Wax Having Melting Point Above 120 Deg. F (49 Deg. C) Patents (Class 524/489)
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Patent number: 5804266Abstract: A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene-vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments.Type: GrantFiled: March 28, 1996Date of Patent: September 8, 1998Assignee: The University of DaytonInventor: Ival O. Salyer
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Patent number: 5763516Abstract: Hot-melt adhesive compositions useful for packaging are disclosed. These hot-melt adhesive compositions are based on modified polyethylene and contain a linear, low density copolymer or terpolymer of ethylene and another alpha-olefin, a polyethylene graft copolymer, a tackifying resin, and a high-melting low viscosity wax. The hot-melt adhesive compositions disclosed herein produce very good adhesive bonds, even at high speed packaging conditions under a broad range of ambient packaging temperatures. These inventive adhesive compositions have a novel combination of good hot tack and good adhesive bond properties, even at extreme conditions.Type: GrantFiled: April 24, 1996Date of Patent: June 9, 1998Assignee: H.B. Fuller Licensing & Financing, Inc.Inventor: Darryl Aubrey Godfrey
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Patent number: 5717021Abstract: The present invention involves blends of polycarbonate resin with rubber grafted terpolymer resin, one or more styrenic rigid coplymers wherein a small amount of an aliphatic C.sub.4 to C.sub.16 polyalpha olefin homopolymer or copolymer or its functionalized derivatives is included in the blend.Type: GrantFiled: November 18, 1996Date of Patent: February 10, 1998Assignee: General Electric CompanyInventors: Jianing Huang, Ronald L. Jalbert, Mark Giammattei, Gregory J. Stoddard
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Patent number: 5686515Abstract: A process for manufacture of articles comprised of polyethylene terephthalate wherein the PET is colored with a composition comprised of a wax dispersant, ethylene copolymer, and a colorant. In a preferred embodiment, the wax dispersant is a maleated polyethylene wax. In an alternative embodiment, the wax dispersant is a low molecular weight polyethylene wax and the composition further includes linear low density polyethylene. A preferred ethylene copolymer is ethylene-(meth)acrylic acid.Type: GrantFiled: November 13, 1995Date of Patent: November 11, 1997Assignee: The M.A. Hanna CompanyInventors: Tracy L. Phillips, Ronald M. Harris, Alan R. Burgess, Judy A. Johnston
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Patent number: 5670566Abstract: A carton, case or tray formed utilizing a hot melt adhesive composition said adhesive consisting essentially of a) 10 to 60% by weight of at least one ethylene n-butyl acrylate copolymer containing 25 to 45% by weight n-butyl acrylate and having a melt index of at least about 850; b) 20 to 60% of a rosin ester tackifying resin; c) 10 to 50% by weight of a microcrystalline or paraffin wax having a melting point of 150.degree. to 200.degree. F.; d) 1 to 20% by weight of a polymeric additive selected from the group consisting of ethylene vinyl acetate containing 10 to 40% by weight vinyl acetate, ethylene methyl acrylate polymers containing 10 to 28% methyl acrylate, ethylene acrylic acid copolymers having an acid number of 25 to 150, polyethylene, polypropylene, poly-(butene-1-co-ethylene), and lower melt index ethylene n-butyl acrylate copolymers; and e) 0 to 1.5% stabilizer, said adhesive characterized by a viscosity of less than 3000 cps at 135.degree. C., fiber tearing bonds from within the range of -35.Type: GrantFiled: January 6, 1995Date of Patent: September 23, 1997Assignee: National Starch and Chemical Investment Holding CorporationInventors: Ingrid Liedermooy, Daniel C. Stauffer, Paul P. Puletti
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Patent number: 5643984Abstract: A new wax composition for use in the ink industry, which composition is prepared from: (a) 40% to 90% of solvent having a boiling point within the range of about 100.degree. to 550.degree. C., said solvent being selected from the group consisting of aromatic and aliphatic solvents, (b) 10% to 40% of wax having an average particle size within the range of about 1 to about 300 microns, (c) 5% to 40% of polymeric pour point depressant, and optionally dependant on the characteristics required, 4% to 40% of a resin material which is soluble in aromatic and aliphatic solvents.Type: GrantFiled: January 3, 1996Date of Patent: July 1, 1997Assignee: Flint Ink CorporationInventors: Raymond J. Mueller, George S. Hassaballa
