Solid Polymer Derived From Halogen-containing Reactant Patents (Class 524/7)
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Patent number: 10731079Abstract: A process for forming a flame retardant polymer, as well as the flame retardant polymer, are disclosed. A flame retardant polymer is a polymer that can be resistant to thermal degradation and/or thermal oxidation. A flame retardant polymer can be mixed or otherwise incorporated into a standard polymer to give flame retardancy to the standard polymer. The flame retardant polymers can include polycaprolactone functionalized with flame retardant substituents. The flame retardant substituents can include halides, substituted phosphoryl, and substituted phosphonyl.Type: GrantFiled: April 24, 2019Date of Patent: August 4, 2020Assignee: International Business Machines CorporationInventors: Eric J. Campbell, Sarah K. Czaplewski, Brandon M. Kobilka, Jason T. Wertz
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Publication number: 20140323359Abstract: A treatment fluid comprises: a base fluid; and at least one additive, wherein the additive: (i) comprises a fluorinated compound; and (ii) is a lubricant that is surface active. The additive can reduce the coefficient of friction between two or more surfaces. The surfaces can be the surface of a wellbore component. The additive can also be a corrosion inhibitor. A method of treating a portion of a well comprises: forming the treatment fluid; and introducing the treatment fluid into the well.Type: ApplicationFiled: April 24, 2013Publication date: October 30, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Kay A. MORRIS, Jay P. DEVILLE, Greg P. PEREZ
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Publication number: 20140316025Abstract: A gypsum composition for making lightweight blocks, panels, boards, coatings or other user defined shapes that are specially beneficial to the building construction industry. The novel gypsum composition comprises one to five volume percent starch; one to five volume percent crystalline silica; one to ten volume percent cellulose; ten to eighty volume percent gypsum; and ten to eighty volume percent Styrofoam particles, hard plastic particles, rubber particles or a combination thereof, wherein the particles have an average particle size in a range of about 15 to about 150 mesh. The particles can be from a virgin source, a recycled source or a combination thereof.Type: ApplicationFiled: April 19, 2013Publication date: October 23, 2014Inventor: Michael Rodgers
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Publication number: 20130146286Abstract: A self-adaptive cement formulation includes cement, water and thermoplastic block-polymer particles. The set cement demonstrates self-healing properties when exposed to methane, and is particularly suited for well-cementing applications. After placement and curing, the self healing properties help maintain zonal isolation should bonding be disrupted between the set cement and the formation or a casing string, should cracks or defects appear in the set-cement matrix, or both.Type: ApplicationFiled: July 5, 2011Publication date: June 13, 2013Inventors: Sylvaine Le Roy-Delage, Laure Martin-Al-Khatib
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Patent number: 8461233Abstract: A fiber-cement product which includes a treated cellulose wood pulp fiber. The fiber is treated with fibrillated carboxymethyl cellulose or a carboxyethyl cellulose and poly(diallyldimethyl ammonium)chloride. The fiber can be bleached or partially bleached, refined or unrefined or a mixture of refined and unrefined fiber.Type: GrantFiled: June 13, 2012Date of Patent: June 11, 2013Assignee: Weyerhaeuser NR CompanyInventors: S. Ananda Weerawarna, Harshadkumar M. Shah
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Publication number: 20130029050Abstract: A composition that may be used to retain moisture within fresh concrete as it cures to optimize the curing of the concrete may include one or more hardening and densifying agents and one or more temporary moisture sealing agents. Additionally such a composition may include a siliconate. The hardening and densifying agent of such a composition may penetrate the surface of fresh concrete to react with free lime, providing the fresh concrete with a strong surface. The temporary moisture sealing agent may form a moisture barrier on the surface of the fresh concrete to prevent moisture from escaping from the fresh concrete before the fresh concrete has sufficiently cured. The temporary moisture sealing agent may degrade within a matter of days, facilitating its removal from the surface of the concrete once the concrete has cured and enabling further treatment of the surface without undue delay.Type: ApplicationFiled: January 31, 2011Publication date: January 31, 2013Applicant: ADVANCED CONCRETE TECHNOLOGIES, LLCInventors: Dal N. Hills, Kent Barrus
