Interpolymer With At Least One Aliphatic Hydrocarbon Monomer Patents (Class 524/578)
  • Patent number: 7550526
    Abstract: A high impact polymer adapted to be recyclable comprising a polymer, a cross-linking agent, an accelerator, and a nano-clay. The cross-linking agent comprises a sulfur and a peroxide with an activity ranging from 40% to 99%. The accelerator is present in ratios ranging from 1:2 to 1:10 in relation to the sulfur and the peroxide. The nano-clay comprises a weight percent ranging from 1% to 40%. The high impact polymer is formed by preparing the nano-clay with the cross-linking agent and accelerator. Next, the polymer and the nano-clay are mixed, initiating cross-linking. The high impact polymer is formed through creation of macro radicals which create macromolecular polymer chains with sulfur bridges without requiring high torque. The accelerator ensures that the cross-linking and the formation of sulfur bridges occur simultaneously, and partially inhibits the cross-linking. The nano-clay enhances the reversibility of the cross-linking and provides enhanced strength.
    Type: Grant
    Filed: August 14, 2007
    Date of Patent: June 23, 2009
    Inventor: Said Bouhelal
  • Publication number: 20090082520
    Abstract: A composition includes specific amounts of a high molecular weight poly(arylene ether), a rubber-modified polystyrene, and a hydrogenated block copolymer. The use of the high molecular weight poly(arylene ether) unexpectedly provides substantially improved durability to articles molded from the composition. The composition is particularly useful for molding hot water pipes and fittings.
    Type: Application
    Filed: September 20, 2007
    Publication date: March 26, 2009
    Inventors: Geuch Zijlma, Michael L. Todt
  • Publication number: 20090030141
    Abstract: The invention provides a composition including a crosslinked styrenic block copolymer, a poly(arylene ether), and a non-polyolefin crystalline or semi-crystalline resin. The composition exhibits an improved balance of stiffness, ductility, and heat resistance. The composition can be prepared by a process that includes melt-kneading the poly(arylene ether), an acid functionalized styrenic block copolymer, an amine crosslinking agent, and a non-polyolefin crystalline or semi-crystalline resin.
    Type: Application
    Filed: July 23, 2007
    Publication date: January 29, 2009
    Inventors: Kim Gene Balfour, Scott Michael Fisher, Hua Guo, Vijay Mhetar
  • Patent number: 7468408
    Abstract: Disclosed is a flame retarded styrene-based resin composition containing a brominated flame retardant and an additive capable of enhancing the flame retardancy of the shaped article of the composition even in a very small amount of addition. The composition comprises (A) a styrene-based resin, (B) 0.1 to 30 parts by weight per 100 parts by weight of the resin (A) of a brominated flame retardant having a bromine content greater than 50 wt %, and (C) 0.01 to 0.2 parts by weight per 100 parts by weight of the resin (A) of a metal phthalocyanine selected from iron, manganese, cobalt, nickel, platinum or paradium phthalocyanine.
    Type: Grant
    Filed: January 11, 2005
    Date of Patent: December 23, 2008
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Hideaki Onishi, Makoto Teramoto
  • Patent number: 7445827
    Abstract: A polymeric composition comprising a polymer and a nucleation agent, and having isotropic shrinkage of less than about 20% and a differential shrinkage of less than about 20%.
    Type: Grant
    Filed: December 2, 2005
    Date of Patent: November 4, 2008
    Assignee: Fina Technology, Inc.
    Inventors: Dang Le, Jerome Thierry-Mieg, Doug Burmaster, Frank Li
  • Publication number: 20080251180
    Abstract: A water-based cement for producing tyres includes 5 to 80% by weight of water, 10 to 60% by weight of a cross-linkable unsaturated-chain polymer base, 1 to 15% by weight of emulsifiers, and a quantity of metal oxide depending on the desired degree of adhesion.
    Type: Application
    Filed: April 11, 2008
    Publication date: October 16, 2008
    Applicant: BRIDGESTONE CORPORATION
    Inventors: Veronica Cantonetti, Salvatore Cotugno
  • Publication number: 20080177242
    Abstract: This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines. The compositions of the present invention preferably comprise an elastomeric polyolefin resin and a high pressure low density type resin.
    Type: Application
    Filed: January 14, 2008
    Publication date: July 24, 2008
    Applicant: Dow Global Technologies Inc.
