From Halogen-containing Monomer Containing Three Or More Carbon Atoms And Wherein At Least One Halogen Atom Is Present In Other Than Salt Form Patents (Class 524/551)
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Publication number: 20080306206Abstract: Composite structures are manufactured from fiber and saturant. The saturant composition comprises a polymerization initiator system and a binder of chlorosulfonated polyolefin and a monomer mixture. The monomer mixture comprises 1) (meth)acrylic monomers having a single (meth)acrylic group and 2) (meth)acrylate monomers having at least two (meth)acrylate groups.Type: ApplicationFiled: May 22, 2008Publication date: December 11, 2008Inventor: Daniel Lee Neumann
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Publication number: 20080269377Abstract: Compositions including composites of polyvinyl chloride (PVC) and nanoparticles are disclosed. A wood-polymer composite using the PVC-nanoparticle composite as a matrix also is disclosed. The nanoparticle filler is dispersed throughout the PVC matrix by blending the nanoparticles with a mixture of PVC particles that have been pre-heated to a temperature at or above a fusion point of the PVC, thereby fusing the PVC particles prior to the addition of the nanoparticles to the matrix. Also disclosed are methods of forming the composite compositions. The composite compositions can be used to replace wood boards.Type: ApplicationFiled: April 17, 2008Publication date: October 30, 2008Applicant: Board of Trustees of Michigan State UniversityInventor: Laurent M. Matuana
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Publication number: 20080182085Abstract: An ink set, comprising: an oil based ink composition containing a metallic pigment; and at least one or more oil based ink compositions selected from a group consisting of a chromatic color ink composition containing chromatic color pigment, a black ink composition containing black pigment, and a white ink composition containing white pigment.Type: ApplicationFiled: January 29, 2008Publication date: July 31, 2008Applicant: SEIKO EPSON CORPORATIONInventors: Takashi OYANAGI, Kiyohiko TAKEMOTO, Chiyoshige NAKAZAWA
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Publication number: 20080152818Abstract: Non-aqueous graft polymers and coatings, including aerosol coatings, are described. The graft copolymers are useful for application to plastic and other substrates.Type: ApplicationFiled: December 5, 2007Publication date: June 26, 2008Applicant: THE SHERWIN-WILLIAMS COMPANYInventor: Pillai T. Perumal
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Patent number: 7381755Abstract: An aqueous ink jet ink composition including a pigment, a polymer latex containing at least one halogenated vinyl monomer, at least one surfactant, and a humectant. An ink and receiver combination for a non-absorbing substrate is also disclosed.Type: GrantFiled: September 27, 2002Date of Patent: June 3, 2008Assignee: Eastman Kodak CompanyInventors: Xiaoru Wang, Huijuan D. Chen, Ricky G. Frazier, Jin-Shan Wang
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Patent number: 7375157Abstract: A polymer melt additive that is suitable for use as a processing aid in the extrusion of a non-fluorinated polymer. The polymer melt additive composition includes a fluoropolymer that has a long chain branching index (LCBI) of at least 0.2 and a zero shear rate viscosity at 265° C. of not more than 107 Pa's. The polymer melt additive may additionally include other compounds such as, polyoxyalkylene polymer or polycaprolactone.Type: GrantFiled: June 9, 2004Date of Patent: May 20, 2008Assignee: 3M Innovative Properties CompanyInventors: Stephen E. Amos, Klaus Hintzer, Harald Kaspar, Claude Lavallée
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Patent number: 7217760Abstract: A fluoropolymer-based water-and-oil repellant composition which comprises a copolymer comprising units derived from (a) an ethylenic monomer having a perfluoroalkyl group, (b) an ethylenic monomer having a group comprising an aromatic ring and a halogen atom or halogenomethyl group bonded thereto, and (c) an ethylenic monomer copolymerizable with these. The composition imparts excellent water and oil repellency through cold cure.Type: GrantFiled: March 6, 2002Date of Patent: May 15, 2007Assignee: Daikin Industries, Ltd.Inventors: Takuya Yoshioka, Masato Kashiwagi
