Containing Ether Or Hydroxyl Group Dnrm Patents (Class 524/747)
  • Patent number: 11118074
    Abstract: The present invention aims to provide a coating material which has high mechanical stability and is capable of providing a coat which has excellent appearance and exhibits excellent damping properties in a wide temperature range. The present invention relates to a damping-imparting agent including a compound having a sulfosuccinic acid (salt) structure. The present invention also relates to a resin composition for damping materials, including an emulsion prepared by polymerizing a monomer component, the composition further including a component having a sulfosuccinic acid (salt) structure.
    Type: Grant
    Filed: March 30, 2016
    Date of Patent: September 14, 2021
    Assignee: Nippon Shokubai Co., Ltd.
    Inventor: Yukihiro Miyawaki
  • Patent number: 9902817
    Abstract: Disclosed herein is a polyvinyl chloride resin, including: a first particle group having a particle diameter of 0.01 ?m or more and less than 1 ?m; and a second particle group having a particle diameter of 1 to 10 ?m, wherein the volume ratio of the first particle group to the second particle group is 1:0.4 to 1:1.
    Type: Grant
    Filed: November 1, 2013
    Date of Patent: February 27, 2018
    Assignee: Hanwha Chemical Corporation
    Inventors: Jeong Hwan Ko, Jung Ho Kong, Ji Eun Namgoong
  • Patent number: 9376509
    Abstract: An extended anionic surfactant having the general formula: RO—(PO)n-YZ wherein R is a linear alkyl chain ranging from C6 to C36, a branched alkyl chain ranging from C6 to C36, or a mixture thereof; PO is a propyleneoxy group; Y is —SO3, —CH2CH2CH2—SO3, —CH2CH(CH3)—SO3, or —CH2COO; Z is a cation; and n is 1 to 50.
    Type: Grant
    Filed: August 24, 2012
    Date of Patent: June 28, 2016
    Assignee: Sasol Performance Chemicals, GmbH
    Inventors: Melanie Anne Sharp, Oliver Herzog, Sebastiano Giovanni Giordano, Teresa Linville Marino, Kip Douglas Sharp
  • Patent number: 9296849
    Abstract: An object of the present invention is to provide a polychloroprene latex with improved rubber coagulability that gives a film superior in strength by dip molding, a polychloroprene latex composition, and a molded article. The polychloroprene latex is prepared by polymerization of 2-chloro-1,3-butadiene alone or by polymerization of raw monomers at least containing 2 -chloro-1,3-butadiene and 2,3-dichloro 1,3-butadiene and has a precipitation rate of 5 to 40%, as calculated according to Equation (I). In Equation (I), A is the mass (g) of the dry product, which is obtained by adding 50 ml of saturated aqueous solution of calcium hydroxide at 23° C. to 50 g of a latex having a solid matter concentration adjusted to 45 to 65 mass % at a liquid temperature of 23° C. over 2 minutes, filtering and collecting the generated precipitate with a 80 -mesh wire mesh, and drying the precipitate at 110° C.
    Type: Grant
    Filed: March 1, 2013
    Date of Patent: March 29, 2016
    Assignee: DENKA COMPANY LIMITED
    Inventors: Hidehito Otsuka, Kiyoshi Sunada, Kenji Mochizuki, Toru Shiraiwa
  • Patent number: 9029470
    Abstract: Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive, have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions can be prepared by mixing an ethylenically unsaturated monomer component and a stabilizer comprising a strong acid, in a carrier to form a monomer emulsion, reacting the monomer emulsion with an initiator to form the latex emulsion, and reacting the latex emulsion with a neutralizer. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.
    Type: Grant
    Filed: February 22, 2010
    Date of Patent: May 12, 2015
    Assignee: Akzo Nobel Coatings International B.V.
    Inventors: Jude Thomas Rademacher, Gary Charles Pompignano, Willy P Kulhanek
  • Publication number: 20140348887
    Abstract: A stable, aqueous composition containing a crosslinked, nonionic, amphiphilic polymer capable of forming a yield stress fluid in the presence of a surfactant is disclosed. The yield stress fluid is capable of suspending insoluble materials in the form of particulates and/or droplets requiring suspension or stabilization.
    Type: Application
    Filed: September 13, 2012
    Publication date: November 27, 2014
    Applicant: Lubrizol Advanced Materials, Inc.
