Aldehyde Reaction Product Patents (Class 524/49)
  • Patent number: 9187668
    Abstract: Metal deco ink formulations are improved by the use of fluorescent dyes, UV-absorbing dyes and/or IR-absorbing dyes. These may be premixed with a phenol-formaldehyde resin without microencapsulation to protect the dye from other ink ingredients that have chemistries which are incompatible with that of the dye, in order to obtain photochromic ink formulation with a good shelf life.
    Type: Grant
    Filed: October 29, 2012
    Date of Patent: November 17, 2015
    Assignee: Chromatic Technologies, Inc.
    Inventors: Timothy J. Owen, Eric Cathie, Kristin A. Fletcher
  • Patent number: 8815003
    Abstract: Crosslinking systems suitable for use in a polymer melt composition wherein the polymer melt composition comprises a hydroxyl polymer; polymeric structures made from such polymer melt compositions; and processes/methods related thereto are provided.
    Type: Grant
    Filed: November 20, 2013
    Date of Patent: August 26, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Stephen Wayne Heinzman, Linda Evers Smith, Gregory Charles Gordon, Larry Neil Mackey, John Gerhard Michael, Mark Ryan Richards
  • Patent number: 8759279
    Abstract: A film formed from a biodegradable polymer matrix within which is contained at least one fragrance is provided. The ability to incorporate a fragrance into the polymer matrix is achieved in the present invention by controlling a variety of aspects of the film construction, including the nature of the fragrance, the nature of the biodegradable polymer, the manner in which the polymer matrix and fragrance are melt processed, etc. For example, the fragrance may be injected directly into the extruder and melt blended with the biodegradable polymer. In this manner, the costly and time-consuming steps of pre-encapsulation or pre-compounding of the fragrance into a masterbatch are not required. Furthermore, to obtain a balance between the ability of the fragrance to release the desired odor during use and likewise to minimize the premature exhaustion of the odor during melt processing, the fragrance is selected to have a boiling point (at atmospheric pressure) within a certain range, such as from about 125° C.
    Type: Grant
    Filed: June 30, 2008
    Date of Patent: June 24, 2014
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Sara A. Funk, James H. Wang
  • Patent number: 8691003
    Abstract: An indicator is useful for detecting pressure points on a denture. The indicator is made of a composition that easily adheres to oral mucosa, has a proper viscosity in an oral cavity environment, can be properly spread between an oral mucosa surface and a denture base, and easily specifies an affected part. The composition includes a fatty acid ester having a melting point of 30 to 50° C., a water-soluble high polymer, and a metal oxide. Preferably, the fatty acid is 40 to 95% by weight of the composition, the water-soluble high polymer is 1 to 59% by weight of the composition, and the metal oxide is 0.1 to 50% by weight of the composition.
    Type: Grant
    Filed: September 29, 2011
    Date of Patent: April 8, 2014
    Assignee: GC Corporation
    Inventors: Yutaka Shinozaki, Hiroshi Kamohara
  • Patent number: 8410200
    Abstract: A polymer composition and its use for thin film packaging applications including on a dry basis: a) from 45 to 90% by weight of starch; b) from 0.1 to 15% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinyl alcohol which have a melting point compatible with the molten state of the starch component; and c) from 5 to 45% by weight of one or more plasticizers having a molecular weight in the range of 50-6000, more preferably 50-2500 and more preferably still 100-400 and desirably selected from the group consisting of sorbitol, glycerol, maltitol, xylitol, mannitol, erythritol, glycerol trioleate, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate, polyethylene oxide, ethylene glycol, diethylene glycol or polyethylene glycol.
    Type: Grant
    Filed: April 18, 2007
    Date of Patent: April 2, 2013
    Assignee: Plantic Technologies Limited
    Inventors: Nicholas R. Oakley, Nicholas J. McCaffrey, Kishan C. Khemani
  • Patent number: 8357237
    Abstract: Crosslinking systems suitable for use in a polymer melt composition wherein the polymer melt composition comprises a hydroxyl polymer; polymeric structures made from such polymer melt compositions; and processes/methods related thereto are provided.
