Abstract: An ultraviolet ray curable ink composition adapted to be ejected by using an ink jet method is provided. The ultraviolet ray curable ink composition includes a polymerizable compound, metal powder, and a liquid component having an alicyclic structure including a hetero atom. The metal powder is constituted from metal particles subjected to a surface treatment with a fluorine type silane compound and/or a fluorine type phosphoric acid ester as a surface treatment agent. An amount of the liquid component contained in the ultraviolet ray curable ink composition is in the range of 0.05 mass % or more but 7.0 mass % or less. A printed object is also provided. Such a printed object is produced by using the ultraviolet ray curable ink composition.

Abstract: The present invention relates to a flexible polyurethane coating composition for application, preferably by spraying, to a substrate to protect and or improve the properties of the substrate. Specifically, the coating composition is a reactive polyurethane formulation which forms an elastomeric polyurethane coating with improved flammability properties. The reactive formulation comprises an A side comprising an isocyanate prepolymer with optional flame retardant compounds and a B side comprising a dispersion of red phosphorous, with optional additional flame retardant compounds, in an aromatic polyester polyol.

Abstract: A composition which comprises polylactide and has excellent heat stability, color and hydrolytic resistance. The composition comprises (i) polylactide, (ii) a metal catalyst and (iii) a hypophosphorous acid-based deactivator or a metaphosphoric acid-based deactivator.

Abstract: Disclosed is a fluorine-containing polymer aqueous dispersion in which a fluorine-containing polymer is dispersed using, as an emulsifier, a polyfluoroalkylphosphonic acid salt represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OM1)(OM2)??[I], wherein M1 is a hydrogen atom, an alkali metal, an ammonium base, or an organic amine base, M2 is an alkali metal, an ammonium base, or an organic amine base, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3. This fluorine-containing polymer aqueous dispersion uses a polyfluoroalkylphosphonic acid salt with a low bioaccumulation potential as an emulsifier, and has excellent mechanical stability.

Abstract: A process for manufacturing a dispersions of a vinylidene fluoride (VDF) thermoplastic polymer [polymer (F)], said process comprising polymerizing VDF in an aqueous phase comprising: at least one surfactant selected from the group consisting of non-fluorinated surfactants [surfactant (HS)] and fluorinated surfactants having a molecular weight of less than 400 [surfactant (FS)]; and at least one functional (per)fluoropolyether (functional PFPE) comprising at least one (per)fluoropolyoxyalkylene chain [chain (R?F)] and at least one functional group, said functional PFPE having a number average molecular weight of at least 1000 and a solubility in water of less than 1% by weight at 25° C., wherein said functional PFPE is present in the aqueous phase in an amount of 0.001 to 0.3 g/l.

Abstract: Disclosed is a polymerizable composition for optical materials containing (a) an aromatic isocyanate, (b) a mercapto group-containing compound, and (c) a phosphorus-containing compound represented by the following general formula (1). (O?)nP—X3 ??(1) (wherein n represents an integer of 0 or 1. X represents a substituted or unsubstituted straight or branched alkyl group having 1 to 6 carbon atoms or the like. In the case where X is a substituted group, the substituted group represents a halogen atom or the like.

Abstract: An emulsion polymerization process for the production of fluoroelastomers is disclosed wherein at least one fluorosurfactant is employed as dispersant, said fluorosurfactant being a fluoroalkylphosphoric acid ester of the formula X—Rf-(CH2)n—O—P(O)(OM)2, wherein n=1 or 2, X=H or F, M=a univalent cation, and Rf is a C4-C6 fluoroalkyl or fluoroalkoxy group. Optionally, a second dispersing agent may be employed in the polymerization, said second agent being a perfluoropolyether having at least one endgroup selected from the group consisting of carboxylic acid, a salt thereof, sulfonic acid and a salt thereof, phosphoric acid and a salt thereof.

