Carboxylic Acid Or Derivative, E.g., Acetoacetic Acid Or Ester Or Salt Thereof, Etc. Patents (Class 524/772)
  • Publication number: 20120101188
    Abstract: The invention relates to a coating composition comprising: A) at least one thiol-functional compound having at least one thiol group, B) at least one polyisocyanate cross-linking agent with at least one free isocyanate group and C) at least one catalyst compound, said catalyst compound comprising at least one catalyst for the curing reaction between the thiol groups of component A and the free isocyanate groups of component B, and at least one cyclodextrine.
    Type: Application
    Filed: April 29, 2010
    Publication date: April 26, 2012
    Inventors: Carmen Flosbach, Stefanie Matten, Katharina Dreger
  • Publication number: 20040048959
    Abstract: The present invention is directed to a water-based acrylic emulsion dispersant to be used as a grind resin to incorporate inorganic pigment into a pigment dispersion for a coating composition. The acrylic emulsion dispersant is the reaction product of butyl methacrylate, butyl acrylate, styrene, methyl ether polyethylene glycol methacrylate, polyethylene glycol methacrylate, and polyphosphoric acid. The present invention is also directed to a method of preparing the acrylic emulsion dispersant. In this method, the butyl methacrylate, butyl acrylate, and styrene are combined with water to establish a first reaction blend. Similarly, the methyl ether polyethylene glycol methacrylate and the polyethylene glycol methacrylate are combined with water to establish a second reaction blend. Next, the first and second reaction blends are polymerized to form an intermediate emulsion polymer containing a hydroxyl group from the functionality of the polyethylene glycol methacrylate.
    Type: Application
    Filed: July 15, 2003
    Publication date: March 11, 2004
    Inventors: Swaminathan Ramesh, JoAnn Lanza, Paul J. Harris
  • Patent number: 6559264
    Abstract: The present invention relates to blocked polyisocyanate crosslinking agents, to the production thereof and to the use thereof in single-component stoving lacquers, particularly OEM clear lacquers (original equipment material, initial lacquer coating).
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: May 6, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Eberhard K├Ânig, Hans-Ulrich Meier-Westhues, Thomas Klimmasch
  • Patent number: 6060573
    Abstract: The present invention relates to a stabilized, aliphatic and/or cycloaliphatic, blocked polyisocyanates which havei) isocyanate groups blocked with CH-acidic esters,ii) a content of blocked isocyanate groups (calculated as NCO, MW 42) of 5 to 20, preferably 7 to 15 wt. %, based on the solids content of the blocked polyisocyanate andiii) a content of formaldehyde of 0.1 to 5 wt. %, based on the solids content of the blocked polyisocyanate.The present invention also related to a process for the preparation of these stabilized, blocked polyisocyanates and to their use in one-component polyurethane stoving compositions, which may be cured at relatively low stoving temperature of about C., as crosslinking agents for organic polyhydroxy compounds.
    Type: Grant
    Filed: March 17, 1999
    Date of Patent: May 9, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Eberhard Konig, Claus Kobusch, Wolfram Kuttner
  • Patent number: 6010757
    Abstract: The present invention provides a surface coating composition including: an organometallic comound (I) and/or a hydrolytic condensation product thereof: an organic compound (II) having a primary and/or secondary amino group in its molecule; and a compound (III) having a functional group reactable with the amino group in its molecule. The surface coating composition is capable of forming a coating layer which exhibits excellent gas barrier properties, transparency, and flexibility. A resin molding formed with the coating layer is preferably used as a wrapping material and a substrate for liquid crystal display device.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: January 4, 2000
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Tetsuya Yamamoto, Akio Naka, Yukiko Nishio
  • Patent number: 5821299
    Abstract: The present invention relates to a process for separating polyhydroxyalkanoate (PHA) from a biomass comprising the PHA, the process comprising: a) treating the biomass with a PHA solvent and a marginal nonsolvent for PHA; b) removing any insoluble biomass, thereby leaving behind a solution of PHA and marginal nonsolvent for PHA; and c) removing the PHA solvent from the solution, thereby resulting in a suspension of precipitated PHA in the marginal nonsolvent for PHA. Optionally, the process further comprises removing the marginal nonsolvent for PHA, thereby leaving behind the PHA. The present invention further relates to the suspension and the PHA produced by the process.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: October 13, 1998