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Publication number: 20120318174Abstract: A sealant composition may include a fly ash, hydrated lime, and at least one filler material selected from the group consisting of sand, barite, calcium carbonate, ground marble, iron oxide, manganese oxide, glass beads, crushed glass, crushed drill cuttings, ground vehicle tire, crushed rock, ground asphalt, crushed concrete, crushed cement, salt, ilmenite, hematite, silica flour, diatomaceous earth, a highly swellable clay miner, and any derivative thereof, and wherein the fly ash and hydrated lime together are present in an amount from about 0.25% to about 30% by weight of the sealant composition.Type: ApplicationFiled: August 30, 2012Publication date: December 20, 2012Inventors: Krishna M. Ravi, Gunnar Lende
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Patent number: 8299145Abstract: A method of producing a nonfoamed formed article of a vinyl chloride resin by mixing a hydrated water-containing gypsum powder and a vinyl chloride resin powder together, and heating the obtained mixture at a temperature lower than a temperature at which the vinyl chloride resin starts decomposing thereby to remove the hydrated water of the gypsum and to form the mixture. The method makes it possible to obtain a nonfoamed formed article free of defective appearance by directly adding the hydrated gypsum (specifically dihydrate gypsum) to the vinyl chloride resin without converting it to the anhydrous gypsum, without requiring wasteful energy cost, without causing foaming or defective forming stemming from the hydrated water and maintaining stability.Type: GrantFiled: December 23, 2011Date of Patent: October 30, 2012Assignee: Tokuyama CorporationInventors: Makoto Kataoka, Yasuto Yasuzawa, Yuusuke Shimahara
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Publication number: 20120205105Abstract: A self-adaptive cement formulation includes cement, water, block copolymer and asphaltite-mineral particles. The set cement demonstrates self-healing properties when exposed to methane, and is particularly suited for well-cementing applications. After placement and curing, the self-healing properties help maintain zonal isolation should bonding be disrupted between the set cement and the formation or a casing string, should cracks or defects appear in the set-cement matrix, or both.Type: ApplicationFiled: January 25, 2012Publication date: August 16, 2012Inventors: Sylvaine Le Roy-Delage, Laure Martin
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Publication number: 20120189794Abstract: PVC compositions, concrete composition including the PVC compositions, and reinforced concrete structures that contain the concrete compositions are described. Methods for manufacturing the reinforced concrete structures of the present technology, methods for repairing reinforced concrete structures having corroded rebar, and methods for reducing rebar corrosion in reinforced concrete structures are also described.Type: ApplicationFiled: January 26, 2011Publication date: July 26, 2012Inventor: Sung-Wei Chen
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Publication number: 20120167802Abstract: The present invention provides the composition of the modified RAP-recycled warm mix asphalt, whose composition is characterized as consisting of a mixed asphalt concrete mix, a cohesive agent, a recycling modifier, a plasticized warm mix additive, and if necessary, reinforcing agent will be added to the composition. The aforementioned composition can be mixed to produce the modified RAP-recycled warm mix asphalt. This invention is characterized in reusing a great portion of RAP compared to the less use in the existing practice. The use of a recycling modifier improves further better performance properties to extend the life cycle of recycled asphalt pavements, compared to the conventional virgin asphalt pavements as well as the existing recycling ones. The plasticized warm mix additives offer economic, social, and technical advantages by saving the fuel consumption required for production, reducing greenhouse gas emissions, and shorten traffic opening times.Type: ApplicationFiled: March 7, 2012Publication date: July 5, 2012Inventor: Jung Do HUH
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Publication number: 20120165433Abstract: A method of producing a nonfoamed formed article of a vinyl chloride resin by mixing a hydrated water-containing gypsum powder and a vinyl chloride resin powder together, and heating the obtained mixture at a temperature lower than a temperature at which the vinyl chloride resin starts decomposing thereby to remove the hydrated water of the gypsum and to form the mixture. The method makes it possible to obtain a nonfoamed formed article free of defective appearance by directly adding the hydrated gypsum (specifically dihydrate gypsum) to the vinyl chloride resin without converting it to the anhydrous gypsum, without requiring wasteful energy cost, without causing foaming or defective forming stemming from the hydrated water and maintaining stability.Type: ApplicationFiled: December 23, 2011Publication date: June 28, 2012Inventors: Makoto KATAOKA, Yasuto Yasuzawa, Yuusuke Shimahara
