Halogenated Hydrocarbon Dnrm Patents (Class 524/792)
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Patent number: 8076411Abstract: A method of making a diluted polysiloxane containing polymer comprising the steps of: i) Preparing a polysiloxane containing polymer by the polycondensation of siloxane containing monomers and/or oligomers which comprise condensable groups in the presence of an organopolysiloxane and/or an organic based diluent material, a suitable catalyst and optionally an end-blocking agent; and ii) Where required quenching the polymerization process; wherein the diluent material is substantially retained within the resulting diluted organopolysiloxane.Type: GrantFiled: April 3, 2006Date of Patent: December 13, 2011Assignee: Dow Corning CorporationInventors: Isabelle Maton, Giuseppina Lavinaro, Jean Willieme, Thierry Dessilly, Tommy Detemmerman, Robert Drake
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Patent number: 7691934Abstract: The invention is directed to a method of making ultra high molecular weight diallyldialkyl ammonium salt homopolymers, compositions thereof and use of compositions as a fixative in papermaking.Type: GrantFiled: October 19, 2006Date of Patent: April 6, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Zhiqiang Song, George William Schriver, Holger Reinicke
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Publication number: 20100022697Abstract: The invention relates to a process for microencapsulation of phase change materials based on free radicals polymerization comprising: a) the preparation of i) a solution with, at least, a hydrophilic liquid and a stabilizer (continuous phase) and ii) a solution with, at least, a phase change material, a free radical initiator and a polymerizable material (discontinuous phase); b) the preparation of an emulsion by dispersing the discontinuous phase in the continuous phase under vigorous stirring; and c) the polymerization of monomers until the phase change material becomes microencapsulated. This process is simple and effective and avoids the use of hazardous compounds. The invention also relates to microcapsules obtainable by said process and to the use thereof in the thermal protection and storage of heat.Type: ApplicationFiled: March 23, 2006Publication date: January 28, 2010Applicant: UNVERSIDAD DE CASTILLA-LA MANCHAInventors: Juan Francisco Rodriguez Romero, Maria Luz Sanchez Silva, Paula Sanchez Paredes, Antonio De Lucas Martinez, Martha Liliana Torres Barreto
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Publication number: 20080306210Abstract: The invention relates to new compositions having good binder properties, wetting properties and dispersing properties not only for virtually foam-free aqueous pigment preparations but also for solvent-borne and solvent-free pigment preparations with very good heat stability and weathering stability.Type: ApplicationFiled: November 6, 2006Publication date: December 11, 2008Inventors: Patrick Glockner, Evelyn Albrecht, Andreas Wenning
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Patent number: 7435774Abstract: This invention relates to compositions, and methods for producing compositions, for increasing oil repellency, water repellency, or both, of fabric or fibers, containing: (a) an effective amount of a repellent polymer selected from the group consisting of homopolymers and copolymers of one or more monomers having formula I: Rf—(CH2)n—P ??(I) wherein P is a polymerizable or copolymerizable moiety; and (b) a fluorinated carbon solvent.Type: GrantFiled: September 11, 2002Date of Patent: October 14, 2008Assignee: Peach State Labs, Inc.Inventors: Michael S. Williams, Robert Jackson, Robert Andrus
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Patent number: 7169845Abstract: In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1–C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1–C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13–16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1–C10 hydocarbyl or hydrogen, R4 is C1–C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1–C10 alkoxyl, C1–C10 alkylthio, or C1–C10 mercaptoalkythio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect.Type: GrantFiled: April 4, 2002Date of Patent: January 30, 2007Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Masaki Tamura, Takahiro Matsui, Masanori Shimuta, Yuichi Yoshimura, Motoharu Takeuchi, Hiroshi Horikoshi, Hiroyuki Okada