Abstract: A urethane based polymer composition is provided that exhibits superior shielding properties during and after exposure to high level radiation. The composite is formed by mixing a liquid isocyanate monomer, preferably 4,4?-diisocyanate monomer with a liquid phenolic resin, preferably phenol formaldehyde resin, and a phosphate ester flame retardant. An optional pyridine catalyst may be added to shorten the cure time. The resulting composition cures at room temperature and can be utilized in several manners, including spraying or pouring the composition prior to curing over radioactive material to prevent leakage of radiation. The uncured composite can be sprayed on the walls of a room or container to prevent leakage of radiation and can also be used to contain radiation prior to demolition. The uncured composite can also be molded into bricks or panels for use in construction.

Abstract: A urethane based polymer composition is provided that exhibits superior shielding properties during and after exposure to high level radiation. The composite is formed by mixing a liquid isocyanate monomer, preferably 4,4′-diisocyanate monomer with a liquid phenolic resin, preferably phenol formaldehyde resin, and a phosphate ester flame retardant. An optional pyridine catalyst may be added to shorten the cure time. The resulting composition cures at room temperature and can be utilized in several manners, including spraying or pouring the composition prior to curing over radioactive material to prevent leakage of radiation. The uncured composite can be sprayed on the walls of a room or container to prevent leakage of radiation and can also be used to contain radiation prior to demolition. The uncured composite can also be molded into bricks or panels for use in construction.

Abstract: A urethane based polymer composition is provided that exhibits superior shielding properties during and after exposure to high level radiation. The composite is formed by mixing a liquid isocyanate monomer, preferably 4,4′-diisocyanate monomer with a liquid phenolic resin, preferably phenol formaldehyde resin, and a phosphate ester flame retardant. An optional pyridine catalyst may be added to shorten the cure time. The resulting composition cures at room temperature and can be utilized in several manners, including spraying or pouring the composition prior to curing over radioactive material to prevent leakage of radiation. The uncured composite can be sprayed on the walls of a room or container to prevent leakage of radiation and can also be used to contain radiation prior to demolition. The uncured composite can also be molded into bricks or panels for use in construction.

Abstract: A curable dental restorative composition comprising about 1 to about 90 wt %, based on the total weight of the composition, of a filler component, the filler component comprising about 10 to 100 wt %, based on the total weight of the filler component, of a surface reactive glass component; about 1 to about 50 wt %, based on the total weight of the composition, of water; and about 10 to about 97 wt %, based on the total weight of the composition, of a curable organic component, comprising about 50 to about 99 wt %, based on the total weight of the curable organic component, of an ethylenically unsaturated resin component, about 1 to about 50 wt %, based on the total weight of the curable organic component, of an ethylenically unsaturated phosphoric acid ester; and about 0.01 to about 5 wt % of a curing system.

Abstract: Disclosed is a cis-bridged metal complex of the formula (I) where R5 is an electron-withdrawing radical, and catalyst systems based on these complexes for copolymerizing carbon monoxide and olefinically unsaturated compounds.

Abstract: The catalyst systems comprise as active constituentsa) a metal complex of the formula (I) ##STR1## b) one or more Lewis or protic acids or a mixture of Lewis and protic acids.

Abstract: The invention relates to compositions for flame-retardant cast panels made of (meth)acrylic polymers.The composition comprises at least one (meth)acrylic ester monomer, (meth)acrylic acid and at least one phosphorus compound which is anhydrous and is chosen from phosphoric acids, phosphoric acid esters or their mixtures, optionally in combination with an optionally halogenated neutral phosphoric ester. The amount of (meth)acrylic acid and of phosphorus compound, by weight with respect to the total mixture constituting the composition, is such that the flame-retardancy coefficient FRC: ##EQU1## is greater than 0.95.

Abstract: A process for the copolymerization of carbon monoxide with ethene and optionally another olefinically unsaturated compound in which process the monomers are copolymerized in the presence of a liquid diluent and a catalyst composition which is based on(a) a Group VIII metal compound,(b) an anion of an acid which is obtainable by combining a Br.o slashed.nsted acid with a Lewis acid, and(c) an organic oxidant in a quantity of less than 30 moles per mole of Group VIII metal.

