Acetate Patents (Class 524/41)
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Patent number: 4801632Abstract: Thermoplastic moulding materials consisting of(1) 70 to 99.9% by weight of a cellulose ester or cellulose mixed ester(2) 0.1 to 30% by weight of a rubber polymer built up in the form of blocks from recurring structural units (I) with molecular weights of 10,000 to 1,000,000--A--B-- IwhereinA denotes bifunctional polysiloxane segements of the formula--(R.sup.1)(R.sup.2)SiO--.sub.x IIin whichR.sup.1 and R.sup.2 =aryl (in particular phenyl) or alkyl (in particular methyl) andx is a number such that the molecular weight is .gtoreq.500, andB denotes bifunctional aliphatic polyester and/or aliphatic polyester segments with molecular weights of .gtoreq.800,and the glass transition temperatures of the polymeric blocks A and B are less than 20.degree. C., which contains additionally(3) 0 to 30% by weight based on the mixture of (1) and (2) of a plasticizer.Type: GrantFiled: February 24, 1987Date of Patent: January 31, 1989Assignee: Bayer AkteingesellschaftInventors: Herbert Eichenauer, Christian Lindner, Friedemann Muller, Hartwig Hocker, Helmut Keul
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Patent number: 4780340Abstract: A plastic article, in particular a highly crystalline plastic, can be effectively coated with a paint by using a primer composition comprising (A) a polyurethane, (B) a spiro-ortho-ester resin being capable of the ring-opening expansion, (C) a cellulose derivative and (D) a surfactant having a hydroxy group.Type: GrantFiled: July 16, 1987Date of Patent: October 25, 1988Assignee: Polyplastics Co., Ltd.Inventors: Katsuhiko Takahashi, Yoshiharu Suzuki, Haruyasu Ito
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Patent number: 4772646Abstract: The present invention relates to a liquid suspension of a high molecular weight, water-soluble polymer or water-soluble salt prepared by admixing and water-soluble polymer with a hydrocarbon carrier fluid and a suspending agent comprising an aqueous emulsion of a copolymer comprising a water-insoluble and substantially hydrocarbon-insoluble polymer consisting of particles having a dry weight average particle size of below 10 .mu.m and which is formed from monomers of which 80% to 100% are hydrophobic, 30 to 100% are polar and 0% to 20% are hydrophilic. More particularly, the copolymer comprises from about 80% to about 100% C.sub.1-30 alkyl methacrylate monomers and from about 0% to about 20% hydrophilic monomers. Preferably, the copolymer comprises 90% to 100% 2-ethylhexylacrylate and from about 0.5% to about 10% acrylic acid. The liquid suspension is capable of supporting about 5 pounds of water-soluble polymer per gallon of suspension.Type: GrantFiled: November 17, 1986Date of Patent: September 20, 1988Assignee: Halliburton CompanyInventors: Weldon M. Harms, Lewis R. Norman
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Patent number: 4771089Abstract: Miscible blends of solids, non-crosslinked polymers are disclosed. The blends comprise from 2 to 95 parts by weight of a water-insoluble, hydrophobic polymer and, correspondingly from 98 to 5 parts by weight of a hydrophilic polymer. The blends are capable of absorbing at least their own weight in water.Type: GrantFiled: July 10, 1985Date of Patent: September 13, 1988Assignee: Minnesota Mining and Manufacturing Co.Inventor: Ronald F. Ofstead
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Patent number: 4696958Abstract: An electrophoretic gel which, when used in an electrophoretic process for the separating chylomicrons, beta lipoproteins, pre-beta lipoproteins, and alpha lipoproteins, enables the separation of the alpha lipoprotein band from the faster moving free fatty acid albumin band. The electrophoretic gel comprises a matrix selected from the group consisting of polysaccharides and derivatives thereof, a buffer having a buffering capacity in an alkaline pH range, and an effective amount of a poly(oxyethylene)-poly(oxypropylene)-poly(oxyethylene) block copolymer.An improved electrophoretic technique characterized in that the above electrophoretic gel is employed therein.Type: GrantFiled: November 22, 1985Date of Patent: September 29, 1987Assignee: Beckman Instruments, Inc.Inventor: William A. Gurske
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Patent number: 4650821Abstract: The present invention relates to a novel acrylic composition, novel acrylic castings prepared therefrom, and a novel process for the preparation of the acrylic castings. The composition comprises methyl methacrylate, about 0.5 to 20% by weight of a carboxylated cellulose ester, and about 1 to 100 ppm of a vanadium promoter. Optionally, a heat dissipative material, such as a plasticizer or an additional monomer, can also be employed. In accordance with the process of the present invention, an acrylic monomer comprising methyl methacrylate is combined with about 0.5 to 20% by weight of a carboxylated cellulose ester so as to form an easily pourable syrup, about 1 to 100 ppm of a vanadium promoter is added to the syrup and the resulting solution is poured into a suitable mold, and the solution is cured at room temperature so as to form a hard acrylic casting.Type: GrantFiled: April 25, 1986Date of Patent: March 17, 1987Assignee: Eastman Kodak CompanyInventor: Donald R. Leonard
