Abstract: Non-aqueous emulsions comprise a continuous organic phase comprising an organic vehicle. The non-aqueous emulsions further comprise a discontinuous phase comprising a polyfluoropolyether silane. Methods of preparing surface treated articles therewith are also disclosed.

Abstract: The compound below. R1 is an alkyl group or —(SiR72—O)m—R8. R7 is an alkoxy group. The value m is a nonnegative integer. R8 is an alkyl group or R3 and R4 are organic groups. R5 is an aliphatic group or a residue of a homopolymer of an aliphatic polyisocyanate. R6 has an electron withdrawing group that is bound to a carbon atom that is bound to the CHR4 group. The value n is an integer greater than or equal to 2. A method of: reacting a 3-trialkoxysilylpropyl amine with an organic compound having a carbon-carbon double bond activated by an electron withdrawing group to form a secondary amino propylalkoxysilane, and reacting the secondary amino propylalkoxysilane with an aliphatic polyisocyanate or a polymer thereof.

Abstract: The present invention relates to an organopolysiloxane composition that can be vulcanized at room temperature into an elastomer that is crosslinked by polycondensation and that does not contain alkyltin-based catalysts and also to novel organopolysiloxane polycondensation catalysts.

Abstract: A composition including an actinic radiation or thermally curable polyorganosiloxane ionomer having one or more reactive groups, for example, vinyl, acrylate, epoxy groups.

Abstract: A coating for an ink jet printhead front face, wherein the coating comprises an oleophobic anti-wetting coating having high thermal stability and maintaining good contact and sliding angle performance. In particular, the coating comprises fluorinated silicone.

Abstract: Novel silicone polyether copolymers of inverse structure of the formula 1, characterized in that no unsaturated functional groups caused by side reactions or conversion products thereof are present in the copolymer, and a process for preparation thereof, in which a polyether modified terminally and/or laterally with alkoxysilyl groups is reacted with silanes and/or siloxanes which bear one or more hydrolysis-labile groups, in a hydrolysis and condensation reaction.

Abstract: Reversibly and irreversibly-linking amino-polysiloxanes, methods of making such amino-polysiloxanes, and systems and methods of using such amino-polysiloxanes for the containment and/or remediation of a release and/or spill of a crude oil, a petroleum product and/or a chemical is described. Gels and/or emulsions formed from the combination and/or contacting of such an amino-polysiloxane with these materials can be used to recover these oils or chemicals while allowing the amino-polysiloxane to be recovered and reused to clean up or contain additional materials. Such amino-polysiloxanes can be used as well for the selective uptake of one component of liquid mixtures when such mixtures contain more and less lipophilic components. Methods of making and using adhesive and sealants containing such amino-polysiloxanes are described.

Abstract: A thermally conductive silicone rubber sponge composition which is composed of 100 parts by weight of heat-curable organopolysiloxane composition, 0.1 to 50 parts by weight of organic resin hollow filler having an average particle diameter of up to 200 ?m and a true specific gravity of up to 0.3, and 20 to 300 parts by weight of thermally conductive filler having an average particle diameter of 1 to 30 ?m and a thermal conductivity of at least 15 W/m·K, with the highly thermally conductive silicone rubber sponge having voids accounting for 10 to 70% of the entire volume thereof. The silicone rubber sponge composition of the present invention gives a silicone rubber sponge having high thermal conductivity, small heat capacity, low hardness, light weight, and low permanent compression set.

Abstract: The general field of the invention is that of airbags. The invention relates to a process for improving the tear strength and the combing strength of coated fabrics intended for uses in the field of inflatable bags, using a silicone composition comprising an additive consisting of a polyorganosiloxane resin (V) and a calcium carbonate. After coating the composition onto the fabric supports and curing, the coated supports not only have optimum adhesion and crease resistance properties, but also have good properties in terms of combing strength and tear strength.

Abstract: Disclosed is a low dielectric constant insulating film formed of a polymer containing Si atoms, O atoms, C atoms, and H atoms, which includes straight chain molecules in which a plurality of basic molecules with an SiO structure are linked in a straight chain, binder molecules with an SiO structure linking a plurality of the straight chain molecules. The area ratio of a signal indicating a linear type SiO structure is 49% or more, and the signal amount of the signal indicating Si(CH3) is 66% or more.