    Inventors: Andy C. Chang, Stephen M. Hoenig, Yunwa W. Cheung, Daniel G. Moldovan, Wenbin Liang, Charles F. Diehl
  • Publication number: 20080160305
    Abstract: A nano-particle composition including a polar core and a hydrophobic surface layer is provided. The nano-particles have a mean average diameter less than about 100 nm. Methods are disclosed for making and using the nano-particles. The nano-particles can be modified via, for example, hydrogenation or functionalization. The nano-particles can advantageously be incorporated into rubbers, elastomers, and thermoplastics.
    Type: Application
    Filed: June 13, 2007
    Publication date: July 3, 2008
    Inventors: Sandra Warren, Xiaorong Wang
  • Patent number: 7384682
    Abstract: An encapsulant composition and an electronic package. The composition includes a resin, a flexibilizing agent, and a filler material. The electronic package includes a substrate, a semiconductor chip, and a material. The semiconductor chip is mounted on an upper surface of the substrate and electrically coupled to the substrate. The material is positioned on the upper surface of the substrate and against an edge surface of the semiconductor chip. The edge surface of the semiconductor chip is substantially perpendicular to a bottom surface of the semiconductor chip. The material is the encapsulant composition.
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: June 10, 2008
    Assignee: International Business Machines Corporation
    Inventor: Konstantinos I. Papathomas
  • Patent number: 7321005
    Abstract: A method of making an encapsulant composition. The method includes: providing a first quantity of resin material of epoxy or cyanate ester resins; adding to the first quantity of resin material a second quantity of flexibilizing agent; adding to the first quantity of resin material a third quantity of filler material; blending the resin material. After adding the flexibilizing agent, adding the filler material, and blending the resin material, applying the composition to a gap between a substrate and a semiconductor chip. After applying the composition to the gap, pregelling the composition. After pregelling the composition, substantially curing the composition.
    Type: Grant
    Filed: March 19, 2007
    Date of Patent: January 22, 2008
    Assignee: International Business Machines Corporation
    Inventor: Konstantinos I. Papathomas
  • Patent number: 7192997
    Abstract: A composition for use in making an encapsulant usable in the encapsulation of a semiconductor chip assembled to a substrate with C4 solder interconnections therebetween, which in turn may form part of an electronic package. The composition comprises a resin, a flexibilizing agent and a filler material.
    Type: Grant
    Filed: February 7, 2001
    Date of Patent: March 20, 2007
    Assignee: International Business Machines Corporation
    Inventor: Konstantinos I. Papathomas
  • Patent number: 7005476
    Abstract: Disclosed is a multicomponent, isocyanate-terminated or silane-functionalized coating and adhesive material which is continuously produced by mixing the individual components and by heating the latter and continuing mixing until said components reach a liquid state, wherein the resulting reactive coating and adhesive material is fed for direct use especially in profile sheathing plants, coating plants or the like. In the case of isocyanate-terminated material, one component has a reactive high-molecular weight starting polymer and a second component has a reactive isocyanate-terminated cross-linking agent. In the case of the silane- functionalized material, one component has a high-molecular weight starting material and a second component has a reactive, silane-functionalized cross-linking agent.
    Type: Grant
    Filed: February 10, 2000
    Date of Patent: February 28, 2006
    Assignee: Jowat Lobers und Frank GmbH & Co. KG
    Inventors: Christian Terfloth, Theodor Hippold
  • Patent number: 6852821
    Abstract: Aqueous primary dispersions and coating materials comprising dispersed and/or emulsified, solid and/or liquid polymer particles and/or dispersed solid core-shell particles having a diameter?500 nm preparable by controlled free-radical microemulsion or miniemulsion polymerization of A) at least one olefinically unsaturated monomer and B) at least one olefinically unsaturated monomer which is different than the olefinically unsaturated monomer (A) and has the general formula I: R1R2C?CR3R4 (I), in which the radicals R1, R2, R3 and R4 independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; and also their use.
    Type: Grant
    Filed: November 8, 2000
    Date of Patent: February 8, 2005
    Assignee: BASF Coatings AG
    Inventors: Maximilian Bendix, Wolfgang Bremser, David Christie
  • Patent number: 6852787
    Abstract: The present invention relates to substantially free-flowing polymer particles. The polymer particles are those which have a one millimeter penetration temperature of less than about 75° C. as determined by thermal mechanical analysis or an unconfined yield strength of greater than about 15 pounds per square foot (73 kilograms per square meter). The composition also comprises an effective amount of an anti-blocking agent in the presence or absence of a binding agent.
