Formamide Or N,n-dialkyl Amide Or N-alkyl Pyrrolidone Patents (Class 524/726)
  • Patent number: 12251463
    Abstract: Provided is a composition containing water-soluble non-ionic polyurethane, comprising (a) 0.1-30 parts of water-soluble non-ionic polyurethane dispersions by weight; (b) 10-30 parts of decontaminating surfactants by weight; (c) 0.01-5 parts of conditioning agents by weight; and (d) 100 parts of aqueous carriers by weight. The composition in the present invention is used as shampoo, and can make hair naturally strong and extend the volumizing duration of hair.
    Type: Grant
    Filed: December 11, 2018
    Date of Patent: March 18, 2025
    Assignee: WANHUA CHEMICAL GROUP CO., LTD.
    Inventors: Bangbang Li, Cao Zhou, Nuo Xu, Haidong Jia, Jie Zhang, Pengfei Qu, Jiakuan Sun
  • Patent number: 11332637
    Abstract: The present application discloses a single-component coating for automobile seal strip, which includes one or several kinds of waterborne polyurethane resin, waterborne polyacrylate resin, waterborne epoxy resin, as well as polysilicone dispersion and sealant isocyanate curing agent. The coating of the present application is sprayed on the automobile glass guide groove, automobile door frame sponge strip, automobile trunk seal strip, automobile skylight seal strip and other rubber base materials and then baked; after the reaction, it can solve the problem of abnormal sound when the automobile is in motion, and the problem of feeling soft and smooth on the coating surface.
    Type: Grant
    Filed: May 11, 2018
    Date of Patent: May 17, 2022
    Inventor: Zhenglin Chen
  • Patent number: 10816900
    Abstract: A polymer of a polyimide precursor which includes a structural unit represented by the following general formula (7), where X1 represents a tetravalent organic group, X2 represents a divalent organic group, and R1 represents a group represented by the following general formula (2), where the dotted line represents a bonding, Y1 represents an organic group with a valency of k+1, Rs represents a group containing at least one silicon atom, “k” represents 1, 2 or 3, and “n” represents 0 or 1.
    Type: Grant
    Filed: September 21, 2018
    Date of Patent: October 27, 2020
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Hiroyuki Urano, Katsuya Takemura, Masashi Iio, Koji Hasegawa, Kenji Funatsu
  • Patent number: 10597816
    Abstract: Composition, comprising at least components (A) and (B) and optionally at least one of components (C) to (E): (A) a polyacrylate obtained in the polymerisation of monomers (M1) CH2?CR3COO—R1 with (M2) CH2?CR3COO—R2 and optionally (M3) CH2?CR6COO—Y—RF (M4) CH2?CR3—X—R4; (B) a wax; (C) a blocked isocyanate; (D) an organic polysiloxane; (E) a melamine resin.
    Type: Grant
    Filed: July 3, 2015
    Date of Patent: March 24, 2020
    Assignee: Archroma IP GmbH
    Inventors: Wolfgang Knaup, Waltraud Gasafi-Martin
  • Patent number: 9458572
    Abstract: [Object] To provide an anti-soiling agent compound that can sufficiently prevents adhesion of pitch to a dry part region. [Solution] The present invention provides an anti-soiling agent composition is provided with: a low molecular polysiloxane compound represented by the following formula (1); and a high molecular polysiloxane compound represented by the following formula (2), and characterized in that the number of modified groups per low molecular polysiloxane compound is in a range from 0.1 to 3, the number of modified groups per high molecular polysiloxane compound is in a range from 1.
    Type: Grant
    Filed: August 13, 2015
    Date of Patent: October 4, 2016
    Assignee: MAINTECH CO., LTD.
    Inventors: Hiroshi Sekiya, Hiraku Sawada, Daisuke Kobayashi
  • Patent number: 9335644
    Abstract: Provided is an electron transport material represented by formula (1): wherein X represents an oxygen atom or ?C(CN)2; R1, R2, R3, R4, R5, R6, and R7 each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group, an alkoxy group, an aryl group, or an aralkyl group; R8, R9, and R10 each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group, an aralkyl group, an aryl group, —R11—O—R12, or —R13—CO—O—R14; R11 represents a linear or branched alkylene group; R12 represents a linear or branched alkyl group; R13 represents a single bond or a linear or branched alkylene group; and R14 represents a linear or branched alkyl group, an aryl group, or an aralkyl group, provided that at least two or more groups of R8, R9, and R10 represent a group other than a hydrogen atom.