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Patent number: 7019096Abstract: This invention discloses a rubbery polymer which is comprised of repeat units that are derived from (1) at least one conjugated diolefin monomer, and (2) at least one leaving group-bearing monomer having the structural formula: wherein R represents an alkyl group containing from 1 to about 10 carbon atoms or a hydrogen atom, wherein R? represents a methyl group or a hydrogen atom, with the proviso that if R represents an alkyl group then R? represents a hydrogen atom, and wherein R1 and R2 can be the same or different, wherein R1 represents an alkyl group that is functionalized with a leaving group, wherein R2 represents a moiety selected from the group consisting of hydrogen atoms, alkyl groups containing from 1 to 18 carbon atoms, aryl groups containing from 6 to 18 carbon atoms, alkaryl groups containing from 7 to 18 carbon atoms, and alkyl groups that are functionalized with a leaving group.Type: GrantFiled: February 13, 2004Date of Patent: March 28, 2006Assignee: The Goodyear Tire & Rubber CompanyInventors: Jake Alexandre Dalphond, Steven Kristofer Henning, Stephan Rodewald
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Patent number: 6884827Abstract: A seal ring seals operating oil hermetically and is attached to an annular seal ring groove provided on an outer circumference of a shaft member. The seal ring comprises fluororesin, metal powder having a hardness equal to or more than that of any of a side surface of the seal ring groove serving as a sliding partner and an inner circumferential surface of a housing engaged relatively rotatable with the outer circumference of the shaft member, and modified fluororesin formed by irradiating an ionizing radiation in a range from 1 kGy to 10 MGy inclusive in a state of being heated up to a melting point thereof or higher under an inert gas atmosphere with an oxygen partial pressure of 1.33 kPa or less.Type: GrantFiled: April 1, 2003Date of Patent: April 26, 2005Assignees: Nissan Motor Co., Ltd., Hitachi Cable Ltd.Inventors: Tomohito Ota, Tomihito Hashimoto, Yasuaki Yamamoto, Hiroo Kusano
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Patent number: 6878231Abstract: What is disclosed are adhesives and bonding methods employing a single coat of a solvent-based adhesive that effectively bonds thermoplastic polymers and especially thermoplastic elastomers. The adhesive components are a organosilane component selected from organosilane-isocyanate adduct and isocyanato-organosilane, a post-chlorinated polymer containing propylene repeating units or derivative thereof, and solvent. Also disclosed are methods for joining a rigid, structural substrate to a molten polymer such as a TPE via injection molding or extrusion. Durable adhesion between the adhesive treated portion of the rigid substrate and the melt-processed polymer is achieved with or without a previous heat treatment on the adhesive-coated substrate prior to joining to the thermoplastic melt.Type: GrantFiled: February 28, 2003Date of Patent: April 12, 2005Assignee: Lord CorporationInventors: Douglas H. Mowrey, Patrick A. Warren
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Patent number: 6852791Abstract: An anti-reflection coating-forming composition is provided. This composition includes a polymer and a solvent. The polymer has a structural unit represented by the formula (1): wherein R1 is a monovalent atom other than a hydrogen atom or a monovalent group, and n is an integer of 0-4, provided that when n is an integer of 2-4, a plural number of R1's are the same or different; R2 and R3 are each a monovalent atom or group; and X is a bivalent group. The anti-reflection coating formed from this composition has a high antireflective effect, does not generate intermixing with a resist film, and enables a good resist pattern profile excellent in resolution and precision in cooperation with a positive or negative resist.Type: GrantFiled: November 14, 2001Date of Patent: February 8, 2005Assignee: JSR CorporationInventors: Kazuo Kawaguchi, Masato Tanaka, Tsutomu Shimokawa
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Publication number: 20040254288Abstract: The method disclosed by the present invention includes the following steps. First, liquid-phased acetic tri butyl citrite is combined with liquid-phased stabilizer to get the first mixture. Secondly, powder-like poly vinyl chloride, filling agent, light stabilizer uvasorb and fireproof agent are combined together to get the second mixture. Third, the first mixture and the second mixture are combined, and stirred under the room temperature. Finally, a cream-like finished product is gotten.Type: ApplicationFiled: June 11, 2003Publication date: December 16, 2004Inventor: Su-Tuan Hsu Tang
