Natural Resin Or Modified Forms Thereof Other Than Rosin Or Its Modified Forms Dnrm, E.g., Shellac, Dammar, Etc. Patents (Class 524/77)
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Elastic blends of semicrystalline propylene polymers and high glass transition temperature materials
Patent number: 6984696Abstract: Compositions are provided having from 70 wt % to 95 wt % of a polymer selected from homopolymers and random copolymers of propylene and from 5 wt % to 30 wt % of a miscible hydrocarbon resin with a glass transition temperature greater than 20° C. The polymer has a heat of fusion of less than 50 J/g, a melt index (MI) of less than 20 dg/min, and contains stereoregular propylene crystallinity. Also provided are films containing such compositions, and articles, such as diapers or incontinence garments, including such films.Type: GrantFiled: March 28, 2003Date of Patent: January 10, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: Christopher L. Curry, Sudhin Datta -
Patent number: 6805954Abstract: Pressure sensitive adhesive formulations comprising an acrylic copolymer and a mixture of tackifiers exhibit outstanding adhesion to foam facestocks.Type: GrantFiled: August 28, 2001Date of Patent: October 19, 2004Assignee: National Starch and Chemical Investment Holding CorporatonInventors: Eric Silverberg, Peter A. Walter
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Patent number: 6797774Abstract: The present invention provides a polyolefin resin for hot melt adhesives containing [I] a propylene polymer in an amount of 20 to 99 mass %, and [II] an adhesive capacity applying resin in an amount of 80 to 1 mass %, wherein [I] the propylene polymer satisfies the requirements of (1) a meso pentad fraction (mmmm) is from 0.2 to 0.6; and (2) a racemic pentad fraction (rrrr) and (1−mmmm) satisfy the relation: [rrrr/(1−mmmm)]≦0.1. The polyolefin resin for hot melt adhesives is superior in thermostability or flowing ability at high-temperature, easy for coating, environmentally friendly with little fear of generating toxic gas in the disposal and incineration, superior in adhesive property to lowly polar substances and in heat resistance of the adhesion face.Type: GrantFiled: December 12, 2002Date of Patent: September 28, 2004Assignee: Idemitsu Petrochemical Co., Ltd.Inventor: Masato Kijima
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Patent number: 6780910Abstract: An aqueous emulsion of an alkyd resin which contains as an emulsifier at least one branched primary alcohol alkoxylate of the formula (I): [CH3.(CH2)n][CH3.(CH2)m].CH.[(CH2)p.O.(AO)q.H], where n and m are each independently from 1 to 13; and p is 1 or 2; such that n+m+p is from 5 to 15; AO is an alkylene oxide residue having from 2 to 4 carbon atoms, and q is from 5 to 50. The alkyd emulsion is particularly suitable for use as a waterborne paint or surface coating composition.Type: GrantFiled: November 26, 2002Date of Patent: August 24, 2004Assignee: Imperial Chemical Industries PLCInventors: Alain Bouvy, Bart Simon Alfons Dehuvyne
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Patent number: 6723778Abstract: An aqueous composition that includes (A) a butadiene polymer latex that is prepared by an emulsion polymerization in the presence of a styrene sulfonate stabilizer and (B) a phenolic resin. A preferred aqueous butadiene polymer latex is one that is prepared by emulsion polymerization of at least 60 weight percent dichlorobutadiene monomer (based on the amount of total monomers used to form the butadiene polymer), in the presence of a styrene sulfonate stabilizer.Type: GrantFiled: March 20, 2002Date of Patent: April 20, 2004Assignee: Lord CorporationInventors: Helmut W. Kucera, Thomas Rizzo
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Publication number: 20040024094Abstract: The present invention relates to a composition comprising an aqueous dispersion of shellac and a copolymer, to a process for preparing it, and to the use thereof for coating sausages having a natural or artificial sausage casing, and hard cheese.Type: ApplicationFiled: July 24, 2003Publication date: February 5, 2004Inventor: Heinz Stemmler
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Patent number: 6565960Abstract: The invention relates to methods of treating mixtures containing polymeric materials, e.g., collagen, to form a polymer that intercalates into the polymeric material. The treatment provides greater tensile strength to the mixture, among other advantages. The polymer is formed of a monomeric unit having at least one catechol group that is oxidized to a quinone upon polymerization.Type: GrantFiled: June 1, 2001Date of Patent: May 20, 2003Assignee: Shriners Hospital of ChildrenInventors: Thomas J. Koob, Daniel J. Hernandez
