Ether Group Containing, Other Than Solely Linking Carbohydrate Groups Directly To Each Other Patents (Class 524/42)
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Patent number: 7371279Abstract: A composition comprising cellulose ether, a superplasticizer and defoamer suitable for use as an additive in extruding inorganic compositions is disclosed. The inventive composition functions as a water retention agent, plasticizer and lubricant in the extrusion of inorganic compositions. The use of the inventive composition in the extrusion of building materials leads to improved processing properties, to a higher surface quality and product properties of the extruded article.Type: GrantFiled: June 27, 2006Date of Patent: May 13, 2008Assignee: Dow Wolff Cellulosics GmbHInventors: Roland Bayer, Hartwig Schlesiger, Daniel Auriel
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Patent number: 7337587Abstract: A construction assembly includes a plurality of plaster boards, each of the plaster boards having a plaster body and at least one sheet of liner, the liner including an inner surface attached to the plaster body and an outer surface having an outer face; wherein said plaster boards are assembled creating at least one joint; and a joint-pointing coat jointing said plaster boards to form a substantially plane outer surface including the outer surface of said at least one joint and said outer surface of said liner, wherein the composition of the joint-pointing coat is adapted for the finishing of said at least one joint; wherein both the joint-pointing coat in the dry state and the outer face of the sheet of liner are adapted to form an overall surface having a substantially homogeneous coloration.Type: GrantFiled: June 1, 2004Date of Patent: March 4, 2008Assignee: Lafarge PlatresInventors: Francois Zuber, Claude Leclercq, Pascal Bourne-Chastel
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Patent number: 7335690Abstract: The present invention provides crosslinkable compositions useful in the preparation of hydrophilic gels, and are prepared from polymers having pendent hydrophilic groups, and pendant Michael donor groups, and crosslinked by polyacryl Michael acceptor compounds.Type: GrantFiled: January 25, 2005Date of Patent: February 26, 2008Assignee: 3M Innovative Properties CompanyInventors: David J. Plaut, Duane D. Fansler, Kevin M. Lewandowski, Babu N. Gaddam
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Patent number: 7276546Abstract: The invention relates to methods of making carbohydrate and polyol esters suitable for use as plasticizers for polymer compositions. The invention also relates to plasticized polymer compositions comprising such carbohydrate and polyol esters. The invention also relates to articles prepared from such plasticized polymer compositions. The invention further relates to methods of using these compositions.Type: GrantFiled: May 17, 2005Date of Patent: October 2, 2007Assignee: Eastman Chemical CompanyInventors: Charles M. Buchanan, Norma L. Buchanan, Kevin J. Edgar, Juanelle L. Lambert
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Patent number: 7138439Abstract: The present invention relates to biodegradable polymer compositions comprising poly(lactic acid) and co-polyester polymer with adipic acid mixed with organic peroxide and mineral particles. In addition, the present invention relates to products made on the basis of such compositions, such as molded and extruded articles.Type: GrantFiled: February 27, 2004Date of Patent: November 21, 2006Assignee: Biocorp North America, Inc.Inventors: Frederic Scheer, William Kelly
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Patent number: 7066996Abstract: A mixture composition of a cellulose ether made from raw cotton linters and at least one additive is used in a ready mixed joint compound composition wherein the amount of the cellulose ether in the joint compound composition is significantly reduced. When this joint compound composition is mixed with water and applied to a substrate, the water retention, sag resistance, and workability of the wet joint compound are comparable or improved as compared to when using conventional similar cellulose ethers.Type: GrantFiled: April 25, 2005Date of Patent: June 27, 2006Assignee: Hercules IncorporatedInventor: Thomas J. Podlas
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Patent number: 6977275Abstract: The invention relates to methods of making carbohydrate and polyol esters suitable for use as plasticizers for polymer compositions. The invention also relates to plasticized polymer compositions comprising such carbohydrate and polyol esters. The invention also relates to articles prepared from such plasticized polymer compositions. The invention further relates to methods of using these compositions.Type: GrantFiled: January 10, 2003Date of Patent: December 20, 2005Assignee: Eastman Chemical CompanyInventors: Charles M. Buchanan, Norma L. Buchanan, Kevin J. Edgar, Juanelle L. Lambert
