Disaccharide Or Trisaccharide, E.g., Sucrose, Etc. Patents (Class 524/56)
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Patent number: 5565509Abstract: A dried film reinforced with coalescable water insoluble polymer particles which are substantially noncoalesced is disclosed. Also disclosed are dried films reinforced with noncoalesced water insoluble polymer particles which are readily water dispersible. Also disclosed are stable aqueous dispersions for formation of such films which comprise (a) a water insoluble component comprising coalescable polymer particles which have a T.sub.g less than 55.degree. C. and a majority of which have a particle size of less than 1 micron; and (b) a water soluble component which comprises a water soluble polymer capable of inhibiting coalescence of the polymer particles, or a water soluble polymer and a component capable of inhibiting coalescence of the polymer particles.Type: GrantFiled: June 2, 1995Date of Patent: October 15, 1996Assignee: Penford Products CompanyInventors: Charles C. Nguyen, Verne J. Martin, Edward P. Pauley
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Patent number: 5563192Abstract: A method for producing stabilized polymers, exhibiting enhanced thermal stability, which comprises polymerizing a mixture comprising: a monomer comprising an allyl-containing group which is bonded to primary and/or secondary hydroxyl groups on a saccharide, preferably a long chain (C.sub.3 -C.sub.20) allyl-containing ether group on the hydroxyl group; and one or monomers selected from methacrylate ester monomers, acrylate ester monomers, acrylamide monomers and styrene monomers, in mounts sufficient to produce a polymer exhibiting enhanced thermal stability. Polymers having enhanced thermal stability are obtained using a monomer comprising an allyl-containing group which is bonded to primary and/or secondary hydroxyl groups on a saccharide, as a novel stabilization crosslinking agent.Type: GrantFiled: June 6, 1995Date of Patent: October 8, 1996Assignee: Hawaiian Sugar Planters' AssociationInventors: Navzer D. Sachinvala, Redford F. Ju, Morton H. Litt
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Patent number: 5556460Abstract: A cement admixture composed of a low molecular weight oxyalkylene compound and a comb polymer having carboxylic acid groups and oxyalkylene units therein.Type: GrantFiled: September 18, 1995Date of Patent: September 17, 1996Assignee: W.R. Grace & Co.-Conn.Inventors: Neal S. Berke, Michael P. Dallaire, Ellis M. Gartner, Awdhoot V. Kerkar, Timothy J. Martin
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Patent number: 5552462Abstract: A novel blend composition comprising one or more cationic polygalactomannas and xanthan gum is provided. The blend is capable of producing enhanced viscosities when distributed in a solvent. The blend is suitable for use in foods, explosives, oil field chemicals, textile fibers, agricultural chemicals and cosmetics.Type: GrantFiled: November 22, 1993Date of Patent: September 3, 1996Assignee: Rhone-Poulenc Inc.Inventor: Michael H. Yeh
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Patent number: 5550178Abstract: Crosslinked biocompatible compositions comprising an ionically crosslinked component and a covalently crosslinked component for encapsulating biologics are disclosed. In accordance with the present invention, also disclosed are crosslinkable biocompatible mixtures comprising an ionically crosslinkable component and a covalently crosslinkable component. Methods for encapsulating biologics with the crosslinked and cross-linkable biocompatible compositions are provided. Also, retrievable macrocapsules for encapsulating microcapsules or biologics are disclosed.Type: GrantFiled: June 13, 1994Date of Patent: August 27, 1996Assignee: VivoRx, Inc.Inventors: Neil P. Desai, Patrick Soon-Shiong, Paul A. Sandford, Roswitha E. Heintz
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Patent number: 5545732Abstract: A method for producing stabilized polymers, exhibiting enhanced thermal stability, which comprises polymerizing a mixture comprising: a monomer comprising an allyl-containing group which is bonded to primary and/or secondary hydroxyl groups on a saccharide, preferably a long chain (C.sub.3 -C.sub.20) allyl-containing ether group on the hydroxyl group; and one or monomers selected from methacrylate ester monomers, acrylate ester monomers, acrylamide monomers and styrene monomers, in mounts sufficient to produce a polymer exhibiting enhanced thermal stability. Polymers having enhanced thermal stability are obtained using a monomer comprising an allyl-containing group which is bonded to primary and/or secondary hydroxyl groups on a saccharide, as a novel stabilization crosslinking agent.Type: GrantFiled: June 6, 1995Date of Patent: August 13, 1996Assignee: Hawaiian Sugar Planters' AssociationInventors: Navzer D. Sachinvala, Redford F. Ju, Morton H. Litt