    Type: Grant
    Filed: February 9, 2015
    Date of Patent: May 10, 2016
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Masahiro Iwasaki, Shinya Yamamoto, Jiro Korenaga, Daisuke Haruyama, Yukimi Kawabata, Keisuke Kusano, Kenta Shingu, Yoshifumi Shoji
  • Patent number: 9040625
    Abstract: To provide a water/oil repellent composition which can impart sufficient post-air-drying water/oil repellency to the surface of an article, and which presents a low environmental impact, and an article having its surface treated with the water/oil repellent composition. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a), structural units based on a monomer (b), structural units based on a monomer (c) and/or structural units based on a monomer (d); and an aqueous medium (B) containing water, and a film-forming assistant (x) and/or a film-forming assistant (y). Monomer (a): a monomer having a C1-6 polyfluoroalkyl group, monomer (b): vinylidene chloride, monomer (c): a monomer, the homopolymer of which has a glass transition temperature of at least 20° C., monomer (d): a monomer having a crosslinkable functional group, film-forming assistant (x): a specific amide solvent, and film-forming assistant (y): a specific glycol solvent.
    Type: Grant
    Filed: October 24, 2013
    Date of Patent: May 26, 2015
    Assignee: ASAHI GLASS COMPANY, LIMITED
    Inventors: Kyouichi Kaneko, Kazunori Sugiyama, Reika Fukuda, Takao Hirono
  • Publication number: 20150115255
    Abstract: Provided are a resin composition and a substrate that are capable of being used for manufacturing an electronic device having excellent light extraction efficiency. The resin composition contains a polymer and a solvent dissolving the polymer. The resin composition is used to form a layer, and when refractive indexes of the layer along two perpendicular in-plane directions thereof are respectively defined as “Nx” and “Ny” and a refractive index of the layer along a thickness direction thereof is defined as “Nz”, Nx, Ny and Nz satisfy a relationship of “(Nx+Ny)/2?Nz”>0.01. Further, a method of manufacturing the electronic device by using such a substrate, and the electronic device are also provided.
    Type: Application
    Filed: October 24, 2014
    Publication date: April 30, 2015
    Applicants: AKRON POLYMER SYSTEMS INC., SUMITOMO BAKELITE COMPANY LIMITED
    Inventors: Limin SUN, Jiaokai Jing, Dong Zhang, Frank W. Harris, Hideo Umeda, Ritsuya Kawasaki, Toshihiko Katayama, Yusuke Inoue, Jun Okada, Mizuho Inoue, Manabu Naito
  • Publication number: 20150087778
    Abstract: A method and system for formation of a polyarylene sulfide is described. The method includes a first stage in which a complex is formed in a reactor. The complex includes the hydrolysis product of an organic amide solvent and an alkali metal hydrosulfide. The complex formation reaction also forms hydrogen sulfide as a by-product. The method also includes treating a fluid stream that is pulled off of the reactor. The treatment includes scrubbing the fluid stream to recover hydrogen sulfide from the stream and return the hydrogen sulfide to the reactor. The recovery and recycle of the hydrogen sulfide can prevent loss of sulfur from a polyarylene sulfide formation process.
    Type: Application
    Filed: September 9, 2014
    Publication date: March 26, 2015
    Inventor: Hendrich Alvarez Chiong
  • Patent number: 8889789
    Abstract: The present disclosure provides a low dielectric constant resin formulation comprising 20-150 parts by weight of diisocyanate, 20-400 parts by weight of poly(2,6-dialkyl-1,4-phenylene oxide), and 200-650 parts by weight of a solvent. The present disclosure also provides a low dielectric constant resin prepolymer, composition, and composite produced from the above formulation, and a method for preparing the low dielectric constant resin prepolymer solution.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: November 18, 2014
    Assignee: Industrial Technology Research Institute
    Inventors: Lu-Shih Liao, Kuo-Chan Chiou
  • Publication number: 20140312278
    Abstract: Disclosed herein are a polymer nanocapsule and a preparing method thereof, and more particularly, a 3D covalent molecular network nanocapsule, and a preparing method thereof. According to the present invention, a nanocapsule having thermal stability and solvent resistance due to a 3D covalent molecular network structure may be easily prepared without performing an additional post-processing process such as addition of a cross-linking agent or catalyst or removal of a template or core. Since the nanocapsule formed as described above may support an organic dye, metal particles, and the like, it is expected that the nanocapsule will be variously applied to material storage and transport, drug delivery, and the like.
    Type: Application
    Filed: December 30, 2013
    Publication date: October 23, 2014
    Applicant: GWANGJU INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Ji-woong PARK, Ji-Yoon JEONG, Su-Young MOON
  • Publication number: 20140249269
    Abstract: In order to provide a thermally-detachable sheet that detaches at higher temperatures, this thermally-detachable sheet has a shear bond strength with respect to a silicon wafer of 0.25 kg/5×5 mm or larger, at a temperature of 200° C., after said temperature has been maintained for one minute, and a shear bond strength with respect to a silicon wafer of 0.25 kg/less than 5×5 mm at any temperature in a range of over 200° C. to not more than 500° C., after said temperature has been maintained for three minutes.