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Publication number: 20120157578Abstract: Methods and compositions are provided that relate to cement compositions comprising sub-micron calcium carbonate and latex. An embodiment includes a cement composition comprising: cement, water, sub-micron calcium carbonate having a particle size in a range of from greater than 100 nanometers to about 1 micron, and latex.Type: ApplicationFiled: February 28, 2012Publication date: June 21, 2012Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Rahul Chandrakant Patil, Abhijit Tarafdar, Abhimanyu Deshpande, Christopher L. Gordon
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Publication number: 20120029120Abstract: Disclosed are methods of removing particulate matter from potash tailings fluid. The invention includes providing an activating material capable of being affixed to the particulate matter, affixing the activating material to the particulate matter to form an activated particle, providing an anchor particle and providing a tethering material capable of being affixed to the anchor particle; and attaching the tethering material to the anchor particle and the activated particle to form a removable complex in the potash tailings fluid.Type: ApplicationFiled: July 26, 2011Publication date: February 2, 2012Inventors: David S. Soane, Nathan Ashcraft, Phyo Nyi Nyi Kyaw
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Publication number: 20110257303Abstract: The invention provides hydraulically setting sealing composition based on a) a hydraulically setting compound out of the group comprising high-alumina cement, ordinary portland cement, blast furnace slag, b) protective-colloide stabilized polymer of one or more ethylenically unsaturated monomers in form of an aqueous polymer dispersion or a water-redispersible polymer powder, and c) one or more fillers.Type: ApplicationFiled: December 17, 2009Publication date: October 20, 2011Applicant: Wacker Chemie AGInventors: Dimitrios Moussios, Jürgen Bezler, Mohammed Sanaobar
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Publication number: 20110257304Abstract: The invention relates to acid-resistant, hydraulically setting masses based on a) slag sand, b) one or more pozzolanas, c) one or more fillers, d) one or more polymers based on ethylenically unsaturated monomers, and water.Type: ApplicationFiled: December 15, 2009Publication date: October 20, 2011Applicant: Wacker Chemie AGInventors: Harald Zeh, Jürgen Bezler, Stefan Bonimeier, Armin Hoffman, Hermann Lutz
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Patent number: 8013029Abstract: Disclosed are a mortar for concrete mainly consisting of urethane foam and a method for manufacturing the same, in which urethane foam and Styrofoam used as insulating materials for household electronic appliances and a pre-cast panel are not discarded, but recycled such that the urethane foam and the Styrofoam are mixed with concrete in the construction of flooring of apartments or an ondol of houses. Low weight structure, superior sound-absorption effect and heat insulation effect can be obtained, and cracks are prevented from being generated in the constructed part. Construction work is simplified, and economical efficiency is enhanced. Collected waste urethane foam and waste Styrofoam are pulverized into a size of 1 to 10 mm using a pulverizer. The pulverized urethane foam and Styrofoam are mixed to each other to form urethane foam.Type: GrantFiled: November 9, 2007Date of Patent: September 6, 2011Inventor: Soon-Ok Shin
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Patent number: 7939592Abstract: Copolymers of ethylene and vinyl chloride also containing a protective colloid, optionally in conjunction with a fatty acid compound or precursor thereof or with an organosilicon compound, can be employed to increase the water repellency of hydraulically settable construction materials.Type: GrantFiled: October 21, 2009Date of Patent: May 10, 2011Assignee: Wacker Chemie AGInventors: Hans Peter Weitzel, Hermann Lutz
