Abstract: A method of preparing an acrylonitrile-based copolymer for a carbon fiber. The method includes: preparing a reaction solution including a (meth)acrylonitrile-based monomer and a first reaction solvent; adding a first portion of a radical polymerization initiator to the reaction solution to initiate polymerization; and adding a second portion of the radical polymerization initiator to the reaction solution when a polymerization conversion ratio is between 70 to 80%.

Abstract: The present invention relates to a continuous process for producing poly(trimethylene terephthalate). According to the process of the present invention, it is possible to continuously produce poly(trimethylene terephthalate) containing low levels of toxic by-products such as acrolein and ally alcohol without additional additives.

Abstract: One of the purposes of the present invention is to provide an silicone adhesive composition which comprises no antioxidant, has sufficient adhesive, tack properties and excellent heat resistance, and provides a silicone adhesive composition which has no adhesive residue in a test described below. The other purpose of the present invention is to provide an adhesive film and an adhesive tape having a cured layer obtained from the composition. The present invention provides an addition curable or peroxide curable silicone adhesive composition, wherein the addition curable silicone adhesive composition comprises (A1) a diorganopolysiloxane having an alkenyl group and a viscosity at 25 degrees C. of 100,000 mPa·s or more, (B) an organopolysiloxane having R13SiO0.

Abstract: Methods of preparing high-density polyethylene (HDPE) nanocomposites by in situ polymerization with a zirconocene catalyst, a methylaluminoxane cocatalyst, a calcium zirconate nanofiller in a solvent. The calcium zirconate nanofiller, which is dispersed across the polyethylene matrix, is found to enhance catalyst activity, and other properties of the HDPE nanocomposites produced, including but not limited to flame retardency, crystallinity and surface morphology.

Abstract: Methods of preparing high-density polyethylene (HDPE) nanocomposites by in situ polymerization with a zirconocene catalyst, a methylaluminoxane cocatalyst, a calcium zirconate nanofiller in a solvent. The calcium zirconate nanofiller, which is dispersed across the polyethylene matrix, is found to enhance catalyst activity, and other properties of the HDPE nanocomposites produced, including but not limited to flame retardency, crystallinity and surface morphology.

Abstract: There is provided an ink for white reflective film formation including: a liquid binder resin component containing a crosslinkable silicone liquid resin and crosslinkable silicone resin particles; and titanium oxide particles, the ink containing 10 to 500 parts by mass of the titanium oxide particles relative to a solid content of a total of 100 parts by mass in the liquid binder resin component.

Abstract: An aspect of the present invention relates to a polarizing lens, which comprises a polarizing layer comprising a dichroic dye and a functional film in this order on a lens substrate, and further comprises a waterborne resin layer between the polarizing layer and the functional film as a layer adjacent to both the polarizing layer and functional film, wherein the waterborne resin layer is greater than 0.50 ?m in thickness and has been formed by coating and drying a waterborne resin composition comprising a polyether polyurethane resin and a water-based solvent.

Abstract: Golf balls that have at least one layer formed from a cationic polyurea material. In particular, the compositions of the invention, which include a polymer backbone including urea linkages with cationic groups, may be formed from an isocyanate-containing component and an isocyanate-reactive component, at least one of which includes precursor cationic groups, in the presence of an alkylating, quaternizing, or ternarizing agent.

Abstract: A tire dressing composition is provided that includes at least one silicone fluid having a viscosity of between 40 and 500,000 centiStokes at room temperature. An amine functionalized silicone fluid having a viscosity of between 40 and 500,000 centiStokes at room temperature is also present. A thickener is present to yield a coating from the composition has limited sag, low tack upon coating formation, and desirable durability properties. An organic solvent is present in which the at least one silicone fluid and the amine functionalized silicone fluid are soluble or suspended. A process is provided for dressing a tire having a previous silicone coating thereon, the process including applying the tire dressing composition and allowing a solvent to evaporate from the composition to form a tire dressing coating. The coating producing an initial gloss of great than 200 units.

Abstract: The present invention relates to composite materials with a high dielectric constant and high dielectric strength and to methods of producing the composite materials. The composite materials have high dielectric constants at a range of high frequencies and possess robust mechanical properties and strengths, such that they may be machined to a variety of configurations. The composite materials also have high dielectric strengths for operation in high power and high energy density systems. In one embodiment, the composite material is composed of a trimodal distribution of ceramic particles, including barium titanate, barium strontium titanate (BST), or combinations thereof and a polymer binder.