Abstract: Linear alternating copolymers of carbon monoxide and at least one compound containing an alkenyl unsaturation are obtained by reaction between carbon monoxide and at least one compound containing an alkenyl unsaturation, in a solvent which is liquid under the operating conditions, in the presence of a preformed bischelated catalyst having general formula (I) active without cocatalysts:?Pd(chel)(chel')!.sup.++ ?A.sup.- !.sub.2 (I)wherein: chel and chel', the same or different, represent a nitrogenated or phosphorated bidentate chelating agent, and A.sup.- represents an essentially non-co-ordinating, non-esterifiable and non-labile anion selected from (3,5-(CF.sub.3).sub.2 -C.sub.6 H.sub.3).sub.4 B.sup.-, tetra(perfluorophenyl)borate B(C.sub.6 F.sub.5).sub.4.sup.- and Al(C.sub.6 F.sub.5).sub.4.sup.-.

Abstract: An improved process is described for the preparation of alternating linear copolymers based on carbon monoxide and at least one compound containing an alkenyl unsaturation which comprises reacting in a liquid solvent under the operating conditions, a mixture of carbon monoxide and one or more compounds containing an alkenyl unsaturation in the presence of:(i) a catalyst having general formula (I)?Pd(chel) (chel') !.sup.++ ?A.sup.- !.sub.2 (I)wherein chel and chel' the same or different, represent a nitrogenated or phosphorated bidentate chelating agent, and A.sup.- represents an essentially non-coordinating, non esterifiable and non labile anion of an acid with pKa less than 2; and(ii) a cocatalyst having general formula (II)?chel"H.sup.+ !?A'.sup.- ! (II)wherein A'.sup.-, the same as or different from A.sup.-, has the same meaning defined above and chel" represents a nitrogenated bidentate chelating agent the same as or different from chel and chel'.

Abstract: A curable resin composition comprising:(A) a compound having at least one curable acrylic radical, methacrylic radical or vinyl radial, or a mixture thereof;(B) an organic solvent containing an alcoholic organic solvent with an amount of not less than 40% by weight;(C) a compound having at least one pentavalent P with phosphoryl bonding; and(D) a polymerization initiator whichwhen coated on the surface of molded inorganic or organic materials, the coating shows superiority in curing under atmosphere and the cured composition has excellent adhesion, surface hardness, resistance to scratch, resistance to abrasion, surface luster, transparency and antistatic property.

Abstract: Rigid polyurethane-modified polyisocyanuate compositions having improved physical properties are obtained by curing thermosettable compositions containing alkoxylated aromatic compounds, organic polyisocyanates and cyclic alkylene carbonates using an isocyanate trimerization catalyst. The use of an alkoxylated aromatic compound permits a reduction in the proportion of organic polyisocyanate required to achieve satisfactory tensile strength and stiffness. The cured compositions are useful for the production of composites as well as molded articles containing reinforcing fillers.

Abstract: Included are the title phosphorate compounds, and a process to prepare them comprising contacting a carbylphosphorate mono acid halide with a carbyloxide. For example, ((2-(3-bromo-2,2-bis(bromomethyl)propoxy)ethyl(chloroethyl)-(ethyl))phosph orate can be prepared with (2-(3-bromo-2,2-bis(bromomethyl)propoxy)ethyl)(ethyl)-chloridophosphorate and ethylene oxide. The compounds are useful so-called flame-retardants for polyurethanes, especially flexible foams because, for example, substantially non-scorching and non-odoriferous flame-retardant flexible foams can be readily prepared with the compounds.

