Containing Ether Or Hydroxyl Group Dnrm Patents (Class 524/747)
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Patent number: 11118074Abstract: The present invention aims to provide a coating material which has high mechanical stability and is capable of providing a coat which has excellent appearance and exhibits excellent damping properties in a wide temperature range. The present invention relates to a damping-imparting agent including a compound having a sulfosuccinic acid (salt) structure. The present invention also relates to a resin composition for damping materials, including an emulsion prepared by polymerizing a monomer component, the composition further including a component having a sulfosuccinic acid (salt) structure.Type: GrantFiled: March 30, 2016Date of Patent: September 14, 2021Assignee: Nippon Shokubai Co., Ltd.Inventor: Yukihiro Miyawaki
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Patent number: 9902817Abstract: Disclosed herein is a polyvinyl chloride resin, including: a first particle group having a particle diameter of 0.01 ?m or more and less than 1 ?m; and a second particle group having a particle diameter of 1 to 10 ?m, wherein the volume ratio of the first particle group to the second particle group is 1:0.4 to 1:1.Type: GrantFiled: November 1, 2013Date of Patent: February 27, 2018Assignee: Hanwha Chemical CorporationInventors: Jeong Hwan Ko, Jung Ho Kong, Ji Eun Namgoong
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Patent number: 9376509Abstract: An extended anionic surfactant having the general formula: RO—(PO)n-YZ wherein R is a linear alkyl chain ranging from C6 to C36, a branched alkyl chain ranging from C6 to C36, or a mixture thereof; PO is a propyleneoxy group; Y is —SO3, —CH2CH2CH2—SO3, —CH2CH(CH3)—SO3, or —CH2COO; Z is a cation; and n is 1 to 50.Type: GrantFiled: August 24, 2012Date of Patent: June 28, 2016Assignee: Sasol Performance Chemicals, GmbHInventors: Melanie Anne Sharp, Oliver Herzog, Sebastiano Giovanni Giordano, Teresa Linville Marino, Kip Douglas Sharp
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Patent number: 9296849Abstract: An object of the present invention is to provide a polychloroprene latex with improved rubber coagulability that gives a film superior in strength by dip molding, a polychloroprene latex composition, and a molded article. The polychloroprene latex is prepared by polymerization of 2-chloro-1,3-butadiene alone or by polymerization of raw monomers at least containing 2 -chloro-1,3-butadiene and 2,3-dichloro 1,3-butadiene and has a precipitation rate of 5 to 40%, as calculated according to Equation (I). In Equation (I), A is the mass (g) of the dry product, which is obtained by adding 50 ml of saturated aqueous solution of calcium hydroxide at 23° C. to 50 g of a latex having a solid matter concentration adjusted to 45 to 65 mass % at a liquid temperature of 23° C. over 2 minutes, filtering and collecting the generated precipitate with a 80 -mesh wire mesh, and drying the precipitate at 110° C.Type: GrantFiled: March 1, 2013Date of Patent: March 29, 2016Assignee: DENKA COMPANY LIMITEDInventors: Hidehito Otsuka, Kiyoshi Sunada, Kenji Mochizuki, Toru Shiraiwa
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Patent number: 9029470Abstract: Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive, have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions can be prepared by mixing an ethylenically unsaturated monomer component and a stabilizer comprising a strong acid, in a carrier to form a monomer emulsion, reacting the monomer emulsion with an initiator to form the latex emulsion, and reacting the latex emulsion with a neutralizer. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.Type: GrantFiled: February 22, 2010Date of Patent: May 12, 2015Assignee: Akzo Nobel Coatings International B.V.Inventors: Jude Thomas Rademacher, Gary Charles Pompignano, Willy P Kulhanek
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Publication number: 20140348887Abstract: A stable, aqueous composition containing a crosslinked, nonionic, amphiphilic polymer capable of forming a yield stress fluid in the presence of a surfactant is disclosed. The yield stress fluid is capable of suspending insoluble materials in the form of particulates and/or droplets requiring suspension or stabilization.Type: ApplicationFiled: September 13, 2012Publication date: November 27, 2014Applicant: Lubrizol Advanced Materials, Inc.Inventors: Shui-Jen Raymond Hsu, Krishnan Chari, Wei-Yeih Yang, Prachur Bhargava, Murat Kadir
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Patent number: 8883880Abstract: The present invention relates to a soluble shell polymer composition comprising an alkali soluble emulsion polymer shell and an alkali insoluble emulsion polymer core, which composition is stabilized by a surfactant of the formula R—(OCH2CH2)2-6OSO3?M+, where R is a linear, branched, or cyclic C8-C24 alkyl or C12-C18 aralkyl group and M+ is a counterion. The invention further relates to a method of preparing the composition and its use as a binder in coatings formulations. Formulations prepared with the soluble shell polymer composition have excellent freeze-thaw profiles and hiding.Type: GrantFiled: August 29, 2012Date of Patent: November 11, 2014Assignee: Rohm and Haas CompanyInventors: Monica Luckenbach, Ozzie M. Pressley, Wei Zhang
