Containing Hetero Chalcogen Dnrm Patents (Class 524/719)
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Patent number: 10604653Abstract: Disclosed is an active energy ray curable hot melt silicone composition that is non-flowable at 25° C. and has a viscosity of 1,000 Pa·s or less at 100° C. The active energy ray curable hot melt silicone composition comprises: (A) a mixture of (A1) an organopolysiloxane having an aliphatic unsaturated bond-containing organic group and (A2) an organopolysiloxane optionally having an aliphatic unsaturated bond-containing organic group, (B) a compound having at least two mercapto groups in a molecule, and (C) a photoradical initiator. A cured product and a method of making a film are also disclosed.Type: GrantFiled: October 12, 2016Date of Patent: March 31, 2020Assignee: Dow Toray Co., Ltd.Inventors: Ryota Dogen, Haruna Yamazaki, Shin Yoshida, Makoto Yoshitake
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Patent number: 8933168Abstract: There is provided a cyanoacrylate composition comprising: a cyanoacrylate; and a 2-substituted benzothiazole or a derivative thereof wherein the 2-substituent is an alkyl, an alkene, an alkylbenzyl, an alkylamino, an alkoxy, an alkylhydroxy, an ether, a sulfenamide, a thioalkyl or a thioalkoxy group, with the proviso that an amide portion of the sulfenamide does not have a tert butylamino or a morpholine group.Type: GrantFiled: April 20, 2011Date of Patent: January 13, 2015Assignee: Henkel IP & Holding GmbHInventors: William Hally, Emer Ward, Patricia A. Hedderman, Deborah A. Moore, Dermot F. Heatley
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Patent number: 8759443Abstract: The invention relates to a curable composition comprising: at least one benzoxazine and at least one toughening additive which can be bound to the at least one benzoxazine in the curing process, characterized in that the toughening additive is distributed in the cured composition in form of discrete domains, and that at least 50% of the discrete domains related to the total amount of discrete domains have a maximum length in any direction of space in the range of 10 nm to 500 nm as determined by transmission electron microscopy (TEM).Type: GrantFiled: April 23, 2010Date of Patent: June 24, 2014Assignees: Henkel AG & Co. KGaA, Henkel IP & Holding GmbHInventors: Andreas Taden, Stefan Kreilling, Rainer Schoenfeld, Stanley Leroy Lehmann
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Publication number: 20140057048Abstract: Ionic liquid (IL)-mediated sol-gel hybrid organic-inorganic materials present enormous potential for effective use in analytical microextraction. One obstacle to materializing this prospect arises from high viscosity of ILs significantly slowing down sol-gel reactions. A method was developed which provides phosphonium-based, pyridinium-based, and imidazolium-based IL-mediated advanced sol-gel organic-inorganic hybrid materials for capillary microextraction. Scanning electron microscopy results demonstrate that ILs can serve as porogenic agents in sol-gel reactions. IL-mediated sol-gel coatings prepared with silanol-terminated polymers provided up to 28 times higher extractions compared to analogous sol-gel coatings prepared without any IL in the sol solution.Type: ApplicationFiled: October 4, 2013Publication date: February 27, 2014Applicant: UNIVERSITY OF SOUTH FLORIDAInventors: Abdul Malik, Anne M. Shearrow
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Patent number: 8580875Abstract: An improved aqueous acrylic emulsion pressure sensitive adhesive (PSA) composition of improved sheer strength includes an aqueous acrylic emulsion including at least one hydrophobic monomer, at least one hydrophilic monomer, and at least one hydrogen bonding monomer; and a peel control additive. The PSA composition is substantially devoid of phosphate-based surfactants.Type: GrantFiled: December 12, 2007Date of Patent: November 12, 2013Assignee: Ashland Licensing and Intellectual Property LLCInventors: Kang I. Lee, Keith D. King
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Publication number: 20130137018Abstract: The invention provides a dye compound having a partial structure represented by the following formula (5): wherein in formula (5), Dye represents a dye structure; G1 represents NR or an oxygen atom; G2 represents a monovalent substituent group having an ?Es? value as a steric parameter of 1.5 or more; p represents an integer from 1 to 8; when p is 2 or greater, the two or more structures represented by p may be the same or different from each other; and R represents a hydrogen atom or a monovalent substituent group.Type: ApplicationFiled: January 22, 2013Publication date: May 30, 2013Applicant: FUJIFILM CORPORATIONInventor: FUJIFILM CORPORATION
