Derived From Terephthalic Acid Or Derivative Patents (Class 524/605)
  • Patent number: 4802061
    Abstract: In microelectronic components and thick-film hybrid circuits, the multilayer substrates of the said components and the substrates of the said circuits are produced using liquid crystalline polymers which can be processed by a thermoplastic method.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: January 31, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Portugall, Hans-Josef Sterzel, Gerd Blinne, Heinz-Dieter Vondenhagen, Erhard Seiler, Hans-Friedrich Schmidt, Sybille Von Tomkewitsch
  • Patent number: 4772422
    Abstract: An electrically conductive resin composition comprises (1) a polymer of the thermotropic liquid crystals being capable of the anisotropic property in the molten state and (2) an electrically conductive carbon black. It is improved in the impact strength and can contain a large amount of carbon black.
    Type: Grant
    Filed: November 21, 1986
    Date of Patent: September 20, 1988
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kenji Hijikata, Toshio Kanoe
  • Patent number: 4758616
    Abstract: A thermoplastic polyester composition for a powdered paint which comprises:(a) a copolyester derived from a dicarboxylic acid component comprising 40 to less than 60 molar % of terephthalic acid and a diol component comprising at least 70 molar % of 1,4-butanediol and having a melting point determined by differential thermal analysis of 100.degree. to 150.degree. C.,(b) a nucleating agent, and(c) a leveling agent.This composition can be applied with a lowered pre-heat temperature and a lowered heat setting temperature and can form a coating film having an excellent adhesion, a good appearance and a high impact resistance.
    Type: Grant
    Filed: August 15, 1986
    Date of Patent: July 19, 1988
    Assignees: Toray Industries, Inc., Seitetsu Kagaku Co.
    Inventors: Tatsuro Okano, Hirofumi Eguchi
  • Patent number: 4745142
    Abstract: A polyester fiber having a superior stainproof property comprises at least one fiber-forming polyester copolymer comprising a backbone polyester polymer and at least one type of terminal substituent which blocks at least some of the terminals of the molecules of the backbone polyester polymer and which substituent consists of a polyoxyalkyleneglycol monoether group of the formula (I):R.sup.1 -O--R.sup.2 -O.sub.n (I)wherein R.sup.1 is a monovalent organic radical free from active hydrogen atom, R.sup.2 is an alkylene radical, and n is an integer of 2 or more.
    Type: Grant
    Filed: October 10, 1986
    Date of Patent: May 17, 1988
    Assignee: Teijin Limited
    Inventors: Shinji Ohwaki, Togi Suzuki, Shigenobu Kobayashi
  • Patent number: 4740538
    Abstract: A filled engineering plastic is provided with improved impact strength by pretreating the filler to provide separate coating deposits of a coupling agent and an impact modifier for the plastic matrix. For a nylon plastic composite, a kaolin filler coated with separate deposits of an amino functional silane coupling agent and a phenol or triethanolamine impact modifier has resulted in an improved impact strength without sacrificing tensile and elastic properties of the nylon.
    Type: Grant
    Filed: July 3, 1986
    Date of Patent: April 26, 1988
    Assignee: Engelhard Corporation
    Inventor: Dennis G. Sekutowski
  • Patent number: 4727108
    Abstract: Disclosed herein is a polyester composition comprising 0.001-5% by weight of particles which have an average particle size of 0.05-5 micrometers, are mainly composed of calcium carbonate and contain 0.001-5% by weight of at least one compound selected from the group consisting of magnesium compounds, strontium compounds and barium compounds.Also disclosed herein is a process for preparing a polyester film by the electrostatic cooling method, which process is characterized by using the polyester composition of the present invention.
    Type: Grant
    Filed: October 21, 1986
    Date of Patent: February 23, 1988
    Assignee: Diafoil Company, Limited
    Inventors: Takashi Kagiyama, Kazuo Endo, Chikakazu Kawaguchi, Yosio Meguro, Kazuhiro Kunugihara
  • Patent number: 4719250
    Abstract: An improved thermoplastic molding composition is provided which is particularly suited for use in the impervious void-free encapsulation on a relatively expeditious basis of an electronic component wherein the preformed electronic component is positioned in a mold cavity prior to the introduction of the molding composition via injection molding. The molding composition comprises a melt processable thermotropic liquid crystalline polymer which is of a relatively low weight average molecular weight of approximately 4,000 to 25,000 (e.g. approximately 4,000 to 10,000) and which is substantially incapable of further chain growth upon heating. Uniformly dispersed within the liquid crystalline polymer is approximately 40 to 80 percent by weight (e.g. approximately 50 to 75 percent by weight) of a particulate inorganic material (preferably of silicon dioxide) which serves to advantageously decrease its volumetric coefficient of thermal expansion and to advantageously increase its thermal conductivity.