    Type: Application
    Filed: September 21, 2012
    Publication date: September 4, 2014
    Inventors: Daisuke Uenda, Yusuke Shirakawa, Hiroshi Hamamoto, Takashi Oda, Eiji Toyoda, Takeshi Matsumura
  • Publication number: 20140221567
    Abstract: A method of forming a low gloss, high solids polyurea coating containing very low volatile organic compounds (VOC) in the coating composition. The low volatile content not only makes the coating environmentally friendly but allows it to be applied at variable thickness levels and over a wide variety of environmental conditions. The coating composition is comprised of an isocyanate reactive agent containing a secondary diamine, a polyisocyanate, a gloss reducing agent and a viscosity modifier. The gloss reducing agent is generally pre-mixed into an isocyanate reactive agent containing a secondary diamine and/or polyisocyanate containing the viscosity modifier before mixing the two components together to form a low gloss polyurea coating.
    Type: Application
    Filed: February 4, 2014
    Publication date: August 7, 2014
    Applicant: Air Products And Chemical, Inc.
    Inventors: Shafiq Nisarali Fazel, Jared Denis Bender
  • Publication number: 20140159264
    Abstract: This disclosure, viewed from one aspect, this disclosure relates to a solution of polyamide comprising: an aromatic polyamide, a silane coupling agent and a solvent. The solution of polyamide can improve adhesion between the polyamide film and the base of glass or silicon wafer.
    Type: Application
    Filed: December 5, 2013
    Publication date: June 12, 2014
    Applicants: SUMITOMO BAKELITE CO., LTD., AKRON POLYMER SYSTEMS, INC.
    Inventors: Frank W. HARRIS, DONG ZHANG, LIMIN SUN, JIAOKAI JING, TOSHIMASA EGUCHI, HIDEO UMEDA, RITSUYA KAWASAKI, JUN OKADA, MIZUHO INOUE
  • Publication number: 20140154490
    Abstract: The present invention aims to provide a non-combustible film having excellent flexibility, excellent moisture resistance, and high mechanical strength. The present invention also aims to provide a dispersion liquid for non-combustible films which is used in production of the non-combustible film, a method for producing a non-combustible film using the above dispersion, and a solar cell back sheet and a flexible board each of which is formed from the above non-combustible film. The present invention further aims to provide a solar cell including the solar cell back sheet. The non-combustible film of the present invention includes a water-insoluble inorganic compound and a heat-resistant synthetic resin, the water-insoluble inorganic compound constituting from 30% by weight to 90% by weight inclusive of the total weight of the non-combustible film, the film exhibiting a flammability of VTM-0 in the UL-94 VTM test.
    Type: Application
    Filed: June 7, 2012
    Publication date: June 5, 2014
    Applicants: SUMITOMO SEIKA CHEMICALS CO., LTD., Tokyo University of Science Educational Foundation Administrative Organization, National Institute of Advanced Industrial Science and Technology
    Inventors: Seiji Bando, Noriyuki Hayashizaka, Yuki Umeda, Kazunori Kawasaki, Takeo Ebina, Hiromichi Hayashi, Manabu Yoshida, Takashi Yamashita
  • Publication number: 20140045992
    Abstract: A water/oil repellent composition comprising a polymer having structural units based on the following monomer (a) and structural units based on the following monomer (b), and an aqueous medium containing water and the following amide solvent (I) is used. Monomer (a): a compound represented by (Z—Y)nX, wherein Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group having no fluorine atom or the like, n is 1 or 2, and X is a polymerizable unsaturated group. Monomer (b): vinyl chloride. Amide solvent (I): a compound represented by R1O(CH2)r(CHR4)sC(O)NR2R3, wherein r is an integer of from 0 to 3, s is 0 or 1, R1 is a C1-3 alkyl group, each of R2 and R3 is a methyl group or the like, and R4 is a hydrogen atom or the like.
    Type: Application
    Filed: October 22, 2013
    Publication date: February 13, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Takao HIRONO, Minako SHIMADA, Eiji MORIMOTO, Yuuichi OOMORI
  • Patent number: 8575244
    Abstract: The present invention relates to substituted N-(cyclo)alkylpyrrolidones as solvents for use in processes for preparing polyurethane dispersions.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: November 5, 2013
    Assignee: BASF SE
    Inventors: Gerd Buelow, Manfred Dargatz, Karl Haeberle, Maria Teresa Hechavarria Fonseca, Karl Ott, Juan Salgado-Valle, Tobias Wabnitz
  • Publication number: 20130101858
    Abstract: The present disclosure provides a low dielectric constant resin formulation comprising 20-150 parts by weight of diisocyanate, 20-400 parts by weight of poly(2,6-dialkyl-1,4-phenylene oxide), and 200-650 parts by weight of a solvent. The present disclosure also provides a low dielectric constant resin prepolymer, composition, and composite produced from the above formulation, and a method for preparing the low dielectric constant resin prepolymer solution.