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Patent number: 8318836Abstract: Curing agents for air-drying alkyd-based resins, coatings, such as paint, varnish or wood stain, inks and linoleum floor coverings, based on an iron/manganese complex containing tetradentat, pentadentate or hexadentate nitrogen donor ligands are disclosed.Type: GrantFiled: July 29, 2011Date of Patent: November 27, 2012Assignee: OMG UK Technology LimitedInventors: Ronald Hage, Philana Veronica Wesenhagen
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Patent number: 8013044Abstract: The present invention relates to a curing agents for air-drying alkyd-based resins, coatings, such as paint, varnish or wood stain, inks and linoleum floor coverings, based on an iron/manganese complex containing tetradentate, pentadentate or hexadentate nitrogen donor ligands.Type: GrantFiled: June 29, 2007Date of Patent: September 6, 2011Assignee: Conopco, Inc.Inventors: Ronald Hage, Philana Veronica Wesenhagen
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Publication number: 20110144271Abstract: The present invention aims to provide a radiation-curing liquid resin composition for optical tridimensional modeling having good storage stability. The suitable radiation-curing liquid resin composition for optical tridimensional modeling of the present invention includes a compound represented by the below general formula (1), a compound having phenolic hydroxyl group, a cationic polymerizable compound, a radical polymerization initiator, a radical polymerizable compound, one or more sulfur compound selected from the group consisting of 2-mercaptobenzothiazole, 2-(4-morpholinodithiobenzothiazole, diisopropylxantogendisulfide and diphenyldisulfide, a polyether polyol compound.Type: ApplicationFiled: June 16, 2006Publication date: June 16, 2011Applicant: JSR CORPORATIONInventors: Katsuyuki Takase, Takayoshi Tanabe, Noriyasu Shinohara
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Patent number: 7074851Abstract: The invention relates to a process for preparing stabilized compositions based on polyamide. The stabilizer is a phosphorus stabilizer selected from phosphorous acid and hypophosphorous acid. It is introduced before or during the polymerization of the polyamide. The use of these stabilizers prevents foaming phenomena.Type: GrantFiled: December 21, 2001Date of Patent: July 11, 2006Assignee: Nylstar S.A.Inventors: Thierry Charbonneaux, Jean-François Thierry
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Patent number: 6617378Abstract: A golf ball coating composition is obtained by incorporating in a base resin paint a fluorescent whitening agent which is a 7-triazinylamino-3-phenylcoumarin derivative. A golf ball painted on its cover surface with the coating composition is improved in weather resistance and brightness and minimized in color fading due to diffusion of the whitening agent into the cover.Type: GrantFiled: October 25, 2001Date of Patent: September 9, 2003Assignee: Bridgestone Sports Co., Ltd.Inventors: Takashi Ohira, Nobuhiko Sato
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Publication number: 20020086937Abstract: A method for preparing a thermoplastic elastomer is disclosed, said method comprising (I) mixingType: ApplicationFiled: October 26, 2001Publication date: July 4, 2002Inventors: Igor Chorvath, Frances Marie Fournier, Michael Kang-Jen Lee, Dawei Li, Robert Leo Oldinski, Richard Leroy Rabe, Jeffrey Paul Sage, Dean Curtis Gray, Yongjun Lee, Koji Nakanishi
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Patent number: 6268457Abstract: Anti-reflective coating materials for deep ultraviolet photolithography include one or more organic dyes incorporated into spin-on-glass materials. Suitable dyes are strongly absorbing over wavelength ranges around wavelengths less than 260 nm such as 248 nm and 193 nm, that may be used in photolithography. A method of making dyed spin-on-glass materials includes combining one or more organic dyes with alkoxysilane reactants during synthesis of the spin-on-glass materials.Type: GrantFiled: June 10, 1999Date of Patent: July 31, 2001Assignee: Allied Signal, Inc.Inventors: Joseph Kennedy, Teresa Baldwin, Nigel P. Hacker, Richard Spear
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Patent number: 6191247Abstract: A polysiloxane composition comprising (A) a polysiloxane having a group represented by the formula (I): ≡Si—OR (I) wherein, R is a C1 to C18 substituted or unsubstituted monovalent hydrocarbon group or ether bond containing an organic group; and (B) at least 1 ppm of (a) a compound having an N, P, S, Sn, or As component or (b) an acetylene alcohol and a rubber composition containing the same. Specific polysiloxanes (A) contain both formula (I): ≡Si—OR as well as Si—H.Type: GrantFiled: April 4, 1997Date of Patent: February 20, 2001Assignee: The Yokohama Rubber Co., Ltd.Inventors: Kazunori Ishikawa, Fumito Yatsuyanagi, Tetsuji Kawazura