    Type: Grant
    Filed: January 10, 2012
    Date of Patent: January 22, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Stephen Wayne Heinzman, Linda Evers Smith, Gregory Charles Gordon, Larry Neil Mackey, John Gerhard Michael, Mark Ryan Richards
  • Patent number: 7854994
    Abstract: A barrier composition which is injection mouldable and able to be made into a transparent film or incorporated (by co-extrusion and/or lamination) into multi-layer film products, the composition on dry basis: a) from 45 to 90% by weight of a starch and/or a modified starch selected from starches modified by reaction with a hydroxyl alkyl group, an acetate or a dicarboxylic acid anhydride or a grafting polymer; b) from 4 to 12% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten state of the starch components c) from 5 to 45% by weight of a non-crystallising mixture of sorbitol and at least one other plasticizer selected from glycerol, maltitol, xylitol, mannitol, glycerol trioleate, epoxidised linseed or soybean oil, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate; polyethylene oxide or polyethylene glycol; d) from
    Type: Grant
    Filed: October 18, 2005
    Date of Patent: December 21, 2010
    Assignee: Plantic Technologies Ltd.
    Inventors: Rulande Henderson-Rutgers, Mark Fink, Nicholas Roy Oakley
  • Patent number: 7255732
    Abstract: Starch can be gelatinised more efficiently by a thermomechanical treatment, if a dialdehyde polysaccharide with a relatively low degree of oxidation is added to the starch. This thermomechanical treatment can be carried out at a temperature below 115 DEG C., or even below 100 DEG C., and with a high throughput rate. With this treatment a granulate or other semi-finished product is obtained that can be shaped to produce an article that has excellent dimensional stability in water. By adding dialdehyde polysaccharide with a low degree of oxidation to starch it is possible to blow transparent films based on thermoplastic starch which have improved mechanical properties.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: August 14, 2007
    Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno
    Inventors: Sabine Fischer, Eric G. M. Craenmehr, Jan J. De Vlieger, Theodoor M. Slaghek
  • Patent number: 7025821
    Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.
    Type: Grant
    Filed: October 7, 2004
    Date of Patent: April 11, 2006
    Assignee: The Procter & Gamble Company
    Inventors: Larry Neil Mackey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
  • Patent number: 6896725
    Abstract: The invention concerns the use of a water-soluble or water-dispersible polymer having a molecular weight of at least 800, containing at least 5 aldehyde groups per molecule and at least 1 carboxyl group per molecule, the ratio of aldehyde groups to carboxyl groups being higher than 0.75:1, as a wet strength additive. The invention also discloses novel cationic derivatives thereof.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: May 24, 2005
    Assignee: SCA Hygiene Products Zeist B.V.
    Inventors: Jeffrey Wilson Thornton, Dorine Lisa Van Brussel-Verraest, Arie Besemer, Sussan Sandberg
  • Patent number: 6802895
    Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: October 12, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Larry Neil Mackey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
  • Patent number: 6800593
    Abstract: Disclosed is a hydrophilic, water soluble polymer concentrate for addition to aqueous liquids to enhance the properties thereof, particularly to increase the viscosity or decrease the fluid loss of well drilling and servicing fluids, the concentrate comprising a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, the water soluble polymer, and a stabilizing agent comprising one or more acids in an amount from about 0.001% to about 1.5%, one or more anionic surfactants in an amount from about 0.001% to about 1.0%, one or more nonionic surfactants in an amount from 0.001% to about 0.625% and, from about 0% to about 0.75% of one or more water soluble organic liquids, wherein the total concentration of the stabilizing agent is from about 0.1% to about 2.5%, these percentages being based on the weight of the concentrate.
    Type: Grant
    Filed: June 19, 2002
    Date of Patent: October 5, 2004
    Assignee: Texas United Chemical Company, LLC.
    Inventors: James W. Dobson, Jr., Shauna Leigh Hayden, Carolina Trejo Rangel
  • Patent number: 6777465
    Abstract: A tackifier utilizing a synthetic polymer of polyacrylamide, polyacrylate, or a co-polymer of acrylamide or acrylate, combined with a natural organic material. A cross-linking agent is also employed to cross-link the synthetic polymer to the natural organic material.
