Acetate Patents (Class 524/41)
  • Patent number: 4780340
    Abstract: A plastic article, in particular a highly crystalline plastic, can be effectively coated with a paint by using a primer composition comprising (A) a polyurethane, (B) a spiro-ortho-ester resin being capable of the ring-opening expansion, (C) a cellulose derivative and (D) a surfactant having a hydroxy group.
    Type: Grant
    Filed: July 16, 1987
    Date of Patent: October 25, 1988
    Assignee: Polyplastics Co., Ltd.
    Inventors: Katsuhiko Takahashi, Yoshiharu Suzuki, Haruyasu Ito
  • Patent number: 4772646
    Abstract: The present invention relates to a liquid suspension of a high molecular weight, water-soluble polymer or water-soluble salt prepared by admixing and water-soluble polymer with a hydrocarbon carrier fluid and a suspending agent comprising an aqueous emulsion of a copolymer comprising a water-insoluble and substantially hydrocarbon-insoluble polymer consisting of particles having a dry weight average particle size of below 10 .mu.m and which is formed from monomers of which 80% to 100% are hydrophobic, 30 to 100% are polar and 0% to 20% are hydrophilic. More particularly, the copolymer comprises from about 80% to about 100% C.sub.1-30 alkyl methacrylate monomers and from about 0% to about 20% hydrophilic monomers. Preferably, the copolymer comprises 90% to 100% 2-ethylhexylacrylate and from about 0.5% to about 10% acrylic acid. The liquid suspension is capable of supporting about 5 pounds of water-soluble polymer per gallon of suspension.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: September 20, 1988
    Assignee: Halliburton Company
    Inventors: Weldon M. Harms, Lewis R. Norman
  • Patent number: 4771089
    Abstract: Miscible blends of solids, non-crosslinked polymers are disclosed. The blends comprise from 2 to 95 parts by weight of a water-insoluble, hydrophobic polymer and, correspondingly from 98 to 5 parts by weight of a hydrophilic polymer. The blends are capable of absorbing at least their own weight in water.
    Type: Grant
    Filed: July 10, 1985
    Date of Patent: September 13, 1988
    Assignee: Minnesota Mining and Manufacturing Co.
    Inventor: Ronald F. Ofstead
  • Patent number: 4696958
    Abstract: An electrophoretic gel which, when used in an electrophoretic process for the separating chylomicrons, beta lipoproteins, pre-beta lipoproteins, and alpha lipoproteins, enables the separation of the alpha lipoprotein band from the faster moving free fatty acid albumin band. The electrophoretic gel comprises a matrix selected from the group consisting of polysaccharides and derivatives thereof, a buffer having a buffering capacity in an alkaline pH range, and an effective amount of a poly(oxyethylene)-poly(oxypropylene)-poly(oxyethylene) block copolymer.An improved electrophoretic technique characterized in that the above electrophoretic gel is employed therein.
    Type: Grant
    Filed: November 22, 1985
    Date of Patent: September 29, 1987
    Assignee: Beckman Instruments, Inc.
    Inventor: William A. Gurske
  • Patent number: 4650821
    Abstract: The present invention relates to a novel acrylic composition, novel acrylic castings prepared therefrom, and a novel process for the preparation of the acrylic castings. The composition comprises methyl methacrylate, about 0.5 to 20% by weight of a carboxylated cellulose ester, and about 1 to 100 ppm of a vanadium promoter. Optionally, a heat dissipative material, such as a plasticizer or an additional monomer, can also be employed. In accordance with the process of the present invention, an acrylic monomer comprising methyl methacrylate is combined with about 0.5 to 20% by weight of a carboxylated cellulose ester so as to form an easily pourable syrup, about 1 to 100 ppm of a vanadium promoter is added to the syrup and the resulting solution is poured into a suitable mold, and the solution is cured at room temperature so as to form a hard acrylic casting.
    Type: Grant
    Filed: April 25, 1986
    Date of Patent: March 17, 1987
    Assignee: Eastman Kodak Company
    Inventor: Donald R. Leonard
  • Patent number: 4603160
    Abstract: The present invention relates to a novel acrylic composition, novel acrylic castings prepared therefrom, and a novel process for the preparation of the acrylic castings. The composition comprises methyl methacrylate, about 0.5 to 20% by weight of a carboxylated cellulose ester, and about 1 to 100 ppm of a vanadium promoter. Optionally, a heat dissipative material, such as a plasticizer or an additional monomer, can also be employed. In accordance with the process of the present invention, an acrylic monomer comprising methyl methacrylate is combined with about 0.5 to 20% by weight of a carboxylated cellulose ester so as to form an easily pourable syrup, about 1 to 100 ppm of a vanadium promoter is added to the syrup and the resulting solution is poured into a suitable mold, and the solution is cured at room temperature so as to form a hard acrylic casting.
