Chlorine Or Bromine Organic Compound Containing A Bridged, Fused, Or Cycloalphatic Ring Patents (Class 524/467)
  • Patent number: 8841370
    Abstract: A rubber compound based on propylene-oxide rubber SKPO, including sulfur, stearic acid, zinc oxide, thiuram disulphide, carbon black P-803. The compound is characterized by replacement of 2-mercaptobenzothiazole (kaptax), as well as fluoroplastic F-4, with dibenzothiazyl disulfide (altax), phenyl-?-naphthylamine (neozone D), dibutoxyethyl adipate, and ultrafine polytetrafluoroethylene (UPTFE). Such replacement of ingredients allows for significant improvement of wear resistance, frost resistance, and relative elongation. Additionally, relatively less UPTFE (compared to fluoroplastic F-4) can be used to achieve similar beneficial results, significantly reducing the cost of manufacturing the material.
    Type: Grant
    Filed: May 8, 2013
    Date of Patent: September 23, 2014
    Assignees: North-Eastern Federal University, Science Inst of Oil and Gas Problems of SB RAS
    Inventors: Nataliya Nikolaevna Petrova, Viktoriya Vitalievna Portnyagina
  • Patent number: 8822587
    Abstract: A vinyl chloride-based resin emulsion obtained by using a vinyl chloride-based polymer emulsion, which is obtained by subjecting a vinyl chloride monomer (B) or a monomer mixture comprising a vinyl chloride monomer (B) and an ethylenically unsaturated group-containing monomer (C) to emulsion polymerization in the presence of (A) a styrene-acrylic acid ester oligomer and/or an acrylic acid ester oligomer, as a seed (D), and subjecting a vinyl chloride monomer (E) or a monomer mixture comprising a vinyl chloride monomer (E) and an ethylenically unsaturated group-containing monomer (F) to emulsion polymerization using the seed (D). This vinyl chloride-based resin emulsion exhibits excellent water resistance, moisture resistance, high gloss and alcohol resistance if used in a water-based ink and exhibits excellent color development properties, water resistance, moisture resistance, color visibility, high gloss and release properties if used in a recording paper.
    Type: Grant
    Filed: March 14, 2012
    Date of Patent: September 2, 2014
    Assignee: Nissin Chemical Industry Co., Ltd.
    Inventors: Yasuhiro Mitta, Yuji Gama
  • Patent number: 8557906
    Abstract: A flame-retardant composition having (a) a copolymer comprising at least about 50 wt. % of propylene-derived units, and about 5-35 wt. % of units derived from at least one of ethylene or a C4-10 alpha-olefin, wherein the copolymer has a heat of fusion of about 75 J/g or less; and (b) a flame retardant, wherein the composition satisfies the requirements of UL94 with a V2 rating.
    Type: Grant
    Filed: May 26, 2011
    Date of Patent: October 15, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Randal Howard Kerstetter, III
  • Patent number: 7470734
    Abstract: Polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of (i.) at least one compound selected from the group consisting of nitroxyl stabilizers, hydroxylamine stabilizers, nitrone stabilizers, substituted hydroxylamine stabilizers, amine oxide stabilizers, benzofuranone stabilizers, phosphite and phosphonite stabilizers, quinone methide stabilizers and monoacrylate esters of 2,2?-alkylidenebisphenol stabilizers and (ii.) at least one compound selected from the group consisting of brominated flame retardants, phosphorus containing flame retardants and inorganic flame retardants such as ammonium polyphosphate or decabromodiphenyl oxide; wherein the amount of organic or inorganic flame retardant of component (ii.) required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when component (i.) is not present.
    Type: Grant
    Filed: December 7, 2005
    Date of Patent: December 30, 2008
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Malisa V. Troutman, Ramanathan Ravichandran, Rangarajan Srinivsan, Roswell Easton King, Douglas Wayne Horsey
  • Patent number: 7405255
    Abstract: The present invention relates to solutions and/or dispersions of organic semiconductors in a solvent mixture of at least two different organic solvents, characterized in that A. Each of the solvents on its own has a boiling point of below 200° C. and a melting point of 15° C. or less, B. at least one of the solvents has a boiling point in the range from greater than 140 to less than 200° C., C. the solvents used have no benzylic CH2 or CH groups, D. the solvents used are not benzene derivatives containing tert-butyl substituents or more than two methyl substituents, and their use in printing processes for producing layers of organic semiconductors, especially for the electronics industry.
