Inorganic Nrm Additive Patents (Class 524/586)
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Patent number: 4892763Abstract: The invention relates to fiber glass reinforced resins suitable to be used for producing articles such as containers, bottles and the like by stretch-blowing, and it relates also to the so obtained articles.The resins are mixed with from 0.3% to 5% by weight of glass fibers having a diameter from 5 to 20 microns and chopped to lengths such that the length to diameter ratio ranges between 50 to 1000.Type: GrantFiled: January 16, 1985Date of Patent: January 9, 1990Inventor: Diego Duse
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Patent number: 4889879Abstract: Coherent thermoplastic aggregates with very high content of pulverized mineral materials, composed of the said materials, of polyolefin polymers and/or copolymers, and possibly also of various familiar adjuvants, characterized by the fact that, in order for them to have both a volumetric mass close to or at most equal to the theoretical volumetric mass of the pulverized mineral substances entering into their composition and an excellent compatibility with redispersion polymers, the polymers and/or copolymers entering into the composition of the said aggregates in presence of a fluidizing agent are chosen within the group of thermoplastics with melting and/or softening point at least equal to 60.degree. C. and index of fluidity at least 50 (measured according to the standard ASTM D 1238) of the polyolefin type, other than those containing a polar monomer.Type: GrantFiled: July 24, 1987Date of Patent: December 26, 1989Assignee: Pluess Staufer AGInventors: Henry Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
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Patent number: 4879332Abstract: The present invention relates to a self-fire distinguishable halogen-free flame resisting synthetic resin composition obtained by adding 0.5 to 15 parts by weight of synthetic silicate (also called "hydrated silicic acid" or "wet silica") to 100 parts by weight of a mixture comprising 70 to 30 parts by weight of at least one thermoplastic synthetic resin and 30 to 70 parts by weight of magnesium hydroxide or aluminum hydroxide having an average particle size of 0.1 to 10 .mu.m.This composition is white semitranslucent unlike the one containing carbon black according to the prior art, so that it is suitable for decorative use including floor materials and wall covering materials.Type: GrantFiled: April 5, 1988Date of Patent: November 7, 1989Assignee: Dainichiseika Color & Chemicals Mfg. Co. Ltd.Inventors: Nobuo Saito, Mitsuo Noda
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Patent number: 4853069Abstract: Elastomer structures having exposed controlled surface release characteristics can be made by coating at least a portion of their surface with a releasing composition comprising (a) a chlorosulphonated polymer; (b) a reinforcing filler and (c) a green tackifying agent. Optionally, these compositions can also contain a chemical curing system and one or more volatile solvent/diluent viscosity-reducing vehicle. In a specific example, the coating are applied to flexible structures used in machines for the manufacture of articles having natural tack due to their rubber or elastomer content.Type: GrantFiled: October 17, 1984Date of Patent: August 1, 1989Assignee: The Firestone Tire & Rubber CompanyInventors: Cleo M. Williams, Myron D. Sanders, William C. Cook
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Patent number: 4798856Abstract: There is provided a pigment concentrate dispersible in plastics and having a substantially improved characteristic extrusion screen life, comprising a dispersion in a resin carrier of an inorganic pigment of the type having a hydrophilic surface, having on its surface in an effective amount a surfactant of the type characterized by an attached polar terminus, in relation to the surface of the pigment, and an unattached nonpolar terminus, in relation to the carrier resin, or of the type characterized by a high molecular weight surface blocking agent. Such pigments include iron oxide pigments, red iron oxide pigment, yellow iron oxide pigment, black iron oxide pigment, divalent ferrite pigments, zinc ferrite pigment, and magnesium ferrite pigment. Such surfactants include dimethyl polysiloxane, isopropyl triisostearoyl titanate, trimethylol propane, trimethylol ethane, and low molecular weight polyethylene.Type: GrantFiled: November 6, 1987Date of Patent: January 17, 1989Assignee: Columbian Chemicals Co.Inventors: Jorge A. Ayala, George A. Joyce, David Crabbe
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Patent number: 4795768Abstract: A mineral-filled thermoplastic composition is disclosed which comprises polyethylene or an ethylene-vinyl acetate compolymer; a mineral filler consisting, in the case of polyethylene, of aluminum trihydrate, magnesium hydrate, calcium carbonate or calcium/magnesium carbonates, and, in the case of the ethylene-vinyl acetate copolymer, barium titanite or neodymium titanate; and, in the case of polyethylene, an impact promoter consisting of tri(2-ethylhexyl) phosphate, isostearic acid or dodecylpyridinium salts, the selection of the impact promoter being dependent upon the mineral filler being employed, and, in the case of the ethylene-vinyl acetate copolymer, an amount of isostearic acid sufficient to increase the ductility of the composition; also disclosed is an additive composition for a thermoplastic composition which comprises a hydrophobic agent and an impact promoter.Type: GrantFiled: December 3, 1986Date of Patent: January 3, 1989Assignee: Union Carbide CorporationInventors: Fred H. Ancker, Arnold C. Ashcraft, Jr.