    Type: Grant
    Filed: June 11, 2001
    Date of Patent: August 17, 2004
    Inventor: Michael L. Haile
  • Patent number: 6777454
    Abstract: This invention relates to a process of preparing vesiculated granules of crosslinked carboxylated polyester resin utilising a particular class of non-alkylphenolethoxylate surfactant.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: August 17, 2004
    Assignee: Orica Australia Pty Ltd.
    Inventors: Philip J. A. Ritchie, Algirdas K. Serelis
  • Publication number: 20040149165
    Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.
    Type: Application
    Filed: December 19, 2003
    Publication date: August 5, 2004
    Applicant: The Procter & Gamble Company
    Inventors: Larry Neil MacKey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
  • Patent number: 6723160
    Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: April 20, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Larry Neil Mackey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
  • Patent number: 6713554
    Abstract: The present invention relates to a composition comprising a component (A) containing, an aqueous alkali silicate solution and a primary amino-alcohol as a catalyst, and a component (B) containing a polyisocyanate. The present invention further relates to organo-mineral products which can be obtained by the transformation of polyisocyanates and aqueous alkali silicate solutions in the presence of a primary amino-alcohol as a catalyst. The organo-mineral products can be used as building, coating, sealing or insulating materials, or as a cement or adhesive.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: March 30, 2004
    Assignee: Fosroc International Limited
    Inventor: Harald Bode
  • Publication number: 20030199617
    Abstract: The present invention relates to use of an alkylhydroxyalkyl cellulose, which has alkyl groups having 1-3 carbon atoms and hydroxyalkyl groups having 2-3 carbon atoms, is free from hydrophobically modifying alkyl groups having at least 4 carbon atoms and has a turbidity point of 50-95° C. The amount of carboxymethyl cellulose constitutes up to 1200 percent by weight of the amount of alkylhydroxyalkyl cellulose. An aqueous coating composition containing a combination of alkylhydroxyethyl cellulose and carboxymethyl cellulose is also described.
    Type: Application
    Filed: February 5, 2003
    Publication date: October 23, 2003
    Inventors: Kerstin Larsson, Erland Hermansson
  • Publication number: 20030154883
    Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal•Seconds to about 80 Pascal•Seconds and an apparent extensional viscosity in the range of from about 150 Pascal•Seconds to about 13,000 Pascal•Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.
    Type: Application
    Filed: February 1, 2002
    Publication date: August 21, 2003
    Applicant: The Procter & Gamble Company
    Inventors: Larry Neil MacKey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
  • Patent number: 6461422
    Abstract: The problems of applying ink jet inks to various known coating surfaces so as to overcome smearing, poor resolution and attack by water etc., is overcome by the use of the new ink jet receptive media. The media comprises in combination: (1) a waterproof ink jet receptive coating, (2) a primer coating, (3) a non-porous substrate, (4) a pressure sensitive adhesive coating, (5) a silicone coating and (6) a backer layer. The receptive coating comprises the combination of: (1) binder, (2) charge control agent, (3) cross-linking agent, (4) adhesion enhancing agent and (5) dispersant. The absorption of the ink jet ink to the substrate is maximized, thus attracting and fixing the ink and providing a waterproofing effect.
    Type: Grant
    Filed: January 27, 2000
    Date of Patent: October 8, 2002
    Assignee: Chartpak, Inc.
    Inventors: Victor Yang, Norman P. De Bastiani
  • Patent number: 6391945
    Abstract: The present invention relates to a rubber composition containing a combination of starch, modified starch and/or starch/plasticizer composite together with selected methylene donor and/or methylene acceptor compounds. The invention also relates to tires having at least one component comprised of such rubber composition. Such tire component can be, for example, its circumferential tread or other component of the tire.
