Solid Polymer Derived From Ethylenically Unsaturated Hydrocarbon Only Patents (Class 524/76)
  • Patent number: 5977287
    Abstract: There is provided a composition comprising tannin containing hydroxyl groups which has been (a) chemically modified by reaction of at least one of said hydroxyl groups with at least one member selected from the group consisting of an esterification agent (e.g. acetic anhydride), etherification agent (e.g. dichloromethane or quaternary organic amine such as N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride) to form the corresponding ester, or ether, through said hydroxyl group, and (b) derivatized. The chemically modified tannin is derivatized by reaction with aldehyhde (e.g. formaldehyde), or aldehyde and at least one member selected from the group consisting of ammonia and organic amine containing at least one primary or secondary nitrogen (e.g. cyclohexyl amine); said derivatized tannin being water soluble or dispersable at a pH below 7 and water insoluble at a pH above 7.
    Type: Grant
    Filed: July 16, 1998
    Date of Patent: November 2, 1999
    Assignee: BetzDearborn Inc.
    Inventors: David Brian Mitchell, Ralph Lemmel Minnis, Thomas Peter Curran, Steven M Deboo, John Arthur Kelly, Rashmi Patwardhan, Wun Ten Tai
  • Patent number: 5973035
    Abstract: Composites of a resin and texturized cellulosic or lignocellulosic fiber, and methods for forming the composites, are disclosed.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: October 26, 1999
    Assignee: Xyleco, Inc.
    Inventors: Marshall Medoff, Arthur Lagace
  • Patent number: 5973036
    Abstract: Phase-change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibilty, offset and pick resistance, adhesion, and other desired properties. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: October 26, 1999
    Assignee: Westvaco Corporation
    Inventors: Michael D. Matzinger, Robert P. Rodebaugh
  • Patent number: 5849818
    Abstract: Solid organic polymers, for example, rubber and plastic particles, which may include coated papers, to especially include as recovered from recycle streams, can be made to have a sulfonated outer layer by treatment with a reactant gas containing sulfur trioxide. A silo apparatus can be employed to make these sulfonated particles, wherein untreated particles fall through the silo which is provided with a reactant gas supply. The sulfonated particles may optionally be neutralized, for example, with moist ammonia. These sulfonated particles can be used in articles of manufacture such as aggregates in cements, organic resins, cellulosics, and so forth, with beneficial properties being imparted to the composite. When used in a Portland cement, for example, increased performance concrete can result. Also, sulfonated sheets may be correspondingly employed for the sulfonated particles.
    Type: Grant
    Filed: June 3, 1993
    Date of Patent: December 15, 1998
    Inventors: Wilhelm E. Walles, Luis C. Mulford
  • Patent number: 5631313
    Abstract: A new stable liquid suspension of a non soluble particulate material, and a method of preparation of same are provided. Such compositions comprise at least one oil, one oil soluble resin and a non oil soluble particulate material mixed together In the appropriate quantities and conditions.
    Type: Grant
    Filed: November 14, 1991
    Date of Patent: May 20, 1997
    Assignee: Phillips Petroleum Company
    Inventors: Marshall D. Bishop, John E. Hostettler
  • Patent number: 5321065
    Abstract: A degradable plastic film comprising film forming ethylene copolymers and lignin incorporated in the form of pulverulent powder having a grain diameter of about 1 to 5 microns. The films are homogeneous and possess a thickness of about 15 to 25 microns. The films may be made doubly decomposable by adding photoactive or oxidizing agents.
    Type: Grant
    Filed: July 9, 1992
    Date of Patent: June 14, 1994
    Inventors: Pierre Bono, Claude Lambert
  • Patent number: 5288772
    Abstract: A fiber-reinforced thermoplastic composition for producing composite structural members and a method for making same is provided. The composition is made by combining a thermoplastic resin with pre-treated high moisture cellulosic materials, such as discarded newspaper, having lignin contained therein. Moisture treatment of the cellulosic materials exhibit improvements over composites using dry cellulosic materials. The composite composition may then be extruded or compression molded into various articles of manufacture.
    Type: Grant
    Filed: June 23, 1992
    Date of Patent: February 22, 1994
    Assignee: Clemson University
    Inventor: David N.-S. Hon
  • Patent number: 5274014
    Abstract: A stable emulsion of gilsonite, lignosulphonates and acrylic polymers in water.