    Type: Grant
    Filed: July 1, 1985
    Date of Patent: July 29, 1986
    Assignee: Eastman Kodak Company
    Inventor: Donald R. Leonard
  • Patent number: 4576981
    Abstract: The invention relates to an adhesive composition which is suitable for use on a shaped part of polyester, in particular a polyester film, and comprises a copolyester, optionally in combination with light-sensitive substances, fillers and pigments, whereby the copolyester additionally contains at least one copolymer of vinylidene chloride, preferably in a weight ratio of about 3:1 to 1:1. The adhesive composition can furthermore contain cellulose acyl esters, such as low molecular-weight cellulose acetobutyrate or cellulose propionate. Polybasic oxycarboxylic acids and levelling agents can also be present. The adhesive composition can be employed in mixtures with, for example, light-sensitive lacquer systems.
    Type: Grant
    Filed: April 25, 1984
    Date of Patent: March 18, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hilger, Gunter Hultzsch, Roman Keiper
  • Patent number: 4532277
    Abstract: Contact lenses and implants for human medicine can be fabricated from a polymer blend comprising 98-80% by weight of component A and 2-20% by weight of component B wherein:component A is a cellulose ester of an aliphatic carboxylic acid with up to 40% by weight of total component A of an ethylene/vinyl acetate copolymer having 30-98% by weight, relative to ethylene/vinyl acetate, of incorporated vinyl acetate andcomponent B is a homopolymer or copolymer of water-soluble vinyl monomers and up to 10% by weight relative to the total polymer B of multifunctional crosslinker vinyl compounds.
    Type: Grant
    Filed: December 27, 1983
    Date of Patent: July 30, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventor: Frank Wingler
  • Patent number: 4506045
    Abstract: Thermoplastic moulding compositions consisting of from 1 to 99% by weight of at least one cellulose ester or cellulose mixed ester, from 99 to 1% by weight of an aliphatic polyester or polyether containing carbonate groups and, optionally, standard auxiliaries and additives.
    Type: Grant
    Filed: September 14, 1983
    Date of Patent: March 19, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Waniczek, Christian Lindner, Carlhans Suling, Herbert Bartl, Walter Uerdingen
  • Patent number: 4500667
    Abstract: Gas separation membranes comprising an organic polymer-inorganic compound blend may be prepared by admixing an organic polymer such as poly(vinyl alcohol) with a heteropoly acid or salt thereof such as dodecamolybdophosphoric acid in a mutually miscible solvent. After allowing the mixture to react for a period of time sufficient to form a blend, the solution may be cast on an appropriate casting surface and, after the solvent has been evaporated, the desired membrane which may have a thickness of from about 1 to about 50 microns is recovered.
    Type: Grant
    Filed: October 26, 1983
    Date of Patent: February 19, 1985
    Assignee: UOP Inc.
    Inventors: Anthony J. Polak, Allyson J. Beuhler
  • Patent number: 4483947
    Abstract: Molding composition containing(a) 2,4,5-triketoimidazolidine precondensates containing terminal oxamide ester, urethane and/or isocyanate groups and(b) customary organic and/or inorganic fillers, which contain the triketo compound a) as a reactive filler in the form of a composite of a.sub.1) a 2,4,5-triketoimidazolidine precondensate pulp and a.sub.2) a pulp of other fiber-forming polymers or, instead of this pulp a.sub.
    Type: Grant
    Filed: August 31, 1982
    Date of Patent: November 20, 1984
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Franz Jakob, Ernst Horoldt
  • Patent number: 4482654
    Abstract: Foundry sand grains coated with a binder composition which comprises 100 wt. parts of methylolmelamine or alkylated methylolmelamine and 5 to 100 wt. parts of a water-soluble organic compound having a hydroxyl group. The sand grains coated with the composition are effective in a low-temperature foundry, especially for forming a core in an aluminum-alloy foundry.