    Type: Grant
    Filed: February 2, 2006
    Date of Patent: July 29, 2008
    Assignee: Merck Patent GmbH
    Inventors: Hubert Spreitzer, Heinrich Becker, Kevin Treacher, Susanne Heun, Andreas Sauer
  • Patent number: 7230042
    Abstract: The instant invention pertains to a thermoplastic organic polymer containing a conventional flame retardant and a hydroxylamine ester, in particular a tetraalkyl piperidine hydroxylamine ester. Further aspects of the invention are the use of hydroxylamine esters as flame retardants and a method for improving flame retardancy of a thermoplastic organic polymer.
    Type: Grant
    Filed: April 10, 2003
    Date of Patent: June 12, 2007
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Michael Roth, Dirk Simon, Grant Leslie, Peter Nesvadba, Roswell Easton King, Nikolas Kaprinidis
  • Patent number: 7105589
    Abstract: The invention relates to thermoplastic molded masses, comprising A) 10 to 97 wt. % of at least one thermoplastic polyester, B) 1 to 30 wt. % of a flame-resistant agent combination with, based on 100 wt. % B), b1) 20 to 99 wt. % of a halogenated flame resistant agent, b2) 1 to 80 wt. % of a antimony oxide, C) 0.01 to 3 wt. % of at least one polyamide, D) 0.01 to 2 wt. % of at least one nigrosin, E) 0.01 to 3 wt. % of at least one anti-dripping agent and F) 0 to 70 wt. % of further adjuncts, whereby the sum of components A) to F) is 100%.
    Type: Grant
    Filed: April 22, 2003
    Date of Patent: September 12, 2006
    Assignee: BASF Aktiengesellschaft
    Inventor: Michael Geprägs
  • Patent number: 7045564
    Abstract: A flame retardant formulation which is the combination of at least (1) at least one bromine-containing polyol flame retardant formed from the reaction of (a) tetrabromophthalic anhydride, (b) an aliphatic polyol, and (c) an epoxide, and (2) at least one aliphatic diester of an alkane dicarboxylic acid, with the proviso that the formulation has a viscosity at 25° C. of about 20,000 cps or less, and a bromine content of at least about 40 wt %. A flame retardant compound formed from A) tetrabromophthalic anhydride; B) diethylene glycol; C) at least one alpha-omega alkane diol, or at least one alpha-omega alkane diol and at least one aliphatic monool; and D) at least one alkylene oxide; with the proviso that the compound has a viscosity at 25° C. of about 60,000 cps or less, and a bromine content of at least about 43 wt %. Polymer compositions formed from (a) a polyurethane or a polyisocyanurate and (b) a formulation of the invention.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: May 16, 2006
    Assignee: Albemarle Corporation
    Inventors: Elbert F. Feske, Nelson E. Clark, Arthur G. Mack, Jeffrey Todd Aplin
  • Patent number: 6953823
    Abstract: Non-asbestos elastomeric insulating materials for solid propellant rocket motors are disclosed. The insulating materials are composed of EPDM rubber, polyaramide fiber, liquid EPDM rubber, magnesium hydroxide or aluminum hydroxide, silicon dioxide, chlorinated flame retardant compound and zinc hydroxystannate. The char forming organic fiber is used to substitute asbestos in traditional insulating materials that are believed to cause serious environmental problems. These fillers in the formulation, which when combined, have a synergistic effect that reduces the ablation rate significantly. Also, use of zinc hydroxystannate to substitute Sb2O3, may further reduce density of the insulator and smoke density and smoke toxicity of exhausted gas from the rocket motor.
    Type: Grant
    Filed: May 14, 2003
    Date of Patent: October 11, 2005
    Assignee: Chung Shan Institute of Science and Technology
    Inventor: Jun-Ling Fan
  • Patent number: 6632870
    Abstract: Flame-retarded transparent plastic compositions comprising polyhalgenated trimethylphenyl indan. The polyhalogenated trimethylphenyl indan is a mixture of polyhalogenated trimethylphenyl indanes having each 3 to 9 halogen atoms. The halogen may be bromine or a mixture of bromine and chlorine. The transparent plastic is selected from polycarbonate, polymethylmethacrylate, and polystyrene. The polyhalogenated trimethylphenyl indan is present in an amount of up to about 40% by weight. The transparent plastic flame-retarded material is prepared by mixing the plastic matrix with a flame-retardant effective amount of a polyhalogenated trimethylphenyl indan.
    Type: Grant
    Filed: November 29, 2000
    Date of Patent: October 14, 2003
    Assignee: Bromine Compounds Ltd.
    Inventors: Ita Finberg, Lev Utevski
  • Publication number: 20030004252
    Abstract: The flame retardant additive compositions comprise (a) one or more bromocycloaliphatic flame retardants; (b) one or more bromoaromatic flame retardants; and (c) one or more synthetic zeolites. Flame retardant polymer compositions comprising at least one thermoplastic polymer such as HIPS with which has been blended, singly and/or in one or more combinations, a flame retardant amount of at least (a), (b), and (c) have a very desirable balance of properties.