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Patent number: 6518334Abstract: This invention relates to polymer blends comprising a polycarboxypolyamide resin with an alkali dispersible resin. This invention also relates to the use of the polymer blends to prepare aqueous dispersions. The aqueous dispersions were obtained by heating polycarboxypolyamide resins with alkali dispersible resins in an aqueous medium. The invention further relates to coating compositions containing the aqueous dispersions. Such coating compositions include inks, floor finishes, overprint varnishes, sizing, paints and adhesives.Type: GrantFiled: March 22, 2000Date of Patent: February 11, 2003Assignee: JohnsonDiversey, Inc.Inventors: Glenn C. Calhoun, Michael T. Sarkis
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Patent number: 6350794Abstract: A denture adhesive base composition comprising a polycarbophil component and ethylene oxide polymer. A denture adhesive composition including this base composition is also provided with other optional adhesive components. Also is provided a method for formulating a novel denture adhesive base composition comprising a polycarbophil component and ethylene oxide polymer.Type: GrantFiled: October 10, 2000Date of Patent: February 26, 2002Assignee: Block Drug Company, Inc.Inventor: Michael J. Borja
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Patent number: 6348217Abstract: A stable bleached shellac and an improved method for making stable bleached shellac is provided which involves precipitating bleached stable shellac from a pre-shellac solution at a pH of from 5.0 to 6.8, preferably from 5.0 to 6.5, most preferably from 5.0 to 6.0. The stable particulate shellac and the stable shellac solution, have a longer shelf life than conventional shellac. The stable shellac solution is comprised of solubilized particulate shellac in a solvent, most preferably ethanol. The stable particulate shellac and the stable shellac solution have a pH of from 4 up to less than 5 or from 5.0 to 6.8, more preferably from 5.0 to 6.5, even more preferably from 5.0 to 6.3, most preferably from 5.0 to 6.0.Type: GrantFiled: August 4, 2000Date of Patent: February 19, 2002Assignee: Mantrose-Haeuser Co. Inc.Inventors: Stephen A. Santos, Joseph F. Cotter, Sr., Margaret M. McWeeney
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Patent number: 6302950Abstract: The invention relates to an aqueous solution or dispersion with high shellac content. The aqueous shellac solution or dispersion is characterized in that it has a pH value of 2 to 4.2, and contains: 1 to 60% wt. shellac; 0.1 to 3% wt. of at least one water-soluble film former; 0.1 to 1% wt. of at least acid-resistant gel former; and water bringing the total to 100% wt. In accordance with the invention, the solution is produced by the following method: particle-shaped shellac is added to an aqueous solution and homogenized by stirring at 10 to 1500 rev/min., at a temperature of 5 to 20° C. The aqueous solution has a pH value of 2 to 4.2 and contains at least one water-soluble film former and at least one acid-resistant gel former. The shellac solution or dispersion can be used in the paint and varnish industry, the food industry and in cosmetics.Type: GrantFiled: January 31, 2000Date of Patent: October 16, 2001Assignee: Lancaster Group GmbHInventors: Karin Golz-Berner, Leonhard Zastrow
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Patent number: 6288148Abstract: Acrylic emulsions are obtained by carrying out a polymerization reaction of a first acrylic monomer dispersion, adding a second acrylic monomer dispersion, and carrying out a further polymerization reaction wherein the first acrylic monomer dispersion contains acrylic monomer and tackifier in a first proportion to acrylic monomer contained in the first acrylic monomer dispersion and wherein the second acrylic monomer dispersion contains acrylic monomer and tackifier in a second proportion to acrylic monomer contained in the second acrylic monomer dispersion, and wherein the proportion of tackifier in the first acrylic monomer dispersion is lower than the proportion of tackifier in the second acrylic monomer dispersion. A high molecular weight acrylic polymer is obtained when the first acrylic monomer dispersion is polymerization reacted. The second acrylic monomer dispersion is added to the first acrylic monomer dispersion after the first acrylic monomer dispersion is polymerization reacted.Type: GrantFiled: July 30, 1999Date of Patent: September 11, 2001Assignee: Sony Chemicals Corp.Inventors: Hiroshi Samukawa, Kazuki Shibata
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Patent number: 6275816Abstract: A aqueous ink for a ball-point pen which is stable over time and has high pigment dispersion stability, includes a pigment, a water-soluble organic solvent, water, xanthane gum of about 0.01 to about 0.2 wt. % and a sodium alginate of about 0.2 to about 0.6 wt. % of a total amount of the ink.Type: GrantFiled: August 26, 1999Date of Patent: August 14, 2001Assignee: Kotobuki & Co., LTDInventors: Katsuya Hattori, Akio Nakamura, Mikio Morishita