    Assignee: The Proctor & Gamble Company
    Inventor: Isao Noda
  • Patent number: 5623045
    Abstract: A process for the preparation of coatings using a coating composition having a binder containing a two-component system of a) a polyisocyanate component and b) an isocyanate-reactive component b) which is essentially free from hydroxyl groups and contains b1) 5 to 95 parts by weight of a polyamine containing ester groups and secondary amino groups and b2) 5 to 95 parts by weight of polyketimines.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: April 22, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Zwiener, Reinhard Halpaap, Josef Pedain, Wolfgang Kiel
  • Patent number: 5621043
    Abstract: An elastomer composition, resistant to hydrocarbon fluid and water absorption, comprisinga) an isocyanate reactive component comprising a polypropylene ether polyol containing from about 5 percent to about 60 percent of a dispersion comprising a condensation or addition polymer,b) from about 5 percent to about 35 percent of an epoxy resin, andc) a polyurethane formed from said polypropylene ether polyol, having active hydrogen atoms and at least one isocyanate component in the presence of said dispersion and said epoxy resin,said polyurethane having an isocyanate index of less than 100, said elastomer composition exhibiting less than about 20 percent weight gain after being immersed in kerosene for 24 hours at C.
    Type: Grant
    Filed: August 2, 1995
    Date of Patent: April 15, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Thomas S. Croft
  • Patent number: 5605958
    Abstract: A composition for surface treatment, which comprises the following components (I), (II) and (III) as essential components:(I) at least one compound capable of forming a coating film with a contact angle of at least against water;(II) a solvent capable of dissolving the component (I); and(III) a solvent having an evaporation rate lower than the component (II).
    Type: Grant
    Filed: September 20, 1995
    Date of Patent: February 25, 1997
    Assignee: Asahi Glass Company Ltd.
    Inventors: Takashige Yoneda, Fumiaki Gunji, Takeshi Morimoto, Yukiko Ono
  • Patent number: 5502096
    Abstract: A room temperature curable rubber composition of a condensation curing type that comprises as a base polymer a diorganopolysiloxane or a polyoxyalkylene in which both ends of the molecular chain are blocked with a hydrolyzable silyl group, and a carbonyl compound, an amino group containing organic compound, and an .alpha.,.beta.-unsaturated carbonyl compound that are blended with the base polymer. Since the room temperature curable rubber composition is cured with water in the air and at the same time the dehydration condensation of the carbonyl group and the amino group produces water in the composition, the quick curability and deep curability are improved remarkably.
    Type: Grant
    Filed: October 19, 1994
    Date of Patent: March 26, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Tsuneo Kimura, Masatoshi Arai
  • Patent number: 5432001
    Abstract: A method for forming a homogeneous, concentrated, prepolymer composition, and a method of using the concentrated prepolymer composition to uniformly coat fibers is described. The prepolymer mixture is formed by dissolving a dialkyl, trialkyl, or tetraalkylester of biphenyltetracarboxylic acid in a solvent comprising ethyl acetate and methanol in a molar ratio of from about 1:3 to about 1:60, to form an ester solution. Diamine and end cap compound are added to the ester solution to form a monomer mixture solution. The end cap compound is a divalent compound characterized by (i) at least one unsaturated moiety, (ii) capable of reacting with the diamine or the ester to form an end cap radical that precludes further reaction of the diamine with the ester, and (iii) capable of undergoing addition polymerization. A portion of the solvent is evaporated from the monomer solution to form the substantially homogeneous, concentrated, prepolymer composition.
    Type: Grant
    Filed: June 23, 1994
    Date of Patent: July 11, 1995
    Assignee: TRW Inc.
    Inventors: Tito T. Serafini, Paul G. Cheng, Ward F. Wright
  • Patent number: 5326816
    Abstract: A room temperature curable silicone composition comprising(A) an organopolysilethylenesiloxane represented by the following general formula (1): ##STR1## wherein R.sup.1 to R.sup.4 each represent a monovalent hydrocarbon group having 1 to 10 carbon atoms, and n is an integer of 10 or over,(B) an organosilane or an organosiloxane having at least two hydrolyzable groups in the molecule, and(C) at least one ultraviolet absorbing agent and antioxidant. The cured product formed from this composition exhibits good soil resistance for a long period of time and soiling of the surface of the cured product and its surroundings due to dust or the like in the air can be obviated effectively.