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Publication number: 20140329099Abstract: Methods of using inhibitor compounds are described. In particular, methods of using inhibitor compounds to inhibit the curing of a silicone composition that is a precursor of a silicone elastomer produced by a hydrosilylation reaction are described.Type: ApplicationFiled: June 19, 2012Publication date: November 6, 2014Inventors: Sébastien Marrot, Yassine Maadadi
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Patent number: 8871882Abstract: A method for the preparation of a fluoropolymer by means of emulsion polymerization of a reaction mixture in an aqueous medium is disclosed wherein the reaction mixture includes a fluoromonomer having the structure of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring; b) an emulsion stabilizer combination comprising: i) an anionic surfactant; and, ii) a cationic surfactant or a non-ionic surfactant; and, c) a free-radical initiator.Type: GrantFiled: February 14, 2012Date of Patent: October 28, 2014Assignee: Akron Polymer Systems, Inc.Inventors: Xiaoliang Zheng, Dong Zhang, Jiaokai Jing, Ted Calvin Germroth, Frank W. Harris, Thauming Kuo, Bin Wang, Douglas Stephens McWilliams
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Publication number: 20140221568Abstract: Provision of a molding material excellent in molding accuracy without using a silicone resin and suitable for use in producing a molded body having high hardness and excellent appearance; a resin film formed from the molding material; a molded body obtained by using the molding material as a starting material; and a method for producing the molded body. A molding material used as a starting material in producing a molded body, containing a (meth)acrylic resin emulsion, a polyfunctional (meth)acrylic acid ester and a polymerization initiator; a resin film formed from the molding material; a molded body including a substrate and a molding material layer formed on the substrate wherein the molding material layer is formed from the molding material; and a method for producing the molded body.Type: ApplicationFiled: July 3, 2012Publication date: August 7, 2014Applicant: NIPPON SHOKUBAI CO., LTD.Inventors: Teruo Kikuta, Kanji Nakao, Fuyuko Namimoto, Hironobu Akutagawa
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Patent number: 8735492Abstract: An object of the present invention is to provide a method for producing a fluoropolymer which produces a large number of particles with a small particle size using a specific non-fluorous compound having surfactant ability. The method for producing a fluoropolymer includes aqueous dispersion polymerization of a monomer including at least one fluoroolefin in the presence of a compound (1) represented by the formula: CH2?CR1—R2—O-(AO)p—X (in the formula, R1 is hydrogen or an alkyl group; R2 is an alkylene group having two or more carbon atoms; AO is a linear or branched oxyalkylene group having 2 to 4 carbon atoms; p is a positive integer; X is H or SO3Y wherein Y is NH4 or an alkaline metal; and AO may be the same or different and may form two or more blocks if there is more than one AO.Type: GrantFiled: August 25, 2010Date of Patent: May 27, 2014Assignee: Daikin Industries, Ltd.Inventors: Katsuhiko Imoto, Shumi Nishii, Yoshinari Fukuhara
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Publication number: 20130066005Abstract: The present invention relates to a soluble shell polymer composition comprising an alkali soluble emulsion polymer shell and an alkali insoluble emulsion polymer core, which composition is stabilized by a surfactant of the formula R—(OCH2CH2)2-6OSO3?M+, where R is a linear, branched, or cyclic C8-C24 alkyl or C12-C18 aralkyl group and M+ is a counterion. The invention further relates to a method of preparing the composition and its use as a binder in coatings formulations. Formulations prepared with the soluble shell polymer composition have excellent freeze-thaw profiles and hiding.Type: ApplicationFiled: August 29, 2012Publication date: March 14, 2013Inventors: Monica Luckenbach, Ozzie M. Pressley, Wei Zhang
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Patent number: 8252425Abstract: An improved aqueous acrylic emulsion pressure sensitive adhesive composition of diminished foaming and being formulated from an aqueous acrylic emulsion including at least one carboxyl monomer having a residual carboxyl group, which residual carboxyl group is neutralized with a hydroxyl-functional amine, such as a trialkanolamine.Type: GrantFiled: December 12, 2007Date of Patent: August 28, 2012Assignee: Ashland Licensing and Intellectual Property LLCInventors: Kang I. Lee, Keith D. King