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Patent number: 4785042Abstract: The object of the present invention is to provide a polyethylene resin composition which is improved in anti-blocking and slipping properties, and further in antistatic properties without deteriorating the excellent properties of polyethylene, such as transparency and heat sealability.The inventive polyethylene resin composition comprises(A) polyethylene,(B) a zeolite or an anhydrous amorphous aluminosilicate having the basic particle characteristics of zeolite as prepared by acid-treating zeolite,(C) fatty acid amide having a melting point of not more than 130.degree. C., and(D) an antistatic agent.Type: GrantFiled: November 10, 1987Date of Patent: November 15, 1988Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Yutaka Azuma, Yoshikatsu Tanaka
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Patent number: 4767799Abstract: A composition of enhanced radio frequency sensitivity and a method for providing enhanced radio frequency sensitivity to a composition in which a substance suitable for enhancement of radio frequency sensitivity is admixed with a radio frequency sensitizing amount of an inorganic radio frequency sensitizer treated essentially to remove absorbed water and/or other volatiles with the radio frequency sensitizer chosen from among zinc oxide (American Process), bentonite clay, and crystalline or amorphous alkali or alkaline earth metal aluminosilicate. A process for molding using these compositions and the molded product. The composition, method for enhancing radio frequency sensitivity, process for molding and molded product with a polymeric substance, particularly ultra high molecular weight polyethylene, as the substance suitable for enhancement of radio frequency sensitivity.Type: GrantFiled: January 30, 1987Date of Patent: August 30, 1988Assignee: Phillips Petroleum CompanyInventor: Agmund K. Thorsrud
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Patent number: 4762876Abstract: The present invention provides a novel sealant composition consisting essentially of an admixture of at least one polyolefin resin in particulate form, magnesium oxide, a metal salt of a fatty acid and a suitable liquid carrier. In general, the ingredients are normally present in the range of from about 15 to 25 percent polyolefin, from about 0 to about 6 percent of the metal fatty acid salt, from about 10 to 18 percent magnesium oxide and from about 53 to about 70 percent carrier.Type: GrantFiled: August 13, 1987Date of Patent: August 9, 1988Assignee: Cajon CompanyInventor: James L. Bunyan
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Patent number: 4758396Abstract: A process for the preparation of a biaxially stretch-oriented film having at least one opaque layer is described. The opaque layer is composed essentially of propylene polymer and fillers in a quantity of about 10 to 40% by weight, relative to the total weight of propylene polymer and fillers. In production, the granules are melted in a screw extruder, are forced through a die and are formed by cooling to give a preformed film. The preformed film is then stretch-oriented both along the machine direction and transversely perpendicular to the machine direction and is then heat-set. The fillers are added in the form of a masterbatch to the granules of unfilled polymers. The masterbatch should have a filler content of more than about 30% by weight.Type: GrantFiled: September 9, 1986Date of Patent: July 19, 1988Assignee: Hoechst AktiengesellschaftInventors: Guenther Crass, Gunter Schloegl, Lothar Bothe, Herbert Peiffer
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Patent number: 4717742Abstract: Silanes grafted onto celluloses and lignocelluloses' fibers, in presence of free radical initiator, reinforced thermoplastic composites, which replace the inorganic fillers. Polyethylene composites are prepared by a hot melt mixing process, wherein the cellulosic molecules graft with silanes, and part of the thermoplastic polymer, can be initiated to attach with the maleic anhydride present. The grafted cellulose molecules with aminosilanes combine easily and strongly with that maleiated polymer to give the superior composite properties. The silanes grafted onto organic fillers proved to be higher in energy, secant modulus, tensile strength and strain compared to inorganic fillers such as glass fibers or mica composites. Noting that the cost of silanes grafted onto cellulosic or lignocellulosic fibers are several times lower than that of treated glass fibers or mica.Type: GrantFiled: May 29, 1985Date of Patent: January 5, 1988Inventor: Alphons D. Beshay