    Inventors: Shui-Jen Raymond Hsu, Krishnan Chari, Wei-Yeih Yang, Prachur Bhargava, Murat Kadir
  • Patent number: 8883880
    Abstract: The present invention relates to a soluble shell polymer composition comprising an alkali soluble emulsion polymer shell and an alkali insoluble emulsion polymer core, which composition is stabilized by a surfactant of the formula R—(OCH2CH2)2-6OSO3?M+, where R is a linear, branched, or cyclic C8-C24 alkyl or C12-C18 aralkyl group and M+ is a counterion. The invention further relates to a method of preparing the composition and its use as a binder in coatings formulations. Formulations prepared with the soluble shell polymer composition have excellent freeze-thaw profiles and hiding.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: November 11, 2014
    Assignee: Rohm and Haas Company
    Inventors: Monica Luckenbach, Ozzie M. Pressley, Wei Zhang
  • Publication number: 20140329099
    Abstract: Methods of using inhibitor compounds are described. In particular, methods of using inhibitor compounds to inhibit the curing of a silicone composition that is a precursor of a silicone elastomer produced by a hydrosilylation reaction are described.
    Type: Application
    Filed: June 19, 2012
    Publication date: November 6, 2014
    Inventors: Sébastien Marrot, Yassine Maadadi
  • Patent number: 8871882
    Abstract: A method for the preparation of a fluoropolymer by means of emulsion polymerization of a reaction mixture in an aqueous medium is disclosed wherein the reaction mixture includes a fluoromonomer having the structure of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring; b) an emulsion stabilizer combination comprising: i) an anionic surfactant; and, ii) a cationic surfactant or a non-ionic surfactant; and, c) a free-radical initiator.
    Type: Grant
    Filed: February 14, 2012
    Date of Patent: October 28, 2014
    Assignee: Akron Polymer Systems, Inc.
    Inventors: Xiaoliang Zheng, Dong Zhang, Jiaokai Jing, Ted Calvin Germroth, Frank W. Harris, Thauming Kuo, Bin Wang, Douglas Stephens McWilliams
  • Publication number: 20140221568
    Abstract: Provision of a molding material excellent in molding accuracy without using a silicone resin and suitable for use in producing a molded body having high hardness and excellent appearance; a resin film formed from the molding material; a molded body obtained by using the molding material as a starting material; and a method for producing the molded body. A molding material used as a starting material in producing a molded body, containing a (meth)acrylic resin emulsion, a polyfunctional (meth)acrylic acid ester and a polymerization initiator; a resin film formed from the molding material; a molded body including a substrate and a molding material layer formed on the substrate wherein the molding material layer is formed from the molding material; and a method for producing the molded body.
    Type: Application
    Filed: July 3, 2012
    Publication date: August 7, 2014
    Applicant: NIPPON SHOKUBAI CO., LTD.
    Inventors: Teruo Kikuta, Kanji Nakao, Fuyuko Namimoto, Hironobu Akutagawa
  • Patent number: 8735492
    Abstract: An object of the present invention is to provide a method for producing a fluoropolymer which produces a large number of particles with a small particle size using a specific non-fluorous compound having surfactant ability. The method for producing a fluoropolymer includes aqueous dispersion polymerization of a monomer including at least one fluoroolefin in the presence of a compound (1) represented by the formula: CH2?CR1—R2—O-(AO)p—X (in the formula, R1 is hydrogen or an alkyl group; R2 is an alkylene group having two or more carbon atoms; AO is a linear or branched oxyalkylene group having 2 to 4 carbon atoms; p is a positive integer; X is H or SO3Y wherein Y is NH4 or an alkaline metal; and AO may be the same or different and may form two or more blocks if there is more than one AO.
    Type: Grant
    Filed: August 25, 2010
    Date of Patent: May 27, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Katsuhiko Imoto, Shumi Nishii, Yoshinari Fukuhara
  • Publication number: 20130066005
    Abstract: The present invention relates to a soluble shell polymer composition comprising an alkali soluble emulsion polymer shell and an alkali insoluble emulsion polymer core, which composition is stabilized by a surfactant of the formula R—(OCH2CH2)2-6OSO3?M+, where R is a linear, branched, or cyclic C8-C24 alkyl or C12-C18 aralkyl group and M+ is a counterion. The invention further relates to a method of preparing the composition and its use as a binder in coatings formulations. Formulations prepared with the soluble shell polymer composition have excellent freeze-thaw profiles and hiding.