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Patent number: 6107395Abstract: The present invention relates to a novel photochromic polyurethane consisting essentially of an isocyanate reactive mixture consisting essentially of: i) from about 40 to about 85% by weight of one or more polyols having a nominal functionality of from 2 to 4 and molecular weights of from 500 to 6000 g/mole; ii) from about 15 to about 60% by weight of one or more diols or triols or mixtures thereof having a functionality of from 2 to 3 and molecular weights of from 62 to 499; b) an aliphatic polyisocyanate having a functionality ranging from about 2 to about 3; and c) a photochromic compound selected from a group consisting of spirooxazines, fulgides, fulgimides, and naphthopyrans, wherein the photochromic compound is present in an amount of 0.01 to 5 parts per hundred parts by weight of the isocyanate reactive mixture.Type: GrantFiled: December 16, 1998Date of Patent: August 22, 2000Assignee: Bayer CorporationInventors: James W. Rosthauser, Karl W. Haider, Sivaram Krishnan, James N. Rieck
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Patent number: 6048927Abstract: A method for forming a fiber treating composition comprising contacting an aminofunctional polysiloxane comprising at least one aminofunctional siloxy unit with a mixture comprising a lactone and an alkylsulfate of benzimidazole thereby effecting formation of an amide-functional polysiloxane in admixture with the alkylsulfate of benzimidazole. The composition formed by the method is particularly useful for treating textiles such as cotton and cotton-synthetic blends to provide good softness and water absorbency and improved whiteness and treatment durability.Type: GrantFiled: March 1, 1999Date of Patent: April 11, 2000Assignee: Dow Corning CorporationInventor: Howard Edwin Griffin
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Patent number: 6011112Abstract: The invention relates to organopolysiloxane compounds which can be stored subject to the exclusion of moisture, can be cross-linked by cleaving of alcohols to form elastomers when moisture gains access at room temperature and are based on (A) polydiorganosiloxanes with organyloxy groups, optionally (B) organyloxy functional cross-linkers with at least three organyloxy groups, and optionally (C) condensation catalysts, characterised in that they contain at least one (D) compound selected from the compounds (D.sub.a) to (D.sub.f) given in claim 1.Type: GrantFiled: March 23, 1998Date of Patent: January 4, 2000Assignee: Wacker-Chemie GmbHInventors: Stefan Oberneder, Michael Stepp, Erich Pilzweger, Norman Dorsch
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Patent number: 5962559Abstract: One-part alkoxy curing room temperature vulcanizable silicone compositions comprising the bi-functional compounds containing the 1-sila-azacyclopentane structure wherein the compounds function as alcohol scavengers in one-part alkoxy curing room temperature vulcanizable silicone compositions and the alcohol reaction products of these compounds function as adhesion promoters in such room temperature vulcanizable compositions.Type: GrantFiled: September 30, 1997Date of Patent: October 5, 1999Assignee: General Electric CompanyInventors: Gary M. Lucas, Slawomier Rubinsztajn, Brian P. Bayly
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Patent number: 5932681Abstract: Describes a method of preparing a polymerizate by polymerizing a two-component organic composition comprising: a first component containing a polyfunctional reactant having two or more functional groups selected from isocyanate, isothiocyanate and combinations of isocyanate and isothiocyanate groups; and a second component containing a polythiol represented by the following general formula I, ##STR1## wherein R.sub.1 and R.sub.2 are each selected from the group consisting of straight or branched chain alkylene, e.g., methylene and ethylene, cyclic alkylene, phenylene and C.sub.1 -C.sub.9 alkyl substituted phenylene. The second component may also optionally contain a reactive hydrogen compound that is different than the polythiol of general formula I. Polymerizates prepared according to the present invention are useful as ophthalmic lenses and have a refractive index of at least 1.57, an Abbe number of at least 33 and an initial Barcol hardness of at least 1.Type: GrantFiled: March 9, 1998Date of Patent: August 3, 1999Assignee: PPG Industries Ohio, Inc.Inventors: Robert D. Herold, Michael O. Okoroafor