Abstract: A novel silicon compound capable of initiating radical polymerization is provided. The silicon compound is represented by the following general formula (1) A-Z1—S—Z2—Si(OR1)n(R2)3-n??(1) wherein A is a group capable of initiating radical polymerization, Z1 and Z2 are each independently a bivalent group that has at least a carbon atom, R1 and R2 are each independently an alkyl group having from 1 to 3 carbon atoms, and n is an integer of 1 to 3. A radical polymerization initiator comprising the silicon compound, and a polymer obtained by radical polymerization of a monomer with the radical polymerization initiator are also provided. Also provided is a complex having a polymer graft chain formed on a solid substance surface with the use of the silicon compound.

Abstract: The present invention relates to an organic-inorganic composite comprising an inorganic compound particle and a polymer attached to the inorganic compound particle, wherein a molecular weight distribution of the polymer is 2.3 or less, and a content of the inorganic compound particle is 96% by mass or less with respect to a total mass of the organic-inorganic composite. Moreover, the present invention relates to a photonic crystal, an organic-inorganic composite film, a coating material, and a thermoplastic composition comprising the organic-inorganic composite.

Abstract: The invention relates to an inorganic-organic hybrid material which comprises an inorganic component and an organic component, has a content of the inorganic component of 20-80% by mass, and has a refractive index of 1.60 or higher, wherein, when preparing a strip specimen having a thickness of 1,000 ?m, a width of 5 mm and a length of 70 mm by using the inorganic-organic hybrid material and winding the specimen by 180° on a cylindrical metal rod having a diameter of 10 mm at 25° C., the specimen does not crack.

Abstract: A binder composition for a rechargeable battery, including a binder polymer having a glass transition temperature (Tg) of 20° C. or less, and having a storage modulus (60° C.) of 50-150 MPa. The binder composition according to an embodiment can improve life characteristics of the rechargeable battery by efficiently controlling expansion of a negative electrode plate.

Abstract: There is provided a method of producing a conjugated diene rubber capable of being used as a starting material for a crosslinked rubber that can be used in applications such as tire treads and can raise the fuel efficiency.

Abstract: A polyester composition containing: a) aluminum atoms; and b) alkaline earth atoms or alkali metal atoms or alkali compound residues such as lithium atoms; and c) particles comprising titanium, zirconium, vanadium, niobium, hafnium, tantalum, chromium, tungsten, molybdenum, iron, or nickel atoms or combinations thereof, where the particles improve the reheat rate of the polyester composition. The polyester polymer compositions may also contain phosphorus catalyst deactivators/stabilizers. The polyester compositions and the articles made from the compositions such as bottle preforms and stretch blow molded bottles have improved reheat rate while maintaining low haze, high L*, a b* below 3, and have low levels of acetaldehyde. In the process for making the polyester polymer, the polymer melt is polycondensed in the presence of a) and b), with the particles c) added in a melt phase process or added to the polymer in an injection molding machine or extruder.

Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

Abstract: The present application relates to a high-refractive composition. The composition of the present application exhibits excellent transparency, moisture resistance, heat resistance, water resistance, weather resistance, light resistance, and durability, and enables formation of a highly refractive film having a high index of refraction. The composition exhibits little outgassing during or after a process and can be applied to a solution application method, and thus can be effectively used in various electronic optical devices.

Abstract: A curable composition and use thereof are provided. The composition can be useful in exhibiting excellent processability and workability, and providing a cured product which exhibits superior light extraction efficiency, crack resistance, hardness, thermal shock resistance, and adhesive properties, has superior reliability under severe conditions for a long period of time and prevents opacity and stickiness onto a surface thereof when cured. Also, the curable composition capable of preventing precipitation of an additive such as a fluorescent material or a photoconversion material and being formed into a cured product having excellent transparency even when the additive is added to the curable composition can be provided.

Abstract: Polycarbonate nanocomposites comprising a polycarbonate matrix having non-oxidized metal nanoparticles dispersed therein are disclosed. The polycarbonate nanocomposite is produced by a process comprising forming a reaction mixture comprising a dihydroxy compound, an activated carbonate, a metal precursor, and a solvent; and in-situ polymerizing the reaction mixture to form a nanocomposite comprising a polycarbonate matrix and metal nanoparticles dispersed therein. The metal precursor comprises a metal selected from a specified group. The nanocomposites have improved mechanical, optical, electrical and/or magnetic properties. Also disclosed are articles formed from such polycarbonate nanocomposites.

Abstract: Presently described are optical films comprising a polymerized (e.g. microstructured) surface that comprises the reaction product of a polymerizable resin composition and polymerizable resin compositions that comprise nanoparticles; at least one first monomer comprising at least two (meth)acrylate groups; and at least one second (meth)acrylate monomer having following the structure (I); wherein at least one R1 comprises an aromatic substituent, t is an integer from 1 to 4, and R2 is hydrogen or methyl.

