Aldehyde Reaction Product Patents (Class 524/49)
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Patent number: 9187668Abstract: Metal deco ink formulations are improved by the use of fluorescent dyes, UV-absorbing dyes and/or IR-absorbing dyes. These may be premixed with a phenol-formaldehyde resin without microencapsulation to protect the dye from other ink ingredients that have chemistries which are incompatible with that of the dye, in order to obtain photochromic ink formulation with a good shelf life.Type: GrantFiled: October 29, 2012Date of Patent: November 17, 2015Assignee: Chromatic Technologies, Inc.Inventors: Timothy J. Owen, Eric Cathie, Kristin A. Fletcher
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Patent number: 8815003Abstract: Crosslinking systems suitable for use in a polymer melt composition wherein the polymer melt composition comprises a hydroxyl polymer; polymeric structures made from such polymer melt compositions; and processes/methods related thereto are provided.Type: GrantFiled: November 20, 2013Date of Patent: August 26, 2014Assignee: The Procter & Gamble CompanyInventors: Stephen Wayne Heinzman, Linda Evers Smith, Gregory Charles Gordon, Larry Neil Mackey, John Gerhard Michael, Mark Ryan Richards
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Patent number: 8759279Abstract: A film formed from a biodegradable polymer matrix within which is contained at least one fragrance is provided. The ability to incorporate a fragrance into the polymer matrix is achieved in the present invention by controlling a variety of aspects of the film construction, including the nature of the fragrance, the nature of the biodegradable polymer, the manner in which the polymer matrix and fragrance are melt processed, etc. For example, the fragrance may be injected directly into the extruder and melt blended with the biodegradable polymer. In this manner, the costly and time-consuming steps of pre-encapsulation or pre-compounding of the fragrance into a masterbatch are not required. Furthermore, to obtain a balance between the ability of the fragrance to release the desired odor during use and likewise to minimize the premature exhaustion of the odor during melt processing, the fragrance is selected to have a boiling point (at atmospheric pressure) within a certain range, such as from about 125° C.Type: GrantFiled: June 30, 2008Date of Patent: June 24, 2014Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Sara A. Funk, James H. Wang
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Patent number: 8691003Abstract: An indicator is useful for detecting pressure points on a denture. The indicator is made of a composition that easily adheres to oral mucosa, has a proper viscosity in an oral cavity environment, can be properly spread between an oral mucosa surface and a denture base, and easily specifies an affected part. The composition includes a fatty acid ester having a melting point of 30 to 50° C., a water-soluble high polymer, and a metal oxide. Preferably, the fatty acid is 40 to 95% by weight of the composition, the water-soluble high polymer is 1 to 59% by weight of the composition, and the metal oxide is 0.1 to 50% by weight of the composition.Type: GrantFiled: September 29, 2011Date of Patent: April 8, 2014Assignee: GC CorporationInventors: Yutaka Shinozaki, Hiroshi Kamohara
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Patent number: 8410200Abstract: A polymer composition and its use for thin film packaging applications including on a dry basis: a) from 45 to 90% by weight of starch; b) from 0.1 to 15% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinyl alcohol which have a melting point compatible with the molten state of the starch component; and c) from 5 to 45% by weight of one or more plasticizers having a molecular weight in the range of 50-6000, more preferably 50-2500 and more preferably still 100-400 and desirably selected from the group consisting of sorbitol, glycerol, maltitol, xylitol, mannitol, erythritol, glycerol trioleate, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate, polyethylene oxide, ethylene glycol, diethylene glycol or polyethylene glycol.Type: GrantFiled: April 18, 2007Date of Patent: April 2, 2013Assignee: Plantic Technologies LimitedInventors: Nicholas R. Oakley, Nicholas J. McCaffrey, Kishan C. Khemani
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Patent number: 8357237Abstract: Crosslinking systems suitable for use in a polymer melt composition wherein the polymer melt composition comprises a hydroxyl polymer; polymeric structures made from such polymer melt compositions; and processes/methods related thereto are provided.Type: GrantFiled: January 10, 2012Date of Patent: January 22, 2013Assignee: The Procter & Gamble CompanyInventors: Stephen Wayne Heinzman, Linda Evers Smith, Gregory Charles Gordon, Larry Neil Mackey, John Gerhard Michael, Mark Ryan Richards