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Patent number: 6235818Abstract: A hot melt adhesive composition exhibiting excellent adhesive strength and which is useful as an adhesive for styrene resins contains (B) tackifier and (C) ethylene/C3-C20 &agr;-olefin/aromatic vinyl compound random copolymer and, in some embodiments also (A) base polymer, such as polyolefin, polar group-containing polymer and aromatic vinyl compound/conjugated diene copolymer. A low molecular weight polyolefin may also be included in all embodiments. The randon copolymer (C) may be prepared by polymerizing the &agr;-olefin and aromatic vinyl compound in the presence of a metallocene containing catalyst. In addition to excellent adhesive strength the hot melt adhesives have improved workability.Type: GrantFiled: July 29, 1999Date of Patent: May 22, 2001Assignee: Mitsui ChemicalsInventors: Kenichi Morizono, Keiji Okada, Suguru Tokita
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Patent number: 6207265Abstract: A water soluble, non-ionic masking agent is used in the manufacture of printed circuit boards. The masking agent masks portions of the circuit board to prevent adhesion of solder, flux and the like. The masking agent includes a water soluble non-ionic binder resin, a cellulosic non-ionic filler, a non-ionic surfactant, at least one non-ionic associative thickener, and deionized water. The masking agent material is readily removed from the circuit board after manufacture and does not render further wash water processing ineffective. The masking agent is non-ionic, and thus does not agglomerate or clump downstream ion-exchange or filtration media.Type: GrantFiled: September 24, 1999Date of Patent: March 27, 2001Assignee: Illinois Tool Works Inc.Inventors: John W. Holdren, II, Eric Martini
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Patent number: 6172146Abstract: A hot melt composition comprising a specific ratio of: (a) an ethylene copolymer resin; (b) a modified aromatic petroleum resin having a specific weight-average molecular weight and produced by copolymerization using a Friedel-Crafts catalyst from a specific ratio of: (1) a polymerizable component of the thermal cracked oil fraction having boiling points in a specific range and obtained by the thermal cracking of petroleum hydrocarbons, and containing vinyltoluene and indene at specific contents, (2) a turpentine oil having a specific diene value, and (3) a phenol compound; and (c) a wax. It is possible to develop a hot melt composition having excellent heat stability and improved adhesion resistance to heat, which can be used as hot melt coating, printing ink, adhesive, and sealant, etc.Type: GrantFiled: January 27, 1998Date of Patent: January 9, 2001Assignee: Nippon Petrochemicals, Co. Ltd.Inventor: Hitoshi Yanagishita
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Patent number: 6020405Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of the above-described inks.Type: GrantFiled: May 8, 1998Date of Patent: February 1, 2000Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 6011104Abstract: Footware dressings containing fluorocarbons in a carrier base plus optional colorants and additives. These dressings create a relatively slick and non-stick surface with excellent "contamination" resistance.Type: GrantFiled: January 20, 1998Date of Patent: January 4, 2000Inventor: Joseph D. Udy
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Patent number: 6007610Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Also, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks. Furthermore, the disclosed phase change inks inhibit corrosion of metallic internal printer parts.Type: GrantFiled: May 8, 1998Date of Patent: December 28, 1999Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 6001904Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks.Type: GrantFiled: May 8, 1998Date of Patent: December 14, 1999Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 6001910Abstract: A remoistenable hot melt adhesive composition comprising (i) 25 to 80% by weight of a sulfonated polyester;(ii) 3 to 40% by weight of an anionic or cationic plasticizer;(iii) 0 to 40% by weight of a polar tackifier;(iv) 0 to 3% by weight of an antioxidant; and(v) 10 to 35% by weight of a polar wax; and(vi) optionally 0 to 30% nonionic plasticizer, wherein the total of (i)-(vi) to equal 100% by weight.Type: GrantFiled: April 9, 1999Date of Patent: December 14, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: Mitchell J. Blumenthal, Charles W. Paul, Matthew L. Sharak