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Patent number: 5621032Abstract: A method and product which provides a solid, non-powdered homogeneous form to liquid and low melting point solid compounds which facilitates stability, storage, dispersability and handling and which may be added directly to formulations requiring the liquid compound or low melting point solid compound. The liquid or low melting point solid ingredient is combined with a binder which is comprised of at least a wax and thermoplastic polymer. During the method of forming the product, both the binder and the liquid compound (or low melting point solid compound) pass through a liquid phase during which they are mixed. The product is then formed and cooled.Type: GrantFiled: April 26, 1995Date of Patent: April 15, 1997Assignee: Elastochem, Inc.Inventors: Richard D. Cortelezzi, Clifford C. Martin
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Patent number: 5565132Abstract: A thermoplastic, moldable, non-exuding phase change material in the form of a composite useful for thermal energy storage. The composite is preferably a solidified melt mixture of a polyolefin resin, and ethylene copolymer, silica particles and a fatty acid, fatty acid ester, primary alcohol or hydrocarbon phase change material. For a microwave heating capability, a microwave absorbing additive may be added as a fifth major ingredient. The composite can be formed into a variety of configurations such as pellets, sheets, rods, tubes, plugs for hollow core cement blocks, films, and fibers, all for thermal energy storage uses.Type: GrantFiled: June 6, 1995Date of Patent: October 15, 1996Assignee: The University of DaytonInventor: Ival O. Salyer
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Patent number: 5530054Abstract: Disclosed are hot melt adhesives comprising ethylene/alpha-olefin copolymers prepared with either supported or unsupported metallocene-alumoxane catalysts for applications in hot melt adhesives used in automotive product assembly, packaging and food packaging. These ethylene copolymers have weight average molecular weight ranging from about 20,000 to about 100,000 and comonomer weight percent ranging from about 6 to about 30. The hot melt adhesive composition includes the ethylene copolymer and a compatible tackifier at a ratio of tackifier to copolymer of from 70:30 to 30:70 and may also include up to 30 weight percent of a paraffinic and microcrystalline wax of the copolymer and tackifier.Type: GrantFiled: March 24, 1995Date of Patent: June 25, 1996Assignee: Exxon Chemical Patents Inc.Inventors: Mun F. Tse, Aspy K. Mehta, Vince L. Hughes
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Patent number: 5527869Abstract: A composition of methacrilic resin which constitutes a resin possessing an outstandingly easy release from the mold of injection molding machine without defilement of the stamper and the peripheral ring of stamper holder, and therefore proves suitable material for replica of raser disk is provided. This methacrylic resin composition is characterized by having incorporated in a methyl methacrylate copolymer the three lubricant components, i.e. a higher alcohol (x), a monoglyceride of a higher fatty acid (y), and a paraffin (z), in such amounts that the individual contents of (x), (y), and (z) are in the respective ranges of 0.05 to 0.2% by weight, 0.05 to 0.2% by weight, and 0.02 to 0.15% by weight and the total content of (x), (y), and (z) is in the range of 0.2 to 0.35% by weight.Type: GrantFiled: April 18, 1995Date of Patent: June 18, 1996Assignee: Kuraray Co., Ltd.Inventors: Yoshio Fuchigami, Kouichi Warino, Shigeo Matsumaru, Yosokichi Kobayashi
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Patent number: 5510408Abstract: A composition of methacrilic resin which constitutes a resin possessing an outstandingly easy release from the mold of injection molding machine without defilement of the stamper and the peripheral ring of stamper holder, and therefore proves suitable material for replica of raser disk is provided. This methacrylic resin composition is characterized by having incorporated in a methyl methacrylate copolymer the three lubricant components, i.e. a higher alcohol (x), a monoglyceride of a higher fatty acid (y), and a paraffin (z), in such amounts that the individual contents of (x), (y), and (z) are in the respective ranges of 0.05 to 0.2% by weight, 0.05 to 0.2% by weight, and 0.02 to 0.15% by weight and the total content of (x), (y), and (z) is in the range of 0.2 to 0.35% by weight.Type: GrantFiled: May 26, 1994Date of Patent: April 23, 1996Assignee: Kuraray Co., Ltd.Inventors: Yoshio Fuchigami, Kouichi Warino, Shigeo Matsumaru, Yosokichi Kobayashi