    Type: Grant
    Filed: March 18, 1993
    Date of Patent: December 28, 1993
    Inventor: Albert G. Silverton
  • Patent number: 5227411
    Abstract: A sealing composition for a container closure comprising a polymeric matrix material and is modified by the inclusion therein of an oxygen scavenger. The composition can be in fluid or meltable form ready for application to a closure or it can be present as a deposit on the closure, for instance a gasket around the closure. Preferably the scavenging properties of the deposit are activated by pasteurizing or sterilizing the deposit when sealing a container with the closure. The invention is of particular value when the closure is a metal cap for a beer bottle.
    Type: Grant
    Filed: January 14, 1992
    Date of Patent: July 13, 1993
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Robert H. Hofeldt, Steven A. C. White
  • Patent number: 5204389
    Abstract: A sealing composition for a container closure comprising a polymeric matrix material and is modified by the inclusion therein of an oxygen scavenger. The composition can be in fluid or meltable form ready for application to a closure or it can be present as a deposit on the closure, for instance a gasket around the closure. Preferably the scavenging properties of the deposit are activated by pasteurizing or sterilizing the deposit when sealing a container with the closure. The invention is of particular value when the closure is a metal cap for a beer bottle.
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: April 20, 1993
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Robert H. Hofeldt, Stephen A. C. White
  • Patent number: 5196460
    Abstract: A tackifier composition for use in rubber compounds is disclosed. The tackifier comprises a pure lignin with a water solubility of up to 1% by weight and a carbohydrate level of less than 50% by weight. In another embodiment of the invention, the pure lignin functions as both a tackifier and an antioxidant. In yet another preferred embodiment of the invention, the improved tackifier produces synergistic results when blended with a commercial tackifier, and the antioxidant likewise yields synergistic results when mixed with a commercial antioxidant.
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: March 23, 1993
    Assignee: Repap Technologies Inc.
    Inventors: Jairo H. Lora, Michael J. Trojan, William H. Klingensmith
  • Patent number: 5131827
    Abstract: This invention relates to a resin composition for scroll compressor parts which comprises(A) about 40 to 70 parts by weight of at least one thermoplastic resin selected from the group consisting of polyphenylene sulfide, polyetheretherketone, polyetherketone, all-aromatic polyester, nylon-4,6, nylon-MXD6, polysulfone, polyarylsulfone, polyethersulfone, polyetherimide, polyamide-imide and polyimide,(B) about 15 to 45 parts by weight of whisker with an average fiber diameter of not more than about 3 .mu.m and a tensile modulus of not less than about 10,000 kgf/mm.sup.2 ;(C) about 10 to 25 parts by weight of heat-resistant fiber with an average fiber diameter of not more than about 30 .mu.m and a tensile modulus of not less than about 6,500 kgf/mm.sup.2 ; and(D) about 5 to 20 parts by weight of a finely divided solid lubricant, the sum total of components (A) to (D) being 100 parts by weight and a method of manufacturing scroll compressor parts characterized in that the above composition is injection molded.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: July 21, 1992
    Assignee: Otsuka Kagaku Kabushiki Kaisha
    Inventor: Takio Tasaka
  • Patent number: 5075362
    Abstract: A sealing composition for a container closure comprises a polymeric matrix material and is modified by the inclusion therein of an oxygen scavenger. The composition can be in fluid or meltable form ready for application to a closure or it can be present as a deposit on the closure, for instance a gasket around the closure. Preferably the scavenging properties of the deposit are activated by pasteurizing or sterilizing the deposit when sealing a container with the closure. The invention is of particular value when the closure is a metal cap for a beer bottle.
    Type: Grant
    Filed: May 1, 1991
    Date of Patent: December 24, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Robert M. Hofeldt, Steven A. C. White
  • Patent number: 4600728
    Abstract: Elastomer compositions are provided which contain high molecular weight water-insoluble humic acid humates. The compositions show improved bloom resistance in both the uncured and the vulcanized or otherwise cured state. Methods to make sponge rubber are also disclosed in which the humic acid humate is the gas producing agent. A predominantly humic acid humate containing composition maintains a clean mold, and curing an uncured article coated with the humate at elevated temperature will clean metal molds which have dirty surfaces, particularly when green coated articles are vulcanized in contact with the mold's surfaces.