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Patent number: 4603160Abstract: The present invention relates to a novel acrylic composition, novel acrylic castings prepared therefrom, and a novel process for the preparation of the acrylic castings. The composition comprises methyl methacrylate, about 0.5 to 20% by weight of a carboxylated cellulose ester, and about 1 to 100 ppm of a vanadium promoter. Optionally, a heat dissipative material, such as a plasticizer or an additional monomer, can also be employed. In accordance with the process of the present invention, an acrylic monomer comprising methyl methacrylate is combined with about 0.5 to 20% by weight of a carboxylated cellulose ester so as to form an easily pourable syrup, about 1 to 100 ppm of a vanadium promoter is added to the syrup and the resulting solution is poured into a suitable mold, and the solution is cured at room temperature so as to form a hard acrylic casting.Type: GrantFiled: July 1, 1985Date of Patent: July 29, 1986Assignee: Eastman Kodak CompanyInventor: Donald R. Leonard
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Patent number: 4576981Abstract: The invention relates to an adhesive composition which is suitable for use on a shaped part of polyester, in particular a polyester film, and comprises a copolyester, optionally in combination with light-sensitive substances, fillers and pigments, whereby the copolyester additionally contains at least one copolymer of vinylidene chloride, preferably in a weight ratio of about 3:1 to 1:1. The adhesive composition can furthermore contain cellulose acyl esters, such as low molecular-weight cellulose acetobutyrate or cellulose propionate. Polybasic oxycarboxylic acids and levelling agents can also be present. The adhesive composition can be employed in mixtures with, for example, light-sensitive lacquer systems.Type: GrantFiled: April 25, 1984Date of Patent: March 18, 1986Assignee: Hoechst AktiengesellschaftInventors: Manfred Hilger, Gunter Hultzsch, Roman Keiper
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Patent number: 4532277Abstract: Contact lenses and implants for human medicine can be fabricated from a polymer blend comprising 98-80% by weight of component A and 2-20% by weight of component B wherein:component A is a cellulose ester of an aliphatic carboxylic acid with up to 40% by weight of total component A of an ethylene/vinyl acetate copolymer having 30-98% by weight, relative to ethylene/vinyl acetate, of incorporated vinyl acetate andcomponent B is a homopolymer or copolymer of water-soluble vinyl monomers and up to 10% by weight relative to the total polymer B of multifunctional crosslinker vinyl compounds.Type: GrantFiled: December 27, 1983Date of Patent: July 30, 1985Assignee: Bayer AktiengesellschaftInventor: Frank Wingler
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Patent number: 4506045Abstract: Thermoplastic moulding compositions consisting of from 1 to 99% by weight of at least one cellulose ester or cellulose mixed ester, from 99 to 1% by weight of an aliphatic polyester or polyether containing carbonate groups and, optionally, standard auxiliaries and additives.Type: GrantFiled: September 14, 1983Date of Patent: March 19, 1985Assignee: Bayer AktiengesellschaftInventors: Helmut Waniczek, Christian Lindner, Carlhans Suling, Herbert Bartl, Walter Uerdingen
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Patent number: 4500667Abstract: Gas separation membranes comprising an organic polymer-inorganic compound blend may be prepared by admixing an organic polymer such as poly(vinyl alcohol) with a heteropoly acid or salt thereof such as dodecamolybdophosphoric acid in a mutually miscible solvent. After allowing the mixture to react for a period of time sufficient to form a blend, the solution may be cast on an appropriate casting surface and, after the solvent has been evaporated, the desired membrane which may have a thickness of from about 1 to about 50 microns is recovered.Type: GrantFiled: October 26, 1983Date of Patent: February 19, 1985Assignee: UOP Inc.Inventors: Anthony J. Polak, Allyson J. Beuhler
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Patent number: 4483947Abstract: Molding composition containing(a) 2,4,5-triketoimidazolidine precondensates containing terminal oxamide ester, urethane and/or isocyanate groups and(b) customary organic and/or inorganic fillers, which contain the triketo compound a) as a reactive filler in the form of a composite of a.sub.1) a 2,4,5-triketoimidazolidine precondensate pulp and a.sub.2) a pulp of other fiber-forming polymers or, instead of this pulp a.sub.Type: GrantFiled: August 31, 1982Date of Patent: November 20, 1984Assignee: Hoechst AktiengesellschaftInventors: Franz Jakob, Ernst Horoldt