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Patent number: 5990227Abstract: Disclosed herein is an ink-jet recording process which comprises applying a first liquid at least containing a water-soluble resin having at least one carboxyl group or anhydride thereof, or sulfonic group per molecule to a recording medium and then applying an ink at least comprising water, an organic solvent, a dye, an alkali-soluble resin and an alkali to the portions where the first liquid has adhered, thereby forming an image. An ink set and an instrument for use in such a process are also disclosed.Type: GrantFiled: February 19, 1997Date of Patent: November 23, 1999Assignee: Canon Kabushiki KaishaInventors: Yoshihisa Takizawa, Makoto Aoki, Yutaka Kurabayashi
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Patent number: 5973036Abstract: Phase-change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device are disclosed to comprise:(a) from about 0.1% to about 30% of one or more colorants; and(b) from about 0.1 to about 99.9% of one or more reversibly-crosslinked-polymers.Recording is conducted by thermally melting the ink at a temperature above ambient temperature (20.degree. C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibilty, offset and pick resistance, adhesion, and other desired properties. Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements. Furthermore, the present invention also includes methods for the preparation of reversibly-crosslinked-polymers and for their use in the above-described inks.Type: GrantFiled: May 8, 1998Date of Patent: October 26, 1999Assignee: Westvaco CorporationInventors: Michael D. Matzinger, Robert P. Rodebaugh
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Patent number: 5932680Abstract: The hot-melt adhesive of the invention includesA) at least one polyurethane prepolymer ofa) at least one polyisocyanate, in particular, toluene diisocyanate and/or MDI,b) at least one polyalkylene glycol at a concentration of more than 10% by weight based on total hot-melt adhesive, in particular, polypropylene glycol,c) at least one polyester glycol, preferably of at least two polyester glycols having different glass transition temperature, andB) optional additives such asd) a resin, particularly a hydrocarbon resin, ande) a stabilizer, particularly toluenesulfonyl isocyanate.Preferably, the hot-melt adhesive has a melt viscosity ranging from 10 to 300 Pa.s at 130.degree. C. The PU pre-polymer has only one single Tg in the DSC diagram. The hot-melt adhesive is notable for its high creep resistance with similarly high initial and final strength.Type: GrantFiled: October 30, 1996Date of Patent: August 3, 1999Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Roland Heider
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Patent number: 5854306Abstract: There is provided a method and novel formulations for printing images on a latex rubber surface. An ink containing natural or synthetic rubber, a pigment dispersion, and an aromatically unsaturated solvent medium for said rubber is used. The stability of the image is improved providing to the rubber molecules of the ink, an agent, such as an aryl diisocyanate, that will form a tough, flexible, chemically resistant matrix between the rubber molecules of the ink, the base coat, where present and the latex surface. A base coat may be used upon the latex surface to anchor the printing ink thereto. This base coat can comprise a natural rubber in an aromatically unsaturated solvent and may also contain the aryl diisocyanate. The method may be improved by certain post printing steps such as heating and curing the printed product.Type: GrantFiled: July 8, 1997Date of Patent: December 29, 1998Assignee: Herbert GlattInventors: Henry Mattesky, James Gugger
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Patent number: 5599895Abstract: The hot-melt adhesive of the invention includesA) at least one polyurethane prepolymer ofa) at least one polyisocyanate, in particular, toluene diisocyanate and/or MDI,b) at least one polyalkylene glycol at a concentration of more than 10% by weight based on total hot-melt adhesive, in particular, polypropylene glycol,c) at least one polyester glycol, preferably of at least two polyester glycols having different glass transition temperature, andB) optional additives such asd) a resin, particularly a hydrocarbon resin, ande) a stabilizer, particularly toluenesulfonyl isocyanate.Preferably, the hot-melt adhesive has a melt viscosity ranging from 10 to 300 Pa.s at 130.degree. C. The PU prepolymer has only one single Tg in the DSC diagram. The hot-melt adhesive is notable for its high creep resistance with similarly high initial and final strength.Type: GrantFiled: May 25, 1995Date of Patent: February 4, 1997Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Roland Heider