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Patent number: 4704424Abstract: Various type A zeolites can be combined with thermoplastic materials to provide antiblock and improved optical properties to films or sheets of said thermoplastic. The zeolites are of less than full hydration, and at least a portion of the sodium is replaced with multivalent ions such as calcium and magnesium. The zeolites can also be acid treated to provide zeolites that contain hydronium ions.Type: GrantFiled: May 21, 1986Date of Patent: November 3, 1987Assignee: PQ CorporationInventor: Bruce W. Sands
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Patent number: 4690959Abstract: Compositions which are particularly useful as coupling agents and primers for polyolefin composites. The compositions comprise fumaric acid and diaminefunctional silanes in mole ratios from 1.0 to 1.4 in nonreactive solvent, particularly water. These compositions are particularly effective in polyethylene composite materials.Type: GrantFiled: May 9, 1986Date of Patent: September 1, 1987Assignee: Dow Corning CorporationInventor: Edwin P. Plueddemann
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Patent number: 4661537Abstract: A mineral-filled thermoplastic composition is disclosed which comprises polyethylene or an ethylene-vinyl acetate copolymer; a mineral filler consisting, in the case of polyethylene, of aluminum trihydrate, magnesium hydrate, calcium carbonate or calcium/magnesium carbonates, and, in the case of the ethylene-vinyl acetate copolymer, barium titanite or neodymium titanate; and, in the case of polyethylene, an impact promoter consisting of tri(2-ethylhexyl) phosphate, isostearic acid or dodecylpyridinium salts, the selection of the impact promoter being dependent upon the mineral filler being employed, and, in the case of the ethylene-vinyl acetate copolymer, an amount of isostearic acid sufficient to increase the ductility of the composition; also disclosed is an additive composition for a thermoplastic composition which comprises a hydrophobic agent and an impact promoter.Type: GrantFiled: July 11, 1985Date of Patent: April 28, 1987Assignee: Union Carbide CorporationInventors: Fred H. Ancker, Arnold C. Ashcraft, Jr.
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Patent number: 4623755Abstract: The invention relates to an electrical insulation composition of a polyolefin, which can be used for medium and high voltage from about 10 kV and which resists effectively and permanently the formation of so-called water trees. The insulative polyolefin contains an inorganic oxide additive, in homogeneous distribution therewith, at a concentration of 0.05 to 10% by weight, relative to the total weight of the composition. The additive is absorption-active for heavy metal ions and/or binds heavy metal ions in an ion exchange, with a particle size of up to 50 um or an agglomerate size of up to 100 um. It can be silica, alumina, hydrated alumina or an aluminum silicate. The electrical insulation according to the invention is particularly well-suited for use in cables and wires.Type: GrantFiled: September 13, 1985Date of Patent: November 18, 1986Assignee: Siemens AktiengesellschaftInventors: Hans-Joachim Henkel, Norbert Muller
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Patent number: 4617201Abstract: A method for producing a finely distributed powder, which contains a thermoplastic synthetic material, where, in order to form particles containing the synthetic material, thermoplastic synthetic material is introduced in a non-aqueous carrier substance, which is liquid in the melting temperature range of the synthetic material, and is mixed in the melting temperature range with the carrier substance, and ground lime is then added to this mass, and thereafter an aqueous slurry is added to the mass. By the reaction between the lime and the aqueous slurry, the mass is converted to a powder containing synthetic material, More particularly,bitumen is selected as a carrier substance. The powder can preferably be introduced to produce a synthetic material-containing bituminous binder for building materials.Type: GrantFiled: August 9, 1985Date of Patent: October 14, 1986Assignee: Novophalt Societe AnonymeInventor: Erich Strommer
