Unsaturated Hydrocarbon Contains A Bridged Or Fused Ring Patents (Class 524/482)
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Patent number: 10815401Abstract: A main object of the present disclosure is to provide a block copolymer composition that allows a hot melt adhesive composition having excellent hot melt properties and heat resistance stability to be obtained. The object is achieved by providing a block copolymer composition comprising a block copolymer A including an Ar1-D1 diblock as a branched chain, the block copolymer A represented by the following general formula (I), characterized in that: a molecular weight distribution (Mw/Mn) of the block copolymer A is 1.20 or less; a content of the block copolymer A in the block copolymer composition is 10% by mass or more; a content of a block copolymer B corresponding to an Ar2-D2 diblock represented by the following general formula (II), in the block copolymer composition is 60% by mass or less, and a molecular weight distribution (Mw/Mn) of the block copolymer B is 1.Type: GrantFiled: September 16, 2016Date of Patent: October 27, 2020Assignee: ZEON CORPORATIONInventors: Atsushi Nozawa, Sadaharu Hashimoto
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Patent number: 9868845Abstract: The invention relates to an oil extended ethylene-a-olefin-non-conjugated-diene copolymer composition consisting of i) 100 parts of at least one ethylene-a-olefin-non-conjugated-diene copolymer having —a weight average molecular weight (Mw) of at least 300,000 g/mol. —an intrinsic viscosity higher than 4, preferably higher than 4.2 measured in Xylene at 70° C. and —a polydispersity (Mw/Mn) smaller than 3, preferably smaller than 2.8, in particular smaller than 2.6; ii) 30 to 70 parts by weight per 100 parts by weight of the ethylene-a-olefin-non-conjugated-diene copolymer (i) of an extender oil and iii) up to 5 parts by weight per 100 by weight of the ethylene-a-olefin-non-conjugated-diene copolymer (i) of auxiliary agents, whereby the oil extended copolymer composition has a phase angle ?min of lower than 2.5.Type: GrantFiled: June 24, 2014Date of Patent: January 16, 2018Assignee: ARLANXEO NETHERLANDS B.V.Inventors: Henri Jacob Hubert Beelen, Ulrich Frenzel, Claus Wrana, Christoph Goegelein
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Patent number: 8329782Abstract: A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion comprising contacting the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with an anion exchange resin comprising a polymer and quaternary ammonium functional groups to reduce fluorosurfactant content, the functional groups being resistant to degradation which releases trialkylamines. The anion exchange resin is separated from the dispersion after the fluorosurfactant content has been reduced.Type: GrantFiled: December 18, 2009Date of Patent: December 11, 2012Assignee: E I du Pont de Nemours and CompanyInventors: James R. Combes, David William Johnson, Stephen Thomas Breske
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Patent number: 8227526Abstract: A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion comprising contacting the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with an anion exchange resin comprising a polymer and quaternary ammonium functional groups to reduce fluorosurfactant content, the functional groups being resistant to degradation which releases trialkylamines. The anion exchange resin is separated from the dispersion after the fluorosurfactant content has been reduced.Type: GrantFiled: December 18, 2009Date of Patent: July 24, 2012Assignee: E I du Pont de Nemours and CompanyInventors: James R. Combes, David William Johnson, Stephen Thomas Breske
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Patent number: 8123971Abstract: The invention relates to composites made of an elastic carrier medium comprising polynorbornene (PNR) and magnetisable particles which are polarized reversibly in a magnetic field. Thus the mechanical properties, such as e.g. storage modulus G? (describes the elastic behavior or the energy storage) and loss modulus G? (describes the viscous behavior or the energy dissipation), of such elastomer composites can be increased rapidly and reversibly within wide limits (up to approx. two orders of magnitude) as a function of an external magnetic field. Wide-ranging application possibilities are produced herefrom, e.g. for adaptive damping systems, in which the damping force can be adjusted via the strength of the magnetic field.Type: GrantFiled: April 10, 2007Date of Patent: February 28, 2012Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.Inventors: Holger Böse, Rene' Röder, Nikolaus Rennar
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Patent number: 7829621Abstract: A rubber composition which provides an improved balance in grip performance, grip durability and abrasion resistance, and a tire and/or tire tred made from the same Wherein the rubber composition includes a diene rubber, 50 to 120 parts by weight of a reinforcing agent containing particular carbon black and 10 to 100 parts by weight of silica based on 100 parts by weight of a the diene rubber, 2 to 50 parts by weight of a styrene-butadiene polymer, in which weight average molecular weight is 1,000 to 15,000, the amount of a styrene being 17 to 27% by weight and the amount of vinyl being 60 to 80% by weight, and 2 to 25 parts by weight of an indene resin, in which the melting point is 100 to 150° C., based on 100 parts by weight of the diene rubber which includes at least 60% by weight of a particular solution polymerization styrene-butadiene rubber and at most 40% by weight of a natural rubber and/or a butadiene rubber.Type: GrantFiled: September 26, 2005Date of Patent: November 9, 2010Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tetsuya Kunisawa, Toshiro Matsuo, Takuya Horiguchi, Takashi Nakamura