    Type: Application
    Filed: May 18, 2001
    Publication date: January 2, 2003
    Inventor: Susan D. Landry
  • Patent number: 6489390
    Abstract: The flame retardant additive compositions comprise (a) one or more bromocycloaliphatic flame retardants; (b) one or more bromoaromatic flame retardants; and (c) one or more synthetic zeolites. Flame retardant polymer compositions comprising at least one thermoplastic polymer such as HIPS with which has been blended, singly and/or in one or more combinations, a flame retardant amount of at least (a), (b), and (c) have a very desirable balance of properties.
    Type: Grant
    Filed: May 18, 2001
    Date of Patent: December 3, 2002
    Assignee: Albemarle Corporation
    Inventor: Susan D. Landry
  • Publication number: 20010021742
    Abstract: Flame-retarded transparent plastic compositions comprising polyhalgenated trimethylphenyl indan. The polyhalogenated trimethylphenyl indan is a mixture of polyhalogenated trimethylphenyl indanes having each 3 to 9 halogen atoms. The halogen may be bromine or a mixture of bromine and chlorine. The transparent plastic is selected from polycarbonate, polymethylmethacrylate, and polystyrene. The polyhalogenated trimethylphenyl indan is present in an amount of up to about 40% by weight. The transparent plastic flame-retarded material is prpared by mixing the plastic matrix with a flame-retardant effective amount of a polyhalogenated trimethylphenyl indan.
    Type: Application
    Filed: November 29, 2000
    Publication date: September 13, 2001
    Inventors: Ita Finberg, Lev Utevski
  • Patent number: 6096818
    Abstract: A polyester-type resin composition which has sufficient anti-static property and flame-retardant property, in addition to maintaining mechanical strength and thermal resistance and which is useful for, in particular, electrical and electronic mechanical parts field. The flame-retardant anti-static polyester-type resin composition of the present invention comprises 100 parts by weight of a thermoplastic polyester (A), from 1 to 35 parts by weight of a bromine-type flame-retardant (B), from 0.1 to 5 parts by weight of an antimony compound (C) and from 3 to 12 parts by weight of conductive carbon black (D), wherein the Br/Sb weight ratio in said polyester-type resin composition is in a range from 5.5/1 to 35.0/1. Moreover, a reinforcing filler (E), a crystallizing accelerator (F) and a multifunctional compound (G) can be added in further to the said polyester-type resin composition.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: August 1, 2000
    Assignee: Kaneka Corporation
    Inventors: Misuzu Nakaura, Kimihiko Nakano, Kazushi Hirobe
  • Patent number: 6008283
    Abstract: Flame retardants comprising oligomeric bromine-containing compounds comprising aryl groups that are connected by aliphatic chains are described. Flame retardant compositions comprising the flame retardants of the present invention and flame retardant aids are also described. Polymeric compositions comprising the flame retardants of the present invention optionally combined with a flame retardant aid, along with a method of fireproofing a material, are further described.
    Type: Grant
    Filed: March 19, 1998
    Date of Patent: December 28, 1999
    Assignee: Great Lakes Chemical Corporation
    Inventors: Richard S. Rose, Gurudas Zingde, David M. Hemmerly
  • Patent number: 5869560
    Abstract: Materials not releasing gaseous organic materials during use are used as a dry-type sealing material such as a gasket disposed upon mounting an air filter to an opening of a ceiling or the like, a wet-type sealing material filled and used in a gap for connecting wall materials or partitionings, a vinyl chloride sheet or a vinyl chloride cloth as a facing material for walls and floors. Specifically, a carboxylic acid ester having a molecular weight of not less than 400 is used as a plasticizer, a phenolic compound having a molecular weight of not less 300 is used as an antioxidant, an aliphatic hydrocarbon having not less than 19 carbon atoms (for example, microcrystalline wax) is used as a lubricant, and an alkylamine ethylene oxide adduct having a molecular weight of not less than 350 is used as an antistatic agent.
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: February 9, 1999
    Assignee: Taisei Corporation
    Inventors: Sadao Kobayashi, Masayuki Imafuku, Yoshihide Wakayama
  • Patent number: 5679736
    Abstract: Novel fire retardant compounds are disclosed, which are poly-halogenated TMPI and MPI compounds containing three or more halogen atoms per molecule. A process for the preparation of these compounds and polymeric compositions containing them are also described.
    Type: Grant
    Filed: May 17, 1993
    Date of Patent: October 21, 1997
    Assignee: Bromine Compounds Limited
    Inventor: Leonard Shorr
  • Patent number: 5674972
    Abstract: This invention relates to polyamide-based formulations flame retarded with synergized brominated flame retardants and having good thermal stability.