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Publication number: 20120157621Abstract: An object of the present invention is to provide a method for producing a fluoropolymer which produces a large number of particles with a small particle size using a specific non-fluorous compound having surfactant ability. The method for producing a fluoropolymer includes aqueous dispersion polymerization of a monomer including at least one fluoroolefin in the presence of a compound (1) represented by the formula: CH2?CR1—R2—O-(AO)p—X (in the formula, R1 is hydrogen or an alkyl group; R2 is an alkylene group having two or more carbon atoms; AO is a linear or branched oxyalkylene group having 2 to 4 carbon atoms; p is a positive integer; X is H or SO3Y wherein Y is NH4 or an alkaline metal; and AO may be the same or different and may form two or more blocks if there is more than one AO.Type: ApplicationFiled: August 25, 2010Publication date: June 21, 2012Applicant: DAIKIN INDUSTRIES, LTDInventors: Katsuhiko Imoto, Shumi Nishii, Yoshinari Fukuhara
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Publication number: 20120136119Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.Type: ApplicationFiled: November 28, 2011Publication date: May 31, 2012Applicant: Ethox Chemicals, LLCInventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
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Publication number: 20120136118Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.Type: ApplicationFiled: November 28, 2011Publication date: May 31, 2012Applicant: Ethox Chemicals, LLCInventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
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Publication number: 20120108744Abstract: Provided are a polychloroprene latex composition giving immersion-molded articles superior in releasability from the mold during immersion molding and also superior in flexibility, a production method thereof and a molded article prepared by using the same. A polychloroprene latex composition containing an alkyldiphenyletherdisulfonic acid alkali-metal salt in an amount of 0.01 to 1.0 part by mass with respect to 100 parts by mass of a polychloroprene latex is prepared by emulsion polymerization of the monomer in the presence of a rosin acid alkali-metal salt and an alkyldiphenyletherdisulfonic acid alkali-metal salt each in an amount of 3 parts or less by mass with respect to 100 parts by mass of the monomer.Type: ApplicationFiled: July 6, 2010Publication date: May 3, 2012Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHAInventors: Ikuka Hashimoto, Misaki Tada, Kosuke Watanabe
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Patent number: 8067513Abstract: The present invention relates to the use of Styrenated Phenol Ethoxylates as surfactants in emulsion polymerization. The present invention further relates to the use of both anionic and nonionic Styrenated Phenol Ethoxylates in emulsion polymerization. Latexes with small average particle and narrow particle size distributions are obtained. Prepared latexes also have low coagulum levels and exhibit excellent mechanical and chemical stability.Type: GrantFiled: August 11, 2008Date of Patent: November 29, 2011Assignee: Ethox Chemicals LLCInventors: Lawrence C. Davis, Edward R. Godwin, Charles V. Hinton, James T. Tanner
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Patent number: 7687560Abstract: The present invention is a low-color plasticized PVB sheet and a process for preparing the same. The sheet of the present invention yields a YID measurement of less than 12. A sheet of the present invention is useful for making glass laminates that are useful in cars, boats, trains, buildings, and display cases, for example.Type: GrantFiled: March 11, 2003Date of Patent: March 30, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Donald L. Rymer, Nolan K. Read, III
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Patent number: 7642307Abstract: The present invention describes laminate articles comprising a stiff, low-color PVB sheet having a YID of less than 12 and having a low concentration of plasticizer in the PVB composition, wherein the sheet is prepared from a composition that includes a PVB bleaching compound. A sheet of the present invention is useful for making glass laminates useful for parts in making cars, boats, trains, buildings, display cases, and other articles that utilize transparent glass laminates.Type: GrantFiled: January 30, 2006Date of Patent: January 5, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Bert C. Wong, Donald L. Rymer, Nolan K. Read, III
