Reactant Contains Atom Other Than C, H, Or O Patents (Class 524/603)
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Publication number: 20140357789Abstract: A sulfopolyester includes the reaction product of a diacid and a diol wherein the diacid includes at least 30 mole percent of one difunctional sulfomonomer containing at least one sulfonate group bonded to an aromatic ring wherein the functional groups are carboxyl or esters thereof and a diacid moiety which is not a sulfonated aromatic moiety. The sulfopolyester composition of the present invention has a charge density of greater than 1.0 meq/g polymer solids. Another aspect of the invention is a coating composition containing from 1 to 50 weight percent of the sulfopolyester.Type: ApplicationFiled: May 29, 2013Publication date: December 4, 2014Applicant: Eastman Chemical CompanyInventors: Scott Ellery George, Joshua Seth Cannon, Suzanne Winegar Dobbs, James Allen McCaulley
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Publication number: 20140333999Abstract: There is provided a polyester-based primer composition including 100 parts by weight of a polyester resin, 1 to 20 parts by weight of water-dispersible particles, and water as a remainder. Since a polyester-based primer composition of the present disclosure is excellent in water resistance and solvent resistance differently from a urethane primer composition, the polyester-based primer composition may obtain sufficient adhesive strength between a protection film and a functional coating layer even without assistance from additives such as a cross-linking agent, and may retain stable adhesive strength for a long period of time.Type: ApplicationFiled: December 20, 2013Publication date: November 13, 2014Inventors: Hwa-Sub Shim, Yi-Rang Lim, Jun-Wuk Park, Kyoung-Won Kim, Sung-Hyun Jeon
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Publication number: 20140251178Abstract: This invention provides a viscosity modifier for high concentration dispersion of inorganic fine particles which can reduce, by giving excellent viscosity modifying function to a high concentration dispersion of inorganic fine particles (e.g., printing ink composition, functional paste composition or paint composition, of high concentration dispersion of inorganic fine particles), the occurrence of inconvenience in a printing step or coating step for the manufacture of components or substrates, and also provides a high concentration dispersion of inorganic fine particles which contains said viscosity modifier.Type: ApplicationFiled: February 24, 2014Publication date: September 11, 2014Applicant: KUSUMOTO CHEMICALS, LTD.Inventors: Daisuke SHIMIZU, Junpei SUETOU, Chihiro HAMAZAKI, Kenichi ASANO, Hideki SATAKE, Eiichi SATO
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Patent number: 8809451Abstract: According to the present invention, a polymer is obtained by polycondensation of a fluorinated dicarboxylic acid derivative of the general formula (M-1) or an acid anhydride of the fluorinated dicarboxylic acid with a polyfunctional compound having two to four reactive groups corresponding in reactivity to carbonyl moieties of the fluorinated dicarboxylic acid derivative or acid anhydride. [Chem. 134] AOCF2C-Q-CF2COA???(M-1) In the above formula, Q represents a divalent organic group having a substituted or unsubstituted aromatic ring; and A and A? each independently represent an organic group. This polymer exhibits a sufficiently low dielectric constant for use as a semiconductor protection film and has the capability of forming a film at a relatively low temperature of 250° C. or lower.Type: GrantFiled: February 18, 2010Date of Patent: August 19, 2014Assignee: Central Glass Company, LimitedInventors: Yoshimi Isono, Satoru Narizuka, Hidehisa Nanai, Kazuhiro Yamanaka
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Publication number: 20140227516Abstract: A carbon fiber sizing agent imparts good bonding performance to carbon fiber, is used to reinforce a thermoplastic matrix resin, and provides a carbon fiber strand applied with the sizing agent and a fiber-reinforced composite reinforced with the carbon fiber strand. The sizing agent for carbon fiber is used to reinforce thermoplastic matrix resin. The sizing agent essentially contains a polymer component having a glass transition temperature of at least 20 deg.C. and exhibits no endothermic peaks indicating an endothermic heat of fusion due to crystalline melting of at least 3 J/g in a determination with a DSC. The weight ratio of the polymer component is 10 to 100 wt % of the nonvolatile components of the sizing agent. The polymer component is at least one component selected from the group consisting of an aromatic polyester resin, aromatic polyester-polyurethane resin and amine-modified aromatic epoxy resin.Type: ApplicationFiled: October 15, 2012Publication date: August 14, 2014Inventors: Yoshio Hashimoto, Yusuke Shimizu, Mikio Nakagawa
