Group Iia Metal (be, Mg, Ca, Sr, Ba) Patents (Class 524/400)
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Patent number: 4761444Abstract: An elastomeric blend composition having improved tear properties and having a viscosity at 0.73 sec.sup.-1 and at 200.degree. C. of about 8.times.10.sup.3 to about 8.times.10.sup.5 poises, said composition formable into an elastomeric article, which comprises:(a) a neutralized sulfonated EPDM terpolymer having a viscosity at 0.73 sec.sup.-1 and at 200.degree. C. of about 5.times.10.sup.4 poises to about 5.times.10.sup.6 poises and about 10 to about 50 meq. sulfonate groups per 100 grams of said sulfonated EPDM terpolymer, said sulfonate groups being neutralized; and(b) about 2 to about 60 parts by weight of a fluorohydrocarbon elastomer per 100 parts of such sulfonated EPDM terpolymer.Type: GrantFiled: June 9, 1986Date of Patent: August 2, 1988Assignee: Exxon Research and Engineering CompanyInventors: Pawan K. Agarwal, William M. Petrik, Richard T. Garner
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Patent number: 4760099Abstract: A storage-stable premix composition for use in a foam-forming reaction with an organic polyisocyanate in the manufacture of a polyurethane or polyisocyanurate foam comprising(a) at least one polyol,(b) at least one halogenated organic blowing agent,(c) at least one amine catalyst, and(d) a stabilizing amount of at least one polyvalent metal-containing organometallic compound.Some organometallic compounds of the invention have a slight catalytic effect but do not have the pronounced activity of conventional urethane and isocyanurate catalysts such as dibutyltin dilaurate and stannous octoate.Type: GrantFiled: December 22, 1986Date of Patent: July 26, 1988Assignee: Sloss Industries CorporationInventors: John S. Canaday, Michael J. Skowronski, Michael E. Londrigan
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Patent number: 4758616Abstract: A thermoplastic polyester composition for a powdered paint which comprises:(a) a copolyester derived from a dicarboxylic acid component comprising 40 to less than 60 molar % of terephthalic acid and a diol component comprising at least 70 molar % of 1,4-butanediol and having a melting point determined by differential thermal analysis of 100.degree. to 150.degree. C.,(b) a nucleating agent, and(c) a leveling agent.This composition can be applied with a lowered pre-heat temperature and a lowered heat setting temperature and can form a coating film having an excellent adhesion, a good appearance and a high impact resistance.Type: GrantFiled: August 15, 1986Date of Patent: July 19, 1988Assignees: Toray Industries, Inc., Seitetsu Kagaku Co.Inventors: Tatsuro Okano, Hirofumi Eguchi
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Patent number: 4758611Abstract: An acid scavenger additive for a one-component, acyloxy-functional RTV composition. The acid scavenger is selected from magnesium materials, zinc materials, and aluminum materials. The acid scavenger prevents a discoloration of the metallic substrate and a decrease in bonding properties of the RTV composition to the substrate on which it is applied.Type: GrantFiled: January 12, 1987Date of Patent: July 19, 1988Assignee: General Electric CompanyInventor: Melvin D. Beers
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Patent number: 4757103Abstract: Self-extinguishing polycarbonates consisting of mixtures of polycarbonates with at least one salt of particular carboxylic organic compounds, said salt being of metals of Group I A and/or B, and/or Group II A and/or B of the Periodic Table of elements, and/or of ammonium.Type: GrantFiled: October 23, 1986Date of Patent: July 12, 1988Assignee: Anic, S.p.A.Inventors: Giovanni Dozzi, Salvatore Cucinella, Giorgio Della Fortuna
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Patent number: 4753971Abstract: Peroxide vulcanizable chlorinated polyethylene compositions can, after being press cured at a temperature of 204.degree. Centigrade for a period of ten minutes, withstand ozone-induced cracking for a period of 168 hours or more when elongated 60% and exposed to 200 parts of ozone per hundred million parts of air at a temperature of 400.degree. Centigrade.Type: GrantFiled: July 10, 1987Date of Patent: June 28, 1988Assignee: The Dow Chemical CompanyInventors: William H. Davis, Jr., Raymond L. Laakso, Jr., Michael E. Price