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Patent number: 4482654Abstract: Foundry sand grains coated with a binder composition which comprises 100 wt. parts of methylolmelamine or alkylated methylolmelamine and 5 to 100 wt. parts of a water-soluble organic compound having a hydroxyl group. The sand grains coated with the composition are effective in a low-temperature foundry, especially for forming a core in an aluminum-alloy foundry.Type: GrantFiled: January 20, 1983Date of Patent: November 13, 1984Assignees: Daicel Chemical Industries, Ltd., Shinto Kogio Ltd.Inventors: Kazuyuki Nishikawa, Katsumi Hirao, Kazuhiko Mizuguchi, Hiroshi Suzuki
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Patent number: 4460721Abstract: A printing ink or varnish having a binder comprising isopropylmethacrylate and hydrophilic comonomers, particularly unsaturated carboxylic acids, their hydroxyalkyl esters, or a mixture thereof; preferably in combination with cellulose esters such as nitrocellulose, as an additional binder. The ink or varnish also contains dissolved or undissolved dyes, as well as a lower alkyl alcohol solvent. The printing and coatings thus produced are characterized by hardness and a high sealing stability.Type: GrantFiled: May 24, 1983Date of Patent: July 17, 1984Assignee: Rohm GmbH Chemische FabrikInventors: Wilhelm Elser, Manfred Munzer
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Patent number: 4435531Abstract: A cellulose derivative-containing emulsion composition which is the product of emulsion polymerization of at least one ethylenically unsaturated monomer in the presence of a water-solubilized product of a cellulose derivative-modified vinyl copolymer having an acid value of from about 3 to about 150, said vinyl copolymer being obtained by copolymerizing a cellulose derivative with an ethylenically unsaturated monomeric component composed of an ethylenically unsaturated acid and another ethylenically unsaturated monomer.Type: GrantFiled: August 2, 1982Date of Patent: March 6, 1984Assignee: Kansai Paint Co., Ltd.Inventors: Yasuharu Nakayama, Kenji Yamamoto, Toshiki Komatsuzawa, Hajime Sukejima, Kazuo Nomoto
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Patent number: 4428776Abstract: Semipermeable membranes prepared from at least one cellulosic polymer, such as cellulose triacetate, and containing at least one silicon compound, such as tetraethoxy silane, are useful for the separation of various gaseous mixtures into their constituent parts, such as separating natural gas into enriched fractions of carbon dioxide and methane.Type: GrantFiled: June 23, 1982Date of Patent: January 31, 1984Assignee: The Standard Oil CompanyInventor: George S. Li
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Patent number: 4397971Abstract: A process for the production of a thermoplastically processible polymer granulate or powder containing from 0.01 to 50%, by weight, of burr-shaped or fibrous, doped polyacetylene, in which a plastics material and the doped polyacetylene particles are mixed in the presence of an inert suspending liquid and said liquid is removed.Type: GrantFiled: March 29, 1982Date of Patent: August 9, 1983Assignee: Bayer AktiengesellschaftInventors: Jurgen Hocker, Rolf Dhein
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Patent number: 4389503Abstract: The present invention relates to non-pigmented jet ink compositions and to a method of producing opaque coded messages therewith. The compositions comprise, on a weight basis, between 2 and 15% of a gellable cellulose ester having a hydroxyl content of from 2 to 8%, from 1.5 to 15% of a binding agent selected from the group consisting of alkali soluble rosin type and maleic type resins, polyvinyl acetate resins, and acrylic resins, and a solvent blend, the blend consisting essentially of an organic solvent system and a non-solvent, said non-solvent comprising from 2 to 10% by weight of the ink compositions. Preferred solvents are methanol, acetone, methyl ethyl ketone and ethyl acetate, while the preferred non-solvent is water. Upon evaporation of the solvent blend, the resultant dry films scatter light incident thereto whereby the opaque images are produced. In a particularly preferred embodiment, a hygroscopic salt is included in the composition as an opacity enhancement agent.Type: GrantFiled: April 28, 1982Date of Patent: June 21, 1983Assignee: American Can CompanyInventors: Dorothy Maxwell, David A. Fell
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Patent number: 4381372Abstract: Polymers and oligomers of the formula ##STR1## are useful as ultraviolet light stabilizers for various polymers, especially polyolefins.Type: GrantFiled: April 8, 1981Date of Patent: April 26, 1983Assignee: American Cyanamid CompanyInventor: Frank F. Loffelman