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Publication number: 20100212549Abstract: The present invention concerns a method for preparing materials containing binder systems derived from amorphous silica and bases as well as the materials prepared by the method. Relative to known methods, the present invention allows for a continuous production of material as the two components of the binder are brought onto into contact where the binder system is to be applied. The product achieved by the invention has a broad range of applications, such as for construction materials, insulating materials, fire proof materials, reinforcement materials etc. The present invention also relates to a method for preparing materials containing binder systems derived from amorphous inorganic material and bases as well as the materials prepared by the method.Type: ApplicationFiled: January 22, 2010Publication date: August 26, 2010Inventors: Kjeld HOLBEK, Erik Gydesen Sogaard
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Publication number: 20100041796Abstract: Copolymers of ethylene and vinyl chloride also containing a protective colloid, optionally in conjunction with a fatty acid compound or precursor thereof or with an organosilicon compound, can be employed to increase the water repellency of hydraulically settable construction materials.Type: ApplicationFiled: October 21, 2009Publication date: February 18, 2010Applicant: WACKER CHEMIE AGInventors: Hans Peter Weitzel, Hermann Lutz
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Publication number: 20090320720Abstract: A variety of methods and compositions are disclosed herein, including, in one embodiment, a method comprising: introducing a settable composition into a subterranean formation, wherein the settable composition comprises: a cementitious component comprising a hydraulic cement and cement kiln dust; a swellable particle; and water; and allowing the settable composition to set in the subterranean formation. Another embodiment comprises a settable composition comprising: a cementitious component comprising a hydraulic cement and cement kiln dust, a swellable particle, and water.Type: ApplicationFiled: September 11, 2009Publication date: December 31, 2009Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Craig W. Roddy, Jiten Chatterji, D. Chad Brenneis, Bobby J. King
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Publication number: 20090264556Abstract: A method of finishing an interior wall includes the steps of preparing a substrate of building panels comprising gypsum, cement or combinations thereof, said substrate having a surface, followed by applying a coating to the substrate, said coating comprising 5-20% by weight of a latex emulsion binder, 40-80% by weight calcium sulfate hemihydrate, 0.05-2% by weight of a set preventer and 20-60% by weight water.Type: ApplicationFiled: April 22, 2008Publication date: October 22, 2009Inventor: Lee K. Yeung
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Publication number: 20090155478Abstract: A method of producing a water resistant fibre-cement product. The water repelling agent can be added or applied to the fibre-cement or indeed the material forming the fibre cement at a number of different stages in the process. The resultant material has increased water impermeability over conventional fibre-cement products.Type: ApplicationFiled: November 13, 2008Publication date: June 18, 2009Inventor: Simon Trevethick
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Patent number: 7528184Abstract: A perfluoroelastomer composition comprises a perfluoroelastomer (e.g., tetrafluoroethylene/perfluoro(methyl vinyl ether) copolymer), an organic peroxide (e.g., 2,5-dimethyl-2,5-di(tert-butylperoxy)hexane and a scorch retarder (e.g., o-phenylphenol), and the perfluoroelastomer composition is excellent in processability and unlikely to scorch. Furthermore, a perfluoro rubber molded article obtained by thermal crosslinking of the perfluoroelastomer composition is excellent in rubber physical properties such as tensile strength and elongation at break and in a compression set property.Type: GrantFiled: August 18, 2006Date of Patent: May 5, 2009Assignee: Asahi Glass Company, LimitedInventors: Hiroshi Funaki, Makoto Honda, Masayuki Saito, Hiroki Kamiya
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Publication number: 20080287570Abstract: The present invention is directed to a heavy duty pavement structure comprising an open-graded asphalt layer fortified with a non-segregating grout mixture. The heavy duty pavement structure is made through the steps including forming an open-graded asphalt layer and then fortifying the layer with a non-segregating grout mixture that includes a predetermined amount of portland cement, sand and cement binder system.Type: ApplicationFiled: April 11, 2008Publication date: November 20, 2008Inventors: Jerry Alan Thayer, Ronald Lee Terrel, Gaylon L. Baumgardner, Geoffrey Michael Rowe, Eric Ferrall, Michael L. Costello