Abstract: A curable resin composition to which at least phosphor particles and nanoparticles having a primary particle size of 1 nm or more and less than 100 nm are added, wherein the nanoparticles are dispersed in the form of secondarily aggregated particles having an average particle size of 100 nm or more and 20 ?m or less in terms of volume Q3 is provided for an optical semiconductor apparatus in which when a sealant obtained by dispersing phosphor particles in a curable resin composition having a low viscosity is filled into a package substrate, the dispersion state of the phosphor particles is not changed at the early and late stages of the fabrication, specifically the amounts of the phosphor particles to be contained at the early and late stages are the same, and the color rendering property can be stably maintained, a hardened material thereof, and an optical semiconductor apparatus.

Abstract: A film-forming composition according to one embodiment includes a siloxane polymer (A) containing a condensation product (A1) and a condensation product (A2). In the (A), a contained amount of the (A1) is 75 percent or less by mass in terms of SiO2 with respect to the total of the (A1) and the (A2). The (A) has a weight-average molecular weight (MW) of 80 percent or greater of a molecular weight value M determined by expression (1) if RA1>RA2, expression (2) if RA1<RA2, or expression (3) if RA1?RA2: M=(RA1/RA2)*(MA1+MA2)+[(RA2?RA1)/RA2)]MA2??expression (1): M=(RA1/RA2)*(MA1+MA2)+[(RA2?RA1)/RA2)]MA2??expression (2): M=MA1+MA2??expression (3): (MA1 and RA1 are MW and the SiO2-converted-mass ratio in the (A), respectively, for the (A1). MA2 and RA2 are MW and the SiO2-converted-mass ratio in the (A), respectively, for the (A2)).

Abstract: A chemical two-component mortar compound including a resin component (A) that contains at least one radically curable, ethylenically unsaturated compound (a) as the curable component, and including a separately arranged so as to inhibit reaction curing component (B) that contains a curing agent for the resin of the resin component (A), with improved adhesion to the surface of partially cleaned and/or moist holes in mineral substrates, characterized by a content of 0.

Abstract: A method for producing a curable composition for imprints includes the step of passing a curable composition containing a polymerizable monomer (A) and a polymerization initiator (B) through a filter having an effective filter area of 200 cm2 or more at least one time. The method suppresses pattern-peeling when peeling the mold employed in forming a pattern using the curable composition for imprints, and thus provides excellent patternability.

Abstract: There is described a process for preparing an silane-functional oligomer (such as an alkoxysilane polyurethane) suitable for use as a crosslinkable coating component, the process comprising the steps of: 1) reacting an aminoalkyl silane with a cyclic carbonate, lactone or lactam to form a hydroxyl (OH) or imino (NH) functional silane intermediate, 2) reacting the silane intermediate from step 1) (optionally immediately without isolation) with a diisocyanate (diNCO) to form a silane functional polyurethane; where in step 2) the molar ratio of the total amount OH or NH groups on the silane intermediate of step 1) to the diisocyanate is from 1.8 to 2.2 (preferably about 2.0) and the resultant silane polymer is substantially-free of isocyanate groups thereon.

Abstract: A resin for making abrasion and scratch resistant UV blocking glass coating. The resin can include an inorganic polysiloxane polymer matrix formed from water-based colloidal silica and tetraethylorthosilicate (TEOS). The resin also can include a bi-functional silanol coupling agent coupled to the inorganic polysiloxane polymer matrix. The resin further can include a UV absorber conjugated to the bi-functional silanol coupling agent. The resin also can include a solvent that is compatible with the colloidal silica, TEOS, bi-functional silanol agent, and UV absorber.

Abstract: A multi-component type curable silicone rubber composition includes: (A) 100 parts by weight of an organopoly-siloxane capped at molecular terminals with an alkoxy group or silanol group, (B) 0.5 to 20.0 parts by weight of an organic compound having at least two alkoxysilyl groups within single molecule and including a non-silicon-oxygen bond between the silyl groups, (C) 0.05 to 2.0 parts by weight of water, and (D) a catalytic amount of a curing catalyst. The multi-component type curable silicone rubber composition is composed of multiple separately stored compositions.

Abstract: A silicon polymer material, which has a silicon polymer backbone with chromophore groups attached directly to at least a part of the silicon atoms, the polymer further exhibiting carbosilane bonds. The film forming composition and resulting coating properties can be tailored to suit the specific exposure wavelength and device fabrication and design requirements. By using two different chromophores the refractive index and the absorption co-efficient can be efficiently tuned. By varying the proportion of carbosilane bonds, and a desired Si-content of the anti-reflective coating composition can be obtained.