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Publication number: 20040259983Abstract: An additive for a cement composition comprising:Type: ApplicationFiled: March 11, 2004Publication date: December 23, 2004Inventors: Satoshi Okazawa, Minoru Yaguchi, Tsutomu Yamakawa, Yoshiaki Sasage
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Publication number: 20040225035Abstract: The present invention encompasses cellulose ether blends comprisingType: ApplicationFiled: January 30, 2004Publication date: November 11, 2004Inventors: Hartwig Schlesiger, Erik-Andreas Klohr, Wolfgang Dannhorn, Hans-Jurgen Juhl, Arne-Henning Kull, Gunter Weber, Peter Wolbers
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Patent number: 6800593Abstract: Disclosed is a hydrophilic, water soluble polymer concentrate for addition to aqueous liquids to enhance the properties thereof, particularly to increase the viscosity or decrease the fluid loss of well drilling and servicing fluids, the concentrate comprising a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, the water soluble polymer, and a stabilizing agent comprising one or more acids in an amount from about 0.001% to about 1.5%, one or more anionic surfactants in an amount from about 0.001% to about 1.0%, one or more nonionic surfactants in an amount from 0.001% to about 0.625% and, from about 0% to about 0.75% of one or more water soluble organic liquids, wherein the total concentration of the stabilizing agent is from about 0.1% to about 2.5%, these percentages being based on the weight of the concentrate.Type: GrantFiled: June 19, 2002Date of Patent: October 5, 2004Assignee: Texas United Chemical Company, LLC.Inventors: James W. Dobson, Jr., Shauna Leigh Hayden, Carolina Trejo Rangel
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Publication number: 20040092625Abstract: A gypsum-based composite structure is prepared from a slurry comprising a mixture of calcium sulfate hemihydrate, a cellulose ether additive other than CMC and an amount of water that is sufficient to form a slurry. The calcium sulfate hemihydrate is hydrated by the water forming a wallboard core reinforced by the cellulose ether additive. The concentration, viscosity grade and degree of substitution of the cellulose ether are selected to give the composite improved nail pull resistance and greater flexural strength.Type: ApplicationFiled: May 27, 2003Publication date: May 13, 2004Applicant: Innovative Construction and Building MaterialsInventors: Jacob Freas Pollock, Christopher D. Tagge, Lennard Torres, David S. Soane
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Publication number: 20040092624Abstract: A reinforced wallboard core is prepared from a slurry comprising a mixture of &bgr;-calcium sulfate hemihydrate, a cellulose ether additive other than CMC and an amount of water that is sufficient to form a slurry and resulting in a wallboard density of less than 0.8 g/cc. The &bgr;-calcium sulfate hemihydrate is hydrated by the water forming a wallboard core reinforced by the cellulose ether additive. The cellulose ether, having a molecular weight of at least about 20,000 and a viscosity grade of at least about 100 cps, is selected to give the reinforced wallboard core improved nail pull resistance and greater flexural strength than unreinforced wallboard of the same density. The reinforced wallboard core may be used for reduced-paper wallboard and/or for lightweight wallboard, for example.Type: ApplicationFiled: January 23, 2003Publication date: May 13, 2004Applicant: Innovative Construction and Building MaterialsInventors: Christopher D. Tagge, Jacob Freas Pollock, Lennard Torres, David S. Soane
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Patent number: 6667354Abstract: Stable and environmentally friendly suspensions of solid particulates are provided through the addition of such solid particulates to a suspension medium which is comprised of a liquid carrier, a liquid carrier soluble resin, an organophyllic clay, and an activator wherein said liquid carrier is a carboxylic acid ester, preferably 2-ethylhexyl oleate, said liquid carrier soluble resin is selected from the group consisting of styrene-isoprene copolymers, styrene ethylene-propylene block copolymers, styrene isobutylene copolymers, styrene butadiene copolymers, polybutylene, polystyrene, polyethylene-propylene copolymers, methyl methacrylate and mixtures thereof, said organophyllic clay is one of kaolinite, halloysite, vermiculite, chlorite, attapullgite, smectite, montmorillonite, bentonite, hectorite, and mixtures thereof and said activator is an alcohol of the formula ROH wherein R is an alkyl group of 1 to 10 carbon atoms.Type: GrantFiled: July 18, 2000Date of Patent: December 23, 2003Assignee: Phillips Petroleum CompanyInventors: Kelly B. Fox, Alvin Evans, Jr.