    Type: Grant
    Filed: August 16, 2000
    Date of Patent: February 8, 2005
    Inventors: James W. McMichael, Friedhelm Bunge, Jeffrey R. Montanye, Shrikant V. Dhodapkar
  • Publication number: 20040132894
    Abstract: The present invention is a composition including an isobutylene-based copolymer and polybutene. The copolymers may be mixed with an exfoliating compound and clay, the entire composition forming a nanocomposite. The clay may or may not have an additional exfoliating treatment present prior to mixing with the interpolymer. The composition of the invention has improved air barrier properties and processing properties, and is suitable as an air barrier. One embodiment of the invention is an elastomeric composition including at least one random copolymer of at least a C4 to C7 isomonoolefin derived unit, at least one filler, and polybutene oil having a number average molecular weight greater than 400. The copolymer may be selected from a halogenated poly(isobutylene-co-p-methylstyrene), a halogenated star-branched butyl rubber, or a halogenated butyl rubber, and mixtures thereof.
    Type: Application
    Filed: April 3, 2003
    Publication date: July 8, 2004
    Inventors: Anthony Jay Dias, Glenn E Jones, Donald S Tracey, Walter H Waddell
  • Patent number: 6727314
    Abstract: A composition comprising a polymer, wherein the polymer comprises at least one of: i) a blend of a first polymer comprising a reaction product of acetoacetoxyethyl (meth)acrylate monomer and a second polymer comprising a reaction product of castor oil (meth)acrylate monomer, and ii) a third polymer comprising a reaction product of acetoacetoxyethyl (meth)acrylate monomer and castor oil (meth)acrylate monomer. These polymer compositions can be cured by at least one of auto-oxidation and actinic radiation. Optionally, at least a portion of the acetoacetoxyethyl (meth)acrylate moieties in the polymer can be converted to a corresponding enamine by reaction with at least one of ammonia and an amine.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: April 27, 2004
    Assignee: BASF AG
    Inventors: Armin Burghart, Robert Shane Porzio, Dieter Urban
  • Patent number: 6710116
    Abstract: Transparent and colorable elastomeric compositions are provided. The transparent elastomeric compositions can be covulcanized with rubbers such as polybutadiene, polyisoprene, styrene-butadiene rubber, styrene-isoprene-butadiene rubber, isoprene-butadiene rubber, ethylene-propylene diene rubber or natural rubber and a processing aid. The colorable rubber compositions have sufficient properties to function as a reinforcing member in a shoe sole or automobile tire. Preferably, both the transparent and colorable elastomeric compositions include at least one copolymer of a C4 to C7 isoolefin and a para-alkylstyrene, silica and a high cis-polybutadiene rubber.
    Type: Grant
    Filed: October 18, 2000
    Date of Patent: March 23, 2004
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Walter Harvey Waddell, Robert Ryan Poulter
  • Patent number: 6683126
    Abstract: The present invention provides a coating composition for producing difficult-to-wet surfaces, comprising i) at least one finely divided powder whose particles have a hydrophobic surface and a porous structure characterized by a BET surface area (determined in accordance with DIN 66131) of at least 1 m2/g, and ii) at least one film-forming binder characterized by a surface tension <50 mN/m, the weight ratio of powder to binder being at least 1:4. It also provides a process for producing difficult-to-wet surfaces, and provides for the use of the coating compositions for producing surfaces having a self-cleaning effect and for reducing the flow resistance for liquids in pipes.