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Patent number: 5539044Abstract: Flow of a stream comprised of hydrocarbons is improved by introducing into the stream a stable, non-agglomerating suspension comprising:(a) water,(b) highly dispersed in the water, and substantially insoluble therein, and extremely finely-divided, non-crystalline, ultra-high molecular weight, hydrocarbon-soluble, undegraded polyalkene having 2 to about 30 carbon atoms per alkene precursor and an inherent viscosity of at least 20 dL/g, and(c) a small but effective amount of a surfactant having a HLB of at least about 9. The finely divided polyalkene is prepared by polymerization and then cryogrinding below the glass transition temperature of the polyalkene.Type: GrantFiled: September 2, 1994Date of Patent: July 23, 1996Assignee: Conoco In.Inventors: Aysen Dindi, Ray L. Johnston, Yung N. Lee, Debora F. Massouda
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Patent number: 5536778Abstract: A pressure-sensitive adhesive is obtainable by a process comprising polymerizingan ester of acrylic or methacrylic acid having a non-tertiary alcohol comprising 4 to 12 carbon atoms in the alkyl chain (component A) in the presence ofat least one kind of a naturally occuring polysaccharide except hydrolyzed starch, cellulose ethers and cellulose esters (component B),radical chain initiators (component C).The pressure sensitive articles manufactured from the pressure sensitive adhesive have improved properties. In particular, the articles are repositionable and the adhesion under humid conditions is improved when cellulose powder is used as component B.Type: GrantFiled: April 21, 1993Date of Patent: July 16, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Karl W. Kreckel, Andreas H. Graichen
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Patent number: 5536446Abstract: Solid state conductive polymer compositions which are ionically-conductive regardless of the amount of water present in the composition are disclosed. The compositions have solvating polymer, ionic salt, and optionally if the composition is not cohesive and pliable, essentially non-volatile plasticizer in an amount sufficient to render the composition cohesive and pliable. Biomedical electrodes having means for electrical communication contacting the compositions are also disclosed. Methods of making the compositions and electrodes are also disclosed.Type: GrantFiled: September 27, 1994Date of Patent: July 16, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Rosa Uy, Timothy M. Dietz
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Patent number: 5534566Abstract: Use of a di- or polysaccharide alcohol and an inorganic or organic zinc, aluminum or rare-earth compound allows a high degree of stabilization of a halogen-containing polymer or polymer recyclate.Type: GrantFiled: April 10, 1995Date of Patent: July 9, 1996Assignee: Ciba-Geigy CorporationInventors: Wolfgang Wehner, Rolf Drewes, Karl J. Kuhn, Hans-Jurgen Sander, Markus Kolb
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Patent number: 5522974Abstract: Described is a method of preparing polyacrylamide gel containing capillary tube wherein acrylamide is polymerized from a liquid to a gel within the tube, the improvement comprising the steps of: a) after the polymerization, annealing the gel inside the tube by cycling the gel/tube at least once in a temperature range from 20.degree. C. to a temperature not to exceed about 75.degree. C. and back to ambient; and b) recovering the stress released gel-filled tube. Preferably, the polymerization commences at the middle of the tube and commences toward the extremities of the tube.Type: GrantFiled: October 21, 1993Date of Patent: June 4, 1996Assignee: Laurence A. FishelInventors: Laurence A. Fishel, Barnett Rosenberg, David A. Juckett
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Patent number: 5523335Abstract: A flexible packaging printing ink is formulated from a resin binder (e.g. an alcohol soluble polyamide or a water-dispersible polyacrylate), pigment, solvent (e.g. a lower alkanol or water), and an alkyl polyglycoside surfactant. Related methods, compositions and articles are also provided. A method of preparing a polyamide resin by condensing a dibasic acid mixture with a diamine mixture and melt blending the resin with an alkyl polyglycoside is also provided. These polymers are particularly useful as the binder for a flexible packaging laminating ink composition.Type: GrantFiled: October 17, 1994Date of Patent: June 4, 1996Assignee: Henkel CorporationInventors: Paul D. Whyzmuzis, Kenneth Breindel, Roger A. Lovald
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Patent number: 5521233Abstract: A biodegradable air drying screen printing ink. The ink includes a base made of water and a colloidal gum, preferably sodium alginate. A naturally-occurring binder is added to the base, preferably natural latex. The ink also includes one or more pigments made from natural ingredients, preferably plants or insects.Type: GrantFiled: February 9, 1995Date of Patent: May 28, 1996Inventor: Shari Shifrin
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Patent number: 5512619Abstract: A curing composition for concrete that is an effective water barrier and that is relatively easily removed contains an acrylic or a styrene polymer latex and a polysaccharide. The polysaccharide makes the coating composition susceptible to enzyme action and thus easily removable by flooding the surface of the coated concrete with a dilute solution of enzyme reactive with the polysaccharide.Type: GrantFiled: April 8, 1994Date of Patent: April 30, 1996Assignee: National Starch and Chemical Investment Holding CorporationInventors: Dennis R. DeWacker, Leon Rosenberg, Nicholas J. Lacamera, Jr.