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Patent number: 5746820Abstract: The use of sulfuric monoesters of the formulae (I) and (II)R.sup.1 --O--(CH.sub.2 O).sub.n --SO.sub.3 .sup.- M.sup.+ (I)R.sup.1 --CO--NR.sup.2 --(CH.sub.2 O)(.sub.n+1)--SO.sub.3 .sup.- M.sup.+ (II)in whichR.sup.1 is a straight-chain or branched alkyl group of 10 to 24 carbon atoms,R.sup.2 is a hydrogen atom or a C.sub.1 -C.sub.6 -alkyl group,M.sup.+ is a hydrogen ion, an alkali metal ion, 1/2 an alkaline earth metal ion, or an ammonium ion of the formula N.sup.+ R.sup.3 R.sup.4 R.sup.5 R.sup.6, where the substituents R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another are each hydrogen atoms or C.sub.1 -C.sub.6 -alkyl groups, which alkyl groups can be substituted by 1 to 3 hydroxyl groups, andn is a number from 0 to 4; or of a mixture of at least two sulfuric monoesters of the formulae (I) and/or (II),for preparing surface-treated pigments from the classes of the quinacridones and dioxazines.Type: GrantFiled: April 22, 1997Date of Patent: May 5, 1998Assignee: Hoechst AktiengesellschaftInventors: Manfred Urban, Dieter Schnaitmann
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Patent number: 5708064Abstract: Organic ophthalmic articles are photochromic and have high indices of refraction.Type: GrantFiled: October 13, 1994Date of Patent: January 13, 1998Assignee: PPG Industries, Inc.Inventors: Charles R. Coleman, Robert D. Herold, Christopher D. Selvig
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Patent number: 5698618Abstract: A coating composition is formed from an acid-set coating varnish and a pigment composition. The pigment composition includes a specific organic dyestuff derivative and a specific basic-group-containing resin-type pigment dispersant. The coating composition excels in pigment dispersibility, nonflocculation properties, noncrystallizability and fluidity. When used as a coating, the coating composition has excellent color tone, gloss, hardness, weather resistance, and solvent resistance.Type: GrantFiled: July 18, 1996Date of Patent: December 16, 1997Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Takashi Kamikubo, Tadashi Itabashi, Masami Kuwahara
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Patent number: 5698624Abstract: Nanocomposites are manufactured by combining a matrix polymer and exfoliated intercalates formed by contacting a phyllosilicate with a water-insoluble polymer to adsorb or intercalate the polymer between adjacent phyllosilicate platelets. Sufficient water-insoluble polymer is adsorbed between adjacent phyllosilicate platelets to expand the adjacent platelets to a spacing of at least about 10 .ANG. (as measured after water removal), up to about 100 .ANG. and preferably in the range of about 30-40 .ANG., so that the intercalate easily can be exfoliated, e.g., when mixed with a polymer melt, to provide a matrix polymer/platelet composite (nanocomposite) material--the platelets being exfoliated from the intercalate.Type: GrantFiled: June 7, 1995Date of Patent: December 16, 1997Assignee: AMCOL International CorporationInventors: Gary W. Beall, Semeon Tsipursky, Anatoliy Sorokin, Anatoliy Goldman
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Patent number: 5633313Abstract: A method and apparatus (10) for detection of the degree of cure of a polymer in situ and non-invasively. The method and apparatus uses a solvatochromic probe molecule which upon curing produces a shift in the fluorescence emission spectrum as compared to a liquid polymerizable composition. The method and apparatus is particularly adapted for poly(vinyl) polymers. Preferred solvatochromic probe molecules are oxazones and pyrene.Type: GrantFiled: April 24, 1995Date of Patent: May 27, 1997Assignee: Board of Trustees operating Michigan State UniversityInventors: Gary J. Blanchard, Julie L. Jessop, Alec B. Scranton
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Patent number: 5461175Abstract: A method for separating enantiomers of a derivative of an aryloxipropanolamine is disclosed, characterized in that the derivative is contacted with a chiral solid-phase chromatography material containing molecular imprints of an optically pure enantiomer of the derivative to be separated.Type: GrantFiled: July 8, 1994Date of Patent: October 24, 1995Inventors: Lutz Fischer, Ralf Muller, Klaus Mosbach, Bjorn Ekberg