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Patent number: 7339002Abstract: Removable, water-whitening resistant pressure sensitive adhesive (PSA) comprising a crosslinked aqueous emulsion polymer comprising (a) at least one hydrophobic monomer; (b) at least about 2 wt. % of at least one hydrophilic monomer; and (c) at least about 5 wt. % of at least one partially hydrophilic monomer; wherein the crosslinked aqueous emulsion polymer is crosslinked with an effective amount of at least one polyfunctional aziridine crosslinker, and the wt. % of monomers (a), (b), and (c) are based on the total weight of monomers (a), (b), and (c).Type: GrantFiled: September 25, 2003Date of Patent: March 4, 2008Assignee: Cytec Surface Specialties, Inc.Inventors: Jong-Shing Guo, Augustin T. Chen, Sharon D. Trembley
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Patent number: 7115682Abstract: Removable pressure sensitive adhesive compositions having enhanced resistance to water-whitening comprising a crosslinked aqueous emulsion polymer are disclosed. The crosslinked aqueous emulsion polymer comprises (a) at least one hydrophobic monomer; (b) greater than 1 wt. % of at least one hydrophilic monomer; (c) greater than 3 wt. % of at least one mono-olefinically unsaturated monomer having an aldehyde or ketone group; (d) optionally at least one partially hydrophilic monomer; and (e) an effective amount of at least one water-soluble or water-dispersible polymerizable surfactant; wherein the crosslinked aqueous emulsion polymer is crosslinked with an effective amount of at least one polyhydrazide crosslinker, the wt. % of monomers (a), (b), (c) and (d) are based on the total weight of monomers (a), (b), (c) and (d), and the mean particle size of the crosslinked aqueous emulsion polymer is less than about 400 nm.Type: GrantFiled: September 25, 2003Date of Patent: October 3, 2006Assignee: Cytec Surface Specialties, Inc.Inventors: Jong-Shing Guo, Augustin T. Chen, Sharon D. Trembley
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Patent number: 7053146Abstract: The invention relates to compositions comprising copolymers based on acryloyldimethyltaurine and also synergistic additives selected from anionic, cationic, nonionic, and betaine surfactants. The compositions exhibit a pronounced thermoassociative behavior and are outstandingly suitable as thickeners. The copolymers of the present invention are useful in formulating cosmetics, pharmaceuticals, and oil field chemicals.Type: GrantFiled: November 28, 2001Date of Patent: May 30, 2006Assignee: Clariant GmbHInventors: Roman Morschhäuser, Christoph Kayser, Matthias Löffler, Karl Heinz Heier, Aranka Tardi, Manfred Schade, Gernold Botthof
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Patent number: 6870001Abstract: An emulsifier mixture comprising an emulsifier I of the formula in which X is O, S, CH2, NH or NR7, one or two of the radicals R1 to R6 are a group SO3?K? and the remainder of R1 to R6 are H or a C1-C18 alkyl group, R7 is a C1-C18 alkyl group and K is a countercation, an emulsifier II of the formula R8—O—(Z?O)n—SO3?K? in which the variables have the following meanings: R8: C1-C18 alkyl Z: CH2—CH2 or n: an integer from 1 to 50 K: a cation, and a nonionic emulsifier III.Type: GrantFiled: April 18, 2002Date of Patent: March 22, 2005Assignee: BASF AktiengesellschaftInventors: Dirk Wulff, Gerhard Auchter
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Patent number: 6827982Abstract: The adhesion of overlying layers to a silicalite-plus-binder dielectric layer is enhanced by forming a layer that includes the binder in a higher concentration. The overlying layer, e.g., silicon dioxide, silicon carbide or silicon nitride, adheres more tightly to the higher-concentration binder layer. Although the presence of the higher-concentration binder layer may increase the dielectric constant of the overall silicalite-plus-binder stack, the increase is generally minimal.Type: GrantFiled: April 30, 2002Date of Patent: December 7, 2004Assignee: Novellus Systems, Inc.Inventors: Judy Huang, Justin F. Gaynor, Archita Sengupta
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Publication number: 20040192831Abstract: A removable, plasticizer resistant pressure sensitive composition that is particularly useful for PSA applications on plasticizer containing vinyl films is provided. The pressure sensitive adhesive comprises: (a) at least one hydrophobic monomer; (b) about 0.2 to about 10 wt. % of at least one hydrophilic monomer; (c) about 1 to about 40 wt.Type: ApplicationFiled: March 31, 2003Publication date: September 30, 2004Inventors: Augustin T. Chen, Hui Liu, Leo Ternorutsky
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Patent number: 6787594Abstract: The invention is the use of a glycolic acid adduct of sodium sulfite as the reducing agent in the redox couple for polymerization of vinyl acetate polymer based emulsions for nonwoven binders which contain formaldehyde, primarily from the self-crosslinking co-monomer N-methylolacrylamide.Type: GrantFiled: October 30, 2000Date of Patent: September 7, 2004Assignee: Air Products Polymers, L.P.Inventors: Joel Erwin Goldstein, Christian Leonard Daniels, Chung-Ling Mao