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Publication number: 20140087149Abstract: An aromatic copoly(ester-sulfone) that contains one or more aromatic ester repeating units and one or more aromatic sulfonyl repeating units is provided. While a wide variety of aromatic ester repeating units may be employed, the polymer is nevertheless “low naphthenic” to the extent that it contains a minimal content of repeating units derived from naphthenic hydroxycarboxylic acids and naphthenic dicarboxylic acids. Despite the absence of a high level of conventional naphthenic acid repeating units, the present inventors have discovered that selective control over the type and relative concentration of the aromatic sulfonyl repeating units can lead to “low naphthenic” polymers that are not only soluble in certain solvents, but also capable of exhibiting good mechanical properties. Thus, the ability of the resulting polymer to be dissolved or dispersed in various solvents can be enhanced without sacrificing performance.Type: ApplicationFiled: September 16, 2013Publication date: March 27, 2014Applicant: Ticona LLCInventors: Kamlesh P. Nair, Young Shin Kim, James P. Shepherd, Prabuddha Bansal
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Publication number: 20140087086Abstract: A powder that contains microparticles formed from an aromatic polyester is provided. The mean size of the microparticles is generally from about 0.1 to about 40 micrometers. The microparticles may also have a shape that is generally spherical in nature. Regardless of the actual size and shape, however, the size distribution of the microparticles may be consistent throughout the powder. For example, at least about 50% by volume of the microparticles may have a mean size within a range of from about 0.1 to about 200 micrometers. Without intending to be limited by theory, the present inventor believes that a certain size and/or size distribution can improve the quality of coatings formed from the powder.Type: ApplicationFiled: September 16, 2013Publication date: March 27, 2014Applicant: Ticona LLCInventors: Kamlesh P. Nair, James P. Shepherd
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Publication number: 20140018496Abstract: A sulfopolyester containing residues of 2,2,4,4-tetralkylcyclobutane-1,3-diol such as 2,2,4,4-tetramethylcyclobutane-1,3-diol is highly dispersible in water. This allows one to reduce the content of sulfonate groups or reduce the amount of ethylene glycol or other hydrophilic glycols to retain good water resistance in cured coatings. The sulfopolyester may also be a reaction product of a 2,2,4,4-tetralkylcyclobutane-1,3-diol along with 1,4-cyclohexanedimethanol, neopentyl glycol, or a mixture thereof with an acid component. Coating compositions may also contain these sulfopolyesters along with water and a polymer resin.Type: ApplicationFiled: September 13, 2013Publication date: January 16, 2014Applicant: EASTMAN CHEMICAL COMPANYInventors: Thauming Kuo, Phillip Bryan Hall
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Patent number: 8604101Abstract: The present invention relates to a process for producing aqueous dispersions of thermoplastic polymers which have a plurality of ester groups and/or carbonate groups in the main polymer chain and which have an acid number of less than 5 mg KOH/g, in particular at most 3 mg KOH/g, and which have a zero-shear viscosity ?0 (180° C.) of at least 60 Pa·s at 180° C. The invention also relates to the polymer dispersions obtainable by said process, and to the use thereof.Type: GrantFiled: March 24, 2011Date of Patent: December 10, 2013Assignee: BASF SEInventors: Liqun Ren, Gimmy Alex Fernandez Ramirez, Motonori Yamamoto, Hermann Seyffer, Gabriel Skupin
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Patent number: 8569394Abstract: An active light-curable ink composition contains a polymerizable compound, a color material having an absorption peak in a wavelength region, and a polymerization initiator having an absorption peak in a different wavelength region from the color material.Type: GrantFiled: March 3, 2009Date of Patent: October 29, 2013Assignee: Seiko Epson CorporationInventor: Satoru Miura
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Patent number: 8389117Abstract: Disclosed are hot-melt adhesives prepared from polyesters containing 1,4-cyclohexane-dicarboxylic acid as a diacid component and a diol component containing at least two diols chosen from 1,4-cyclohexanedimethanol, triethylene glycol, and diethylene glycol. These adhesives set up rapidly within a well-defined temperature window. The hot-melt adhesives can be used in a variety of applications, but are especially suited as seaming adhesives for roll-applied labels. These adhesives have melting temperatures and crystallization properties that allow their application at temperatures cool enough to prevent curling and premature shrinkage of the shrink label during seaming, and yet produce strong label seams that can withstand the elevated temperatures of a shrink tunnel without sacrificing line speed. Also disclosed are labeled containers and a process for applying a roll-on, shrink label to a container using the hot-melt adhesives of the invention.Type: GrantFiled: October 12, 2009Date of Patent: March 5, 2013Assignee: Eastman Chemical CompanyInventors: Marcus David Shelby, Scott Ellery George, Gary Robert Robe, Freddie Wayne Williams, Michael Eugene Donelson, Joshua Seth Cannon, Emmett Patrick O'Brien, Jeremy Richard Lizotte, Anthony Joseph Pasquale
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Publication number: 20130023604Abstract: A sulfopolyester containing residues of 2,2,4,4-tetralkylcyclobutane-1,3-diol such as 2,2,4,4-tetramethylcyclobutane-1,3-diol is highly water dispersible in water. This allows one to reduce the content of sulfonate groups or reduce the amount of ethylene glycol or other hydrophilic glycols to retain good water resistance in cured coatings.Type: ApplicationFiled: July 21, 2011Publication date: January 24, 2013Applicant: EASTMAN CHEMICAL COMPANYInventors: Thauming Kuo, Phillip Bryan Hall