    Type: Grant
    Filed: June 9, 1986
    Date of Patent: January 12, 1988
    Assignee: Hoechst Celanese Corporation
    Inventors: Nancy C. Eickman, Charles E. McChesney, Gary E. Williams, Hyun-Nam Yoon
  • Patent number: 4717583
    Abstract: A material is provided for adding image areas to grained lithographic offset plates. A polyester resin with imbedded fibers changes the surface characteristics of the printing plate from an oily ink repellant condition to an oily ink receptive condition. In a preferred embodiment, a resin of PBT or PET is provided in generally solid form which may be shaped to a desired form for application to the plate. Corrections may be made to a plate either on or off a printing press and at any stage of the print run.
    Type: Grant
    Filed: March 3, 1987
    Date of Patent: January 5, 1988
    Inventors: Gregory L. McKissick, James L. Orcutt
  • Patent number: 4713407
    Abstract: The present invention relates to a polyester resin composition, and more particularly, to a polyester resin composition having excellent properties in flame retardance, mechanical property, heat resistance and moldability. Said polyester resin composition comprises 100 parts by weight of polyester resin (A), from 20 to 70 parts by weight of glass fibers (B), from 2 to 8 parts by weight of a crystallization-accelerating agent (C), from 10 to 25 parts by weight of flame retardant (D) and, as a auxiliary flame retardant (E), from 1 to 10 parts by weight of an antimony compound and from 2 to 12 parts by weight of a boric acid salt.
    Type: Grant
    Filed: July 7, 1986
    Date of Patent: December 15, 1987
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Philip E. Bailey, Gordon E. Pickett, Manfred Luttinger, Takashi Umeda
  • Patent number: 4713408
    Abstract: A polybutylene terephthalate resin composition comprises polybutylene terephthalate, a sulfonate anionic antistatic agent and an oxidized polyolefin wax. It is improved in the antistatic property and useful as a part for an electric instrument.
    Type: Grant
    Filed: December 20, 1985
    Date of Patent: December 15, 1987
    Assignee: Polyplastics Co., Ltd.
    Inventors: Katsuhiko Takahashi, Yoshihisa Tajima
  • Patent number: 4699942
    Abstract: Compositions suitable for molding are produced by examining a (1) polyethylene terephthalate polyester, (2) a low molecular weight polyethylene mold release agent (3) talc as nucleating agent, (4) carbon black, (5) a hindered phenolic antioxidant and (6) other optional ingredients such as reinforcing glass fibers.
    Type: Grant
    Filed: August 30, 1985
    Date of Patent: October 13, 1987
    Assignee: Eastman Kodak Co.
    Inventors: James C. Weaver, Wayne P. Pruett
  • Patent number: 4693932
    Abstract: An oriented polyester film comprising ethylene terephthalate as the major repeating units, which comprises 0.01 to 1.0% by weight of silica particles and/or titanium dioxide particles having each an average particle size of 0.01 to 0.5.mu. and 0.005 to 1.0% by weight of calcium carbonate having an average particle size of 0.01 to 0.5.mu., which provides an oriented polyester film for the base film of video tape which has a flatness on the surface and has excellent slipperiness, abrasion resistance and running characteristics as well as excellent magnetic transducer characteristics.
    Type: Grant
    Filed: May 2, 1986
    Date of Patent: September 15, 1987
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Katsuaki Kuze, Yasuhiro Nishino, Yujiro Matsuyama, Kozo Maeda, Masahiro Kobayashi, Tadashi Okudaira, Tsuyoshi Hongo, Osamu Makimura
  • Patent number: 4687795
    Abstract: Polyester compositions having present a small amount of a salt of salicyclic acid and a cation of a metal from Group IA of the periodic Table of Elements, for example sodium salicylate, have been found to have good crystalization and other properties.
    Type: Grant
    Filed: December 24, 1984
    Date of Patent: August 18, 1987
    Assignee: Allied Corporation
    Inventors: Steven R. Dunkle, John C. Haylock
  • Patent number: 4687802
    Abstract: Metal salts are disclosed as effective to reduce Arc Track Rate in poly(1,4-butylene terephthalate) resin molding compositions.