    Type: Grant
    Filed: July 27, 1995
    Date of Patent: October 7, 1997
    Assignee: Albemarle Corporation
    Inventors: Luc Van Wabeeke, Daniel De Schryver
  • Patent number: 5593619
    Abstract: This invention relates to compositions containing improved granulated hexabromocyclododecane flame retardant products, flame retardant formulations containing products, and to a process for forming the improved granulated flame retardant products, wherein the granulated product is characterized as having a friability loss of less than about 8 percent.
    Type: Grant
    Filed: March 16, 1995
    Date of Patent: January 14, 1997
    Assignee: Albemarle Corporation
    Inventors: Scott A. Bottelberghe, Dustin H. Thomas, Terry M. Shurtleff, Roland G. Poertner
  • Patent number: 5476893
    Abstract: The invention relates to the use of nucleus-brominated phthalic acid derivatives, optionally in combination with polyalkylene oxides corresponding to formula (V) ##STR1## in which R is H, C.sub.1-6 alkyl, tetrahydropyranyl or a silyl group,R' is H or C.sub.1-6 alkyl andx is an integer of 1 to 100,for stabilizing thermoplastic polycarbonates against the effect of .gamma.-rays.
    Type: Grant
    Filed: September 21, 1993
    Date of Patent: December 19, 1995
    Assignee: Bayer Corporation
    Inventors: Charles Lundy, Ulrich Grigo, Alexa Sommer, Klaus Horn, Klaus Sommer, Arno Becker
  • Patent number: 5395874
    Abstract: A flame retardant resin composition which includes 100 weight parts of a rubber-reinforced styrene-based resin, 2.about.35 weight parts of an epoxy-oligomer of tetrabromobisphenol-A (A1), 2.about.35 weight parts of bis-(tribromophenoxy)ethane (A2), 1.about.15 weight parts of antimony trioxide (B), and 0.1.about.10 weight parts of chlorinated polyethylene (C), wherein the total of the above (A1), (A2), (B) and (C) are 8.about.50 weight parts and the weight ratio of (A1)/(A2) is 10/90.about.75/25. The composition of the present invention has well-balanced flame retardance and impact resistance.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: March 7, 1995
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Ikuhiro Mishima, Rika Munakata, Mamoru Ishida
  • Patent number: 5326797
    Abstract: A roofing system incorporates a fire resistant asphalt composition comprising a thermoplastic elastomer modified bitumen, a filler, a brominated diphenyl ether, antimony oxide, and zinc borate. The asphalt composition is utilized with and impregnated into at least one layer of fiberglass or polyester mat. Preferably at least two layers are utilized wherein an upper layer is a fiberglass mat and a lower layer is a polyester mat, both mat layers being impregnated with the composition. In its preferred formulation, the asphalt composition comprises, in weight percent, about 30% to 90% bitumen, about 4% to 16% styrene-butadiene-styrene copolymer, about 10% to 40% filler, and up to about 20% each of the brominated diphenyl ether, the antimony oxide, and the zinc borate. The preferred brominated diphenyl ether is decabromodiphenyl ether.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: July 5, 1994
    Assignee: GS Roofing Products Company, Inc.
    Inventors: Harold Zimmerman, David Ploense, Robert Lilleston, Mario Butera
  • Patent number: 5281648
    Abstract: The impact strength of articles made from a flame-retarded formulated ABS resin containing an impact modifier is increased by forming a concentrate or masterbatch containing the flame retardant and impact modifier, blending the concentrate with ABS resin and extruding the resultant blend.
    Type: Grant
    Filed: August 3, 1992
    Date of Patent: January 25, 1994
    Assignee: Ethyl Corporation
    Inventors: David K. Doucet, Janet F. Jones, Susan D. Landry, F. Alexander Pettigrew, Jon S. Reed, James E. Torres
  • Patent number: 5280050
    Abstract: A thermoplastic polycarbonate molding composition which is rendered resistant to deterioration induced by exposure to gamma radiation is disclosed. The composition is imparted an improved degree of color stability upon the incorporation of a minor amount of a poly(alkylene oxide) oligomer and a halogenated aromatic acid derivative therewith. In addition, the composition is characterized by its low initial color and the small change in its yellowness index after a waiting period of several weeks.
    Type: Grant
    Filed: May 19, 1992
    Date of Patent: January 18, 1994
    Assignee: Miles Inc.
    Inventors: Douglas G. Powell, Sivaram Kirshnan
  • Patent number: 5116898
    Abstract: A flame retardant polypropylene based formulation which contains polypropylene and a flame retardant amount of decabromodiphenyl oxide and a polybrominated cycloalkane having an 8 to 12 carbon atom ring and at least 4 ring-attached bromine atoms.