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Patent number: 6489387Abstract: Acrylic emulsion PSA polymers which when cast as a film resist water whitening by hot or ambient temperature water are provided, and are formed by copolymerizing a monomer mixture comprising at least one alkyl acrylate ester of an alcohol containing at least four carbon atoms, at least one polar comonomer and at least one partially water soluble comonomer present in an amount of at least about 7% by weight of the monomers. Polymerization is carried out in the presence of at least one nonionic surfactant containing at least about 8 moles of ethylene oxide per mole nonionic surfactant and at least one anionic surfactant containing up to about 10 moles ethylene oxide per mole anionic surfactant. There is added to the product of polymerization at least one base to produce an emulsion having a pH greater than 7 and containing particles having a mean “volume-average” particle diameter of up to about 210 nm as determined by laser light scattering.Type: GrantFiled: March 28, 1997Date of Patent: December 3, 2002Assignee: Avery Dennison CorporationInventors: Prakash Mallya, Xing-Ya Li, Colin C. Smith, George Dilts, Kregg D. Albrecht, Joseph T. Tenhagen, Robert D. Petrasko
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Publication number: 20020104460Abstract: The current invention relates to a coating composition comprising a polyisocyanate compound, a hydroxyl-functional film-forming polymer, and a nonvolatile branched monoalcohol. An aliphatic branched monoalcohol is preferred. More preferred are long chain non-volatile branched monoalcohols. This results in coating compositions that have improved flow behavior and that produce coatings having improved appearance without an adverse effect on other properties.Type: ApplicationFiled: August 10, 2001Publication date: August 8, 2002Inventors: Antonius H.G. Van Engelen, Alexander Leo Yahkind
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Patent number: 6380302Abstract: The present invention provides a surfactant composition for emulsion polymerization. The surfactant composition for emulsion polymerization comprises a compound (a) represented by the formula (I) and having a critical micelle concentration (CMC) in the range of from not less than 0.007 mol L−1 to not more than 0.1 mol L−1 and a compound (b) represented by the formula (II) and having a CMC in the range of from not less than 1×10−5 mol L−1 to less than 0.007 mol L−1, as essential components, and the molar ratio of the components (a) to (b) in terms of (a)/(b) is from 5/95 to 75/25: R1O—(A1O)m—SO3M1 (I) R2O—(A2O)n—SO3M2 (II) (in the formulae, R1 and R2 are monovalent aliphatic hydrocarbon groups; A1 and A2 are alkylene groups having 2 to 4 carbons; m and n are numbers from 1 to 50; and M1 and M2 are monovalent cations).Type: GrantFiled: February 28, 2000Date of Patent: April 30, 2002Assignee: Kao CorporationInventors: Takayuki Ikenaga, Atsuhito Mori, Hiroyuki Aizawa, Hiroki Sawada, Yasuo Ishii, Yoshinori Mitsuda
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Patent number: 6319980Abstract: An organic silicon compound emulsion for quickly imparting excellent water-repellent properties to the surfaces of porous inorganic base materials such as concrete, mortar, and masonry. The emulsion is prepared by the steps of emulsifying a mixture consisting of (A) an organoalkoxysilane, (B) an organopolysiloxane having in its molecule at least 2 alkoxy groups or hydroxyl groups bonded to a silicon atom, (C) an anionic emulsifying agent, and (D) water, and heat aging the emulsion at a temperature below 100° C. In another embodiment, the method comprises the steps emulsifying a mixture of the components (A) to (D) and adding an acidic or alkaline substance to the emulsion. In a third embodiment, the method comprises the steps of forming a mixture consisting of the components (A) to (D), adding an acidic or alkaline substance thereto, and performing the emulsification thereafter.Type: GrantFiled: October 19, 1999Date of Patent: November 20, 2001Assignee: Dow Corning Toray Silicone Company, Ltd.Inventors: Hiroki Ishikawa, Atsushi Sakuma, Tsutomu Naganawa, Naohiro Muramoto, Isao Ona
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Publication number: 20010003765Abstract: Acrylic emulsion PSA polymers which when cast as a film resist water whitening by hot or ambient temperature water are provided, and are formed by copolymerizing a monomer mixture comprising at least one alkyl acrylate ester of an alcohol containing at least four carbon atoms, at least one polar comonomer and at least one partially water soluble comonomer present in an amount of at least about 7% by weight of the monomers. Polymerization is carried out in the presence of at least one nonionic surfactant containing at least about 8 moles of ethylene oxide per mole nonionic surfactant and at least one anionic surfactant containing up to about 10 moles ethylene oxide per mole anionic surfactant. There is added to the product of polymerization at least one base to produce an emulsion having a pH greater than 7 and containing particles having a mean “volume-average” particle diameter of up to about 210 nm as determined by laser light scattering.Type: ApplicationFiled: March 28, 1997Publication date: June 14, 2001Applicant: Prakash MallyaInventors: PRAKASH MALLYA, XING-YA LI, COLIN C. SMITH, GEORGE DILTS, KREGG D. ALBRECHT, JOSEPH T. TENHAGEN, ROBERT D. PETRASKO