Abstract: The invention relates to an inorganic-organic hybrid material which comprises an inorganic component and an organic component, has a content of the inorganic component of 20-80% by mass, and has a refractive index of 1.60 or higher, wherein, when preparing a strip specimen having a thickness of 1,000 ?m, a width of 5 mm and a length of 70 mm by using the inorganic-organic hybrid material and winding the specimen by 180° on a cylindrical metal rod having a diameter of 10 mm at 25° C., the specimen does not crack.

Abstract: A resist underlayer film forming composition for EUV lithography, comprising: as a silane, a hydrolyzable silane, a hydrolyzate of the hydrolyzable silane, a hydrolysis condensate of the hydrolyzable silane, or a mixture of any of the hydrolyzable silane, the hydrolyzate, and the hydrolysis condensate, wherein the hydrolyzable silane includes a combination of tetramethoxysilane, an alkyltrimethoxysilane, and an aryltrialkoxysilane, and the aryltrialkoxysilane is represented by formula (1): (R2)n2—R1—(CH2)n1—Si(X)3??Formula (1) In formula (1), R1 is an aromatic ring consisting of a benzene ring or a naphthalene ring or a ring including an isocyanuric acid structure, R2 is a substituent replacing a hydrogen atom on the aromatic ring and is a halogen atom or a C1-10 alkoxy group, and X is a C1-10 alkoxy group, a C2-10 acyloxy group, or a halogen group.

Abstract: A curable composition includes: 100 parts by mass of a silicon-containing polymer having a Mw of 3,000 to 100,000 obtainable by hydrolysis-condensation of an organosilane mixture including R1SiX3, R2SiX3, R3R4SiX2 and R5SiX3, the total of R2SiX3 and R3R4SiX2 being 5 to 60 mol %, optionally a prepolymer, optionally a cyclic siloxane compound, 0.0001 to 10 parts by mass of an organic peroxide and optionally a metal catalyst, and 10 to 1,500 parts by mass of a filler, wherein R1 is a C2-6 alkenyl group, R2 is a C1-6 alkyl group, R3 and R4 are each a C1-6 alkyl group, R5 is a phenyl group optionally substituted with a C1-6 alkyl group, and X is a C1-6 alkoxy group, one or more of R2 to R4 is a methyl group, f represents a number of 2 to 10, g represents a number of 0 to 8, and n represents 1 or 2.

Abstract: An objective of the present invention is to provide a lignocellulose material exhibiting superior dimensional stability and having a reduced water-absorbing property, as well as provide a lignocellulose hybrid material, a paper product or a wood product, with superior dimensional stability and a reduced water-absorbing property. In the present invention, a lignocellulose material is treated with a treatment agent for use in a lignocellulose material containing: (A) a polyvalent carboxylic acid or a derivative thereof; and (B) a silicon compound containing a functional group binding to a silicon atom, and thereby, a lignocellulose hybrid material is obtained. In addition, a paper product or a wood product is obtained by using the aforementioned lignocellulose hybrid material.

Abstract: This invention relates to thermoplastic elastomers comprising at least one silicone ionomer. These thermoplastic elastomers may be reprocessed and/or recycled.

Abstract: The present invention relates to a coating composition comprising (d) at least one binder (A) having reactive groups, (e) at least one crosslinking agent (B) which is able to react, with crosslinking with the reactive groups of the binder (A), and at least one catalyst (C) for the crosslinking of silane groups, one or more constituents (A) and/or (B) and/or at least one further constituent of the coating composition containing hydrolyzable silane groups, wherein the catalyst (C) is a phosphoric acid compound, more particularly phosphoric acid or phosphonic acid, which is blocked with an amine having a pKb?3 and a boiling point >100° C.

Abstract: A UV-shielding coating composition comprises (A) a dispersion in a dispersing medium of composite zinc oxide nanoparticles which are obtained by coating surfaces of zinc oxide nanoparticles with an oxide or hydroxide of Al, Si, Zr and Sn, the dispersion having a photocatalytic degradability of up to 25%, (B) a vinyl copolymer obtained from copolymerization of an alkoxysilyl-containing vinyl monomer, a UV-absorbing vinyl monomer, and another monomer, and (C) a solvent. The composition is transparent to visible light, UV-shielding, mar resistant, weatherable, and durable.