    Type: Grant
    Filed: July 24, 1985
    Date of Patent: July 15, 1986
    Assignee: Alfred D. Lobo Co., L.P.A.
    Inventors: Harold R. MacKeighen, Vincent T. Cortesi
  • Patent number: 4559376
    Abstract: A method to produce composites based on cellulose or lignocellulosic materials and plastics according to which method the cellulose or lignocellulose material is subjected to a pre-hydrolytic or other chemically degrading treatment prior to or during the compounding or processing step whereby a comminution and improved dispersion of the cellulose or lignocellulose material in the plastic phase is achieved.
    Type: Grant
    Filed: August 8, 1983
    Date of Patent: December 17, 1985
    Inventors: Josef Kubat, Tore C. F. Klason
  • Patent number: 4477612
    Abstract: A novel lignin reinforced synthetic rubber comprises 100 parts of a substituted acrylamide-containing synthetic rubber and from about five to 100 parts by weight of lignin, based upon the weight of said synthetic rubber. The substituted acrylamide-containing synthetic rubber, in turn, comprises from about 45 to 99 percent by weight of a conjugated diene monomer, from about 0.5 to 40 percent by weight of a monomer containing a vinyl group and copolymerizable with said conjugated diene monomer and, from about 0.5 to 15 percent by weight of an N-(alkoxymethyl)acrylamide monomer, the weight of each said monomer component being based upon the total weight of said substituted acrylamide-containing synthetic rubber. The synthetic rubber can optionally contain other SBR rubber and/or some carbon black. It has been found to possess better properties than standard SBR filled with lignin, with or without carbon black.
    Type: Grant
    Filed: January 27, 1983
    Date of Patent: October 16, 1984
    Assignee: The Firestone Tire & Rubber Company
    Inventor: Stephen P. Boutsicaris
  • Patent number: 4419470
    Abstract: Naturally occurring dark, tacky, low softening thermoplastic resins of low acid number can be used as substitutes for all or part of the non-elastomeric petroleum-derived components of rubber stocks used for manufacture of tires and other rubber articles. For example, such resins can be used to replace petroleum-derived process oils or resins, or both, used in making tires. The resins, which are derived from wood, are low softening thermoplastic resins characterized by having about 15-30% unsaponifiables, 3-20% rosin acids, 3-15% fatty acids and 5-15% sterols. A typical useful resin is commerically available under the name Pamak TP.
    Type: Grant
    Filed: March 19, 1982
    Date of Patent: December 6, 1983
    Assignee: The Firestone Tire & Rubber Company
    Inventors: James A. Davis, Robert C. Koch
  • Patent number: 4412864
    Abstract: An asphalt composition comprising (A) 100 parts by weight of straight asphalt; (B) 0.1 to 20 parts by weight of a diene liquid rubber having at least one carboxyl group, epoxy group or amino group in the molecule; and (C) 2 to 350 parts by weight of (i) a fibrous filler or (ii) at least one filler selected from the group consisting of wood flour, talc, calcium carbonate, clay, carbon black and white carbon, having a grain size of 200 microns or less. The composition may also contain (D) 1 to 50 parts by weight of a resinous tackifier. The invention also provides a vibration damping sheet comprising said composition.
    Type: Grant
    Filed: April 10, 1981
    Date of Patent: November 1, 1983
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Tomozo Kurashige, Hidetoshi Shimada
  • Patent number: 4324710
    Abstract: Natural occurring thermoplastic resins are used as a substitute for process oils and/or hydrocarbon resins, as well as for tackifiers, softeners, extenders, processing aids, and cure retarders, in rubber stocks, as for example, a rubber skim stock used in making a tire. The resins, which are derived from crude wood rosin, are high melting thermoplastic resins having carboxylic acid groups and are insoluble in aliphatic hydrocarbons. The source of the natural occurring resins is in ample supply as they are obtained from pine trees grown in North America. A specific type of thermoplastic resin is Vinsol, a registered trademark of Hercules Corporation.
    Type: Grant
    Filed: October 2, 1980
    Date of Patent: April 13, 1982
    Assignee: The Firestone Tire & Rubber Company
    Inventors: James A. Davis, Robert C. Koch