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Patent number: 7765855Abstract: Adhesive compositions and a method for selecting adhesive compositions are disclosed herein. Preferred adhesives generally have small domains and/or a homogeneous domain distribution. The method of selecting adhesives is based on size and distribution of the domains.Type: GrantFiled: November 7, 2006Date of Patent: August 3, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kenneth Lewtas, Antonie Jan Bons, Johan Stuyver
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Patent number: 7745526Abstract: Disclosed herein are various compositions, including a transparent compositions with maximum haze of 50%, comprising (including): a first polymer component (FPC) that includes polypropylene having a melting point (Tm) ?110° C.; a second polymer component (SPC) that includes a propylene polymer having 60 wt % or more units derived from propylene, including isotactically arranged propylene derived sequences and Tm<105° C. or a Heat of Fusion<45 J/g, or both; and a hydrocarbon resin having a Tg?20° C.; wherein: the SPC is present in the amount of ?10 wt % and ?70 wt % based on the total weight of a), b) and c) and the composition has: Haze value of ?50 percent; and Shore A Hardness of 90 or below.Type: GrantFiled: November 5, 2004Date of Patent: June 29, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventor: Trazollah Ouhadi
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Patent number: 7666927Abstract: A process for reducing fluorosurfactant content of a stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion comprising contacting the stabilized fluorosurfactant-containing aqueous fluoropolymer dispersion with an anion exchange resin comprising a polymer and quaternary ammonium functional groups to reduce fluorosurfactant content, the functional groups being resistant to degradation which releases trialkylamines. The anion exchange resin is separated from the dispersion after the fluorosurfactant content has been reduced.Type: GrantFiled: December 2, 2005Date of Patent: February 23, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: James R. Combes, David William Johnson, Stephen Thomas Breske
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Patent number: 7582339Abstract: Disclosed is a method of manufacturing a biaxial polynorbornene-film having a compensation film which has good light transmittance and a uniform in-plane retardation value and can function as both a negative C-plate and an A-plate.Type: GrantFiled: November 15, 2005Date of Patent: September 1, 2009Assignee: LG Chem, Ltd.Inventors: Won Kook Kim, Sung Ho Chun, Kyung Lim Paik, Belyaev Sergey, Malimonenko Nikolai
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Patent number: 7507426Abstract: The present invention relates to a unified polarizing plate, which employs, as a protection layer of a polarizing film, a transparent film that can simultaneously function as a negative C-plate and transparent protection layer of a polarizing film and has negative refractive index toward thickness direction, thereby simultaneously performing functions as a negative C-plate for optical compensation and as a polarizing plate, and a method for preparing the same. The unified polarizing plate has superior durability at high temperature and high humidity compared to those employing TAC as a protection layer, and improves wide view angle of liquid crystal display having positive refractive index toward thickness direction, when the liquid crystal display device is ON or OFF.Type: GrantFiled: February 6, 2004Date of Patent: March 24, 2009Assignee: LG Chem, Ltd.Inventors: Won-Kook Kim, Sung-Ho Chun, Sung-Cheol Yoon, Tae-Sun Lim, Heon Kim, Jung-Min Lee, Jeong-Su Yu, In-Seok Hwang, Beom-Seok Kim
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Patent number: 7431061Abstract: A cross-linkable or cross-linked rubber composition which is usable to constitute a tire tread having improved wear resistance, to such a tread and to a tire incorporating this tread. The rubber composition is particularly applicable to tires of passenger-vehicle type. The rubber composition includes a plasticizing resin of number-average molecular weight of from 400 to 2000 g/mol, the resin containing units resulting from the polymerization of vinylcyclohexene.Type: GrantFiled: January 31, 2005Date of Patent: October 7, 2008Assignee: Michelin Recherche et Technique S.A.Inventors: Samuel Mathieu, Gérard Labauze