    Type: Grant
    Filed: May 8, 2001
    Date of Patent: May 21, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Paul Harry Sandstrom
  • Publication number: 20010031803
    Abstract: The invention relates to the preparation of a rubber composition containing starch/plasticizer composite reinforcement, together with at least one additional reinforcing filler, through the utilization of a combination of an organosilane disulfide compound mixed with a rubber composition in a preparatory, non-productive, mixing stage(s) followed by adding an organosilane polysulfide compound in a subsequent, productive, mixing stage. The invention further relates to the resulting rubber composition and use thereof in rubber products, including tires.
    Type: Application
    Filed: May 8, 2001
    Publication date: October 18, 2001
    Applicant: The Goodyear Tire & Rubber Company
    Inventors: Thierry Florent Edme Materne, Filomeno Gennaro Corvasce
  • Patent number: 6255369
    Abstract: A water-resistant, viscosity stable, alkaline curing, starch-based corrugating adhesive composition comprising starch, an alkali material, a ketone-formaldehyde crosslinking additive containing selected sulfite salts and having reduced free-formaldehyde content, and water.
    Type: Grant
    Filed: December 18, 1998
    Date of Patent: July 3, 2001
    Assignee: National Starch & Chemical Investment Holding Corporation
    Inventors: Michael T. Philbin, Norman G. Albrecht
  • Patent number: 6242089
    Abstract: A coated substrate comprising: (a) a substrate; (b) a primer layer containing adhesion-promoting polymer on said substrate; and (c) at least one topcoat of a permeation resistant composition of ethylene-tetrafluoroethylene (ETFE) copolymer and mica, therein the ETFE is a copolymer of about 40 to 60 mole % ethylene and about 60 to 40 mole % tetrafluoroethylene, wherein the mica is present in amounts of about 3 to about 25 wt % based on the ETFE and mica, and wherein the topcoat having a thickness of at least 150 &mgr;m. The coated substrate is formed by applying the primer to the substrate and drying, followed by dry powder coating at least one layer of ETFE and mica composition, followed by heating said layer.
    Type: Grant
    Filed: August 11, 1998
    Date of Patent: June 5, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Anne Buegman
  • Patent number: 5874486
    Abstract: A polymeric composition comprises a matrix including a starch component and at least one synthetic thermoplastics polymeric component in which a filler is dispersed, characterised in that the matrix includes a fluidising agent selected from the group consisting of C.sub.12 -C.sub.22 fatty acids, C.sub.12 -C.sub.22 fatty alcohols, esters and amides of the said fatty acids, poly and polyglycol ethers of alditols or polyglycerols esterified with the said fatty acids and their mixtures and the said filler comprises natural fillers of an organic nature dispersed in the matrix in quantities of from 5% to 70% by weight with reference to the total weight of the composition.
    Type: Grant
    Filed: March 27, 1995
    Date of Patent: February 23, 1999
    Assignee: Novamont S.p.A.
    Inventors: Catia Bastioli, Vittorio Bellotti, Roberto Lombi, Matteo Nicolini
  • Patent number: 5654353
    Abstract: The present invention relates to a degradable starch resin composition, a process for preparing the same and the use thereof. Said composition comprises starch, synthetic resin, mixing promoter, plasticizer, degradation accelerator and other additives. Said process comprising: (a) selecting a biodegradation accelerator; (b) preparing modified starch concentrate; (c) extruding the modified starch, EAA and the synthetic resin in a double-screw extruder and pelleting to obtain the degradable starch resin. The composition of the present invention contains a biodegradation accelerator and its starch content can be up to 80%. Having excellent biodegradability and good physico-mechanical property, the composition is particularly suitable to be used to prepare various light or heavy packaging films and agricultural films, etc.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: August 5, 1997
    Assignee: Beijing Xingchen Modern Control Engineering Institute
    Inventors: Yunzheng Li, Haojun Zhu, Jianguang Sun, Anhua Li
  • Patent number: 5654359
    Abstract: A paper coating composition comprising (I) a pigment, (II) an aqueous binder, and (III) a water-soluble resin obtainable by the reaction of at least (a) an alkylenediamine or a polyalkylenepolyamine, (b) an urea compound, and (c) a compound selected from aldehydes, epihalohydrins and is further improved by incorporating therein, (IV) a compound selected from the group consisting of (f) amines selected from the group consisting of monoamines, diamines and their salts each having at least 4 carbon atoms, (g) quaternary organic ammonium salts, and (h) polyamides obtainable by the reaction between a dibasic carboxylic compound and a polyamine. The water-soluble resin of the component (III) may be further allowed to react with a dibasic carboxylic compound, an alicyclic amine and/or an alicyclic epoxy compound in addition to the above three ingredients. Paper coated by using the above composition is especially excellent in ink receptivity and water resistance.