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Patent number: 5498662Abstract: Disclosed herein is a gas barrier film formed from a mixture containing (A) at least one poly(meth)acrylic acid polymer selected from the group consisting of poly(meth)acrylic acid and partially neutralized products of poly(meth)acrylic acid and (B) a saccharide in a weight ratio of 95:5 to 20:80, and having an oxygen gas permeability coefficient of 5.00.times.10.sup.-3 ml(STP).cm/m.sup.2.h. atm {Pa} or lower as measured under conditions of 30.degree. C. and 80% relative humidity. A production process of the gas barrier film, in which a film is formed from the mixture, and then subjected to a heat treatment under specific conditions, is also disclosed.Type: GrantFiled: October 18, 1994Date of Patent: March 12, 1996Assignee: Kureha Kagaku Kogyo K.K.Inventors: Hideaki Tanaka, Hiroyuki Oba, Tomoaki Sato, Tomohisa Hasegawa
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Patent number: 5496874Abstract: Disclosed is a hydrodisintegratable material which, when injection molded into an object, acquires and maintains the desired shape without becoming brittle. Additionally, in the presence of water, the molded object has the ability to rapidly disintegrate and disperse when subjected to standardized agitation testing. The moldable material typically includes: (1) from about 7.5 to about 85 weight percent of at least one water dispersible polymer; (2) from about 7.Type: GrantFiled: November 2, 1994Date of Patent: March 5, 1996Assignee: Kimberly-Clark CorporationInventors: Judith K. Faass, Lee K. Jameson, Bernard Cohen, Lamar H. Gipson
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Patent number: 5459181Abstract: A three-part dry blended soluble mixture which includes a water soluble hydroxyl group bearing polymer, a covalent crosslinking agent, and a catalyst is made into an aqueous solution which is then applied to any underlying material of choice. After drying, the crosslinked polymer forms a material that is completely insoluble in water, thereby serving as a binder or tackifier. One additive that may be included with the dry blend is wood fiber in an approximate weight ratio of nine to one and thereafter this dry blend is combined with water where the three-part dry blend goes into solution while the fibers remain in suspension. This composition is then spray applied to any underlying material and upon drying, there is formed a bonded fiber matrix which is relatively strong and which has many applications such as for use as an erosion control/seeding material, a covering for landfills, or a covering for other particulate materials stored in an outside location.Type: GrantFiled: July 23, 1993Date of Patent: October 17, 1995Assignee: Weyerhaeuser CompanyInventors: Hugh West, Ezequeil Delgado-Fornue
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Patent number: 5412004Abstract: A silicone polymer, a paste-like silicone composition prepared by kneading the silicone polymer and a silicone oil under a shearing force, and a water-in-oil type cosmetic composition comprising the paste-like silicone composition as an oil phase component are disclosed. The silicone polymer is prepared by the addition polymerization of components comprising an organohydrogenpolysiloxane R.sup.1.sub.a R.sup.2.sub.b H.sub.c SiO.sub.(4-a-b-c)/2 (1) or R.sup.1.sub.f H.sub.g SiO.sub.(4-f-g)/2 (2) and a polyoxyalkylene C.sub.m H.sub.2m-1 O(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i C.sub.m H.sub.2m-l (A) or an organopolysiloxane R.sup.1.sub.j R.sup.4.sub.k SiO.sub.(4-j-k)/2 (B) the components, including (1) or (A) as an essential component. The silicone polymer can swell in silicone oils and function as a viscosity increasing agent for silicone oils.Type: GrantFiled: February 25, 1994Date of Patent: May 2, 1995Assignees: Kose Corporation, Shin-Etsu Chemical Co., Ltd.Inventors: Kiyomi Tachibana, Koji Sakuta, Kenichi Isobe
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Patent number: 5403394Abstract: An additive to cement based materials to render the materials self-leveling upon being mixed with water and applied as a coating upon a floor substrate. The additive comprises a formaldehyde based resin, preferably melamine formaldehyde, and a water retention agent, preferably xanthan gum alone, hydroxyethyl cellulose alone, or a combination thereof.Type: GrantFiled: February 24, 1994Date of Patent: April 4, 1995Inventor: Yves Burgand
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Patent number: 5393810Abstract: Compositions and methods are provided which provide improved viscosity reduction of crosslinked hydratable polymer treating fluids in the presence of uncured resin-coated proppants. The uncured resins are generally uncured phenolic or furan resins. The breaker comprises an oxidizing agent to which is added a sequestering agent comprising a copolymer of vinylpyrrolidone and acrylic acid to sequester at least a portion of any phenolic extracts from said resin that may be present in said treating fluid from contact with the uncured resin.Type: GrantFiled: December 30, 1993Date of Patent: February 28, 1995Assignee: Halliburton CompanyInventors: Phillip C. Harris, Stanley J. Heath