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Patent number: 7854994Abstract: A barrier composition which is injection mouldable and able to be made into a transparent film or incorporated (by co-extrusion and/or lamination) into multi-layer film products, the composition on dry basis: a) from 45 to 90% by weight of a starch and/or a modified starch selected from starches modified by reaction with a hydroxyl alkyl group, an acetate or a dicarboxylic acid anhydride or a grafting polymer; b) from 4 to 12% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten state of the starch components c) from 5 to 45% by weight of a non-crystallising mixture of sorbitol and at least one other plasticizer selected from glycerol, maltitol, xylitol, mannitol, glycerol trioleate, epoxidised linseed or soybean oil, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate; polyethylene oxide or polyethylene glycol; d) fromType: GrantFiled: October 18, 2005Date of Patent: December 21, 2010Assignee: Plantic Technologies Ltd.Inventors: Rulande Henderson-Rutgers, Mark Fink, Nicholas Roy Oakley
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Patent number: 7255732Abstract: Starch can be gelatinised more efficiently by a thermomechanical treatment, if a dialdehyde polysaccharide with a relatively low degree of oxidation is added to the starch. This thermomechanical treatment can be carried out at a temperature below 115 DEG C., or even below 100 DEG C., and with a high throughput rate. With this treatment a granulate or other semi-finished product is obtained that can be shaped to produce an article that has excellent dimensional stability in water. By adding dialdehyde polysaccharide with a low degree of oxidation to starch it is possible to blow transparent films based on thermoplastic starch which have improved mechanical properties.Type: GrantFiled: September 29, 2003Date of Patent: August 14, 2007Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek TnoInventors: Sabine Fischer, Eric G. M. Craenmehr, Jan J. De Vlieger, Theodoor M. Slaghek
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Patent number: 7025821Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.Type: GrantFiled: October 7, 2004Date of Patent: April 11, 2006Assignee: The Procter & Gamble CompanyInventors: Larry Neil Mackey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
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Patent number: 6896725Abstract: The invention concerns the use of a water-soluble or water-dispersible polymer having a molecular weight of at least 800, containing at least 5 aldehyde groups per molecule and at least 1 carboxyl group per molecule, the ratio of aldehyde groups to carboxyl groups being higher than 0.75:1, as a wet strength additive. The invention also discloses novel cationic derivatives thereof.Type: GrantFiled: April 25, 2003Date of Patent: May 24, 2005Assignee: SCA Hygiene Products Zeist B.V.Inventors: Jeffrey Wilson Thornton, Dorine Lisa Van Brussel-Verraest, Arie Besemer, Sussan Sandberg
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Patent number: 6802895Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.Type: GrantFiled: December 19, 2003Date of Patent: October 12, 2004Assignee: The Procter & Gamble CompanyInventors: Larry Neil Mackey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
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Patent number: 6800593Abstract: Disclosed is a hydrophilic, water soluble polymer concentrate for addition to aqueous liquids to enhance the properties thereof, particularly to increase the viscosity or decrease the fluid loss of well drilling and servicing fluids, the concentrate comprising a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, the water soluble polymer, and a stabilizing agent comprising one or more acids in an amount from about 0.001% to about 1.5%, one or more anionic surfactants in an amount from about 0.001% to about 1.0%, one or more nonionic surfactants in an amount from 0.001% to about 0.625% and, from about 0% to about 0.75% of one or more water soluble organic liquids, wherein the total concentration of the stabilizing agent is from about 0.1% to about 2.5%, these percentages being based on the weight of the concentrate.Type: GrantFiled: June 19, 2002Date of Patent: October 5, 2004Assignee: Texas United Chemical Company, LLC.Inventors: James W. Dobson, Jr., Shauna Leigh Hayden, Carolina Trejo Rangel