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Publication number: 20120244336Abstract: A spun-dyed polyester monofilament is provided having a linear density of at least 40 dtex containing at least one pigment selected from the group of phthalocyanine, metallophthalocyanine, pyrazolone, anthraquinone, dioxazine, sulfur, azo, dibenzanthrone and/or perylene pigments, wherein the sum total of free hot-air shrinkage after 30 minutes' treatment at 180° C. and extension at a specified load of 27 cN/tex from the stress-strain diagram of the polyester monofilament is less than 15%.Type: ApplicationFiled: October 21, 2010Publication date: September 27, 2012Applicant: Nextrusion GMBHInventors: Kurt-Günther Berndt, Rex Delker, Reinhardt Schenzinger, Andreas Dirr
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Publication number: 20120086761Abstract: This disclosure is generally directed to curable phase change inks, such as radiation-curable phase change inks, and their use in forming images, such as through inkjet printing. More specifically, this disclosure is directed to radiation-curable phase change inks, such as ultraviolet-light-curable phase change inks, that an ink vehicle and at least one crystalline polyester resin.Type: ApplicationFiled: October 8, 2010Publication date: April 12, 2012Applicant: XEROX CORPORATIONInventors: Michelle N. CHRÍTIEN, Bryan J. ROOF, Barkev KEOSHKERIAN, Naveen CHOPRA, Peter G. ODELL
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Publication number: 20120046405Abstract: A method of making a composite barrier coating composition comprising: (a) providing a first aqueous dispersion comprising a dispersed, anionically functionalized matrix resin; (b) providing a second aqueous dispersion comprising a dispersed platy mineral filler; the first and second dispersions optionally including one or more additives selected from the group consisting surfactants, emulsifiers, anti-foaming agents, dispersing agents, wetting agents, leveling agents and thickeners; (c) adding a multi-valent metal cation crosslinking agent to at least one of said first and second aqueous dispersions; and (d) admixing the first and second aqueous dispersions to form the composite wherein the composite forms a stable aqueous emulsion and the multi-valent metal cation is operative to stabilize a film formed from the composite against gas barrier performance loss at elevated levels of relative humidity.Type: ApplicationFiled: April 30, 2010Publication date: February 23, 2012Applicant: Inmat Inc.Inventors: Carrie A. Feeney, Harris A. Goldberg, Michele Farrell
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Publication number: 20110269903Abstract: The present invention provides bis(hydroxyalkyl)mercaptosuccinates of the formula: and derivatives thereof, where X1, X2, Z1, Z2, Y1, Y2, Ra, Rb, R1, and R2 are those defined herein. The present invention also provides methods for producing and using the same.Type: ApplicationFiled: April 29, 2011Publication date: November 3, 2011Applicant: WYSIS TECHNOLOGY FOUNDATION, INC.Inventors: John P. Droske, Mark J. Juetten
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Patent number: 8029894Abstract: Thermosetting compositions comprising an adhesion-promoting agent are disclosed. The adhesion-promoting agent is derived from boric acid or an equivalent and an ester having two or more functional groups that are derived at least in part from a 1,3-polyol.Type: GrantFiled: August 18, 2006Date of Patent: October 4, 2011Assignee: PPG Industries Ohio, Inc.Inventors: Karen A. Morow, Jane N. Valenta, Shanti Swarup, Lawrence G. Anderson
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Publication number: 20110150808Abstract: The present invention relates to pigment colorants and more directly to a pigment composition comprising a pigment treated with a water-dispersible polyester or polyesteramide polymer in the presence of added water. The invention also relates to a method grinding a mixture containing a pigment with a water-dispersible polyester or polyesteramide in the presence of added water.Type: ApplicationFiled: December 20, 2010Publication date: June 23, 2011Inventor: RICHARD RIGG
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Patent number: 7781514Abstract: A method of making a thickened hardener composition useful in a two part resin system. The thickened hardener composition includes a carrier, a peroxide catalyst, and a thickening and volumetrically increasing agent, wherein the thickening and volumetrically increasing agent is microspheres. A method of making a thermoset resin from a two-part polyester resin system is also provided.Type: GrantFiled: May 3, 2006Date of Patent: August 24, 2010Assignee: Illinois Tool Works Inc.Inventor: Jeffrey Andrew Reynolds
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Patent number: 7713674Abstract: An emulsion polymerization process comprising polymerizing monomer in an emulsion in a reaction vessel at a first temperature to form a resin; cooling the reaction vessel to a second temperature that is above the softening point of the resin yet below the temperature required for significant depolymerization reaction to occur; and adding water to the cooled reaction vessel in an amount sufficient to effect phase inversion with mixing for a sufficient time to form an aqueous latex emulsion in the absence of a surfactant.Type: GrantFiled: September 9, 2005Date of Patent: May 11, 2010Assignee: Xerox CorporationInventors: Allan Kwok-Wai Chen, Milan Maric, Tie Hwee Ng, George Liebermann, Enno Eric Agur, Hadi Khan Mahabadi