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Patent number: 6515049Abstract: The present invention relates to water-soluble ionic cellulose ethers from the group of the hydroxyalkylcelluloses which are substituted by on average from 0.001 to 1.0 alkyl group per anhydroglucose unit and which carry from 0.01 to 0.1 sulfoalkyl group per anhydroglucose unit, to processes for preparing them and to the use of water-soluble ionic cellulose ethers from the group of the hydroxyalkylcelluloses which are substituted by on average from 0.001 to 1.0 alkyl group per anhydroglucose unit and which carry from 0.01 to 0.4 sulfoalkyl group per anhydroglucose unit as protective colloids in polymerizations.Type: GrantFiled: October 26, 1999Date of Patent: February 4, 2003Assignee: Clariant GmbHInventors: Reinhard Doenges, Horst Wurm
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Patent number: 6506824Abstract: Biodegradable thermoplastic compositions comprising a starch component, a cellulose ester or ether, a plasticizer for the starchy phase and of the cellulose and derivatives, and a compatibilizer agent selected from polymers compatible with the cellulose and or starchy component, grafted with aliphatic or polyhydroxilated chains; copolymers obtained from hydroxy acids and/or diamines with 2-24C and aliphatic or aromatic diisocyanates; copolymers obtained from aliphatic polyesters, polyureas and polyalkylene glycols and aliphatic or aromatic diisocyanates; copolymers obtained from polymers compatible with cellulose ester or ethers and/or the starchy component by grafting starch soluble polyols; polymer capable of complexing starch; starch compatible polyols.Type: GrantFiled: October 17, 1997Date of Patent: January 14, 2003Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Vittorio Bellotti, Roberto Lombi, Gabriele Perego
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Patent number: 6489406Abstract: The invention relates unsaturated polyester resins for the manufacture of subzero flexible, weather-resistant products. The liquid unsaturated polyester resin comprises a linear unsaturated polyester obtained by reacting 5-30 mol % of one or more ethylenically unsaturated dicarboxylic acids (A), 20-45 mol % of one or more other aliphatic or aromatic acids (B) and 40-60 mol % of two or more polyhydric alcohols and 30-60 wt % of one or more reactive monomers. The linear unsaturated polyesters have a cone and plate viscosity (I.C.I.) of 2 ps/125° C.-20 ps/125° C. and a molecular weight Mw of 20,000-100,000. The invention also relates to a process for the manufacture of such unsaturated polyester resins and to the use of them in applications wherein good adhesion to supporting material and flexibility at ambient and especially at low temperatures are needed.Type: GrantFiled: March 29, 2001Date of Patent: December 3, 2002Assignee: Ashland Inc.Inventors: Paul Mahbub, Karri Airola, Eija Valtonen
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Patent number: 6482876Abstract: The invention relates to an agglomerate containing at least one of the following water-soluble or water-dispersible materials as a bonding base polymer: carboxylized and/or alkoxylized starch, cellulose ether and fully synthetic vinyl polymers and/or polyacrylates. The agglomerate is characterized in that it contains a blasting agent which produces a high swelling pressure, but, advantageously, does not gel. The agglomerate can have a regular geometric form or not. Its weight should be between 0.5 and 500 g. The agglomerate is used in particular in the production of lump-free paste.Type: GrantFiled: March 15, 2000Date of Patent: November 19, 2002Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Sandra Witt-Nuesslein, Werner Haller, Bernhard Schoettmer, Monika Boecker, Wolfgang Seiter, Ingo Hardacker, Heinz-Peter Hoffmann
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Publication number: 20020045684Abstract: A thickener based vinyl alcohol copolymers and cellulose ethers, containingType: ApplicationFiled: August 1, 2001Publication date: April 18, 2002Applicant: Wacker-Chemie GmbHInventors: Andreas Bacher, Werner Bauer, Ulf Dietrich, Bernd Kayser, Marion Schmitz, Harald Zeh, Theo Mayer, Hardy Herold
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Patent number: 6362238Abstract: The present invention relates to associative cellulose ethers with improved thickening effects, especially in paint. The improvement depends on the presence of a hydrophobic modifying group of the general formula where R is an aliphatic group of 12-22 carbon atoms and n is a number from 3 to 7. The DS of the hydrophobic group is 0.003 to 0.012.Type: GrantFiled: March 15, 2001Date of Patent: March 26, 2002Assignee: Akzo Nobel N.V.Inventor: Leif Karlson