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Patent number: 6777465Abstract: A tackifier utilizing a synthetic polymer of polyacrylamide, polyacrylate, or a co-polymer of acrylamide or acrylate, combined with a natural organic material. A cross-linking agent is also employed to cross-link the synthetic polymer to the natural organic material.Type: GrantFiled: June 11, 2001Date of Patent: August 17, 2004Inventor: Michael L. Haile
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Patent number: 6777454Abstract: This invention relates to a process of preparing vesiculated granules of crosslinked carboxylated polyester resin utilising a particular class of non-alkylphenolethoxylate surfactant.Type: GrantFiled: June 28, 2002Date of Patent: August 17, 2004Assignee: Orica Australia Pty Ltd.Inventors: Philip J. A. Ritchie, Algirdas K. Serelis
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Publication number: 20040149165Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.Type: ApplicationFiled: December 19, 2003Publication date: August 5, 2004Applicant: The Procter & Gamble CompanyInventors: Larry Neil MacKey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
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Patent number: 6723160Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.Type: GrantFiled: February 1, 2002Date of Patent: April 20, 2004Assignee: The Procter & Gamble CompanyInventors: Larry Neil Mackey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
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Patent number: 6713554Abstract: The present invention relates to a composition comprising a component (A) containing, an aqueous alkali silicate solution and a primary amino-alcohol as a catalyst, and a component (B) containing a polyisocyanate. The present invention further relates to organo-mineral products which can be obtained by the transformation of polyisocyanates and aqueous alkali silicate solutions in the presence of a primary amino-alcohol as a catalyst. The organo-mineral products can be used as building, coating, sealing or insulating materials, or as a cement or adhesive.Type: GrantFiled: August 30, 2002Date of Patent: March 30, 2004Assignee: Fosroc International LimitedInventor: Harald Bode
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Publication number: 20030199617Abstract: The present invention relates to use of an alkylhydroxyalkyl cellulose, which has alkyl groups having 1-3 carbon atoms and hydroxyalkyl groups having 2-3 carbon atoms, is free from hydrophobically modifying alkyl groups having at least 4 carbon atoms and has a turbidity point of 50-95° C. The amount of carboxymethyl cellulose constitutes up to 1200 percent by weight of the amount of alkylhydroxyalkyl cellulose. An aqueous coating composition containing a combination of alkylhydroxyethyl cellulose and carboxymethyl cellulose is also described.Type: ApplicationFiled: February 5, 2003Publication date: October 23, 2003Inventors: Kerstin Larsson, Erland Hermansson
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Publication number: 20030154883Abstract: Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal•Seconds to about 80 Pascal•Seconds and an apparent extensional viscosity in the range of from about 150 Pascal•Seconds to about 13,000 Pascal•Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g/mol.Type: ApplicationFiled: February 1, 2002Publication date: August 21, 2003Applicant: The Procter & Gamble CompanyInventors: Larry Neil MacKey, Gregory Charles Gordon, Lora Lee Buchanan, Stephen Wayne Heinzman, Paul Arlen Forshey
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Patent number: 6461422Abstract: The problems of applying ink jet inks to various known coating surfaces so as to overcome smearing, poor resolution and attack by water etc., is overcome by the use of the new ink jet receptive media. The media comprises in combination: (1) a waterproof ink jet receptive coating, (2) a primer coating, (3) a non-porous substrate, (4) a pressure sensitive adhesive coating, (5) a silicone coating and (6) a backer layer. The receptive coating comprises the combination of: (1) binder, (2) charge control agent, (3) cross-linking agent, (4) adhesion enhancing agent and (5) dispersant. The absorption of the ink jet ink to the substrate is maximized, thus attracting and fixing the ink and providing a waterproofing effect.Type: GrantFiled: January 27, 2000Date of Patent: October 8, 2002Assignee: Chartpak, Inc.Inventors: Victor Yang, Norman P. De Bastiani
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Patent number: 6391945Abstract: The present invention relates to a rubber composition containing a combination of starch, modified starch and/or starch/plasticizer composite together with selected methylene donor and/or methylene acceptor compounds. The invention also relates to tires having at least one component comprised of such rubber composition. Such tire component can be, for example, its circumferential tread or other component of the tire.Type: GrantFiled: May 8, 2001Date of Patent: May 21, 2002Assignee: The Goodyear Tire & Rubber CompanyInventor: Paul Harry Sandstrom