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Patent number: 6818692Abstract: This invention pertains to rubber cement compositions containing a rubber elastomer, a tackifier, and an organic solvent that is not a hazardous air pollutant (HAP). This invention also includes the method of making this rubber cement composition and of using this adhesive to bond to surfaces together.Type: GrantFiled: September 4, 2002Date of Patent: November 16, 2004Assignee: W. W. Henry CompanyInventors: John W. Bulluck, Holly McKee
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Publication number: 20040214945Abstract: A cationically polymerizable composition excellent in curability, long-term storage stability and stability on heating is provided, which contains at least a cationically polymerizable compound, a cationic polymerization initiator and a nitrogen-containing alicyclic compound, and an ink is also provided which comprises the above composition with a colorant. Preferably the cationically polymerizable compound includes at least an alicyclic epoxy compound and an oxetane compound. The alicyclic compound preferably comprises a secondary amine nitrogen atom as a ring constituent atom, and more preferably contains two or more amine nitrogen atoms, particularly secondary amine nitrogen atoms in one ring thereof, such as pyrazolidine, piperazine, homopiperazine and derivatives thereof. Preferably, the alicyclic compound is present in an amount of from 0.001 to 1% by weight of the total amount of the composition or ink.Type: ApplicationFiled: April 19, 2004Publication date: October 28, 2004Applicant: RISO KAGAKU CORPORATIONInventor: Shunsuke Uozumi
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Patent number: 6790894Abstract: A rubber-based soundproofing material comprises a mixture of a rubber blend, a metal or its oxides, alloys or salts, and conventional mixing ingredients. The mixture is either a non-blended chlorobutyl rubber, bromobutyl rubber or acrylate rubber, or a blend of nitrile rubber or styrene-butadiene rubber with epoxidized natural rubber. The mixture has the following proportions: 10-15% by wt. rubber or rubber blend, 85-40% by wt. metal or its oxides, alloys or salts, and 5-10 wt. % mixing ingredients.Type: GrantFiled: June 5, 2002Date of Patent: September 14, 2004Assignee: Thüringen GmbHInventors: Frank Albracht, Gerd Lotze, Karl-Heinz Krause, Gerhard Merkmann, Wolfgang Timm
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Patent number: 6759477Abstract: This invention discloses a method for preparing imides (I) and (II) from compounds having a sulfonyl fluoride functional group. The imides so prepared are useful in a variety of catalytic and electrochemical applications.Type: GrantFiled: May 1, 2002Date of Patent: July 6, 2004Assignee: E. I. du Pont de Nemours and CompanyInventor: Hanne Anna Katharina Blau
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Patent number: 6740721Abstract: A plastic lens composition having a low viscosity, a plastic lens by curing the composition, and a method for producing the plastic lens are disclosed. The plastic lens composition contains a bromine-containing (meth)allyl ester-based compound and exhibits low viscosity and the cured composition has a high refractive index of 1.58 or more and a low specific gravity of 1.40 or less.Type: GrantFiled: October 31, 2001Date of Patent: May 25, 2004Assignee: Showa Denko K.K.Inventors: Kazuhiko Ooga, Tsuneo Tajima, Kazufumi Kai, Hiroshi Uchida
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Patent number: 6737468Abstract: The use of a copolymer (A) preparable by free-radical polymerization of a) at least one olefinically unsaturated monomer and b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a) and of the general formula I R1R2C=CR3R4 (I), in which the radicals R1, R2, R3 and R4 each independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals, in an aqueous medium, in a basecoat material used to produce color and/or effect basecoats BL and multicoat color and/or effect coating systems ML.Type: GrantFiled: January 11, 2002Date of Patent: May 18, 2004Assignee: BASF Coatings AGInventor: Wolfgang Bremser