    Type: Grant
    Filed: September 17, 1990
    Date of Patent: May 26, 1992
    Assignee: Ethyl Corporation
    Inventor: Robert A. Schleifstein
  • Patent number: 5086098
    Abstract: Flame retardant compositions are provided containing at least one ester of a polyhaloaromatic acid and at least one polyolefin resin. The compositions may also contain one or more brominated and/or chlorinated compounds to provide additional flame retardancy, and other resins or engineering thermoplastics may be blended with the polyolefin. In addition to providing flame retardancy, the polyhaloaromatic acid esters are effective as processing and compatibilizing aids for the resin, and may also function as tackifiers, mold release agents, plastisole, adhesives, plasticizers, polymer additives, and aids in preventing melt fracture.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: February 4, 1992
    Assignee: Atochem North America, Inc.
    Inventors: Joseph M. Bohen, Gerald H. Reifenberg
  • Patent number: 5079283
    Abstract: A flame-retardant polypropylene composition comprises a modified polypropylene-based polymer, antimony oxide or sodium antimonate, and a halogenated organic compound or, in lieu thereof, a phosphorous-containing compound. The polypropylene-based polymer is modified in the presence of a free-radical generator source which typically is an organic peroxide so that it has a narrow polydispersity range, improved flow, and lower compounding and molding temperatures so that temperature-sensitive components are protected from thermal degradation. The modification of the polypropylene-based polymer generally occurs in situ in the processing apparatus and the composition can also contain various fillers, fibers, and the like.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: January 7, 1992
    Assignee: Ferro Corporation
    Inventors: Neil A. Burditt, Deenadayalu Chundury
  • Patent number: 5059650
    Abstract: A process for the preparation of flameproofed polystyrene whicha) contains halohydrocarbons as flameproofing agents and which additionally contains one or more agents from the group ofb) synergists for the flameproofing agent,c) stabilizers,d) antioxidants ande) additivesby mixing polystyrene with one or more of agents a) to e) in a plurality of stages, wherein in a first stage the flameproofing agent a) and the entire amount or a proportion of the stabilizers c) are premixed at up to 100.degree. C. in a mixing apparatus and this premix is then, in a second stage, mixed with the other agents, in a continuously operated single-screw or twin-screw extruder or a kneader of conventional construction, in such a manner that, viewed in the conveying direction of the extruder, first the premix, with or without other agents, is continuously fed in and thereafter, in the further mixing zones, a melt of a polystyrene resin, which has been substantially freed from monomers and solvents and is at from 200.degree. to 250.
    Type: Grant
    Filed: September 7, 1988
    Date of Patent: October 22, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Goettsch, Hubert Kindler, Norbert Moedersheim, Guenther Rudolph
  • Patent number: 5041479
    Abstract: A process for dispersing one or more powdered ignition resistant or flame retardant additives into carbonate polymers which comprises the steps of preparing a base concentrate having about 5 to about 50 weight per cent of said additives by blending said additives with a carbonate polymer having a melt flow rate from about 3 to about 20, pelletizing said base concentrate having said ignition resistant additive dispersed therein, dry blending said concentrate pellets with carbonate pellets having a melt flow rate from about 1 to about 80 whereby said polymer/concentrate blend has an amount of said additive dispersed therein effective to render said blend ignition resistant, and pelletizing or molding said carbonate polymer/concentrate blend. The use of this method gives ignition resistant carbonate polymers with improved impact properties as measured by Izod impact tests.
    Type: Grant
    Filed: August 24, 1989
    Date of Patent: August 20, 1991
    Assignee: The Dow Chemical Company
    Inventor: Samuel A. Ogoe
  • Patent number: 5015685
    Abstract: The novel compound 5,6,7,8-tetrabromo-1,2,3,4-tetrahydro-naphthalene (tetrabromotetralin) of the formula: ##STR1## was prepared using 1,2,3,4-tetrahydro-naphthalene as the starting compound. Tetrabromotetralin was employed to prepare flame-retardant plastic compositions.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: May 14, 1991
    Assignee: Bromine Compounds Ltd.
    Inventors: Leonard M. Shorr, Michael Peled
  • Patent number: 4963606
    Abstract: This invention relates to a styrenic polymer-based thermoplastic formulation containing a brominated cycloaliphatic flame retardant and a thermal stabilizer system comprising an organotin stabilizer, a hindered phenolic antioxidant and, optionally, a polyhydroxy aliphatic compound.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: October 16, 1990
    Assignee: Ethyl Corporation
    Inventor: Robert A. Schleifstein
  • Patent number: 4952624
    Abstract: The invention relates to mixtures of polyarylene sulfides (PAS), preferably polyphenylene sulfide (PPS), and pyrenes. The mixtures show reduced radical formation under highly accelerated weathering conditions (UV irradiation).