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Patent number: 5500472Abstract: Hot melt adhesive compositions consisting essentially of: a) 15 to 45% by weight of at least one ethylene n-butyl acrylate copolymer containing 15 to 40% by weight n-butyl acrylate and having a melt index of at least 600; b) 25 to 55% of a terpene phenolic tackifying resin or a hydrogenated derivative thereof, the resin having a Ring and Ball softening point less than 125.degree. C.; c) 15 to 40% by weight of a low melting point synthetic Fischer-Tropsch wax; and d) 0 to 1.5% stabilizer. The adhesives are characterized by an excellent balance of high and low temperature performance without sacrifice to machinability or thermal stability.Type: GrantFiled: February 17, 1995Date of Patent: March 19, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventors: Ingrid Liedermooy, Julie Birch, Daniel C. Stauffer, Paul P. Puletti
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Patent number: 5470897Abstract: A radically curable coating composition containing) 50 to 95 parts by weight of an unsaturated polyester component having a viscosity at 23.degree. C. of 1,000 to 15,000 mPa.s, B) 5 to 50 parts by weight of compounds containing (meth)acryloyl groups and/or vinyl ether groups, C) 0.01 to 0.3 wt. %, based on the total weight, of waxes and/or paraffins having a melting point of 35+ to 100.degree. C. and D) 0 to 10 wt. %, based on the total weight, of at least one plasticizer or carbamic acid resin, and the use of the coating composition for coating substrates, in particular wood substrates.Type: GrantFiled: April 28, 1994Date of Patent: November 28, 1995Assignee: Bayer AktiengesellschaftInventors: Jurgen Meixner, Wolfgang Fischer, Manfred Muller
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Patent number: 5441999Abstract: The foregoing and other objects and advantages of the present invention are accomplished by a hot melt adhesive comprising a blend of a low molecular weight polyolefin, olefin-carboxylic acid graft polymer or olefin-maleic anhydride graft polymer or blend thereof; a propylene-ethylene copolymer or propylene-ethylene-butene terpolymer; and a tackifying resin or blend of tackifying resins. The blend can include an antioxidant or blends of antioxidants, a high molecular weight or functionalized polyolefin or a copolymer or terpolymer of a vinyl monomer (e.g., ethylene/vinyl acetate).Type: GrantFiled: October 15, 1993Date of Patent: August 15, 1995Assignee: Reichhold Chemicals, Inc.Inventors: Neil R. Jarvis, Anil B. Goel
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Patent number: 5441998Abstract: A composition is provided which, when added to an elastomer or tackifier, renders a repulpable hot melt adhesive. The compositions consists of an alkoxylated alcohol of the formulaA-B (I)wherein A is the unit ##STR1## and B is the unit ##STR2## and further wherein R and R.sub.1 are independently selected from the group consisting of hydrogen and a C.sub.1 -C.sub.10 alkyl group; R.sub.2 is hydrogen or a C.sub.1 -C.sub.5 alkyl group; x is between about 1 to about 142; and y is between about 2 to about 817, provided the weight ratio of B/A+B is between 51 and 90 percent. Such adhesive compositions may further contain wax or a primary linear polymeric alcohol. When combined with an elastomer and tackifier, such adhesives are repulpable and thus have particular applicability when used in combination with recyclable paper.Type: GrantFiled: February 16, 1993Date of Patent: August 15, 1995Assignee: Petrolite CorporationInventors: Susan M. Teeters, Charles H. Heroux, Michael D. Watson, William P. Cottom, Terrance D. Duryee
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Patent number: 5437722Abstract: The water resistance of gypsum compositions, such as those used in gypsum wallboard, is improved by incorporating in the compositions an aqueous emulsion containing a paraffinic hydrocarbon having a melting point of 40.degree. to 80.degree. C., montan wax and polyvinyl alcohol.Type: GrantFiled: March 1, 1994Date of Patent: August 1, 1995Assignee: Bakor Inc.Inventor: Lionel Borenstein
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Patent number: 5416153Abstract: Polyolefin molding composition of high rigidity and hardnessA polyolefin molding composition essentially comprisinga) a polyolefin wax andb) a high-molecular-weight polyolefin or, instead of b),c) a high-molecular-weight olefin copolymer has high rigidity and hardness.In order to increase the impact strength, this molding composition may additionally be admixed with a rubber having a glass transition temperature of below -20.degree. C.Type: GrantFiled: June 22, 1994Date of Patent: May 16, 1995Assignee: Hoechst AktiengesellschaftInventors: Andreas Winter, Bernd Bachmann