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Patent number: 5376707Abstract: Disclosed herein is a polyvinyl chloride resin composition for powder molding which comprises granular polyvinyl chloride resin (as component A), particulate polyvinyl chloride resin (as component B), stabilizer, plasticizer, and saccharide (as component C). Disclosed also herein is a process for producing said resin composition by mixing granular polyvinyl chloride resin (as component A), particulate polyvinyl chloride resin (as component B), stabilizer, plasticizer, and saccharide (as component C). The resin composition is suitable for the production of covering materials for automotive interior.Type: GrantFiled: October 13, 1992Date of Patent: December 27, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshihiro Nakatsuji, Toshio Igarashi, Akira Wakatsuki, Yuu Shida, Hikaru Shimizu
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Patent number: 5362779Abstract: A dampening water composition which is inexpensive and which does not contaminate working environment as well as exterior environment wherein the dampening water composition comprising water, a pH buffering agent, a water-soluble polymer and n-propyl alcohol, wherein at least a portion of the water-soluble polymer comprises pullulan.Type: GrantFiled: December 2, 1992Date of Patent: November 8, 1994Assignees: Dai Nippon Printing Co., Ltd., Kabushiki Kaisha Nichinan KagakuInventors: Takuo Kitayama, Isamu Setoguchi
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Patent number: 5360847Abstract: A coating composition for concrete that is an effective water barrier and that is relatively easily removed comprises an acrylic copolymer or a styrene copolymer latex and a polysaccharide. The polysaccharide makes the coating composition susceptible to enzyme action and thus easily removable by flooding the surface of the coated concrete with a dilute solution of enzyme reactive with the polysaccharide.Type: GrantFiled: January 19, 1993Date of Patent: November 1, 1994Assignee: National Starch and Chemical Investment Holding Corp.Inventors: Dennis R. Dewacker, Leon Rosenberg, Nicholas J. Lacamera, Jr.
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Patent number: 5340389Abstract: The invention provides aqueous multicolor compositions containing discrete hydrated colored globules dispersed in an aqueous dispersing medium containing a film forming material. To impart the enhanced properties of long term stability and resistance to application by means of brush and roller, the globules are obtained by reacting two or more pigment containing hydrophilic colloids selected from carboxylated cellulose colloids, polysaccaride gums and acrylic polymers with at least two metal cations selected from Fe.sup.3+, Al.sup.3+, Ca.sup.2+, and Mg.sup.2+. The thus obtained colored globules contain from 2.5 to 20.0% by weight of pigment and fillers and 10 to 40% by weight of a film forming resin. The globules constitute and are about 60 to 90% by weight of the final composition, while the dispersing medium is 40 to 10% by weight of the final composition.Type: GrantFiled: June 18, 1993Date of Patent: August 23, 1994Assignee: Brymore Enterprises S.A.Inventor: Germano Bollini
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Patent number: 5340853Abstract: The present invention relates to an absorbing and swelling agent for water, aqueous solutions and body liquids, which consists of a mixture of at least two components, whereby component A is at least a water-swellable, synthetic polymer or copolymer cross-linked with a polyfunctional compound, and component B is at least a polysaccharide selected from the group consisting of galactomannans or polygalactomannans, as well as galactomannan derivatives or mixtures thereof with other natural or synthetic polymers which at normal temperature are present as pourable powders or as fibrous materials and are only partially soluble or insoluble in water.Type: GrantFiled: September 17, 1991Date of Patent: August 23, 1994Assignee: Chemische Fabrik Stockhausen GmbHInventors: Miroslav Chmelir, Helmut Klimmek
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Patent number: 5338490Abstract: A two-phase composite of ionically-conductive pressure-sensitive adhesive, biomedical electrodes using the composite and methods of preparing the composite and the electrode are disclosed. The continuous phase is a hydrophilic, solid state pressure-sensitive adhesive composition ionically-conductive regardless of an amount of water present in the composition. The discontinuous phase are domains of a hydrophobic pressure-sensitive adhesive which enhances adhesion of the composite to mammalian skin while maintaining acceptable alternating current impedance of the composite.Type: GrantFiled: August 31, 1993Date of Patent: August 16, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Timothy M. Dietz, Robert A. Asmus, Rosa Uy