    Type: Grant
    Filed: August 3, 1989
    Date of Patent: August 28, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Burkhard Kohler, Gerhard Heywang, Eberhard Zirngiebl
  • Patent number: 4933412
    Abstract: This invention relates to a flame retardant for synthetic fiber substrates and a method of imparting flame resistance to such substrates using the flame retardant. The flame retardant of this invention comprises 75 to 95 weight parts of a hexabromocyclododecane compound having a melting point not less than 195.degree. C. and 25 to 5 weight parts of a hexabromocyclododecane compound having a melting point less than 160.degree. C., which hexabromocyclododecane compounds are available on bromination of trans-trans-cis-cyclododecatriene. This flame retardant imparts excellent flame resistance to synthetic fiber substrates. Moreover, when a synthetic fiber substrate is dyed using a dye bath containing this flame retardant and a dye, the soiling of the substrate and dyeing equipment is kept at the minimum.
    Type: Grant
    Filed: February 10, 1989
    Date of Patent: June 12, 1990
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Etsuo Ito, Masanari Matsumura, Kazuhiko Ishihara, Toshiaki Doyama
  • Patent number: 4885318
    Abstract: Flame retardant compositions comprise linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon and a minor quantity, relative to the polymer, of certain flame retardants containing an organo halide.
    Type: Grant
    Filed: March 31, 1989
    Date of Patent: December 5, 1989
    Assignee: Shell Oil Company
    Inventors: Richard L. Danforth, Darlene G. Smith
  • Patent number: 4842781
    Abstract: Disclosed is a colored polarizing film having excellent durability which comprises (a) an organic polymer film or sheet and (b) at least one dichroic dye having an azo, anthraquinone, thioindigo, perylene or phthalone structure containing no water-soluble group. Also disclosed is a method of making a colored polarizing film using an organic polymer film or sheet formed of a polyamide or polyester resin, which comprises the steps of (a) blending (preferably, dry blending) a dichroic dye with the resinous polymer in advance, (b) melting the resulting blend and forming it into a film, and then (c) stretching the film in at least one direction.
    Type: Grant
    Filed: January 11, 1988
    Date of Patent: June 27, 1989
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tsutomu Nishizawa, Yasuyuki Yamada, Junichi Fujio, Shin Hosonuma
  • Patent number: 4810742
    Abstract: UV stable, impact resistant, flame retarded thermoplastic compositions are obtained by compounding ABS with aliphatic resin, Diels-Alder adduct of 2 moles of chlorocyclopentadiene and 1 mole of cyclooctadiene (commonly known as Dech Plus), antimony oxide and optionally with nitrile rubber and/or surfactant. Such compositions consist essentially by weight of from about 0.5 to about 10% of aliphatic resin, from 0% to about 5% nitrile rubber, from 0% to about 5% surfactant, from about 14% to about 30% Dech Plus, from about 4% to about 20% antimony oxide and from about 50% to about 80% ABS. The ABS constituent has an Izod Impact Strength of at least 1.5 foot-pounds per inch; the amounts of said aliphatic resin, said nitrile rubber and said surfactant being such as to provide an Izod Impact Strength in foot-pounds per inch of notch determined by ASTM D-256, of at least 2.0 in the thermoplastic composition.
    Type: Grant
    Filed: February 1, 1988
    Date of Patent: March 7, 1989
    Assignee: Occidental Chemical Corporation
    Inventor: Rudolph F. Mundhenke
  • Patent number: 4810743
    Abstract: UV stable, impact resistant, flame retarded ABS compositions are obtained by compounding ABS with nitrile rubber, surfactant, Diels-Alder adduct of 2 moles of chlorocyclopentadiene and 1 mole of cyclooctadiene (commonly known as Dech Plus) and antimony oxide. Such compositions consist essentially by weight of from about 1% to about 9% nitrile rubber, from about 0.3% to about 5% surfactant, from about 14% to about 30% Dech Plus, from about 4% to about 20% antimony oxide and from about 50% to about 80.9% ABS. The ABS constituent has an Izod Impact Strength of at least 1.5 foot-pounds per inch. The nitrile rubber is preferably acrylonitrile-butadiene copolymer containing by weight from about 15 to about 50% acrylonitrile component, and the surfactant is preferably siloxane-oxyalkylene copolymer. The compositions have Izod Impact Strengths ranging from 2.0 to 4 foot-pounds per inch and in most cases a V-O (UL94) flammability classification.