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Patent number: 5391601Abstract: The present invention relates to a blend of a linear or branched chain saturated aliphatic hydrocarbon wax having a molecular weight of between about 300 to about 5,000 and an alkoxylated alcohol of the formula A--B, wherein A is the unit: CH.sub.3 (CHR--CHR.sub.1).sub.x -- and B is the unit: --CH.sub.2 O(CH.sub.2 CHR.sub.2 O).sub.y H. R and R.sup.1 are independently selected from the group consisting of hydrogen and a C.sub.1 -C.sub.10 alkyl group; R.sub.2 is hydrogen or a C.sub.1 -C.sub.5 alkyl group; x is between about 1 to about 142; and y is between about 2 to about 817, provided the weight ratio of B/A+B is between 51 and 90 percent. Such blends may be used with an elastomer and tackifier to form a repulpable laminating adhesive. The invention further relates to a laminating adhesive containing alkoxylated alcohol, elastomer, wax and tackifier.Type: GrantFiled: February 16, 1993Date of Patent: February 21, 1995Assignee: Petrolite CorporationInventors: Susan M. Teeters, Charles H. Heroux, Michael D. Watson, William P. Cottom, Terrance D. Duryee
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Patent number: 5384353Abstract: A thermoplastic resin composition is provided comprising an aromatic polycarbonate resin, rubber modified vinyl aromatic-vinyl cyanide graft copolymer, and glass fibers which have been treated with polyolefin wax and optionally a functionalized silane. The nature of the coating on the glass fibers provides the composition with improved impact strength over binding glass. The composition is useful as molding material.Type: GrantFiled: May 12, 1993Date of Patent: January 24, 1995Assignee: General Electric CompanyInventors: Linda M. Gemmell, Otho W. Tennant, Robert R. Gallucci
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Patent number: 5382615Abstract: Hot-melt adhesive compositions useful for packaging are disclosed. These hot-melt adhesive compositions are based on modified polyethylene and contain an ethylene-alkylacrylate copolymer, a polyethylene graft copolymer, a tackifying resin, and a high-melting low viscosity wax. The hot-melt adhesive compositions disclosed have fast setting times and a novel combination of desired properties with good high and low temperature bond strength.Type: GrantFiled: October 1, 1993Date of Patent: January 17, 1995Assignee: Eastman Chemical CompanyInventor: Darryl A. Godfrey
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Patent number: 5373049Abstract: Hot-melt adhesives, useful for both glue-pot and glue-gun applications, are formulated so that they can be applied at temperatures no higher than 280.degree. F. and preferably at temperatures of at most 250.degree. F. The adhesive compositions have a heat resistance of at least 125.degree. F. and are readily shaped into glue sticks for use in glue guns, The adhesive for the hot-melt adhesive compositions is suitably compounded with tackifying resin and/or wax. The resulting composition has a sharp viscosity profile, which is readily achieved, e.g., by using a high melt index adhesive polymer as an essential component.Type: GrantFiled: May 31, 1991Date of Patent: December 13, 1994Assignee: Adhesive TechnologiesInventors: Robert L. Ornstern, Peter S. Melendy, Dennis J. Fitzmeyer
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Patent number: 5362792Abstract: An adhesive composition is comprised of a mixture of an EVA copolymer and two tackifying resins, a high temperature tackifying resin and a low temperature tackifying resin. The viscosity of the adhesive composition is between 2,000 cps to 80,000 cps over a temperature range of 250.degree. F. to 380.degree. F. The composition comprises 60% by weight of the copolymer, 15% by weight of the low temperature tackifying resin and 25% by weight of the high temperature tackifying resin.Type: GrantFiled: June 1, 1993Date of Patent: November 8, 1994Assignee: Uniplast, Inc.Inventor: Elias S. Maayeh