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Patent number: 5350786Abstract: Stabilizers for organic polymers, consisting of one or more compounds of the classis of the sterically hindered amines (HALS) are directly added to the reaction mixture during the (co)polymerization of the .alpha.-olefins or of their mixtures with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized and show a thermo- and photo-oxidative resistance higher than that of the same polymeric compositions to which the same stabilizers are added by a traditional route.Type: GrantFiled: March 4, 1993Date of Patent: September 27, 1994Assignee: Enichem Synthesis S.p.A.Inventors: Silvestro Costanzi, Damiano Gussoni, Luciano Pallini
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Patent number: 5284908Abstract: A copolymer latex which is useful in an adhesive composition, a paper coating composition, an adhesive composition for carpet lining and an adhesive composition for a rock fiber substrate is prepared by emulsion copolymerizing an aliphatic conjugated diene monomer and at least one other monomer copolymerizable therewith in the presence of a chain transfer agent and at least one compound having no copolymerizing reactivity selected from the group consisting of hydrocarbons having 5 to 12 carbon atoms, halogenated aromatic hydrocarbons, five or six membered ring heterocyclic compounds, aliphatic ethers and aliphatic esters in an amount of 1 to 100 parts by weight per 100 parts by weight of a total amounts of the aliphatic conjugated diene monomer and the other monomer.Type: GrantFiled: January 29, 1991Date of Patent: February 8, 1994Assignee: Sumitomo Dow LimitedInventors: Wataru Fujiwara, Junko Hyoda, Yasushi Toyoda, Saburo Mishiba
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Patent number: 5238992Abstract: A process for preparing solid polymer blends and composites of controlled porosity in microemulsions containing both hydrophilic and hydrophobic phases. The microemulsions are prepared with surfactant systems that may include a cosolvent as a part thereof, together with a hydrophilic monomer, or monomers, dissolved in the hydrophilic phase of the microemulsion, and a hydrophobic monomer, or monomers, dissolved in the hydrophobic phase. Polymerization of the monomers thus present is carried out to provide highly uniform dispersions of the resulting polymers in each other. The invention allows for the control of the morphology of the blends, the improvement in compatability of otherwise incompatible polymers, and improvements in the processability of the polymers due to enhanced thermal and mechanical properties.Type: GrantFiled: August 26, 1992Date of Patent: August 24, 1993Assignee: Edison Polymer Innovation CorporationInventor: Syed Outubuddin
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Patent number: 5217839Abstract: Disclosed herein is a process for the preparation of a toner, which comprises dissolving or dispersing a compound having at least one >C.dbd.N.sup..sym. < bond in its molecule and a colorant in a vinyl monomer and then suspension-polymerizing the vinyl monomer in an aqueous dispersion medium.Type: GrantFiled: December 20, 1990Date of Patent: June 8, 1993Assignees: Nippon Zeon Co., Ltd., Casco Nobel ABInventors: Fumio Yamada, Hiromitsu Kikuchi, Tsuyoshi Yamamoto, Jun Saito, Shizuo Kitahara
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Patent number: 5124394Abstract: A method for preparing an aqueous copolymer emulsion comprising the aqueous copolymerization of vinyl acetate and ethylene in the presence of a stabilizing system consisting essentially of a stabilizing effective amount of poly(ethyloxazoline).Type: GrantFiled: April 12, 1991Date of Patent: June 23, 1992Assignee: Air Products and Chemicals, Inc.Inventor: William E. Lenney
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Patent number: 5106933Abstract: An addition reaction-type adhesive silicone composition comprising (A) an alkenyl group-containing polyorganosiloxane; (B) a polyorganohydrogensiloxane; (C) at least two members selected from the group consisting of (1) (meth)acryloxy group-containing alkoxysilanes or siloxanes, (2) epoxy ring-containing alkoxysilanes or siloxanes and (3) isocyanurate compounds; and (D) Pt, Pd, or Rh compounds. The composition exhibits excellent adhesiveness for plastic materials, and its cured products have excellent heat-resistant and moisture-resistant properties.Type: GrantFiled: June 8, 1990Date of Patent: April 21, 1992Assignee: Toshiba Silicone Co., Ltd.Inventors: Takaomi Kobayashi, Yasuji Matsumoto