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Publication number: 20080171814Abstract: An alpha-halocarbo aromatic monomer or comonomer and/or an allyl halide monomer or comonomer can be reacted with aluminum or an aluminum-containing catalyst to form a polymer.Type: ApplicationFiled: August 20, 2007Publication date: July 17, 2008Inventors: Richard H. Hall, Daniel F. Hall
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Patent number: 7288580Abstract: Water-redispersible polymer powder compositions with accelerated-setting action based on homo- or copolymers of one or more monomers of vinyl esters of optionally branched C1-15 alkylcarboxylic acids, (meth)acrylic esters of C1-15 alcohols, vinylaromatics, olefins, dienes, and vinyl halides, one or more protective colloids, and optionally antiblocking agent(s), contain one or more setting-accelerants NR3, R2N—(CH2)n—NR2, or one or more singly or doubly NH2-terminated polyalkylene glycols having a C1-C6-alkylene group is/are present, where n=from 1 to 4, and where the radicals R are identical or different, and are hydrogen, a C1-C6-alkyl radical, or a C1-C6-hydroxyalkyl radical, where at least one radical R is a C1-C6-hydroxyalkyl radical, and wherein the setting-accelerants may optionally be present in the form of their salts.Type: GrantFiled: October 14, 2003Date of Patent: October 30, 2007Assignee: Wacker Polymer Systems GmbH & Co. KGInventor: Hans-Peter Weitzel
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Publication number: 20070204543Abstract: The present invention relates to the use of polymeric microparticles in hydraulically setting building material mixtures for the purpose of enhancing their frost resistance and cyclical freeze/thaw durability.Type: ApplicationFiled: March 24, 2006Publication date: September 6, 2007Applicant: ROEHM GMBH & CO. KGInventors: Jan Hendrik Schattka, Holger Kautz, Gerd Lohden
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Publication number: 20070193156Abstract: The present invention relates to the use of polymeric microparticles that are gas-filled in hydraulically setting building material mixtures for the purpose of enhancing their frost resistance and cyclical freeze/thaw durability.Type: ApplicationFiled: March 24, 2006Publication date: August 23, 2007Applicant: ROEHM GMBH & CO. KGInventors: Holger Kautz, Jan Hendrik Schattka, Gerd Lohden
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Publication number: 20070197671Abstract: The present invention relates to the use of polymeric microparticles having thin shells in hydraulically setting building material mixtures for the purpose of enhancing their frost resistance and cyclical freeze/thaw durability.Type: ApplicationFiled: March 24, 2006Publication date: August 23, 2007Applicant: ROEHM GBMH & CO. KGInventors: Jan Hendrik Schattka, Holger Kautz, Gerd Lohden
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Publication number: 20070197691Abstract: The present invention relates to the use of polymeric microparticles containing hydrolytically labile ionic emulsifiers in hydraulically setting building material mixtures for the purpose of enhancing their frost resistance and cyclical freeze/thaw durability.Type: ApplicationFiled: March 24, 2006Publication date: August 23, 2007Applicant: ROEHM GMBH & CO. KGInventors: Holger Kautz, Jan Hendrik Schattka, Gerd Lohden
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Publication number: 20070193159Abstract: The present invention relates to the use of different-sized polymeric microparticles in hydraulically setting building material mixtures for the purpose of enhancing their frost resistance and cyclical freeze/thaw durability.Type: ApplicationFiled: March 24, 2006Publication date: August 23, 2007Applicant: ROEHM GMBH & CO. KGInventors: Jan Hendrik Schattka, Holger Kautz, Gerd Lohden
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Patent number: 7241818Abstract: The present invention is a fly ash filler or filler blend having a particle size distribution with at least three modes that can be combined with a polymer or bitumen at higher filler loadings to produce a filled polymer or bitumen for composites that, in many cases, can produce improved mechanical properties for the composites over composites using conventional fillers. As a result, superior composites (e.g. those used in carpet backing) can be produced at a lower cost than conventional composites. The present invention also includes a method for producing a composite, comprising the steps of combining a polymer or bitumen with a fly ash filler or a filler blend having a particle size distribution with at least three modes to produce a filled polymer or bitumen and producing a composite with the resulting filled polymer or bitumen. The present invention further includes a method of determining what fly ashes can be used as fillers for composites.Type: GrantFiled: February 28, 2005Date of Patent: July 10, 2007Assignee: Boral Material Technologies, Inc.Inventors: Raymond T. Hemmings, Russell L. Hill, Bruce J. Cornelius