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Patent number: 5346942Abstract: The present invention provides a monolithic refractory with self-flowability. A monolithic refractory of the first invention of the present invention contains refractory aggregates, liquid novolak type phenol resin and an organic separation preventative. A monolithic refractory of the second invention of the present invention contains refractory aggregates and a novolak type phenol resin solution with a number-average molecular weight of not more than 600. The first invention of the present invention gives good hot flowability and prevention of sedimentation of the aggregates to the monolithic refractory. The second invention gives good hot flowability, stabilization in adhesion and prevention of warpage of the hardened body obtained. With the present invention a monolithic refractory can be suitably selected and used according to its intended use and purpose.Type: GrantFiled: March 22, 1993Date of Patent: September 13, 1994Assignee: Shinagawa Refractories Co., Ltd.Inventors: Takashi Yamamura, Ryosuke Nakamura, Hiroshi Kiriyama
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Patent number: 5338790Abstract: A polymer composition having a good balance of improved mechanical properties and optical properties such as low haze, which comprisesa) propylene-butene random copolymer,b) at least one additive, andc) a clarifying agent which is calcium montanate, at least one polyolefin wax or combinations thereof.Type: GrantFiled: July 14, 1993Date of Patent: August 16, 1994Assignee: Shell Oil CompanyInventor: Ananda M. Chatterjee
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Patent number: 5334644Abstract: Aqueous application systems for applying additives to polymeric particles, methods of preparing aqueous emulsions which include at least one processing, stabilizing or other functional polymer additive and an emulsifiable wax. Also disclosed are methods of applying additives to polymeric particles and to polymeric particles treated by such methods.Type: GrantFiled: March 2, 1993Date of Patent: August 2, 1994Assignee: Eastman Chemical CompanyInventors: William C. Gose, Kenneth W. Hyche
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Patent number: 5331033Abstract: Hot melt packaging adhesive compositions consisting essentially of 20 to 50% by weight of an ethylene n-butyl acrylate copolymer containing 25-45% by weight, preferably 30 to 40% n-butyl acrylate and having a melt index of at least 10; 30 to 60% of an aliphatic or cycloaliphatic hydrocarbon resin or hydrogenated derivative thereof or a hydrogenated aromatic hydrocarbon resin; and 10 to 30% by weight of a high melting synthetic wax provide adhesives characterized by an excellent balance of high and low temperature performance without sacrifice to machinability or thermal stability. Further, the adhesive is characterized by a low density and consequently is readily filterable in recycling systems.Type: GrantFiled: February 23, 1993Date of Patent: July 19, 1994Assignee: National Starch and Chemical Investment Holding CorporationInventors: Daniel Stauffer, Paul P. Puletti, Thomas F. Kauffman
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Patent number: 5300538Abstract: An erasable highlighting composition is provided including a block copolymer, a wax, and a fluorescent pigment. The composition is in solid form, and, when applied to an underlying marking on a substrate, is capable of forming a highlighting marking which may be erased without lifting the underlying marking.Type: GrantFiled: June 2, 1992Date of Patent: April 5, 1994Assignee: The Gillette CompanyInventor: Rachel M. Loftin
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Patent number: 5284890Abstract: The invention disclosed relates to an injection mouldable synthetic rubber composition which provides twenty-four hour protection from penetration by H-agent and as such is particularly suitable for use in gas masks. The novel rubber composition comprises a synthetic rubber such as bromobutyl rubber, carbon black and other appropriate additives.Type: GrantFiled: January 31, 1985Date of Patent: February 8, 1994Assignee: Her Majesty the Queen as represented by the Minister of National Defence of Her Majesty's Canadian GovernmentInventors: John C. Collyer, John R. Clark
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Patent number: 5270360Abstract: A two-phase thermoplastic composition adapted for forming thermoplastic patterns. The composition comprises an organic thermoplastic pattern material and at least about 5% by weight of discrete particles of cross-linked poly(methylmethacrylate) that are physically stable at temperatures above 130.degree. F. Also disclosed are investment casting patterns of such composition and processes utilizing such composition.Type: GrantFiled: January 3, 1992Date of Patent: December 14, 1993Assignee: Yates Manufacturing CompanyInventor: Paul Solomon