    Type: Grant
    Filed: February 1, 1988
    Date of Patent: March 7, 1989
    Assignee: Occidental Chemical Corporation
    Inventor: Rudolph F. Mundhenke
  • Patent number: 4801405
    Abstract: There have been provided hard-to-combustion property impartation agents for polyester fibers. The agent is prepared by dissolving an alkyl cyclohexane containing bromine atoms in a solvent and dripping the solution into a liquid to provide an emulsion or dispersion of alkyl cyclohexane containing bromine.
    Type: Grant
    Filed: April 8, 1987
    Date of Patent: January 31, 1989
    Inventors: Mamoru Yamada, Takeo Tanaka
  • Patent number: 4786663
    Abstract: The present invention provides flame retardant resin compositions containing thermoplastic polyesters, organic halides and sodium antimonate, characterized in that the sodium antimonate has a ratio of the peak intensity of X-ray diffraction from face distances d of 5.25.about.5.35 (.ANG.) to that of 2.64.about.2.66 (.ANG.) being 1.5 or higher and mean particle diameter of 0.5.about.50 .mu.m, and is 1.about.15 parts by weight in proportion to 100 parts by weight of the aformentioned thermoplastic polyester. This invention provides thermoplastic resin compositions excellent in mechanical properties, hygroscopicity and thermal stability.
    Type: Grant
    Filed: January 22, 1987
    Date of Patent: November 22, 1988
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shunitsu Miyashita, Kenji Mogami
  • Patent number: 4780496
    Abstract: Normally combustible thermoplastic polyolefins such as polystyrene and polypropylene may be flame retarded without discoloration utilizing a flame retardant additive mixture comprising hexabromocyclododecane and one or more bis-(polybromophenoxy)ethane.
    Type: Grant
    Filed: July 14, 1987
    Date of Patent: October 25, 1988
    Assignee: Great Lakes Chemical Corporation
    Inventors: Enrico J. Termine, Harry A. Hodgen
  • Patent number: 4721746
    Abstract: Disclosed is a flameproofing synthetic fiber comprising a halogenated cycloalkane and at least one member selected from phosphorus compounds represented by the following general formulae (I) through (IV): ##STR1## According to the present invention, the flameproofing synthetic fiber which is excellent in flameproofing property and feeling and significantly improved in spinning property and corrosion protective property can be provided. Furthermore, the foaming during operation and the passing processability through a stuffing crimper are also extremely improved.
    Type: Grant
    Filed: August 22, 1986
    Date of Patent: January 26, 1988
    Assignee: Teijin Limited
    Inventors: Mikio Tashiro, Nobuo Sakashita, Yasunori Tatsuoka, Tamio Mitamura, Kazunori Orii
  • Patent number: 4719258
    Abstract: Derivatives of diphenylhexafluoropropane having the formula: ##STR1## where R is an unsubstituted or substituted alkylene, an epoxy, a silyl or alkoxysilyl group; and where X and Y are hydrogen or halogen. The derivatives are useful in formulating polymer structures.
    Type: Grant
    Filed: December 1, 1986
    Date of Patent: January 12, 1988
    Assignee: Hughes Aircraft Company
    Inventors: Kreisler S. Y. Lau, William J. Kelleghan
  • Patent number: 4699734
    Abstract: The invention relates to base polyolefin compositions, and concentrates thereof adapted to be let down or diluted by addition of further polyolefin, flameproofed by incorporation therein of an organohalo flame-retardant and a metal oxide or sulfide synergist, are rendered resistant to exudation by incorporating therein the combination of an epoxy resin, an elastomeric resin, and a nucleating agent, the epoxy resin being present in an amount of from about 0.01 to about 10 percent, the elastomeric resin being present in an amount of from about 0.1 to about 20 percent, and the nucleating agent being present in an amount of from about 0.1 to about 10 percent and non-fogging molded products obtained thereby.
    Type: Grant
    Filed: November 6, 1985
    Date of Patent: October 13, 1987
    Assignee: A. Schulman, Inc.
    Inventors: Shirley N. Kendall, Ramesh Rengarajan
  • Patent number: 4552912
    Abstract: A glass-reinforced, fire-retardant, arc-track resistant polyamide composition characterized in that it contains:(a) at least 35% by weight of a fibre-forming polyamide,(b) 15% to 30% by weight of glass fibres or particulate fillers,(c) 17.5 to 27.5% by weight of melamine or melamine cyanurate,(d) 1 to 10% by weight of brominated fire retardants selected from a brominated polyphenylene oxide or a brominated epoxy resin, and(e) a synergist selected from zinc oxide, zinc borate, a mixture of zinc oxide and zinc borate and a mixture of antimony oxide and zinc borate, wherein the concentration of oxide present in the synergist is between 0 and 5%, the concentration of borate present is between 0 and 25% by weight, and the total weight of synergist is at least 1%, the weight percentages of the constituents (a), (b), (c), (d) and (e) totalling 100%.