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Patent number: 5071908Abstract: The present invention is directed to a silicon polyimide precursor composition which has a viscosity suitable for the formation of films by application or another mean and which is capable of forming hard and tough films having excellent heat resistance, low coefficient of thermal expansion and strong adhesive force by heating the films, the above-mentioned films being formed by the chemical bond between silicon and polyimide. Another feature of the present invention is directed to a method for preparing a crosslinked/cured material of the aforesaid silicon polyimide precursor composition.That is, the present invention is connected with a soluble silicon polyimide precursor composition which comprises 0.5 to 40% by weight of a silicon polyimide precursor represented by the following formula (I) on another precursor obtained by imidizing the compound represented by the formula (I) and having a logarithmic viscosity number of 0.05 to 5 dl/g, 0.Type: GrantFiled: January 24, 1990Date of Patent: December 10, 1991Assignee: Chisso CorporationInventors: Kouichi Kunimune, Ryuji Kobayashi
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Patent number: 5017686Abstract: Aromatic polyamides having improved stability with respect to thermal oxidation are produced by adding to the reaction mixture present as a melt, a stabilizing amount, e.g., 0.05-4 mol % based on the sum total of components A and B, of a compound of Formula (I) ##STR1## wherein Q is --O--; --S--; or N--R'";R" and R'" are: --H; C.sub.1 -C.sub.6 -alkyl; or phenyl, e.g., benzimidazole.Type: GrantFiled: January 31, 1990Date of Patent: May 21, 1991Assignee: Huels AktiengesellschaftInventors: Jurgen Finke, Roland Feinauer
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Patent number: 4931220Abstract: Described is photochromic particulate material comprising a photochromic substance within a matrix of a polymerizate of a polyfunctional acrylate monomer. The photochromic particulate material may be produced by adding an organic photochromic substance to a polymerizable composition including a polyfunctional acrylate monomer and polymerizing the resultant admixture, e.g., by emulsion polymerization. In the case of emulsion or suspension polymerization, finely divided particulate organic photochromic materials are separated from the polymerization medium in the form of spheroidal thermoset photochromic particles of fairly uniform size. If desired, the particles recovered from the polymerization medium may be further ground in conventional attrition mills to further reduce the size of the particulate product. In the case of bulk polymerization, the polymerizate may be formed as a continuously cast sheet, which is then pulverized to a particulate material of pigmentary size.Type: GrantFiled: November 24, 1987Date of Patent: June 5, 1990Assignee: PPG Industries, Inc.Inventors: Ronald L. Haynes, Charles H. Hoelscher, Jonathan G. Lasch
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Patent number: 4914137Abstract: This invention relates to the stabilization of polyurethane foam by using a combination of a phenothiazine with at least a co-stabilizing effective amount of a compound selected from the group consisting of certain dithiocarbamates, thiuramsulfides, mercaptobenzothiazole, phosphites, phosphonites, phenolic antioxidants, pentaerythritol-tetrakis(beta-laurylthiopropionate), 4,4'-thiobis(2-t-butyl-5-methylphenol) and mixtures thereof.Type: GrantFiled: August 11, 1988Date of Patent: April 3, 1990Assignee: Uniroyal Chemical Company, Inc.Inventors: Bernard C. Smith, Frank Powell, John F. Sierakowski
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Patent number: 4874805Abstract: Compounds of the general formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, phenyl or benzyl and R.sup.2 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are hydrogen, C.sub.1 -C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is a group of the formula --CH.sub.2 OR.sup.7 (II) in which R.sup.7 is C.sub.1- C.sub.12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen or C.sub.1 -C.sub.4 -alkoxy, or is --C(O)--R.sup.8, and R.sup.8 is C.sub.1 -C.sub.12 -alkyl, and also not more than two of the radicals R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are one or two groups of the formula --CH.sub.2 CH.sub.2 Si(OR.sup.9).sub.3 (III), --CH.Type: GrantFiled: June 29, 1988Date of Patent: October 17, 1989Assignee: Ciba-Geigy CorporationInventors: Rolf Mulhaupt, Hubert Simon
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Patent number: 4855351Abstract: Cyclic aminoalkylsilane compositions are prepared by the reaction of approximately equimolar amounts of an aminoalkyltrialkoxysilane such as 3-aminopropyltrimethoxy-silane and a glycidyl ether such as methyl glycidyl ether. They are useful as adhesion promotors in room temperature vulcanizable compositions comprising polyalkoxysilyl-terminated polydiorganosiloxanes.Type: GrantFiled: August 22, 1988Date of Patent: August 8, 1989Assignee: General Electric CompanyInventor: Judith Stein