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Patent number: 6284819Abstract: The present invention provides a recording medium comprising a substrate having a glossy coating thereon, wherein the glossy coating comprises a binder and first and second groups of particles, wherein: (a) the first group comprises metal oxide particles, wherein the metal oxide particles are aggregates of smaller, primary particles, (b) the mean diameter of the primary particles is less than about 100 nm, (c) the mean diameter of the aggregates is from about 100 nm to about 500 nm, (d) the mean diameter of the particles in the second group is less than about 50% of the mean diameter of the aggregates in the first group, and (e) the ratio of particles in the first group to particles in the second group is from about 0.1:1 to about 10:1 by weight. The glossy coating of the inventive recording medium has an excellent rate of liquid absorption, a relatively high liquid absorption capacity, excellent adhesiveness, and a non-brittle, crack-resistant, glossy surface.Type: GrantFiled: July 1, 1999Date of Patent: September 4, 2001Assignee: Cabot CorporationInventors: Michael S. Darsillo, David J. Fluck, Rudiger Laufhutte
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Patent number: 6225381Abstract: An inkjet printing coating compositions and recording sheets having printable coating compositions on substrates which are suitable for photographic quality prints by inkjet printing technology, such as thermal and piezo. The recording sheet which comprises a substrate and a dried coating composition on the substrate, which coating composition comprises either (i) a hydrophilic or amphiphilic polyether polyurethane plus one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers or (ii) cellulose acetate trimellitate plus optionally one or more polymers selected from the group consisting of cellulose ester polymers, cellulose ether polymers and vinyl polymers; a quaternary ammonium compound; a metal salt chelating agent; and a microcrystalline filler drying agent.Type: GrantFiled: April 9, 1999Date of Patent: May 1, 2001Assignee: AlliedSignal Inc.Inventors: Jyoti Sharma, David James Gibboni, Elizabeth Joyce Lanigan
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Patent number: 6214907Abstract: A biologically degradable polymer mixture is proposed which consists essentially of starch and at least one hydrophobic polymer. The hydrophobic polymer is in this connection at least substantially biologically degradable and thermoplastically processable and the mixture with the starch comprising a polymer phase mediator or a macromolecular dispersing agent so that the starch is present in the mixture as disperse phase with the hydrophobic polymer as continuous phase, and the phase mediator or the dispersing agent is responsible for the molecular coupling of the two phases. As starch there is preferably used thermoplastic starch which has been prepared substantially with the exclusion of water by means of sorbitol or glycerol. The production of the biologically degradable polymer mixture is also carried out substantially with the exclusion of water.Type: GrantFiled: September 16, 1998Date of Patent: April 10, 2001Assignee: Bio-Tec Biologische Naturverpackungen GmbH & Co. KGInventor: Ivan Tomka
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Patent number: 6166119Abstract: A cement pumpability-enhancing additive which confers good pumpability on cementitious compositions such as concrete consists essentially of(a) polyethylene glycol;(b) diethylene glycol monobutyl ether and/or a derivative thereof;(c) polysaccharide; and(d) a thickening polymer selected from the group consisting of polyacrylic acid derivatives, polyacrylic amide derivatives, cellulose ethers, polyphenyl ethers and polyalkylene glycol fatty acid esters;the weight solids proportions of (a), (b), (c), and (d) in the additive being respectively 5-55%, 10-80%, 1-20% and 1-20%. The additive is preferably used with a cement dispersing agent.Type: GrantFiled: April 14, 1999Date of Patent: December 26, 2000Assignee: MBT Holding AGInventors: Shigemi Matsuo, Hidenori Nagamine, Akira Ota
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Patent number: 6121439Abstract: A coating composition is composed of a water-soluble polysaccharide composition comprising at least one hydrophobic group selected from aryl, alkyl, alkenyl, aralkyl and mixtures thereof and at least one quaternary ammonium salt group, both connected to a polysaccharide backbone by covalent bonds. This coating is used for improving the leveling of waterborne paints.Type: GrantFiled: July 27, 1998Date of Patent: September 19, 2000Assignee: Hercules IncorporatedInventor: Gijsbert Kroon