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Patent number: 7238736Abstract: The present invention provides a process for preparing a filled halobutyl elastomer, which includes mixing a halobutyl elastomer with at least one mineral filler and at least one phosphine modifier and optionally curing the filled elastomer with sulfur or other curative systems. Filled halobutyl elastomers prepared according to the present invention possess improved levels of filler dispersion which results in a reduction in the hardness of the compound and an increased tensile strength.Type: GrantFiled: April 29, 2004Date of Patent: July 3, 2007Assignees: LANXESS Inc., Queens University at KingstonInventors: John Scott Parent, Ralph Allen Whitney, Andrea Liskova, Rui Resendes
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Patent number: 7150787Abstract: A composition including two components is provided. When the two components are admixed in the method of the invention a polymer-modified gypsum composition is provided. The admixture exhibits a useful balance of setting time and stability.Type: GrantFiled: September 18, 2003Date of Patent: December 19, 2006Assignee: Rohm and Haas CompanyInventors: Guy Joseph Clamen, Bruno Pollet
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Patent number: 7148270Abstract: A method for providing a polymer-modified fiber-cement composite by forming an aqueous composition including admixing an emulsion polymer having a glass transition temperature (Tg) of from ?25° C. to 150° C., cement, cellulosic fibers, siliceous material, and water; forming a composite precursor by removal of at least some of the water; and curing/drying the composite precursor at a temperature at least 10° C. higher than the Tg of the polymer is provided. In an alternative embodiment the emulsion polymer is applied to the composite precursor. Polymer-modified fiber-cement composites formed by the method of the invention are also provided.Type: GrantFiled: May 15, 2003Date of Patent: December 12, 2006Assignee: Rohm and Haas CompanyInventor: Michael Damian Bowe
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Patent number: 6964986Abstract: An aqueous adhesive system consisting of two separate components, A and B. Component A is an aqueous dispersion of polymer containing at least one olefinically unsaturated double bond and Component B consists of a dispersion of a drying agent in an oil phase liquid. The adhesive produced by this system is useful for bonding material made of wood, cork, metal, plastic, stone and concrete.Type: GrantFiled: July 28, 2001Date of Patent: November 15, 2005Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thomas Bachon, Udo Frank Windhoevel, Thomas Tamcke, Hartmut Urbath, Sebastian Kostyra, Katja Raker
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Patent number: 6951686Abstract: A concrete article comprised of concrete having therein a reinforcing polymer that has a surface comprised of a thermoplastic hydroxy-functionalized polyether or polyester. The concrete article is made by mixing concrete, water and a reinforcing polymer that has a surface comprised of a thermoplastic hydroxy-functionalized polyether or polyester and curing said concrete mixture forming the concrete article.Type: GrantFiled: February 19, 2003Date of Patent: October 4, 2005Assignee: Dow Global Technologies Inc.Inventors: Aleksander J. Pyzik, Kenneth B. Stewart, Jr., John M. Beckerdite, Hari P. Reddy, Uday V. Deshmukh, Ted A. Morgan, Sharon M. Allen, Kwanho Yang, Nicholas M. Shinkel, David F. Pawlowski
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Patent number: 6869987Abstract: A settable composition which can be applied by spraying to form a coating on a surface such as the walls of a mine comprises (i) a cementitious composition comprising the following components: (a) from 25 to 95% of calcium aluminate, (b) from 0 to 10% of lien and (c) from 0 to 50% of calcium sulphate, and where the sum of (b) and (c) is at least 5% the % being by weight based on the combined weight of (a), (b) and (c) and where the proportions of the components are such that the composition on hydration is capable of absorbing at least its own weight of water and (ii) an aqueous emulsion of an organic polymer, the amount of (ii) in relation to (i) being such as to provide a weight ratio of polymer, expressed as solids, to combined weight of (a), (b) and (c) of from 0.5:1 to 10:1, preferably 1:1 to 2.5:1 or (iii) a dispersible organic polymer and where the amount of dispersible polymer is such as to give a weight ratio of polymer to combined weight of (a), (b) and (c) o from 0.5:1 to 10:1, preferably 1:1 to 2.Type: GrantFiled: March 12, 2002Date of Patent: March 22, 2005Assignee: Minova International LimitedInventors: Peter Shelley Mills, David Neil Degville, Aj Rohaly