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Patent number: 7381766Abstract: A low-VOC (volatile organic compound) and/or low-toxicity coating formulation, including at least one non-halogenated organic solvent including any terpene or terpenoid, and at least one conducting polymer, electroactive polymer and/or conjugated polymer. In another embodiment, the present invention includes a low-VOC (volatile organic compound) and/or low-toxicity coating formulation, including about 0.001% wt. to about 99.9% wt. of at least one non-halogenated organic solvent including a terpene or terpenoid, about 0.01% wt. to about 90% wt. of at least one conducting polymer, and about 0.001% wt to about 90% wt. of at least one surfactant.Type: GrantFiled: September 6, 2006Date of Patent: June 3, 2008Assignee: The United States of America as represented by the Secretary of the NavyInventor: Nicole Marie Anderson
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Patent number: 7329704Abstract: The present invention relates to a cross-linkable or cross-linked rubber composition which is usable to constitute a tire tread having improved wear resistance, to such a tread and to a tire incorporating this tread. A rubber composition according to the invention comprises a diene elastomer of a number-average molecular weight Mn of less than 2000 g/mol which has a glass transition temperature Tg of greater than ?25° C., and it is such that said elastomer comprises one or more units resulting from the polymerisation of a vinylaromatic monomer, such as styrene. The invention applies in particular to tires of passenger-vehicle type.Type: GrantFiled: March 10, 2005Date of Patent: February 12, 2008Assignee: Michelin Recherche et Technique S.A.Inventor: Gerard Labauze
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Patent number: 7253225Abstract: The invention relates to a cross-linked rubber composition for a tire tread having a Shore A hardness greater than 45 and less than 57, measured in accordance with Standard ASTM D 2240, wherein the composition comprises greater than 25 phr and up to 100 phr, of one or more diene elastomers each having a temperature Tg of between ?75° C. and ?40° C., less than 75 phr and down to 0 phr, of one or more diene elastomers each having a temperature Tg of between ?110° C. and ?75° C., from 5 phr to 35 phr, of at least one hydrocarbon plasticizing resin miscible in said elastomer(s), said resin having a Tg of between 10° C. and 150° C. and a molecular weight Mn of between 400 and 2000 g/mol, and from 5 phr to 35 phr of at least one synthetic or natural plasticizing compound which comprises at least one glycerol fatty acid triester, wherein an aggregate constituted by the fatty acid(s) comprises oleic acid in a mass fraction equal to or greater than 60%.Type: GrantFiled: March 3, 2005Date of Patent: August 7, 2007Assignee: Michelin Recherche et Technique, S.A.Inventors: Gerard Labauze, Didier Vasseur
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Patent number: 7199180Abstract: Disclosed are adhesives and processes for preparing the same, comprising at least one first homogeneous ethylene/?-olefin interpolymer, and optionally at least one tackifier, and optionally at least one plasticizer. The claimed adhesives are useful as adhesives such as are employed in various applications, such as in masking tape, clear office tape, labels, decals, bandages, decorative and protective sheets (such as shelf and drawer liners), floor tiles, sanitary napkin/incontinence device placement strips, sun control films, the joining of gaskets to automobile windows, packaging, bookbinding, construction of nonwoven articles, and insulation bonding.Type: GrantFiled: March 14, 1997Date of Patent: April 3, 2007Assignees: The Dow Chemical Company, H.B. Fuller Licensing & Financing Inc.Inventors: Eugene R. Simmons, William L. Bunnelle, David B. Malcolm, Keith C. Knutson, Thomas F. Kauffman, Mark S. Kroll, Michael S. Keehr, Deepak R. Parikh, Jimmy D. Allen, David R. Speth, Selim Yalvac, Malcolm F. Finlayson, Cynthia L. Rickey
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Patent number: 7015276Abstract: A melt-moldable, thermoplastic norbornene resin composition characterized by being obtained by compounding (A) a base polymer comprising a thermoplastic norbornene resin with (B) an olefin compound having a number-average molecular weight of 200 to 10,000 and a softening point of 70 to 170° C.; and a molded article or optical film obtained by melt-molding or extrusion-molding the thermoplastic norbornene resin composition.Type: GrantFiled: October 1, 2001Date of Patent: March 21, 2006Assignee: Sekisui Chemical Co., Ltd.Inventors: Takeharu Morita, Hiroshi Hiraike, Shoji Nozato
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Patent number: 6872768Abstract: The present invention is a thermoplastic elastomeric resin granule for powder molding having a longer diameter of 400 ?m or less and a ratio of the longer diameter to a shorter diameter of from 3:1 to 1:1, wherein said granule comprises a composition prepared by dynamically vulcanizing 100 parts by weight of (a) a block copolymer consisting of at least two polymeric blocks (A) composed mainly of a vinyl aromatic compound and at least one polymeric block (B) composed mainly of a conjugated diene compound, and/or a hydrogenated block copolymer obtained by hydrogenating said block copolymer, 20 to 300 parts by weight of (b) a non-aromatic softening agent for rubber, and 10 to 150 parts by weight of (c) a peroxide-decomposing olefinic resin and/or a copolymer thereof. The resin granule has excellent fluidity in a powder molding.Type: GrantFiled: April 7, 2000Date of Patent: March 29, 2005Assignee: Riken Technos CorporationInventors: Michihisa Tasaka, Toshimi Yamanaka