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Publication number: 20010031803Abstract: The invention relates to the preparation of a rubber composition containing starch/plasticizer composite reinforcement, together with at least one additional reinforcing filler, through the utilization of a combination of an organosilane disulfide compound mixed with a rubber composition in a preparatory, non-productive, mixing stage(s) followed by adding an organosilane polysulfide compound in a subsequent, productive, mixing stage. The invention further relates to the resulting rubber composition and use thereof in rubber products, including tires.Type: ApplicationFiled: May 8, 2001Publication date: October 18, 2001Applicant: The Goodyear Tire & Rubber CompanyInventors: Thierry Florent Edme Materne, Filomeno Gennaro Corvasce
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Patent number: 6255369Abstract: A water-resistant, viscosity stable, alkaline curing, starch-based corrugating adhesive composition comprising starch, an alkali material, a ketone-formaldehyde crosslinking additive containing selected sulfite salts and having reduced free-formaldehyde content, and water.Type: GrantFiled: December 18, 1998Date of Patent: July 3, 2001Assignee: National Starch & Chemical Investment Holding CorporationInventors: Michael T. Philbin, Norman G. Albrecht
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Patent number: 6242089Abstract: A coated substrate comprising: (a) a substrate; (b) a primer layer containing adhesion-promoting polymer on said substrate; and (c) at least one topcoat of a permeation resistant composition of ethylene-tetrafluoroethylene (ETFE) copolymer and mica, therein the ETFE is a copolymer of about 40 to 60 mole % ethylene and about 60 to 40 mole % tetrafluoroethylene, wherein the mica is present in amounts of about 3 to about 25 wt % based on the ETFE and mica, and wherein the topcoat having a thickness of at least 150 &mgr;m. The coated substrate is formed by applying the primer to the substrate and drying, followed by dry powder coating at least one layer of ETFE and mica composition, followed by heating said layer.Type: GrantFiled: August 11, 1998Date of Patent: June 5, 2001Assignee: E. I. du Pont de Nemours and CompanyInventor: Anne Buegman
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Patent number: 5874486Abstract: A polymeric composition comprises a matrix including a starch component and at least one synthetic thermoplastics polymeric component in which a filler is dispersed, characterised in that the matrix includes a fluidising agent selected from the group consisting of C.sub.12 -C.sub.22 fatty acids, C.sub.12 -C.sub.22 fatty alcohols, esters and amides of the said fatty acids, poly and polyglycol ethers of alditols or polyglycerols esterified with the said fatty acids and their mixtures and the said filler comprises natural fillers of an organic nature dispersed in the matrix in quantities of from 5% to 70% by weight with reference to the total weight of the composition.Type: GrantFiled: March 27, 1995Date of Patent: February 23, 1999Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Vittorio Bellotti, Roberto Lombi, Matteo Nicolini
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Patent number: 5654353Abstract: The present invention relates to a degradable starch resin composition, a process for preparing the same and the use thereof. Said composition comprises starch, synthetic resin, mixing promoter, plasticizer, degradation accelerator and other additives. Said process comprising: (a) selecting a biodegradation accelerator; (b) preparing modified starch concentrate; (c) extruding the modified starch, EAA and the synthetic resin in a double-screw extruder and pelleting to obtain the degradable starch resin. The composition of the present invention contains a biodegradation accelerator and its starch content can be up to 80%. Having excellent biodegradability and good physico-mechanical property, the composition is particularly suitable to be used to prepare various light or heavy packaging films and agricultural films, etc.Type: GrantFiled: May 25, 1995Date of Patent: August 5, 1997Assignee: Beijing Xingchen Modern Control Engineering InstituteInventors: Yunzheng Li, Haojun Zhu, Jianguang Sun, Anhua Li