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Patent number: 4751118Abstract: Polyvinyl chloride articles such as bottles and films are provided which have a high degree of clarity, low haze, low blush, excellent color stability and which do not impart taste and odor to the contents of the article. A novel composition is used to form the articles. Said composition comprises at least one ingredient selected from the group having the formula:OH--X--O--RandR--O--X--O--R.X in the above formulas is a straight chain, branched or cyclic radical having from 2 to about 20 oxygen atoms, preferably from 2 to 10 and more preferably from 2 to 6. At least one of said oxygen atoms must form an ether linkage and the remainder may form ether, epoxy or hydroxy bonds or mixtures thereof. X also has from about 4 to about 60 carbon atoms, preferably 6 to 30, more preferably 6 to 20. R is a straight chain radical having from about 5 to about 40 carbon atoms, preferably 12 to 20.Type: GrantFiled: August 26, 1985Date of Patent: June 14, 1988Assignee: The B. F. Goodrich CompanyInventors: Roman W. Wypart, James W. Summers
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Patent number: 4746573Abstract: Free-flowing granular compositions based on fluoroelastomers containing dispersed on their surface, as an anti-caking agent, from 5% to 70% by weight of a polyolefine powder.Type: GrantFiled: March 25, 1986Date of Patent: May 24, 1988Assignee: Ausimonth S.p.A.Inventors: Vincenzo Arcella, Gaetano Bianchi, Dionisio D'Auria
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Patent number: 4743643Abstract: Stable dispersion of addition (co)polymers in an inert relatively non-polar organic hydrocarbon liquid, the dispersed particles embracing both a (co)polymer and a polymer containing an ethylenically unsturated monamer. The (co)polymers are substantially composed of:(a) 5 to 100 mole % of styrene and/or methyl styrene;(b) 0 to 95 mole % of alkyl methacrylate having 1 or 2 carbon atoms in the alkyl group and/or alkoxyalkylene methacrylate having 1 or 2 carbon atoms in the alkoxy group and the alkylene group;(c) 0 to 40 mole % of alkyl methacrylate having 3 to 12 carbon atoms in the alkyl group;(d) 0 to 40 mole % of hydroxyalkyl methacrylate having 2 to 12 carbon atoms in the alkyl group and/or glycidyl methacrylate; and(e) 0 to 20 mole % of methacrylic acid.Type: GrantFiled: November 20, 1986Date of Patent: May 10, 1988Assignee: Akzo nvInventor: Roelof Buter
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Patent number: 4727104Abstract: Compounds of formula I ##STR1## wherein R is --COOCH.sub.3, --COOC.sub.2 H.sub.5 or methyl, R.sub.1 is --COOR.sub.3, R.sub.2 is hydrogen, methyl or ethyl and R.sub.3 is C.sub.1 -C.sub.22 alkyl, are suitable for stabilizing organic polymers, in particular chlorinated thermoplastics, against the influence of heat and/or light.Type: GrantFiled: January 27, 1986Date of Patent: February 23, 1988Assignee: Ciba-Geigy CorporationInventors: Wolfgang Wehner, Klaus-Peter Michaelis, Rainer Schneider
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Patent number: 4717747Abstract: Stabilizer mixtures for vinyl chloride polymerizates for the improvement of the initial clarity and the heat constancy thereof. The stabilizer mixture contains nitrogen-free 3,5-substituted tetrahydropyrane-2,4,6-trione compounds of the formula: ##STR1## wherein R is a substituted or unsubstituted alkyl radical having 1 to 6 C atoms, and a metal salt of an organic acid and/or a metal phenolate.Type: GrantFiled: June 20, 1985Date of Patent: January 5, 1988Assignee: Lonza Ltd.Inventor: Theodor Volker
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Patent number: 4690953Abstract: A method of mechanically frothing and casting an aqueous ionic polyurethane dispersion to yield a mechanically frothed polyurethane foam. The method comprises admixing an aqueous ionic polyurethane dispersion with a stearate stabilizer and an optional aziridine crosslinking agent, and frothing the low viscosity admixture. The polyurethane dispersion contains particles having an average size of less than one micron, and contains between 35 and 70 percent by weight dispersed polyurethane solids. Preferably, each polyurethane particle in the aqueous dispersion is crosslinked. Before frothing, the low viscosity admixture contains between 33 and 87 percent by weight of the polyurethane dispersion, up to 33 percent by weight of an azirdine composition and between 13 and 50 percent by weight of a 33 percent aqueous dispersion of a stearate salt and has, as a result, a viscosity in the range of 100 to 200 centipoise. After frothing, the frothed admixture is knife-coated and cured into a flexible foam sheet.Type: GrantFiled: March 11, 1986Date of Patent: September 1, 1987Assignee: Seton CompanyInventors: Robert B. Orr, Leon Chicosky, Jr.