    Type: Grant
    Filed: February 25, 1985
    Date of Patent: August 18, 1987
    Assignee: General Electric Company
    Inventor: Leonard R. Hepp
  • Patent number: 4686256
    Abstract: Difficult to mold polyester resin containing compositions are made thermoplastically moldable by the addition of an aromatic polycarbonate and mold-release additives of the formula:R-Ywherein R is selected from saturated and unsaturated hydrocarbyl having 13 to 44 carbon atoms, inclusive; and Y is selected from monovalent moieties of the formulae:--H, --COOR', and --O--R"wherein R' is selected from hydrogen and hydrocarbyl of 1 to 36 carbon atoms, inclusive; and R" represents one of lower alkyl and lower alkenyl.
    Type: Grant
    Filed: December 17, 1985
    Date of Patent: August 11, 1987
    Assignee: General Electric Company
    Inventor: Omar M. Boutni
  • Patent number: 4684686
    Abstract: Particulate and fibrous metal are disclosed to improve the physical properties of poly(1,4-butylene terephthalate) resin molding compositions.
    Type: Grant
    Filed: February 25, 1985
    Date of Patent: August 4, 1987
    Assignee: General Electric Company
    Inventor: Leonard R. Hepp
  • Patent number: 4670498
    Abstract: A polyester block copolymer composition comprising 100 parts by weight of a polyester block copolymer and 0.05 to 10 parts by weight of a metal alcoholate of the formula: M(OR).sub.n, wherein M is a metal of the groups I to III in periodic table, R is a hydrocarbon group having 1 to 20 carbon atoms, and n is 1 to 3, said polyester block copolymer composition having improved melt properties and being suitable for producing various shaped articles by extrusion molding.
    Type: Grant
    Filed: November 5, 1985
    Date of Patent: June 2, 1987
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Hironobu Furusawa, Tadao Taika
  • Patent number: 4668732
    Abstract: A polyester composition having an enhanced melt-spinnability and processability and useful for producing polyester fibers having excellent mechanical properties and whiteness, comprises (A) a polyester resin derived from esterification or interesterification and polycondensation of a diol component with an acid component which comprises a terephthalic acid, 0.1 to 20 molar % based on the amount of the terephthalic acid, of a naphthalene dicarboxylic acid compound and/or diphenyl dicarboxylic acid compound, and 0.01 to 20 molar % based on the amount of the terephthalic acid, of a p-hydroxybenzoic acid compound and/or benzoic acid compound and/or 0.005 to 0.15 molar % based on the amount of the terephthalic acid, of at least one member selected from alkali and alkaline earth metal salts of organic carboxylic acids; and (B) 0.01 to 3% based on the weight of the polyester resin (A), of titanium dioxide particles dispersed in the polyester resin (A), having an average size of 0.5 .mu.
    Type: Grant
    Filed: May 16, 1986
    Date of Patent: May 26, 1987
    Assignee: Teljin Limited
    Inventors: Masashi Kuno, Kimihiro Ogawa
  • Patent number: 4666965
    Abstract: Disclosed is a flame-retardant glass-fiber-reinforced polyethylene terephthalate resin composition formed by blending (A) a polyethylene terephthalate resin, (B) glass fibers, (C) a nucleating agent, (D) a monoepoxy compound having a specific chemical structure and/or a benzoic acid ester having a specific chemical structure, (E) a bromine-containing polymeric flame retarder having aromatic rings in the polymeric side chains, and (E) an antimony oxide in specified proportions.This resin composition has a very high degree of crystallizability and can yield molded articles having excellent appearance, mechanical strength, heat distortion resistance and flame retardancy.
    Type: Grant
    Filed: December 30, 1985
    Date of Patent: May 19, 1987
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventor: Yoshihisa Aoki
  • Patent number: 4664983
    Abstract: A polyester composition according to the subject invention is composed of thermoplastic polyesters and the titanium dioxide and/or aluminum oxide having specific particle diameters.The polyester composition provides the molded articles which display reduced warpage.The polyester composition has high plating characteristic and provide superior metal-plated moldings.
    Type: Grant
    Filed: January 8, 1985
    Date of Patent: May 12, 1987
    Assignee: Toray Industries Inc.