    Type: Application
    Filed: August 29, 2012
    Publication date: March 14, 2013
    Inventors: Monica Luckenbach, Ozzie M. Pressley, Wei Zhang
  • Patent number: 8252425
    Abstract: An improved aqueous acrylic emulsion pressure sensitive adhesive composition of diminished foaming and being formulated from an aqueous acrylic emulsion including at least one carboxyl monomer having a residual carboxyl group, which residual carboxyl group is neutralized with a hydroxyl-functional amine, such as a trialkanolamine.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: August 28, 2012
    Assignee: Ashland Licensing and Intellectual Property LLC
    Inventors: Kang I. Lee, Keith D. King
  • Publication number: 20120157621
    Abstract: An object of the present invention is to provide a method for producing a fluoropolymer which produces a large number of particles with a small particle size using a specific non-fluorous compound having surfactant ability. The method for producing a fluoropolymer includes aqueous dispersion polymerization of a monomer including at least one fluoroolefin in the presence of a compound (1) represented by the formula: CH2?CR1—R2—O-(AO)p—X (in the formula, R1 is hydrogen or an alkyl group; R2 is an alkylene group having two or more carbon atoms; AO is a linear or branched oxyalkylene group having 2 to 4 carbon atoms; p is a positive integer; X is H or SO3Y wherein Y is NH4 or an alkaline metal; and AO may be the same or different and may form two or more blocks if there is more than one AO.
    Type: Application
    Filed: August 25, 2010
    Publication date: June 21, 2012
    Applicant: DAIKIN INDUSTRIES, LTD
    Inventors: Katsuhiko Imoto, Shumi Nishii, Yoshinari Fukuhara
  • Publication number: 20120136118
    Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.
    Type: Application
    Filed: November 28, 2011
    Publication date: May 31, 2012
    Applicant: Ethox Chemicals, LLC
    Inventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
  • Publication number: 20120136119
    Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.
    Type: Application
    Filed: November 28, 2011
    Publication date: May 31, 2012
    Applicant: Ethox Chemicals, LLC
    Inventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
  • Publication number: 20120108744
    Abstract: Provided are a polychloroprene latex composition giving immersion-molded articles superior in releasability from the mold during immersion molding and also superior in flexibility, a production method thereof and a molded article prepared by using the same. A polychloroprene latex composition containing an alkyldiphenyletherdisulfonic acid alkali-metal salt in an amount of 0.01 to 1.0 part by mass with respect to 100 parts by mass of a polychloroprene latex is prepared by emulsion polymerization of the monomer in the presence of a rosin acid alkali-metal salt and an alkyldiphenyletherdisulfonic acid alkali-metal salt each in an amount of 3 parts or less by mass with respect to 100 parts by mass of the monomer.
    Type: Application
    Filed: July 6, 2010
    Publication date: May 3, 2012
    Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHA
    Inventors: Ikuka Hashimoto, Misaki Tada, Kosuke Watanabe
  • Patent number: 8067513
    Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.
    Type: Grant
    Filed: August 11, 2008
    Date of Patent: November 29, 2011
    Assignee: Ethox Chemicals LLC
    Inventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
  • Patent number: 7687560
    Abstract: The present invention is a low-color plasticized PVB sheet and a process for preparing the same. The sheet of the present invention yields a YID measurement of less than 12. A sheet of the present invention is useful for making glass laminates that are useful in cars, boats, trains, buildings, and display cases, for example.
    Type: Grant
    Filed: March 11, 2003
    Date of Patent: March 30, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Donald L. Rymer, Nolan K. Read, III
  • Patent number: 7642307
    Abstract: The present invention describes laminate articles comprising a stiff, low-color PVB sheet having a YID of less than 12 and having a low concentration of plasticizer in the PVB composition, wherein the sheet is prepared from a composition that includes a PVB bleaching compound. A sheet of the present invention is useful for making glass laminates useful for parts in making cars, boats, trains, buildings, display cases, and other articles that utilize transparent glass laminates.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: January 5, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Bert C. Wong, Donald L. Rymer, Nolan K. Read, III
  • Patent number: 7339002
    Abstract: Removable, water-whitening resistant pressure sensitive adhesive (PSA) comprising a crosslinked aqueous emulsion polymer comprising (a) at least one hydrophobic monomer; (b) at least about 2 wt. % of at least one hydrophilic monomer; and (c) at least about 5 wt. % of at least one partially hydrophilic monomer; wherein the crosslinked aqueous emulsion polymer is crosslinked with an effective amount of at least one polyfunctional aziridine crosslinker, and the wt. % of monomers (a), (b), and (c) are based on the total weight of monomers (a), (b), and (c).
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: March 4, 2008
    Assignee: Cytec Surface Specialties, Inc.