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Patent number: 4680363Abstract: An acid scavenger additive for a one-component, acyloxy-functional RTV composition. The acid scavenger is selected from magnesium materials, zinc materials, and aluminum materials. The acid scavenger prevents a discoloration of the metallic substrate and a decrease in bonding properties of the RTV composition to the substrate on which it is applied.Type: GrantFiled: January 13, 1984Date of Patent: July 14, 1987Assignee: General Electric CompanyInventor: Melvin D. Beers
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Patent number: 4680329Abstract: Polyphenylene ether resin compositions, optionally also containing polystyrenes, with improved impact properties and resistance to stress-cracking and delamination are prepared by blending with said resin at least one hydrocarbon polymer containing phosphorus acid or derivative (preferably phosphonate) groups and at least one fatty acid salt such as zinc stearate. Preferably, there are added to the blend at least one plasticizer (especially a triaryl phosphate) and at least one aromatic polymer containing acidic (especially sulfonic acid) substituents or salts thereof.Type: GrantFiled: August 19, 1985Date of Patent: July 14, 1987Assignee: General Electric CompanyInventors: Sterling B. Brown, Dennis J. McFay
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Patent number: 4678826Abstract: Substituted-(aminoxy)-pyrrolidine-2,5-dione derivatives of the formula ##STR1## are prepared by the reaction of the appropriate maleimide and hydroxylamine compounds and are useful as stabilizers for organic polymers.Type: GrantFiled: January 24, 1986Date of Patent: July 7, 1987Assignee: Ciba-Geigy CorporationInventors: Stephen D. Pastor, Edward T. Hessell
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Patent number: 4677147Abstract: A release coating used in cooking and baking comprising a thermosettable polyorganosiloxane resin, a noncurable polydiorganosiloxane fluid, and a combination of at least two metal containing compounds. Optionally, the coatings may contain carboxylic acid.Type: GrantFiled: March 24, 1986Date of Patent: June 30, 1987Assignee: Dow Corning CorporationInventors: Terence J. Swihart, Dennis W. Broderick
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Patent number: 4659764Abstract: A polyvinyl chloride powder molding composition is made which is resistant to staining upon thermal exposure when used as a covering for polyurethane articles. Staining of the mold lining is also inhibited. The polymer composition affording these advantages comprises a dry blended mixture of a vinyl chloride resin, a plasticizer, a pigment, a filler and as a thermal stabilizer, a barium-zinc C.sub.6 to C.sub.9 carboxylic acid soap mixture and at least one inorganic magnesium compound.Type: GrantFiled: March 12, 1986Date of Patent: April 21, 1987Assignee: Sumitomo Chemical Company, LimitedInventors: Matsuura Isao, Masanori Kobayashi, Akira Wakatsuki
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Patent number: 4652282Abstract: An electretized material for a dust filter which is made of an insulating polymer material such as polypropylene incorporated with a fatty acid metal salt in an amount of not less than 100 ppm in terms of the metal.Type: GrantFiled: March 18, 1985Date of Patent: March 24, 1987Assignee: Toyo Boseki Kabushiki KaishaInventors: Susumu Ohmori, Akira Yagi, Satoshi Takase
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Patent number: 4639482Abstract: Compositions for the stabilization of polyvinylchloride comprising blends or tri- and tetrathiophosphoric acid esters and at least one polyvinylchloride stabilizer of the type Me(II)-carboxylate and/or Me(II)-phenolate as well as the polyvinylchloride stabilized therewith.Type: GrantFiled: March 21, 1983Date of Patent: January 27, 1987Assignee: Ciba-Geigy CorporationInventors: Horst Muller, Horst Zinke, Wolfgang Wehner
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Patent number: 4629753Abstract: This invention relates to non-asphaltic, non-mastic type, water dispersed rust inhibitive coating compositions comprising in admixture a film forming organic polymer and a non-Newtonian colloidal disperse system comprising (1) solid metal containing colloidal particles, (2) a liquid dispersing medium and (3) an organic compound the molecules of which contain a hydrophobic portion and at least one polar substituent.Type: GrantFiled: November 25, 1985Date of Patent: December 16, 1986Assignee: The Lubrizol CorporationInventor: Robert E. Quinn