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Patent number: 6737467Abstract: Powder coating compositions containing 5 to 60 wt % of spherical or near spherical particles having a median diameter of greater than 10, and most preferably of greater than 15 microns exhibit lower gloss without undesirable side effects such as loss of coating flow or creation of an “orange peel” effect.Type: GrantFiled: November 21, 2000Date of Patent: May 18, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Owen H. Decker, M. Aaron Sparks
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Patent number: 6673870Abstract: A composition of polyolefin, ester additive, and hyperbranched polymer with improved tensile energy-to-break value compared to polyolefins wihtout the hyperbranched polymer. The concentration of the hyperbranched polymers can be between about 0.1% and about 10% by weight of the polyolefins. The polyolefins have a melt flow index of about 14 g/10 min or greater.Type: GrantFiled: May 13, 2002Date of Patent: January 6, 2004Assignee: The Procter & Gamble CompanyInventors: Blair Alex Owens, Nancy Eckert Jackson, Dimitris Ioannis Collias
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Patent number: 6653381Abstract: Novel compounds derived from traditional semi- drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10 ° C. and cure to above ambient glass transition (Tg polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.Type: GrantFiled: April 10, 2001Date of Patent: November 25, 2003Assignee: University of Southern MississippiInventors: Shelby Freland Thames, Kamlesh Gopichand Panjnani, Rajan Hariharan, Zhiyu Wang
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Publication number: 20030171458Abstract: The invention relates to methods of making carbohydrate and polyol esters suitable for use as plasticizers for polymer compositions. The invention also relates to plasticized polymer compositions comprising such carbohydrate and polyol esters. The invention also relates to articles prepared from such plasticized polymer compositions. The invention further relates to methods of using these compositions.Type: ApplicationFiled: January 10, 2003Publication date: September 11, 2003Inventors: Charles M. Buchanan, Norma L. Buchanan, Kevin J. Edgar, Juanelle L. Lambert
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Patent number: 6599972Abstract: Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated derivatives of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of fatty alcohols. A process for the synthesis of the latex composition is also disclosed, which involves (a) polymerization of the ethylenically unsaturated derivatives of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C.Type: GrantFiled: January 12, 2001Date of Patent: July 29, 2003Assignee: University of Southern MississippiInventors: Shelby Freland Thames, Kamlesh Gopichand Panjnani, Olan Stanley Fruchey
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Patent number: 6541561Abstract: A method is disclosed of making a polymerizable printing ink which comprises mixing a powdered polymer with a liquid composition comprising at least one polymerizable monomer or oligomer, said oligomer or monomer being polymerizable and the powdered polymer being soluble in said liquid composition at elevated temperature.Type: GrantFiled: May 18, 2000Date of Patent: April 1, 2003Assignee: Trip Industries Holding, B.V.Inventor: Alan Lennox Lythgoe
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Patent number: 6495625Abstract: A chloroprene type rubber composition which comprises a chloroprene type rubber, a carbon black having an average stacking height Lc of at least 2 nm in a C axis direction of the layer planes in the crystallites, and a zinc powder.Type: GrantFiled: December 18, 2000Date of Patent: December 17, 2002Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Yasushi Abe, Mitsuyuki Nakada, Isao Yamagishi, Kazuomi Aoki
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Patent number: 6469082Abstract: A solvent based polychloroprene contact bond adhesive having less than 250 grams per liter volatile organic compounds (VOCs) at high solids content is disclosed. The composition contains polychloroprene polymer, phenolic and tackifying resins, a zinc resinate, metallic oxide and antioxidants, mixed uniformly in a blend of organic solvents. The blend of organic solvents contains VOC exempt solvents as well as aliphatic and aromatic solvents.Type: GrantFiled: June 29, 2001Date of Patent: October 22, 2002Assignee: Illinois Tool Works, Inc.Inventors: Paul A. Raymond, John S. Piwnlca, Jr.