    Inventors: Kiyokazu Nakamura, Kiichi Kometani, Toshihide Inoue
  • Patent number: 4659753
    Abstract: In an aqueous sizing agent for glass fibers, comprising a bonding agent, a film-former and, optionally, a lubricant, wetting agent and/or other conventional additive, the improvement which comprises including therein a masked polyisocyanate which is water-soluble or dispersible. The sized glass fibers are especially useful in reinforcing polymeric products such as polyamides, giving improved physical properties.
    Type: Grant
    Filed: October 5, 1984
    Date of Patent: April 21, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christoph Tiburtius, Anna Marx, Hans-Ulrich Buschhaus, Kurt Findeisen
  • Patent number: 4650836
    Abstract: A method for rending melt processable a liquid crystal polymer otherwise not readily processable as a result of an interfering degradation temperature or an elevated viscosity. In the method the liquid crystal polymer is blended with a second, low molecular weight liquid crystal diester to form a miscible mesophase which is typified by a reduced viscosity and or at a lower temperature may be formed into a desired configuration. The low molecular weight liquid crystal may be then transesterified into the polyester to produce a long chain having desirable final liquid crystal polymer properties.
    Type: Grant
    Filed: April 4, 1985
    Date of Patent: March 17, 1987
    Inventors: Eric R. George, Roger S. Porter
  • Patent number: 4649067
    Abstract: One-component baking enamels of polyesters, containing hydroxyl groups, and polyisocyanates, wherein the polyisocyanate component consists of 2-methyl-1,5-diisocyanatopentane (MPDI) having the formula (I): ##STR1## which is blocked totally or partially by .epsilon.-caprolactam or acetoxime, or a mixture of the same with 2-ethyl-1,4-diisocyanatobutane (EBDI) having the formula (II): ##STR2## which is blocked totally or partially by .epsilon.-caprolactam or acetoxime, wherein the diisocyanate mixture of (I) and (II) has about 88 to 99% by weight of (I) and about 12 to 1% by weight of (II) and the free isocyanate (NCO) content is up to about 10% by weight.The one-component baking enamels are suitable for application to metal, glass and plastic objects and exhibit excellent flexibility and weather resistance.
    Type: Grant
    Filed: May 24, 1984
    Date of Patent: March 10, 1987
    Assignee: Chemische Werke Huls Aktiengesellschaft
    Inventor: Rainer Gras
  • Patent number: 4639480
    Abstract: Disclosed are compositions of polyethylene terephthalate and certain N-substituted phthalimide plasticizers, particularly polyethylene terephthalate molding compositions additionally containing a reinforcing agent and a nucleating agent.
    Type: Grant
    Filed: May 17, 1985
    Date of Patent: January 27, 1987
    Assignee: Monsanto Company
    Inventors: Gail H. Birum, Thomas C. Mathis, Richard D. Stolk
  • Patent number: 4636544
    Abstract: Titanium dioxide is disclosed to improve the comparative tracking index of flame retarded poly(1,4-butylene terephthalate) resin molding compositions.
    Type: Grant
    Filed: February 25, 1985
    Date of Patent: January 13, 1987
    Assignee: General Electric Company
    Inventor: Leonard R. Hepp
  • Patent number: 4629750
    Abstract: Cuprous iodide is disclosed to improve the impact strength of flame retarded, glass reinforced, impact modified, poly(1,4-butylene terephthalate) resin molding compositions.
    Type: Grant
    Filed: February 25, 1985
    Date of Patent: December 16, 1986
    Assignee: General Electric Company
    Inventor: Leonard R. Hepp
  • Patent number: 4626566
    Abstract: A composition comprising an aromatic carbonate polymer in admixture with a mold release effective amount of a hydrogenated alpha-olefin oligomer fluid.
    Type: Grant
    Filed: December 26, 1985
    Date of Patent: December 2, 1986
    Assignee: General Electric Company
    Inventors: Kenneth F. Miller, Omar M. Boutni
  • Patent number: 4623562
    Abstract: A process for producing light-reflecting bodies is described. The wall of the light-reflecting body consists of a polyalkylene terephthalate and/or a copolyester thereof, containing in each case 10-40% by weight of a finely-divided filler, a light-reflecting metal layer being applied directly to at least one surface of the wall. According to the novel process, a polyester moulding compound containing:(a) 90-60% by weight of a polyalkylene terephthalate and/or copolyester thereof, or of a mixture of polyalkylene terephthalates, and(b) 10-40% by weight of a finely-divided filleris subjected before shaping, at elevated temperature but at a temperature below the melting point of the moulding compound, to a vacuum treatment.