    Inventors: Jong-Shing Guo, Augustin T. Chen, Sharon D. Trembley
  • Patent number: 7115682
    Abstract: Removable pressure sensitive adhesive compositions having enhanced resistance to water-whitening comprising a crosslinked aqueous emulsion polymer are disclosed. The crosslinked aqueous emulsion polymer comprises (a) at least one hydrophobic monomer; (b) greater than 1 wt. % of at least one hydrophilic monomer; (c) greater than 3 wt. % of at least one mono-olefinically unsaturated monomer having an aldehyde or ketone group; (d) optionally at least one partially hydrophilic monomer; and (e) an effective amount of at least one water-soluble or water-dispersible polymerizable surfactant; wherein the crosslinked aqueous emulsion polymer is crosslinked with an effective amount of at least one polyhydrazide crosslinker, the wt. % of monomers (a), (b), (c) and (d) are based on the total weight of monomers (a), (b), (c) and (d), and the mean particle size of the crosslinked aqueous emulsion polymer is less than about 400 nm.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: October 3, 2006
    Assignee: Cytec Surface Specialties, Inc.
    Inventors: Jong-Shing Guo, Augustin T. Chen, Sharon D. Trembley
  • Patent number: 7053146
    Abstract: The invention relates to compositions comprising copolymers based on acryloyldimethyltaurine and also synergistic additives selected from anionic, cationic, nonionic, and betaine surfactants. The compositions exhibit a pronounced thermoassociative behavior and are outstandingly suitable as thickeners. The copolymers of the present invention are useful in formulating cosmetics, pharmaceuticals, and oil field chemicals.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: May 30, 2006
    Assignee: Clariant GmbH
    Inventors: Roman Morschhäuser, Christoph Kayser, Matthias Löffler, Karl Heinz Heier, Aranka Tardi, Manfred Schade, Gernold Botthof
  • Patent number: 6870001
    Abstract: An emulsifier mixture comprising an emulsifier I of the formula in which X is O, S, CH2, NH or NR7, one or two of the radicals R1 to R6 are a group SO3?K? and the remainder of R1 to R6 are H or a C1-C18 alkyl group, R7 is a C1-C18 alkyl group and K is a countercation, an emulsifier II of the formula R8—O—(Z?O)n—SO3?K? in which the variables have the following meanings: R8: C1-C18 alkyl Z: CH2—CH2 or n: an integer from 1 to 50 K: a cation, and a nonionic emulsifier III.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: March 22, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Dirk Wulff, Gerhard Auchter
  • Patent number: 6827982
    Abstract: The adhesion of overlying layers to a silicalite-plus-binder dielectric layer is enhanced by forming a layer that includes the binder in a higher concentration. The overlying layer, e.g., silicon dioxide, silicon carbide or silicon nitride, adheres more tightly to the higher-concentration binder layer. Although the presence of the higher-concentration binder layer may increase the dielectric constant of the overall silicalite-plus-binder stack, the increase is generally minimal.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: December 7, 2004
    Assignee: Novellus Systems, Inc.
    Inventors: Judy Huang, Justin F. Gaynor, Archita Sengupta
  • Publication number: 20040192831
    Abstract: A removable, plasticizer resistant pressure sensitive composition that is particularly useful for PSA applications on plasticizer containing vinyl films is provided. The pressure sensitive adhesive comprises: (a) at least one hydrophobic monomer; (b) about 0.2 to about 10 wt. % of at least one hydrophilic monomer; (c) about 1 to about 40 wt.
    Type: Application
    Filed: March 31, 2003
    Publication date: September 30, 2004
    Inventors: Augustin T. Chen, Hui Liu, Leo Ternorutsky
  • Patent number: 6787594
    Abstract: The invention is the use of a glycolic acid adduct of sodium sulfite as the reducing agent in the redox couple for polymerization of vinyl acetate polymer based emulsions for nonwoven binders which contain formaldehyde, primarily from the self-crosslinking co-monomer N-methylolacrylamide.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: September 7, 2004
    Assignee: Air Products Polymers, L.P.