Abstract: A tire dressing composition is provided that includes at least one silicone fluid having a viscosity of between 40 and 500,000 centiStokes at room temperature. An amine functionalized silicone fluid having a viscosity of between 40 and 500,000 centiStokes at room temperature is also present. A thickener is present to yield a coating from the composition has limited sag, low tack upon coating formation, and desirable durability properties. An organic solvent is present in which the at least one silicone fluid and the amine functionalized silicone fluid are soluble or suspended. A process is provided for dressing a tire having a previous silicone coating thereon, the process including applying the tire dressing composition and allowing a solvent to evaporate from the composition to form a tire dressing coating. The coating producing an initial gloss of great than 200 units.

Abstract: A nanoparticle composition comprising a substrate comprising aluminum nanoparticles, an Al2O3 component coating said aluminum nanoparticles, and a metallocene catalyst component coupled to the Al2O3 component; and a polyolefin component coupled to said substrate.

Abstract: A composition includes an organopolysiloxane component (A) having at least one aryl group and having an average of at least two alkenyl groups per molecule. The composition further includes an organohydrogensiloxane component (B) having at least one of an alkyl group and an aryl group and an average of at least two silicon-bonded hydrogen atoms per molecule. Components (A) and (B) each independently have a number average molecular weight less than or equal to 1500 (g/mole). The composition yet further includes a catalytic amount of a hydrosilylation catalyst component (C), and metal-oxide nanoparticles (D) other than titanium dioxide (TiO2) nanoparticles. The composition has a molar ratio of alkyl groups to aryl groups ranging from 1:0.25 to 1:3.0. A product of the present invention is the reaction product of the composition, which may be used to make a light emitting diode.

Abstract: A compound having a guanidine structure and uses thereof as organopolysiloxane polycondensation catalysts are described.

Abstract: Microstructured films such as brightness enhancing films, polymerizable resin compositions comprising an organic component and surface modified nanoparticles, and surface modified nanoparticles are described. The microstructured film has a polymerized structure comprising the reaction product of the polymerizable resin composition (e.g. having a refractive index of at least 1.58). The cured nanocomposite (e.g. structure) can exhibit improved crack resistance. In some embodiments, the flexibility is expressed in terms of a cylindrical mandrel bend test property (e.g. a mandrel size to failure of less than 6 mm or a mandrel size to failure according to the equation D=1000(T/0.025?T) wherein T is the thickness in millimeters of a (e.g. preformed base layer). In other embodiments, the flexibility is expressed in terms of a tensile and elongation property (e.g. a tensile strength at break of at least 25 MPa and an elongation at break of at least 1.75%).

Abstract: A tire dressing composition is provided that includes at least one silicone fluid having a viscosity of between 40 and 500,000 centiStokes at room temperature. An amine functionalized silicone fluid having a viscosity of between 40 and 500,000 centiStokes at room temperature is also present. A thickener is present to yield a coating from the composition has limited sag, low tack upon coating formation, and desirable durability properties. An organic solvent is present in which the at least one silicone fluid and the amine functionalized silicone fluid are soluble or suspended. A process is provided for dressing a tire having a previous silicone coating thereon, the process including applying the tire dressing composition and allowing a solvent to evaporate from the composition to form a tire dressing coating. The coating producing an initial gloss of great than 200 units.

Abstract: Curing agents for air-drying alkyd-based resins, coatings, such as paint, varnish or wood stain, inks and linoleum floor coverings, based on an iron/manganese complex containing tetradentate, pentadentate or hexadentate nitrogen donor ligands are disclosed.

Abstract: The present disclosure relates to a curable composition to be prepared by mixing a base paste and a catalyst paste, the base paste comprising (A) a hardenable compound comprising at least two aziridine moieties, and (B) a metal containing component containing anions and/or ligands, the metal containing component being present in an amount of about 0.1 to about 5 wt.-%, the metal being selected from Zn, Cu, Co, Ni, Ag and combinations thereof, the anions or ligands being selected from oxide, hydroxyl, (hydro)carbonate, sulphate, nitrate, halide, lactate, benzoate, wolframate, linear or branched aliphatic carboxylic acid anions, ligands having not more than two coordinating moieties and combinations thereof, the catalyst paste comprising (C) a Lewis acid, the composition optionally further comprising (D) a retarder, (E) filler and (F) additive(s).