    Type: Grant
    Filed: November 27, 1985
    Date of Patent: November 18, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Franz Breitenfellner, Karl Leidig, Thomas Kainmuller
  • Patent number: 4618643
    Abstract: Glue sticks for use in a hand held glue gun comprise thermoplastic coplyester corresponding to a product of an acid component comprising in selected proportions terephthalic acid, isophthalic acid and aliphatic dicarboxylic acid, an hydroxyl component comprising one or more aliphatic diols of which not less than 90 moles % is 1.4 butane diol, and a polymeric plasticizer component. The glue stick has a melting point of 90.degree. to 120.degree. C. and a reduced viscosity of 0.5 to 0.7. Preferred glue sticks have a melting point of about 110.degree. C., a reduced viscosity of 0.6 to 0.65 and comprise a copolyester from an acid component comprising 45 to 48 moles % terephthalic acid, 38 to 45 moles % isophthalic acid and 10 to 15 moles % azelaic acid, an hydroxyl component comprising 1.4 butane diol and 1.6 hexane diol in a molar ratio of 90 to 95:5 to 10, and a polymeric plasticizer component comprising a polycaprolactone or selected hydroxy polyester to an extent of 3 to 4% by weight of the copolyester.
    Type: Grant
    Filed: March 2, 1984
    Date of Patent: October 21, 1986
    Assignee: USM Corporation
    Inventors: Hubertus von Voithenberg, Gotz Hillert
  • Patent number: 4603073
    Abstract: A magnetic recording medium has a biaxially-oriented polyester film base which includes carbon black beads having a median diameter from 50 to 500 nm and is substantially free from beads or agglomerates more than 5 micrometers in diameter. The beads provide opacity such as is often required of the flexible recording disk of a diskette. The film base may be either a single layer, throughout which the beads are uniformly dispersed, or it may be multi-layer, e.g., a central layer containing the carbon black beads and two surface layers which are free from the beads.
    Type: Grant
    Filed: June 24, 1985
    Date of Patent: July 29, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Brenda L. Renalls, Douglas G. Pedrotty, John F. Donlon
  • Patent number: 4600743
    Abstract: An antistatic fiber obtained by melt spinning of a fiber-forming thermoplastic polymer containing at least one of polyoxyalkylene glycol and its derivatives in an amount of not less than 0.5% by weight, characterized in that said fiber has a half life time of electric charge leakage of not more than 150 seconds before and after treatment with a weight decreasing agent and, when treated with a weight decreasing agent, provides a number of streaks arranged in parallel in the lengthwise direction at the surface.
    Type: Grant
    Filed: April 13, 1984
    Date of Patent: July 15, 1986
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Tatsuhiko Shizuki, Kaoru Ban, Fumikazu Yoshida, Masakatsu Ohguchi
  • Patent number: 4595715
    Abstract: An oriented polyester film comprising ethylene terephthalate as the major repeating unit, which comprises particles of kaolinite and calcium carbonate uniformly dispersed therein, said kaolinite and said calcium carbonate having each an average particle size of 0.05 to 0.8 micron and being contained in such amounts as satisfying the following equations:70.ltoreq.D.times.A.ltoreq.1000 (I)1000.ltoreq.A+B.ltoreq.10000 (II)0.1.ltoreq.B/A.ltoreq.25 (III)wherein D is an average particle size (micron) of calcium carbonate, A is a content (ppm) of calcium carbonate and B is a content (ppm) of kaolinite, said oriented polyester film being excellent in flatness, slipperiness, abrasion resistance, etc. with a small number of coarse particles.
    Type: Grant
    Filed: September 7, 1984
    Date of Patent: June 17, 1986
    Assignees: Toyo Boseki Kabushiki Kaisha T/A Toyobo Co., Ltd., Nippon Magphane Kabushiki Kaisha
    Inventors: Katsuaki Kuze, Yujiro Matsuyama, Kozo Maeda, Takeshi Ota, Masahiro Kobayashi, Tsuyoshi Hongo, Osamu Makimura
  • Patent number: 4590119
    Abstract: An oriented polyester film is provided according to the present invention which contains, per 100 parts by weight of a polyester,(A) 0.005-2 parts by weight of fine particles having average size of 0.05-3 .mu.m, and(B) 0.005-2 parts by weight of at least one compound selected from the group consisting of high aliphatic monocarboxylic acids having 10-33 carbon atoms and esters thereof.Herein also disclosed is a composite polyester film which comprises a resin layer of copolyester or copolyester ether containing an ester-forming alkali metal salt of sulfonic acid compound, the layer being laminated on at least one side of the oriented polyester film as a substrate. The present invention further provides a magnetic recording medium comprising the oriented polyester film or the composite polyester film as a base.The novel films of the present invention have a surface satisfying three properties: flatness, slipperiness and adhesion, which are considered unable to be attained with a conventional polyester film.