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Patent number: 5504130Abstract: Disclosed are compositions having the characteristic of improved flow for compositions comprising a poly(phenylene ether) resin, a polyester resin, a polycarbonate resin, a reinforcing filler, a terpene phenol resin. The compositions may further comprise at least one additional material from the group consisting of impact modifiers, non-elastomeric polymers of an alkenyl aromatic compound and an additive package. The heat distortion temperature of the compositions can be further improved with the addition of an optional non-reinforcing filler in combination with a poly(tetrafluoroethylene) resin without significant loss of the physical properties.Type: GrantFiled: September 1, 1994Date of Patent: April 2, 1996Assignee: General Electric CompanyInventor: Geoffrey H. Riding
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Patent number: 5502094Abstract: This invention relates to physiologically acceptable emulsions of perfluorocarbon ether hydrides having 8 to 12 carbon atoms. These novel emulsions have various medical applications. They are especially useful medically as contrast media for various biological imaging modalities such as nuclear magnetic resonance, .sup.19 F-magnetic resonance imaging, ultrasound, x-ray, and computed tomography, as oxygen transport agents or "artificial bloods" in the treatment of heart attack, stroke, and other vascular obstructions, as adjuvants to coronary angioplasty and in cancer radiation treatment and chemotherapy.Type: GrantFiled: May 17, 1995Date of Patent: March 26, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: George G. I. Moore, Richard M. Flynn, Miguel A. Guerra
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Patent number: 5378739Abstract: A W/O emulsion ink for use in stencil printing is composed of an oil phase and a water phase with the respective ratios by wt. % thereof being (20 to 40):(80 to 60). The oil phase is composed of a solvent component containing a volatile solvent with an initial boiling point of 150.degree. to 210.degree. C. and a nonvolatile solvent, with the respective ratios by wt. % thereof being (10 to 30):(90 to 70), a coloring agent, a resin, and a surface-active agent, with the amount of the resin in the oil phase being in the range of 2 to 8 wt. % of the total weight of the emulsion.Type: GrantFiled: October 30, 1992Date of Patent: January 3, 1995Assignee: Ricoh Company, Ltd.Inventors: Masahiro Koike, Hitoshi Ueda, Hiroshi Tateishi, Naohito Shimota, Fumiaki Arai
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Patent number: 5362792Abstract: An adhesive composition is comprised of a mixture of an EVA copolymer and two tackifying resins, a high temperature tackifying resin and a low temperature tackifying resin. The viscosity of the adhesive composition is between 2,000 cps to 80,000 cps over a temperature range of 250.degree. F. to 380.degree. F. The composition comprises 60% by weight of the copolymer, 15% by weight of the low temperature tackifying resin and 25% by weight of the high temperature tackifying resin.Type: GrantFiled: June 1, 1993Date of Patent: November 8, 1994Assignee: Uniplast, Inc.Inventor: Elias S. Maayeh
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Patent number: 5270360Abstract: A two-phase thermoplastic composition adapted for forming thermoplastic patterns. The composition comprises an organic thermoplastic pattern material and at least about 5% by weight of discrete particles of cross-linked poly(methylmethacrylate) that are physically stable at temperatures above 130.degree. F. Also disclosed are investment casting patterns of such composition and processes utilizing such composition.Type: GrantFiled: January 3, 1992Date of Patent: December 14, 1993Assignee: Yates Manufacturing CompanyInventor: Paul Solomon
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Patent number: 5242963Abstract: A pressure sensitive adhesive composition comprising a vinyl acetate/ethylene/acrylate copolymer emulsion containing 5 to 60 wt % tackifier resin, on a total solids basis.Type: GrantFiled: April 10, 1991Date of Patent: September 7, 1993Assignee: Air Products and Chemicals, Inc.Inventor: Chung-Ling Mao
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Patent number: 5231123Abstract: A basing cement comprises, in weight percent, 80 to 85 filler material of limestone and lithopone, and 15 to 20 of binder resins including at least 6 weight percent of araucaria resin.Type: GrantFiled: January 2, 1990Date of Patent: July 27, 1993Assignee: GTE Products CorporationInventors: Nidhi Goel, John A. Arbie, Sr., Kevin L. Brown, Doris L. Brown