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Patent number: 6077887Abstract: An aqueous composition is described, which is characterised in that it comprises comprises a water-soluble electrolyte complex containing a combination of a water-soluble, anionic polyelectrolyte with hydrophobic groups having 6-30 carbon atoms, and a water-soluble cationic polyelectrolyte with hydrophobic groups having 6-30 carbon atoms. The polyelectrolyte composition can be used as thickening agent in water-based systems, such as paints, coating slips, cosmetics or cleaning compositions, and as water-binding agent in sanitary products, e.g. nappies, sanitary towels and the like.Type: GrantFiled: May 26, 1998Date of Patent: June 20, 2000Assignee: Akzo Nobel Surface Chemistry ABInventor: Krister Thuresson
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Patent number: 6071984Abstract: This invention relates to reinforced thermoplastic moulding compositions prepared from biodegradable polymers, for example aliphatic or polyester amides, aliphatic polyester urethanes, and to the use thereof for the production of mouldings and to the mouldings, wherein the reinforcing materials are selected from wood flour, fibres of natural origin, minerals of natural origin, cellulose and cellulose derivatives.Type: GrantFiled: June 25, 1998Date of Patent: June 6, 2000Assignee: Bayer AktiengesellschaftInventors: Ernst Grigat, Hanns Peter Muller, Wolfgang Schulz-Schlitte, Aziz El Sayed, Ralf Timmermann
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Patent number: 6063842Abstract: The present invention relates to a thermal transfer ink layer composition, wherein polyvinylacetal resin and cellulose derivatives are used in a mixture for the binder in the thermal transfer ink layer composition of the sublimation thermal transfer ink ribbon, or the another type of a binder is mixed into the mixture of polyvinylacetal resin and cellulose derivatives and so used therein. As a result, the adhesion between the thermal transfer ink layer and substrate film, and the gradation property of printed images are improved as compared to the case in which the respective binders are used individually. More particularly, the present invention relates to the thermal transfer ink layer composition of the sublimation thermal transfer ink ribbon, which can yield high quality images by means of the aforementioned improvements.Type: GrantFiled: May 11, 1998Date of Patent: May 16, 2000Assignee: Hansol Paper Co., Ltd.Inventors: Oh-Seung Kwon, Jeong-Seok Seo, Yong-Cheol Shin, Tae-Woon Cha, Eun-Seong Kim
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Patent number: 6054511Abstract: Hydroxyethylcellulose (HEC), hydrophobically modified hydroxyethylcellulose (HMHEC), hydroxypropylcellulose (HPC), methylhydroxypropylcellulose (MHPC), carboxymethylhydroxyethylcellulose (CMHEC), guar, starch, xanthan, hydroxypropylguar (HP Guar) or carboxymethylhydroxypropylguar (CMHP Guar) are stepwise or continuously reacted with hydrogen peroxide to produce aqueous compositions with a solids content greater than 5% by weight at a viscosity at 25.degree. C. below 9500 mPa.s. It is preferred to use 30-50% hydrogen peroxide to depolymerize the polysaccharide.Type: GrantFiled: January 15, 1993Date of Patent: April 25, 2000Assignee: Aqualon CompanyInventors: J David Angerer, Jashawant Jamanadas Modi, Robert C Szafranski
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Patent number: 6020405Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of the above-described inks.Type: GrantFiled: May 8, 1998Date of Patent: February 1, 2000Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 6007610Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Also, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks. Furthermore, the disclosed phase change inks inhibit corrosion of metallic internal printer parts.Type: GrantFiled: May 8, 1998Date of Patent: December 28, 1999Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 6001904Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks.Type: GrantFiled: May 8, 1998Date of Patent: December 14, 1999Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 5994530Abstract: The present invention provides certain carboxymethyl cellulose (CMC) esters of higher acids (e.g., CMC acetate propionate, CMC propionate, CMC acetate butyrate, and CMC butyrate)having specific use in aqueous dispersions useful in formulating waterborne coating compositions containing pigments, especially metallic pigments such as aluminum flakes and mica. The esters also have specific use as wetting agents and in high solids coatings.Type: GrantFiled: June 25, 1998Date of Patent: November 30, 1999Assignee: Eastman Chemical CorporationInventors: Jessica Dee Posey-Dowty, Alan Kent Wilson, Larry Gerald Curtis, Paul Michael Swan, Kab Sik Seo