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Patent number: 6831125Abstract: The invention is directed to resin coating, adhesive, and cement compositions comprising styrenic copolymers and a terpene solvent. The compositions are particulary useful for toy article applications because of the use of safe, naturally occuring terpene solvents. These compositions form high adhesion bonding with molded elastomeric styrene copolymer surface substrates. The invention is also directed to a method of applying the instant coatings to substrate surfaces.Type: GrantFiled: November 19, 2002Date of Patent: December 14, 2004Assignee: Mattel, Inc.Inventor: John Sneddon
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Patent number: 6689483Abstract: The present invention relates to an improved packaging composition comprising an ethylene copolymer selected from ethylene acid or ester copolymers such as ethylene vinyl acetate, ethylene/acrylic acid or methacrylic acid copolymers which optionally contain a third comonomer such as an alkyl acrylate and the corresponding ionomers of said copolymers which are blended with a hydrophilic zeolite to form a composition which removes residual acids or small esters from the polymeric or ionomeric composition containing such residual acids. The acids may be present as initial by products in the copolymerization process or may be degradation products. The use of these compositions is particularly important when the resins are formed into packages or other fabricated material which are exposed to acid sensitive material.Type: GrantFiled: November 28, 2001Date of Patent: February 10, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: George Lok Kwong Hoh, David Richard Corbin, Steven B. Oblath
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Patent number: 6677396Abstract: An adhesive composition comprises an amorphous polyalphaolefin, 50-90 wt %; a tackifier 10-40 wt %; a functionalised polypropylene trace-20 wt %; and optional further ingredients selected from stablisers, fillers and waxes; wherein the proportions of the amorphous polyalphaolefin, tackifier and functionalised polypropylene are selected to total 100%. A method of forming polypropylene packaging using the adhesive is also provided.Type: GrantFiled: December 23, 2002Date of Patent: January 13, 2004Assignee: Gluco LimitedInventors: Sum-Wing Tsui, Anthony Francis Johnson
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Patent number: 6515059Abstract: A method of recycling EPDM rubber including the steps of devulcanizing previously cured EPDM rubber and adding the devulcanized EPDM rubber to a composition for forming an elastomeric membrane for roofing, the composition including a rubber mixture including from about 50 to about 95 parts by weight virgin EPDM rubber, and from about 5 to about 50 parts by weight of the devulcanized EPDM rubber, to total one hundred parts by weight rubber, from about 75 to about 300 parts by weight phr of a filler, from about 35 to about 135 parts by weight phr of a processing oil, and a cure package.Type: GrantFiled: November 18, 1997Date of Patent: February 4, 2003Assignee: BFS Diversified Products, LLCInventors: James A. Davis, Brenda J. Fannin, J. Arvis McKamie
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Patent number: 6310220Abstract: This invention relates to compositions comprising a polycarbonate, polyester or polyketone which is subject to oxidative, thermal and/or light-induced degradation, or their mixtures and blends, and at least one benzofuran-2-one type compound, to the use thereof for stabilising polycarbonate, polyester or polyketone or their mixtures or blends against oxidative, thermal and/or light-induced degradation, as well as to a process for stabilising these plastic materials.Type: GrantFiled: March 2, 2000Date of Patent: October 30, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: André Schmitter, Alfred Georges Oertli
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Patent number: 6174944Abstract: Provided are a flame retardant polycarbonate resin composition and housings of the composition for electric and electronic instruments and appliances. Having good fluidity and good moldability, the composition can be well molded into thin-wall moldings with good appearance. The composition contains additive components of a fibrous filler, a terpene resin, a composite rubber-based graft copolymer, a halogen-free phosphate compound and a polytetrafluoroethylene.Type: GrantFiled: March 30, 1999Date of Patent: January 16, 2001Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Jiro Chiba, Masahiro Kitayama