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Patent number: 5194464Abstract: An enteric film is produced by spraying on a material a mixed solution of (a) hydroxypropylmethylcellulose phthalate exhibiting a viscosity of about 136 to 204 centistokes as 10% methanol/dichloromethane (1:1 by weight) solution at 20.degree. C., (b) polyethylene glycol presenting solid state at ambient temperature and (c) shellac, wherein respective ratios of (b) and (c) to (a) are 0.1 to 20 weight percent and 5 to 40 weight percent; and then drying the solution.The enteric film excels in film strength and acid resistance, and can be employed in pharmaceutical preparations.Type: GrantFiled: March 23, 1990Date of Patent: March 16, 1993Assignee: Takeda Chemical Industries, Ltd.Inventors: Shunichi Itoh, Hiroyoshi Koyama, Toshio Kashihara, Shin-ichiro Hirai
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Patent number: 5176779Abstract: Adhesively edge-padded stack of carbonless copy paper better separates upon fanning into collated sets when a thin layer of hot-melt adhesive is used for the edge-padding. As in the prior art, the outer surfaces of each set should have a release coating such as a fluorocarbon. The layer of hot-melt adhesive includes, by weight:20-50% thermoplastic copolymer,15-50% tackifying resin, and20-60% wax having a melting point of at least 60.degree. C.As soon as the adhesive has cooled below its softening point, the stack can be fanned, thus breaking it into sets. Fanning can usually be performed within 45 seconds, because there is no need to wait for the adhesive to dry as has been necessary with the aqueous adhesives that have been used in the prior art. Preferably at least 20% by weight of the adhesive is a paraffin wax that is [.alpha.] C.sub.35 -C.sub.70 substantially straight-chain hydrocarbon.Type: GrantFiled: February 12, 1991Date of Patent: January 5, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Kenneth J. Perrington, James M. DeWanz
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Patent number: 5164441Abstract: Acrylic copolymer PSA compositions having enhanced peel strength without substantially decreasing shear properties have been formulated by homogeneously incorporating the tackifying resin into the polymer matrix. The tackifying resin is dissolved into a solution of alkyl (meth) acrylate and (meth) acrylic acid monomers prior to polymerization. To enhance the molecular weight of the resultant PSA, the monomer/tackifier solution is emulsion polymerized in the absence of chain transfer agents, such as antioxidant additives typically found in commercially available tackifiers, and allylic hydrogen present in many unsuitable tackifiers.Type: GrantFiled: December 20, 1990Date of Patent: November 17, 1992Assignee: Exxon Chemical Patents Inc.Inventor: Henry W. Yang
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Patent number: 5112889Abstract: Pressure-sensitive adhesive compositions and an improved refastenable tape closure system comprising a release tape and a fastening tape wherein the fastening tape has a balance of properties such that the tape exhibits a maximum in the peel force between peel rates of 10 cm./minute and 400 cm./minute when peeled from a polyolefin substrate as found in disposable diaper back sheets are disclosed. The adhesive of the fastening tape comprises a specific range of compositions including an elastomeric component based on an A-B-A block copolymer wherein the A blocks are derived from styrene or alphamethylstyrene and the B block are derived from isoprene, butadiene, or hydrogenated versions of these or an (AB) block copolymer of the same type of composition in another geometry such as a tapered block copolymer or a radial block copolymer, a solid tackifier resin, a liquid tackifier resin, and an end block reinforcing resin.Type: GrantFiled: February 15, 1991Date of Patent: May 12, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: John A. Miller, Egbert A. von Jakusch
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Patent number: 5098943Abstract: A water repellent having the following components (A), (B), (C) and (D) emulsified in water:(A) a wax having a melting point of from 40.degree. to 90.degree. C.;(B) a styrene-maleic anydride copolymer;(C) a water-soluble alkaline compound; and(D) a polyvinyl alcohol having a saponification degree of at least 85 mol %.Type: GrantFiled: May 9, 1991Date of Patent: March 24, 1992Assignee: Mitsubishi Kasei CorporationInventors: Toru Tagawa, Takao Tadenuma, Yasoji Ozawa
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Patent number: 5074915Abstract: Printing inks comprising an oxidation polymerization type resin, at least a part of which sets to gel in a non-polar ink solvent, a color agent, and an ink solvent, at least a part of which being a non-volatile polar solvent. When the printing ink is applied onto an absorbent printing object, the non-volatile polar solvent is easily absorbed by the printing object to gel the oxidation polymerization type resin, thereby to allow the ink to dry quickly, whereas the ink on non-absorbent printing members of a printing machine does not dry easily.Type: GrantFiled: January 11, 1990Date of Patent: December 24, 1991Assignee: Taniguchi Ink Manufacturing Co., Ltd.Inventors: Yoshioki Yoshioka, Kiyoe Hoshino, Shigeru Nakamura