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Patent number: 5334640Abstract: Crosslinked biocompatible compositions comprising an ionically crosslinked component and a covalently crosslinked component for encapsulating biologics are disclosed. In accordance with the present invention, also disclosed are crosslinkable biocompatible mixtures comprising an ionically crosslinkable component and a covalently crosslinkable component. Methods for encapsulating biologics with the crosslinked and crosslinkable biocompatible compositions are provided. Also, retrievable macrocapsules for encapsulating microcapsules or biologics are disclosed.Type: GrantFiled: April 8, 1992Date of Patent: August 2, 1994Assignee: Clover Consolidated, Ltd.Inventors: Neil P. Desai, Patrick Soon-Shiong, Paul A. Sandford, Roswitha E. Heintz
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Patent number: 5321064Abstract: A biodegradable interpolymer and composition is prepared by the reactive blending of a synthetic polymer having functional groups with a naturally occurring biodegradable polymer such as a carbohydrate or protein compound. During reactive blending, the synthetic polymer can undergo a chemical reaction with the biodegradable natural polymer which results in covalent and physical bonding between the two polymers, thereby forming an interpolymer. By this process, a biodegradable interpolymer composition is produced that is suitable for molding various articles.Type: GrantFiled: May 12, 1992Date of Patent: June 14, 1994Assignee: Regents of the University of MinnesotaInventors: Utpal R. Vaidya, Mrinal Bhattacharya
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Patent number: 5292782Abstract: A thermoplastic polymeric composition including starch, at least one synthetic thermoplastic polymer and a plasticiser in which the plasticiser is at least one compound selected from the group consisting of:a) polyols formed by from 1 to 20 repeating hydroxylated units each including from 2 to 6 carbon atoms, provided that when the polyol is formed by only one repeating unit it has at least 4 carbon atoms, with the exclusion of sorbitol,b) ethers, thioethers, inorganic and organic esters, acetals and amino-derivatives of polyols formed by from 1 to 20 repeating hydroxylated units each including from 2 to 6 carbon atoms with the exclusion of acetic esters of glycerine, triethyl citrate and tributyl citrate,c) polyol reaction products having from 1 to 20 repeating hydroxylated units each including from 2 to 6 carbon atoms with chain extenders;d) polyol oxidation products having from 1 to 20 repeating hydroxylated units each including from 2 to 6 carbon atoms including at least one aldehydic or carboxylic functiType: GrantFiled: December 28, 1992Date of Patent: March 8, 1994Assignee: Novamont S.p.A.Inventors: Catia Bastioli, Vittorio Bellotti, Alessandro Montino
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Patent number: 5290832Abstract: A molding based on finely divided organic and/or inorganic materials containing, as binder, the solid component of an aqueous polymer dispersion which is obtainable by polymerizing unsaturated monomers which can be polymerized by means of free radicals in the aqueous phase in the presence of a monosaccharide, oligosaccharide, polysaccharide, oxidatively, hydrolytically and/or enzymatically degraded polysaccharide, chemically modified monosaccharide, oligosaccharide or polysaccharide, or a mixture of the said compounds, by the process of free-radical aqueous emulsion polymerization.Type: GrantFiled: October 7, 1992Date of Patent: March 1, 1994Assignee: BASF AktiengesellschaftInventors: Thomas Schwerzel, Kurt Wendel, Thomas Anselmann, Ruediger Fuessl
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Patent number: 5278217Abstract: A water absorptive composition comprising a thermoplastic elastomer as a first component, a water-absorptive resin as a second component, and a third component selected from the group which consists of: a water-soluble resin; a hydrophilic compound selected from the group consisting of metal salt of carboxylic acid, polyhydric alcohol, amino alcohol, linear polyether, saccharide, and sugar alcohol; and a surface treating agent selected from the group consisting of sorbitan fatty acid ester, glycidyl ether of polyhydric alcohol, and silane coupling agent. The composition is suitably used for producing a water absorptive member for protecting optical fiber elements of an optical fiber cable.Type: GrantFiled: October 7, 1992Date of Patent: January 11, 1994Assignees: Tokai Rubber Industries, Ltd., Summitomo Electric Industries, Ltd., Nippon Telegraph and Telephone Corp.Inventors: Masanari Umeda, Yukio Sakuraba, Fumihiro Ashiya, Toshinobu Matsuo