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Patent number: 4851471Abstract: A direct casting process for manufacturing a shaped synthetic plastic article, such as an ophthalmic lens, which has photochromic properties, the process comprising incorporating a photochromic spiro-oxazine compound into a mixture comprising a highly reactive polyfunctional monomer and a low amount of a polymerization catalyst, and curing the composition in a mould to form the shaped synthetic plastic article.Type: GrantFiled: December 17, 1986Date of Patent: July 25, 1989Assignee: Pilkington Brothers P.L.C.Inventors: William R. Maltman, Ian M. Threlfall
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Patent number: 4803236Abstract: An aromatic polyester composition comprising an aromatic polyester derived from terephthalic acid and/or isophthalic acid and a bisphenol and a stabilizer comprising mercaptobenzothiazole.Type: GrantFiled: December 21, 1987Date of Patent: February 7, 1989Assignee: Celanese CorporationInventor: Jerold C. Rosenfeld
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Patent number: 4803241Abstract: A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding grade linear or unsaturated polyester or polycarbonate having reacted or copolymerized therein the residue of one or a mixture of styrylbenzazole reactants of the formula: ##STR1## wherein A is the residue of a benzene ring of a benzoxazole, benzothiazole or benzionidazole radical; X is --O--, --S-- or --N(R.sup.2)--; Ph is a phenylene radical; and R.sup.1 is halogen or --Y--R.sup.2 in which Y is --O-- or --N(R.sup.2)-- and each R.sup.2 is hydrogen, alkenyl or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical.Type: GrantFiled: July 20, 1987Date of Patent: February 7, 1989Assignee: Eastman Kodak CompanyInventors: Max A. Weaver, Wayne P. Pruett, Samuel D. Hilbert, Robert D. Burpitt
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Patent number: 4764537Abstract: Disclosed are internal mold release agents for the preparation of molded articles using polyisocyanate addition polymerization, which are comprised of:(A) at least one ketimine, aldimine, enamine, cyclic Schiff base or a mixture of at least two of said compounds;(B) at least one metal salt of an organic carboxylic acid having from 8 to 24 carbon atoms; and(C) optionally including at least one carboxylic acid, organic sulphonic acid, mineral acid, or amidosulphonic acid, and their use in preparing molded articles comprised of polyurethane-plastics, polyurea-plastics, polyurethane-polyurea-plastics, polyurethane-polyurea-polyamide-plastics, or polyurea-polyamide-plastics.Type: GrantFiled: September 15, 1987Date of Patent: August 16, 1988Assignee: BASF AktiengesellschaftInventors: Peter Horn, Hans U. Schmidt
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Patent number: 4753966Abstract: The present invention is directed to a mold release composition which is a solution, liquid at room temperature, of(A) at least one zinc salt of a straight chain or branched, saturated or unsaturated aliphatic carboxylic acid containing 8 to 24 carbon atoms in(B) at least one organic compound containing nitrogen which is liquid at room temperature, the solution containing the zinc salt in a quantity of about 10 to 75% by weight, based on the total weight of the composition.The present invention is additionally directed to an isocyanate reactive mixture containing isocyanate reactive compounds and the above described mold release composition. The present invention is further directed to a process for the preparation of molded products based on the above mixture and to the molded products obtained according to this process.Type: GrantFiled: November 12, 1987Date of Patent: June 28, 1988Assignee: Bayer AktiengesellschaftInventors: Peter Haas, Christian Weber
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Patent number: 4728690Abstract: Process for producing molded polyurethane parts using as internal release agents, compounds of the general formula ##STR1## in amounts of 0.5 to 10 weight percent, based on the reaction formulation, in which at least one R.sup.2 radical in the average molecule represents ##STR2## R.sup.3 is a divalent hydrocarbon radical with 2 to 4 carbon atoms and R.sup.4, R.sup.5 are univalent hydrocarbon radicals or together are part of a morpholine or a piperazine ring. The molded polyurethane parts can be removed from the mold using significantly lower tensional forces without residues being built up on the mold.Type: GrantFiled: March 18, 1986Date of Patent: March 1, 1988Assignee: Th. Goldschmidt AGInventors: Helmut Lammerting, Hans-Joachim Kollmeier