    Inventors: Joel Erwin Goldstein, Christian Leonard Daniels, Chung-Ling Mao
  • Patent number: 6489387
    Abstract: Acrylic emulsion PSA polymers which when cast as a film resist water whitening by hot or ambient temperature water are provided, and are formed by copolymerizing a monomer mixture comprising at least one alkyl acrylate ester of an alcohol containing at least four carbon atoms, at least one polar comonomer and at least one partially water soluble comonomer present in an amount of at least about 7% by weight of the monomers. Polymerization is carried out in the presence of at least one nonionic surfactant containing at least about 8 moles of ethylene oxide per mole nonionic surfactant and at least one anionic surfactant containing up to about 10 moles ethylene oxide per mole anionic surfactant. There is added to the product of polymerization at least one base to produce an emulsion having a pH greater than 7 and containing particles having a mean “volume-average” particle diameter of up to about 210 nm as determined by laser light scattering.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: December 3, 2002
    Assignee: Avery Dennison Corporation
    Inventors: Prakash Mallya, Xing-Ya Li, Colin C. Smith, George Dilts, Kregg D. Albrecht, Joseph T. Tenhagen, Robert D. Petrasko
  • Publication number: 20020104460
    Abstract: The current invention relates to a coating composition comprising a polyisocyanate compound, a hydroxyl-functional film-forming polymer, and a nonvolatile branched monoalcohol. An aliphatic branched monoalcohol is preferred. More preferred are long chain non-volatile branched monoalcohols. This results in coating compositions that have improved flow behavior and that produce coatings having improved appearance without an adverse effect on other properties.
    Type: Application
    Filed: August 10, 2001
    Publication date: August 8, 2002
    Inventors: Antonius H.G. Van Engelen, Alexander Leo Yahkind
  • Patent number: 6380302
    Abstract: The present invention provides a surfactant composition for emulsion polymerization. The surfactant composition for emulsion polymerization comprises a compound (a) represented by the formula (I) and having a critical micelle concentration (CMC) in the range of from not less than 0.007 mol L−1 to not more than 0.1 mol L−1 and a compound (b) represented by the formula (II) and having a CMC in the range of from not less than 1×10−5 mol L−1 to less than 0.007 mol L−1, as essential components, and the molar ratio of the components (a) to (b) in terms of (a)/(b) is from 5/95 to 75/25: R1O—(A1O)m—SO3M1  (I) R2O—(A2O)n—SO3M2  (II) (in the formulae, R1 and R2 are monovalent aliphatic hydrocarbon groups; A1 and A2 are alkylene groups having 2 to 4 carbons; m and n are numbers from 1 to 50; and M1 and M2 are monovalent cations).
    Type: Grant
    Filed: February 28, 2000
    Date of Patent: April 30, 2002
    Assignee: Kao Corporation
    Inventors: Takayuki Ikenaga, Atsuhito Mori, Hiroyuki Aizawa, Hiroki Sawada, Yasuo Ishii, Yoshinori Mitsuda
  • Patent number: 6319980
    Abstract: An organic silicon compound emulsion for quickly imparting excellent water-repellent properties to the surfaces of porous inorganic base materials such as concrete, mortar, and masonry. The emulsion is prepared by the steps of emulsifying a mixture consisting of (A) an organoalkoxysilane, (B) an organopolysiloxane having in its molecule at least 2 alkoxy groups or hydroxyl groups bonded to a silicon atom, (C) an anionic emulsifying agent, and (D) water, and heat aging the emulsion at a temperature below 100° C. In another embodiment, the method comprises the steps emulsifying a mixture of the components (A) to (D) and adding an acidic or alkaline substance to the emulsion. In a third embodiment, the method comprises the steps of forming a mixture consisting of the components (A) to (D), adding an acidic or alkaline substance thereto, and performing the emulsification thereafter.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: November 20, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Hiroki Ishikawa, Atsushi Sakuma, Tsutomu Naganawa, Naohiro Muramoto, Isao Ona
  • Publication number: 20010003765
    Abstract: Acrylic emulsion PSA polymers which when cast as a film resist water whitening by hot or ambient temperature water are provided, and are formed by copolymerizing a monomer mixture comprising at least one alkyl acrylate ester of an alcohol containing at least four carbon atoms, at least one polar comonomer and at least one partially water soluble comonomer present in an amount of at least about 7% by weight of the monomers. Polymerization is carried out in the presence of at least one nonionic surfactant containing at least about 8 moles of ethylene oxide per mole nonionic surfactant and at least one anionic surfactant containing up to about 10 moles ethylene oxide per mole anionic surfactant. There is added to the product of polymerization at least one base to produce an emulsion having a pH greater than 7 and containing particles having a mean “volume-average” particle diameter of up to about 210 nm as determined by laser light scattering.