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Patent number: 5989329Abstract: Water-borne paints containing reduced molecular weight polysaccharide derivatives that are resistant to enzyme hydrolysis. The water-borne paints are biostable, retaining at least about 80% of their initial viscosity 24 hours after they are inoculated with polysaccharide hydrolysis enzyme.Type: GrantFiled: November 10, 1998Date of Patent: November 23, 1999Assignee: Hercules IncorporatedInventor: Arjun Chandra Sau
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Patent number: 5973036Abstract: Phase-change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibilty, offset and pick resistance, adhesion, and other desired properties. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks.Type: GrantFiled: May 8, 1998Date of Patent: October 26, 1999Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 5922790Abstract: This invention provides esters of acetobacter acid useful as adhesion promoters for waterborne coatings compositions applied to corroded or rusty metal substrates. The esters of acetoacetic acid also function as a coalescing aid in the coating composition.Type: GrantFiled: October 6, 1997Date of Patent: July 13, 1999Assignee: Eastman Chemical CompanyInventor: Douglas Grant Atkins
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Patent number: 5879440Abstract: Water-borne paints containing reduced molecular weight polysaccharide derivatives that are resistant to enzyme hydrolysis. The water-borne paints are biostable, retaining at least about 80% of their initial viscosity 24 hours after they are inoculated with polysaccharide hydrolysis enzyme. A process for making the biostable water-borne paints has the steps: a) treating precursor polysaccharide derivative with polysaccharide hydrolysis enzyme in aqueous medium for a time sufficient to obtain reduced molecular weight polysaccharide derivative; and b) mixing the reduced molecular weight polysaccharide derivative with an effective amount of at least one other water-borne paint ingredient to obtain a water-borne paint.Type: GrantFiled: July 28, 1997Date of Patent: March 9, 1999Assignee: Hercules IncorporatedInventor: Arjun Chandra Sau
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Patent number: 5847046Abstract: A surgical bonding material includes a continuous phase and a discontinuous phase. The continuous phase is formed from a polymerizable liquid. The discontinuous phase includes particles of bioabsorbable polymer. The bonding material may be partially or completely bioabsorbable.Type: GrantFiled: March 12, 1997Date of Patent: December 8, 1998Assignee: United States Surgical CorporationInventors: Ying Jiang, Mark Roby
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Patent number: 5834533Abstract: A stable liquid suspension composition comprising a liquid carrier, a solid fatty acid or a salt thereof, and a solid particulate is disclosed wherein said liquid carrier is selected from the group consisting of oils, olefins, terpenes, glycols, esters, ethers, alcohols, and combinations of any two or more thereof and said liquid carrier, solid fatty acid or salt thereof, and solid particulate are each present in said composition in a stabilizing amount sufficient to produce a stable liquid suspension. Also disclosed is a stable liquid composition comprising a liquid carrier, an oil-soluble polymer, and a solid particulate wherein said liquid carrier is selected from the group consisting of liquid alkenes, terpenes, esters, and combinations of any two or more thereof and said liquid carrier, oil-soluble polymer, and solid particulate are each present in said composition in a stabilizing amount sufficient to effect the formation of a stable liquid suspension.Type: GrantFiled: November 20, 1996Date of Patent: November 10, 1998Assignee: Phillips Petroleum CompanyInventors: Bharat B. Patel, Marshall D. Bishop
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Patent number: 5753723Abstract: An improved denture fixative composition comprising an adhesion promoter and a highly cross-linked copolymer of a lower alkyl vinyl ether and maleic anhydride or acid is disclosed wherein at least 65.0% of the total number of initial carboxyl groups in the copolymer are reacted. The cross-linking agent employed in this invention is calcium cation and optionally up to about 30.0% of the calcium function can be replaced with other inorganic cross-linking agents or polyhydroxy compounds either singly or in combination. The adhesion promoters are chelating agents such as polycarboxylic acids, hydroxycarboxylic acids, aminocarboxylic acids, polyphosphoric acids and their alkali salts.Type: GrantFiled: July 25, 1997Date of Patent: May 19, 1998Inventors: Tiang Shing Chang, Donna Diferdinando