    Type: Application
    Filed: April 27, 2012
    Publication date: April 25, 2013
    Inventors: Lu-Shih LIAO, Kuo-Chan Chou
  • Publication number: 20130101862
    Abstract: A stable solution of a ring-opened polymer is provided. The stable solution can be prepared using the following steps: (d) adding an N,O-heterocyclic compound of formula I or II and a DOPO-based compound into an organic solvent to provide a reaction solution: wherein R1 to R3, W1, W2, m, n, p and q are as defined in the specification. (e) heating the reaction solution to carry out a ring-opening reaction to provide a polymer solution; and (f) cooling the polymer solution to obtain the stable solution, wherein the organic solvent is unreactive to the N,O-heterocyclic compound and the DOPO-based compound, and the amount of the DOPO-based compound is about 0.01 wt % to about 50 wt % based on the total weight of the N,O-heterocyclic compound and the DOPO-based compound. The stable solution is useful as a self-crosslinkable resin or a hardener for hardening epoxies.
    Type: Application
    Filed: January 6, 2012
    Publication date: April 25, 2013
    Applicant: TAIWAN UNION TECHNOLOGY CORPORATION
    Inventor: Hsin-Ho Wu
  • Publication number: 20120168688
    Abstract: The present invention relates to a binder resin composition for an electrode, including a polyamic acid and a solvent, wherein the polyamic acid is (i) a polyamic acid which includes a tetracarboxylic acid component including 10 to 100 mol % of 4,4?-oxydiphthalic acid and 90 to 0 mol % of 3,3?,4,4?-biphenyltetracarboxylic acid and/or pyromellitic acid and a diamine component including an aromatic diamine having 1 to 4 aromatic rings, (ii) a polyamic acid which includes a tetracarboxylic acid component including 3,3?,4,4?-biphenyltetracarboxylic acid dianhydride and a diamine component including 10 to 90 mol % of p-phenylene diamine and 90 to 10 mol % of 4,4?-diaminodiphenyl ether, or (iii) a polyamic acid which includes a tetracarboxylic acid component including 3,3?,4,4?-biphenyltetracarboxylic acid dianhydride and a diamine component including 40 mol % or more of a bis[4-(4-aminophenoxy)phenyl] compound.
    Type: Application
    Filed: September 22, 2010
    Publication date: July 5, 2012
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Takeshige Nakayama, Tomonori Nakayama, Seiichirou Takabayashi, Tetsuji Hirano
  • Publication number: 20120076932
    Abstract: The present invention relates to substituted N-(cyclo)alkylpyrrolidones as solvents for use in processes for preparing polyurethane dispersions.
    Type: Application
    Filed: June 7, 2010
    Publication date: March 29, 2012
    Applicant: BASF SE
    Inventors: Gerd Buelow, Manfred Dargatz, Karl Haeberle, Maria Teresa Hechavarria Fonseca, Karl Ott, Juan Salgado-Valle, Tobias Wabnitz
  • Publication number: 20110304817
    Abstract: [Problem] To provide a coating composition for forming a hard coating which, by itself, favorably adheres to a plastic optical substrate, and effectively prevents the occurrence of cracks caused by the thermal hysteresis at the time of curing. [Means for Solution] The coating composition for forming a hard coating, contains a fine inorganic oxide particle, a hydrolyzable organosilicon compound, water, a curing catalyst and an organic solvent, wherein cyclic ketone is contained in an amount of 0.10 parts by mass to 30.00 parts by mass per 100 parts by mass of the total of the fine inorganic oxide particle and the hydrolyzable organosilicon compound.
    Type: Application
    Filed: April 9, 2010
    Publication date: December 15, 2011
    Inventors: Shunichiro Nakatsukasa, Katsuhiro Mori
  • Publication number: 20080306210
    Abstract: The invention relates to new compositions having good binder properties, wetting properties and dispersing properties not only for virtually foam-free aqueous pigment preparations but also for solvent-borne and solvent-free pigment preparations with very good heat stability and weathering stability.
    Type: Application
    Filed: November 6, 2006
    Publication date: December 11, 2008
    Inventors: Patrick Glockner, Evelyn Albrecht, Andreas Wenning
  • Publication number: 20080214732
    Abstract: Aromatic sulfonimide ionene polymers useful as membranes in electrochemical cells are prepared.
    Type: Application
    Filed: October 1, 2007
    Publication date: September 4, 2008
    Inventor: Mark F. TEASLEY
  • Patent number: 7259225
    Abstract: Disclosed are polyphosphazenes of Formula 1 showing a sol-gel behavior with a temperature change, a preparation method thereof, and injectable thermosensitive polyphosphazene hydrogels using the same
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: August 21, 2007
    Assignee: Korea Institute of Science and Technology
    Inventors: Soo-Chang Song, Bae-Houn Lee
  • Patent number: 7250461
    Abstract: Organic compositions of conductive polymers are provided. The compositions have at least one polymer selected from polypyrrole, polythiophene, or combinations and at least one colloid-forming polymeric acid dispersed in a liquid medium that is at least 60% by weight at least one organic liquid. Also provided is a method of making such compositions.
    Type: Grant
    Filed: March 17, 2004
    Date of Patent: July 31, 2007
    Assignees: E. I. du Pont de Nemours and Company, DuPont Displays, Inc.