    Type: Grant
    Filed: April 25, 2001
    Date of Patent: January 27, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Harald Keller, Ingolf Kühn, Ekkehard Jahns, Christian Lach, Stephan Hüffer, Thilo Krebs, Yi Thomann, Thomas Frechen
  • Patent number: 6683120
    Abstract: A bioadhesive composition for use as a skin adhesive, the composition formed by polymerizing with cross-linking and/or entanglement an aqueous reaction mixture comprising effective amounts of at least one monomer dissolved or suspended therein and capable of forming a hydrogel on polymerization, optionally at least one cross-linking agent for the monomer, and water, said composition having an elastic modulus (G′) and a viscous modulus (G″), wherein the degree of polymerization and/or the degree of cross-linking and/or entanglement are selected to control the skin adhesion properties of the bioadhesive composition having regard to the rate of change of tan delta (G″÷G″) against frequency in a diagnostic portion of the frequency range 0.01 to 300 rad/s, typically the lower end of the said frequency range below about 100 rad/s.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: January 27, 2004
    Assignee: First Water Limited
    Inventor: Hugh Semple Munro
  • Patent number: 6596832
    Abstract: A drag-reducing polymer capable of dissolving even in cold fluids is described, along with a method for manufacturing said drag-reducing polymer. The drag-reducing polymer has at least one alpha-olefin monomer with between a four and nine carbon chain length and a co-monomer and has less than 25% monomers (molar content) with carbon chain lengths of 12 or longer. A drag-reducing polymer suspension is also described.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: July 22, 2003
    Assignee: ConocoPhillips Company
    Inventors: Ray L. Johnston, Stuart N. Milligan
  • Publication number: 20030119974
    Abstract: Disclosed are compositions comprising at least one substantially random interpolymer of ethylene and a vinylidene aromatic monomer or a hindered aliphatic vinylidene monomer and optionally at least one C3-C20 &agr;-olefin monomer, and at least one tackifier. The claimed compositions are useful in adhesives, such as are employed in various applications, such as in packaging and carton sealing, bookbinding, masking tape, clear office tape, labels, decals, bandages, decorative and protective sheets (such as shelf and drawer liners), floor tiles, sanitary napkin/incontinence device placement strips, sun control films, and the joining of gaskets to automobile windows. The claimed compositions further find use in a variety of applications, such as sealants, coatings, molded articles, and multilayered structures.
    Type: Application
    Filed: December 18, 2001
    Publication date: June 26, 2003
    Inventors: Deepak R. Parikh, Martin J. Guest, David A. Speth
  • Patent number: 6576732
    Abstract: A drag-reducing polymer is described, along with a method for manufacturing the drag-reducing polymer. The drag-reducing polymer is manufactured by bulk polymerizing a vinyl aromatic with an &agr;-olefin, wherein the &agr;-olefin has a carbon chain length of between two and twenty carbons. A drag-reducing polymer suspension and drag-reducing polymer solution are also described.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: June 10, 2003
    Assignee: ConocoPhillips Co.
    Inventors: Stuart N. Milligan, Kenneth W. Smith
  • Patent number: 6541558
    Abstract: A composition of matter formed by melt-blending certain thermoplastic polymers and from about 1.0 to about 7.5 wt. % of a fluorocarbon additive, the additive having a lower by surface energy than that of the polymer; the blending resulting in a cooled admixture having a concentration of fluorocarbon additive through a cross-section of the solid composition lower in the interior thereof and higher at the surfaces thereof.
    Type: Grant
    Filed: April 20, 2000
    Date of Patent: April 1, 2003
    Assignee: RES Development Corporation
    Inventors: Robert E. Sterling, Eugene P. Goldberg
  • Patent number: 6472490
    Abstract: The present invention provides an ethylene-aromatic vinyl compound copolymer having an aromatic vinyl compound content of from 1 to less than 55% by molar fraction, and otherwise defined in the claims, and compositions and molded products containing same.
    Type: Grant
    Filed: February 28, 2000
    Date of Patent: October 29, 2002
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Toru Arai, Akihiko Nakamura, Shigeru Suzuki, Toshiaki Otsu, Akio Okamoto
  • Patent number: 6444738
    Abstract: Emulsions containing a hydrocarbon liquid in a continuous phase and alcohol and/or water in a dispersed phase. The emulsions are stabilized by an emulsifier and a coupling agent. The emulsifier is a copolymer containing at least one relatively hydrophobic polymeric block of styrene or ring substituted styrene monomer, and at least one relatively hydrophilic polymeric block of at least one monomer, such as ethylene oxide, selected from the group having the formula H(O—R)nOH where R is an aliphatic radical containing from 1 to 4 carbon atoms and n is a number between 20 and 300. The coupling agent is a copolymer containing at least one polymeric block of styrene or ring substituted styrene monomer, and at least one block being of a saturated or unsaturated aliphatic hydrocarbon moiety, such as butadiene. In order to stabilize the emulsion against stratification or breakage under heat soak conditions the coupling agent contains the styrene monomer and the hydrocarbon moiety in a weight ratio of from 1:0.