    Type: Application
    Filed: March 28, 1997
    Publication date: June 14, 2001
    Applicant: Prakash Mallya
    Inventors: PRAKASH MALLYA, XING-YA LI, COLIN C. SMITH, GEORGE DILTS, KREGG D. ALBRECHT, JOSEPH T. TENHAGEN, ROBERT D. PETRASKO
  • Patent number: 6147165
    Abstract: Inherently tacky, pressure-sensitive adhesive compositions useful in marking film applications are provided. The compositions comprise polymer particles prepared by emulsion polymerization of at least one monomer mixture. The monomer mixture comprises at least one alkyl acrylate, the alkyl group of which has from about 4 to 12 carbon atoms, preferably in an amount of from about 73% to 90% by weight, at least one unsaturated carboxylic acid containing from about 3 to 5 carbon atoms, preferably in an amount of from about 2% to 12% by weight, and at least one hard monomer, preferably present in an amount of from about 5% to 15% by weight. The particles have a mean diameter of about 300 nm or less, as determined by laser light scattering. Preferably the hard monomer comprises a styrenic monomer, more preferably both a styrenic monomer and an alkyl methacrylate. In some embodiments, the compositions are prepared by sequential polymerization of the first and second monomer charges.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: November 14, 2000
    Assignee: Avery Dennison Corporation
    Inventors: Ivan S. P. Lee, Graham Yeadon, Paul Keller
  • Patent number: 6133372
    Abstract: Aqueous polymer dispersions are produced by polymerizing monoethylenically unsaturated monomers bearing acid groups in an acid, partially or totally neutralized form, optionally with other monomers that can be copolymnerized therewith in the presence of hydrophilized vegetable, animal and/or synthetic fats or oils. Also disclosed is a process for preparing the same, their use for preparing oil-in-water emulsions by admixture of another oil phase composed of vegetable, animal or synthetic oils and/of fats and/or non-self-emulsifying silicones, and their use in the field of wet currying of leather or pelts.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: October 17, 2000
    Assignee: Stockhausen GmbH & Co. KG
    Inventors: Helmut Lohmann, Thomas Muller, Waldemar Inger, Stephan Ramlow
  • Patent number: 6036869
    Abstract: A method for improving the flocculation of suspended solids in a Bayer process liquor in a primary settler stage. The method includes the step of adding to a primary settler feed a composition including water-continuous polymer, said polymer being hydrolyzable in a Bayer process liquor to an acid form, said acid form being an active red mud flocculent. A novel emulsion, and a polymerization technique for obtaining high molecular weight emulsions are also disclosed.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: March 14, 2000
    Assignee: Nalco Chemical Company
    Inventors: Radhakrishnan Selvarajan, Everett C. Phillips
  • Patent number: 5620796
    Abstract: A method of producing an acrylic emulsion adhesive characterized in that a composition comprising 100 parts by weight of a monomeric mixture of alkyl (meth)acrylate, acrylic acid, methacrylic acid and N-vinylpyrrolidone, 0.5-2 parts by weight of a surfactant mixture of an anionic surfactant and a nonionic surfactant, and 0.03 to 0.5 part by weight of a polymerization initiator is subjected to emulsion polymerization reaction. The acrylic emulsion adhesive of this invention is rich in solids, features good adhesion and cohesion as well as high water resistance. Therefore, by coating one side of a transparent support, this adhesive can be used as an adhesive sheet for surface protection.
    Type: Grant
    Filed: April 10, 1995
    Date of Patent: April 15, 1997
    Assignee: Sekisui Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kazuhiro Kawabata, Norio Numata
  • Patent number: 5616645
    Abstract: The present invention relates to a gelled fluoride resin fine particle dispersion for use as a coating, to a method of production thereof, and to a method using this gelled fluoride resin fine dispersion to protect an alkaline inorganic hardened body.The objective of the present invention is to provide an aqueous resin for use as a coating, this aqueous resin being able to form a high performance coating film that is superior in its ability to inhibit the leaching out of the alkaline substance from the alkaline inorganic hardened body, which has excellent weatherability, water resistance, alkaline resistance, and dirt picking resistance.The present invention accomplishes the stated objective through the utilization of gelled fine particles of a fluorine containing resin.The present invention may be used in the coating field.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: April 1, 1997
    Assignee: Dainippon Ink & Chemicals, Inc.