    Inventors: Che-Hsiung Hsu, Charles Douglas Macpherson, Hjalti Skulason
  • Patent number: 7199205
    Abstract: An organopolysiloxane-modified polysaccharide prepared by esterification reacting (A) an organopolysiloxane having residual carboxylic anhydride groups and (B) a polysaccharide having hydroxyl groups, wherein the organopolysiloxane is bonded to the polysaccharide through half ester groups, and a process for the preparation of organopolysiloxane-modified polysaccharide, in which component (A) and component (B) are subjected to an esterification reaction in the presence of (C) a non-protonic polar solvent. The organopolysiloxane-modified polysaccharide comprising polysaccharide and organopolysiloxane bonded thereto through half ester groups is novel. The process for the preparation of organopolysiloxane-modified polysaccharide permits introduction of organopolysiloxane into polysaccharide at a high introduction ratio.
    Type: Grant
    Filed: September 8, 2003
    Date of Patent: April 3, 2007
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Tadashi Okawa, Masayuki Hayashi
  • Patent number: 6887947
    Abstract: This invention relates to processes for the production of purified, partially esterified polyol fatty acid polyesters and the compositions derived from those processes. The purified, partially esterified polyol fatty acid polyesters of the present invention are particularly well suited for use in a variety of food, beverage, pharmaceutical, and cosmetic applications and comprise less than about 5% polyol; less than about 5 ppm of residual solvent; less than about 700 ppm of lower alky esters; less than about 5% of a soap and free fatty acid mixture; less than about 3% of ash; and have an acid value of less than about 6.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: May 3, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Jared John Schaefer, James Earl Trout
  • Patent number: 6696517
    Abstract: The invention relates to the use of copolymers consisting essentially of a1) 1 to 50% by weight of the repeat structural unit of the formula (1):  where n is an integer from 2 to 9 or a2) 1 to 50% by weight of a mixture of the repeat structural unit of the formula (1) and of the repeat structural unit of the formula (2):  where R, R1 and R2 may be identical or different and are hydrogen or a linear or branched alkyl or alkenyl group having in each case 1 to 30 carbon atoms, and b) 49.99 to 98.99% by weight of the repeat structural unit of the formula (3):  in which R3 is hydrogen, methyl or ethyl, Z is (C1-C8)-alkylene and X is an ammonium, alkali metal or alkaline earth metal ion and c) 0.01 to 8% by weight of crosslinking structures which originate from monomers having at least two olefinic double bonds, as thickeners in preparations comprising organic solvents.
    Type: Grant
    Filed: April 16, 2002
    Date of Patent: February 24, 2004
    Assignee: Clariant GmbH
    Inventors: Matthias Löffler, Roman Morschhäuser, Peter Klug
  • Patent number: 6548621
    Abstract: The invention provides a poly(imide-benzoxazole) (PIBO) copolymer prepared from a trimellitic anhydride halide monomer and a bis(o-diaminophenol) monomer. The PIBO copolymer is characterized by the following recurring unit: wherein X is —O—, —S—, —C(CF3)2—, —C(CH3)2—, —CO—, —CH2—, —SO2—, —SO—, or deleted; and n is an integer. The PIBO copolymers of this invention are particularly useful as dielectric layers in semiconductor devices because they possess hydroxyl groups which create better adhesion to semiconductor substrates.
    Type: Grant
    Filed: November 8, 2001
    Date of Patent: April 15, 2003
    Assignee: Industrial Technology Research Institute
    Inventors: Shih-Jung Tsai, Steve Lien-Chung Hsu, Yuan-Pin Huang
  • Publication number: 20030040565
    Abstract: A holder for waterproof connector comprising a holder portion made of a resin and a packing portion made of a gel-like material for keeping a waterproof connector having the terminal portion of an electric wire with a terminal inserted therein watertight at the electric wire side thereof, wherein the packing portion made of a gel-like material is obtained by hardening a silicone composition containing all of the following components (A) to (D): (A) an organopolysiloxane having at least two alkenyl groups per molecule in an amount of 100 parts by weight; (B) an organopolysiloxane having at least two hydrogen atoms having a silicon atom bonded thereto per molecule in an amount such that the amount of the hydrogen atom having a silicon atom bonded thereto in the component (B) is from not smaller than 0.
    Type: Application
    Filed: April 1, 2002
    Publication date: February 27, 2003
    Applicant: YAZAKI CORPORATION
    Inventors: Osamu Sugiyama, Masao Nagano
  • Patent number: 6521719
    Abstract: The present invention relates to multifunctional macromers, to a method for the manufacture thereof and to their use in unsaturated polyester resins as additives to improve mechanical properties of preparations manufactured thereof. The process for the manufacture of multifunctional macromers comprises the following steps: a) reacting a polycarboxylic acid with 2 to 4 carboxylic groups, preferably 3 to 4 carboxylic groups, with glycidyl (meth)acrylate or allyl glycidyl ether, the amount of glycidyl (meth)acrylate or allyl glycidyl ether being at least one mol of glycidyl (meth)acrylate or allyl glycidyl ether per free carboxylic group of formed macromer, and b) reacting the product from step a) with an unsaturated, aromatic or aliphatic anhydride in an amount sufficient to esterify part or all of the free hydroxyl groups of the product from step a).