Abstract: Improved mechanical properties of either clay or carbon nanotube (CNT)-reinforced polymer matrix nanocomposites are obtained by pre-treating nanoparticles and polymer pellets prior to a melt compounding process. The clay or CNTs are coated onto the surfaces of the polymer pellets by a milling process. The introduction of moisture into the mixture of the nanoparticles and the polymer pellets results in the nanoparticles more easily, firmly, and thoroughly coating onto the surfaces of the polymer pellets.

Abstract: The invention relates to an inorganic-organic hybrid material which comprises an inorganic component and an organic component, has a content of the inorganic component of 20-80% by mass, and has a refractive index of 1.60 or higher, wherein, when preparing a strip specimen having a thickness of 1,000 ?m, a width of 5 mm and a length of 70 mm by using the inorganic-organic hybrid material and winding the specimen by 180° on a cylindrical metal rod having a diameter of 10 mm at 25° C., the specimen does not crack.

Abstract: Polycarbonate nanocomposites comprising a polycarbonate matrix having non-oxidized metal nanoparticles dispersed therein are disclosed. The polycarbonate nanocomposite is produced by a process comprising forming a reaction mixture comprising a dihydroxy compound, an activated carbonate, a metal precursor, and a solvent; and in-situ polymerizing the reaction mixture to form a nanocomposite comprising a polycarbonate matrix and metal nanoparticles dispersed therein. The metal precursor comprises a metal selected from a specified group. The nanocomposites have improved mechanical, optical, electrical and/or magnetic properties. Also disclosed are articles formed from such polycarbonate nanocomposites.

Abstract: Methods and systems are provided for a dry silicone gel. The dry silicone gel comprises a base polymer having a vinyl-silicone group, a crosslinker, and a chain extender. The dry silicone gel may be made by reacting (a) a first set of components comprising a base polymer having a vinyl-silicone group and an addition cure catalyst with (b) a second set of components comprising a crosslinker, a chain extender, and additional base polymer. In certain circumstances, the base polymer and additional base polymer are vinyl-terminated polydimethylsiloxane.

Abstract: A wall repair compound useful for filling and repairing cracks, holes, and other imperfections in a wall surface includes a conventional filler material, a conventional binder material, and a dust reducing additive which reduces the quantity of airborne dust particles generated when sanding the hardened joint compound. Airborne dust reducing additives include oils, surfactants, solvents, waxes, and other petroleum derivatives. The additive can be added to conventional ready-mixed joint compounds and to setting type joint compounds. A method of reducing the quantity of airborne dust generated when sanding a fully hardened joint compound includes mixing a sufficient quantity of the dust reducing additive with the joint compound prior to when the joint compound has been applied to the wall.

Abstract: Two-part polyurea-urethane adhesive compositions comprising a Part A prepolymer component having an isocyanate component comprising polymeric isocyanate and an oligomer content greater than 15 weight percent, polyol having a molecular weight of about 5,000 to about 12,000 and about 20 weight percent to about 44 percent weight percent filler; and a Part B curative component comprising polyol having molecular weight of about 5,000 to about 12,000, aromatic amine, about 20 weight percent to about 44 percent weight percent filler and catalyst wherein the adhesive has an 85° C. storage modulus greater than about 20 MPa. The two-part polyurea-urethane adhesive composition can be applied to bond various substrates including composite materials and metal, including making parts for the transportation and assembly markets.

Abstract: The present invention relates to a silicone resin composition including a silicone resin and metal oxide fine particles dispersed therein, the silicone resin being obtained by reacting a siloxane derivative having at least one selected from the group consisting of an alkoxysilyl group and a silanol group at a molecular end thereof and having a weight-average molecular weight (Mw) as determined by a gel permeation method of 300 to 6,000, with silica fine particles having silanol groups on a surface thereof.

Abstract: A process for preparing aqueous dispersions of composite particles using monomers containing silane groups.

Abstract: The present invention is directed toward a method for making a polymer that has nanostructures incorporated into the matrix of the polymer. The method of the present invention involves mixing a precursor solution for the polymer with a precursor for the nanostructures to form a mixture. Nanostructures are formed in the mixture from the precursor of the nanostructures, such that the nanostructures are surrounded by the precursor solution for the polymer. The polymer is formed from the precursor solution of the polymer, which results in the nanostructures being incorporated into the matrix of the polymer.

Abstract: Disclosed is a coating formed from a composition containing a film-forming resin and a plurality of particles dispersed in the resin. The average particle size of the particles is 0.1 to 50 microns, and the particles have a hardness sufficient to impart greater mar and/or scratch resistance to the coating as compared to a coating where no particles are present. Also, the difference between the refractive ranges from 1 to 1.5. A method for preparing a powder coating including the particles also is provided.