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Patent number: 6867249Abstract: The present invention relates to a process for manufacturing a construction material by mixing a cementitious material, rubber bits and water. It also extends to a construction material comprising cured cementitious material and rubber bits in which the rubber bits are bonded together in a porous and permeable matrix by the cementitious material. An elastic binding material improves the physical properties of the construction material. The construction material can be cast in place or formed into blocks for transport to a construction site.Type: GrantFiled: December 12, 2002Date of Patent: March 15, 2005Inventor: Kin Man Amazon Lee
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Patent number: 6730722Abstract: The invention provides cross-linkable polymer powder compositions containing a) at least one water-soluble polyhydroxy compound; b) at least one boric acid complex compound which is of limited solubility in water that is, it has a water solubility of less than 10 g per liter at normal conditions; and optionally c) a water-soluble film-forming polymer consisting of one or more free-radical polymerizable, ethylenically unsaturated monomers. The compositions are useful as a constituent in adhesives, plaster, jointing mortars, paints and binders for coating compositions, textiles, paper and the like.Type: GrantFiled: February 2, 2001Date of Patent: May 4, 2004Assignee: Wacker-Chemie GmbHInventors: Herbert Eck, Hans Donislreiter
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Patent number: 6649671Abstract: A concrete article is prepared by mixing concrete, water and a reinforcing polymer comprised of a substantially random interpolymer of at least one &agr;-olefin, with at least one vinyl or vinylidene aromatic monomer and curing said concrete mixture to form a concrete article having the reinforcing polymer therein, such that the reinforcing polymer has a surface comprised of the substantially random interpolymer in contact with the concrete.Type: GrantFiled: March 12, 2001Date of Patent: November 18, 2003Assignee: Dow Global Technologies Inc.Inventors: Aleksander J. Pyzik, Ted A. Morgan, Kenneth B. Stewart, Jr.
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Patent number: 6646093Abstract: Water-soluble polyurethane according to the present invention is obtained from polyalkylene glycols, diisocyanates, and comb-shaped hydrophobic diols represented by the following general formula (3): wherein each of R1, R2 and R3 is a hydrocarbon group; each of Y and Y′ is hydrogen, a methyl group or a CH2Cl group; each of Z and Z′ is oxygen, sulfur or a CH2 group; n is an integer of 0 to 15 when Z is oxygen and is 0 when Z is sulfur or a CH2 group; n′ is an integer of 0 to 15 when Z′ is oxygen and is 0 when Z′ is sulfur or a CH2 group. The water-soluble polyurethane is used as, for example, an extruding auxiliary for cement materials, a mortar thickening agent, an underwater concrete thickening agent, a ceramics forming binder and a moisturizer for hair cosmetics, all of which are characterized by excellent water retention and high shape retention.Type: GrantFiled: December 12, 2000Date of Patent: November 11, 2003Assignee: Mitsui Chemicals, Inc.Inventors: Manabu Tsuruta, Masahiko Mitsuzuka, Yunzhi Wu
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Patent number: 6593402Abstract: The present invention provides improved compositions and methods for sealing pipe in a well bore. The compositions which harden into highly resilient solid masses having high strengths are basically comprised of a hydraulic cement, an aqueous rubber latex, an aqueous rubber latex stabilizing surfactant and silica hydrophobicized with silicon oil.Type: GrantFiled: February 6, 2001Date of Patent: July 15, 2003Assignee: Halliburton Energy Services, Inc.Inventors: Jiten Chatterji, Roger S. Cromwell, Baireddy R. Reddy, Bobby J. King
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Patent number: 6537366Abstract: A composition for coloring concrete and methods for making the composition is provided, which includes a hydrophobic efflorescence control agent selected from the group consisting of calcium stearates, zinc stearates, sodium stearates, butyl stearate, stearic acid derivatives, stearic acid salts, and a mixture thereof, a particulated polymer selected from the group consisting of styrene-based polymers and copolymers, acrylic-based polymers and copolymers, polyvinyl acetates, polyepoxides, polyurethanes, butadiene rubbers, and a mixture thereof; and a colorant, wherein the composition improves the durability of the concrete while enhancing the durability and retention of said colorant.Type: GrantFiled: December 26, 2000Date of Patent: March 25, 2003Assignee: Color & Chemical Technologies, Inc.Inventor: William W. Supplee, Sr.