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Patent number: 6147165Abstract: Inherently tacky, pressure-sensitive adhesive compositions useful in marking film applications are provided. The compositions comprise polymer particles prepared by emulsion polymerization of at least one monomer mixture. The monomer mixture comprises at least one alkyl acrylate, the alkyl group of which has from about 4 to 12 carbon atoms, preferably in an amount of from about 73% to 90% by weight, at least one unsaturated carboxylic acid containing from about 3 to 5 carbon atoms, preferably in an amount of from about 2% to 12% by weight, and at least one hard monomer, preferably present in an amount of from about 5% to 15% by weight. The particles have a mean diameter of about 300 nm or less, as determined by laser light scattering. Preferably the hard monomer comprises a styrenic monomer, more preferably both a styrenic monomer and an alkyl methacrylate. In some embodiments, the compositions are prepared by sequential polymerization of the first and second monomer charges.Type: GrantFiled: March 9, 1998Date of Patent: November 14, 2000Assignee: Avery Dennison CorporationInventors: Ivan S. P. Lee, Graham Yeadon, Paul Keller
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Patent number: 6133372Abstract: Aqueous polymer dispersions are produced by polymerizing monoethylenically unsaturated monomers bearing acid groups in an acid, partially or totally neutralized form, optionally with other monomers that can be copolymnerized therewith in the presence of hydrophilized vegetable, animal and/or synthetic fats or oils. Also disclosed is a process for preparing the same, their use for preparing oil-in-water emulsions by admixture of another oil phase composed of vegetable, animal or synthetic oils and/of fats and/or non-self-emulsifying silicones, and their use in the field of wet currying of leather or pelts.Type: GrantFiled: December 23, 1998Date of Patent: October 17, 2000Assignee: Stockhausen GmbH & Co. KGInventors: Helmut Lohmann, Thomas Muller, Waldemar Inger, Stephan Ramlow
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Patent number: 6036869Abstract: A method for improving the flocculation of suspended solids in a Bayer process liquor in a primary settler stage. The method includes the step of adding to a primary settler feed a composition including water-continuous polymer, said polymer being hydrolyzable in a Bayer process liquor to an acid form, said acid form being an active red mud flocculent. A novel emulsion, and a polymerization technique for obtaining high molecular weight emulsions are also disclosed.Type: GrantFiled: December 12, 1997Date of Patent: March 14, 2000Assignee: Nalco Chemical CompanyInventors: Radhakrishnan Selvarajan, Everett C. Phillips
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Patent number: 5620796Abstract: A method of producing an acrylic emulsion adhesive characterized in that a composition comprising 100 parts by weight of a monomeric mixture of alkyl (meth)acrylate, acrylic acid, methacrylic acid and N-vinylpyrrolidone, 0.5-2 parts by weight of a surfactant mixture of an anionic surfactant and a nonionic surfactant, and 0.03 to 0.5 part by weight of a polymerization initiator is subjected to emulsion polymerization reaction. The acrylic emulsion adhesive of this invention is rich in solids, features good adhesion and cohesion as well as high water resistance. Therefore, by coating one side of a transparent support, this adhesive can be used as an adhesive sheet for surface protection.Type: GrantFiled: April 10, 1995Date of Patent: April 15, 1997Assignee: Sekisui Kagaku Kogyo Kabushiki KaishaInventors: Kazuhiro Kawabata, Norio Numata
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Patent number: 5616645Abstract: The present invention relates to a gelled fluoride resin fine particle dispersion for use as a coating, to a method of production thereof, and to a method using this gelled fluoride resin fine dispersion to protect an alkaline inorganic hardened body.The objective of the present invention is to provide an aqueous resin for use as a coating, this aqueous resin being able to form a high performance coating film that is superior in its ability to inhibit the leaching out of the alkaline substance from the alkaline inorganic hardened body, which has excellent weatherability, water resistance, alkaline resistance, and dirt picking resistance.The present invention accomplishes the stated objective through the utilization of gelled fine particles of a fluorine containing resin.The present invention may be used in the coating field.Type: GrantFiled: July 11, 1994Date of Patent: April 1, 1997Assignee: Dainippon Ink & Chemicals, Inc.Inventors: Shin'ichi Kuwamura, Yoshinobu Deguchi, Tokio Goto, Fumio Yoshino
