0.5% by mass.
    Type: Application
    Filed: November 30, 2012
    Publication date: November 13, 2014
    Inventors: Masataka Takimoto, Kenzo Kasahara, Akira Shimizu, Mutsumi Kasahara
  • Publication number: 20140175855
    Abstract: Disclosed is a matte powder coating composition, and more specifically, a novel matte powder coating composition comprising a plurality of heterogeneous resins having different refractive indices, which can secure a coated film having excellent corrosion resistance and which embodies a matt effect on par with a liquid coating.
    Type: Application
    Filed: April 8, 2013
    Publication date: June 26, 2014
    Applicants: KIA MOTORS CORPORATION, HYUNDAI MOTOR COMPANY
    Inventor: Hwan-Ho Kim
  • Publication number: 20140142223
    Abstract: The problem of the present invention is to provide a phase difference film, by utilizing a cellulose ester having an acyl group substitution degree of less than 2.0 and improved compatibility, having high phase difference property despite its small film thickness and imparting high contrast and optical transmittance to a liquid crystal display device. A polarizing plate and a liquid crystal display device provided with the phase difference film are also provided. The phase difference film of the invention contains a cellulose ester which is obtained by substituting an acyl group having at least two carbon atoms for a hydroxy group in a glucose unit composing a cellulose, the film satisfies specific expressions when DS2, DS3 and DS6 are degrees of substitution of the acyl groups for the hydroxy groups at a 2C, 3C and 6C positions, respectively, of the glucose unit.
    Type: Application
    Filed: May 28, 2012
    Publication date: May 22, 2014
    Applicant: KONICA MINOLTA, INC.
    Inventor: Kazuki Akasaka
  • Publication number: 20140113995
    Abstract: Included are polymer compositions including a polymer and about 0.1% to 25% by weight of a cellulose additive. The polymer composition is in the form of a film and the cellulose additive may be a cellulose ester such as cellulose acetate butyrate.
    Type: Application
    Filed: October 5, 2011
    Publication date: April 24, 2014
    Applicant: INVISTA NORTH AMERICA S.a.r.l.
    Inventors: Ronald D. Bing-Wo, Robert Van De Kerkhof
  • Publication number: 20130150495
    Abstract: A process to produce a cellulose ester concentrate is provided. The process comprising mixing at least one cellulose ester with one or more carrier elastomers to produce the cellulose ester concentrate, wherein at least a portion of the mixing occurs at a temperature that exceeds the Tg of the cellulose ester, wherein at least a portion of the mixing operates at a shear rate of at least 50 s?1.
    Type: Application
    Filed: November 30, 2012
    Publication date: June 13, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130150498
    Abstract: A process for producing a tire component is provided. The process comprises blending an elastomeric composition containing at least one non-fibril cellulose ester, at least one primary elastomer, and one or more fillers, wherein the elastomeric composition exhibits a dynamic mechanical analysis (DMA) strain sweep modulus as measured at 5% strain and 30° C. of at least 1,450,000 Pa and a molded groove tear as measured according to ASTM D624 of at least 120 lbf/in.
    Type: Application
    Filed: November 30, 2012
    Publication date: June 13, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130150496
    Abstract: A process for producing a tire component is provided. The process comprises: (a) blending at least one cellulose ester, at least one non-nitrile primary elastomer, and at least 70 phr of one or more fillers to produce an elastomeric composition, wherein at least a portion of the blending occurs at a temperature exceeding the Tg of the cellulose ester, wherein the elastomeric composition exhibits a Mooney viscosity at 100° C. as measured according to ASTM D1646 of not more than 110 AU; and (b) forming the tire component with the elastomeric composition.
    Type: Application
    Filed: November 30, 2012
    Publication date: June 13, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130150493
    Abstract: A cellulose ester concentrate is provided comprising at least one non-nitrile carrier elastomer and at least one non-fibril cellulose ester, wherein said cellulose ester concentrate comprises at least 15 weight percent of said cellulose ester.