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Publication number: 20090227733Abstract: An active light-curable ink composition contains a polymerizable compound, a color material having an absorption peak in a wavelength region, and a polymerization initiator having an absorption peak in a different wavelength region from the color material.Type: ApplicationFiled: March 3, 2009Publication date: September 10, 2009Inventor: Satoru Miura
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Publication number: 20080281038Abstract: The aqueous dispersion adhesive composition contains an aqueous dispersion copolymer obtained by reacting of a reaction component containing alkyl (meth)acrylate whose linear or branched alkyl group has 4 to 18 carbon atoms, (meth)acrylic acid, a phosphoric acid group-containing vinyl monomer and an alkoxysilyl group-containing vinyl monomer to react; and a crosslinking agent having reactivity with a carboxyl group. In the aqueous dispersion adhesive composition, an amount of the crosslinking agent is from 0.07 to 4 parts by weight per 100 parts by weight of the aqueous dispersion copolymer, and in an adhesive layer made of the aqueous dispersion adhesive composition, an elongation at 90° C. is 200% or less.Type: ApplicationFiled: May 1, 2008Publication date: November 13, 2008Applicant: Nitto Denko CorporationInventors: Toshitaka Takahashi, Kenichi Okada, Yousuke Makihata, Kuniaki Inui, Taiki Shimokuri, Mika Okada, Namiko Murayama
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Patent number: 7129286Abstract: A process for preparing an acrylic-modified alkyd resin comprising the steps of: d) preparing a sulfonated alkyd resin product; e) preparing an acrylated fatty acid product; and f) reacting the product of step a) and the product of step b) under appropriate polymerization conditions, and for preparing a waterbome composition on the basis thereof as well as products obtainable by those processes.Type: GrantFiled: November 12, 2001Date of Patent: October 31, 2006Assignee: Hexion Specialty Chemicals, Inc.Inventor: Bernd Kuhneweg
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Patent number: 7015262Abstract: Compositions, methods, devices and kits utilizing water-based hydrophilic coating formulations on medical implements. The composition for applying a coating comprises a sulfonated polyester, water, and a surface active agent. Methods for coating a medical implement comprise providing an aqueous dispersion comprising sulfonated polyester and surface active agent, contacting the medical implement with the aqueous dispersion, and drying the medical implement. Methods for acquiring a sample of bodily fluid from a patient comprise coating a needle with a sulfonated polyester, penetrating the needle into the patient, and drawing bodily fluid through the needle.Type: GrantFiled: May 1, 2002Date of Patent: March 21, 2006Assignee: LifeScan, Inc.Inventor: Koon-wah Leong
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Patent number: 6861468Abstract: A polyester resin composition containing a thermoplastic polyester resin; a polyester copolymer containing a monomer having at least one of an amino group, an imino group, an amido group, and a sulfonic acid group; a layered silicate; and an antioxidant. The monomer having at least one of an amino group, an imino group, an amido group, and a sulfonic acid group is contained in the polyester copolymer in an amount of 5 to 15 mol %. The monomer having at least one of an amino group, an imino group, an amido group, and a sulfonic acid group is contained in the polyester resin composition in an amount of 1 to 5 mol % based on a total polyester content of the polyester resin composition. The antioxidant is contained in the polyester resin composition in an amount of 0.01% to 1.0% by mass.Type: GrantFiled: September 26, 2003Date of Patent: March 1, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Tetsuya Yoshida, Yukio Shirokura, Tadahiro Kegasawa, Masami Okamoto
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Patent number: 6680353Abstract: A polyester resin composition containing, as a resin component, a polyester with its main component formed from a polytrimethylene terephthalate and having an intrinsic viscosity of 0.4 to 2, which satisfies the following conditions (1) to (3): (1) the polyester resin composition is composed of a polyester resin component comprising 90% by weight or more of a polytrimethylene terephthalate; (2) the polyester resin composition contains 0.01 to 3% by weight of titanium oxide having an average particle size from 0.01 to 2 &mgr;m; and (3) the polyester resin composition contains 25 or less/mg of the resin of agglomerates of titanium oxide particles which agglomerates have a lengthwise size exceeding 5 &mgr;m. A polytrimethylene terephthalate-based polyester fiber, having a low frictional coefficient, excellent in wear resistance, and showing a suitable luster and a delustered effect, can be stably spun and drawn by applying a melt spinning method to the polyester resin composition.Type: GrantFiled: April 25, 2001Date of Patent: January 20, 2004Assignee: Asahi Kasei Kabushiki KaishaInventors: Jinichiro Kato, Tetsuko Takahashi