    Type: Grant
    Filed: February 2, 2000
    Date of Patent: September 3, 2002
    Assignee: Apace Research Limited
    Inventor: Russell Robert Reeves
  • Patent number: 6420475
    Abstract: Novel crystal gels and articles are formed from one or more copolymers having at least one crystalline poly(ethylene) components and high levels of a plasticizer, said midblock segment having an amount of crystallinity sufficient to achieve improvements in one or more physical properties including improved crack propagation resistance, improved tear resistance, improved resistance to fatigue and resistance to catastrophic failure not obtainable in amorphous gels.
    Type: Grant
    Filed: March 28, 1999
    Date of Patent: July 16, 2002
    Assignee: Applied Elastomerics, Inc.
    Inventor: John Y. Chen
  • Patent number: 6344515
    Abstract: Disclosed are compositions comprising at least one substantially random interpolymer of ethylene and a vinylidene aromatic monomer or a hindered aliphatic vinylidene monomer and optionally at least one C3-C20 &agr;-olefin monomer, and at least one tackifier. The claimed compositions are useful in adhesives, such as are employed in various applications, such as in packaging and carton sealing, bookbinding, masking tape, clear office tape, labels, decals, bandages, decorative and protective sheets (such as shelf and drawer liners), floor tiles, sanitary napkin/incontinence device placement strips, sun control films, and the joining of gaskets to automobile windows. The claimed compositions further find use in a variety of applications, such as sealants, coatings, molded articles, and multilayered structures.
    Type: Grant
    Filed: September 4, 1997
    Date of Patent: February 5, 2002
    Assignee: The Dow Chemical Company
    Inventors: Deepak R. Parikh, Martin Guest, David R. Speth
  • Patent number: 6254956
    Abstract: A floor, wall or ceiling covering which comprises one or more substantially random interpolymers prepared by polymerizing one or more &agr;-olefin monomers with one or more vinylidene aromatic monomers and/or one or more hindered aliphatic or cycloaliphatic vinylidene monomers, and optionally with other polymerizable ethylenically unsaturated monomer(s). The floor, wall or ceiling covering has a good balance of properties, such as sufficient flexibility and conformability to uneven or contoured surfaces for efficient application to floors, walls, or ceilings, sufficient scratch resistance, sufficient indentation resistance, indentation recovery and/or sufficient abrasion resistance.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: July 3, 2001
    Assignee: The Dow Chemical Company
    Inventors: Jerker B. I. Kjellqvist, Stephen R. Betso, Ronald Wevers, Johan A. Thoen, John O. Bieser
  • Patent number: 6235818
    Abstract: A hot melt adhesive composition exhibiting excellent adhesive strength and which is useful as an adhesive for styrene resins contains (B) tackifier and (C) ethylene/C3-C20 &agr;-olefin/aromatic vinyl compound random copolymer and, in some embodiments also (A) base polymer, such as polyolefin, polar group-containing polymer and aromatic vinyl compound/conjugated diene copolymer. A low molecular weight polyolefin may also be included in all embodiments. The randon copolymer (C) may be prepared by polymerizing the &agr;-olefin and aromatic vinyl compound in the presence of a metallocene containing catalyst. In addition to excellent adhesive strength the hot melt adhesives have improved workability.
    Type: Grant
    Filed: July 29, 1999
    Date of Patent: May 22, 2001
    Assignee: Mitsui Chemicals
    Inventors: Kenichi Morizono, Keiji Okada, Suguru Tokita
  • Patent number: 6187837
    Abstract: Podalic foot pads of various shapes and configurations which utilize a padding material that is primarily an A-B-A triblock copolymer and a plasticizer. A-B diblock copolymers may be compounded into the padding material. An anti-bleed agent is preferably employed. The plasticizer may be a resin, mineral oil or otherwise. A detackifier may be employed such as grape seed oil or another slip agent. Antioxidants, pigments and micropsheres may be added to the material. The material has good cushioning properties.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: February 13, 2001
    Assignee: EdiZone, LC
    Inventor: Tony M. Pearce
  • Patent number: 6077874
    Abstract: A process involving (a) homogeneously dispersing tris(2-aminoethyl) amine in a recycled rubber having an individual particle size no greater than 420 microns, (b) mixing the treated recycled rubber with unvulcanized rubber and (c) vulcanizing the rubber mixture.