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Patent number: 5028646Abstract: Pressure-sensitive adhesive compositions and an improved refastenable tape closure system comprising a release tape and a fastening tape wherein the fastening tape has a balance of properties such that the tape exhibits a maximum in the peel force between peel rates of 10 cm./minute and 400 cm./minute when peeled from a polyolefin substrate as found in disposable diaper back sheets are disclosed. The adhesive of the fastening tape comprises a specific range of compositions including an elastomeric component based on an A-B-A block copolymer wherein the A blocks are derived from styrene or alphamethylstyrene and the B blocks are derived from isoprene, butadiene, or hydrogenated versions of these or an (AB) block copolymer of the same type of composition in another geometry such as a tapered block copolymer or a radial block copolymer, a solid tackifier resin, a liquid tackifier resin, and an end block reinforcing resin.Type: GrantFiled: November 15, 1989Date of Patent: July 2, 1991Assignee: Minnesota Mining and Manufacturing CompanyInventors: John A. Miller, Egbert A. von Jakusch
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Patent number: 5021476Abstract: The invention relates to an elastic street pavement mass comprising aggregate bound by a binder and, when needed, coloring agents and other additives, and which is particularly suitable for preparing pavements having the shade of the aggregate or being toned. The efforts made so far to replace bitumen, which is hard to dye, by a colorless binder, have resulted in the use of expensive and brittle binders. However, an economical, strong and dyeable pavement mass has now been discovered, the binder of which consists of tall oil resin, wood resin, turpentine resin, their derivatives or a mixture formed by these agents, and of a process oil softening the above resins, comprising additionally rubber and plastic as auxiliary agents. The products have a better stability and at least as high an abrasion resistance to studded tires as a conventional bitumenous pavement mass.Type: GrantFiled: August 15, 1988Date of Patent: June 4, 1991Assignee: O Pinomaa KYInventor: Olli Pinomaa
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Patent number: 5011876Abstract: Pneumatic tires having an improved steering response have a tread portion which comprises an elastomeric composition containing a long chain hydroxy fatty acid or a derivative thereof, or an inter-condensed or intracondensed form thereof. The hydroxy fatty acid can be a saturated monocarboxylic acid having:(a) 9 to 25 (for example 13 to 17 and especially 15, 16, or 17) carbon atoms as well as the carbon atom of the carboxylic acid group; and(b) 1 to 6 (for example 2, 3 or 4) hydroxy groups.Suitable compounds are di- and tri-hydroxy palmitic and stearic acids. The invention is concerned particularly with the use of shellac as the hydroxy fatty acid compound.Type: GrantFiled: February 2, 1989Date of Patent: April 30, 1991Assignee: Sumitomo Rubber Industries LimitedInventors: Robert J. Blythe, Paul G. Scally
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Patent number: 5006583Abstract: Irregular shaped particles of cross-linked copolymer of styrene-divinylbenzene in which essentially 90% or more of the particles pass through a 100 mesh screen (U.S. Sieve Series) and essentially 50% pass through a 200 mesh screen (U.S. Sieve Series) is produced by high speed attrition milling of relatively inexpensive large-sized copolymer beads. The resulting particles are irregularly shaped cross-linked copolymer particles which are desirable and useful as a filler material for investment casting waxes. The small-sized irregularly-shaped cross-linked copolymer beads produced by high speed attrition milling essentially eliminate any "orange peel" effect on wax pattern surface and also results in improved packing of the wax composition thereby producing high quality precision parts more readily than heretofore possible.Type: GrantFiled: August 15, 1988Date of Patent: April 9, 1991Assignee: M. Argueso & Co., Inc.Inventor: Peter G. Argueso
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Patent number: 4985475Abstract: The invention provides a grease compatible encapsulant composition capable of use with signal transmission devices, such as electrical or optical cable. The composition is the extended reaction product of an admixture of an anhydride functionalized compound, a crosslinking agent, and an oxirane containing material which provides improved hydrolytic stability to the encapsulant composition.Type: GrantFiled: November 25, 1988Date of Patent: January 15, 1991Assignee: Minnesota Mining and ManufacturingInventors: Thomas S. Croft, Hartwick Haugen