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Patent number: 5654359Abstract: A paper coating composition comprising (I) a pigment, (II) an aqueous binder, and (III) a water-soluble resin obtainable by the reaction of at least (a) an alkylenediamine or a polyalkylenepolyamine, (b) an urea compound, and (c) a compound selected from aldehydes, epihalohydrins and is further improved by incorporating therein, (IV) a compound selected from the group consisting of (f) amines selected from the group consisting of monoamines, diamines and their salts each having at least 4 carbon atoms, (g) quaternary organic ammonium salts, and (h) polyamides obtainable by the reaction between a dibasic carboxylic compound and a polyamine. The water-soluble resin of the component (III) may be further allowed to react with a dibasic carboxylic compound, an alicyclic amine and/or an alicyclic epoxy compound in addition to the above three ingredients. Paper coated by using the above composition is especially excellent in ink receptivity and water resistance.Type: GrantFiled: February 28, 1996Date of Patent: August 5, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Toshiyuki Hasegawa, Yoshifumi Yoshida, Akira Tanikawa, Fujiko Kumei
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Patent number: 5565509Abstract: A dried film reinforced with coalescable water insoluble polymer particles which are substantially noncoalesced is disclosed. Also disclosed are dried films reinforced with noncoalesced water insoluble polymer particles which are readily water dispersible. Also disclosed are stable aqueous dispersions for formation of such films which comprise (a) a water insoluble component comprising coalescable polymer particles which have a T.sub.g less than 55.degree. C. and a majority of which have a particle size of less than 1 micron; and (b) a water soluble component which comprises a water soluble polymer capable of inhibiting coalescence of the polymer particles, or a water soluble polymer and a component capable of inhibiting coalescence of the polymer particles.Type: GrantFiled: June 2, 1995Date of Patent: October 15, 1996Assignee: Penford Products CompanyInventors: Charles C. Nguyen, Verne J. Martin, Edward P. Pauley
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Patent number: 5536764Abstract: Board coating compositions are provided comprising a cationic starch and a vinyl acetate polymerization product as protein binder substitutes.Type: GrantFiled: August 8, 1994Date of Patent: July 16, 1996Assignee: Penford Products CompanyInventors: Charles C. Nguyen, D. Eric Tupper
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Patent number: 5480923Abstract: A starch composition including destructurized starch, an acrylate copolymer having a molecular weight of more than 400,000, water, and additives such as plasticizers, lubricants, fillers, reinforcing agents, stabilizers, impact modifiers, and flame retardants. Also disclosed are a method of preparation thereof and articles produced therefrom. The compositions are readily usable on existing devices and can be thermoplastically processed substantially in accordance with methods currently in use.Type: GrantFiled: August 12, 1994Date of Patent: January 2, 1996Assignee: EMS-Inventa AGInventors: Eduard Schmid, Friedrich S. Buehler, Hans-Joachim Schultze
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Patent number: 5346937Abstract: The present invention relates to modifying agents for melamine-formaldehyde resins and highly reactive thermosetting resins which are prepared with this agent and consist of 1 mol of melamine, 1.5 to 3.5 mol of formaldehyde, 0.5 to 5% by weight of a polyhydric alcohol, based on the melamine plus formaldehyde, and 0.5 to 10% by weight of the modifying agent, based on the liquid resin. The modifying agent can be added to the melamine-formaldehyde resin as a pulverulent mixture before or during the condensation reaction or in the liquid state in the form of a condensation product prepared in a known manner. The modifying agent consists of 10 to 75% by weight of dicyandiamide, 5 to 70% by weight of cold water-soluble starch (soluble between about 18.degree. and about 25.degree. C.) and 20 to 85% by weight of a guanamine. The highly reactive resins modified in this way are preferably used for coating chipboard and hardboard by a short cycle process.Type: GrantFiled: June 11, 1993Date of Patent: September 13, 1994Assignee: SKW Trostberg AktiengesellschaftInventors: Josef Kuchler, Hans-Georg Erben, Josef Seeholzer