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Patent number: 5270358Abstract: A composite of a gel of swollen hydrocolloid dispersed in a pressure sensitive adhesive matrix is provided. The gel has a natural or synthetically derived hydrocolloid swollen with a non-volatile swelling agent, such that the gel may have a shear modulus of less than 6.2.times.10.sup.6 dynes/cm.sup.2. The gel-adhesive composite has continued skin adhesion whether applied to or existing in dry or moist skin conditions. The gel contributes a high moisture vapor transmission rate to attempt to maintain dry skin conditions while the adhesive maintains skin adhesion. The gel-adhesive composite may be used in a variety of tape, dressing, bandage, drape, or other skin contacting usage and may optionally include antimicrobial agents to treat the skin while adhesion continues.Type: GrantFiled: June 25, 1992Date of Patent: December 14, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventor: Robert A. Asmus
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Patent number: 5264471Abstract: The invention relates to a process for the production of absorbers for water, aqueous solutions and body liquids, the absorbers consisting of at least two components A and B, whereby component A is at least a water-swellable synthetic polymer or copolymer, and component B is at least a natural or synthetic compound being present at normal temperature as a pourable powder which is highly or at least partially soluble, in water, or as a liquid. The present invention is characterized by the fact that component B is added in the form of a powder, a liquid or as a solution to component A during the end phase of the production process thereof after a polymer reaction degree of 90%, preferably 95% is attained, that is is mixed with the polymer gel of component A and, in order to obtain a powdery, pourable end product, is dried, if necessary, and ground.Type: GrantFiled: September 17, 1991Date of Patent: November 23, 1993Assignee: Chemische Fabrik Stockhausen GmbHInventor: Miroslav Chmelir
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Patent number: 5248712Abstract: A binder for preparing an aqueous ceramics slurry, which contains a hydrophilic polymer such as a water-soluble (meth)acrylic polymer, a polysaccharide of natural origin such as pectin, pectinic acid, glucan, etc., and a polyvinyl compound such as poly(vinyl butyral). The aqueous ceramics slurry contains less than 25 parts by weight of the binder to 100 parts by weight of ceramics powder. The slurry is applied on a carrier film by a doctor blade method and dried to give a ceramics green sheet. A ceramics sheet can be produced by sintering the green sheet.Type: GrantFiled: December 18, 1991Date of Patent: September 28, 1993Assignee: Takeda Chemical Industries, Ltd.Inventors: Tatsuro Takeuchi, Motoya Mouri, Tetsuya Sahara
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Patent number: 5246986Abstract: A bituminous binder emulsion is provided and is formed from a dispersion of an organic phase consisting of a bituminous binder in an aqueous phase incorporating an emulsifying system made up of one or more emulsifying agents, a water-soluble thickener and optionally, a pH regulating agent. The thickener which may be used to control the viscosity of the emulsion incorporates at least 40% scleroglucan by weight. The emulsion obtained may be used for road building applications, water-proofing in civil engineering or construction works, or for industrial purposes.Type: GrantFiled: June 25, 1991Date of Patent: September 21, 1993Assignee: Elf FranceInventors: Chaverot Pierre, Francis Demangeon, Huet Yves
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Patent number: 5218021Abstract: Co-oligmers of the formula R.sub.f --E.sub.m --(S).sub.n --[M.sub.1 ].sub.x --[M.sub.2 ].sub.y --H and mixtures thereof, wherein R.sub.f is a perfluoroalkyl group, E is a linkage group, M.sub.1 represents a non-ionic hydrophilic monomer unit, M.sub.2 represents an anionic hydrophilic monomer unit, n and m are optionally 0 or 1, and x and y represent the number of monomer units present in the novel co-oligomers, the sum of x and y being between 5 and 200, and y/(x+y) being between 0.01 and 0.98; are useful as additives in polar-solvent fire-fighting compositions when used in conjunction with polysaccharides and other adjuvants. They improve dynamic foam stability and vapor suppressing ability of the foam, thereby reducing the flammability of polar solvent contaminated foams and consequently improving extinguishment and burnback resistance.Type: GrantFiled: February 6, 1992Date of Patent: June 8, 1993Assignee: Ciba-Geigy CorporationInventors: Kirtland P. Clark, Michael Jacobson, Chang H. Jho
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Patent number: 5218020Abstract: The invention relates to elastomers and articles reinforced with 5 to 30 phr Chitosan particles having a diameter of 0.5 to 75 microns. In an illustrated embodiment, the Chitosan may be modified with an oxygen reactive group or a nitrogen reactive group to make the Chitosan more reactive with an elastomer. Also provided is an economical method of incorporating very fine Chitosan particles into an elastomer matrix. In the method Chitosan is dissolved in an acid and mixed with a coagulating liquid (for coagulating latex), and the mixture of chitosan/coagulating liquid is mixed with a latex solution to provide an elastomer/chitosan composite. The elastomer/chitosan composite may be used as formed or it can be used as a masterbatch and mixed with more elastomer.Type: GrantFiled: February 12, 1992Date of Patent: June 8, 1993Assignee: The Goodyear Tire & Rubber CompanyInventors: Deborah A. Tung, Richard G. Bauer