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Patent number: 4559381Abstract: Polymeric compositions particularly suitable for agricultural purposes are disclosed. These compositions contain at least 80% of either a polyolefin such as polyethylene or a copolymer of ethylene. A 0.5-15% additive containing the bond boron-oxygen such as anhydrous borax imparts a desirable opacity to these polymers in the high wavelength infra-red region of the spectrum, while not substantially interfering with the visible light necessary for photosynthesis.Type: GrantFiled: January 13, 1984Date of Patent: December 17, 1985Assignee: Alcudia, Empresa Para la Indusrria Quimica, S.A.Inventors: Graciano J. Tapia, Oscar G. Martinez
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Patent number: 4555439Abstract: According to the present invention, rolled sheet-like materials having superior mechanical properties, in particular toughness and high-impact properties, as well as superior heat resistance and showing no whitening can be provided.Such rolled sheet-like materials are manufactured by isotropically rolling sheet-like materials, which were obtained by melting, blending and forming the mixture consisting of thermoplastic resin having the degree of crystallinity of 10% or more of 20 to 90% by weight and flaky fillers of 10 to 80% by weight, to orientate a part of crystals after it was melted at the melting point of said sheet-like materials and then recrystallizing the melted crystals under the rolled condition.Type: GrantFiled: January 13, 1984Date of Patent: November 26, 1985Assignee: Kuraray Company, Ltd.Inventors: Ryuhei Ueeda, Kiyonobu Fujii, Hiroshi Narukawa
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Patent number: 4551499Abstract: A nucleating agent comprising either a substantially non-polar wax or an inert inorganic finely divided powder is incorporated in a thermoplastics polymer, e.g. polyethylene. Thus reduces the spherulite size of the material and thus increases its breakdown field strength.Type: GrantFiled: August 8, 1984Date of Patent: November 5, 1985Assignee: International Standard Electric CorporationInventors: Brian A. Cranfield, John C. Fothergill, Susan V. Wolfe
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Patent number: 4501841Abstract: Non-asbestos elastomeric insulating materials for rocket motors are disclosed. The insulating materials are low in density (between about 0.035 and 0.050 lb./cubic inch) and comprise 100 parts by weight of a crosslinked elastomer polymer in which are dispersed between about 10 and 100 (preferably 15-75) parts by weight of a char forming organic fiber selected from polyaramide pulps and between about 5 and 75 parts by weight inorganic particulate. The insulating materials issue little smoke, have notable erosion resistance and can be tailored to have thermal, mechanical and other properties of desired character. Ingredients such as phenolics, flame retardants, and liquid polybutadiene can enhance the utility of the insulating materials in certain embodiments.Type: GrantFiled: February 3, 1983Date of Patent: February 26, 1985Assignee: Hercules IncorporatedInventor: Liles G. Herring
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Patent number: 4497931Abstract: Antioxidants are enhanced in their activity by the presence of soluble lithium ion.Type: GrantFiled: July 1, 1983Date of Patent: February 5, 1985Assignee: Union Camp CorporationInventor: Samuel D. Hollis
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Patent number: 4465801Abstract: The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and neutralized sulfonated polymer transferring from the organic liquid to the water phase, thereby causing the water phase to thicken.Type: GrantFiled: May 3, 1982Date of Patent: August 14, 1984Assignee: Exxon Research & Engineering Co.Inventors: Dennis G. Peiffer, Robert D. Lundberg, Thad O. Walker