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Patent number: 5401801Abstract: There is disclosed a novel silicone emulsion useful as a mold coating in aluminum die casting operations. The silicone emulsion of the invention comprises an aqueous dispersion of an organopolysiloxane of a particular general formula in combination with an alkyl diphenyl ether disulfate salt. The novel silicone emulsion of the invention exhibits stability even when diluted tens of times and subjected to mechanical shear. When applied to a heated mold surface, water is driven from the silicone emulsion and there is formed a oil film. The oil film allows for easy release of the cast part. Furthermore, the film exhibits good paintability and lubricity under extreme pressure.Type: GrantFiled: April 6, 1993Date of Patent: March 28, 1995Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Tsutomu Naganawa, Isao Ona
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Patent number: 5322886Abstract: Polychloroprene latexes, well suited for the production of adhesives, are prepared by (co)polymerizing chloroprene, in aqueous emulsion, in the presence of a free-radical initiator and at least one emulsifying agent, said aqueous emulsion further comprising (a) at least one non-carboxylic ionic surfactant and (b) at least two nonionic surfactants, the HLB values thereof differing by at least 3 units.Type: GrantFiled: May 13, 1991Date of Patent: June 21, 1994Assignee: DistugilInventor: Francois Sauterey
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Patent number: 5238992Abstract: A process for preparing solid polymer blends and composites of controlled porosity in microemulsions containing both hydrophilic and hydrophobic phases. The microemulsions are prepared with surfactant systems that may include a cosolvent as a part thereof, together with a hydrophilic monomer, or monomers, dissolved in the hydrophilic phase of the microemulsion, and a hydrophobic monomer, or monomers, dissolved in the hydrophobic phase. Polymerization of the monomers thus present is carried out to provide highly uniform dispersions of the resulting polymers in each other. The invention allows for the control of the morphology of the blends, the improvement in compatability of otherwise incompatible polymers, and improvements in the processability of the polymers due to enhanced thermal and mechanical properties.Type: GrantFiled: August 26, 1992Date of Patent: August 24, 1993Assignee: Edison Polymer Innovation CorporationInventor: Syed Outubuddin
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Patent number: 5187217Abstract: Process for the production of a plasticized polyvinyl butyral particularly used for gluing a base onto glazings. The polyvinyl butyral is obtained by the reaction of a butyric aldehyde with a polyvinyl alcohol, demonstrating a level of hydrolysis greater than 95%, and a viscosity greater than 50 cP, in the presence of an acid catalyst and an emulsifier, the quantity of butyric aldehyde being such that the level of hydroxylation of the polyvinyl butyral obtained is between 22 and 26%.Type: GrantFiled: July 24, 1991Date of Patent: February 16, 1993Assignee: Saint-Gobain VitrageInventors: Robert Degeilh, Daniel Dages
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Patent number: 5109063Abstract: A process for making an aqueous vinyl acetate/ethylene/N-methylolacrylamide copolymer emulsion comprising:(a) adding an initial charge containing all the vinyl acetate monomer to be polymerized and an effective amount of an emulsifying system consisting essentially of an anionic surfactant, especially a salt of an alkylphenoxy poly(ethyleneoxy) sulfate containing about 3-5 ethyleneoxy units,(b) pressurizing the reactor with sufficient ethylene to yield a copolymer having the desired Tg,(c) initiating polymerization at a temperature from 45.degree. to 85.degree. C., and(d) continuing polymerization at a temperature from 45.degree. to 85.degree. C., while continuously adding N-methylolacrylamide over a period of time such that the free vinyl acetate monomer content of the reaction medium is about 2-4% upon completion of the N-methylolacrylamide addition.Type: GrantFiled: December 10, 1990Date of Patent: April 28, 1992Assignee: Air Products and Chemicals, IncInventors: Tze-Chiang Cheng, Phillip A. Mango
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Patent number: 4970251Abstract: A stable latex composition possessing a viscosity of less than about 50 cp. comprised of an ethylacrylate/methylacrylic acid/acrylic acid polymer and co-surfactant system comprising a nonylphenol polyethylene oxide ether sulfate and a propoxylated, ethoxylated propylene glycol nonionic surfactant block polymr useful for increasing the viscosity of water that is injected into subterranean petroleum bearing formations for the enhanced recovery of the petroleum.Type: GrantFiled: June 5, 1989Date of Patent: November 13, 1990Assignee: Union Oil Company of CaliforniaInventor: Wen-Ching Hsieh