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Patent number: 5256717Abstract: Hot melt adhesives having suitable open time and crystallinity properties making them especially useful as temporary adhesives are provided by a composition comprising a combination of 5 to 50% by weight of an isotactic thermoplastic polybutylene copolymer or a low density ethylene polymer with 3 to 65% by weight of a solid benzoate plasticizer.Type: GrantFiled: December 19, 1990Date of Patent: October 26, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Daniel Stauffer, Paul Puletti
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Patent number: 5252421Abstract: An electrophotographic is disclosed, comprising a binder resin, a coloring material, and a polyalkylene, wherein the polyalkylene has an average particle volume of 0.05 .mu.m.sup.3 or more. The toner exhibits broadened fixing latitude when fixed by heat roll fixing without using any offset inhibiting liquid.Type: GrantFiled: February 13, 1991Date of Patent: October 12, 1993Assignee: Fuji Xerox Co., Ltd.Inventors: Masanori Ichimura, Toru Murakami, Koichi Oyamada
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Patent number: 5223562Abstract: A thermosetting powder coating composition comprises (a) a fluororesin having reactive group for crosslinking in the molecule which contains 10 weight % or more of fluorine and has glass transition temperature in the range from 35.degree. to 120.degree. C., (b) a hardener which can form crosslinking by reaction with the reactive group for crosslinking in the fluororesin (a) and (c) a synthetic wax or a natural wax. The amount of the fluororesin is in the range from 60 to 97 weight % and the amount of the hardener is in the range from 3 to 40 weight % based on the total of the fluororesin and the hardener. The amount of the synthetic wax or the natural wax is in the range from 0.01 to 10 weight parts based on 100 weight parts of the total of the fluororesin and the hardener.Type: GrantFiled: October 13, 1992Date of Patent: June 29, 1993Assignee: NOF CorporationInventors: Chiaki Sagawa, Manabu Katagiri, Toru Kurashina
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Patent number: 5189102Abstract: A method for producing a vinyl resin comprising the steps of dissolving or dispersing a polymerizable vinyl monomer in a polymerization solvent containing a silicone oil, and polymerizing the polymerizable vinyl monomer in the presence of a polymerization catalyst.Type: GrantFiled: March 4, 1992Date of Patent: February 23, 1993Assignee: Ricoh Company, Ltd.Inventors: Kazuo Tsubuko, Shinichi Kuramoto, Kazuhiko Umemura, Hidemi Uematsu, Okawara, Makoto
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Patent number: 5176779Abstract: Adhesively edge-padded stack of carbonless copy paper better separates upon fanning into collated sets when a thin layer of hot-melt adhesive is used for the edge-padding. As in the prior art, the outer surfaces of each set should have a release coating such as a fluorocarbon. The layer of hot-melt adhesive includes, by weight:20-50% thermoplastic copolymer,15-50% tackifying resin, and20-60% wax having a melting point of at least 60.degree. C.As soon as the adhesive has cooled below its softening point, the stack can be fanned, thus breaking it into sets. Fanning can usually be performed within 45 seconds, because there is no need to wait for the adhesive to dry as has been necessary with the aqueous adhesives that have been used in the prior art. Preferably at least 20% by weight of the adhesive is a paraffin wax that is [.alpha.] C.sub.35 -C.sub.70 substantially straight-chain hydrocarbon.Type: GrantFiled: February 12, 1991Date of Patent: January 5, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kenneth J. Perrington, James M. DeWanz
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Patent number: 5155160Abstract: The barrier properties of crystalline polyolefin film can be improved substantially by incorporating a precise amount of a partially incompatible wax into the polyolefin. When the polyolefin is polypropylene or polybutylene, the wax is preferably a paraffin wax. The precise amount of wax, which produces optimum improvement in barrier properties, lies in the range of about 3 to 10 percent based on the weight of the polyolefin. The range in which excellent results are obtained can be broadened by contacting the film with a cooling medium immediately after it is extruded. The film may be annealed to further improve the barrier properties.Type: GrantFiled: July 10, 1990Date of Patent: October 13, 1992Assignee: James River II, Inc.Inventors: Gene H. Yeh, Attila Matray, Allyn J. Ziegenhagen