Abstract: This invention is an antistatic thermoplastic, phase-segregated polyurethane containing, as an antistatic additive an effective amount of a monovalent metal tetraphenylboron salt, in the substantial absence of a fatty acid salt, a C.sub.6 -C.sub.30 carboxylic acid ester or phosphate ester compound.Suprisingly, it has been found that, with this particular type of polyurethane, tetraphenylboron salts are very effective antistatic additives even in the absence of enhancer compounds as were previously employed. Accordingly, the antistatic polyurethane is useful for applications such as electronics components and packaging, and other applications where static dissipative ability is needed or desirable.

Abstract: A single-component polyurethane coating mass, applicable in a dry layer up to 2000 microns thick, containing a mixture of 50 to 67 wt. % of an aromatic di- or polyisocyanate as the isocyanate component.

Abstract: Fluid polymer polyol dispersions which impart improved fire resistance to polyurethane foam. The fluid polymer polyol dispersions are prepared by grafting one or more monomers onto a polyol backbone with the difference that the grafting takes place in the presence of a flame retardant. During the grafting process the flame retardant is incorporated into the fluid polymer polyol dispersion. When such fluid polymer polyol dispersions are used, the fire resistance of the final polyurethane foam is improved relative to cases where a conventional fluid polymer polyol dispersion and a flame retardant are added separately to the polyurethane foam formulation.

Abstract: An antistatic additive for polymers, particularly polyurethanes, is disclosed. The additive comprises an ionizable metal salt of a fluoroalkyl sulfonic acid and an enhancer. The enhancer is generally a salt or ester of a carboxylic acid or a phosphate ester.

Abstract: Flame-retardant polyurethane products are produced by mixing and reacting a basic salt-forming compound with an acidic salt-forming compound containing phosphorus and/or halogen compounds in a polyol and/or a polyisocyanate, then reacting the polyol and polyisocyanate.The flame-retardant polyurethane products may be used for thermal and sound insulation, as a coating agent, as an adhesive, for caulking, for cushioning and for molding useful objects.

Abstract: An aromatic, isocyanate-base, polyurethane polymer and a process for preparing the polymer. The process comprises reacting, such as by spraying onto a substrate or an open mold, a caprolactone polyol with a methylene dipara phenylene isocyanate in the presence of a catalytic amount of a metallo catalyst, and a fast-curing and cross-linking amount of a curing agent comprising a polyalkanol amine, particularly a triethanol amine, to provide a fast-reaction aliphatic poilyurethane polymer. The reaction of difunctional caprolactone polyols with low functionality MDI in the presence of a tin catalyst and triethanol amine provides for flexible and rigid polymer films of substantially no porosity.

Abstract: An aliphatic, isocyanate-base, polyurethane polymer and a process for preparing the polymer. The process comprises reacting, such as by spraying onto a substrate or an open mold, a caprolactone polyol with an aliphatic isocyanate in the presence of a catalytic amount of a metallo catalyst, and also in the presence of a fast-curing amount of a curing agent comprising an amine, particularly a triethanol amine, to provide a fast-reaction aliphatic urethane polymer which is a clear, easily color-pigmented polymer.

Abstract: A liquid composition is provided suitable for use as a flame retardant additive for polyurethane foams. The composition overcomes the problems of high viscosity and precipitates forming in formulations of phosphate esters and polybromodiphenyl oxides and avoids scorch and smoldering while preparing polyurethane foams meeting the California 117 standard. In addition, the composition provides an unexpected advantage of improved efficacy and heat stability. The process for preparing the flame retarded polyurethane foam and the foam itself are also claimed.

Abstract: An aliphatic, isocyanate-base, polyurethane polymer and a process for preparing the polymer. The process comprises reacting, such as by spraying onto a substrate or an open mold, a caprolactone polyol with an aliphatic polyisocyanate in the presence of a catalytic amount of a metallo catalyst, and also in the presence of a fast-curing amount of a curing agent comprising an amine, particularly an aromatic diamine, such as diethyl toluene diamine, to provide a fast-reaction aliphatic polyurethane polymer.