    Type: Grant
    Filed: April 15, 2002
    Date of Patent: February 18, 2003
    Assignee: Ashland Inc.
    Inventors: Jukka Tulisalo, Mikael Skrifvars, Karri Airola, Jukka Estamo, Pertti Hietakari
  • Patent number: 6495627
    Abstract: A conductive composition for a biological electrode is capable of reducing the impedance between the electrode and the skin. A conductive gel composition for a biological electrode which is capable of electrically and physically connecting a living body to an electrode element and is composed of at least the following components: (1) a radical-polymerizable unsaturated compound; (2) a moisturizer serving as a plasticizer and functioning to supplementing and promoting the physiological humidifying function of the horny layer; (3) a polymerization initiator; and (4) a crosslinking agent. This moisturizer serves also as a plasticizer and, furthermore, elevates the moisture content in the horny layer at the application of this composition. The above-mentioned composition may further contain a plasticizer selected from among polyhydric alcohols, amines and ethers.
    Type: Grant
    Filed: July 11, 1996
    Date of Patent: December 17, 2002
    Assignee: Nihon Kohden Corporation
    Inventors: Shin Suda, Tohru Kurata
  • Patent number: 6262225
    Abstract: The invention is related to an olefin-carbon monoxide-vinyl monomer terpolymer composition which is derived from an olefin feed and a synthesis gas feed and at least one vinyl monomer feed. The invention is also related to a method for preparing olefin-carbon monoxide-vinyl monomer terpolymers by heating an olefin feed, a synthesis gas feed and at least one vinyl monomer feed in the presence of a free radical polymerization initiator. More particularly, the synthesis gas feed comprises predominantly carbon monoxide and hydrogen. The terpolymers of the invention are useful as polyvinyl chloride plasticizers.
    Type: Grant
    Filed: July 18, 2000
    Date of Patent: July 17, 2001
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Abhimanyu O. Patil, Manika Varma-Nair
  • Publication number: 20010005736
    Abstract: The disclosed invention relates to isocyanate reactive systems which have an internal mold release agents having improved stability. The isocyanate reactive system includes (1) at least one compound containing a plurality of isocyanate-reactive groups and (2) an internal mold release system comprising (a) a carboxylic acid and (b) a compound selected from the group consisting of a fatty polyester, a fatty acid ester and a fatty amide, and a surfactant selected rom the group consisting of ethoxylated alcohols, propoxylated alcohols or blends thereof.
    Type: Application
    Filed: January 22, 2001
    Publication date: June 28, 2001
    Inventor: Andreas H. Rothacker
  • Patent number: 6252010
    Abstract: Adhesive film useful for the production of semiconductor devices is produced from a siloxane-modified polyamideimide resin composition, comprising 100 parts by weight of a siloxane-modified polyamideimide resin and 1 to 200 parts by weight of a thermosetting resin ingredient.
    Type: Grant
    Filed: October 29, 1998
    Date of Patent: June 26, 2001
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Kazumasa Takeuchi, Tetsuya Saito, Ken Nanaumi
  • Patent number: 6218496
    Abstract: Disclosed is a polyimidesiloxane adhesive made by reacting in a solution of an organic solvent a dianhydride selected from the group consisting of biphenyl dianhydride and oxydiphthalic anhydride with an approximately stoichiometric amount of a diamine. The diamine is a mixture of about 5 to about 30 mole % of a siloxane-containing diamine and about 70 to about 95 mole % of a non-siloxane containing diamine. The non-siloxane containing diamine is a mixture of about 10 to about 90 mole % each of at least two of the diamines 2,2-bis(4[4-aminophenoxy]phenyl) propane, &agr;,&agr;′-bis(4-aminophenyl)-1,4-diisopropylbenzene, 3,3′-diaminophenylsulfone, and 1,3-bis(3-aminophenoxy)benzene. The adhesive can be made into one, two, and three-layer tapes (or dispensed in other ways) which have a high Tg and a relatively low bonding temperature.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: April 17, 2001
    Assignee: Occidental Chemical Corporation
    Inventors: Jerold C. Rosenfeld, Sergio R. Rojstaczer, John A. Tyrell
  • Patent number: 6168782
    Abstract: Elastomeric silicones, especially elastomeric silicone polyethers, are prepared by combining and reacting (A) an ≡Si—H containing polysiloxane, (B) a mono-alkenyl polyether, (C) an active ingredient such as a vitamin, antimicrobial agent, sunburn prevention agent, astringent, or sex hormone, (D) an &agr;,&ohgr;-unsaturated hydrocarbon, (E) a platinum catalyst, and (F) an oil. The reaction of components (A)-(F) is allowed to continue, forming a crosslinked three-dimensional gelled network of the elastomeric silicone polyether containing the active ingredient and the oil. The compositions are useful in personal and health care applications, personal hygiene, and household cleaning applications.