    Type: Grant
    Filed: February 28, 1996
    Date of Patent: August 5, 1997
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toshiyuki Hasegawa, Yoshifumi Yoshida, Akira Tanikawa, Fujiko Kumei
  • Patent number: 5565509
    Abstract: A dried film reinforced with coalescable water insoluble polymer particles which are substantially noncoalesced is disclosed. Also disclosed are dried films reinforced with noncoalesced water insoluble polymer particles which are readily water dispersible. Also disclosed are stable aqueous dispersions for formation of such films which comprise (a) a water insoluble component comprising coalescable polymer particles which have a T.sub.g less than 55.degree. C. and a majority of which have a particle size of less than 1 micron; and (b) a water soluble component which comprises a water soluble polymer capable of inhibiting coalescence of the polymer particles, or a water soluble polymer and a component capable of inhibiting coalescence of the polymer particles.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: October 15, 1996
    Assignee: Penford Products Company
    Inventors: Charles C. Nguyen, Verne J. Martin, Edward P. Pauley
  • Patent number: 5536764
    Abstract: Board coating compositions are provided comprising a cationic starch and a vinyl acetate polymerization product as protein binder substitutes.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: July 16, 1996
    Assignee: Penford Products Company
    Inventors: Charles C. Nguyen, D. Eric Tupper
  • Patent number: 5480923
    Abstract: A starch composition including destructurized starch, an acrylate copolymer having a molecular weight of more than 400,000, water, and additives such as plasticizers, lubricants, fillers, reinforcing agents, stabilizers, impact modifiers, and flame retardants. Also disclosed are a method of preparation thereof and articles produced therefrom. The compositions are readily usable on existing devices and can be thermoplastically processed substantially in accordance with methods currently in use.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: January 2, 1996
    Assignee: EMS-Inventa AG
    Inventors: Eduard Schmid, Friedrich S. Buehler, Hans-Joachim Schultze
  • Patent number: 5346937
    Abstract: The present invention relates to modifying agents for melamine-formaldehyde resins and highly reactive thermosetting resins which are prepared with this agent and consist of 1 mol of melamine, 1.5 to 3.5 mol of formaldehyde, 0.5 to 5% by weight of a polyhydric alcohol, based on the melamine plus formaldehyde, and 0.5 to 10% by weight of the modifying agent, based on the liquid resin. The modifying agent can be added to the melamine-formaldehyde resin as a pulverulent mixture before or during the condensation reaction or in the liquid state in the form of a condensation product prepared in a known manner. The modifying agent consists of 10 to 75% by weight of dicyandiamide, 5 to 70% by weight of cold water-soluble starch (soluble between about 18.degree. and about 25.degree. C.) and 20 to 85% by weight of a guanamine. The highly reactive resins modified in this way are preferably used for coating chipboard and hardboard by a short cycle process.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: September 13, 1994
    Assignee: SKW Trostberg Aktiengesellschaft
    Inventors: Josef Kuchler, Hans-Georg Erben, Josef Seeholzer
  • Patent number: 5312850
    Abstract: Hot melt adhesive compositions are prepared from 20 to 98% by weight of a polylactide homo- or copolymer containing at least 20 molar percent of the lactide component; 2 to 80% by weight of a polar tackifier having a Ring and Ball softening point (as described by ASTM E-26) greater than about 60.degree. C.; 0 to 50% by weight of a plasticizer; 0 to 30% by weight of a wax diluent; 0-3% by weight of a stabilizer; and 0-20% of starch. By utilizing a naturally occurring, thermoplastic, biodegradable copolymer as the base polymer, these adhesives advance the state of the art of hot melt adhesives by alleviating the dependence on petroleum based materials and by allowing for the development of hot melt adhesives which either degrade naturally after coming in contact with the soil or which can be composted.