Abstract: A method for the preparation of a molded reaction injection molded rigid non-cellular polyisocyanurate polymer composition by injecting at least two streams into the mold cavity of a RIM machine to react at temperatures of from about ambient to about 140.degree. C. a formulation comprising at least one stream of an organic di- or polyisocyanate and in a second stream a cyclic alkylene carbonate and a soluble adduct of a tertiary amine and a cyclic alkylene carbonate as catalyst.

Abstract: Included are the title phosphorate compounds, and a process to prepare them comprising contacting a carbylphosphorate acid halide with a carbyloxide. For example, (3-chloro-2,2-bis(bromomethyl)propyl)bis(ethyl)phosphorate can be prepared with 3,3-bis(bromomethyl)oxetane and bis(ethyl)chloridophosphorate. The compounds are useful flame retardants for polyurethanes, especially flexible foams because, for example, substantially non-scorching and non-odoriferous flame-retardant flexible foams can be readily prepared with the compounds. Also included is a method for inducing scorch in polyurethanes, which can be used to generally determine polyurethane formulations which are prone to not scorch in commercial production.

Abstract: A high modulus polyurethane elastomer having improved combustion resistance and satisfactory physical properties comprising the reaction product of a polyol or polymer polyol, a low molecular weight chain extender, a liquid organic polymeric isocyanate having an average functionality of at least about 2.4 and a defined concentration of flame retardant.

Abstract: An antistatic agent for polymers, particularly polyurethanes is disclosed comprising an ionizable metal salt and an enhancer comprising a phosphate ester.

Abstract: Means for the sustained release of an active agent into the environment comprise an elastomeric matrix and the active agent contained in the matrix. The matrix material has a modulus between about 10.sup.4 Pa and about 10.sup.8 Pa at 23.degree. C., and a glass transition temperature less than 0.degree. C. The matrix comprises polyurethane formed by reacting polyol and isocyanate, and the active agent can be any biologically or nonbiologically active agent that is compatible with the matrix, e.g., the insecticide 2,2' dichlorovinyl dimethyl phosphate. The inventive sustained release system has particularly advantageous release properties, e.g., it typically can release more than 70% of the active agent contained in the matrix.

Abstract: A polyester composition with an excellent high-speed melt-spinning property, comprising(A) 100 parts by weight of a matrix polyester resin comprising at least 80 molar % of an ethylene terephthalate recurring unit, and(B) 0.2 to 7 parts by weight of a dispersoid dispersed in the matrix,the dispersoid being such that, when it is contained in a predetermined amount (w) in a typical matrix polyester resin consisting of a polyethylene terephthalate having an intrinsic viscosity of 0.640, the resultant exemplary polyester composition satisfies the relationship (I): ##EQU1## wherein: .gamma..sub.1 =shearing rate of 0.01 sec.sup.-1 ; .gamma..sub.2 =shearing rate of 5.0 sec.sup.-1 ; .eta..gamma..sub.1 (w)=melt viscosity (poise=1/10 N.multidot.sec.multidot.m.sup.-2) of the exemplary polyester composition at .gamma..sub.1 ; .eta..gamma..sub.1 (0)=melt viscosity of matrix polyester resin at .gamma..sub.1 ; .eta..gamma..sub.2 (w)=melt viscosity of the exemplary polyester composition at .gamma..sub.2 ; and .eta..gamma..

Abstract: This invention is directed to a polyurethane product produced by a one step process, in the absence of a polymerization catalyst, with reactants, and additives, if any, being initially intermingled in the ambient room temperature range and reacted with intermingling in the absence of externally added heat. The reactants are (1) aliphatic, aromatic, or cycloaliphatic having at least two isocyanate groups and (2) diol/polyol compounds having at least two sterically unhindered hydroxyl groups. The product is a liquid, homogeneous adhesive material characterized by a natural absence of polymerization catalyst residue and capable of being cured because of the presence of unreacted isocyanate groups, the isocyanate reactant being charged in excess of the stoichiometric requirement of the diol/polyol reactant.