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Patent number: 4929668Abstract: Aqueous synthetic dispersions based on copolymers of acryl polymers and/or vinyl polymers containing both hydroxylalkyl(meth)acrylate monomers and etherified N-alkylol(meth)acrylamide monomers. These dispersions are suitable as bonding agents for the production of glossy and solvent-resistant, thermosetting coating materials with good adhesion.Type: GrantFiled: July 21, 1988Date of Patent: May 29, 1990Assignee: Deutsche Texaco AktiengesellschaftInventors: Winfried Zeibig, Heinrich Huskes
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Patent number: 4891398Abstract: A fiber treatment composition comprising an aqueous dispersion containing;(A) 100 parts by weight of a finely particulate epoxy group-containing organosilasesquioxane substantially represented by general unit formula (I):R.sup.1 SiO.sub.3/2 (I)wherein said organic group having an epoxy group comprises from 0.1 to 50 mol % of the whole R.sup.1 ; and;(B) from 10 to 900 parts by weight of an amino group-containing organopolysiloxane represented by general unit formula (II): ##EQU1## wherein R.sup.2 is a monovalent hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group or a hydroxyl group; Z is a particular amino group; and 1<a<3, 0<b<1 and 1<a+b<3. This composition is useful for deepening colors of dyed textiles and fabrics and improving softness and feeling, even with respect to synthetic fibers.Type: GrantFiled: August 12, 1988Date of Patent: January 2, 1990Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masaki Tanaka, Hiroshi Ohashi
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Patent number: 4808648Abstract: A stable latex composition possessing a viscosity of less than about 50 cp. comprised of an ethylacrylane/methylacrylic acid/acrylic acid polymer and a nonylphenol polyethylene oxide ether sulfate useful for increasing the viscosity of water that is injected into subterranean petroleum bearing formations for the enhanced recovery of the petroleum.Type: GrantFiled: November 20, 1984Date of Patent: February 28, 1989Assignee: Union Oil Company of CaliforniaInventor: Wen-Ching Hsieh
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Patent number: 4795772Abstract: A stable latex composition possessing a viscosity of less than about 50 cp. comprised of an ethylacrylate/methylacrylic acid/ acrylic acid polymer and co-surfactant system comprising a nonylphenol polyethylene oxide ether sulfate and a propoxylated, ethoxylated propylene glycol nonionic surfactant block polymer useful for increasing the viscosity of water that is injected into subterranean petroleum bearing formations for the enhanced recovery of the petroleum.Type: GrantFiled: September 8, 1987Date of Patent: January 3, 1989Assignee: Union Oil Company of CaliforniaInventor: Wen-Ching Hsieh
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Patent number: 4785048Abstract: An improved process for the production of microcapsules by the use of hydrogen transfer polymerization in the presence of a mixture of emulsifiers including either an aqueous solution of a sodium salt of naphthalene-sulfonic acid-formaldehyde condensate or diphenyloxide disulfonate with a polyvinyl alcohol. The process is particularly useful for the production of microcapsules containing a colorless dye intermediate used in carbonless copy paper (CCP) applications.Type: GrantFiled: February 8, 1988Date of Patent: November 15, 1988Assignee: Moore Business Forms, Inc.Inventor: Hung-Ya Chao
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Patent number: 4771098Abstract: Acrylic resin dispersions are prepared by a monomer addition process in the presence of a free-radical initiator and an emulsifier, wherein a portion of the emulsifier is dissolved in the initial aqueous phase and the remaining portion in the added monomer phase. The new process decreases the formation of coagulates, reduces the required amount of emulsifier, and allows the preparation of dispersions of resins incorporating a large proportion of units derived from water-soluble monomers, such as carboxylic acids.Type: GrantFiled: November 25, 1986Date of Patent: September 13, 1988Assignee: Rohm GmbH Chemische FabrikInventors: Werner Siol, Hubert Rauch, Norbert Sutterlin
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Patent number: 4753973Abstract: A stable latex composition possessing a viscosity of less than about 50 cp. comprised of an ethylacrylate/methylacrylic acid/acrylic acid polymer and co-surfactant system comprising a nonylphenol polyethylene oxide ether sulfate and a propoxylated, ethoxylated propylene glycol nonionic surfactant block polymer useful for increasing the viscosity of water that is injected into subterranean petroleum bearing formations for the enhanced recovery of the petroleum.Type: GrantFiled: June 27, 1985Date of Patent: June 28, 1988Assignee: Union Oil Company of CaliforniaInventor: Wen-Ching Hsieh