Abstract: A waterproof membrane useful as a coating or flashing for roofs or as a liner for containing liquids which comprises a composition containing a neutralized sulfonated EPDM polymer and asphalt, the former component comprising at least 30% by weight of the total weight of the polymer and asphalt. The composition has outstanding physical properties and an unexpectedly high tensile strength.

Abstract: There is provided a hot melt adhesive for bonding shaped articles and surface structures of ethylene-propylene terpolymer (EPDM) between one another, or with other materials, consisting 100 parts by weight of styrene-ethylene-butylene-styrene block copolymer rubber; 10-150 parts by weight phr (per hundred rubber) aliphatic hydrocarbon resins; 50-300 parts by weight phr (per hundred rubber) aromatic hydrocarbon resins; and up to 1,000 parts by weight phr (per hundred rubber) bitumin with a softening point, according to the Ring and Ball method (DIN test 52011), 37/44-54/59.

Abstract: This invention provides emulsions of rubberized asphalt, which are preferably extended with oil and are especially useful for chip seal, slurry seal and cold mix applications. The novel composition may be prepared by passing an aqueous surfactant-containing solution and a homogeneous gel, comprising rubberized asphalt or oil-extended rubberized asphalt through a colloid mill to provide an emulsion having a small and uniform particle size.

Abstract: Ionomeric polymer compositions are provided which comprise an ionomeric polymer and about 5 to about 125 parts by weight of gilsonite, per 100 parts by weight of the ionomeric polymer. The inventive compositions can be formulated as processable materials which can be fabricated into articles such as sheets, tubes, and films having improved tear propagation resistance and fire retardance and decreased levels of water absorption.

Abstract: An all-weather inorganic fiber mat based roofing shingle is prepared using a novel bituminous coating formulation comprising a partially air blown asphalt combined with a styrenic elastomer and mineral stabilizer, which formulation more particularly comprises about 3 to 80% elastomeric polymer composition, 10 to 87% bituminous composition and 10 to 87% mineral stabilizer. In another embodiment, improved low and high temperature pliability and strength properties are also attained by blending recycled rubber or reclaimed rubber into the basic formulation which thereby comprises about 1 to 74% elastomeric polymer composition, 10 to 83% bituminous composition, 15 to 88% mineral stabilizer and about 1 to 74% recycled or reclaimed rubber.

Abstract: A joint sealing compound comprises the reaction product of a non-blown asphalt flux, a hydroxyl-terminated polymer of butadiene, a vinyl monomer, a butadiene-styrene linear block polymer and an extender oil.

Abstract: The adherence between an asphalt and aggregate is increased by incorporating into the asphalt a vinyl monomer and an alkenyl azabenzene.

Abstract: Medical grade pressure sensitive adhesive compositions comprising a homogeneous mixture of one or more polyisobutylenes or blends of one or more polyisobutylenes and butyl rubber, one or more styrene radial or block type copolymers, mineral oil, one or more water soluble hydrocolloid gums, and a tackifier. One or more water swellable cohesive strengthening agents, an antioxidant, and various other optional ingredients may be included within the adhesive composition.

Abstract: A method for reclaiming used asphalt by mixing it with a chemically modifying system consisting of a polymerizable vinyl monomer and an alkenyl azabenzene.

Abstract: A rubberized asphaltic concrete composition in which the particle sizes of the rubber granulate and the mineral aggregate are adjusted so that a relatively typical particle distribution is achieved in the total aggregate.

Abstract: The viscosity of an asphalt emulsion may be controlled by incorporating up to about 1 percent by weight of a modified starch containing not more than 27 percent amylose and the balance substantially amylopectin.

Abstract: The adherence between an asphalt and aggregate is improved by including in the combination styrene and an acrylamide.

Abstract: The invention relates to an improved process for the production of polymer powders based on graft polymers and optionally rubber-elastic polymers and vinyl monomer polymers.

Abstract: A cutback of a mixture of bitumen and rubber is prepared by treating a mixture of bitumen and rubber with a peroxide at 100.degree.-240.degree. C. and adding a volatile solvent. The obtained cutback can easily be sprayed on roads and shows a good retention for chippings.

Abstract: Method and composition for protecting, maintaining and repairing paved surfaces utilizing a workable fiber-containing asphalt and/or latex emulsion in combination with an active amount of a water-soluble polymer material differing in ionic characteristics from the emulsion or emulsifier component thereof.

Abstract: A reinforced rubber composition is provided comprising a mixture of (a) a sulfur vulcanizable rubber and (b) ground coal having an average mesh size of 25 or more and which produces an aqueous slurry with a pH of less than 7.0, and wherein a metallic reinforcing member is embedded in the rubber mixture of (a) and (b).

Abstract: Stabilization of asphalt and asphalt rubber compositions against degradation, e.g., viscosity increase by addition of a finite small but effective viscosity stabilizing amount of at least one alkali metal salt of an organic or inorganic acid.