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Patent number: 6071996Abstract: A walkway pad composition comprises 100 parts by weight of an ethylene-propylene-diene terpolymer; from about 60 to 700 parts by weight of a filler selected from the group consisting of reinforcing and non-reinforcing materials and mixtures thereof, per 100 parts of the terpolymer; from about 40 to 175 parts by weight of a processing material and mixtures thereof, per 100 parts of the terpolymer; and from about 2 to 10 parts by weight of a cure package, per 100 parts of the EPDM terpolymer, the composition being devoid of any additional polymeric components. The 100 percent EPDM walkway pad composition has better low temperature properties and superior weathering resistance, and heat aging resistance compared to other walkway pad compositions which may include other polymeric components such as natural rubber, synthetic polyisoprene, styrene-butadiene rubber (SBR), polybutadiene, and butyl (IR) rubber. Up to about 25 parts by weight of ethylene-propylene copolymers may be substituted for the EPDM terpolymers.Type: GrantFiled: August 8, 1997Date of Patent: June 6, 2000Assignee: Bridgestone/Firestone, Inc.Inventors: James A. Davis, Joseph J. Kalwara, Jerry C. Rose
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Patent number: 5922802Abstract: A composition, comprising(a) a strained cycloolefin,(b) a filler, and(c) 0.01-10.0% by weight, based on the sum of components (a)+(b), of a copolymer selected from the group consisting of core/shell polymers and microgels, is distinguished by having high storage stability and gives polymers having high heat stability, toughness and mechanical strength, which polymers are suitable as encapsulating material for electrical and electronic components.Type: GrantFiled: December 10, 1997Date of Patent: July 13, 1999Assignee: Ciba Specialty Chemicals CorporationInventor: Frans Setiabudi
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Patent number: 5834533Abstract: A stable liquid suspension composition comprising a liquid carrier, a solid fatty acid or a salt thereof, and a solid particulate is disclosed wherein said liquid carrier is selected from the group consisting of oils, olefins, terpenes, glycols, esters, ethers, alcohols, and combinations of any two or more thereof and said liquid carrier, solid fatty acid or salt thereof, and solid particulate are each present in said composition in a stabilizing amount sufficient to produce a stable liquid suspension. Also disclosed is a stable liquid composition comprising a liquid carrier, an oil-soluble polymer, and a solid particulate wherein said liquid carrier is selected from the group consisting of liquid alkenes, terpenes, esters, and combinations of any two or more thereof and said liquid carrier, oil-soluble polymer, and solid particulate are each present in said composition in a stabilizing amount sufficient to effect the formation of a stable liquid suspension.Type: GrantFiled: November 20, 1996Date of Patent: November 10, 1998Assignee: Phillips Petroleum CompanyInventors: Bharat B. Patel, Marshall D. Bishop
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Patent number: 5762696Abstract: An ink vehicle composition is provided comprising a polymeric type resin binder component and a terpene dimer oil. In an alternate embodiment the compositions further include an additional oil selected from linseed oil, soya bean oil, tung oil, or other oils having drying characteristics defined by an Iodine value greater than 120. Advantageously, the compositions contain a reduced amount of petroleum distillate solvent and lower volatile organic compounds (VOC) than conventional ink vehicles. As an ink vehicle the compositions are further incorporated into ink formulations. The varnish compositions are also used as an overprint varnish on a substrate surface.Type: GrantFiled: July 19, 1996Date of Patent: June 9, 1998Assignee: Arizona Chemical CompanyInventor: Thomas C. Jordan
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Patent number: 5639810Abstract: Improved elastomeric materials useful for medical and therapeutic device applications, such as penetrable septa, are described. In one aspect, the materials are deeply cleaned with solvent to significantly lower levels of undesirable organics. In another aspect, internally lubricated elastomer compositions compatible for use in medical and therapeutic device applications are provided. The lubricating fluid is present in the composition from about 0.5% to 50% by weight, and is initially substantially homogeneously dispersed in the elastomer. The fluid can be integrated into the elastomer by a solvent infusion method. In another aspect an internally lubricated thermoplastic septum, having an appropriate hardness for resealability with multiple penetrations, is provided.Type: GrantFiled: June 7, 1995Date of Patent: June 17, 1997Assignee: COBE Laboratories, Inc.Inventors: Hubert S. Smith, III, James M. Brugger, Helmut W. Frey
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Patent number: 5591792Abstract: The invention relates to an adhesive resin composition comprising an ethylene polymer having a melting point of 70 to 132.degree. C., a density of 0.88 to 0.94% g/cm.sup.3 and a melt flow rate (MFR) of 0.05 to 50 g/10 min. and/or a modified product thereof with an unsaturated carboxylic acid or its derivative (component A); a tackifier (component B); and a block copolymer containing at least one polymer block mainly composed of a vinyl aromatic hydrocarbon and at least one polymer block mainly composed of a conjugated diene or a hydrogenated product thereof (component C). This composition is useful as an adhesives showing excellent adhesion over a wide temperature range as well as processability by film molding, sheet molding, blow molding, etc. It is available for laminates comprising various kinds of resins such as polyolefins, styrenic resins, polyesters, acrylic resins and polyamides.Type: GrantFiled: January 10, 1995Date of Patent: January 7, 1997Assignee: Mitsubishi Chemical CorporationInventors: Masafumi Hattori, Chikako Ikeda, Satoru Sugimoto, Tatsuoki Saito, Hitoshi Yamada, Etsushi Akashige