    Type: Application
    Filed: November 30, 2012
    Publication date: June 13, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130150491
    Abstract: An elastomeric composition is provided comprising at least one non-fibril cellulose ester, at least one non-nitrile primary elastomer, optionally a starch, and at least 70 parts per hundred rubber (phr) of one or more fillers, wherein the weight ratio of the cellulose ester to the starch is at least 3:1, wherein the cellulose ester is in the form of particles having an average diameter of not more than 10 ?m.
    Type: Application
    Filed: November 30, 2012
    Publication date: June 13, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130150494
    Abstract: A tire component is provided comprising an elastomeric composition containing at least one non-fibril cellulose ester, at least one non-nitrile primary elastomer, optionally a starch, and at least 70 parts per hundred rubber (phr) of one or more fillers, wherein the weight ratio of the cellulose ester to the starch is at least 3:1, and wherein the cellulose ester is in the form of particles having an average diameter of not more than 10 ?m.
    Type: Application
    Filed: November 30, 2012
    Publication date: June 13, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130150497
    Abstract: A process to produce an elastomeric composition is provided. The process comprises blending at least one cellulose ester, at least one non-nitrile primary elastomer, and at least 70 phr of one or more fillers to produce the elastomeric composition, wherein at least a portion of the blending occurs at a temperature exceeding the Tg of said cellulose ester, and wherein the elastomeric composition exhibits a Mooney viscosity at 100° C. as measured according to ASTM D1646 of not more than 110 AU.
    Type: Application
    Filed: November 30, 2012
    Publication date: June 13, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130150499
    Abstract: A process to produce an elastomeric composition is provided. The process comprises blending at least one cellulose ester, at least one primary elastomer, and one or more fillers to produce an uncured elastomeric composition, wherein the blending occurs at a temperature exceeding the Tg of the cellulose ester and curing the uncured elastomeric composition to produce a cured elastomeric composition, wherein the cured elastomeric composition exhibits a dynamic mechanical analysis (DMA) strain sweep modulus of at least 1,450,000 Pa and a molded groove tear as measured according to ASTM D624 of at least 120 lbf/in.
    Type: Application
    Filed: November 30, 2012
    Publication date: June 13, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130150492
    Abstract: A process to produce an elastomeric composition is provided. The process comprising: (a) mixing at least one cellulose ester with one or more carrier elastomers to form a cellulose ester concentrate; (b) blending the cellulose ester concentrate with at least one primary elastomer to produce the elastomeric composition, wherein at least a portion of the mixing of step (a) occurs at a temperature that is at least 10° C. greater than the temperature of the blending of step (b).
    Type: Application
    Filed: November 30, 2012
    Publication date: June 13, 2013
    Applicant: Eastman Chemical Company
    Inventor: Eastman Chemical Company
  • Publication number: 20130085213
    Abstract: To provide a resin composition which can suppress discoloration caused by heat history applied at the time of molding. A resin composition containing: (A) a cellulose ester, (B) a styrene-based resin, and (C) a titanium dioxide, and not containing a compatibilizer between the component (A) and the component (B), in which the content of the component (A) is within a range of 95 to 50% by mass, the content of the component (B) is within a range of 5 to 50% by mass, and the content of the component (C) relative to 100 parts by mass of the sum of the amount of component (A) and the amount of component (B) is within a range of 0.1 to 10 parts by mass.
    Type: Application
    Filed: September 28, 2012
    Publication date: April 4, 2013
    Applicants: FUJI XEROX CO., LTD., DAICEL POLYMER LTD.
    Inventors: DAICEL POLYMER LTD., FUJI XEROX CO., LTD.
  • Publication number: 20130041074
    Abstract: A composition for a removable top coating for protecting the exposed face of a temporary removable graphic is provided. A remover for the transferred graphic image is provided that completely dissolves the temporary removable graphic, but does not affect the commonly encountered substrates such as concrete, brick, wooden floors, asphalt surfaces, terrazzo and motor vehicle body surfaces, marine and aeronautical craft surfaces. A method for making, applying and removing the temporary removable graphic is provided.
    Type: Application
    Filed: October 2, 2012
    Publication date: February 14, 2013
    Applicant: CSD, L.L.C.
    Inventor: CSD, L.L.C.