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Patent number: 6455615Abstract: This invention provides a flexible polymer modified waterproofing cement material which can be used on a substrate or in concealed areas of construction engineering, water conservancy projects, municipal works, and its making process. The waterproofing material is made by kneading a hydraulic cement, a polymer dispersion, a water-soluble polymer or re-dispersible resin and water at a weight ratio of cement/polymer of about 100:15 to about 100:150 under conditions of about 25° C. to about 120° C., about 20 rpm to about 80 rpm until the water content of the kneaded materials reaches about 5% to about 20%. The kneaded material is mixed with a toughening polymer at a weight ratio of about 100:10 to about 100:50, then is calendered into sheets. These materials can adhere to dry or wet substrates firmly. They can be used in cold or hot and wet climate areas. After application, the waterproofing structure formed can bear retractive stress and deformation of the base or can resist outer impact.Type: GrantFiled: January 12, 2001Date of Patent: September 24, 2002Assignee: Tianjin Building Materials Science Research InstituteInventors: Ji Guang Yu, Dong Xia, Lei Zhu, Yu Qing Guo, Peng Chen
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Patent number: 6429239Abstract: The invention concerns a dispersion powder composition which is redispersible in water and is made from water-insoluble organic polymers, the composition being characterized in that it contains 0.1 to 30% by wt., relative to the weight of the organic polymers, of one or more silicon compounds which are dispersible in water and which have a boiling point at normal pressure of 160 degrees C., selected from the group comprising the silanes, polysilanes, oligosiloxanes, carbosilanes, polycarbosilanes, carbosiloxanes, polycarbosiloxanes and polysilylenedisiloxanes. The invention also concerns methods for manufacturing such compounds and their use.Type: GrantFiled: August 16, 2000Date of Patent: August 6, 2002Assignee: Wacker-Chemie GmbHInventors: Herbert Eck, Klaus Adler, Heinrich Hopf, Franz Jodlbauer, Dieter Gerhardinger
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Publication number: 20010047045Abstract: A concrete article is prepared by mixing concrete, water and a reinforcing polymer comprised of a substantially random interpolymer of at least one &agr;-olefin, with at least one vinyl or vinylidene aromatic monomer and curing said concrete mixture to form a concrete article having the reinforcing polymer therein, such that the reinforcing polymer has a surface comprised of the substantially random interpolymer in contact with the concrete.Type: ApplicationFiled: March 12, 2001Publication date: November 29, 2001Inventors: Aleksander J. Pyzik, Ted A. Morgan, Kenneth B. Stewart
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Patent number: 6176921Abstract: A cement dispersant composed of water-soluble vinyl copolymers which include specified kinds of constituent units at specified ratios and of which the weight average molecular weight pullulan converted by GPC method is 15000-150000 and the ratio of weight average molecular weight to number average molecular weight is 2-7 is used together with cement, aggregates and water to produce concrete with the water-to-cement ratio of 20-45%.Type: GrantFiled: February 17, 1999Date of Patent: January 23, 2001Assignee: Takemoto Yushi Kabushiki KaishaInventors: Mitsuo Kinoshita, Kazuhisa Okada, Masahiro Iida
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Patent number: RE37655Abstract: An additive for, a method of adding thereof to uncured mixes for and resulting cured cement-type concreations such as cured embodiments of concrete, marcadam, and roof-top shingles each exhibiting improved heat and freeze-thaw durability resulting from reduced efflorescence and stability against sun ultraviolet light exposure.Type: GrantFiled: August 19, 2000Date of Patent: April 16, 2002Inventor: William W. Supplee