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Patent number: 5468789Abstract: A method is provided for making curable silicon containing acrylate silicone hardcoat compositions which employ an anaerobic gelation inhibitor such as galvinoxyl. Devolatilizing of an aqueous/organic solvent mixture from the silicon containing acrylate hardcoat formulation is conducted in an inert atmosphere. Acrylate hardcoat compositions imparting improved weathering resistance to thermoplastic substrates also are provided.Type: GrantFiled: September 12, 1994Date of Patent: November 21, 1995Assignee: General Electric CompanyInventors: Larry N. Lewis, George F. Medford, Arnold Factor
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Patent number: 5468816Abstract: A release modifier which comprises (i) a MQ resin consisting essentially of units of the formulae SiO.sub.2 and R.sub.3 SiO.sub.1/2 wherein R denotes a monovalent hydrocarbon group having up to 3 carbon atoms, a hydrogen atom, a c.sub.2-5 alkenyl group of the formula --R'CH.dbd.CH.sub.2, provided there is at least one group --R'CH.dbd.CH.sub.2 present per MQ molecule and (ii) a .alpha.,.omega.-diolefin having the general formula CH.sub.2 .dbd.CH--(CH.sub.2).sub.n --CH.dbd.CH.sub.2, wherein n denotes an integer with a value of from 4 to 18 gives improved release force over prior art controlled release additives. Also claimed is a solventless release composition based on siloxanes having SiH groups and a catalyst in addition to the release modifier.Type: GrantFiled: October 28, 1994Date of Patent: November 21, 1995Assignee: Dow Corning LimitedInventors: Simon R. Hurford, Bhukandas Parbhoo
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Patent number: 5442001Abstract: The use of C.sub.1 -C.sub.5 alkyl butyrates, d-limonene, ethylene glycol monobutyl ether and C.sub.5 -C.sub.20 petroleum distillates and normal paraffins in place of methyl chloroform (1,1,1-trichloroethane) in conventional waterborne packaging and converting adhesives provides comparable or better adhesive products with reduced environmental and health related problems.Type: GrantFiled: September 7, 1994Date of Patent: August 15, 1995Assignee: National Starch and Chemical Investment Holding CorporationInventors: M. Erin Jones, Paul P. Puletti
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Patent number: 5360855Abstract: A novel 2-substituted butadiene block copolymer is provided which provides adhesives having superior adhesion and tolerance to oil contaminated surfaces. The elastomeric block has a glass transition temperature of less than about minus 65.degree. C. with the 2 substituent being an alkyl group.Type: GrantFiled: June 22, 1993Date of Patent: November 1, 1994Assignee: Minnesota Mining & Manufacturing CompanyInventor: Ramsis Gobran
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Patent number: 5328948Abstract: A composition comprising a halopolymer, such as an ethylene/chlorotrifluoroethylene copolymer, an effective stabilizing amount of an ionomer, and an effective stabilizing amount of a compound such as a phosphite of an organic polyhydric phenol; a thioester; a phosphite; or a hindered phenolic antioxidant. Preferred ionomers are metal salts of ethylene-acrylic acid copolymers, and metal salts of sulfonated polystyrenes. The stabilized halopolymers have improved resistance to thermal degradation and suffer less discoloration when subjected to high melt processing or extrusion molding temperatures.Type: GrantFiled: September 23, 1992Date of Patent: July 12, 1994Assignee: Ausimont, U.S.A., Inc.Inventors: Chii-Shu Chen, L. Lawrence Chapoy
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Patent number: 5264476Abstract: An olefinic resin composition which is moldable to shaped articles coatable with coating compositions without primers is prepared by blending (A) a cross-linked olefinic thermoplastic elastomer obtained from a homo- or co-polymer of alpha-olefin (C.sub.2-20) and elastomeric copolymer composed of alpha-olefins (C.sub.2-20), (B) a low-molecular weight modified polypropylene having Mn of 2,000-20,000 which is grafted with maleic anhydride and (C) a tackifier.Type: GrantFiled: December 17, 1992Date of Patent: November 23, 1993Assignee: Sumitomo Chemical Company, LimitedInventors: Akio Daimon, Koichiro Ibuki
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Patent number: 5252649Abstract: The plasticizer constituent in the rubber mixture of the tread member of a pneumatic vehicle tire contains at least partially at least one fatty acid triglyceride, preferably natural rape seed oil in which more than 50% of the fatty acid residues are present as oleic acid residues and an oleic acid/linoleic acid ratio is greater than or equal to 2:1. Sunflower seed oil or natural rape seed oil and triglyceride of oleic acid also can be used as the fatty acid triglycerides. There is thus achieved improved traction upon ice and snow as well as at dry and wet roads in the absence of negative effects on other properties of the tire.Type: GrantFiled: July 13, 1992Date of Patent: October 12, 1993Assignee: Semperit Reifen AGInventor: Bernadette Hausmann