  • Patent number: 8349921
    Abstract: The present invention relates to films made from mixed cellulose esters having low hydroxyl content and certain plasticizers. These films can exhibit +C plate, ?A plate, and biaxial Nz behavior, which make them particularly suitable for use in optical applications, such as in liquid crystal displays (LCD) as protective and compensator films.
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: January 8, 2013
    Assignee: Eastman Chemical Company
    Inventors: Bin Wang, Michael Eugene Donelson, Marcus David Shelby, James Collins Maine
  • Publication number: 20120149812
    Abstract: A composition for a removable top coating for protecting the exposed face of a temporary removable graphic is provided. A remover for the transferred graphic image is provided that completely dissolves the temporary removable graphic, but does not affect the commonly encountered substrates such as concrete, brick, wooden floors, asphalt surfaces, terrazzo and motor vehicle body surfaces, marine and aeronautical craft surfaces. A method for making, applying and removing the temporary removable graphic is provided.
    Type: Application
    Filed: December 19, 2011
    Publication date: June 14, 2012
    Inventors: Parvez AKHTAR, John FITZWATER, Norman J. GREENBERG
  • Publication number: 20120142826
    Abstract: The present disclosure relates generally to filled polyimides that can be used in films and articles comprising the films. The films are useful in coverlay applications and have advantageous optical properties. The present disclosure also relates to blends of polyimide precursor, polyacrylonitrile, and cellulosic polymer which can be used to obtain the filled polyimides.
    Type: Application
    Filed: December 7, 2010
    Publication date: June 7, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Salah Boussaad, Gloria T. Worrell
  • Publication number: 20120040147
    Abstract: An ink jet recording method for recording a non-water-based glitter ink on a recording medium, including forming an underlayer, in which a resin ink in which resin components are dispersed or dissolved in a dispersion medium is applied to at least a site of the recording medium on which the non-water-based glitter ink is recorded, thereby forming an underlayer, and recording a glitter ink, in which the non-water-based glitter ink is recorded on the underlayer.
    Type: Application
    Filed: August 9, 2011
    Publication date: February 16, 2012
    Inventors: Hidehiko Komatsu, Tetsuya Aoyama, Takashi Oyanagi, Kazuaki Tsukiana
  • Publication number: 20110319532
    Abstract: A cellulose ester composition is provided comprising at least one cellulose ester and at least one additive selected from the group consisting of a compatibilizer, and a plasticizer. Processes for producing the cellulose ester composition are also provided. In another embodiment, a cellulose ester/elastomer composition is provided comprising at least one elastomer, at least one cellulose ester; and at least one additive; wherein the additive is at least one selected from the group consisting of a compatibilizer and a plasticizer. Processes for producing the cellulose ester/elastomer composition is also provided as well as articles comprising the cellulose ester/elastomer composition.
    Type: Application
    Filed: June 28, 2011
    Publication date: December 29, 2011
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventors: Bradley James Helmer, Soumendra Kumar Basu, Matthew Davie Wood, Chris Stanley Dagenhart, Jos Simon De Wit, Carlo Antony Testa, Marcus David Shelby
  • Publication number: 20110319531
    Abstract: A cellulose ester composition is provided comprising at least one cellulose ester and at least one additive selected from the group consisting of a compatibilizer, and a plasticizer. Processes for producing the cellulose ester composition are also provided. In another embodiment, a cellulose ester/elastomer composition is provided comprising at least one elastomer, at least one cellulose ester; and at least one additive; wherein the additive is at least one selected from the group consisting of a compatibilizer and a plasticizer. Processes for producing the cellulose ester/elastomer composition is also provided as well as articles comprising the cellulose ester/elastomer composition.
    Type: Application
    Filed: June 28, 2011
    Publication date: December 29, 2011
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventors: Bradley James Helmer, Soumendra Kumar Basu, Matthew Davie Wood, Chris Stanley Dagenhart, Jos Simon De Wit, Carlo Antony Testa, Marcus David Shelby
  • Patent number: 7812071
    Abstract: A veneer composition that includes a mixture of at least one of an acrylic emulsion and one or more hard resins and also includes at least about 60% by volume of translucent, uniformly spherical, non-resin, absorbent beads of at least one of acrylic and polypropylene.