Abstract: A polysilazane composition, formulated from a vinyl silazane and an organometallic accelerator, and associated methods thereof.

Abstract: The invention provides a water repellent composition for treating porous substrates comprising an emulsion which includes water, at least one surfactant, and a siloxane copolymer having the formula (I) wherein R is an alkyl radical having 1 to 3 carbon atoms; a has a value of from 1 to 12; R? is an alkyl radical having 8 to 12 carbon atoms, b?2; (a+b) is at least 5. This composition shows a good depth of penetration of porous substrates especially reinforced concrete and has a low Volatile Organic Content to ASTM D 5095.

Abstract: A curable organopolysiloxane composition in grease or paste form, which including: (A) an organopolysiloxane having at least two alkenyl groups bonded to silicon atom in one molecule; (B) an organohydrogenpolysiloxane having at least two hydrogen atoms bonded to silicone atom in the molecule; (C) gallium and/or a gallium alloy having a melting point of 0 to 70° C.; (D) a thermally conductive filler having an average particle size of 0.1 to 100 ?m; (E) a platinum-based catalyst; and (F) a polysiloxane of the following general formula (1): wherein R1 may be the same or different and represents a monovalent hydrocarbon group, R2 represents an alkyl group, an alkoxyl group, an alkenyl group or an acyl group, a is an integer of 5 to 100, and b is an integer of 1 to 3.

Abstract: A stabilized composition containing a metal hydride of boron, including complex metal hydrides of boron, in a polyalkylsiloxane amorphous fumed silica mixture is provided. In a preferred embodiment the composition is a stabilized mixture of aluminum borohydride, polydimethylsiloxane and amorphous fumed silica. A method to prepare the stabilized mixture is also provided.

Abstract: A charging member includes a substrate and an outermost layer that is on the substrate, is in contact with a member to be charged, and contains a cross-linking fluorocarbon siloxane rubber composition, wherein the charging member charges the member to be charged by being brought into contact with the member to be charged while a voltage is applied.

Abstract: A carbon nanotube composite material having carbon nanotubes and carbon fibers dispersed in a matrix is provided wherein a carbon nanotube group formed from a plurality of the carbon nanotubes is present between the carbon fibers, an average diameter of the carbon fibers is 1 ?m or more and 50 ?m or less, an average diameter of the carbon nanotubes is 0.7 nm or more and 50 nm or less, the carbon nanotubes are included in a range of 0.01 wt % or more and 30 wt % or less and the carbon fibers are included in a range of 10 wt % or more and 60 wt % or less with respect to 100 wt % of the carbon nanotube composite material, thermal conductivity of the matrix is less than 10 W/mK, and the carbon nanotube composite material includes thermal conductivity in a direction of 10 W/mK or more.

Abstract: This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer.

Abstract: The disclosure relates to curable polysilyl phosphate compounds and compositions as well as related methods and flame-retardant textiles incorporating the same. Curable polysilyl phosphate compounds according to the disclosure include a hydrocarbon moiety comprising at least one phosphate group and more than two hydrolysable silyl groups linked to the hydrocarbon moiety. In some embodiments, the hydrocarbon moiety is derived from spirocyclic pentaerythritol diphosphoryl chloride. The curable polysilyl phosphate compound can applied to a textile substrate and then cured to provide a flame-retardant textile with the cured polysilyl phosphate compound as a coating bonded to the textile substrate.

Abstract: A molded article produced by molding a coating solution that contains a polycarbonate resin represented by the following formula (1) has excellent transparency, good water repellency and oil repellency, a lower friction coefficient and excellent surface lubricity, having a capability of improving abrasion resistance. In the formula (1), Rf represents a perfluoroalkyl group having 5 or more carbon atoms and 11 or more fluorine atoms or a perfluoroalkyl group having a specific structure; and W represents a divalent group including therein a specific structural unit.

Abstract: A process for preparing a cyclic siloxane copolymer, a water repellent composition and the use for treating porous substrates like concrete, especially reinforced concrete.

Abstract: Methods and compositions are provided for reducing or eliminating charge buildup during scanning electron microscopy (SEM) metrology of a critical dimension (CD) in a structure produced by lithography. An under layer is utilized that comprises silicon in the construction of the structure. When the lithography structure comprising the silicon-comprising under layer is scanned for CDs using SEM, the under layer reduces or eliminates charge buildup during SEM metrological observations.