    Type: Grant
    Filed: January 20, 1983
    Date of Patent: November 13, 1984
    Assignees: Daicel Chemical Industries, Ltd., Shinto Kogio Ltd.
    Inventors: Kazuyuki Nishikawa, Katsumi Hirao, Kazuhiko Mizuguchi, Hiroshi Suzuki
  • Patent number: 4460721
    Abstract: A printing ink or varnish having a binder comprising isopropylmethacrylate and hydrophilic comonomers, particularly unsaturated carboxylic acids, their hydroxyalkyl esters, or a mixture thereof; preferably in combination with cellulose esters such as nitrocellulose, as an additional binder. The ink or varnish also contains dissolved or undissolved dyes, as well as a lower alkyl alcohol solvent. The printing and coatings thus produced are characterized by hardness and a high sealing stability.
    Type: Grant
    Filed: May 24, 1983
    Date of Patent: July 17, 1984
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Wilhelm Elser, Manfred Munzer
  • Patent number: 4435531
    Abstract: A cellulose derivative-containing emulsion composition which is the product of emulsion polymerization of at least one ethylenically unsaturated monomer in the presence of a water-solubilized product of a cellulose derivative-modified vinyl copolymer having an acid value of from about 3 to about 150, said vinyl copolymer being obtained by copolymerizing a cellulose derivative with an ethylenically unsaturated monomeric component composed of an ethylenically unsaturated acid and another ethylenically unsaturated monomer.
    Type: Grant
    Filed: August 2, 1982
    Date of Patent: March 6, 1984
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Yasuharu Nakayama, Kenji Yamamoto, Toshiki Komatsuzawa, Hajime Sukejima, Kazuo Nomoto
  • Patent number: 4428776
    Abstract: Semipermeable membranes prepared from at least one cellulosic polymer, such as cellulose triacetate, and containing at least one silicon compound, such as tetraethoxy silane, are useful for the separation of various gaseous mixtures into their constituent parts, such as separating natural gas into enriched fractions of carbon dioxide and methane.
    Type: Grant
    Filed: June 23, 1982
    Date of Patent: January 31, 1984
    Assignee: The Standard Oil Company
    Inventor: George S. Li
  • Patent number: 4397971
    Abstract: A process for the production of a thermoplastically processible polymer granulate or powder containing from 0.01 to 50%, by weight, of burr-shaped or fibrous, doped polyacetylene, in which a plastics material and the doped polyacetylene particles are mixed in the presence of an inert suspending liquid and said liquid is removed.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: August 9, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Hocker, Rolf Dhein
  • Patent number: 4389503
    Abstract: The present invention relates to non-pigmented jet ink compositions and to a method of producing opaque coded messages therewith. The compositions comprise, on a weight basis, between 2 and 15% of a gellable cellulose ester having a hydroxyl content of from 2 to 8%, from 1.5 to 15% of a binding agent selected from the group consisting of alkali soluble rosin type and maleic type resins, polyvinyl acetate resins, and acrylic resins, and a solvent blend, the blend consisting essentially of an organic solvent system and a non-solvent, said non-solvent comprising from 2 to 10% by weight of the ink compositions. Preferred solvents are methanol, acetone, methyl ethyl ketone and ethyl acetate, while the preferred non-solvent is water. Upon evaporation of the solvent blend, the resultant dry films scatter light incident thereto whereby the opaque images are produced. In a particularly preferred embodiment, a hygroscopic salt is included in the composition as an opacity enhancement agent.
    Type: Grant
    Filed: April 28, 1982
    Date of Patent: June 21, 1983
    Assignee: American Can Company
    Inventors: Dorothy Maxwell, David A. Fell
  • Patent number: 4381372
    Abstract: Polymers and oligomers of the formula ##STR1## are useful as ultraviolet light stabilizers for various polymers, especially polyolefins.
    Type: Grant
    Filed: April 8, 1981
    Date of Patent: April 26, 1983
    Assignee: American Cyanamid Company
    Inventor: Frank F. Loffelman
  • Patent number: 4357267
    Abstract: Transparent thermoplastic moulding compositions having improved mechanical properties consist essentially of a cellulose ester of aliphatic C.sub.1 -C.sub.5 -carboxylic acids and a graft copolymer of an ethylene vinyl ester copolymer having grafted thereon polymerized units of vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid and, optionally, C.sub.2 -C.sub.4 -olefins.