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Patent number: 4460737Abstract: A profound improvement in the properties and capabilities of elastomeric polyurethane joint sealing compositions is achieved by incorporating a fibrillated polyolefin of high surface area which is rendered compatible by combining it with effective stabilizing cofillers, such as titanium dioxide, calcium carbonate, carbon black, fibrous talc, serpentine, kaolin, or various other metal silicate fillers. Such cofillers are capable of improving compatibility and stabilizing the sealant mixture so that unacceptable sweat out or exudation of liquid is prevented and so that the outer surface of the applied sealant has an acceptable surface quality after curing.Type: GrantFiled: March 23, 1981Date of Patent: July 17, 1984Assignee: RPM, Inc.Inventors: Robert M. Evans, Thomas M. Leonard
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Patent number: 4452841Abstract: A shaped sound barrier component comprising a thermoplastic member highly loaded with barium sulfate (more than 200 to about 400 parts) and zinc oxide (1 to 500 parts). Preferably the thermoplastic contains 20 to 50 parts of chopped fibers per 100 parts of said thermoplastic although larger amounts can be used, for instance a 100 parts where the usage is severe.Type: GrantFiled: December 20, 1982Date of Patent: June 5, 1984Assignee: The Goodyear Tire & Rubber CompanyInventor: Paul E. Oliveira
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Patent number: 4426469Abstract: Glass fibers for the production of reinforced polymers, characterized in that said fibers have a coating comprising, besides a film forming agent of polyolefinic kind and a silane, also a bis-maleamic acid such as N,N'-hexamethylene-bis-maleamic acid, N,N'-dodecamethylene-bis-maleamic acid or N,N'-isophoron-bis-maleamic acid.The invention also concerns blends consisting of 50-90% by weight of a crystalline polyolefin, e.g. polypropylene and 50-10% by weight of said coated glass fibers.Type: GrantFiled: May 24, 1982Date of Patent: January 17, 1984Assignee: Montedison S.p.A.Inventors: Roberto Marzola, Enea Garagnani, Alessandro Moro
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Patent number: 4414396Abstract: Polyhalophthalimidoalkyl-functional carbonates may be employed as fire retardant additives to polymers. Examples of such carbonates are 2-(tetrabromophthalimido)ethyl 2,4,6-tribromophenyl carbonate, 2-(tetrabromophthalimido)ethyl pentabromophenyl carbonate and bis[2-(tetrabromophthalimido)ethyl] carbonate.Polyhalophthalimidoalkyl haloformates, N-(hydroxyalkyl)-polyhalophthalimides, and 2-(hydroxyalkylcarbamyl)-polyhalobenzoic acids are useful as intermediates in the preparation of the carbonates.Type: GrantFiled: January 7, 1982Date of Patent: November 8, 1983Assignee: PPG Industries, Inc.Inventor: Nicodemus E. Boyer
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Patent number: 4396730Abstract: A fire-retarding resin composition composed of(a) a thermoplastic resin,(b) about 20 to about 60% by weight, based on the total weight of (a), (b) and (c), of a magnesium hydroxide powder whose surface is treated with an alkali metal oleate, and(c) about 0.1 to about 10% by weight, based on the total weight of (a), (b) and (c), of at least one fatty acid metal salt selected from the group consisting of magnesium oleate and aluminum oleate; and a fire retardant composition for thermoplastic resins, said composition comprising(b) a magnesium hydroxide powder whose surface is treated with an alkali metal oleate, and(c) at least one fatty acid metal salt selected from the group consisting of magnesium oleate and aluminum oleate, the weight ratio of (b) to (c) being from 2 to 600:1.Type: GrantFiled: November 19, 1981Date of Patent: August 2, 1983Assignee: Kyowa Chemical Industry Co., Ltd.Inventor: Takeshi Imahashi
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Patent number: 4394475Abstract: Sized glass fiber strands are provided that have improved slip/flow characteristics. This improved characteristic is achieved by sizing glass fibers with an aqueous sizing composition having one or more nonstarch film forming polymers, one or more coupling agents, one or more lubricants or a mixture thereof, polyethylene-containing polymer with limited branching and water. The aqueous sizing composition can also have a wax having a melting point greater than 50.degree. C. where the total amount of the polyethylene polymer and wax is not greater than about 15 weight percent of the aqueous sizing composition.Type: GrantFiled: December 24, 1981Date of Patent: July 19, 1983Assignee: PPG Industries, Inc.Inventors: Chester S. Temple, Ed C. Hsu