Abstract: A novel acrylic thermoplastic resin composition, transparent and excellent in flexibility, consisting of at least two different multi-layer structure polymers. Polymer [I] contains an inner layer of crosslinked acrylic elastomer and an outer layer of acrylic resin, wherein the amount of elastomeric inner layer is minor in comparison with the amount of the resin outer layer; polymer [II] has the same fundamental polymer structure as multi-layer structure polymer [I] except that the amount of crosslinked elastomer inner layer is a major amount as compared to the amount of resin outer layer. It is preferred that an intermediate layer having an intermediate property exist between the inner and outer layers of the multi-layer structure polymers.

Abstract: A cold applied joint sealant usable for both portland cement and asphaltic concrete pavements, which comprises an asphalt/urethane formulation resulting from the mixture of a liquid butadiene polymer, containing predominantly primary terminal hydroxyl groups, with a urethane reactant of di- or polyisocyanate. The sealant has low urethane content and cures to provide a low modulus, high penetration, with 85%-95% resilience and zero flow. An initial set time of less than about 120 minutes is achieved, which permits vehicular traffic to be accommodated thereover soon after application.

Abstract: Stabilization of asphalt and asphalt-rubber compositions against degradation, e.g., viscosity increase by addition of a finite small and effective viscosity stabilizing amount of an alkali metal nitrite.

Abstract: An aqueous asphaltic emulsion is provided in which the dispersed asphaltic material is the prereacted reaction product of asphalt having a viscosity of less than about 120,000 cps (at 140.degree. F.), an acrylamide, a vinyl aromatic monomer and an elastomer.

Abstract: An improved pavement binder composition comprises a digestion of rubber particles of low bulk density, preferably of the porous nodular surface morphological type, in a bituminous material.

Abstract: Thermally insensitive adhesives having good adhesion to cementitious substrates and having good low temperature flexural strengths, which consists essentially of the reaction product of asphalt flux, a polymerizable vinyl aromatic monomer, a non-depolymerized rubber, a depolymerized rubber and a terpene resin are provided. These adhesives are outstandingly adapted for use as the adhesives for preformed membranes of the type which comprise an asphaltic coated fibrous reinforcement material having an asphalt based pressure sensitive adhesive on one side thereof.

Abstract: Thermoplastic elastomer compositions of the present invention comprise a blend of from about 10 to about 50 parts by weight of a crystalline 1-olefin polymer, from about 80 to about 15 parts by weight of a styrene-butadiene rubber, and from about 5 to about 50 parts by weight of bitumen. The thermoplastic blends have unexpectant increases in properties, especially tear strength, tensile strength, high temperature (100.degree. C.) tear strength, and smooth surfaces when injection molded. Moreover, the bitumen lowers the injection molding pressure, thus enabling larger parts to be molded. The compositions, which may be partially cured, also have excellent aging properties. The compositions are a true thermoplastic in that they can be repeatedly processed and yet maintain their good physical properties.

Abstract: Chemically modified asphalts having utility for road construction, repair and maintenance as well as coating for various substrates, including cementitious substrates, glass and metal are provided. These asphalts are the product produced by reacting an acrylamide, asphalt having a viscosity of less than about 120,000 cps (at 140.degree. F.), a vinyl aromatic monomer and a rubbery polymer.

Abstract: Thermoplastic elastomer compositions of the present invention comprise a blend of from about 10 to about 50 parts by weight of a crystalline 1-olefin polymer, from about 80 to about 15 parts by weight of a styrene-butadiene rubber, and from about 5 to about 50 parts by weight of bitumen. The thermoplastic blends have unexpectant increases in properties, especially tear strength, tensile strength, high temperature (100.degree. C.) tear strength, and smooth surfaces when injection molded. Moreover, the bitumen lowers the injection molding pressure, thus enabling larger parts to be molded. The compositions, which may be partially cured, also have excellent aging properties. The compositions are a true thermoplastic in that they can be repeatedly processed and yet maintain their good physical properties.

Abstract: A rubberized asphalt composition which comprises a moisture-curing diene series liquid rubber, asphalt and aggregates, and a process for producing same. Liquid rubber having a molecular weight of from 500 to 50,000 and having an isocyanate group or an isocyanate group blocked by phenol or acetoxime as a functional group at the terminals of the molecule is preferably utilized. The liquid rubber comprises from 4 to 10% by weight of the total of liquid rubber and asphalt.

Abstract: This invention relates to asphalt composition exhibiting improved physical properties comprising asphalt, hydrogenated rubber copolymer and sulfur which compositions exhibit improved temperature viscosity stability and improved tensile properties.

Abstract: A polyolefin resin composition which is suitable mainly for affording superior processing properties of sheet and little in the variation of flowability at hot processing temperatures is provided.The composition comprises (A) a resin mixture comprising a polypropylene resin and a polyethylene resin, the respective percentages by weight of these resins in the mixture being specified, (B) a polyolefin resin modified with a polymerizable unsaturated carboxylic acid, its salt or its ester by graft polymerization and (C) finely divided vegetable fibers, the ratio of (A) to (B) and the content of (C) in the composition being both specified. Further an agent (D) may be added to the composition, such as petroleum resin, rosin, rosin-like resin, plasticizer or inorganic filler.