    Type: Grant
    Filed: June 3, 1992
    Date of Patent: July 5, 1994
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hitoshi Kinami, Shinichi Sato, Hirokazu Yamada, Toshio Takago
  • Patent number: 5288794
    Abstract: A cyanoacrylate monomer adhesive formulation which has improved thermal properties resulting from the inclusion in the formulation of an effective amount for enhancing the thermal resistance of the cured polymer of a mono, poly or hetero aromatic compound characterized by at least three substitutions on an aromatic ring thereof, two or more of said substitutions being electron withdrawing groups selected from the group consisting of NO.sub.2, CN, CF.sub.3, NR.sup.1.sub.3.sup.+, SR.sup.1.sub.2.sup.+, C(.dbd.O)R.sup.1, C(.dbd.O)OR.sup.1, NO, CCl.sub.3, SO.sub.2, S(.dbd.O), SO.sub.3, SO.sub.2 R.sup.1, SO.sub.2 OR.sup.1 and F, one or more of said substitutions being leaving groups selected from the group consisting of F, Br, Cl, I, NO.sub.2, CN, SOR.sup.1, SO.sub.2 R.sup.1 and SO.sub.2 OR.sup.1, and R.sup.1 is an optionally substituted hydrocarbon group. Example such compounds have the formula: ##STR1## where L is the leaving group and the W groups are the electron withdrawing groups.
    Type: Grant
    Filed: October 23, 1992
    Date of Patent: February 22, 1994
    Assignee: Loctite Corporation
    Inventor: Shabbir Attarwala
  • Patent number: 5204384
    Abstract: The curable organosiloxane compositions of the present invention contain a hydrosilylation catalyst that is microencapsulated within a layer of silicone resin or polysilane resin. These compositions are characterized by the presence of carbon black or a member from a specified group of metal compounds that prevents coagulation in cured materials of the resin portion of the microencapsulated catalyst.
    Type: Grant
    Filed: January 23, 1991
    Date of Patent: April 20, 1993
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Takao Matsushita, Toshio Saruyama
  • Patent number: 5196477
    Abstract: Silicone compositions comprising an organopolysiloxane composition and an organic compound capable of coordination with metals are described. Since the organic compound is preferentially adsorbed on a metal surface, the composition is particularly suitable for use in electric or electronic parts to prevent contact failure. A more specific embodiment comprises a diorganopolysiloxane of the average unit formula, R.sub.a SiO.sub.(4-a)/2, wherein each R independently represents an unsubstituted or substituted monovalent hydrocarbon group, and a is a value of from 1.90 to 2.05, a filler, an alkoxysilane or its hydrolyzate, a silylation catalyst made of an organic silicon compound having at least one specific type of group, an organic tin compound, another organosilicon compound capable of reaction with an alcohol in order to stabilize the composition, and an organic compound capable of coordination with metals.
    Type: Grant
    Filed: July 24, 1990
    Date of Patent: March 23, 1993
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masatoshi Arai, Yoshifumi Inoue, Kei Miyoshi
  • Patent number: 5137966
    Abstract: The present invention is directed to a novel internal mold release agent for use in a polyurethane(urea) RIM process. The release agent broadly consists of the transesterification product of a fatty acid and a lower alkyl acetoacetate.
    Type: Grant
    Filed: February 25, 1991
    Date of Patent: August 11, 1992
    Assignee: Miles Inc.
    Inventor: Neil H. Nodelman
  • Patent number: 4855378
    Abstract: Organosilicon compounds and organopolysiloxane compositions which are crosslinked by the addition of Si-bonded hydrogen with SiC-bonded vinyl groups and contain the organosilicon compounds as additives for improving the adhesion of the resultant elastomers on the substrates on which they are formed.