    Type: Grant
    Filed: June 20, 1984
    Date of Patent: May 20, 1986
    Assignee: Toray Industries, Inc.
    Inventors: Ken-ichi Kawakami, Toshiya Yoshii, Masaru Suzuki, Hotsuma Okasaka
  • Patent number: 4585823
    Abstract: Ovenwares produced by molding a wholly aromatic polyester resin composition comprising 30 to 80 wt. % of a wholly aromatic polyester having a repeating unit represented by the general formula, ##STR1## wherein X is a C.sub.1 -C.sub.4 alkyl group or --O--, --SO.sub.2 --, --S-- or --CO-- group, m and n are 0 or 1, a d:e ratio is in the range of from 1:1 to 10:1, an e:f ratio is in the range of from 9:10 to 10:9, and the positions of substituents at each aromatic ring of the foregoing general formula are para or meta to each other, 5 to 60 wt. % of wollastonite and 5 to 60 wt. % of titanium oxide.
    Type: Grant
    Filed: May 30, 1985
    Date of Patent: April 29, 1986
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Teruo Saito, Kuniaki Asai, Tadayasu Kobayashi
  • Patent number: 4579902
    Abstract: The present invention provides a permanently antistatic, injection moldable thermoplastic composition comprising a polybutylene terephthalate resin having an intrinsic viscosity in the range of about 0.7 to about 1.4 deciliters per gram measured in ortho-chlorophenol at 25.degree. C., an antistatic dopant comprising an electron acceptor compound, an electron donor compound, and polytetrafluoroethlene, and less than about 10 percent by weight based on the total weight of the molding composition of carbon fibers having lengths between about 0.1 and about 1.0 inch. Such a molding composition exhibits a volume resistivity of less than 1.times.10.sup.8 ohm-cm, exceptional low wear performance, excellent mechanical properties, and ease of manufacture.
    Type: Grant
    Filed: December 5, 1984
    Date of Patent: April 1, 1986
    Assignee: Celanese Corporation
    Inventor: David P. O'Brien
  • Patent number: 4579893
    Abstract: Disclosed are compounds having the formula ##STR1## wherein X is the residue of a benzoxazole radical;Y is carboxyl, alkoxycarbonyl, alkanoyl, cyano, carbamoyl, N-alkylcarbamoyl or N,N-dialkylcarbamoyl; andA is phenyl, naphthyl or phenyl or napthyl substituted with one or more substituents selected from hydroxy, halogen, alkyl, alkoxy, cycloalkyl, aryl, aryloxy or Y. Also disclosed are polymeric materials stabilized against degradation by ultraviolet light by the incorporation therein of one or more of the above-defined compounds.
    Type: Grant
    Filed: January 6, 1984
    Date of Patent: April 1, 1986
    Assignee: Eastman Kodak Company
    Inventors: Richard H. S. Wang, Michael Bellas, William W. Blount, Jr.
  • Patent number: 4569973
    Abstract: Novel copolyetherester elastomer molding compositions are prepared from diols, diacids, poly(alkylene ether) glycol and caprolactone or polycaprolactone.
    Type: Grant
    Filed: August 24, 1984
    Date of Patent: February 11, 1986
    Assignee: General Electric Company
    Inventors: John A. Tyrell, Victor Mark
  • Patent number: 4567224
    Abstract: This invention provides a biaxially oriented container which can be very easily molded by extrusion or injection stretch blow molding and which exhibits satisfactory hat resisting property and pressure resisting property even if the content of glass fibers is less than 10 weight %.
    Type: Grant
    Filed: March 25, 1985
    Date of Patent: January 28, 1986
    Inventors: Daiichi Aoki, Yoshinori Nakamura, Hiroyuki Orimoto
  • Patent number: 4566990
    Abstract: Conductive thermoplastic having high EMI shielding effectiveness comprise a thermoplastic condensation polymer and incorporated therein a synergistic combination of metal flake and conductive metal or metal coated fiber.