Abstract: Sealant compositions, particularly for use in joints between adjacent concrete slabs and deck membranes are provided. The sealant compositions comprise the reaction product of a mixture consisting essentially of asphalt flux, styrene monomer and a vulcanizable rubber.

Abstract: The incorporation of minor amounts of mineral rubber (blown asphalt) in compositions comprising blends of both chlorobutyl and bromobutyl rubbers results in high adhesion to natural rubber or natural rubber/polybutadiene rubber substrates.

Abstract: An improved curable chopped fiber loaded elastomer or plastic composition composed of a blend of about 5 to 50 percent of chopped fiber of up to 1.3 centimeters in length and 95 to 50 percent of particulate unvulcanized elastomer or plastic which is capable of passing a 6 mesh U.S. Standard Screen.

Abstract: This invention relates to emulsion type adhesive compositions which include a metal neutralized sulfonated elastomeric co or terpolymer, wherein the neutralized sulfonated copolymer has about 5 to about 250 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated copolymer, and less than about 200 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, having about 5 to 6 carbon atoms, the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated co or terpolymer.

Abstract: A covering especially for roads consisting of mineral fillers, reclaimed rubber and a binder based on bitumen, it being possible to incorporate 5 to 30% by weight of reclaimed rubber and the binder comprising a hot-homogenized blend of bitumen and thermoplastic polymers, especially of the radial teleblock copolymer type being used. The resultant coverings are capable of reducing the annoyance caused by rolling noises etc. without the necessity of putting up with losses of other qualities.

Abstract: The instant invention relates to improved roofing materials which are a blend composition of a bitumen, a neutralized sulfonated polymer, and a filler, wherein the concentration level of the neutralized sulfonated polymer is about 5 to about 25 parts by weight per 100 parts by weight of the bitumen, more preferably about 7 to about 20, and the concentration level of the filler is about 0 to about 100 parts by weight per 100 parts of the bitumen. The improved roofing material based on such a composition has excellent stability towards oxidation, is U.V. stable and has good resistance to creep.

Abstract: This invention relates to hot melt adhesive compositions which include an amine terminated polyalkylene oxide neutralized sulfonated thermoplastic polymer wherein the neutralized sulfonated thermoplastic polymer has about 5 to about 250 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated thermoplastic polymer, and about 25 to about 200 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, having about 5 to 6 carbon atoms, the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated thermoplastic resin.

Abstract: This invention relates to hot melt adhesive compositions which include a neutralized EPDM terpolymer which has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated elastomeric EPDM terpolymer, a neutralized sulfonated 1,2-syndiotactic polybutadiene resin which has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated polybutadiene, and about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate having about 5 to about 6 carbon atoms the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated EPDM terpolymer.

Abstract: This invention relates to hot melt adhesive compositions which includes a hydrogenated block copolymer block such as Kraton G, about 25 to about 250 parts by weight of a hydrocarbon resin made from a petroleum or coal tar distillate, aliphatic dienes and mono and diolefins, cyclic olefins of 5 to 6 carbon atoms and hydrogenated polycyclics per 100 parts by weight of the hydrogenated block copolymer, and about 25 to about 200 parts by weight of a polybutene or polyisobutylene per 100 parts of the hydrogenated block copolymer.

Abstract: This invention relates to pressure sensitive adhesive compositions which includes a hydrogenated block copolymer such as Kraton G, about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, aliphatic dienes and mono- and diolefins, cyclic olefins of 5 or 6 carbon atoms and hydrogenated poly cyclics per 100 parts by weight of the hydrogenated block copolymer, and about 25 to 200 parts by weight of a polybutene or polyisobutylene per 100 parts of the hydrogenated block copolymer, wherein said mixture of Kraton G, said hydrocarbon resin and said polybutene or polyisobutylene are dissolved in a non-reactive solvent at a concentration level of about 5 to about 25 grams per 100 mil of non-reactive solvent.

Abstract: Sealant compositions, particularly for use in joints between adjacent concrete slabs and deck membranes are provided. The sealant compositions comprise the reaction product of a mixture consisting essentially of asphalt flux, styrene monomer and a vulcanizable rubber.

Abstract: A rubber-modified asphalt composition prepared by reacting a bituminous material with a polymerizable aromatic monomer and a rubbery polymer whereby the rubbery polymer is chemically integrated with the asphalt. The rubber-modified asphalt compositions of the invention can be used in the treatment of glass fibers as well as in road-paving applications, roofing applications and the like.

Abstract: A paving mixture containing black asphalt which is changed to a color other than black by the addition of a limited amount of a coloring agent to the mixture, such as ferric oxide, to impart a permanent, distinctive color to the pavement without sacrificing any of the wearing qualities thereof. At the same time, the cost of the pavement is maintained within practical economic limits so that it may be used in the production of paved areas of limited extent, such as tennis courts, playgrounds, running tracks, parking lots, airport runways, etc. When the mixture is laid down in depths of one-fourth inch to twelve inches, the increased cost of the pavement is made up in a reasonably short period of time by the elimination of the need for painting the conventional black surface repeatedly, especially when the latter is subjected to extensive use and wear.