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Patent number: 5312850Abstract: Hot melt adhesive compositions are prepared from 20 to 98% by weight of a polylactide homo- or copolymer containing at least 20 molar percent of the lactide component; 2 to 80% by weight of a polar tackifier having a Ring and Ball softening point (as described by ASTM E-26) greater than about 60.degree. C.; 0 to 50% by weight of a plasticizer; 0 to 30% by weight of a wax diluent; 0-3% by weight of a stabilizer; and 0-20% of starch. By utilizing a naturally occurring, thermoplastic, biodegradable copolymer as the base polymer, these adhesives advance the state of the art of hot melt adhesives by alleviating the dependence on petroleum based materials and by allowing for the development of hot melt adhesives which either degrade naturally after coming in contact with the soil or which can be composted.Type: GrantFiled: January 4, 1993Date of Patent: May 17, 1994Assignee: National Starch and Chemical Investment Holding CorporationInventors: Carmine P. Iovine, Thomas F. Kauffman, Jules E. Schoenberg, Paul P. Puletti
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Patent number: 5286769Abstract: Corrugating adhesive compositions comprising soluble high amylose starch as the carrier starch may be prepared as a one-piece, dry mixture that can be dispersed in water at 25.degree. to 55.degree. C. and applied to paperboard without further preparation steps. The corrugating adhesives may be prepared without alkali, and used at any pH.Type: GrantFiled: April 19, 1993Date of Patent: February 15, 1994Assignee: National Starch and Chemical Investment Holding CorporationInventors: James Eden, James Kasica, Craig Leake, Norman Lacourse, Paul Altieri
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Patent number: 5247066Abstract: A crosslinking additive for imparting water resistance to starch-based alkaline corrugating adhesive compositions is prepared by reacting acetone and formaldehyde under aqueous alkaline conditions at 20.degree.-80.degree. C. in a molar ratio of from 2 to 5 moles of formaldehyde per mole of acetone. The condensate is thereafter treated with from 1.0 to 2.0 moles of hydrogen peroxide per mole of unreacted formaldehyde which oxidizes the residual formaldehyde to formic acid. The treated crosslinking additive will contain less than 0.4% unreacted formaldehyde and may be added directly to a starch-based corrugating adhesive.Type: GrantFiled: August 29, 1991Date of Patent: September 21, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: Jules E. Schoenberg, Michael Foran
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Patent number: 5236977Abstract: Corrugating adhesive compositions comprising soluble high amylose starch as the carrier starch may be prepared as a one-piece, dry mixture that can be dispersed in water at 25.degree. to 55.degree. C. and applied to paperboard without further preparation steps. The corrugating adhesives may be prepared without alkali, and used at any pH.Type: GrantFiled: September 20, 1991Date of Patent: August 17, 1993Assignee: National Starch and Chemical Investment Holding CorporationInventors: James Eden, James Kasica, Craig Leake, Norman Lacourse, Paul Altieri
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Patent number: 5162394Abstract: A fire-retardant composition for rendering a combustible hydrophilic substrate resistant to combustion and flaming is disclosed. Also disclosed are processes employing said composition for rendering a hydrophilic substrate resistant to combustion, as well as structural material made fire-resistant by such a process. The composition is a thermoset formed by combining two resins, which can be either made and stored separately for long periods until use or stored as a partially polymerized liquid mixture. The resins are water soluble and heat-curable to form the thermoset. The first resin comprises polyols derived preferably from a carbohydrate such as maltodextrin having substituent groups occupying a portion of the available hydroxyls derived from monoammonium phosphate, urea, phosphoric acid, and glyoxal. The second resin can be a methylol-melamine-formaldehyde, methylol-urea-formaldehyde, or methylol-phenol-formaldehyde formulation.Type: GrantFiled: September 18, 1990Date of Patent: November 10, 1992Assignee: 501 Chemco Inc.Inventors: Frank S. Trocino, Fred J. Amundson
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Patent number: 5147908Abstract: A cationic polyvinyl alcohol binder additive is prepared suitable for addition in the wet-end of a paper making process by reacting a blocked glyoxal resin, a cationic water-soluble aldehyde reactive polymer and a polyvinyl alcohol polymer.Type: GrantFiled: September 24, 1990Date of Patent: September 15, 1992Assignee: Sequa Chemicals Inc.Inventors: William C. Floyd, Louis R. Dragner