    Type: Grant
    Filed: November 5, 2007
    Date of Patent: October 12, 2010
    Inventor: Raymond Sandor
  • Patent number: 7790788
    Abstract: There is provided a method for producing a chemical mechanical polishing pad, the method comprising the steps of (1) producing a sheet-shaped polymer molded article and (2) irradiating the sheet-shaped polymer molded article with an electron beam within an irradiation dose of 10 to 400 kGy. A chemical mechanical polishing pad produced by the above method has advantages that it is excellent in removal rate and scratches and in-plane uniformity on a polished surface and that it shows a stable removal rate even when polishing a number of objects to be polished successively.
    Type: Grant
    Filed: October 17, 2008
    Date of Patent: September 7, 2010
    Assignee: JSR Corporation
    Inventors: Yukio Hosaka, Rikimaru Kuwabara
  • Patent number: 7754787
    Abstract: Curable film-forming compositions comprising a film-forming resin and an organic sol of particles are provided. The sol of particles may be prepared by providing a suspension of particles in an aqueous medium; adding a first organic liquid compatible with the aqueous medium to form an admixture; reacting the particles with a first and a second modifying compound; adding a second organic liquid compatible with the liquid portion of the admixture wherein the second organic liquid is different from the first organic liquid; and maintaining the admixture at a temperature and pressure and for a time sufficient to substantially remove the water and the first organic liquid. The film-forming resin comprises an active hydrogen-functional polymer having low functionality; i.e., a functional group equivalent weight greater than 380 g/equivalent, and a crosslinking agent, yet surprisingly offers outstanding mar and scratch resistance.
    Type: Grant
    Filed: August 30, 2007
    Date of Patent: July 13, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Steven V. Barancyk
  • Patent number: 7297732
    Abstract: The invention has for its primary object to provide a solid composition having excellent wet-surface writing properties and high safety. The object is accomplished by the provision of a solid composition characterized by its comprising a colorant, a gelation agent, a resin component and at least two kinds of solvents, each of the resins having the following attribute a) or b): a) the solvent has an HLB value (X) of X?6.5 or b) the solvent has an HLB value (X) and a solubility parameter value (Y) satisfying the relation of Y?18?X (on condition that 6.5<X, 0<Y).
    Type: Grant
    Filed: March 12, 2001
    Date of Patent: November 20, 2007
    Assignee: Sakura Color Products Corporation
    Inventors: Akiko Shirota, Hidetoshi Fukuo
  • Patent number: 7276546
    Abstract: The invention relates to methods of making carbohydrate and polyol esters suitable for use as plasticizers for polymer compositions. The invention also relates to plasticized polymer compositions comprising such carbohydrate and polyol esters. The invention also relates to articles prepared from such plasticized polymer compositions. The invention further relates to methods of using these compositions.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: October 2, 2007
    Assignee: Eastman Chemical Company
    Inventors: Charles M. Buchanan, Norma L. Buchanan, Kevin J. Edgar, Juanelle L. Lambert
  • Patent number: 6977275
    Abstract: The invention relates to methods of making carbohydrate and polyol esters suitable for use as plasticizers for polymer compositions. The invention also relates to plasticized polymer compositions comprising such carbohydrate and polyol esters. The invention also relates to articles prepared from such plasticized polymer compositions. The invention further relates to methods of using these compositions.
    Type: Grant
    Filed: January 10, 2003
    Date of Patent: December 20, 2005
    Assignee: Eastman Chemical Company
    Inventors: Charles M. Buchanan, Norma L. Buchanan, Kevin J. Edgar, Juanelle L. Lambert
  • Patent number: 6506824
    Abstract: Biodegradable thermoplastic compositions comprising a starch component, a cellulose ester or ether, a plasticizer for the starchy phase and of the cellulose and derivatives, and a compatibilizer agent selected from polymers compatible with the cellulose and or starchy component, grafted with aliphatic or polyhydroxilated chains; copolymers obtained from hydroxy acids and/or diamines with 2-24C and aliphatic or aromatic diisocyanates; copolymers obtained from aliphatic polyesters, polyureas and polyalkylene glycols and aliphatic or aromatic diisocyanates; copolymers obtained from polymers compatible with cellulose ester or ethers and/or the starchy component by grafting starch soluble polyols; polymer capable of complexing starch; starch compatible polyols.