    Type: Grant
    Filed: May 24, 1999
    Date of Patent: January 2, 2001
    Assignee: Dow Corning Corporation
    Inventors: Zuchen Lin, William James Schulz, Jr., Janet Mary Smith
  • Patent number: 5985969
    Abstract: Polyimide precursor solutions comprise an organic liquid and the reaction product of an aromatic dianhydride and an aromatic diaminobenzoxazole capped, on at least one terminal end, with a bifunctional chain extender. The bifunctional chain extender has one functional group reactive with the amine of the aromatic diaminobenzoxazole or the anhydride of the aromatic dianhydride and another functional group which does not form amic acid linkages, but which is capable of further reaction to increase the molecular weight of the polyimide precursor under conditions other than those used to react the aromatic diamine and aromatic dianhydride to form the polyimide precursor. These polyimide precursors can be converted into polyimidebenzoxazole polymers.
    Type: Grant
    Filed: February 23, 1998
    Date of Patent: November 16, 1999
    Assignee: The Dow Chemical Company
    Inventors: William J. Harris, Wen-Fang Hwang
  • Patent number: 5977248
    Abstract: Gels, cast films, coatings, extruded rods, extruded fibers, compression molded discs, and machined compression molded discs, are made from organopolysiloxane sheet or tube polymers such as an apophyllite-derived 3-cyanopropyldimethyl siloxy sheet polymer of the formula [((NCC.sub.3 H.sub.6)(CH.sub.3).sub.2 SiO).sub.x (HO).sub.1-x SiO.sub.1.5 ].sub.n. Polymers are prepared by contacting sheet or tube silicates with an organohalosilane containing at least one polar group such as cyanoalkyl, acyloxy, or haloalkyl, in the presence of a polar solvent or a mixture of a polar solvent and a non-polar solvent; and heating the mixture until a polymer is formed.
    Type: Grant
    Filed: June 3, 1998
    Date of Patent: November 2, 1999
    Assignees: Dow Corning Corporation, Case Western Reserve University
    Inventors: Chenggang Chen, Dimitris Elias Katsoulis, Malcolm Edward Kenney
  • Patent number: 5942597
    Abstract: The present invention relates to a process for separating polyhydroxyalkanoate from a biomass, the process comprising extracting the polyhydroxyalkanoate with at least one PHA solvent selected from the group consisting of acetone, acetonitrile, benzene, butyl acetate, butyl propionate, .beta.-butyrolactone, .gamma.-butyrolactone, diethyl carbonate, diethylformamide, dimethyl carbonate, dimethyl succinate, dimethyl sulfoxide, dimethylformamide, ethyl acetate, ethylene glycol diacetate, methyl acetate, methyl ethyl ketone, 1,4-dioxane, tetrahydrofuran, toluene, xylene, and mixtures thereof.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: August 24, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Isao Noda, Lee Arnold Schechtman
  • Patent number: 5889108
    Abstract: Low molecular weight siloxane fluids are thickened by silicone elastomers. The silicone elastomers are made by combining in one pot an .tbd.Si--H containing siloxane, a mono-alkenyl polyether, an alpha, omega-diene, and a low molecular weight siloxane fluid. An elastomer, i.e. gel, with polyether groups is produced. The elastomer can be swollen with the low molecular weight siloxane fluid under shear force, to provide a uniform silicone paste. The silicone paste has excellent spreadability upon rubbing, and possesses unique rheological properties in being thixotropic and shear thinning. The silicone paste can be easily emulsified with water to form a stable uniform emulsion, without using a surfactant to allow normally immiscible materials to become intimately mixed.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: March 30, 1999
    Assignee: Dow Corning Corporation
    Inventor: Shizhong Zhang
  • Patent number: 5886139
    Abstract: To economically produce a polyacetal copolymer excellent in properties including thermal stability by copolymerizing trioxane as the main monomer through simple steps, a polyacetal copolymer is produced by copolymerizing trioxane as the main monomer using a nonvolatile protonic acid catalyst as a polymerization catalyst until the conversion reaches at least 60% (based on all monomers), and then vaporizing unreacted monomers to separate, remove, and recover the same from the polymerization system to thereby reduce the residual monomer content of the polymerization system to 5% by weight or lower.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: March 23, 1999
    Assignee: Polyplastics Co., Ltd.