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Patent number: 5116890Abstract: A water-dispersible, self-crosslinking non-formaldehyde latex is prepared by reacting a starch-polymer graft with a glyoxal compound at temperatures of at least 70.degree. C. to produce a stable emulsion with low viscosity and which upon drying and curing provides a film having good tensile, elongation, water resistance and anti-wicking properties.Type: GrantFiled: June 20, 1991Date of Patent: May 26, 1992Assignee: Sequa Chemicals, Inc.Inventors: William C. Floyd, Louis R. Dragner
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Patent number: 5110657Abstract: An anti-skid coating composition for coating various substrates including structural panel board surfaces, comprises a binder made of urea formaldehyde resin, polyvinyl acetate, ammonium chloride and a dispersant. The binder is used in conjunction with an aggregate, such as walnut shells. A method is also provided for coating the substrates to impart slip resistance thereto.Type: GrantFiled: May 22, 1990Date of Patent: May 5, 1992Assignee: Reichhold Chemicals, Inc.Inventor: Winston C. Ainslie
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Patent number: 5079067Abstract: Formaldehyde containing resins used as curing, setting or crosslinking resins in a variety of natural product adhesives can be made with surprisingly low and novel levels of free formaldehyde, can be made using reactants that can remove free formaldehyde from the resin solution or from the adhesive.Type: GrantFiled: March 11, 1991Date of Patent: January 7, 1992Assignee: H. B. Fuller CompanyInventor: Stephen M. Willging
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Patent number: 5026746Abstract: A binder for non-woven fibers or fabrics is prepared comprising a starch-polymer graft, starch and a starch crosslinking agent. An acrylamide copolymer may optionally be included. The binder is useful for non-woven fibers such as a polyester fiber mat, and particularly single ply, bitumin roofing materials.Type: GrantFiled: June 26, 1989Date of Patent: June 25, 1991Assignee: Sequa Chemicals, Inc.Inventors: William C. Floyd, louis R. Dragner, Blanche H. Black
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Patent number: 4888124Abstract: A process for the preparation of stable dispersions of finely divided polyisocyanates, and the preparation of heat-crosslinkable isocyanate systems.Stable dispersions of finely divided polyisocyanates in a liquid which may or may not contain surfactants, protective colloids and other assistants are obtained by a method in which polyisocyanates are treated with a stabilizer in the presence of absence of the liquid, and the dispersions prepared from these are finely dispersed and/or milled under the action of high shear forces, if necessary with the addition of further stabilizer.These dispersions are useful as crosslinking agents, particularly for the preparation of heat-cross-linkable isocyanate systems.Type: GrantFiled: October 23, 1987Date of Patent: December 19, 1989Assignee: BASF AktiengesellschaftInventors: Rainer Blum, Horst Belde, Rolf Osterloh, Guenter Uhl
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Patent number: 4855354Abstract: The invention relates to a curable aldehyde resin and starch composition useful as a saturant and laminating adhesive for paperboard products, including dual arch corrugated cardboard. The aldehyde resin to starch ratio is from approximately 7:5 to 5:1 by weight. By the present invention is produced corrugated paperboard which has substantially improved crush strength over that obtained with polyvinyl acetate adhesives, and higher moisture resistance than either polyvinyl acetate or starch adhesives.Type: GrantFiled: January 7, 1988Date of Patent: August 8, 1989Assignee: Borden, Inc.Inventors: Paul J. Mohler, Thomas A. Romz, Baird E. Lithgow
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Patent number: 4853428Abstract: This invention relates to an environmentally durable composition which has superior low temperature dynamic properties. The composition comprises a substantially homogeneous mixture of 100 parts by weight elastomer having a fully saturated backbone, curing agent for the elastomer in amounts sufficient to crosslink the elastomer, reinforcing particulate filler, at least 20 parts by weight of particularly defined polyalphaolefin oil and, preferably, particularly defined paraffinic oil and/or naphthenic oil. Inclusion of the polyalphaolefin oil in the composition improves the low temperature dynamic properties and processability of the elastomer, which are further improved by inclusion of naphthenic oil and/or paraffinic oil therein. Particulate graphite may be incorporated into the composition to lower its friction.Type: GrantFiled: November 2, 1987Date of Patent: August 1, 1989Assignee: Ford Motor CompanyInventors: Ares N. Theodore, Paul C. Killgoar, Jr.