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Patent number: 6437019Abstract: The present invention provides a multiple part ionomeric cement system comprising an organic composition that is substantially free of added water, and an aqueous composition comprising water. The organic composition contains at least a hydrophilic component and an acid functional compound that is provided as greater than 1.0% weight of the organic composition. The liquid ingredients of the compositions are miscible, both as separate compositions and when mixed together.Type: GrantFiled: May 16, 2000Date of Patent: August 20, 2002Assignee: 3M Innovative Properties CompanyInventors: Richard P. Rusin, Joel D. Oxman, Edward J. Winters
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Patent number: 6429253Abstract: Papermaking processes are provided which utilize mixtures of wet strength agents and dry strength agents in amounts that provide paper formed therefrom with decreased wet strength, and hence increase repulpability, without unduly compromising dry strength. Stable compositions comprised of mixtures of wet strength agents and dry strength agents, are also provided which may be advantageously used in said processes.Type: GrantFiled: May 16, 2000Date of Patent: August 6, 2002Assignee: Bayer CorporationInventors: Gerald J. Guerro, Leigh Ann Lawrence
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Patent number: 6335395Abstract: A process for making a stable coating comprising an inorganic, anionic pigment, an organic, anionic binder and an organic, cationic mordant comprising: a) mixing the inorganic, anionic pigment with the organic, cationic mordant; b) lowering the pH of the mixture to below about 4; and c) adding the organic, anionic binder to the mixture, thus providing a coating composition which has an approximately constant viscosity over a period of time.Type: GrantFiled: December 1, 1999Date of Patent: January 1, 2002Assignee: Eastman Kodak CompanyInventors: Sridhar Sadasivan, Suresh Sunderrajan, Michelle M. Oakland, Patrick J. Whittaker, Elwood C. Samons, Craig T. Mollon
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Patent number: 6271303Abstract: An interpolymer consisting essentially of units derived from vinyl fluoride and at least two highly fluorinated monomers, at least one of the highly fluorinated monomers introducing into the polymer a side chain of at least one carbon atom. Films from these interpolymers have substantially reduced haze, low surface tension, and can be made to form solutions in common polar organic solvents that are stable at room temperature. The extremely low surface tensions obtained with these interpolymer films provide enhanced stain resistance and improved release properties compared to polyvinyl fluoride or known vinyl fluoride interpolymers.Type: GrantFiled: November 13, 2000Date of Patent: August 7, 2001Assignee: E. I. du Pont de Nemours and CompanyInventor: Ronald Earl Uschold
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Patent number: 6261700Abstract: Described are coatings, composite structures containing coatings, and compositions for preparing and methods of preparing coatings and composite structures, wherein the compositions comprise inorganic oxide particles and polymerizable brominated compounds, and coatings comprise inorganic oxide particles and a brominated polymer.Type: GrantFiled: May 27, 1999Date of Patent: July 17, 2001Inventors: David B. Olson, Bettie C. Fong, Soonkun Kang, David S. Arney, Zayn Bilkadi
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Patent number: 6225395Abstract: Water-in-water dispersions based on water-soluble polymers can be prepared using a polymer dispersant containing hydrophobic units. The dispersions of the invention are stable on storage and are of low viscosity.Type: GrantFiled: October 30, 1998Date of Patent: May 1, 2001Assignee: Elf Atochem, S.A.Inventors: Denis Tembou Nzudie, Christian Collette
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Patent number: 6174948Abstract: Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated derivatives of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of fatty alcohols. A process for the synthesis of the latex composition is also disclosed, which involves (a) polymerization of the ethylenically unsaturated derivatives of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C.Type: GrantFiled: December 24, 1996Date of Patent: January 16, 2001Assignee: The University of Southern MississippiInventors: Shelby Freland Thames, Kamlesh Gopichand Panjnani, Olan Stanley Fruchey