Abstract: A reactive, non-hydrolyzable silane. The silane comprises a quaternary silicon atom and first and second terminal groups. Each of the first and second terminal groups is chemically bonded to the quaternary silicon atom and is selected from a group consisting of cyanate ester, epoxide, episulfide, acrylate, alkene, styrenic, maleimide, phthalonitrile, acetylene, aryl ethynylene, benzoxazine, anthracene, aniline, trifluorovinyl ether, and perfluorocyclobutyl.

Abstract: [Object] To provide an anti-soiling agent compound that can sufficiently prevents adhesion of pitch to a dry part region. [Solution] The present invention provides an anti-soiling agent composition for preventing pitch contamination in a dry part of a paper-making process, and the composition has a polysiloxane compound represented by the following formula (1), wherein the number of amino-modified groups per molecule of the polysiloxane compound is in a range from 0.5 to 5. [wherein, a substituent R1 represents a methyl group or an amino-modified group represented by the following formula (2), and the number n of repeating siloxane units represents an integer in a range from 50 to 1000, and wherein, each of a substituent R2 and a substituent R3 independently represents an alkylene group having carbon atoms of 1 to 6, and the number m of repeating amino-alkylene units represents an integer in a range from 0 to 2].

Abstract: A temporary adhesive for which temporary adhesion and subsequent detachment are simple. The temporary adhesive composition includes: (A) an organopolysiloxane having a weight-average molecular weight of at least 15,000, obtained by a hydrosilylation reaction between (A1) and (A2) described below, and (B) an organic solvent having a boiling point of not more than 220° C., wherein (A1) is an alkenyl group-containing organopolysiloxane having a weight-average molecular weight exceeding 2,000, comprising 35 to 99 mol % of T siloxane units and 1 to 25 mol % of M siloxane units, and in which alkenyl groups bonded to silicon atoms represent at least 2 mol % of all the organic groups bonded to silicon atoms, and (A2) is a specific organohydrogenpolysiloxane having at least two silicon atom-bonded hydrogen atoms or a specific hydrosilyl group-containing compound.

Abstract: Filamentous bodies which are longitudinally extended and other film-like constructions are made by combining liquid siliceous precursors with air and extruding them. Distinct types or grades of fibers, strands, and other film-like constructions are produced which have a multiplicity of useful applications and indications for use owing to their inherent memory, compactability, tensile strength and density. A prosthetic device for a mastectomy bra is constructed with filamentous bodies. It can be sewn permanently into the bra cup. The device can be refilled to counteract volume loss.

Abstract: The invention relates to a cyanate resin that can be obtained by mixing at least (i) one difunctional, oligofunctional and/or polyfunctional cyanate and/or of at least one prepolymer thereof, optionally in combination with at least one additional copolymerizable component and (ii) at least one siloxane and/or a siloxane-containing compound, characterized in that said resin contains a linear polydialkylsiloxane with a viscosity ranging from 500 to 1500 and/or a polydialkylsiloxane caprolactone or caprolactam copolymer as siloxane and/or siloxane-containing compound. The invention further relates to a substrate that is saturated or coated with said type of cyanate resin, and a duromer that can be obtained by compressing and/or heating the cyanate resin or the saturated or coated substrate.

Abstract: A method for creating a replication material corresponding to the appearance of a translucent or partially translucent target material. The appearance of the target material can be measured or may be prescribed by a user. The method includes receiving by a processor optical data related to a target subsurface scattering parameter of the target material. Once the processor has received the optical or light characteristic data, the method includes determining by the processor a replication pigment concentration to replicate the appearance of the target material caused by the target subsurface scattering parameter. The processor determines this concentration based on a plurality of pigment subsurface scattering parameters corresponding to a plurality of stored pigment concentrations in the computing device. Once the replication pigment concentration has been determined, the method includes creating, physically or virtually, the replication material by combining the pigment concentration with a base material.

Abstract: Aqueous emulsions curable to elastomeric solids are preparable without the use of an organic emulsifier, and may be prepared to the exclusion of organic solvents.

Abstract: The present invention relates on the use of 1,3-dihydroxyalkyl functionalized polyorganosiloxanes in compositions for the treatment of materials having a fibrous structure, such as leather, furs, textiles and paper. The invention further relates to a process for treating fibrous materials with waterproofing.