    Type: Grant
    Filed: October 17, 1997
    Date of Patent: January 14, 2003
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Vittorio Bellotti, Roberto Lombi, Gabriele Perego
  • Publication number: 20020198292
    Abstract: Etherified vinyl alcohol polymers based on partially or completely hydrolyzed vinyl acetate homopolymers or copolymers, containing from 0.1 to 100 mol % of whose vinyl alcohol groups of the formula (I) —CH2-CHR—O—R1, R is H or CH3, and R1 in the etherified vinyl alcohol polymers is identical or different and is unsubstituted or substituted alkyl, aryl, or alkaryl radicals each having from 1 to 30 carbon atoms, the substituents selected from the group consisting of halogen, hydroxyl, amine, ammonium, carboxylic acid, carboxylic ester, carboxamide, ether, keto, sulfonic acid, phosphonate, nitrate, and polyoxyalkylene radicals having from 2 to 50 C2-8 oxyalkylene units are useful as thickeners in liquid-containing compositions, particularly hydraulically and non-hydraulically setting construction formulations such as cements, plasters, mortars, adhesives, and renders.
    Type: Application
    Filed: April 18, 2002
    Publication date: December 26, 2002
    Applicant: Wacker-Chemie GmbH
    Inventors: Bernd Kayser, Werner Bauer, Ulf Dietrich, Andreas Bacher, Marion Schmitz, Harald Zeh, Theo Mayer
  • Patent number: 6489406
    Abstract: The invention relates unsaturated polyester resins for the manufacture of subzero flexible, weather-resistant products. The liquid unsaturated polyester resin comprises a linear unsaturated polyester obtained by reacting 5-30 mol % of one or more ethylenically unsaturated dicarboxylic acids (A), 20-45 mol % of one or more other aliphatic or aromatic acids (B) and 40-60 mol % of two or more polyhydric alcohols and 30-60 wt % of one or more reactive monomers. The linear unsaturated polyesters have a cone and plate viscosity (I.C.I.) of 2 ps/125° C.-20 ps/125° C. and a molecular weight Mw of 20,000-100,000. The invention also relates to a process for the manufacture of such unsaturated polyester resins and to the use of them in applications wherein good adhesion to supporting material and flexibility at ambient and especially at low temperatures are needed.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: December 3, 2002
    Assignee: Ashland Inc.
    Inventors: Paul Mahbub, Karri Airola, Eija Valtonen
  • Patent number: 6225381
    Abstract: An inkjet printing coating compositions and recording sheets having printable coating compositions on substrates which are suitable for photographic quality prints by inkjet printing technology, such as thermal and piezo. The recording sheet which comprises a substrate and a dried coating composition on the substrate, which coating composition comprises either (i) a hydrophilic or amphiphilic polyether polyurethane plus one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers or (ii) cellulose acetate trimellitate plus optionally one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers; a quaternary ammonium compound; a metal salt chelating agent; and a microcrystalline filler drying agent.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: May 1, 2001
    Assignee: AlliedSignal Inc.
    Inventors: Jyoti Sharma, David James Gibboni, Elizabeth Joyce Lanigan
  • Patent number: 6218448
    Abstract: The invention pertains to mixtures or pastes comprising a cellulose ester, a binder resin, water, and optionally a plasticiser, an organic solvent, an emulsifier, and/or a thickener, wherein in that at least a portion of the binder resin is functionalized with an amino-functional acetal. The mixtures can be cured at ambient temperature. The mixtures or pastes can be used for, for example, varnishing wood, metal, synthetic material, paper, leather, glass, and plastic films, and in particular on surfaces where great value is placed on solventless coating compositions.
    Type: Grant
    Filed: March 26, 1999
    Date of Patent: April 17, 2001
    Assignee: Akzo Nobel N.V.