    Type: Grant
    Filed: October 25, 1983
    Date of Patent: January 28, 1986
    Assignee: General Electric Company
    Inventors: Nan-I Liu, Roelof van der Meer
  • Patent number: 4563508
    Abstract: The molding properties of molding compounds based on wholly aromatic polyesters are improved by the addition to such wholly aromatic polyester compositions of a minor amount of an aromatic polyester which is a combination of the following units: ##STR1## Where; p=0 to 0.9, q=0.1 to 1.00, r=1 to 7, S=0.3 to 1.00, t=0 to 0.7. A preferred formulation consists of a polyester where the units are: p=0, q=1.0, r=1 to 5 and S=1.0.
    Type: Grant
    Filed: May 18, 1984
    Date of Patent: January 7, 1986
    Assignee: Dart Industries, Inc.
    Inventors: Steve G. Cottis, Richard Layton, Nathan D. Field
  • Patent number: 4562216
    Abstract: Flame retardant reinforced with thermoplastic polyester resin compositions are disclosed glass fiber and a system of flame retardants represented by the following general formulas (I) and (II), together with antimony trioxide. The flame retardant system is a blend of 1-20 parts by weight of component (I), and 2-40 parts by weight of component (II), provided the weight ratio (I)/(II) of the flame retardant components (I) to (II) is in the range of 0<(I)/(II).ltoreq.5, and that the total amount of flame retardants (I) plus (II) is in the range of 3-40 parts by weight. From 2 to 3 parts by weight of antimony trioxide is present and 5 to 60% by weight of glass fiber is also present, these two percentages being expressed on the basis of the weight of the total resin composition. The resin compositions exhibit outstanding mechanical, thermal, forming and machining properties in addition to being fire retardant.
    Type: Grant
    Filed: January 5, 1984
    Date of Patent: December 31, 1985
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Kazuo Kishida, Isao Sasaki, Hiroshi Mori
  • Patent number: 4559164
    Abstract: Poly(butylene terephthalate) injected molded articles which contain small uniformly distributed amounts of amorphous carbon or graphite powder, or graphitic carbon in the form of fibers, or any combination thereof, are electroconductive and possess decreased tendency to accumulate charges of static electricity. Minor amounts of glass fibers, polycarbonate resins and rubbery impact modifiers improve the electroconductivity imparted by the carbon.
    Type: Grant
    Filed: March 9, 1982
    Date of Patent: December 17, 1985
    Assignee: General Electric Company
    Inventors: Robert J. Kostelnik, Allen D. Wambach
  • Patent number: 4558085
    Abstract: The fast crystallizing polyalkyleneterephthalate resin compositions disclosed herein contain 0.05-4 percent by weight of a sodium salt of a hydrocarbon acid having the formula R.degree.(COO).sub.y Na.sub.z wherein R.degree. is a hydrocarbon group having a valency of y and having 1-25 carbon atoms therein, preferably 1-10 carbon atoms, y is an integer having a value of at least one, advantageously 1-10 and preferably 1-3, and z is an integer having a value of at least one and no greater than the value of y, this sodium salt of the hydrocarbon acid being in the form of a complex with a polymeric compound, which contains at least two recurring units of the formula --CH.sub.2 CH.sub.2 O--, together with reinforcing agents, fillers and/or additives and optionally a flow promoter selected from low molecular weight organic esters or polymers containing a recurring structure of [(CH.sub.2).sub.x O--].sub.
    Type: Grant
    Filed: August 20, 1984
    Date of Patent: December 10, 1985
    Assignee: Plastics Engineering Company
    Inventor: Chung J. Lee
  • Patent number: 4555439
    Abstract: According to the present invention, rolled sheet-like materials having superior mechanical properties, in particular toughness and high-impact properties, as well as superior heat resistance and showing no whitening can be provided.Such rolled sheet-like materials are manufactured by isotropically rolling sheet-like materials, which were obtained by melting, blending and forming the mixture consisting of thermoplastic resin having the degree of crystallinity of 10% or more of 20 to 90% by weight and flaky fillers of 10 to 80% by weight, to orientate a part of crystals after it was melted at the melting point of said sheet-like materials and then recrystallizing the melted crystals under the rolled condition.
    Type: Grant
    Filed: January 13, 1984
    Date of Patent: November 26, 1985
    Assignee: Kuraray Company, Ltd.