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Patent number: 4985535Abstract: A moisture-curable hot-melt adhesive composition comprising a reaction product obtainable by reacting (A) a mixture of (a) a high molecular weight thermoplastic polyester component predominantly composed of a hydroxy-terminated high molecular weight polyester containing a hydrocarbon chain with a molecular weight of 600 to 6,000 and having a molecular weight of 8,000 to 25,000 and (b) a low molecular weight polyol having a molecular weight of not more than 5,000 with (B) a polyisocyanate compound in an NCO/OH ratio of 1.4 through 3.This moisture-curable hot-melt adhesive composition is useful for the adhesion at a low temperature, and shows an excellent heat resistance and initial physical properties.Type: GrantFiled: November 14, 1989Date of Patent: January 15, 1991Assignee: Sunstar Engineering Inc.Inventors: Masaharu Takada, Masaru Sugimori
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Patent number: 4975477Abstract: Disclosed are certain polyester adhesive blend compositions comprising about 45-90 wt. percent of a copolyester, about 3-15 wt. percent of a plasticizer, and about 7-40 wt. percent of a tackifying resin. The blends are particularly useful in hot-melt glue gun applications.Type: GrantFiled: April 7, 1989Date of Patent: December 4, 1990Assignee: Eastman Kodak CompanyInventors: Abraham J. Cox, Max F. Meyer, Jr.
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Patent number: 4938801Abstract: Printing inks comprising an oxidation polymerization type resin, at least a part of which sets to gel in a non-polar ink solvent, a color agent, and an ink solvent, at least a part of which being a non-volatile polar solvent. When the printing ink is applied onto an absorbent printing object, the non-volatile polar solvent is easily absorbed by the printing object to gel the oxidation polymerization type resin, thereby to allow the ink to dry quickly, whereas the ink on non-absorbent printing members of a printing machine does not dry easily.Type: GrantFiled: March 28, 1988Date of Patent: July 3, 1990Assignee: Taniguchi Ink Manufacturing Co., Ltd.Inventors: Yoshioki Yoshioka, Kiyoe Hoshino, Shigeru Nakamura
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Patent number: 4904303Abstract: Water-dilutable printing ink binder system based on a binder in the form of a clear, dilute, ammoniacal or amine-containing solution, the binder being a product of reacting a natural resin acid and formaldhyde in at least one stage, the amount of (100% strength) formaldehyde being 1 to 25% by weight, based on the natural resin acid, and the reaction having been carried out under atmospheric or superatmospheric pressure in the absence or in the presence of 0.1 to 2% by weight of a lewis catalyst. A variant comprises partially esterifying the natural resin acid/formaldehyde reaction product with at least one polycarboxylic acid unit of the group (a) an ethylenically unsaturated dicarboxylic acid and/or the anhydride thereof and (b) a hydroxycarboxylic acid. The binder system has added to it as solubilizers monohydric and/or polyhydric alcohols, and the pH value is preferably set to 7.5 to 10.Type: GrantFiled: September 29, 1988Date of Patent: February 27, 1990Assignee: Hoechst AGInventors: Albert Rudolphy, Helmut Eckes
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Patent number: 4870128Abstract: A hot melt gasket for a closure having improved cracking and cut-through resistant properties comprising one or more copolymers of ethylene and an olefinic carboxylic acid. Preferably, a hot melt gasket comprised of one or more ethylene-acrylic acid and/or ethylene-methacrylic acid copolymers. The hot melt gasket is particularly useful in closures which are subjected to elevated temperatures and/or excessive headloads, such as warehoused products and pasteurized food stuffs.Type: GrantFiled: March 18, 1989Date of Patent: September 26, 1989Assignee: W. R. Grace & Co.-Conn.Inventors: Marysusan Couturier, Donna Trainor
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Patent number: 4857563Abstract: The invention provides an encapsulant composition capable of use with signal transmission devices, such as electrical or optical cable. The composition is the extended reaction product of an admixture of an anhydride functionalized composition and a crosslinking agent.Type: GrantFiled: March 9, 1987Date of Patent: August 15, 1989Assignee: Minnesota Mining and Manufacturing CompanyInventors: Thomas S. Croft, Hartwick A. Haugen