    Type: Grant
    Filed: January 4, 1993
    Date of Patent: May 17, 1994
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Carmine P. Iovine, Thomas F. Kauffman, Jules E. Schoenberg, Paul P. Puletti
  • Patent number: 5286769
    Abstract: Corrugating adhesive compositions comprising soluble high amylose starch as the carrier starch may be prepared as a one-piece, dry mixture that can be dispersed in water at 25.degree. to 55.degree. C. and applied to paperboard without further preparation steps. The corrugating adhesives may be prepared without alkali, and used at any pH.
    Type: Grant
    Filed: April 19, 1993
    Date of Patent: February 15, 1994
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: James Eden, James Kasica, Craig Leake, Norman Lacourse, Paul Altieri
  • Patent number: 5247066
    Abstract: A crosslinking additive for imparting water resistance to starch-based alkaline corrugating adhesive compositions is prepared by reacting acetone and formaldehyde under aqueous alkaline conditions at 20.degree.-80.degree. C. in a molar ratio of from 2 to 5 moles of formaldehyde per mole of acetone. The condensate is thereafter treated with from 1.0 to 2.0 moles of hydrogen peroxide per mole of unreacted formaldehyde which oxidizes the residual formaldehyde to formic acid. The treated crosslinking additive will contain less than 0.4% unreacted formaldehyde and may be added directly to a starch-based corrugating adhesive.
    Type: Grant
    Filed: August 29, 1991
    Date of Patent: September 21, 1993
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Jules E. Schoenberg, Michael Foran
  • Patent number: 5236977
    Abstract: Corrugating adhesive compositions comprising soluble high amylose starch as the carrier starch may be prepared as a one-piece, dry mixture that can be dispersed in water at 25.degree. to 55.degree. C. and applied to paperboard without further preparation steps. The corrugating adhesives may be prepared without alkali, and used at any pH.
    Type: Grant
    Filed: September 20, 1991
    Date of Patent: August 17, 1993
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: James Eden, James Kasica, Craig Leake, Norman Lacourse, Paul Altieri
  • Patent number: 5162394
    Abstract: A fire-retardant composition for rendering a combustible hydrophilic substrate resistant to combustion and flaming is disclosed. Also disclosed are processes employing said composition for rendering a hydrophilic substrate resistant to combustion, as well as structural material made fire-resistant by such a process. The composition is a thermoset formed by combining two resins, which can be either made and stored separately for long periods until use or stored as a partially polymerized liquid mixture. The resins are water soluble and heat-curable to form the thermoset. The first resin comprises polyols derived preferably from a carbohydrate such as maltodextrin having substituent groups occupying a portion of the available hydroxyls derived from monoammonium phosphate, urea, phosphoric acid, and glyoxal. The second resin can be a methylol-melamine-formaldehyde, methylol-urea-formaldehyde, or methylol-phenol-formaldehyde formulation.
    Type: Grant
    Filed: September 18, 1990
    Date of Patent: November 10, 1992
    Assignee: 501 Chemco Inc.
    Inventors: Frank S. Trocino, Fred J. Amundson
  • Patent number: 5147908
    Abstract: A cationic polyvinyl alcohol binder additive is prepared suitable for addition in the wet-end of a paper making process by reacting a blocked glyoxal resin, a cationic water-soluble aldehyde reactive polymer and a polyvinyl alcohol polymer.
    Type: Grant
    Filed: September 24, 1990
    Date of Patent: September 15, 1992
    Assignee: Sequa Chemicals Inc.
    Inventors: William C. Floyd, Louis R. Dragner
  • Patent number: 5116890
    Abstract: A water-dispersible, self-crosslinking non-formaldehyde latex is prepared by reacting a starch-polymer graft with a glyoxal compound at temperatures of at least 70.degree. C. to produce a stable emulsion with low viscosity and which upon drying and curing provides a film having good tensile, elongation, water resistance and anti-wicking properties.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: May 26, 1992
    Assignee: Sequa Chemicals, Inc.