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Patent number: 6136885Abstract: The present invention provides a multiple part ionomeric cement system comprising an organic composition that is substantially free of added water, and an aqueous composition comprising water. The organic composition contains at least a hydrophilic component and an acid functional compound that is provided as greater than 1.0% weight of the organic composition. The liquid ingredients of the compositions are miscible, both as separate compositions and when mixed together.Type: GrantFiled: June 14, 1996Date of Patent: October 24, 2000Assignee: 3M Innovative Proprerties CompanyInventors: Richard P. Rusin, Joel D. Oxman, Edward J. Winters
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Patent number: 6103798Abstract: Thermoplastic compositions are provided containing a saturated hydrocarbon amine oxide and stabilizer compositions are provided containing a saturated hydrocarbon amine oxide and a second stabilizer. The thermoplastic compositions exhibit good melt flow rate stability during processing and are useful for making molded and extruded articles. The stabilizer compositions are useful for addition to thermoplastics for the stabilization thereof. A method is also provided for stabilizing thermoplastic compositions and involves admixing a hydrocarbon amine oxide with a thermoplastic resin. The saturated hydrocarbon amine oxides are preferably trialkyl amine oxides. The thermoplastic resin is preferably a polyolefin resin.Type: GrantFiled: May 26, 1998Date of Patent: August 15, 2000Assignee: General Electric CompanyInventors: Vaikunth S. Prabhu, Roger W. Avakian
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Patent number: 6103815Abstract: A composition comprising a latex fluorocarbon elastomer and fluorinated carbon, xerographic component surfaces comprising such latex fluorocarbon elastomer and fluorinated carbon compositions, and image forming apparatii including such xerographic components are disclosed herein.Type: GrantFiled: February 17, 1998Date of Patent: August 15, 2000Assignee: Xerox CorporationInventors: Joseph Mammino, Robert M. Ferguson, George J. Heeks, Arnold W. Henry, Santokh S. Badesha, Ihor W. Tarnawskyj, Frederick E. Knier, Jr., Martin A. Abkowitz, Kock-Yee Law
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Patent number: 6004668Abstract: A composition in the form of pellets comprising a thermoplastic and wood fiber composite material suitable for forming structural members as a replacement for wood in the manufacture of doors and windows. The composite has less than about 10 wt % water based on pellet weight and a Young's modulus of at least about 500,000. Structural members are typically formed from the composite in an extrusion or an injection molding process.Type: GrantFiled: October 26, 1998Date of Patent: December 21, 1999Assignee: Andersen CorporationInventors: Michael J. Deaner, Giuseppe Puppin, Kurt E. Heikkila
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Patent number: 5891948Abstract: One-coating and one-package type coating material in which wall surfaces or the like of a building are finished into natural granite tone are disclosed. A group of flexible resin flakes having more than three kinds of colors and a binder which is turned to be substantially transparent when dried or set are mixed together. The resin flakes have an irregular shape and a random size, the thickness is uneven within one piece and every one piece, having a peripheral end which becomes continuously thin toward the outer edge, and have a color tone similar to the components of granite. Since the peripheral end of the resin flakes is continuously thin toward the outer edge, when coated, there is no unnatural difference in level in the superposed portions of resin flakes. Further, an external appearance and a quality sense extremely close to natural granite are obtained due to the unevenness of thickness of resin flakes.Type: GrantFiled: April 9, 1996Date of Patent: April 6, 1999Assignee: Curios Co., Ltd.Inventor: Hiromichi Kano
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Patent number: 5741847Abstract: A polymer polyol is produced by a process comprising free radical polymerizing an addition polymerizable di-(substituted phenyl)monomer (e.g., methacrylic ester of diglycidylether of tetrabromobisphenol A) component in the presence of a polyol, wherein the monomer has at least one aromatic halogen and at least one aromatic ethylenically unsaturated substituent. The polymer polyol can also be made by copolymerizing said monomer with an additional ethylenically unsaturated monomer component such as styrene and acrylonitrile. Said polymer polyols are reacted with a polyisocyanate compound forming a flame retardant polyurethane foam.Type: GrantFiled: May 23, 1996Date of Patent: April 21, 1998Assignee: The Dow Chemical CompanyInventors: Wayne R. Willkomm, Ruben Solis, Kenneth J. Hinze