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Patent number: 4678825Abstract: An aromatic polyester composition comprising an aromatic polyester derived from terephthalic acid and/or isophthalic acid and a bisphenol and a stabilizer comprising dimercaptothiadiazole.Type: GrantFiled: February 25, 1986Date of Patent: July 7, 1987Assignee: Celanese CorporationInventor: Jerold C. Rosenfeld
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Patent number: 4677154Abstract: The invention relates to elimination of discoloration in polyurethanes, particularly thermoplastic polyurethanes, by the addition to the reaction mixture from 0.Type: GrantFiled: December 18, 1985Date of Patent: June 30, 1987Assignee: BASF CorporationInventors: Thirumurti Narayan, Peter T. Kan
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Patent number: 4574138Abstract: Rapid cure polymerizable monomer sealing and bonding compositions are disclosed. The polymerizable compositions comprise at least one polymerizable acrylate monomer system comprising a urethane acrylate monomer having vinyl reactive ends, and at least one hydroxy-terminated, monofunctional, short chain monomer which is soluble in or miscible with the urethane acrylate monomer; an effective amount for initiation of a free radical initiator; and a compatible filler material.Type: GrantFiled: January 9, 1984Date of Patent: March 4, 1986Inventors: James P. Moran, Jr., Mark Holmes
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Patent number: 4554310Abstract: Room temperature vulcanizable organopolysiloxane compositions are provided which exhibit improved stability and a reduced tendency to corrode copper upon contact resulting from the employment of an effective amount of a tin condensation catalyst having organo radicals attached to tin by carbon tin linkages and whose remaining valences are satisfied by a chelate radical or a dicarboxylate radical in combination with an organic triazole such as benzotriazole.Type: GrantFiled: August 27, 1984Date of Patent: November 19, 1985Assignee: General Electric CompanyInventors: Jeffrey H. Wengrovius, Leonard W. Niedrach
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Patent number: 4530989Abstract: Room temperature stable organopolysiloxane compositions containing organosilicon compounds having Si-bonded hydrogen atoms and aliphatic multiple bonds, a platinum catalyst which promotes the addition of Si-bonded hydrogen atoms to the aliphatic multiple bonds and an inhibitior which prevents premature crosslinking at room temperature selected from the group consisting of a maleinimide and a maleic acid derivative of the formula ##STR1## where R.sup.1 is a hydroxyl group or a trimethylsiloxy group and R.sup.2 is a monovalent hydrocarbonoxy radical having from 1 to 20 carbon atoms per radical, which is bonded to the carbon atom of the ##STR2## group or a monovalent hydrocarbonoxy radical having from 1 to 20 carbon atoms per radical, which is bonded to the carbon atom of the ##STR3## group and which is substituted with at least one triorganosilyl group.Type: GrantFiled: March 16, 1984Date of Patent: July 23, 1985Assignee: Wacker-Chemie GmbHInventors: Ulrich Michel, Josef Radecker
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Patent number: RE32504Abstract: Room temperature stable organopolysiloxane compositions containing organosilicon compounds having Si-bonded hydrogen atoms and aliphatic multiple bonds, a platinum catalyst which promotes the addition of Si-bonded hydrogen atoms to the aliphatic multiple bonds and an inhibitor which prevents premature crosslinking at room temperature selected from the group consisting of a maleinimide and a maleic acid derivative of the formula ##STR1## where R.sup.1 is a hydroxyl group or a trimethylsiloxy group and R.sup.2 is a monovalent hydrocarbonoxy radical having from 1 to 20 carbon atoms per radical, which is bonded to the carbon atom of the ##STR2## group or a monovalent hydrocarbonoxy radical having from 1 to 20 carbon atoms per radical, which is bonded to the carbon atom of the ##STR3## group and which is substituted with at least one triorganosilyl group.Type: GrantFiled: May 30, 1986Date of Patent: September 15, 1987Assignee: Wacker-Chemie GmbHInventors: Ulrich Michel, Josef Radecker
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Patent number: RE35223Abstract: Cyclic aminoalkylsilane compositions are prepared by the reaction of approximately equimolar amounts of an aminoalkyltrialkoxysilane such as 3-aminopropyltrimethoxy-silane and a glycidyl ether such as methyl glycidyl ether. They are useful as adhesion promotors in room temperature vulcanizable compositions comprising polyalkoxysilyl-terrninated polydiorganosiloxanes.Type: GrantFiled: January 23, 1995Date of Patent: April 30, 1996Assignee: General Electric CompanyInventor: Judith Stein