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Patent number: 4357267Abstract: Transparent thermoplastic moulding compositions having improved mechanical properties consist essentially of a cellulose ester of aliphatic C.sub.1 -C.sub.5 -carboxylic acids and a graft copolymer of an ethylene vinyl ester copolymer having grafted thereon polymerized units of vinyl esters and/or alkyl esters of acrylic and/or methacrylic acid and, optionally, C.sub.2 -C.sub.4 -olefins.Type: GrantFiled: December 11, 1980Date of Patent: November 2, 1982Assignee: Bayer AktiengesellschaftInventors: Heinrich Alberts, Winfried Fischer, Friedemann Muller, Horst Peters, Christian Leuschke, Hans-Peter Baasch
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Patent number: 4352901Abstract: The present invention relates to non-pigmented jet ink compositions and to a method of producing opaque coded messages therewith. The compositions comprise, on a weight basis, between 2 and 15% of a gellable cellulose ester having a hydroxyl content of from 2 to 8%, from 1.5 to 15% of a binding agent selected from the group consisting of alkali soluble rosin type and maleic type resins, polyvinyl acetate resins, and acrylic resins, and a solvent blend, the blend consisting essentially of an organic solvent system and a non-solvent, said non-solvent comprising from 2 to 10% by weight of the ink composition. Preferred solvents are methanol, acetone, methyl ethyl ketone and ethyl acetate, while the preferred non-solvent is water. Upon evaporation of the solvent blend, the resultant dry films scatter light incident thereto whereby the opaque images are produced. In a particularly preferred embodiment, a hygroscopic salt is included in the composition as an opacity enhancement agent.Type: GrantFiled: August 14, 1980Date of Patent: October 5, 1982Assignee: American Can CompanyInventors: Dorothy Maxwell, David A. Fell
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Patent number: 4343727Abstract: This invention covers a shoe sole composition compounded from polyvinyl chloride and organic cellulosic flock, and the shoe sole product produced therefrom.Type: GrantFiled: October 24, 1979Date of Patent: August 10, 1982Assignee: Reichhold Chemicals IncorporatedInventor: Arnold Cohen
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Patent number: 4332917Abstract: Method for preparing a polymer alloy which is stable and homogeneous up to high temperatures, from component (a) one or more polymers of high molecular weight, having anhydride groups and component (b) one or more polymers of high molecular weight, having groups which have the ability to interact with hydrogen atoms to form hydrogen bonds, wherein first a solution of component (a) is prepared in an organic solvent, to which solution then component (b) is added, whereas component (a) in dissolved state is protolyzed in whole or in part, prior to or after the addition of component (b) under the action of protolyzing agents, whereupon the solvent is removed; together with the formed products obtained from such a polymer alloy, such as granules, fibres, foils, foam, etc.Type: GrantFiled: December 20, 1979Date of Patent: June 1, 1982Assignee: Nederlandse Centrale Organisatie voor Toegepast-Natuurwetenschappelijk OnderzoekInventors: Adolf Heslinga, Pieter J. Greidanus
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Patent number: 4325861Abstract: Water-soluble polymers are rapidly dissolved by employing a concentrate of (i) a water-soluble particulate polymer, (ii) a water-insoluble organic vehicle which is a non-solvent for the polymer, (iii) a nonionic surfactant agent having an HLB in the ranges of 3-5 and 9-13 and if necessary, a thickening agent.Type: GrantFiled: April 3, 1980Date of Patent: April 20, 1982Assignee: Union Carbide CorporationInventors: David B. Braun, Meyer R. Rosen
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Patent number: RE32261Abstract: Solid copolymers are produced by copolymerizing a mixture of: (A) at least 30% by weight of a monomer having the formula: ##STR1## wherein R.sub.1 is H or CH.sub.3 and R.sub.2 is an alkyl radical containing from 1 to 14 carbon atoms; (B) from 3 to 20% by weight of an ethylenic .alpha.,.beta. unsaturated carboxylic acid or anhydride thereof, or from 3 to 40% by weight of glycidyl acrylate or glycidyl methacrylate; and (C) from 0 to 67% by weight of a monomer copolymerizable with said monomers (A) and (B). Preferably, the mixture is first bulk-polymerized until conversion to the copolymer is from 10 to 80% by weight and the polymerization is completed by suspension-polymerization. Thermosetting solid coating compositions are produced by mixing a major proportion of a solid copolymer so produced with a minor proportion of a cross-linking compound or with an epoxy resin containing at least 2 epoxy radicals in the molecule in presence of a tertiary amine curing accelerator.Type: GrantFiled: March 19, 1979Date of Patent: October 7, 1986Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Kuniomi Hirota, Akio Masumoto, Hiroshi Ozawa, Nobuki Kobayashi, Teruo Honda