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Patent number: 5652296Abstract: A water-based adhesive comprising water-soluble polymers having carboxy groups and quaternary ammonium groups wherein the polymers can be derived by copolymerizing one or more unsaturated aliphatic carboxylic acid monomers, such as acrylic acid and/or methacrylic acid, and alkylaminoalkyl(meth)acrylate or alkylaminoalkyl(meth)acrylamide, such as dimethylaminoethyl methacrylate or dimethylaminopropylmethacrylamide and the water-based adhesive is a viscous liquid that is colorless, relatively odorless, and free of organic solvents.Type: GrantFiled: March 15, 1996Date of Patent: July 29, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventor: Neil A. Randen
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Patent number: 5605953Abstract: A novel aqueous polymeric formulation is disclosed. Also disclosed are methods of making the polymeric formulation, and of using the polymeric formulation to produce a crosslinked polymeric surface coating on a substrate. One embodiment of the novel polymeric formulation comprises an aqueous carrier; at least one polymeric-ingredient; a non-polymeric polyfunctional amine; and base. The one polymeric ingredient has both acid-functional and acetoacetoxy-type functional pendant moieties. The non-polymeric polyfunctional amine has at least two amine-functional moieties. The amount of base contained within the formulation is effective for inhibiting gellation, which would otherwise occur as a result of crosslinking between the acetoacetoxy-type functional and amine-functional moieties. Another embodiment of the novel polymeric formulation comprises at least two polymeric ingredients, one of which has acetoacetoxy-type functional pendant moieties and the other of which has acid-functional pendant moieties.Type: GrantFiled: June 6, 1995Date of Patent: February 25, 1997Assignee: S. C. Johnson & Son, Inc.Inventor: Richard J. Esser
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Patent number: 5597858Abstract: An improved process for the preparing a dispersions of water soluble cationic polymers in an aqueous salt solution is disclosed. The improvement comprises using as a polymeric dispersion stabilizer a water soluble hydrophobically associating copolymer of diallyldimethylammonium chloride and a monomer selected from the group consisting of: ##STR1## and alkyl esters of acrylic acid, where R.sub.1 is either hydrogen or CH.sub.3 ; R.sub.2 and R.sub.3 are each an alkyl group having 1 to 3 carbon atoms; A.sub.1 is either an oxygen atom or NH; B.sub.1 is either an alkylene group having 2 to 4 carbon atoms or a hydroxypropylene group, Q is benzyl, or C.sub.6 -C.sub.20 alkyl, and X.sub.1.sup.- is an anionic counterion.Type: GrantFiled: March 22, 1995Date of Patent: January 28, 1997Assignee: Nalco Chemical CompanyInventors: Manian Ramesh, Jeffrey R. Cramm, Darrell L. Werges, Christopher P. Howland
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Patent number: 5498659Abstract: A novel aqueous polymeric formulation is disclosed. Also disclosed are methods of making the polymeric formulation, and of using the polymeric formulation to produce a crosslinked polymeric surface coating on a substrate. One embodiment of the novel polymeric formulation comprises an aqueous carrier; at least one polymeric ingredient; a non-polymeric polyfunctional amine; and base. The one polymeric ingredient has both acid-functional and acetoacetoxy-type functional pendant moieties. The non-polymeric polyfunctional amine has at least two amine-functional moieties. The amount of base contained within the formulation is effective for inhibiting gellation, which would otherwise occur as a result of crosslinking between the acetoacetoxy-type functional and amine-functional moieties. Another embodiment of the novel polymeric formulation comprises at least two polymeric ingredients, one of which has acetoacetoxy-type functional pendant moieties and the other of which has acid-functional pendant moieties.Type: GrantFiled: October 7, 1994Date of Patent: March 12, 1996Assignee: S. C. Johnson & Son, Inc.Inventor: Richard J. Esser
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Patent number: 5468803Abstract: A polymer composition including a thermoplastic norbornene polymer which preferably has a number average molecular weight of 10,00-200,000 as determined by gel permeation chromatography in toluene solvent and calculated as styrene and a content of norbornene polymer components having a number average molecular weight of 2,000 or less of 1% by weight or less, and a compounding ingredient, such as a rubber-like polymer, wherein the compounding ingredient is preferably dispersed in the form of microdomains in the norbornene polymer; and medical implements and optical naturals formed essentially of the composition.Type: GrantFiled: March 1, 1993Date of Patent: November 21, 1995Assignee: Nippon Zeon Co. Ltd.Inventors: Nobukazu Takahashi, Tohru Hosaka, Koji Minami, Yuichiro Konishi, Teiji Kohara, Tadao Natsuume