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Patent number: 5725648Abstract: This invention relates to paper coating compositions comprising pigment, adhesive binder and rheology modifier wherein the rheology modifier comprises at least one of a) a mixture of guar and at least one other water-soluble polymer in sufficient amount to reduce the amount of guar adsorbed onto the pigment, or b) reduced molecular weight guar. The invention also relates to processes for making coated paper using the coating compositions, and to paper coated with the coating compositions.Type: GrantFiled: September 25, 1996Date of Patent: March 10, 1998Assignee: Hercules IncorporatedInventors: Michael J. Brown, Teng-Shau Young
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Patent number: 5698612Abstract: The present invention provides thermoplastically workable and completely biodegradable moulding compositions, a process for the preparation thereof and the use thereof as biodegradable materials for the production of, for example, injection-moulded parts, films, fibres or coatings.Type: GrantFiled: December 11, 1996Date of Patent: December 16, 1997Assignee: Bayer AkteingesellschaftInventors: Joachim Simon, Hanns Peter Muller, Dirk Jacques Dijkstra, Jurgen Engelhardt, Volkhard Muller, Gunter Weber
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Patent number: 5668273Abstract: This invention provides certain carboxymethyl cellulose (CMC) esters of higher acids (e.g., CMC acetate propionate, CMC propionate, CMC acetate butyrate, and CMC butyrate). These new ether derivatives of cellulose esters exhibit solubility in a wide range of organic solvents, compatibility with a variety of resins, and ease of dispersion in a water-borne formulation and are useful in coating compositions as binder resins and theology modifiers.Type: GrantFiled: January 29, 1996Date of Patent: September 16, 1997Assignee: Eastman Chemical CompanyInventors: John Michael Allen, Alan Kent Wilson, Paul Lee Lucas, Larry Gerald Curtis
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Patent number: 5616635Abstract: The present invention discloses a multicolor paint formulation which is comprised of:(1) from about 5 to about 30 weight percent of a neutralized latex made by a method which comprises (A) free radical aqueous emulsion polymerizing at a pH of less than about 3.5 a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 45 to about 85 weight percent vinyl aromatic monomers, (b) from about 15 to about 50 weight percent of at least one alkyl acrylate monomer, and (c) from about 1 to about 6 weight percent of at least one unsaturated carbonyl compound; in the presence of about 0.5 to 4.0 phm at least one phosphate ester surfactant and in the presence of about 0.5 to 4.0 phm of at least one water insoluble nonionic surface active agent to produce a latex, and (B) neutralizing the latex with ammonia to a pH which is within the range of about 7 to about 10.5 to produce the neutralized latex;(2) from about 0.5 to about 10 weight percent of hectorite clay;(3) from about 0.Type: GrantFiled: November 27, 1995Date of Patent: April 1, 1997Assignee: The Goodyear Tire & Rubber CompanyInventor: Kantilal D. Patel
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Patent number: 5612397Abstract: The composition having wet state clarity includes an aqueous latex binder combination of polymer particles with a diameter of less than 80 nanometers and a thickener. When glitter flakes are dispersed in these novel compositions in their wet state, they glitter more than conventional glitter compositions. Thus, they are more appealing to a consumer or an artist than conventional glitter compositions that tend to be cloudy or dull in their wet state.Type: GrantFiled: December 19, 1994Date of Patent: March 18, 1997Assignee: Rohm and Haas CompanyInventors: Matthew S. Gebhard, William E. deVry, Caren A. Puschak, Anne M. Bacho, Gary R. Larson
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Patent number: 5521234Abstract: A Fluidized Polymer Suspension (FPS) thickener comprising a hydroxyethylcellulose and/or alkyl or arylalkyl hydrophobically modified hydroxyethylcellulose added continuously to an aqueous dispersion increases productivity for manufacture of aqueous coating compositions. The FPS can be stored and metered without delays associated with dry powders. A latex paint is continuously produced by simultaneously or sequentially mixing latex binder, dispersed pigment and FPS thickener along with other ingredients.Type: GrantFiled: April 29, 1994Date of Patent: May 28, 1996Assignee: Aqualon CompanyInventors: Richard G. Brown, Charles L. Burdick, Charles W. Vanderslice