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Patent number: 6653522Abstract: A wetness indicating hot melt adhesive composition comprising a pH adjusting component and an indicating agent which is capable of changing color in response to changes in pH. The adhesive composition may comprise 20 to 80% by weight of a sulfonated polyester, 3 to 30% by weight of an acidic plasticizer and 0.05 to 3% by weight of an indicator.Type: GrantFiled: April 9, 1999Date of Patent: November 25, 2003Assignee: National Starch and Chemical Investment Holding CorporationInventors: Mitchell J. Blumenthal, Charles W. Paul
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Patent number: 6638992Abstract: A latex composition for hair care containing a spray-dried hybrid-graft copolymer of a sulfopolyester and an acid-functional polymer segment. The acid-functional polymer segment is formed from at least one acid-functional monomer, at least one ethylenically unsaturated monomer, and at least one amide-containing monomer. Such compositions exhibit superior curl retention even at high humidity.Type: GrantFiled: October 23, 2000Date of Patent: October 28, 2003Assignee: Eastman Chemical CompanyInventors: Robert Gow-Sheng Chen, Phillip Michael Cook, Ramesh Chand Munjal
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Patent number: 6576717Abstract: Disclosed is a water-dispersible acrylic-modified polyester resin containing sulfonate groups prepared by addition copolymerization of ethylenically unsaturated vinyl monomers and a polyester. The polyester is prepared from a polycondensation reaction with dicarboxylic acids, glycols, ethylenically unsaturated monomer, and a minor amount of a sulfomonomer. The acrylic-modified polyester is prepared by first producing the polyester under polycondensation conditions followed by the addition polymerization of the ethylenically unsaturated vinyl monomers. The acrylic-modified polyesters can be formed into a coating composition that has zero or very little organic solvent and is very useful to produce crosslinked cured enamels having excellent gloss, hardness, impact resistance, and water resistance such as those used in automotive finishes, appliance, and coil coatings.Type: GrantFiled: April 24, 1995Date of Patent: June 10, 2003Assignee: Eastman Chemical CompanyInventor: Thauming Kuo
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Patent number: 6521679Abstract: A polyester aqueous dispersion having excellent properties in waterproof, weatherproof, processibility and adhesion, which provides a large allowance for controlling liquid physical properties by post treatment and is advantageous in making dry powders from the dispersion, and an efficient method for preparing the aqueous dispersion at low costs in a simple manner. The polyester aqueous dispersion comprising (i) a water-insoluble polyester and (ii) a polyester containing a sulfonate group bound to a polymer in a concentration of 0.1 to 1.5 mmol equivalents when calculated as —SO3− group per gram of the polymer, and method for preparing a polyester aqueous dispersion comprises a step of melt-kneading a resin composition comprising the water-insoluble polyester (i) and polyester (ii) and a step of phase inversion of adding water or a basic aqueous solution to the molten kneaded mixture thereby to shift the resin composition into the aqueous dispersion.Type: GrantFiled: March 2, 2001Date of Patent: February 18, 2003Assignee: Mitsui Chemicals, Inc.Inventors: Yasuo Okada, Hidenori Kaya, Suguru Tokita
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Patent number: 6495616Abstract: Provided is a liquid crystal polyester resin composition comprising 100 parts by weight of a liquid crystal polyester resin, 2 to 50 parts by weight of hollow sphere having an average particle diameter of 5 to 500 &mgr;m and a volume hollowness of 60 to 80%, and 0 to 40 parts by weight of inorganic fiber, wherein said liquid crystal polyester resin composition has the specific range of fracture rate of the hollow sphere. The liquid crystal polyester resing composition gives a molded product having necessary mechanical physical properties, light-weighted and excellently low thermal conductivity, with good reproducibility.Type: GrantFiled: December 14, 2000Date of Patent: December 17, 2002Assignee: Sumitomo Chemical Company, LimitedInventor: Mituo Maeda
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Patent number: 6423774Abstract: The present invention is directed to an electrodepositable composition of a resinous phase dispersed in an aqueous medium. The resinous phase includes an ionic polyester polymer prepared from a) an aromatic and/or cycloaliphatic carboxylic acid compound having at least two aromatic and/or secondary aliphatic carboxyl groups, b) a branched aliphatic, cycloaliphatic or araliphatic compound containing at least two aliphatic hydroxyl groups, the aliphatic hydroxyl groups being either secondary or tertiary hydroxyl groups or primary hydroxyl groups attached to a carbon adjacent to a tertiary or quaternary carbon, c) a compound including an ionic salt group or a group which is converted to an ionic salt group, and d) optionally, at least one hydroxyl substituted carboxylic compound comprising at least one tertiary aliphatic carboxyl group and at least two aliphatic hydroxyl groups.Type: GrantFiled: March 21, 2000Date of Patent: July 23, 2002Assignee: PPG Industries Ohio, Inc.Inventors: Steven R. Zawacky, Raphael O. Kollah, Craig A. Wilson, Gregory J. McCollum, Robin M. Peffer, Geoffrey R. Webster, Jr., Venkatachalam Eswarakrishnan, Linda K. Anderson