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Patent number: 5242971Abstract: The present invention provides ethylene-propylene-diene rubbers which are excellent in co-vulcanizability with conjugated diene rubbers and can impart excellent weather resistance, ozone resistance and thermal aging resistance without detriment to excellent mechanical characteristics, wear resistance and dynamic fatigue resistance which the conjugated diene rubbers possess.The ethylene-propylene-diene rubbers of the present invention are characterized by having a Mooney viscosity ML.sub.1+4 (100.degree. C.) of 50 to 120 and comprising(A) 90 to 40% by weight of a high-molecular weight ethylene-propylene-diene copolymer rubber having an ethylene content of 73 to 85 mol %, an intrinsic viscosity [.eta.] of 2.5 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 15 to 35, and(B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene copolymer rubber having an ethylene content of 73 to 85 mol %, an intrinsic viscosity [.eta.] of 0.15 to 0.8 dl/g as measured at 135.degree. C.Type: GrantFiled: June 4, 1991Date of Patent: September 7, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hidenari Nakahama, Takashi Mishima
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Patent number: 5180766Abstract: A resin composition for primer use is described, which contains a copolymer of (I) a radical-polymerizable olefin resin and (c) a monomer copolymerizable with said olefin resin (I) and containing an alkyl (meth)acrylate and/or a fluorine-containing unsaturated monomer as essential ingredients, said radical-polymerizable olefin resin (I) being a product of the reaction of (a) an olefin resin having at least one functional group per molecule with (b) a radical-polymerizable monomer having a functional group reactive to the functional group contained in said olefin resin (a).A primer composition is also described.Type: GrantFiled: April 19, 1991Date of Patent: January 19, 1993Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Kazuhide Hayama, Kazuyuki Hata, Katsuhiko Yamada, Keizo Abe, Takahiro Ozu
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Patent number: 5159007Abstract: A metal binder including a base binder agent including a bonding agent, lubricant, etc. into which is blended as a binder auxiliary agent at least one member selected from the group of adamantane, trimethylene norbornane, and cyclododecane and a molding composition including a metal powder made of a metal of Group VIII etc. into which is blended a base binder agent and as a binder auxiliary agent at least one member selected from the group of adamantane, trimethylene norbornane, and cyclododecane.Type: GrantFiled: July 24, 1991Date of Patent: October 27, 1992Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Katsuyoshi Saitoh, Tomoaki Hanamura
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Patent number: 5112889Abstract: Pressure-sensitive adhesive compositions and an improved refastenable tape closure system comprising a release tape and a fastening tape wherein the fastening tape has a balance of properties such that the tape exhibits a maximum in the peel force between peel rates of 10 cm./minute and 400 cm./minute when peeled from a polyolefin substrate as found in disposable diaper back sheets are disclosed. The adhesive of the fastening tape comprises a specific range of compositions including an elastomeric component based on an A-B-A block copolymer wherein the A blocks are derived from styrene or alphamethylstyrene and the B block are derived from isoprene, butadiene, or hydrogenated versions of these or an (AB) block copolymer of the same type of composition in another geometry such as a tapered block copolymer or a radial block copolymer, a solid tackifier resin, a liquid tackifier resin, and an end block reinforcing resin.Type: GrantFiled: February 15, 1991Date of Patent: May 12, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: John A. Miller, Egbert A. von Jakusch
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Patent number: 5057591Abstract: The invention is a solution of highly advanced phenolic resin with improved inherent foamability that is made from the reaction of phenol, aldehyde, water and alkali the improved foamability being brought about by the incorporation of up to 1.0% by weight, anhydrous basis, lime (calcium hydroxide) into the early stages of the reaction mix. In another embodiment, the invention is a plywood glue composition comprising a solution of lime-containing highly advanced phenolic resin, dried animal blood and preferably an aldehyde glue viscosity-lowering agent.Type: GrantFiled: August 25, 1988Date of Patent: October 15, 1991Assignee: Borden, Inc.Inventors: William D. Detlefsen, Lewis D. Creel, Lee R. Johnson