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Patent number: 4618630Abstract: An antistatic additive for polymers, particularly polyurethanes is disclosed comprising an ionizable metal salt and an enhancer comprising a non-ionizable salt or ester of an organic acid.Type: GrantFiled: July 2, 1985Date of Patent: October 21, 1986Assignee: The Dow Chemical Co.Inventors: Thomas M. Knobel, Earl E. Kennedy, Mary A. Walker
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Patent number: 4594382Abstract: A carboxyl-containing ethylene copolymer composition exhibiting thermal stability and method for preparing the same. The composition comprises (a) an ethylene copolymer containing a carboxyl-functional comonomer in an amount ranging from about 0.01 to about 50 weight percent of the copolymer, and (b) a hydrated compound in intimate admixture therewith. The hydrate dehydrates at a temperature between about 100.degree. C. and about 300.degree. C. and is selected from hydrated metallic salts of organic acids, inorganic hydrates, bimetallic hydrates and combinations thereof. The hydrate is present in the composition in at least an amount effective to impart thermal stability thereto up to about 5 weight percent of the composition, preferably 0.01-0.45 weight percent. The composition is prepared by adding the hydrate to the copolymer and intimately mixing the hydrate and the copolymer. The addition and mixing steps are performed either during or subsequent to the manufacture of the copolymer.Type: GrantFiled: November 16, 1984Date of Patent: June 10, 1986Assignee: The Dow Chemical CompanyInventors: Stephen M. Hoenig, David P. Flores, Gregory S. O'Connell
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Patent number: 4593060Abstract: Smoke retardant compositions comprise a polyvinyl halide resin and a smoke retardant proportion of tin oxalate or calcium oxalate. Small amounts of zinc oxide, magnesium oxide or titanium oxide can also be included to provide cost effective smoke and fire retardant compositions. In flexible compositions a fire retardant additive such as aluminum trihydrate is used.Type: GrantFiled: April 17, 1985Date of Patent: June 3, 1986Assignee: Occidental Chemical CorporationInventors: Manoj K. Gupta, Gideon Salee
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Patent number: 4581398Abstract: Hydrolysis-resistant, thermoplastic molding compositions are made from high-molecular weight, linear polybutylene terephthalate and 0.1-10 mole %, based on the amount of the dicarboxylic acid component of the polyester, of a salt of Formula (A)[(-O.sub.3 S).sub.x R--CO.sub.2.sup.-).sub.2 ]M, (A)whereinM is an alkali or alkaline earth metal cation,R is an aromatic or cycloaliphatic residue or an aliphatic residue of 2-20 carbon atoms in the carbon chain, andx is 0 or 1.Type: GrantFiled: May 29, 1984Date of Patent: April 8, 1986Assignee: Huels AktiengesellschaftInventors: Michael Droscher, Horst Heuer
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Patent number: 4578418Abstract: A two-package air-drying coating system resistant to strong organic solvents, free from toxic heavy metals and excellent, for example, as a primer for adhering urethanes or epoxy enamels to previously painted steel, is based upon a rheologically desirable mixture of (1) plate-like filler, e.g., talc, (2) carbon black, and (3) barium lanolate with a binder composed of a polyol and a polyisocyanate crosslinking agent.Type: GrantFiled: December 31, 1984Date of Patent: March 25, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventor: Achim R. Krueger
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Patent number: 4559380Abstract: A polyacetal composition which comprises polyacetal, an aliphatic ester of a polyhydric alcohol having a hydroxy group, polyethylene glycol, and an organometallic salt, wherein the organometallic salt is present in an amount of from 0.01 to 5 percent by weight based on the total composition.Type: GrantFiled: April 8, 1985Date of Patent: December 17, 1985Assignee: Polyplastics Company, Ltd.Inventors: Takuzo Kasuga, Yukio Ikenaga, Masami Yamawaki, Keizo Tanimura