    Type: Grant
    Filed: February 29, 1984
    Date of Patent: November 12, 1985
    Assignee: Imperial Chemical Industries PLC
    Inventor: Ian G. Williams
  • Patent number: 4548972
    Abstract: A reinforced, fire retardant, polyamide composition containing(a) at least 35% by weight of a fibre-forming polyamide,(b) 15 to 30%, by weight of glass fibres or particulate fillers,(c) 15 to 30%, by weight of melamine demi-sulphate,(d) at least 2.5%, by weight of a halogenated compound selected from the condensation product of 2 moles chlorocylopentadiene and 1 mole of 1,5-cyclooctadiene, brominated polystyrene, brominated polyphenylene oxide or a brominated epoxy resin, and(e) a synergist selected from at least one of zinc borate, zinc oxide and mixtures of antimony oxide and zinc borate, wherein the concentration of oxide present is between 0 and 5%, the concentration of zinc borate is between 0 and 25%, preferably between 2 and 15% by weight and the total weight of synergist is at least 1% by weight and wherein the weight percentages of the constituents total 100%.
    Type: Grant
    Filed: February 29, 1984
    Date of Patent: October 22, 1985
    Assignee: Imperial Chemical Industries PLC
    Inventor: Ian G. Williams
  • Patent number: 4530951
    Abstract: A glass-reinforced, fire-retardant, arc-track resistant composition characterized in that it contains:(a) at least 35% by weight of a fibre-forming polyamide,(b) 15 to 25% by weight of glass fibres,(c) 16-30% by weight of melamine cyanurate,(d) 2 to 7% by weight of the condensation product of 2 moles of chlorocyclopentadiene and 1 mole of 1,5-cyclooctadiene, and an amount of(e) a fire retardant synergist selected from antimony oxide, iron oxide and stannic oxide,to give a weight ratio of (d) to (e) between 1:1 and 5:1, and wherein the constituents of the composition total 100%.
    Type: Grant
    Filed: February 29, 1984
    Date of Patent: July 23, 1985
    Assignee: Imperial Chemical Industries PLC
    Inventor: Ian G. Williams
  • Patent number: 4530880
    Abstract: A granular flame retardant additive is provided comprising from 70 to 99.5% by weight of an organohalide flame retardant and from 0.5 to 30% by weight of thermoplastic synthetic resin as a binder. The additive is easy to handle and resistant to disintegration during transportation and mixing with fabricating resin pellets. Uniform distribution thereof in fabricated thermoplastic articles is achieved by simply co-feeding the granules and the fabricating resin to a fabricating machine.
    Type: Grant
    Filed: January 27, 1984
    Date of Patent: July 23, 1985
    Assignees: Sekisui Kaseihin Kogyo Kabushiki Kaisha, Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Akira Taniuchi, Setsuo Nishibori, Hirohito Komori, Motoshige Hayashi
  • Patent number: 4525516
    Abstract: In accordance with this invention, the formation of bubbles in a composition of (a) ethylene polymer, (b) flame retardant system, and (c) peroxide is inhibited or eliminated by employing as the peroxide a halogenated organic peroxide.
    Type: Grant
    Filed: March 2, 1984
    Date of Patent: June 25, 1985
    Assignee: Phillips Petroleum Company
    Inventors: Rodrigo A. Garcia, Robert J. Martinovich
  • Patent number: 4504611
    Abstract: Polyamide compositions having improved flame retardant properties and arc tracking resistance comprises, in percent by weight, about 35 to about 76 percent polyamide; about 6 to about 10 percent zinc borate; about 10 to about 15 percent melamine cyanurate; 0 to about 35 percent glass fiber; about 0 to about 3 percent antimony trioxide; and about 8 to about 15 percent of a chlorinated compound of the formula: ##STR1##
    Type: Grant
    Filed: August 1, 1983
    Date of Patent: March 12, 1985
    Assignee: Occidental Chemical Corporation
    Inventors: Charles S. Ilardo, James J. Duffy
  • Patent number: 4447572
    Abstract: Polyamides, flame retarded with a halogenated derivative and blended with a polymer blend resin being at least partially incompatible and having a lower melt viscosity than the polyamide, to improve the arc tracking resistance of the polyamide, are disclosed. The polyamides are particularly useful in the manufacture of flame retarded electrical components.
    Type: Grant
    Filed: November 6, 1981
    Date of Patent: May 8, 1984
    Assignee: Occidental Chemical Corporation
    Inventors: Daniel J. Scharf, Charles S. Ilardo, Willis T. Schwartz, Gideon Salee