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Patent number: 5028646Abstract: Pressure-sensitive adhesive compositions and an improved refastenable tape closure system comprising a release tape and a fastening tape wherein the fastening tape has a balance of properties such that the tape exhibits a maximum in the peel force between peel rates of 10 cm./minute and 400 cm./minute when peeled from a polyolefin substrate as found in disposable diaper back sheets are disclosed. The adhesive of the fastening tape comprises a specific range of compositions including an elastomeric component based on an A-B-A block copolymer wherein the A blocks are derived from styrene or alphamethylstyrene and the B blocks are derived from isoprene, butadiene, or hydrogenated versions of these or an (AB) block copolymer of the same type of composition in another geometry such as a tapered block copolymer or a radial block copolymer, a solid tackifier resin, a liquid tackifier resin, and an end block reinforcing resin.Type: GrantFiled: November 15, 1989Date of Patent: July 2, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: John A. Miller, Egbert A. von Jakusch
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Patent number: 4965305Abstract: A hot melt wax composition and process for producing said hot melt wax composition are disclosed. The wax compositions are suitable for coating fibrous materials, for example, paper and corrugated paper boards. The coating compositions comprise a blend of a recrystallized heavy intermediate wax, a polymeric hydrocarbon compound, a tackifier resin and a phenolic anti-oxidant.Type: GrantFiled: November 30, 1988Date of Patent: October 23, 1990Assignee: Conoco Inc.Inventor: Richard L. Jones
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Patent number: 4957960Abstract: An encapsulating composition for electronic devices comprises a curable material such as a silicone resin and an ion scavenger compound selected from certain calixarene or oxacalixarene compounds in which at least half of the phenolic groups have been substituted by specific groups and certain silacrown compounds. Exemplary ion scavenger compounds include ##STR1## the tetraethyl acetate of 7, 13, 19, 25-tetra-tertbutyl-27, 28, 29, 30-tetrahydroxy-2,3-dihomo-3-oxacalix-4-arene and 1,1-dimethasila-17-crown-6.Type: GrantFiled: January 30, 1990Date of Patent: September 18, 1990Assignee: Loctite (Ireland) Ltd.Inventors: Stephen J. Harris, John G. Woods, John M. Rooney, Marueen G. MacManus, John Guthrie
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Patent number: 4939187Abstract: A pattern material for making foundry patterns for use in investment casting process, comprising urea, polyvinyl alcohol and a substance, said substance being capable of forming an eutectic mixture with polyvinyl alcohol to reduce the melting temperature of urea.Type: GrantFiled: November 22, 1988Date of Patent: July 3, 1990Inventor: Tadao Fujita
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Patent number: 4908399Abstract: An encapsulating composition for electronic devices comprises a curable material such as an epoxy resin and an ion scavenger compound selected from certain calixarene or oxycalixarene compounds in which at least half of the phenolic groups have been substituted by specific groups and certain silacrown compounds. Exemplary ion scavenger compounds include ##STR1## the tetraethyl acetate of 7, 13, 19, 25-tetra-tertbutyl-27, 28, 29, 30-tetrahydroxy-2,3-dihomo-3-oxacalix-4-arene and 1,1-dimethasila-17-crown-6.Type: GrantFiled: November 14, 1988Date of Patent: March 13, 1990Assignee: Loctite (Ireland) Ltd.Inventors: Stephen J. Harris, Maureen G. MacManus, John Guthrie
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Patent number: 4874783Abstract: Compounds having defined unsaturated alicyclic groups are described which color stabilize aromatic carbonate polymers or blends therewith upon exposure to sterilizing radiation.Type: GrantFiled: December 22, 1987Date of Patent: October 17, 1989Assignee: General Electric CompanyInventors: Linda H. Nelson, Roger W. Avakian, Arnold Factor
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Patent number: 4792584Abstract: An adhesive composition comprising100 parts by weight of a block copolymer (a) containing of at least one polymer block composed mainly ofa vinyl aromatic hydrocarbon and at least one polymer block composed mainly of butadiene in which(i) the vinyl aromatic hydrocarbon content [S] is 10 to 30% by weight,(ii) the 1,2-vinyl content of butadiene portion [V] is 20 to 50%, and(iii) the relationship between said vinyl aromatic hydrocarbon content [S] and said 1,2-vinyl content of butadiene portion [V] satisfies the formula,:40.ltoreq.[S]+[V].ltoreq.7040 to 200 parts by weight of a tackifier (b), and, optionallyvarious stabilizers, and a process for producing said composition.Type: GrantFiled: April 23, 1987Date of Patent: December 20, 1988Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Toshinori Shiraki, Yasuo Hattori, Masao Karouji
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Patent number: 4789708Abstract: Ethylene propylene copolymer elastomers and ethylene propylene diene terpolymer elastomers are shown which, when cured, exhibit improved oil resistance and chemical aging properties at elevated temperatures and pressures. A previously polymerized liquid 1,2-polybutadiene is incorporated into the elastomer by chemical blending during the polymerization process. Such compositions are useful as electrical insulating materials for use under extreme environmental conditions, particularly in wire and cable constructions.Type: GrantFiled: December 14, 1987Date of Patent: December 6, 1988Assignee: Hughes Tool CompanyInventor: Raymond L. Guzy