    Type: Grant
    Filed: July 15, 1998
    Date of Patent: June 20, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson Gibson Wideman, George Frank Balogh, Raymond Dean McQuate, Paul Harry Sandstrom
  • Patent number: 6075077
    Abstract: The subject invention is directed to a composition comprising a polymer, comprising in polymerized form ethylene and at least one additional polymerizable monomer, prepared by polymerizing ethylene and said at least one addition polymerizable monomer in the presence of a catalyst comprising a recited cyclopentadienyl group-containing metal coordination complex and an activating cocatalyst, wherein said composition is an asphalt, bitumen, or adhesive composition.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: June 13, 2000
    Assignee: The Dow Chemical Company
    Inventors: Francis J. Timmers, James C. Stevens
  • Patent number: 6060549
    Abstract: Toughened nanocomposite materials are prepared based on a blend of one or more thermoplastic engineering resins, e.g., nylon, a functionalized, e.g. brominated, copolymer of a C.sub.4 -C.sub.7 isomonoolefin, e.g. isobutylene, and a para-alkylstyrene, e.g. para-methylstyrene, and further contain a uniformly dispersed exfoliated phyllosilicate layered clay, e.g., montmorillonite. The nanocomposite materials exhibit superior mechanical properties, including enhanced impact strength.
    Type: Grant
    Filed: May 20, 1997
    Date of Patent: May 9, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Dongming Li, Dennis George Peiffer, Chester W. Elspass, Hsien-Chang Wang
  • Patent number: 6022924
    Abstract: A color masterbatch resin composition for a packaging material for a photographic photosensitive material which does not adversely affect photographic properties of the photographic photosensitive material, comprising a light-shielding material in a concentration thrice as much as or more that of the packaging material for a photographic photosensitive material, and a thermoplastic resin of which 50 wt. % or more is the same type as a thermoplastic resin occupying 50 wt. % or more of the total thermoplastic resin composing the packaging material for a photographic photosensitive material, production thereof, a packaging material for a photographic photosensitive material formed of a color masterbatch resin composition, and production thereof.
    Type: Grant
    Filed: July 10, 1998
    Date of Patent: February 8, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mutsuo Akao, Koji Inoue
  • Patent number: 5919841
    Abstract: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance, lower hysterisis at high temperature and comparable or increased hysterisis at low temperature compared to an elastomer containing an untreated carbon black. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: July 6, 1999
    Assignee: Cabot Corporation
    Inventors: Khaled Mahmud, Meng-Jiao Wang, Robert A. Francis
  • Patent number: 5877238
    Abstract: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance, lower hysterisis at high temperature and comparable or increased hysterisis at low temperature compared to an elastomer containing an untreated carbon black. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed is method for preparing elastomers compounded with the treated carbon black.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: March 2, 1999
    Assignee: Cabot Corporation
    Inventors: Khaled Mahmud, Meng-Jiao Wang, Robert A. Francis
  • Patent number: 5869591
    Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of monomer units derived from at least one a-olefin, (b) from 30 to 70 weight percent of monomer units derived from at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of monomer units derived from at least one diene. The subject invention further provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials. The subject invention also pertains to foams and methods for their preparation.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: February 9, 1999
    Assignee: The Dow Chemical Company
    Inventors: Kevin W. McKay, Francis J. Timmers, Edwin R. Feig, Thoi H. Ho, Seema V. Karande
  • Patent number: 5869550
    Abstract: A method of improving traction in an elastomer is disclosed. The method includes the step of adding an effective amount of an aggregate comprising a carbon phase and a silicon-containing species phase to an elastomer. Also disclosed is a method of improving the dynamic compliance of an elastomer which includes the step of adding an effective amount of an aggregate comprising a carbon phase and a silicon-containing species phase to the elastomer. The elastomer is preferably used in tires and results in improved traction, for instance, improved skid resistance on ice and snow.