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Patent number: 4546140Abstract: Shelf-stable, one-package aqueous latices, which are curable with or without the application of heat, consist essentially of an alkaline-curable, self-crosslinking emulsion polymer, selected organic metal salts, and water. The alkali, alkaline earth, or heavy metal salts of C.sub.1 -C.sub.6 organic acids (e.g., sodium acetate) are post-added to th polymer emulsion or present during the polymerization. The polymer typically comprises about 90-99.9% by weight of one or more vinyl polymerizable monomers (e.g., acrylates, vinyl esters, and ethylene) and 0.1-10% by weight of a polymerizable non-ionic or cationic self-crosslinking monomer containing halohydrin groups (e.g., 3-chloro-2-hydroxypropyl (meth)acrylate or the reaction product of epichlorohydrin and N,N-dimethylaminopropyl methacrylamide or methacrylate).Type: GrantFiled: August 2, 1984Date of Patent: October 8, 1985Assignee: National Starch and Chemical CorporationInventor: Yen-Jer Shih
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Patent number: 4543385Abstract: This invention relates to extrusion and injection moldable type elastomeric compositions having improved compression set properties and having a viscosity at 200.degree. C. at 0.73 sec.sup.-1 of about 8.times.10.sup.3 to about 8.times.10.sup.5 poises. The compositions used for elastomeric articles include a major portion of neutralized sulfonated EPDM terpolymer and a minor portion of an unsulfonated EPDM terpolymer or EP copolymer and optionally less than about 150 parts by weight of a non-polar process oil per 100 parts of the sulfonated polymer; less than about 300 parts by weight of a filler per 100 parts of the sulfonated polymer; and a preferential plasticizer at about 1 to about 60 parts by weight per 100 parts of the sulfonated elastomeric polymer.These blend compositions can be readily processed due to their superior rheological properties on conventional plastic fabrication equipment into elastomeric articles having improved compression set properties characteristics.Type: GrantFiled: December 28, 1983Date of Patent: September 24, 1985Assignee: Exxon Research and Engineering Co.Inventors: Pawan K. Agarwal, Ilan Duvdevani, Robert D. Lundberg
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Patent number: 4542178Abstract: For the thermoplastic processing of polyvinyl alcohol, the processing temperature must be below the decomposition temperature of the polyvinyl alcohol; this is attained by incorporating plasticizers. For preparing a plasticizer-containing granular polyvinyl alcohol wherein the plasticizer is homogeneously distributed, there is used as starting material a granular polyvinyl alcohol consisting substantially of particles having a definite diameter. The plasticizer is incorporated in the presence of a small amount of water insufficient to dissolve the polyvinyl alcohol, and the temperature is adjusted in a definite manner during the mixing operation. Simultaneous presence of fine particles of a high molecular weight organic compound soluble or dispersible in water is advantageous. The plasticizer-containing granular polyvinyl alcohol is suitable for the manufacture of any shaped articles, especially films and sheets.Type: GrantFiled: December 2, 1983Date of Patent: September 17, 1985Assignee: Hoechst AktiengesellschaftInventors: Wolfgang Zimmermann, Albrecht Harreus
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Patent number: 4539353Abstract: Aqueous compositions which contain a hydrolysed polymaleic anhydride, a complexing agent and a mixture of nonionic and anionic surfactants are suitable for use as assistants in the opening up of cellulose-containing fibre materials.Type: GrantFiled: January 13, 1984Date of Patent: September 3, 1985Assignee: Ciba-Geigy CorporationInventors: Heinz Abel, Christian Guth
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Patent number: 4536529Abstract: Flame retardant thermoplastic compositions are described which comprise 30-98% by weight thermoplastic, 1-40% by weight of a silicone fluid, 1-20% by weight of metal soap precursors and 1-20% by weight of a silicone resin. Such compositions offer simpler processing, improved impact resistance and other advantages over conventional flame retardant thermoplastic compositions.Type: GrantFiled: December 20, 1983Date of Patent: August 20, 1985Assignee: General Electric CompanyInventors: Robert B. Frye, Michio Zembayashi
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Patent number: 4536531Abstract: A polyester resin composition having excellent molding mobility and crystallizing property, comprises (A) at least one thermoplastic polyester resin selected from polyethylene terephthalate resins and polybutylene terephthalate resins; (B) a polycaprolactone having a number average molecular weight of from 200 to 2,000 in an amount of 0.1 to 30 parts by weight per 100 parts by weight of the polyester resin, in which polycaprolactone molecules, at least 50% of the terminal radicals thereof, are modified to be non-reactive, (C) 0.01 to 10 parts by weight of a crystal nucleating agent per 100 parts of the polyester resin, and optionally, (D) at least one additive selected from fillers and specific phosphorous compounds which may be in combination with a specific epoxy compound, the polyester resin composition being useful for producing a molded product having an excellent dimensional stability and mechanical strength.Type: GrantFiled: May 19, 1983Date of Patent: August 20, 1985Assignee: Teijin LimitedInventors: Yoshinari Ogawa, Noriyuki Akagi