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Patent number: 6384108Abstract: An ink for ink jet printing includes submicron-sized particles in a liquid vehicle, with the submicron-sized particles including a colorant dispersed in an emulsifiable polymer resin. The polymer resin may contain a base chain, such as polyester, having hydrophilic groups, such as alkali sulfonated groups, for emulsifying the resin in water.Type: GrantFiled: September 29, 1995Date of Patent: May 7, 2002Assignee: Xerox CorporationInventors: Marcel P. Breton, Guerino G. Sacripante, Harvey Bruce Goodbrand, Carol A. Jennings, Susanne Birkel
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Patent number: 6303677Abstract: Biodegradable polyesters P1 obtainable by reaction of a mixture consisting essentially of (a1) a mixture consisting essentially of from 35 to 95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof, from 5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and from 0 to 5 mol % of a sulfonate compound, the sum of the individual mole percentages being 100 mol %, and (a2) a dihydroxy compound selected from the group consisting of C2-C6-alkanediols and CS-C10-cycloalkanediols, the molar ratio of (a1) to (a2) being chosen within the range from 0.4:1 to 1.5:1, with the proviso that the polyesters P1 have a molecular weight (Mn) within the range from 5000 to 50,000 g/mol, a viscosity number within the range from 30 to 350 g/ml (measured in 50:50 w/w o-dichlorobenzene/phenol at a concentration of 0.5% by weight of polyester P1 at 25° C.) and a melting point within the range from 50 to 170° C.Type: GrantFiled: July 7, 2000Date of Patent: October 16, 2001Assignee: BASF AktiengesellschaftInventors: Volker Warzelhan, Gunnar Schornick, Bernd Bruchmann, Ursula Seeliger, Motonori Yamamoto, Peter Bauer
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Patent number: 6300405Abstract: A thermoplastic resin composition comprising: (a) Alkylene aryl polyester copolymers having metal sulfonate units represented by the formula IA: or the formula IB: (M+nO3S)d-A-(OR″OH)p where p=1-3, d=1-3, p+d=2-6, n=1-5, and A is an aryl group containing one or more aromatic rings where the sulfonate substituent is directly attached to an aryl ring, R″ is a divalent alkyl group and the metal sulfonate group is bound to the polyester through ester linkages; (b) glass fibers.Type: GrantFiled: June 30, 1998Date of Patent: October 9, 2001Assignee: General Electric CompanyInventors: Bret J. Chisholm, William D. Richards
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Publication number: 20010009944Abstract: A thermoplastic resin composition comprising:Type: ApplicationFiled: June 30, 1998Publication date: July 26, 2001Applicant: GENERAL ELECTRIC COMPANYInventors: BRET J. CHISHOLM, WILLIAM D. RICHARDS
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Patent number: 6262149Abstract: A water-based latex of an acrylic-modified waterborne alkyd dispersion in water is described. The acrylic-modified waterborne alkyd is a hybrid resin prepared by the polymerization of at least one ethylenically unsaturated monomer in the presence of a waterborne alkyd having at least one pendant sulfonate functionality. The ethylenically unsaturated monomer may also be a latent oxidatively functional (LOF) acrylic monomer. Preparation of the latexes may be achieved by emulsion polymerization of at least one ethylenically unsaturated monomer in the presence of a waterborne alkyd having at least one pendant sulfonate functionality. Preparation of hybrid latexes which contain latent oxidative functional (LOF) acrylic monomers may also be achieved by emulsion polymerization of at least one LOF acrylic monomer in the presence of a waterborne alkyd having at least one pendant sulfonate functionality whereby the latent oxidative functionality of the acrylic polymer survives polymerization.Type: GrantFiled: August 12, 1998Date of Patent: July 17, 2001Assignee: Eastman Chemical CompanyInventors: Mark D. Clark, Thauming Kuo, Rebecca R. Stockl, Glen D. Shields
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Patent number: 6136884Abstract: A latex composition for hair care containing a hybrid-graft copolymer of a sulfopolyester and an acid-functional polymer segment. The acid-functional polymer segment is formed from at least one acid-functional monomer, at least one ethylenically unsaturated monomer, and at least one amide-containing monomer. Such compositions exhibit superior curl retention even at high humidity.Type: GrantFiled: January 30, 1998Date of Patent: October 24, 2000Assignee: Eastman Chemical CompanyInventors: Robert Gow-Sheng Chen, Phillip Michael Cook