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Patent number: 5504123Abstract: Cellulose ether derivatives comprising a hydrophobic substituent having an unsaturated alkyl portion are disclosed. The unsaturation in the alkyl portion of the hydrophobic substituent can promote crosslinking of the cellulose ether derivative. The cellulose ether derivatives are useful as ingredients in latex compositions. The cellulose ether derivatives can provide associative thickening and rheological properties to latex composition during storage and application. In addition, after the latex composition is applied to the surface to be coated, the cellulose ethers of the present invention can promote crosslinking of the latex film to provide a hard and durable coating. Latex paint compositions comprising the cellulose ether derivatives of the present invention are also disclosed.Type: GrantFiled: December 20, 1994Date of Patent: April 2, 1996Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Emmett M. Partan, III
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Patent number: 5466731Abstract: Fiber or film of water-absorbent water-insoluble fibrous material has a matrix of a crosslinked copolymer formed from 50 to 95% by weight of ethylenically unsaturated carboxylic monomer and 5 to 50% by weight of copolymerisable ethylenically unsaturated monomer. The matrix contains regions of a dispersed polymeric material, the matrix copolymer and the dispersed polymeric material being mutually immiscible and chemically substantially nonreactive under ambient conditions. The fiber or film can be produced by extruding a solution or dispersion of the polymeric material in a solution of the matrix copolymer in its non-crosslinked state into a gaseous environment.Type: GrantFiled: November 16, 1994Date of Patent: November 14, 1995Assignee: Courtaulds Fibres (Holdings) LimitedInventors: Paul J. Akers, William Brunskill
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Patent number: 5432213Abstract: The present invention relates to a high strength water-permeable resinous road paving composition characterized by the use of 2-20 weight parts of thermosetting resin as a binder per 100 weight parts of granular aggregate and 1-20 weight parts of cellulose or 1-30 weight parts of lignocellulose as botanical fiber or their derivatives as additives per 100 weight parts of said thermosetting resin.Another feature of the present invention is to mix certain amount of inorganic substances in fine granular or fibrous form together with said granular aggregate, thermosetting resin, cellulose or lignocellulose, or their derivatives, wherein said inorganic substance is 5-200 weight parts per 100 weight parts of said resin. Furthermore, footpath blocks or pavement of footpaths, driveways, plazas, etc. by the use of the composition of the present invention is another feature of the present invention.Type: GrantFiled: September 20, 1993Date of Patent: July 11, 1995Assignee: Samsung General Chemicals Co., Ltd.Inventors: Hyun-Don Kim, Cheon-Seok Lee, Ju-Hyun Son, Seung-Ho Jeon
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Patent number: 5432215Abstract: Building material products, such as, for example, jointing compounds, adhesives, emulsion paints, synthetic plasters, fillers and the like, comprising a mixture ofa) at least 10% by weight, in particular 10 to 99% by weight, of a water-soluble natural polymer and derivatives thereof,b) 1 to 89% by weight of an alkali metal salt or ammonium salt of a crosslinked polyacrylate which, if desired, is grafted with a starch, andc) 0 to 60% by weight of a water-soluble alkali metal salt or alkaline earth metal salt of arylsulfonic acid/formaldehyde condensation products or of a sulfo-modified melamine/formaldehyde polycondensation product.Type: GrantFiled: March 18, 1992Date of Patent: July 11, 1995Assignee: Hoechst AGInventors: Friedrich Girg, Jozef Bohme-Kovac
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Patent number: 5420180Abstract: A size for yarn which minimizes thread break is described. The size comprises an aqueous solution of (I) a polyvinyl alcohol resin, (II) a modified starch, and a water-soluble cellulose compound (III), wherein the components are related by the following equations:(I)/(II)+(III))=85/15 to 95/5, and(II)/(III)=20/80 to 80/20,while simultaneously satisfying the expressions0.27X-0.7.ltoreq.log.sub.10 Y.ltoreq.0.27X+0.6; and (1)20.ltoreq.Y.ltoreq.300; (2)(A)/(B).ltoreq.0.5 (3)where X is the solid concentration in % by weight, Y is viscosity in centipoise at 90.degree. C. and a shear rate of 10 sec.sup.-1, (A) is viscosity at 60.degree. C. and a shear rate of 10,000 sec.sup.-1 of an adjusted aqueous solution resulting from the adjustment of the viscosity to 100 centipoise at 60.degree. C. and a shear rate of 10 sec.sup.-1 with said compound ratio of each of the components kept constant, and (B) is viscosity of 100 centipoise at 60.degree. C. and a shear rate of 10 sec.sup.-1 of said adjusted aqueous solution.Type: GrantFiled: October 26, 1993Date of Patent: May 30, 1995Assignee: Kuraray Co., Ltd.Inventors: Tetsuya Katayama, Hirotoshi Miyazaki, Hitoshi Maruyama, Koji Onishi