    Type: Grant
    Filed: December 11, 1980
    Date of Patent: November 2, 1982
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinrich Alberts, Winfried Fischer, Friedemann Muller, Horst Peters, Christian Leuschke, Hans-Peter Baasch
  • Patent number: 4352901
    Abstract: The present invention relates to non-pigmented jet ink compositions and to a method of producing opaque coded messages therewith. The compositions comprise, on a weight basis, between 2 and 15% of a gellable cellulose ester having a hydroxyl content of from 2 to 8%, from 1.5 to 15% of a binding agent selected from the group consisting of alkali soluble rosin type and maleic type resins, polyvinyl acetate resins, and acrylic resins, and a solvent blend, the blend consisting essentially of an organic solvent system and a non-solvent, said non-solvent comprising from 2 to 10% by weight of the ink composition. Preferred solvents are methanol, acetone, methyl ethyl ketone and ethyl acetate, while the preferred non-solvent is water. Upon evaporation of the solvent blend, the resultant dry films scatter light incident thereto whereby the opaque images are produced. In a particularly preferred embodiment, a hygroscopic salt is included in the composition as an opacity enhancement agent.
    Type: Grant
    Filed: August 14, 1980
    Date of Patent: October 5, 1982
    Assignee: American Can Company
    Inventors: Dorothy Maxwell, David A. Fell
  • Patent number: 4343727
    Abstract: This invention covers a shoe sole composition compounded from polyvinyl chloride and organic cellulosic flock, and the shoe sole product produced therefrom.
    Type: Grant
    Filed: October 24, 1979
    Date of Patent: August 10, 1982
    Assignee: Reichhold Chemicals Incorporated
    Inventor: Arnold Cohen
  • Patent number: 4332917
    Abstract: Method for preparing a polymer alloy which is stable and homogeneous up to high temperatures, from component (a) one or more polymers of high molecular weight, having anhydride groups and component (b) one or more polymers of high molecular weight, having groups which have the ability to interact with hydrogen atoms to form hydrogen bonds, wherein first a solution of component (a) is prepared in an organic solvent, to which solution then component (b) is added, whereas component (a) in dissolved state is protolyzed in whole or in part, prior to or after the addition of component (b) under the action of protolyzing agents, whereupon the solvent is removed; together with the formed products obtained from such a polymer alloy, such as granules, fibres, foils, foam, etc.
    Type: Grant
    Filed: December 20, 1979
    Date of Patent: June 1, 1982
    Assignee: Nederlandse Centrale Organisatie voor Toegepast-Natuurwetenschappelijk Onderzoek
    Inventors: Adolf Heslinga, Pieter J. Greidanus
  • Patent number: 4325861
    Abstract: Water-soluble polymers are rapidly dissolved by employing a concentrate of (i) a water-soluble particulate polymer, (ii) a water-insoluble organic vehicle which is a non-solvent for the polymer, (iii) a nonionic surfactant agent having an HLB in the ranges of 3-5 and 9-13 and if necessary, a thickening agent.
    Type: Grant
    Filed: April 3, 1980
    Date of Patent: April 20, 1982
    Assignee: Union Carbide Corporation
    Inventors: David B. Braun, Meyer R. Rosen
  • Patent number: RE32261
    Abstract: Solid copolymers are produced by copolymerizing a mixture of: (A) at least 30% by weight of a monomer having the formula: ##STR1## wherein R.sub.1 is H or CH.sub.3 and R.sub.2 is an alkyl radical containing from 1 to 14 carbon atoms; (B) from 3 to 20% by weight of an ethylenic .alpha.,.beta. unsaturated carboxylic acid or anhydride thereof, or from 3 to 40% by weight of glycidyl acrylate or glycidyl methacrylate; and (C) from 0 to 67% by weight of a monomer copolymerizable with said monomers (A) and (B). Preferably, the mixture is first bulk-polymerized until conversion to the copolymer is from 10 to 80% by weight and the polymerization is completed by suspension-polymerization. Thermosetting solid coating compositions are produced by mixing a major proportion of a solid copolymer so produced with a minor proportion of a cross-linking compound or with an epoxy resin containing at least 2 epoxy radicals in the molecule in presence of a tertiary amine curing accelerator.
    Type: Grant
    Filed: March 19, 1979
    Date of Patent: October 7, 1986
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Kuniomi Hirota, Akio Masumoto, Hiroshi Ozawa, Nobuki Kobayashi, Teruo Honda