    Inventors: Kaoru Yamamoto, Akira Nakai
  • Patent number: 5821299
    Abstract: The present invention relates to a process for separating polyhydroxyalkanoate (PHA) from a biomass comprising the PHA, the process comprising: a) treating the biomass with a PHA solvent and a marginal nonsolvent for PHA; b) removing any insoluble biomass, thereby leaving behind a solution of PHA and marginal nonsolvent for PHA; and c) removing the PHA solvent from the solution, thereby resulting in a suspension of precipitated PHA in the marginal nonsolvent for PHA. Optionally, the process further comprises removing the marginal nonsolvent for PHA, thereby leaving behind the PHA. The present invention further relates to the suspension and the PHA produced by the process.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: October 13, 1998
    Assignee: The Proctor & Gamble Company
    Inventor: Isao Noda
  • Patent number: 5811506
    Abstract: An extrudable urea-extended thermoplastic polyurethane elastomer is formed from at least one aliphatic diisocyanate, at least one polyester glycol or polyether glycol, and at least one diamine curing agent. At least one second diamine curing agent and/or at least one extrusion processing aid may be included. The polyurethane has high-temperature-resistance and is thus extrudable at high temperatures. The polyurethane is also strong and durable. The polyurethane can be liquid-cast, injection-molded, transfer-molded, sprayed, and extruded without changing either the chemistry or stoichiometry of the polyurethane. The polyurethane may be used for making vehicle air bags or other any application for thermoplastic urethanes which requires increased thermal stability.
    Type: Grant
    Filed: February 3, 1997
    Date of Patent: September 22, 1998
    Assignee: Simula Inc.
    Inventor: Edwin C. Slagel
  • Patent number: 5750617
    Abstract: Biologically degradable aqueous dispersions of vinyl ester polymers are provided which have a solids content of 20 to 70% by weight, based on the total weight of the dispersions, and have been prepared by free radical polymerization by the emulsion polymerization process, wherein, in the presence of10 to 50% by weight, based on the monomer phase, of biologically degradable plasticizer and 0.5 to 15.0% by weight, based on the monomer phase, of biologically degradable emulsifier and/or biologically degradable protective colloid,a monomer phase comprisinga) 50 to 100 parts by weight of one or more vinyl esters from the group comprising vinyl esters of unbranched or branched alkylcarboxylic acids having 1 to 15 C atoms,b) 0 to 30 parts by weight of ethylene and/or an ester of (meth)acrylic acid or ethylenically unsaturated dicarboxylic acids from alcohols having 1 to 10 atoms andc) 0 to 20 parts by weight of other mono- or poly-ethylenically unsaturated compounds, is polymerized.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: May 12, 1998
    Assignee: Wacker-Chemie GmbH
    Inventors: Herbert Eck, Gerald Fleischmann, Konrad Wierer
  • Patent number: 5741585
    Abstract: Polyimide precursor solutions comprise an organic liquid and the reaction product of an aromatic dianhydride and an aromatic diaminobenzoxazole capped, on at least one terminal end, with a bifunctional chain extender. The bifunctional chain extender has one functional group reactive with the amine of the aromatic diaminobenzoxazole or the anhydride of the aromatic dianhydride and another functional group which does not form amic acid linkages, but which is capable of further reaction to increase the molecular weight of the polyimide precursor under conditions other than those used to react the aromatic diamine and aromatic dianhydride to form the polyimide precursor. These polyimide precursors can be converted into polyimidebenzoxazole polymers.
    Type: Grant
    Filed: April 24, 1995
    Date of Patent: April 21, 1998
    Assignee: The Dow Chemical Company
    Inventors: William J. Harris, Wen-Fang Hwang
  • Patent number: 5637639
    Abstract: A process for preparing poly(urethane/urea) prepolymers and aqueous poly(urethane/urea) dispersions (PUDs) therefrom, the poly(urethane/urea) polymers having high heat resistance and good water resistance. The method employs a water soluble volatile organic solvent, such as acetone, at a level of 0.1-5%, based on final dispersion weight, a level which does not require removal for purposes of flash point considerations.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: June 10, 1997
    Assignee: H.B. Fuller Licensing and Financing, Inc.
    Inventors: Youlu Duan, Sonja Stammler
  • Patent number: 5602226
    Abstract: The yield of fully substituted, multidimensional aromatic hubs in the condensation of hydroxyl and acid halide functionalities is improved by adding a thallium catalyst, such as thallium ethoxide (T1-OC.sub.2 H.sub.5), in the solvent.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: February 11, 1997
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard, Ronald R. Stephenson
  • Patent number: 5578381
    Abstract: The present invention relates to a release coating composition comprising an organopolysiloxane having fluorine containing organic groups and alkenyl groups, an organohydrogensiloxane, and a platinum-containing catalyst. The present invention also relates to a release coating composition comprising an organopolysiloxane having fluorine containing organic groups and silicon-bonded hydrogen groups, an alkenyl functional organopolysiloxane, and a platinum-containing catalyst. The curable silicone release coating compositions of this invention have excellent release properties from various tacky substances, especially silicone-based pressure sensitive adhesives, after curing, and also have excellent bonding characteristics when applied to various substrates.
    Type: Grant
    Filed: August 30, 1995
    Date of Patent: November 26, 1996
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Yuji Hamada, Hideki Kobayashi, Wataru Nishiumi