    Inventors: Shin'ichi Kuwamura, Yoshinobu Deguchi, Tokio Goto, Fumio Yoshino
  • Patent number: 5401801
    Abstract: There is disclosed a novel silicone emulsion useful as a mold coating in aluminum die casting operations. The silicone emulsion of the invention comprises an aqueous dispersion of an organopolysiloxane of a particular general formula in combination with an alkyl diphenyl ether disulfate salt. The novel silicone emulsion of the invention exhibits stability even when diluted tens of times and subjected to mechanical shear. When applied to a heated mold surface, water is driven from the silicone emulsion and there is formed a oil film. The oil film allows for easy release of the cast part. Furthermore, the film exhibits good paintability and lubricity under extreme pressure.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: March 28, 1995
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Tsutomu Naganawa, Isao Ona
  • Patent number: 5322886
    Abstract: Polychloroprene latexes, well suited for the production of adhesives, are prepared by (co)polymerizing chloroprene, in aqueous emulsion, in the presence of a free-radical initiator and at least one emulsifying agent, said aqueous emulsion further comprising (a) at least one non-carboxylic ionic surfactant and (b) at least two nonionic surfactants, the HLB values thereof differing by at least 3 units.
    Type: Grant
    Filed: May 13, 1991
    Date of Patent: June 21, 1994
    Assignee: Distugil
    Inventor: Francois Sauterey
  • Patent number: 5238992
    Abstract: A process for preparing solid polymer blends and composites of controlled porosity in microemulsions containing both hydrophilic and hydrophobic phases. The microemulsions are prepared with surfactant systems that may include a cosolvent as a part thereof, together with a hydrophilic monomer, or monomers, dissolved in the hydrophilic phase of the microemulsion, and a hydrophobic monomer, or monomers, dissolved in the hydrophobic phase. Polymerization of the monomers thus present is carried out to provide highly uniform dispersions of the resulting polymers in each other. The invention allows for the control of the morphology of the blends, the improvement in compatability of otherwise incompatible polymers, and improvements in the processability of the polymers due to enhanced thermal and mechanical properties.
    Type: Grant
    Filed: August 26, 1992
    Date of Patent: August 24, 1993
    Assignee: Edison Polymer Innovation Corporation
    Inventor: Syed Outubuddin
  • Patent number: 5187217
    Abstract: Process for the production of a plasticized polyvinyl butyral particularly used for gluing a base onto glazings. The polyvinyl butyral is obtained by the reaction of a butyric aldehyde with a polyvinyl alcohol, demonstrating a level of hydrolysis greater than 95%, and a viscosity greater than 50 cP, in the presence of an acid catalyst and an emulsifier, the quantity of butyric aldehyde being such that the level of hydroxylation of the polyvinyl butyral obtained is between 22 and 26%.
    Type: Grant
    Filed: July 24, 1991
    Date of Patent: February 16, 1993
    Assignee: Saint-Gobain Vitrage
    Inventors: Robert Degeilh, Daniel Dages
  • Patent number: 5109063
    Abstract: A process for making an aqueous vinyl acetate/ethylene/N-methylolacrylamide copolymer emulsion comprising:(a) adding an initial charge containing all the vinyl acetate monomer to be polymerized and an effective amount of an emulsifying system consisting essentially of an anionic surfactant, especially a salt of an alkylphenoxy poly(ethyleneoxy) sulfate containing about 3-5 ethyleneoxy units,(b) pressurizing the reactor with sufficient ethylene to yield a copolymer having the desired Tg,(c) initiating polymerization at a temperature from 45.degree. to 85.degree. C., and(d) continuing polymerization at a temperature from 45.degree. to 85.degree. C., while continuously adding N-methylolacrylamide over a period of time such that the free vinyl acetate monomer content of the reaction medium is about 2-4% upon completion of the N-methylolacrylamide addition.
    Type: Grant
    Filed: December 10, 1990
    Date of Patent: April 28, 1992
    Assignee: Air Products and Chemicals, Inc
    Inventors: Tze-Chiang Cheng, Phillip A. Mango
  • Patent number: 4970251
    Abstract: A stable latex composition possessing a viscosity of less than about 50 cp. comprised of an ethylacrylate/methylacrylic acid/acrylic acid polymer and co-surfactant system comprising a nonylphenol polyethylene oxide ether sulfate and a propoxylated, ethoxylated propylene glycol nonionic surfactant block polymr useful for increasing the viscosity of water that is injected into subterranean petroleum bearing formations for the enhanced recovery of the petroleum.
    Type: Grant
    Filed: June 5, 1989
    Date of Patent: November 13, 1990
    Assignee: Union Oil Company of California
    Inventor: Wen-Ching Hsieh
  • Patent number: 4929668
    Abstract: Aqueous synthetic dispersions based on copolymers of acryl polymers and/or vinyl polymers containing both hydroxylalkyl(meth)acrylate monomers and etherified N-alkylol(meth)acrylamide monomers. These dispersions are suitable as bonding agents for the production of glossy and solvent-resistant, thermosetting coating materials with good adhesion.