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Patent number: 6121370Abstract: Color recording liquid which comprises, in combination, (a) an aqueous, black-colored recording liquid and (b) at least one aqueous, colored recording liquid which has other hue than black, in which said liquid (b), when applied to a recording medium, can be fixed in said recording medium within a shorter time than the time required when said liquid (a) is fixed in the same recording medium, and either or both of said liquid (a) and said liquid (b) are a recording liquid which comprises water having dispersed therein a coloring material consisting of particles of colored, ionic group-containing resin. Using the color recording liquid, it becomes possible to obtain high quality black recording without causing blurring of color, along with high quality color recording having no bleeding of color in a borderline between two adjacent color recording areas of different hues.Type: GrantFiled: October 9, 1997Date of Patent: September 19, 2000Assignee: Fujitsu LimitedInventors: Mitsuo Ozaki, Shigeharu Suzuki, Shino Tokuyo, Hiroo Ueda
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Patent number: 6114439Abstract: A crosslinkable aqueous polyester-containing emulsion and a process for preparing the same. The emulsion is obtained by polymerizing unsaturated monomers of acrylic, using a crosslinkable, sulfonated polyester emulsifier having an acid number less than 80 mg KOH/g and an intrinsic viscosity greater than 0.1 dl/g as an emulsifier. The emulsion has the chemical characteristics of both polyester and acrylic resin, i.e. has low volatile organic compounds, good mechanical stability, and good storage stability. Since the emulsion is crosslinkable, a film formed by the emulsion has excellent adhesion, water and heat resistance. Thus, the emulsion is useful for coating and printing on Nylon, PET, OPP films, as well as for high performance industrial surface coating and adhesion for which good heat-, water-, and weather-resistance are required.Type: GrantFiled: October 15, 1997Date of Patent: September 5, 2000Assignee: Industrial Technology Research InstituteInventors: Herng-Dar Hwu, Yih-Her Chang, Tsing-Tang Song, Tsai-Wie Tseng
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Patent number: 6113811Abstract: A dichroic polarizing film is made, for example, by, first combining polyvinyl alcohol and a second polymer, such as, polyvinyl pyrrolidone or a sulfonated polyester, in a solvent. The ratio of polyvinyl alcohol to second polymer is between about 5:1 to 100:1 by weight. The film is coated on a substrate, dried, and then stretched to orient at least a portion of the film. The film incorporates a dichroic dye material, such as iodine, to form a dichroic polarizer. This polarizer may be used in conjunction with a multilayer optical film, such as a reflective polarizer, to form an optical polarizer. The multilayer optical film may contain two or more sets of polyester films, where at least one of the sets is birefringent and orientable by stretching. The polyvinyl alcohol/second polymer film and the multilayer optical film may be simultaneously stretched to orient both polymer films.Type: GrantFiled: January 13, 1998Date of Patent: September 5, 2000Assignee: 3M Innovative Properties CompanyInventors: William L. Kausch, Brian H. Williams, William W. Merrill
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Patent number: 6040360Abstract: A coating composition comprising stabilized inorganic pigments is provided. The coating comprises a pigment treated with a pigment treatment composition of a polyester havng an acid number between 15 and 50 or a phosphate ester or pyrophosphate ester, having an acid number between 10 and 50, solvent, and an amino functional resin.Type: GrantFiled: June 13, 1997Date of Patent: March 21, 2000Assignee: BASF CorporationInventors: Gregory G. Menovcik, Thomas C. Balch, Hilary P. Davis, Paul Dudek
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Patent number: 6031043Abstract: A topical composition comprising an aqueous phase containing a hydrophilic gelling agent of polyester sulphone type selected from water-soluble or water-dispersible terephthalic copolyester oligomers comprising repeating dicarboxylate units of formula (I):CO--A--CO--O(CH.sub.2 CH.sub.2 O).sub.nwherein the weight-average molecular mass of the copolyester oligomer is less than 20,000, preferably less than 15,000, and a cosmetic treatment process for the skin, mucous membranes or the exoskeleton, in which a composition according to the invention is applied to the skin, mucous membranes or the exoskeleton.Type: GrantFiled: March 16, 1998Date of Patent: February 29, 2000Assignee: L'OrealInventors: Christine Dupuis, Henri Samain
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Patent number: 6011085Abstract: A yellow, hot melt alkyd traffic marking composition is described. The yellow, hot melt alkyd traffic marking composition contains 10-25 percent by weight of a hot melt alkyd binder, 5-10 percent by weight of a thermally stable 1,5- or 1,8-substituted anthraquinone colorant selected from a 1,5- or 1,8-substituted anthraquinone aromatic thioether and a 1,5- or 1,8-substituted anthraquinone aromatic thioether polyester, and 65-85 weight percent of a filler. The yellow, hot melt alkyd traffic marking composition of the invention may also contain other components used in traffic marking compositions, such as a reflectivity aid, a plasticizer, or an impact modifier. Other optional components are discussed below. The yellow, hot melt alkyd traffic marking compositions may be applied to any paved surface.Type: GrantFiled: June 12, 1998Date of Patent: January 4, 2000Assignee: Eastman Chemical CompanyInventors: Brian E. Maxwell, Max A. Weaver, Gary R. Robe, Richard A. Miller