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Patent number: 4530975Abstract: A polyamide-imide resin composition comprising (A) a polyamide-imide resin modified with a polyisocyanate containing one or more isocyanurate rings and a lactam and (B) at least one member selected from the group consisting of (i) an alkoxy modified amino resin, (ii) a polyisocyanate containing one or more isocyanurate rings, (iii) a phenol-formaldehyde resin, (iv) an epoxy resin, (v) a polyester resin having one or more hydroxyl groups obtained by using terephthalic acid and/or isophthalic acid as an acid component, and (vi) a metal salt of Sn, Mn, Co or Zn, can give fast curing properties to the resin composition without lowering heat resistance, flexibility, abrasion resistance and also giving good surface appearance to the coating.Type: GrantFiled: September 30, 1982Date of Patent: July 23, 1985Assignee: Hitachi Chemical Company, Ltd.Inventors: Yoshiyuki Mukoyama, Touichi Sakata, Yuichi Osada
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Patent number: 4524181Abstract: Cured epoxy resins having reduced susceptibility to mechanical and thermal shock are prepared from a composition comprising a curable epoxide compound and elastomeric particles colloidally dispersed therein, the particles having been prepared by in situ polymerization in the epoxide compound in the presence of a stabilizer.Type: GrantFiled: August 11, 1983Date of Patent: June 18, 1985Assignee: Minnesota Mining and Manufacturing CompanyInventors: Randall E. Adam, William J. Schultz
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Patent number: 4517316Abstract: A mixture of crumb rubber, binder, such as polyethylene, and slip contact agent, such as talc, and lubricant, such as a metal stearate, is formed in a blender (10), is shaped into pellets (32) by extruding a strand of the mixture (26) into water (28) and breaking the strand into pellets. The pellets (32) are adjusted to a preselected water content in drier (46) before storage in closed bags (50), stored and reinforced in a container (54).The controlled water content pellets (32) are formed into porous pipe (88) by extrusion in pipe extruder (62) having the feeding, transition and metering zones separately heated to temperatures from 320.degree. F. to 400.degree. F. (T.sub.1, T.sub.2, T.sub.3). The die has a separate jacket (90) receiving heat exchange fluid for heating the die (68) to a temperature from 290.degree. F. to 380.degree. F. to form a porous pipe (88) having more uniform porosity. Porosity is controlled by selecting water content of the pellets and controlling die temperature.Type: GrantFiled: January 24, 1984Date of Patent: May 14, 1985Assignee: Dasurat Enterprises PTE Ltd.Inventor: James W. Mason
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Patent number: 4501840Abstract: Pentaerythritol is treated at a temperature of about 180.degree. to 220.degree. C. with a strongly alkaline acting material, e.g. calcium oxide. The thus treated pentaerythritol serves as a costabilizer e.g., with the salt of a polyvalent metal and a carboxylic acid, for a vinyl chloride resin, e.g. polyvinyl chloride and has outstanding properties as such.Type: GrantFiled: October 20, 1983Date of Patent: February 26, 1985Assignee: Degussa AktiengesellschaftInventors: Peter Werle, Wolfgang Merk
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Patent number: 4499227Abstract: A high impact resistant composition consisting essentially of a thermoplastic resin blended with an admixture of mica and at least one ingredient selected from the group consisting of polybutylenes, metal salts of long-chain fatty acids, and mineral oils.Type: GrantFiled: December 2, 1983Date of Patent: February 12, 1985Assignee: Phillips Petroleum CompanyInventor: Fay W. Bailey