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Patent number: 5466496Abstract: Liquid crystal films which are stable to light, moisture and heat, and which have an improved response time and viewing angle are provided by combining ferroelectric liquid crystals and a polymer matrix. The invention further provides for liquid crystal display elements utilizing the liquid crystal films of the invention. Still further, the invention provides methods of producing the liquid crystal films. According to the invention, liquid crystalline polymers having optical anisotropy as a polymer matrix and functional side chain radicals having an asymmetric carbon atom and dipole moment in the polymer matrix are matched with the dipole moment of the ferroelectric crystals.Type: GrantFiled: April 13, 1994Date of Patent: November 14, 1995Assignee: Samsung Electron Devices Co., Ltd.Inventor: Yong W. Jin
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Patent number: 5439970Abstract: Acrylic polymers having glass transition temperatures less than 0.degree. C.Type: GrantFiled: November 4, 1993Date of Patent: August 8, 1995Assignee: Rhone-Poulenc ChimieInventor: Roland Reeb
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Patent number: 5412048Abstract: Spherical monodispersed polymeric particles are prepared from vinyl monomers and crosslinking polymerizable polyvinyl monomers. More particularly, a novel process for producing spherical monodispersed gel particles that are about 1-6 .mu.m in size and contain at least about 0.5 to about 3 weight percent (based on polymerizable vinyl monomer/vinyl polymer) of a polymerizable polyvinyl monomer is disclosed. The process comprises the steps of combining an isoalkanol solvent, a polymerizable vinyl monomer and a crosslinking polymerizable polyvinyl monomer under timed and monitored conditions.Type: GrantFiled: July 26, 1993Date of Patent: May 2, 1995Assignee: General Electric CompanyInventors: Kathryn L. Longley, John C. Schmidhauser
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Patent number: 5306759Abstract: A coating composition prepared by adding 0 to 150 parts by weight, in terms of diorganosilane, of a hydrolyzate and/or a partial condensate of an diorganosilane (b), 2 to 300 parts by weight of a vinyl resin containing a silyl group (c), 0.01 to 50 parts by weight of a metal chelate compound (d), and an organic solvent (e), to 100 parts by weight in terms of organosilane of a hydrolyzate and/or a partial condensate of an organosilane (a), to which are added two or more mols of a type of .beta.-diketone and/or .beta.-ketoester (f) for one mol of the metal chelate compound (d).Type: GrantFiled: February 11, 1993Date of Patent: April 26, 1994Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Toshinori Sakagami, Koichi Nagano, Tomonobu Shimizu, Kinji Yamada
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Patent number: 5290636Abstract: Improved flame retardant latex coatings are disclosed which comprise copolymers of ring-halogenated aromatic monomer units and alkyl acrylate/methacrylate monomer units, and which may additionally include at least one other monomer. In a first embodiment, the coatings include ring-brominated aromatic monomer units and alkyl acrylate and/or alkyl methacrylate monomer units. In a second embodiment, the coatings include these first two types of monomer units and further include third monomer units from unsaturated esters of saturated carboxylic acids, halogen-free aromatic monomers or unsaturated carboxylic or dicarboxylic acid monomers. In a third embodiment, the coatings include four monomer units, namely ring-brominated aromatic monomer units, alkyl acrylate/methacrylate monomer units, halogen-free aromatic monomer units and unsaturated carboxylic or dicarboxylic acid monomer units.Type: GrantFiled: April 29, 1992Date of Patent: March 1, 1994Assignee: Great Lakes Chemical Corp.Inventors: Richard S. Rose, Jin-liang Wang, Nicolai A. Favstritsky, David E. May, David J. Honkomp
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Patent number: 5284890Abstract: The invention disclosed relates to an injection mouldable synthetic rubber composition which provides twenty-four hour protection from penetration by H-agent and as such is particularly suitable for use in gas masks. The novel rubber composition comprises a synthetic rubber such as bromobutyl rubber, carbon black and other appropriate additives.Type: GrantFiled: January 31, 1985Date of Patent: February 8, 1994Assignee: Her Majesty the Queen as represented by the Minister of National Defence of Her Majesty's Canadian GovernmentInventors: John C. Collyer, John R. Clark