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Patent number: 5155155Abstract: An oxidized polyethylene wax or other wax in the form of a salt with a metal selected from groups IB, IIB, IIA, IIIA, IIIB, VIB, VIIB and VIIIB of the Periodic Table of the Elements acts as a photoactivator in a polymer composition and degrades the latter. The quantity of the additive can vary from 0.1 to 2.0% by weight, relative to the weight of the composition. The additive can be added directly or, more suitably, via a masterbatch.Type: GrantFiled: August 26, 1991Date of Patent: October 13, 1992Assignee: Hoechst Italia, S.p.A.Inventor: Riccardo Jurlaro
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Patent number: 5153064Abstract: The invention describes a hot-melt adhesive substance for the coating of fabrics, especially of lining materials of outer wear, comprising a hot-melt adhesive paste on a copolyester basis as the base layer and a covering layer of a hot-melt adhesive. The inventive hot-melt adhesive substance is characterized in that the hot-melt adhesive paste of the base layer contains a mixture of copolyester and low-pressure polyethylene. The covering layer of hot-melt adhesive preferably contains copolyamide. When using the inventive hot-melt adhesive substance, a raster-pattern coated fabric can be obtained in which the hot-melt adhesive substance has substantially improved adhesive strength as well as a high degree of washing and cleaning stability.Type: GrantFiled: May 10, 1991Date of Patent: October 6, 1992Assignee: Kufner Textilwerke GmbHInventor: Josef Hefele
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Patent number: 5145749Abstract: Erasable coatings for xerography paper comprise a pigment such as calcium carbonate in a binder such as an aqueous emulsion of an acrylic polymer. The erasability of the coating is improved by replacing at least 15 wt % of the binder with a polyalkane or (preferably) polyalkene wax, such as an aqueous emulsion of a polyolefin.Type: GrantFiled: June 7, 1989Date of Patent: September 8, 1992Assignee: James River Graphics LimitedInventor: Michael K. Matthew
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Patent number: 5115067Abstract: Disclosed is a molecularly oriented molded body of an ultra-high-molecular-weight ethylene/.alpha.-olefin copolymer having an intrinsic viscosity (.eta.) of at least 5 dl/g and such a content of an .alpha.-olefin having at least 3 carbon atoms that the number of molecules of the .alpha.-olefin is 0.1 to 15 on the average per 1000 carbon atoms, wherein the molded body shows at least two crystal fusion endothermic peaks when the measurement is conducted in the restraint state by using a differential scanning calorimeter, the molded body has at least one crystal fusion endothermic peak (Tp) at a temperature higher by at least 20.degree. C. than the inherent crystal fusion temperature (Tm) of the ultra-high-molecular-weight ethylene/.alpha.-olefin copolymer determined as the main fusion endothermic peak at the time of the second elevation of the temperature, and the quantity of heat based on said crystal fusion endothermic peak (Tp) is at least 15% based on the total fusion heat quantity.Type: GrantFiled: April 4, 1990Date of Patent: May 19, 1992Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuo Yagi, Akinori Toyota
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Patent number: 5106677Abstract: The barrier properties, particularly water vapor transmission rate, of compositions comprising a stryene-butadiene polymer can be improved substantially by adding from about 0.5 to 10 percent of a polyethylene type wax to the composition.Type: GrantFiled: November 3, 1989Date of Patent: April 21, 1992Assignee: James River II Inc.Inventors: Gene H. Yeh, Stephen O. Cook
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Patent number: 5104921Abstract: A cured composition possessing excellent cohesive strength at high temperatures along with excellent adhesion, shear strength and solvent resistance is prepared by the high energy ionizing radiation initiated curing of a polymer composition comprising an alkenyl arene/conjugated diene block copolymer and a oligomer such that the unsaturation index of the composition is minimized. The radiation initiated curing of the adhesive composition is accomplished without requiring the aid of a coupling agent to promote crosslinking of the block copolymer during exposure to the radiation.Type: GrantFiled: October 12, 1989Date of Patent: April 14, 1992Assignee: Shell Oil CompanyInventors: James R. Erickson, Earle E. Ewins, Jr.