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Patent number: 5212219Abstract: A degradable polymer composition is disclosed which comprises a blend of a normally stable chemically saturated polymer, such as polyethylene, a less stable chemically unsaturated polymer or copolymer, such as a styrene/butadiene block copolymer, or natural rubber, an antioxidant active over a limited period and a latent pro-oxidant, such as an organic salt of a transition metal, e.g. cobalt naphthenate. The presence together of the anti-oxidant and the pro-oxidant give rise to a period of induction before a sharp loss of physical strength occurs, whereby the period of induction can be exploited as the effective working life of the polymer composition.Type: GrantFiled: September 4, 1991Date of Patent: May 18, 1993Assignee: Epron Industries LimitedInventor: Gerald J. L. Griffin
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Patent number: 5159049Abstract: A method for preparing stabilized, rehydratable polyacrylamide gels, wherein the stabilizers employed include substituted monosaccharides where the hydroxyl group of the carbon 1 is substituted with a non-charged group comprising an .alpha.-methyl group or an oligosaccharide having from 2 to about 8 repeating units which can be the same or different. These rehydratable gels can be stored for extended periods of time at ambient temperatures, and can be rehydrated without loss of structural or functional integrity to be used for electrophoretic separation of proteins and nucleic acids.Type: GrantFiled: April 22, 1991Date of Patent: October 27, 1992Inventor: Robert C. Allen
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Patent number: 5157063Abstract: The present invention relates to a modeling paste intended particularly for children, characterized by the fact that it consists of expanded polystyrene beads, said beads being uniformly immersed in a synthetic resin which constitutes a binder, by the fact that said paste does not flow, and by the fact that it has sufficient elasticity to provide suitable rebound when used as a ball. It also relates to a process for manufacturing said paste.Type: GrantFiled: November 21, 1991Date of Patent: October 20, 1992Inventor: Joseph J. Wetherell
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Patent number: 5141973Abstract: A method of preparing a polyvinyl alcohol hydrogel contains the steps of charging an aqueous solution of a polyvinyl alcohol having a degree of hydrolysis of not less than 95 mol % and an average polymerization degree of not less than 500 into a container, the aqueous solution containing the polyvinyl alcohol in a concentration of not less than 5 wt. %, cooling the aqueous solution of the polyvinyl alcohol at a temperature of from - (minus) 9.degree. C. to - (minus) 3.degree. C., subjecting the aqueous solution of the polyvinyl alcohol to physical stimulation, and then maintaining the aqueous solution of the polyvinyl alcohol at a temperature of from - (minus) 5.degree. C. to + (plus) 5.degree. C. The polyvinyl alcohol hydrogel may be contained in a plastic container. An MRI phanton is composed of the plastic container containing such polyvinyl alcohol hydrogel.Type: GrantFiled: December 27, 1989Date of Patent: August 25, 1992Assignee: Nippon Oil Co., Ltd.Inventors: Tomokazu Kobayashi, Toshio Morihiro
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Patent number: 5126382Abstract: Metal ion crosslinked superabsorbent polymers and a process for making them are described wherein high concentrations of polyhydroxylated materials are incorporated in order to reduce the sensitivity of the superabsorbent composition to solutions containing dissolved salts. Also provided is a process for forming crosslinked superabsorbents containing high solids polymer content.Type: GrantFiled: January 2, 1991Date of Patent: June 30, 1992Assignee: James River CorporationInventor: David H. Hollenberg
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Patent number: 5066703Abstract: Aqueous coating compositions for applying to rubber articles comprising latex, an emulsifying agent, an inorganic fluoro-containing compound as a filler, which has a refractive index of from 1.32 to about 1.49, a thickening agent, and a compound which imparts mechanical stability to the composition. The composition is applied to the surface of rubber articles prior to molding to impart air venting and release properties thereto and to provide a clear, transparent coating thereon.Type: GrantFiled: April 30, 1990Date of Patent: November 19, 1991Assignee: Wacker Silicones CorporationInventors: George M. Hart, Mark E. Hayford