    Type: Grant
    Filed: April 9, 1997
    Date of Patent: February 9, 1999
    Assignee: Cabot Corporation
    Inventors: Khaled Mahmud, Meng-Jiao Wang
  • Patent number: 5830930
    Abstract: Disclosed are elastomeric compounds including an elastomer and a silicon-treated carbon black, and optionally including a coupling agent. The elastomeric compound exhibits poorer abrasion resistance, lower hysterisis at high temperature and comparable or increased hysterisis at low temperature compared to an elastomer containing an untreated carbon black. Elastomeric compounds incorporating an elastomer and an oxidized, silicon-treated carbon black are also disclosed. Also disclosed are methods for preparing elastomers compounded with the treated carbon black.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: November 3, 1998
    Assignee: Cabot Corporation
    Inventors: Khaled Mahmud, Meng-Jiao Wang, Robert A. Francis
  • Patent number: 5814697
    Abstract: A color masterbach resin composition for a packaging material for a photographic photosensitive material which does not adversely affect photographic properties of the photographic photosensitive material, comprising a light-shielding material in a concentration thrice as much as or more that of the packaging material for a photographic photosensitive material, and a thermoplastic resin of which 50 wt. % or more is the same type as a thermoplastic resin occupying 50 wt. % or more of the total thermoplastic resin composing the packaging material for a photographic photosensitive material, production thereof, a packaging material for a photographic photosensitive material formed of a color masterbatch resin composition, and production thereof.
    Type: Grant
    Filed: March 6, 1997
    Date of Patent: September 29, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mutsuo Akao, Koji Inoue
  • Patent number: 5786412
    Abstract: There is provided a melt extrudable, moisture curable thermoplastic polymer which is produced from a silane modified elastomeric polymer and which has improved hysteresis, reduced stress decay and improved creep properties. The polymer may be processed into a nonwoven web, film or foam which may be laminated to other materials such as spunbond polyolefin layers and may be used in medical, personal care, feminine hygiene and other applications.
    Type: Grant
    Filed: May 28, 1996
    Date of Patent: July 28, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ketan N. Shah, Stephen M. Campbell
  • Patent number: 5744566
    Abstract: An unsaturated copolymer based on olefin which is superior in dynamic fatigue resistance (flexural fatigue resistance), weatherability, fastness to ozone, stability in thermal aging and exhibits also superior performances in chemical reactivity, in processibility and in compatibility as well as co-vulcanizability with aromatic ring-containing resins, such as styrene-butadiene rubber (SBR) etc., and is useful for materials of various rubber products and as modifier for resin products is proposed, said copolymer comprising a structural unit derived from an .alpha.-olefin having 2-20 carbon atoms in a proportion of 30-99.8 mole %, a structural unit derived from an aromatic ring-containing vinyl monomer in a proportion of 0.1-60 mole % and a structural unit derived from a chain-formed non-conjugated triene or tetraene having in the molecule one vinyl group in a proportion of 0.1-10 mole % and said copolymer having an intrinsic viscosity determined in Decalin.RTM. at 135.degree. C. of 0.05-10 dl/g.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: April 28, 1998
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Toshiyuki Tsutsui, Masaaki Kawasaki
  • Patent number: 5741830
    Abstract: A water-absorptive soft contact lens comprising a polymer prepared by polymerizing a monomer mixture comprising (A) a fluorine-containing styrene derivative represented by the general formula (I): ##STR1## wherein R.sup.1 is hydrogen atom or methyl group, m is an integer of 1 to 3 and n is 0 or an integer of 1 to 7, and (B) N, N-dimethyl(meth)acrylamide. The water-absorptive soft contact lens has excellent oxygen permeability, high mechanical strength and excellent flexibility independent of water content.
    Type: Grant
    Filed: February 13, 1996
    Date of Patent: April 21, 1998
    Assignee: Menicon Co., Ltd.
    Inventors: Miyuki Kamiya, Naotaka Kamiya, Noriko Iwata, Yasushi Yamamoto, Yasuo Tarumi
  • Patent number: 5698640
    Abstract: Tire curing bladders are made from poly(isobutylene-co-4-bromomethylstyrene) with a benzylic bromine content of from 0.15 to 0.45 mole percent, vulcanized with a cure system of 1,6-hexamethylene-bis(sodium thiosulfate) and zinc oxide. The vulcanizate has low residual benzylic bromine content which leads to enhanced stability under severe duty applications, reduced hot tension set, and reduced adhesion or co-cure to halobutyl tire innerliners.