    Inventors: Ryuhei Ueeda, Kiyonobu Fujii, Hiroshi Narukawa
  • Patent number: 4551485
    Abstract: The impact strength of thermoplastic poly(ethylene terephthalate) molding compositions containing a reinforcing filler (preferably glass fiber), an epoxidized crystallization promoter (e.g., an epoxidized vegetable oil) and a nucleating agent (e.g., sodium stearate) is markedly improved by including in the composition a small amount of an organofunctional silane, i.e., a compound characterized by having a functional substituent at the end of a methylene chain bound to a silicon atom to which are also bonded a plurality of readily hydrolyzable groups. A few such compounds are gamma-aminopropyltriethoxysilane, gamma-glycidoxypropyltrimethoxysilane, gamma-aminopropyltriethoxysilane and gamma-glycidoxypropyltrimethoxysilane. The formulations may also contain a warp-reducing filler such as mica. Organofunctional silanes typically have application in thermoplastic polymers only as coupling agents, i.e.
    Type: Grant
    Filed: September 4, 1984
    Date of Patent: November 5, 1985
    Assignee: Ethyl Corporation
    Inventors: Gary S. Ragan, Jesse D. Jones
  • Patent number: 4548964
    Abstract: Disclosed is a flame-retardant polyester resin composition comprising (1) a reinforced resin composition obtained by melt blending (A) a polyethylene terephthalate resin, (B) glass fibers, a combination of (C) at least one flame retarder having a specified chemical structure and (D) hexabromobiphenyl ether used in specific proportions, (E) antimony trioxide and optionally (F) an inorganic filler; and (2) (G) at least one ester compound subsequently added to the reinforced resin composition, the ester compound being derived from pentaerythitol and a fatty acid. This flame-retardant polyester resin composition can yield molded articles having excellent mechanical properties and flame retardancy, and exhibits good releasability of the molded article and rapid feed into the molding machine at the time of molding.
    Type: Grant
    Filed: December 10, 1984
    Date of Patent: October 22, 1985
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Tomohiko Yoshida, Hiroshi Mori
  • Patent number: 4548978
    Abstract: Fast crystallizing polyester molding composition comprising (a) a PET or PET/PBT matrix resin having an inherent viscosity of at least 0.4, (b) polyalkylene oxide soft segments incorporated into the matrix resin, (c) a plasticizer of the formula ##STR1## (d) a crystallization promoter, and (e) a reinforcing or filling material.
    Type: Grant
    Filed: February 22, 1985
    Date of Patent: October 22, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: William E. Garrison, Jr.
  • Patent number: 4546036
    Abstract: A magnetic recording medium has a biaxially-oriented polyester film base which includes carbon black beads having a median diameter from 50 to 500 nm and is substantially free from beads or agglomerates more than 5 micrometers in diameter. The beads provide opacity such as is often required of the flexible recording disk of a diskette. The film base may be either a single layer, throughout which the beads are uniformly dispersed, or it may be multi-layer, e.g., a central layer containing the carbon black beads and two surface layers which are free from the beads.
    Type: Grant
    Filed: December 22, 1983
    Date of Patent: October 8, 1985
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Brenda L. Renalls, Douglas G. Pedrotty, John F. Donlan
  • Patent number: H506
    Abstract: Disclosed is a resinous composition having excellent discoloration, processability, heat resistancy and durability comprising,A. 100 parts by weight of an aromatic polyester having the general formulae (I) and (II) ##STR1## B. 0.01 to 5 parts by weight of a phosphoric compound, and C. 0.01 to 0.1 part by weight of a carboxylic acid metal salt. Also disclosed is a process for producing shaped articles, the improvement which comprises adding the additives stepwise to the aromatic polyester.
    Type: Grant
    Filed: April 17, 1987
    Date of Patent: August 2, 1988
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Masashiro Asada, Junji Takase
  • Patent number: RE32765
    Abstract: A polyester which when made into an article such as films, containers, bottles and the like has a very high clarity, a low haze value, and a neutral hue. In the preparation of the resin, an antimony catalyst is utilized along with small amounts of a bluing agent such as a cobalt compound and a phosphate compound with the phosphate compound generally being slightly in excess of an equivalent amount of the cobalt compound. The polyester is made from dicarboxylic acids and preferably aromatic acids such as terephthalic acid reacted with polyhydric alcohols.
    Type: Grant
    Filed: February 13, 1987
    Date of Patent: October 11, 1988
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Douglas D. Callander, Fred L. Massey