    Inventors: Paulus T. F. M. Kraaijevanger, Klaas J. H. Kruithof, Jörgen E. Raasing, Reinhold Heicht, Lutz Hoppe
  • Patent number: 6214907
    Abstract: A biologically degradable polymer mixture is proposed which consists essentially of starch and at least one hydrophobic polymer. The hydrophobic polymer is in this connection at least substantially biologically degradable and thermoplastically processable and the mixture with the starch comprising a polymer phase mediator or a macromolecular dispersing agent so that the starch is present in the mixture as disperse phase with the hydrophobic polymer as continuous phase, and the phase mediator or the dispersing agent is responsible for the molecular coupling of the two phases. As starch there is preferably used thermoplastic starch which has been prepared substantially with the exclusion of water by means of sorbitol or glycerol. The production of the biologically degradable polymer mixture is also carried out substantially with the exclusion of water.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: April 10, 2001
    Assignee: Bio-Tec Biologische Naturverpackungen GmbH & Co. KG
    Inventor: Ivan Tomka
  • Patent number: 6063842
    Abstract: The present invention relates to a thermal transfer ink layer composition, wherein polyvinylacetal resin and cellulose derivatives are used in a mixture for the binder in the thermal transfer ink layer composition of the sublimation thermal transfer ink ribbon, or the another type of a binder is mixed into the mixture of polyvinylacetal resin and cellulose derivatives and so used therein. As a result, the adhesion between the thermal transfer ink layer and substrate film, and the gradation property of printed images are improved as compared to the case in which the respective binders are used individually. More particularly, the present invention relates to the thermal transfer ink layer composition of the sublimation thermal transfer ink ribbon, which can yield high quality images by means of the aforementioned improvements.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: May 16, 2000
    Assignee: Hansol Paper Co., Ltd.
    Inventors: Oh-Seung Kwon, Jeong-Seok Seo, Yong-Cheol Shin, Tae-Woon Cha, Eun-Seong Kim
  • Patent number: 6046259
    Abstract: A stable aqueous dispersion containing cellulose ester, the dispersion being polymeric microparticles comprised of cellulose ester and a polymer formed from at least two different vinyl monomers of which at least one vinyl monomer is polyethylenically unsaturated. The dispersion of microparticles is formed by a high stress technique prior to polymerization of the vinyl monomers in the presence of the cellulose ester. Typically the dispersion also contains surfactant. A method of making the stable, cellulose ester-containing aqueous dispersion by (a) mixing together a cellulose ester, at least two vinyl monomers of which at least one vinyl monomer is polyethylenically unsaturated, surfactant, and water to form an emulsion; (b) particulating the emulsified mixture of (a) into microparticles by a high stress technique; and (c) copolymerizing the vinyl monomers in the cellulose ester-containing particulated emulsion of (b) to form a crosslinked polymer within the microparticles of the dispersion.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: April 4, 2000
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Suryya K. Das, Soner Kilic, Robyn E. McMillan
  • Patent number: 6020405
    Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of the above-described inks.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: February 1, 2000
    Assignee: Westvaco Corporation
    Inventors: Michael D. Matzinger, Robert P. Rodebaugh
  • Patent number: 6007610
    Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Also, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks. Furthermore, the disclosed phase change inks inhibit corrosion of metallic internal printer parts.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: December 28, 1999
    Assignee: Westvaco Corporation
    Inventors: Michael D. Matzinger, Robert P. Rodebaugh
  • Patent number: 6001904
    Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: December 14, 1999
    Assignee: Westvaco Corporation
    Inventors: Michael D. Matzinger, Robert P. Rodebaugh
  • Patent number: 5994530
    Abstract: The present invention provides certain carboxymethyl cellulose (CMC) esters of higher acids (e.g., CMC acetate propionate, CMC propionate, CMC acetate butyrate, and CMC butyrate)having specific use in aqueous dispersions useful in formulating waterborne coating compositions containing pigments, especially metallic pigments such as aluminum flakes and mica. The esters also have specific use as wetting agents and in high solids coatings.
    Type: Grant
    Filed: June 25, 1998
    Date of Patent: November 30, 1999
    Assignee: Eastman Chemical Corporation
    Inventors: Jessica Dee Posey-Dowty, Alan Kent Wilson, Larry Gerald Curtis, Paul Michael Swan, Kab Sik Seo