    Inventors: William C. Floyd, Louis R. Dragner
  • Patent number: 5110657
    Abstract: An anti-skid coating composition for coating various substrates including structural panel board surfaces, comprises a binder made of urea formaldehyde resin, polyvinyl acetate, ammonium chloride and a dispersant. The binder is used in conjunction with an aggregate, such as walnut shells. A method is also provided for coating the substrates to impart slip resistance thereto.
    Type: Grant
    Filed: May 22, 1990
    Date of Patent: May 5, 1992
    Assignee: Reichhold Chemicals, Inc.
    Inventor: Winston C. Ainslie
  • Patent number: 5079067
    Abstract: Formaldehyde containing resins used as curing, setting or crosslinking resins in a variety of natural product adhesives can be made with surprisingly low and novel levels of free formaldehyde, can be made using reactants that can remove free formaldehyde from the resin solution or from the adhesive.
    Type: Grant
    Filed: March 11, 1991
    Date of Patent: January 7, 1992
    Assignee: H. B. Fuller Company
    Inventor: Stephen M. Willging
  • Patent number: 5026746
    Abstract: A binder for non-woven fibers or fabrics is prepared comprising a starch-polymer graft, starch and a starch crosslinking agent. An acrylamide copolymer may optionally be included. The binder is useful for non-woven fibers such as a polyester fiber mat, and particularly single ply, bitumin roofing materials.
    Type: Grant
    Filed: June 26, 1989
    Date of Patent: June 25, 1991
    Assignee: Sequa Chemicals, Inc.
    Inventors: William C. Floyd, louis R. Dragner, Blanche H. Black
  • Patent number: 4888124
    Abstract: A process for the preparation of stable dispersions of finely divided polyisocyanates, and the preparation of heat-crosslinkable isocyanate systems.Stable dispersions of finely divided polyisocyanates in a liquid which may or may not contain surfactants, protective colloids and other assistants are obtained by a method in which polyisocyanates are treated with a stabilizer in the presence of absence of the liquid, and the dispersions prepared from these are finely dispersed and/or milled under the action of high shear forces, if necessary with the addition of further stabilizer.These dispersions are useful as crosslinking agents, particularly for the preparation of heat-cross-linkable isocyanate systems.
    Type: Grant
    Filed: October 23, 1987
    Date of Patent: December 19, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Blum, Horst Belde, Rolf Osterloh, Guenter Uhl
  • Patent number: 4855354
    Abstract: The invention relates to a curable aldehyde resin and starch composition useful as a saturant and laminating adhesive for paperboard products, including dual arch corrugated cardboard. The aldehyde resin to starch ratio is from approximately 7:5 to 5:1 by weight. By the present invention is produced corrugated paperboard which has substantially improved crush strength over that obtained with polyvinyl acetate adhesives, and higher moisture resistance than either polyvinyl acetate or starch adhesives.
    Type: Grant
    Filed: January 7, 1988
    Date of Patent: August 8, 1989
    Assignee: Borden, Inc.
    Inventors: Paul J. Mohler, Thomas A. Romz, Baird E. Lithgow
  • Patent number: 4853428
    Abstract: This invention relates to an environmentally durable composition which has superior low temperature dynamic properties. The composition comprises a substantially homogeneous mixture of 100 parts by weight elastomer having a fully saturated backbone, curing agent for the elastomer in amounts sufficient to crosslink the elastomer, reinforcing particulate filler, at least 20 parts by weight of particularly defined polyalphaolefin oil and, preferably, particularly defined paraffinic oil and/or naphthenic oil. Inclusion of the polyalphaolefin oil in the composition improves the low temperature dynamic properties and processability of the elastomer, which are further improved by inclusion of naphthenic oil and/or paraffinic oil therein. Particulate graphite may be incorporated into the composition to lower its friction.