Abstract: A composition of matter comprising an interpenetrating polymer network of a combination of a silanol-containing polysiloxane phase and a silylated triglyceride oil phase. The two phases are mixed and covalently bound to each other via siloxane crosslinks. A method for producing interpenetrating polymer networks. The method comprises providing triglycerides from oils or fats and reacting the triglycerides with a reactive silane to form a silylated triglyceride oil. The silylated triglyceride oil and a silanol terminated polysiloxane are emulsified with water in a predetermined ratio. Thereafter, crosslinking agents are added and the water is removed from the emulsions providing siloxane crosslinks between the two intimately mixed immiscible phases.

Abstract: A silicone composition and more particularly to a silicone composition comprising at least one organosilicon compound having an average of at least two silicon-bonded hydrogen atoms per molecule, at least one silicone resin having the formula (R1R4R5SiO1/2)w(R12SiO2/2)x(R4SiO3/2)y(SiO4/2)z (II), wherein R1 is C1 to C10 hydrocarbyl or C1 to C10 halogen-substituted hydrocarbyl, both free of aliphatic unsaturation, R4 is C2 to C4 alkenyl, R5 is R1 or R4, w is from 0.01 to 0.6, x is from 0 to 0.5, y is from 0.1 to 0.95, z is from 0 to 0.4, and w+x+y+z)=1, and a hydrosilylation catalyst; a silicone adhesive comprising a cured product of the silicone composition, and a coated substrate and a laminated substrate, each comprising the silicone adhesive.

Abstract: A siloxane compound containing structures represented by the following general formulae (1) and (2): wherein R1 and R2 independently represent a hydrogen atom, a halogen atom, an alkyl group having from 1 to 3 carbon atoms, a halogenated alkyl group, a thiol group, an acetyl group, a hydroxyl group, a sulfonic acid group, a sulfoalkoxyl group having from 1 to 3 carbon atoms, or an alkoxyl group having from 1 to 3 carbon atoms; x and y independently represent an integer of from 0 to 4; and A represents a single bond or an azomethine group, an ester group, an amide group, an azoxy group, an azo group, an ethylene group, or an acetylene group, and wherein R3 and R4 independently represent an alkyl group, a phenyl group, or a substituted phenyl group; and n represents an integer of from 1 to 100.

Abstract: In a polycarbonate resin composition containing a polycarbonate resin and a polycarbosilane compound, the use of the polycarbosilane compound modifies the surface properties of the polycarbonate resin composition without adversely affecting the intrinsic characteristics of the polycarbonate resin, such as transparency, heat resistance, and mechanical properties, e.g., impact resistance. A polycarbonate resin composition containing 100 parts by mass of a polycarbonate resin, 0.001 to 1 part by mass of a metal salt compound, and 0.005 to 5 parts by mass of a polycarbosilane compound has significantly improved flame resistance and high transparency and causes markedly reduced outgassing and mold fouling, without losing impact resistance and heat resistance.

Abstract: A curable organopolysiloxane composition can be used as a sealant or a bonding agent for optical semiconductor elements. The composition comprises at least the following components: (A) a multi-constituent, alkenyl-containing organopolysiloxane; (B) an organopolysiloxane that contains silicon-bonded hydrogen atoms and comprises constituent (B-1) containing at least 0.5 wt. % of silicon-bonded hydrogen atoms and constituent (B-2) containing at least 0.5 wt. % of silicon-bonded hydrogen atoms, and, if necessary, constituent (B-3), an organopolysiloxane; and (C) a hydrosilylation-reaction catalyst. The composition can form a cured body that possesses long-lasting properties of light transmittance and bondability, and relatively high hardness.

Abstract: A silicon-containing antireflective coating formulation comprising: (i) an aqueous base insoluble organosilicon component having a multiplicity of hydrocarbon groups derivatized with hydroxy groups in the absence of Si—O—C and Si—O—H moieties; (ii) a vinylether component having a multiplicity of vinylether groups; and (iii) a casting solvent. Also disclosed is a method for converting the silicon-containing antireflective coating formulation into a crosslinked silicon-containing antireflective film comprising organosilicon units interconnected by acetal or ketal groups. The method entails (a) coating a substrate with the silicon-containing antireflective coating formulation and (b) heating the coated substrate to a temperature at which crosslinking between the organosilicon silicon component and vinylether component occurs.