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Patent number: 6007910Abstract: Disclosed is an essentially odorless water dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. The copolyester adhesive composition can be used neat or formulated and exhibits broad compatibility with a variety of adhesive additives, including non polar tackifiers.Type: GrantFiled: February 2, 1998Date of Patent: December 28, 1999Assignee: Eastman Chemical CompanyInventors: Richard Anthony Miller, Scott Ellery George
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Patent number: 5973028Abstract: A yellow, hot melt adhesive traffic marking composition is described. The yellow, hot melt adhesive traffic marking composition contains 10-25 percent by weight of a hot melt adhesive binder, 5-10 percent by weight of a thermally stable 1,5- or 1,8-substituted anthraquinone colorant selected from a 1,5- or 1,8-substituted anthraquinone aromatic thioether and a 1,5- or 1,8-substituted anthraquinone aromatic thioether polyester, and 65-85 weight percent of a filler. The yellow, hot melt adhesive traffic marking composition of the invention may also contain other components used in traffic marking compositions, such as a reflectivity aid, a plasticizer, or an impact modifier. Other optional components are discussed below. The yellow, hot melt adhesive traffic marking compositions may be applied to any paved surface.Type: GrantFiled: June 12, 1998Date of Patent: October 26, 1999Assignee: Eastman Chemical CompanyInventors: Brian E. Maxwell, Max A. Weaver, Gary R. Robe
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Patent number: 5965259Abstract: The present invention is a pre-oriented, non-stretched polyester fiber spun with spooling speeds of at least 3,000 m/min., wherein the polyester is a copolymer comprised essentially of ethylene terephthalate units and up to 10 weight % of other dicarboxylic acids or other diols, and carboxy phosphonic acid units of the formula: ##STR1## wherein R is selected from C.sub.1-10 -alkylene, C.sub.1-10 -cycloalkylene or C.sub.6-10 -arylene, in a quantity corresponding to 30 to 500 ppm phosphorus, in relation to polyester. The invention also comprises a process for the production of this fiber.Type: GrantFiled: February 10, 1998Date of Patent: October 12, 1999Assignee: Lurgi Zimmer AktiengesellschaftInventors: Heinz-Dieter Schumann, Ulrich Thiele
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Patent number: 5929178Abstract: There are provided a heat-aging-resistant polyamide resin composition comprising (C) a polyamide containing 10 to 100% by weight of (A) a polyamide obtained by polymerizing a monomer containing 70 mole % or more of m-xylylenediamine as a diamine component and a monomer containing 70 mole % or more of adipic acid as a dicarboxylic acid component and 90 to 0% by weight of (B) other polyamide, (D) a copper compound in an amount of 0.001 to 0.1 part by weight per 100 parts by weight of the polyamide (C), (E) a halide of a Group 1 or Group 2 metal of the Periodic Table of the Elements, an ammonium halide, or an organohalide in an amount of 0.005 to 1 part by weight per 100 parts by weight of the polyamide (C), at least one selected from among (F) hindered phenols and (G) hindered amines with the amount of each of the hindered phenols (F) and the hindered amines (G) being 0.05 to 3 parts by weight per 100 parts by weight of the polyamide (C), and (H) an organophosphorus compound in an amount of 0.Type: GrantFiled: October 7, 1997Date of Patent: July 27, 1999Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Takatoshi Shida, Makoto Takahashi, Masahiro Harada
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Patent number: 5913972Abstract: An aqueous pigment dispersion is formed of a pigment, an aqueous medium and a dispersant resin. The dispersant resin contains a hydrophobic moiety and a hydrophilic moiety in its molecule. The hydrophobic moiety is a polyester linkage chain formed of ester linkages as primary linkages. The hydrophilic moiety is a water-soluble resin containing sulfonic groups or their salts. The water-soluble resin can be produced, for example, by reacting a polyol with maleic acid and/or fumaric acid to synthesize an unsaturated polyester resin and then adding acid sulfurous acid or its salt to the unsaturated polyester resin to form groups represented by the following formula (I): ##STR1## wherein M.sup.1 represents a hydrogen atom, an alkali metal, an ammonium group or a lower aliphatic quaternary ammonium group. The aqueous pigment dispersion is useful as a water-based ink for writing or recording equipments such as writing instruments, printers, copying machines, fax machines and printing machines.Type: GrantFiled: April 16, 1997Date of Patent: June 22, 1999Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.Inventors: Kazuo Kanou, Jiro Amano, Naoyuki Sakai
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Patent number: 5820982Abstract: Water-soluble or water-dispersible and curable polyester resins are suitable as binders in various applications. The resins are reaction products of polyterephthalate, sulfoisophthalates, polyols, polyacids, end acids and crosslinker agents. Waste terephthalates can be utilized. The preferred polyol is pentaerythritol. The resins can also be used as dye levelling agents when dyeing synthetic fibers.Type: GrantFiled: December 3, 1996Date of Patent: October 13, 1998Assignee: Seydel Companies, Inc.Inventor: Robert Keith Salsman