    Type: Grant
    Filed: November 2, 1987
    Date of Patent: August 1, 1989
    Assignee: Ford Motor Company
    Inventors: Ares N. Theodore, Paul C. Killgoar, Jr.
  • Patent number: 4841040
    Abstract: A novel phosphated, oxidized starch having a molecular weight of about 1,500 to about 40,000 Daltons, a carboxyl degree of substitution of 0.30 to 0.96, and a phosphate degree of substitution of from about 0.002 to about 0.005, which is useful as a dispersant for aqueous, high-solid slurries of minerals and inorganic pigments, as a replacement for gum arabic in gumming and fountain solutions for lithography, and as a drilling fluid additive.
    Type: Grant
    Filed: December 9, 1987
    Date of Patent: June 20, 1989
    Assignee: Aqualon Company
    Inventors: Ernst K. Just, Robert G. Nickol
  • Patent number: 4801631
    Abstract: This invention relates to formaldehyde-free, aqueous glue dispersions which contain polyisocyanates. These systems are particularly suitable for gluing veneers and surface materials on wood and wood products. The systems are prepared from polyisocyanates in combination with extenders based on flours and cold water-soluble of hydrolyzed natural starch. In this process, polyisocyanates or aqueous dispersions thereof are added while stirring to aqueous solutions or mixtures of starch and flour.The extender-containing adhesive systems are aqueous glue dispersions having increased service life which in their preferred embodiment contain about 15 to 30% by weight of polyisocyanates, preferably polyphenyl-polymethylene polyisocyanate (PMDI), 10 to 15% by weight of starch which is soluble in cold water and 14 to 25% by weight of (cereal) flour and optionally, other additives and the appropriate quantity of water adding up to 100% by weight.
    Type: Grant
    Filed: February 6, 1987
    Date of Patent: January 31, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hanns I. Sachs, Donald R. Larimer
  • Patent number: 4711794
    Abstract: Amylaceous composition of mixtures based on synthetic or natural binders or compounds employed in the manufacture of certain textile or paratextile products and particularly of the composite textile type. It comprises:from 7% to 45% by weight, preferably from 10% to 25% by weight, of a starch swelling in cold water, if necessary modified chemically,from 55% to 93% by weight, preferably from 70% to 85% by weight, of granular starch, modified chemically.
    Type: Grant
    Filed: May 10, 1985
    Date of Patent: December 8, 1987
    Assignee: Roquette Freres Societe Anonyme
    Inventors: Serge Gosset, Jean-Claude Lumaret
  • Patent number: 4461858
    Abstract: Stable aqueous solutions of cationic polyvinylalcohol/melamine-formaldehyde resin interaction products are provided comprising polyvinyl alcohol polymer and cationic melamine-formaldehyde resin acid colloid in a polyvinylalcohol/melamine-formaldehyde resin acid colloid weight ratio, on a dry basis, of from about 0.4/1 to about 5/1, and sufficient water to give a solids content of from about 0.7% by weight up to a level that will not cause gelation to a stage of no flow under the force of gravity in 48 hours but not in excess of 6% by weight. These aqueous polyvinylalcohol/melamine-formaldehyde interaction products have good stability, and high absorption capacity onto cellulose pulp. The use of these interaction products in paper making results in increased processing capability and improved wet and dry strength of the paper.
    Type: Grant
    Filed: November 19, 1981
    Date of Patent: July 24, 1984
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert L. Adelman
  • Patent number: 4440884
    Abstract: An aqueous adhesive, resistant to humidity and water, which debonds in the presence of strong base, comprises finely divided aluminum, a natural product bonding agent and water.
    Type: Grant
    Filed: October 20, 1982
    Date of Patent: April 3, 1984
    Assignee: H. B. Fuller Company
    Inventor: Leonard C. Jannusch
  • Patent number: 4396733
    Abstract: The present invention relates to new azulmic acids stabilized by condensation with carbonyl compounds, several processes for their preparation and their use for various purposes.
    Type: Grant
    Filed: September 11, 1980
    Date of Patent: August 2, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Kuno Wagner, Kurt Findeisen