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Patent number: 5028642Abstract: An improved spandex polymer composition provides fibers or films of the composition with increased heat set efficiency and greater discoloration resistance. The composition contains zinc oxide and a polyhydroxy additive selected from certain sugars, reduced sugars and/or polyhydroxy urethanes formed from these sugars or reduced sugars and an organic diisocyanate.Type: GrantFiled: February 9, 1990Date of Patent: July 2, 1991Assignee: E. I. du Pont de Nemours and CompanyInventors: Charles W. Goodrich, William L. Evans
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Patent number: 5026772Abstract: A lyophilized pharmaceutical composition comprised of a neocarzinostatin derivative having the formula (SMA)-(NCS)-(SMA), is made by a method including dissolving the neocarzinostatin derivative and stabilizing agent comprising at least one saccharide selected from the group consisting of monosaccharides, disaccharides and dextran in an aqueous buffer solution having a pH ranging from about 7.5 to about 9.5, the stabilizing agent being present in an amount by weight (titer) which is at least equal to that of the neocarzinostatin derivative, to provide a solution; adjusting the pH of the solution to provide a pH-adjusted solution having a pH of about 8.0.+-.0.5; sterilizing the pH-adjusted solution by filtration to provide a sterilized solution; and lyophilizing the sterilized solution.Type: GrantFiled: August 29, 1988Date of Patent: June 25, 1991Assignee: Yamanouchi Pharmaceutical Co., Ltd.Inventors: Mitsugu Kobayashi, Go Ohtani, Jun Sekino, Toshimitsu Konno, Hiroshi Maeda
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Patent number: 4992519Abstract: Binder for the production of particle board and plywood with low formaldehyde emission which comprises a polymer formed fron an acidified starch hydrolyzate, urea and formaldehyde. Process for preparation of the polymer and for its use for production of particle board and plywood are also disclosed.Type: GrantFiled: February 1, 1989Date of Patent: February 12, 1991Assignee: Borden, Inc.Inventor: Subhankar Mukherjee
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Patent number: 4983651Abstract: A degradable polymer composition is disclosed which comprises a blend of a normally stable chemically saturated polymer, such as polyethylene, a less stable chemically unsaturated polymer or copolymer, such as a styrene/butadiene block copolymer, or natural rubber, an antioxidant active over a limited period and a latent pro-oxidant, such as an organic salt of a transition metal, e.g. cobalt naphthenate. The presence together of the anti-oxidant and the pro-oxidant give rise to a period of induction before a sharp loss of physical strength occurs, whereby the period of induction can be exploited as the effective working life of the polymer composition.Type: GrantFiled: April 18, 1988Date of Patent: January 8, 1991Assignee: Epron Industries LimitedInventor: Gerald J. L. Griffin
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Patent number: 4978697Abstract: A process for manufacturing thermosetting resins comprises reacting a first compound bearing at least one aldehyde function and a second organic compound bearing at least one hydrogen function. The first chemical is an agricultural by-product containing at least one sugar which can be transformed by hydrolysis into a sugar bearing at least one aldehyde function. Such resins are intended in particular for the manufacture of plywood and particle boards.Type: GrantFiled: December 23, 1988Date of Patent: December 18, 1990Inventor: Philippe Clavier
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Patent number: 4954539Abstract: Aqueous silicone emulsions, especially useful for rendering a wide variety of substrates nonadhesive/water-repellent by polycondensation crosslinking, contain (a) an .alpha.,.omega.-dihydroxydiorganopolysiloxane, (b) an organohydropolysiloxane containing at least 3 hydrogen atoms bonded to silicon atoms per molecule, (c) a polyvinyl alcohol, (d) a nonionic emulsifying agent, and (e) a crosslinking catalytically effective amount of a monochelate of pentacoordinated tin of valency IV.Type: GrantFiled: June 23, 1989Date of Patent: September 4, 1990Assignee: Rhone-Poulenc ChimieInventors: Jacques Cavezzan, Michel Peignier
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Patent number: 4873270Abstract: A substance based on polyurethane from which biodegradable materials can be obtained by rolling comprises, as well as a polyurethane resin serving as its essential constituent, a carbohydrate, at least one second thermoplastic polymer which is miscible in the molten state with the polyurethane resin and/or at least one third biodegradable polymer chosen from among biodegradable aliphatic polyesters, preferably of the same nature as the polyurethane resin used.Type: GrantFiled: February 9, 1988Date of Patent: October 10, 1989Assignee: Charbonnages De FranceInventors: Jean-Marc Aime, Georges Mention, Andre Thouzeau