    Type: Grant
    Filed: July 21, 1988
    Date of Patent: May 29, 1990
    Assignee: Deutsche Texaco Aktiengesellschaft
    Inventors: Winfried Zeibig, Heinrich Huskes
  • Patent number: 4891398
    Abstract: A fiber treatment composition comprising an aqueous dispersion containing;(A) 100 parts by weight of a finely particulate epoxy group-containing organosilasesquioxane substantially represented by general unit formula (I):R.sup.1 SiO.sub.3/2 (I)wherein said organic group having an epoxy group comprises from 0.1 to 50 mol % of the whole R.sup.1 ; and;(B) from 10 to 900 parts by weight of an amino group-containing organopolysiloxane represented by general unit formula (II): ##EQU1## wherein R.sup.2 is a monovalent hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group or a hydroxyl group; Z is a particular amino group; and 1<a<3, 0<b<1 and 1<a+b<3. This composition is useful for deepening colors of dyed textiles and fabrics and improving softness and feeling, even with respect to synthetic fibers.
    Type: Grant
    Filed: August 12, 1988
    Date of Patent: January 2, 1990
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masaki Tanaka, Hiroshi Ohashi
  • Patent number: 4808648
    Abstract: A stable latex composition possessing a viscosity of less than about 50 cp. comprised of an ethylacrylane/methylacrylic acid/acrylic acid polymer and a nonylphenol polyethylene oxide ether sulfate useful for increasing the viscosity of water that is injected into subterranean petroleum bearing formations for the enhanced recovery of the petroleum.
    Type: Grant
    Filed: November 20, 1984
    Date of Patent: February 28, 1989
    Assignee: Union Oil Company of California
    Inventor: Wen-Ching Hsieh
  • Patent number: 4795772
    Abstract: A stable latex composition possessing a viscosity of less than about 50 cp. comprised of an ethylacrylate/methylacrylic acid/ acrylic acid polymer and co-surfactant system comprising a nonylphenol polyethylene oxide ether sulfate and a propoxylated, ethoxylated propylene glycol nonionic surfactant block polymer useful for increasing the viscosity of water that is injected into subterranean petroleum bearing formations for the enhanced recovery of the petroleum.
    Type: Grant
    Filed: September 8, 1987
    Date of Patent: January 3, 1989
    Assignee: Union Oil Company of California
    Inventor: Wen-Ching Hsieh
  • Patent number: 4785048
    Abstract: An improved process for the production of microcapsules by the use of hydrogen transfer polymerization in the presence of a mixture of emulsifiers including either an aqueous solution of a sodium salt of naphthalene-sulfonic acid-formaldehyde condensate or diphenyloxide disulfonate with a polyvinyl alcohol. The process is particularly useful for the production of microcapsules containing a colorless dye intermediate used in carbonless copy paper (CCP) applications.
    Type: Grant
    Filed: February 8, 1988
    Date of Patent: November 15, 1988
    Assignee: Moore Business Forms, Inc.
    Inventor: Hung-Ya Chao
  • Patent number: 4771098
    Abstract: Acrylic resin dispersions are prepared by a monomer addition process in the presence of a free-radical initiator and an emulsifier, wherein a portion of the emulsifier is dissolved in the initial aqueous phase and the remaining portion in the added monomer phase. The new process decreases the formation of coagulates, reduces the required amount of emulsifier, and allows the preparation of dispersions of resins incorporating a large proportion of units derived from water-soluble monomers, such as carboxylic acids.
    Type: Grant
    Filed: November 25, 1986
    Date of Patent: September 13, 1988
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Werner Siol, Hubert Rauch, Norbert Sutterlin
  • Patent number: 4753973
    Abstract: A stable latex composition possessing a viscosity of less than about 50 cp. comprised of an ethylacrylate/methylacrylic acid/acrylic acid polymer and co-surfactant system comprising a nonylphenol polyethylene oxide ether sulfate and a propoxylated, ethoxylated propylene glycol nonionic surfactant block polymer useful for increasing the viscosity of water that is injected into subterranean petroleum bearing formations for the enhanced recovery of the petroleum.
    Type: Grant
    Filed: June 27, 1985
    Date of Patent: June 28, 1988
    Assignee: Union Oil Company of California
    Inventor: Wen-Ching Hsieh