Abstract: The present invention relates to a high dielectric constant paste composition comprising (A) inorganic particles having a perovskite crystal structure or a complex perovskite crystal structure, (B) a compound represented by any one of the general formulas (1) to (4) shown below, and (C) an organic solvent. The present invention provides a high dielectric constant paste composition for producing a high dielectric constant dielectric composition which has high insulation reliability and exhibits satisfactory resistance in a high-temperature high-humidity bias test.

Abstract: Polymerizable compositions comprising particularly useful for brightness enhancing films.

Abstract: Polycarbonate nanocomposites comprising a polycarbonate matrix having non-oxidized metal nanoparticles dispersed therein are disclosed. The polycarbonate nanocomposite is produced by a process comprising forming a reaction mixture comprising a dihydroxy compound, an activated carbonate, a metal precursor, and a solvent; and in-situ polymerizing the reaction mixture to form a nanocomposite comprising a polycarbonate matrix and metal nanoparticles dispersed therein. The metal precursor comprises a metal selected from a specified group. The nanocomposites have improved mechanical, optical, electrical and/or magnetic properties. Also disclosed are articles formed from such polycarbonate nanocomposites.

Abstract: A curable resin composition containing: (A) an organic compound containing in a molecule at least two carbon-carbon double-bonds having reactivity with a SiH group; (B) a compound containing in a molecule at least two SiH groups; and (C) a heat-conductive filler, which is at least one species selected from the group consisting of a-alumina, hexagonal boron nitride, aluminum nitride and zinc oxide, and is a particle wherein a primary particle has a number average particle diameter of at least 0.10 ?m, wherein heat conductivity after curing is at least 0.8 W/mK.

Abstract: A silicone resin composition obtainable by reacting a bifunctional alkoxysilane and a trifunctional alkoxysilane in the presence of a dispersion of fine metal oxide particles. The silicone resin composition is suitably used in backlights for liquid crystal displays, traffic lights, outdoor big displays, advertisement sign boards, and the like.

Abstract: Disclosed are a polyamic acid solution, a polyimide resin prepared by imidization of the polyamic acid solution, a flexible metal clad laminate using the polyimide resin, and a printed circuit board including the flexible metal clad laminate, wherein the polyamic acid solution includes (a) 3,3?,4,4?-biphenyltetracarboxylic acid dianhydride (BPDA), and pyromellitic dianhydride (PMDA) as aromatic tetracarboxylic acid dianhydride; (b) at least one aromatic diamine; (c) an organic solvent; and (d) an inorganic filler.

Abstract: The application discloses a Titanium oxide composition and the application thereof. The mentioned Titanium oxide composition comprises Titanium co-precipitate(s), organic acid, diol, and water. According to this application, a catalyzed poly-esterification with said Titanium oxide composition is also disclosed. The mentioned polyesterification comprises a step of adding said Titanium oxide composition into at least one stage selected from slurry stage, esterification stage, and polycondensation stage.

Abstract: A surface-treating article includes an organic matrix substantially engulfed by a binder that includes a reaction product of a blocked polyurethane prepolymer and a mixture of aromatic amines. The aromatic amines include polymethylene polyaniline having a functionality equal to or greater than 4.

Abstract: Polymerizable compositions comprising particularly useful for brightness enhancing films.

Abstract: A polyester composition containing: a) aluminum atoms; and b) alkaline earth atoms or alkali metal atoms or alkali compound residues such as lithium atoms; and c) particles comprising titanium, zirconium, vanadium, niobium, hafnium, tantalum, chromium, tungsten, molybdenum, iron, or nickel atoms or combinations thereof, where the particles improve the reheat rate of the polyester composition. The polyester polymer compositions may also contain phosphorus catalyst deactivators/stabilizers. The polyester compositions and the articles made from the compositions such as bottle preforms and stretch blow molded bottles have improved reheat rate while maintaining low haze, high L*, a b* below 3, and have low levels of acetaldehyde. In the process for making the polyester polymer, the polymer melt is polycondensed in the presence of a) and b), with the particles c) added in a melt phase process or added to the polymer in an injection molding machine or extruder.

Abstract: The present invention provides a method for tinting an optical substrate. The method includes the steps of applying a coating composition containing: a polymerisable monomer having a polyoxyalkylene backbone containing at least four contiguous oxyalkylene units, and an abrasion resistant agent and/or a high crosslinking polymerisable monomer to the optical substrate, polymerising the coating composition to form an abrasion resistant coating layer, and introducing a tinting compound into the coating layer to thereby tint the optical substrate. The invention also provides a coating composition and an optical substrate that is tinted according to the method of the invention.