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Patent number: 4841040Abstract: A novel phosphated, oxidized starch having a molecular weight of about 1,500 to about 40,000 Daltons, a carboxyl degree of substitution of 0.30 to 0.96, and a phosphate degree of substitution of from about 0.002 to about 0.005, which is useful as a dispersant for aqueous, high-solid slurries of minerals and inorganic pigments, as a replacement for gum arabic in gumming and fountain solutions for lithography, and as a drilling fluid additive.Type: GrantFiled: December 9, 1987Date of Patent: June 20, 1989Assignee: Aqualon CompanyInventors: Ernst K. Just, Robert G. Nickol
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Patent number: 4801631Abstract: This invention relates to formaldehyde-free, aqueous glue dispersions which contain polyisocyanates. These systems are particularly suitable for gluing veneers and surface materials on wood and wood products. The systems are prepared from polyisocyanates in combination with extenders based on flours and cold water-soluble of hydrolyzed natural starch. In this process, polyisocyanates or aqueous dispersions thereof are added while stirring to aqueous solutions or mixtures of starch and flour.The extender-containing adhesive systems are aqueous glue dispersions having increased service life which in their preferred embodiment contain about 15 to 30% by weight of polyisocyanates, preferably polyphenyl-polymethylene polyisocyanate (PMDI), 10 to 15% by weight of starch which is soluble in cold water and 14 to 25% by weight of (cereal) flour and optionally, other additives and the appropriate quantity of water adding up to 100% by weight.Type: GrantFiled: February 6, 1987Date of Patent: January 31, 1989Assignee: Bayer AktiengesellschaftInventors: Hanns I. Sachs, Donald R. Larimer
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Patent number: 4711794Abstract: Amylaceous composition of mixtures based on synthetic or natural binders or compounds employed in the manufacture of certain textile or paratextile products and particularly of the composite textile type. It comprises:from 7% to 45% by weight, preferably from 10% to 25% by weight, of a starch swelling in cold water, if necessary modified chemically,from 55% to 93% by weight, preferably from 70% to 85% by weight, of granular starch, modified chemically.Type: GrantFiled: May 10, 1985Date of Patent: December 8, 1987Assignee: Roquette Freres Societe AnonymeInventors: Serge Gosset, Jean-Claude Lumaret
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Patent number: 4461858Abstract: Stable aqueous solutions of cationic polyvinylalcohol/melamine-formaldehyde resin interaction products are provided comprising polyvinyl alcohol polymer and cationic melamine-formaldehyde resin acid colloid in a polyvinylalcohol/melamine-formaldehyde resin acid colloid weight ratio, on a dry basis, of from about 0.4/1 to about 5/1, and sufficient water to give a solids content of from about 0.7% by weight up to a level that will not cause gelation to a stage of no flow under the force of gravity in 48 hours but not in excess of 6% by weight. These aqueous polyvinylalcohol/melamine-formaldehyde interaction products have good stability, and high absorption capacity onto cellulose pulp. The use of these interaction products in paper making results in increased processing capability and improved wet and dry strength of the paper.Type: GrantFiled: November 19, 1981Date of Patent: July 24, 1984Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert L. Adelman
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Patent number: 4440884Abstract: An aqueous adhesive, resistant to humidity and water, which debonds in the presence of strong base, comprises finely divided aluminum, a natural product bonding agent and water.Type: GrantFiled: October 20, 1982Date of Patent: April 3, 1984Assignee: H. B. Fuller CompanyInventor: Leonard C. Jannusch
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Patent number: 4396733Abstract: The present invention relates to new azulmic acids stabilized by condensation with carbonyl compounds, several processes for their preparation and their use for various purposes.Type: GrantFiled: September 11, 1980Date of Patent: August 2, 1983Assignee: Bayer AktiengesellschaftInventors: Kuno Wagner, Kurt Findeisen