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Patent number: 5098943Abstract: A water repellent having the following components (A), (B), (C) and (D) emulsified in water:(A) a wax having a melting point of from 40.degree. to 90.degree. C.;(B) a styrene-maleic anydride copolymer;(C) a water-soluble alkaline compound; and(D) a polyvinyl alcohol having a saponification degree of at least 85 mol %.Type: GrantFiled: May 9, 1991Date of Patent: March 24, 1992Assignee: Mitsubishi Kasei CorporationInventors: Toru Tagawa, Takao Tadenuma, Yasoji Ozawa
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Patent number: 5087669Abstract: A vinyl chloride polymer formulation having a chlorinated olefin polymer as an impact modifier, and an oxidized high density polyethylene homopolymer having an acid number of from about 5 to about 40 as a fusion promoter can be converted into shaped articles. The invention includes an improved olefin polymer impact modifier composition for use with vinyl chloride polymer formulations, the composition comprising a combination of said chlorinated olefin polymer and said oxidized high density polyethylene homopolymer. The vinyl chloride polymer formulation of the present invention is useful, for example, as a feedstock for the preparation of shaped articles such as vinyl siding and vinyl window frames.Type: GrantFiled: September 18, 1989Date of Patent: February 11, 1992Assignee: The Dow Chemical CompanyInventor: Thomas G. Prejean
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Patent number: 5081174Abstract: A formable, weldable, removable protective coating composition for use on metals, said coating comprising a combination of a base-neutralized acid-funtional copolymer and a wax lubricant, and further comprising a removability enhancing means such as phosphoric acid as an additive to the coating composition.Type: GrantFiled: October 2, 1989Date of Patent: January 14, 1992Assignee: PPG Industries, Inc.Inventor: Ellor J. VanBuskirk
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Patent number: 5073457Abstract: Repositionable adhesives which display surprising latent permanent adhesive properties are described herein. These adhesives are comprised of acrylic pressure sensitive resins. These pressure-sensitive adhesive resins can be either solvent based or water based. In the case of a solvent-based adhesive system, paraffin wax is used, while in the water-based systems, latex emulsions of polyethylene are preferred.Type: GrantFiled: May 17, 1990Date of Patent: December 17, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventor: Elmer Blackwell
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Patent number: 5063271Abstract: Hot melt wax compositions and a process for producing said hot melt wax compositions are disclosed. The wax compositions are suitable for coating fibrous materials, for example, paper and corrugated paper boards. The coating compositions comprise a mixture of a fully refined paraffin wax, a petroleum wax selected from the group consisting of a recrystallized heavy intermediate wax, a microcrystalline wax and mixtures thereof, a polymeric hydrocarbon compound, a tackifier resin and optionally, a phenolic anti-oxidant.Type: GrantFiled: May 31, 1990Date of Patent: November 5, 1991Assignee: Conoco Inc.Inventor: Richard L. Jones
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Patent number: 5055498Abstract: The solid marking composition of the invention includes from about 15% up to about 50% by weight of a polyethylene resin component having a specific gravity in the range of from about 0.95 up to about 0.96. In addition, the composition of the invention includes from about 20% up to about 55% by weight of a compatible plasticizer, and from about 3% up to about 20% by weight active material of a pigment. Optionally, the composition may include a pigment dispersing agent, such as a fatty acid. Further additives which may advantageously employed include extenders or fillers, oxidation stabilizers, UV stabilizers, and mold release agents. The composition of the invention is fabricated into marking instruments having unexpectedly improved eraseability, ease of application, barrel breaking strength, and tip breaking strength, while eliminating bloom entirely.Type: GrantFiled: June 19, 1990Date of Patent: October 8, 1991Assignee: Binney & Smith Inc.Inventor: Armand E. Brachman
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Patent number: 5041484Abstract: Flame retardant hot melt adhesives include atactic polypropylene having grafted thereon a ring-halogenated styrene. The compositions may also include homopolymers of the styrene monomer or equivalents, as well as non-halogenated atactic polypropylene. Tackifying agents, waxes, anti-oxidants and other additives may also be included.Type: GrantFiled: June 20, 1990Date of Patent: August 20, 1991Assignee: Great Lakes Chemical CorporationInventors: Ray W. Atwell, Donna L. Collison, Nicolai A. Favstritsky, Enrico J. Termine
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Patent number: 5041492Abstract: Hot melt adhesive compositions for bonding rigid polypropylene substrates comprise intimate blends of an amorphous copolyolefin copolymer, a polyolefin wax, a rosin-based ester resin and a polybutylene copolymer.Type: GrantFiled: February 21, 1990Date of Patent: August 20, 1991Assignee: Findley Adhesives, Inc.Inventors: George Koprowicz, Patrick Czaplewski, Michael Kaczkowski
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Patent number: 5036129Abstract: Flame retardant hot melt adhesives include ethylene vinyl acetate having grafted thereon a ring-halogenated styrene. The compositions may also include homopolymers of the styrene monomer of equivalents, as well as non-halogenated ethylene vinyl acetate. Tackifying agents, waxes, anti-oxidants and other additives may also be included.Type: GrantFiled: April 17, 1990Date of Patent: July 30, 1991Assignee: Great Lakes Chemical CorporationInventors: Ray W. Atwell, Nicolai A. Favstritsky, John P. Stallings, Enrico J. Termine