    Type: Grant
    Filed: August 1, 1996
    Date of Patent: December 16, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Ilan Duvdevani, Neil Frederick Newman
  • Patent number: 5654361
    Abstract: Polymer prepared by anionic polymerization and having a number average molecular weight of from 300,000 to 10,000,000 contain, as components,from 10 to 100% by weight of an ethylenically unsaturated vinyl-aromatic a),from 0 to 90% by weight of an aliphatic diene having two conjugated double bonds b) andfrom 0 to 30% by weight of further ethylenically unsaturated monomers c).
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: August 5, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Binnur Gunesin, Johannes Dobbelaar, Uwe Dittrich, Joachim Krobb
  • Patent number: 5633290
    Abstract: A method of pore-size selective chemical modification of materials having pores of about 1 to 1,500 nm is disclosed. The resulting novel porous materials are particularly useful as separation media in chromatography, for selective isolation, adsorption and catalysis.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: May 27, 1997
    Assignee: Cornell Research Foundation, Inc.
    Inventors: Jean M. J. Frechet, Frantisek Svec
  • Patent number: 5631316
    Abstract: Vulcanizable tire innerliner compositions are described which are essentially free of halogen atoms or contain a reduced halogen content. The innerliners contain a saturated elastomeric interpolymer of a C.sub.4 -C.sub.7 isomonoolefin, e.g., isobutylene and a para-alkylstyrene e.g., para-methylstyrene, which contains benzylic ester functionality having the structure: ##STR1## wherein R.sub.2 and R.sub.3 are independently selected from hydrogen or C.sub.1 to C.sub.6 alkyl, and R.sub.4 is selected from hydrogen, C.sub.1, to C.sub.28 alkyl, aryl or C.sub.2 to C.sub.28 alkenyl.Innerliners of the invention provide excellent impermeability to air, heat aging properties and good adhesion to tire carcass stock required for tire innerliners, and are also essentially free of halogen or contain low halogen content thereby reducing environmental concerns occasioned by the incineration of used tires.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 20, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Bernard J. Costemalle, James V. Fusco, Pierre T. Hous, Hsien-Chang Wang
  • Patent number: 5428067
    Abstract: A column packing material to be used in gel permeation chromatography (GPC) consists of support particles with a mean particle diameter of 1 to 50.mu. of which the matrix is formed by an inorganic or organic, polymeric and porous hard material with a mean pore diameter of 6 to 50 nm and a pore volume of 0.1 to 3 ml/g, the matrix pores containing chemically bound polymer chains. The column packing material of the invention is characterized in that the polymer chains consist of linear, permeable and not-crosslinked polymers with an upper exclusion limit between 200 and 200,000, the pores of the matrix being entirely filled by the polymer chains. The method of the invention is characterized in that the pores of the support particles are filled by polymer chains chemically bound to the pore surfaces, these polymer chains being permeable to solvents and partly to dissolved substances.
    Type: Grant
    Filed: November 19, 1992
    Date of Patent: June 27, 1995
    Assignee: Macherey, Nagel & Co.
    Inventors: Gunter Wulff, Milan Minarik, Ralf J. Oerschkes
  • Patent number: 5418276
    Abstract: There are disclosed a graft copolymer formed by grafting a styrenic monomer onto a high polymer having double bonds in the side chain to constitute highly syndiotactic polystyrenic chain as the graft component, the graft copolymer having a content of graft component of 0.005 to 99% by weight and a reduced viscosity of 0.01 to 30 dl/g as measured at a concentration of 0.05 g/dl in 1,2,4-trichlorobenzene at 135.degree. C. or a melt index of 0.001 to 500 g/10 minutes as measured at 300.degree. C. under a load of 2.16 kg; a process for efficiently producing the above graft copolymer using a catalyst comprising specific components; and a resin composition comprising the above graft copolymer, a highly syndiotactic styrenic polymer or other thermoplastic resin and, when necessary, an inorganic or organic filler. The above graft copolymer and resin composition are excellent in resistance to heat and chemicals, electrical properties, moldability, compatibility, impact resistance, etc.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: May 23, 1995
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shuji Machida, Noriyuki Tani
  • Patent number: H1922
    Abstract: A composition suitable for coating fabrics is provided. The composition comprises a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene; a filler; a processing aid, and a curing agent. A fabric coated with the composition is also provided.
    Type: Grant
    Filed: January 11, 1994
    Date of Patent: November 7, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: James Vincent Fusco, Donald Frederick Kruse, Irwin Jerome Gardner