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Patent number: 4486562Abstract: A process is provided for preparing a vulcanized carbon black-reinforced chloro- or bromobutyl rubber film comprising admixing a polyfunctional amine vulcanization system with a carbon black-reinforced chloro- or bromobutyl rubber latex containing one or more selected emulsifiers, forming a film from the resulting mixture, drying said film and heating the dried film to provide the vulcanized film. The process may be used in the manufacture of coatings, dipped goods and chemical resistant impermeable treated fabrics.Type: GrantFiled: March 16, 1984Date of Patent: December 4, 1984Assignee: Polysar LimitedInventors: Erhardt Fischer, Douglas C. Edwards
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Patent number: 4481318Abstract: This invention relates to unique and novel compositions based on chemically combining a sulfonated polymer and a tertiary amine terminated polylactone composition. The resulting amine neutralized sulfonated polymer compositions have a variety of uses including those as diverse as adhesive agents, thermoplastic elastomers, additives uses wherein these materials can be utilized to compatibilize two different polymers which are normally incompatible. These compositions can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.Type: GrantFiled: September 29, 1983Date of Patent: November 6, 1984Assignee: Exxon Research & Engineering Co.Inventors: Robert D. Lundberg, Warren A. Thaler
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Patent number: 4480062Abstract: A composition, extrudable or calenderable into a membrane, comprising 100 parts by weight of a neutralized sulfonated elastomeric polymer, 40 to 250 parts of a non-polar process oil, 5 to 50 parts of a preferential plasticizer selected from the group consisting of a basic salt of a carboxylic acid and an organic amide and at least 65 parts of carbon black. The membrane, made in accordance with the composition of this invention, has particular application as a roof covering.Type: GrantFiled: March 28, 1983Date of Patent: October 30, 1984Assignee: Uniroyal, Inc.Inventor: Arnis U. Paeglis
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Patent number: 4476273Abstract: Moldings having enhanced physical properties are made from compositions of a conjugated diene polymer, calcium carbonate and certain .alpha.,.beta.-unsaturated carboxylic modifiers.Type: GrantFiled: November 8, 1982Date of Patent: October 9, 1984Assignee: Phillips Petroleum CompanyInventor: Guy Senatore
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Patent number: 4476277Abstract: A resin composition comprising(I) a granular or powdery resin which is a condensation product of a phenol, an aldehyde and optionally a nitrogen-containing compound having at least two active hydrogens and is characterized by (A) containing spherical primary particles and their secondary agglomerated particles each having a particle diameter of 0.1 to 150 microns, (B) having such a size that at least 50% by weight thereof can pass through a 100 Tyler mesh sieve, and (C) having a free phenol content, determined by liquid chromatography, of not more than 500 ppm, and(II) at least one member selected from the group consisting of (1) a rubbery elastic material, (2) a thermoplastic resin and (3) a curable reisn other than said granular or powdery resin (I) and/or a filler material other than said granular or powdery resin (I).Type: GrantFiled: December 23, 1982Date of Patent: October 9, 1984Assignee: Kanebo Ltd.Inventors: Hiroaki Koyama, Shigeo Shimizu
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Patent number: 4468485Abstract: A method of preparing polymer lattices of homogeneous interpenetrated structure, starting from a mixture of at least two basic prepolymer constituents is characterized by the fact that a microwave radiation is applied having a frequency spectrum chosen in order that it interacts preferentially with the first prepolymer and a power density chosen in order that it directly activates the exothermic reaction of cross-linking of the first prepolymer. The cross-linking of the second prepolymer is only triggered under the combined action of the heat due to the interaction of the microwave energy with the second prepolymer and the heat introduced by the cross-linking reaction of the first prepolymer, which makes it possible to combine propagation of the two cross-linking reactions at similar speeds.Type: GrantFiled: January 11, 1983Date of Patent: August 28, 1984Assignee: Electricite de France (Service National)Inventors: Albert Gourdenne, Pascal Heintz