    Type: Grant
    Filed: September 4, 1987
    Date of Patent: August 8, 1989
    Assignee: Wacker-Chemie GmbH
    Inventors: Ferdinand Pradl, Carlos Weise, Karl-Heinrich Wegehaupt
  • Patent number: 4855348
    Abstract: A storage stable water-based paint comprising a solid silicone resin and an ammonium salt of a drying oil modified acrylic copolymer provide a coating for barbecue grills and other appliances that are subjected to temperatures as high as F. A smooth and continuous coating remains on the metal after burning off of the acrylic resin and firing of the metal at F. The paint is redispersible and may be drawn down to 1.5 mils after storage at F. for more than 3 months when the pH is at least about 8.
    Type: Grant
    Filed: July 14, 1988
    Date of Patent: August 8, 1989
    Assignee: DAP Inc.
    Inventor: Hartzel G. Strader
  • Patent number: 4824903
    Abstract: A heat-resistant silicone rubber is obtained from a composition of a vinyl-containing polyorganosiloxane, a hydrogenpolyorganosiloxane, a platinum-containing catalyst, carbon black, and an acetylacetone salt of a metal wherein the metal can be copper, zinc, aluminum, iron, cerium, zirconium, or titanium. The silicone rubber can maintain its rubber properties at temperatures of C. for prolonged periods of time.
    Type: Grant
    Filed: December 2, 1986
    Date of Patent: April 25, 1989
    Assignee: Dow Corning Kabushiki Kaisha
    Inventors: Koichi Aizawa, Shingo Sewa, Kiyoshi Mizushima, Minoru Emoto
  • Patent number: 4683251
    Abstract: Room temperature-curable organopolysiloxane compositions are made from essentially linear organopolysiloxanes having hydroxyl or hydrolyzable end groups, a crosslinking agent, a filler, optionally a curing catalyst, an unsaturated ester having at least ten carbon atoms in the unsaturated fatty acid component of the ester, and a photosensitizer. These compositions cure to elastomeric materials which do not soil on the surface or the surrounding areas of the substrate in contact with the cure product. The adhesion of these cured products is not reduced.
    Type: Grant
    Filed: June 20, 1986
    Date of Patent: July 28, 1987
    Assignee: Toray Silicone Co., Ltd.
    Inventor: Ryuzo Mikami
  • Patent number: 4532293
    Abstract: .alpha.-cyanoacrylate instant adhesive compositions obtained by adding benzophenonetetracarboxylic acid or anhydride thereof to .alpha.-cyanoacrylate and showing superior heat resistance of the degree of C. with keeping instant adhesive capacity.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: July 30, 1985
    Assignee: Kabushiki Kaisha Alpha Giken
    Inventors: Takayuki Ikeda, Kazuo Kouhara, Minoru Sasaki
  • Patent number: 4418207
    Abstract: Unsaturated acetoacetic acid esters are suitable as comonomers in the polymerization of unsaturated compounds in an aqueous medium. Particularly suitable are acetylacetoxyalkyl-allyl ethers which may be synthesized in an easy manner and correspond to the formulae ##STR1## Said allyl ether derivatives are especially prepared by reacting an allyl alcohol with an epoxide and reacting the resulting hydroxyalkyl-allyl ether with diketene. Both reaction steps are carried out at a temperature of from to C., preferably in the presence of a catalyst. The allyl ether derivatives may be copolymerized especially with vinyl compounds, such as vinyl esters, acrylic acid esters, olefins, vinyl halides and vinyl aromatic hydrocarbons.
    Type: Grant
    Filed: July 9, 1980
    Date of Patent: November 29, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Helmut Braun, Helmut Rinno, Karl J. Rauterkus
  • Patent number: 4341842
    Abstract: A method of coating an automotive part with a room temperature vulcanizable silicone rubber composition comprising applying to the automotive part a thin layer of a composition comprising a silanol end-stopped polysiloxane polymer, an alkyl silicate as the cross-linking agent and as the catalyst a metal salt of a carboxylic acid. The automotive part can be a tail pipe resonator or a muffler. Such composition, which is a two-component or two package room-temperature vulcanizable silicone rubber composition can also be used to coat the underside of a car to protect it from corrosion.
    Type: Grant
    Filed: June 30, 1980
    Date of Patent: July 27, 1982
    Assignee: General Electric Company
    Inventor: Warren R. Lampe