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Patent number: 4390653Abstract: An improved flame-retardant thermoplastic compound based upon a surface modified alumina hydrate composition containing powdered alumina hydrate, a liquid mixture of C.sub.10 -C.sub.20 carboxylic acids and a solid mixture of C.sub.14 -C.sub.20 carboxylic acids. A preferred solid mixture comprises stearic acid and palmitic acid. Thermoplastic compounds made with polypropylene and an alumina hydrate composition containing isostearic acid together with the solid fatty acid mixture of the invention exhibit an increased melt index and reduced molding pressure compared with polypropylene compounds made with isostearic acid coated alumina hydrate and no solid fatty acid mixture.Type: GrantFiled: January 22, 1982Date of Patent: June 28, 1983Assignee: Aluminum Company of AmericaInventors: Thomas L. Levendusky, William L. Burton
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Patent number: 4379882Abstract: A polyolefin composition consisting essentially of(a) 100 parts by weight of a polyolefin containing halogens derived from a polymerization catalyst and/or attributed to the after-halogenation of the polymer, and(b) about 0.001 to about 10 parts by weight of an aluminum-magnesium hydroxide represented by the following formulaMg.sub.1-x Al.sub.x (OH).sub.2+x.mH.sub.2 O (1)wherein x is a positive number represented by 0<x.ltoreq.0.5 and m is a positive number represented by 0.ltoreq.m<2, andhaving a BET specific surface area of no more than about 40 m.sup.2 /g; and a method for inactivating the halogen in a halogen-containing polyolefin.Type: GrantFiled: November 10, 1981Date of Patent: April 12, 1983Assignee: Kyowa Chemical Industry Co., Ltd.Inventor: Shigeo Miyata
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Patent number: 4375520Abstract: A procedure is provided for the production of clean, dustless particulate granules from dusty, dirty particles by treatment with a composition comprising a liquid polymeric substance, illustratively, epoxidized soybean oil, and a solid, low molecular weight polymer having a melting point in the range of about 95.degree. to 105.degree. C., illustratively, a polyethylene vinyl acetate copolymer in the proportions of from 1 part of solid polymer to 1 part of liquid polymeric substance to 2 parts of solid polymer to 1 part of liquid polymeric substance. In one modification of the procedure, the ingredients were charged to a Papenmeir mixer and the mixer was run at 1500 RPM until a temperature of 95.degree. C. was reached. The resulting product comprised clean, dustless uniform beads.Type: GrantFiled: April 10, 1981Date of Patent: March 1, 1983Assignee: Dart Industries Inc.Inventors: Thomas W. Pennie, Sunil S. Parikh, Charles Lowe
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Patent number: 4341827Abstract: The invention is directed to biaxially oriented thermoplastic polymer flexible film having a substantially uniform thickness between about 0.005 and 0.030 of an inch (0.13 mm and 0.76 mm) and characterized by a structure comprised of discrete, platelet-like spherulitic crystalline aggregates compressed transversely to the plane of the film and biaxially oriented in the plane of the film and having a combination of improved properties and also to a rigid conduit or extrudate having a plurality of thermoplastic crystalline polymer layers each of which has a unique microstructure and improved properties.Type: GrantFiled: July 30, 1981Date of Patent: July 27, 1982Assignee: Bethlehem Steel CorporationInventors: Alfred A. Austen, Darral V. Humphries
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Patent number: 4341880Abstract: A resin composition of improved hue which comprises, in specified proportions, an olefin-based resin such as polypropylene and at least three specified antioxidants which are (1) 2,6-di-t-butyl paracresol, (2) tri(mono- and/or di-nonylphenyl)phosphite and/or distearyl pentaerythritol diphosphite, and (3) tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate and/or octadecyl-3-(3,5-di-t-butyl-4-hydroxyphenyl)-propionate.Type: GrantFiled: February 20, 1981Date of Patent: July 27, 1982Assignee: Oji Yuka Goseishi Kabushiki KaishaInventors: Takashi Toyoda, Yozo Ohba, Masaaki Yamanaka