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Patent number: 4468486Abstract: A resin coated sand for shell-molding processes is provided comprising the coating of foundry sand or aggregates with a phenolic resin and a carboxylic acid salt. The carboxylic acid salt is selected from a carboxylic acid salt of an element selected from groups Ia, Ib, IIa, IIb, IIIa, IVa, Va, VIb, VIIa, VIIb or VIII of the Periodic Table of Elements. The proportion of carboxylic acid salt to phenolic resin is from 0.5 to 40 parts carboxylic acid salt to 100 parts phenolic resin. This resin coated sand produces shell-molds having excellent properties for casting, and allows the molded article to be removed in an easy and efficient manner.Type: GrantFiled: November 2, 1982Date of Patent: August 28, 1984Assignee: Sumitomo Durez Company, Ltd.Inventors: Noriaki Matsushima, Yukio Saeki, Yukio Tokunaga
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Patent number: 4462805Abstract: A mixture of cationic compounds of the formulae ##STR1## is obtained by reaction of a compound of the formula ##STR2## with an aldehyde of the formula II ##STR3## in an aqueous or organic medium, in the presence of an acid, in which formulae, the symbols have the meanings defined in claim 1. The mixtures obtained are suitable in particular for the dyeing of paper, whereby neutral-yellow dyeings are obtained.Type: GrantFiled: May 10, 1983Date of Patent: July 31, 1984Assignee: Ciba-Geigy CorporationInventors: Willy Stingelin, Peter Loew
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Patent number: 4463122Abstract: The blocking characteristics of ethylene interpolymers containing --COOH groups are reduced by treating such polymers with a solution of an inorganic compound of a Group I-A metal such as trisodium phosphate and an organic compound of a Group I-A metal such as sodium acetate or a combination thereof.Type: GrantFiled: September 27, 1982Date of Patent: July 31, 1984Assignee: The Dow Chemical CompanyInventors: David P. Flores, James A. Allen
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Patent number: 4461854Abstract: A two-component room temperature vulcanizable polysiloxane composition curable in the presence of a heat-activated catalyst is disclosed. The working life of a condensation curable organopolysiloxane containing terminal silicon-bonded hydroxy groups in a first component is extended by using a metallic salt of an organic carboxylic acid catalyst in a second component by providing in combination with the metallic salt of an organic carboxylic acid catalyst, a solid, inert barrier material capable of melting at an elevated temperature, whereby the catalyst is activated when heat applied thereto, melts the solid barrier material. A cross-linking agent and optionally, a filler, are used in the components. In one embodiment, the catalyst is a tin carboxylate used as a core material and the solid, inert barrier material is calcium stearate used as a wall material to encapsulate the catalyst material.Type: GrantFiled: August 11, 1982Date of Patent: July 24, 1984Assignee: General Electric CompanyInventor: Robert A. Smith
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Patent number: 4456715Abstract: Self-extinguishing thermoplastic polyamide moulding compositions containing barbituric acid and/or reaction products thereof as flameproofing agent.Type: GrantFiled: June 29, 1981Date of Patent: June 26, 1984Assignee: Bayer AktiengesellschaftInventors: Ludwig Rottmaier, Rudolf Merten, Wolfgang Siebourg, Burkhard Lachmann
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Patent number: 4454281Abstract: An ethylene polymer film forming composition comprising an ethylene polymer and from about 450 to about 6000 ppm preferably 500 to 5000 ppm of metal salt of a fatty acid having from 7 to 22 carbon atoms and from about 300 to 7000 ppm preferably 500 to 4000 ppm of an antiblocking agent.Type: GrantFiled: December 1, 1982Date of Patent: June 12, 1984Assignee: Union Carbide CorporationInventors: William D. Heitz, George E. Ealer, Gary S. Cieloszyk
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Patent number: 4454260Abstract: Stable suspension of a water-soluble polymer comprising solid particles of this water-soluble polymer in a liquid hydrocarbon medium which also comprises a thickening agent selected from the alkali or alkaline-earth metal salts of fatty acids having 6-33 carbon atoms. The resultant suspensions are stable and dissolve easily when dispersed in water; they can be used in enhanced oil recovery. They may also contain minor proportions of water and/or of C.sub.1 -C.sub.12 monoalcohols or C.sub.2 -C.sub.12 diols.Type: GrantFiled: January 18, 1983Date of Patent: June 12, 1984Assignee: Institut Francais du PetroleInventors: Francois Dawans, Daniel Binet, Norbert Kohler, Quang D. Vu