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Patent number: 7141614Abstract: A photosensitive resin composition of the present invention contains a (A) soluble polyimide and a (b) (meth)acrylic compound, the (A) soluble polyimide being soluble in an organic solvent and being synthesized by using an acid dianhydride component and at least one of a diamine component containing a siloxane structure or an aromatic ring structure, and a diamine component having, in its structure, a hydroxyl group a carboxyl group or a carbonyl group, and the (B) (meth)acrylic compound having at least one carbon-carbon double bond, and preferably contains at least one of a (C) photo reaction initiator and a (D) fire retardant. With this arrangement, the photosensitive resin composition of the present invention is capable of having excellent properties. Especially, the photosensitive resin composition of the present invention is so excellently useful that it can be used for electronic parts and the like.Type: GrantFiled: October 24, 2002Date of Patent: November 28, 2006Assignee: Kaneka CorporationInventors: Koji Okada, Kaoru Takagahara, Toshio Yamanaka
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Patent number: 7022413Abstract: The present invention provides an aromatic liquid crystalline polyester film excellent in the adhesion property to a substrate. Such film is obtained by an aromatic liquid crystalline polyester film obtained by casting an aromatic liquid crystalline polyester solution composition containing a solvent containing a halogen-substituted phenol defined by the following general formula (I): (wherein A is a halogen atom or a trihalomethyl group; i is an integer of 1 to 5; and in the case i is 2 or higher, the respective A may be the same or different), an aromatic liquid crystalline polyester, and a non-liquid crystalline resin at ratio of 1 to 200 parts by weight of the non-liquid crystalline resin to 100 parts by weight of the aromatic liquid crystalline polyester on a substrate; and removing the solvent.Type: GrantFiled: August 25, 2004Date of Patent: April 4, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Shiro Katagiri, Satoshi Okamoto
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Patent number: 7022806Abstract: Macrocyclic oligoesters and compositions comprising macrocyclic oligoesters are prepared from intermediate molecular weight polyesters. In one embodiment, a diol is contacted with a dicarboxylic acid or a dicarboxylate in the presence of a catalyst to produce a composition comprising a hydroxyalkyl-terminated polyester oligomer. The hydroxyalkyl-terminated polyester oligomer is heated to produce a composition comprising an intermediate molecular weight polyester which preferably has a molecular weight between about 20,000 Daltons and about 70,000 Daltons. The intermediate molecular weight polyester is heated and a solvent is added prior to or during the heating process to produce a composition comprising a macrocyclic oligoester. An optional step is to separate the macrocyclic oligoester from the composition comprising the macrocyclic oligoester.Type: GrantFiled: November 29, 2004Date of Patent: April 4, 2006Assignee: Cyclics CorporationInventor: Gary R. Faler
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Patent number: 6946516Abstract: A rubber-modified flame resistant styrene resin composition, which has superior heat stability and weather resistance to prevent discoloration and deterioration due to heat or light and is processed under various molding condition, is provided. The rubber-modified flame resistant styrene resin composition includes a rubber-modified styrene resin, flame retardant comprising compounds selected from a group consisting of tetrabromobisphenol-A-bis(2,3-dibromopropylether), hexabromocyclododecane and a mixture thereof, and brominated epoxy oligomer, and calcium stearate as a lubricant.Type: GrantFiled: July 7, 2003Date of Patent: September 20, 2005Assignee: LG Chem, Ltd.Inventors: Dae-San Jung, Yong-Yeon Hwang, Su-Yeon Na, Jong-Kuk Choi, Chan-Hong Lee
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Patent number: 6906115Abstract: A perfluoropolyether-containing composition, which can easily conform to a fluorine-free substrate and can form a film on a surface of the substrate to fix the composition to the substrate surface, wherein the composition is a carbon-carbon double bond-containing composition comprising (A) a triisocyanate prepared by trimerizing a diisocyanate, and (B) a combination of at least two active hydrogen-containing compounds, and the component (B) comprises (B-1) a perfluoropolyether having at least one active hydrogen, and (B-2) a monomer having active hydrogen and a carbon-carbon double bond.Type: GrantFiled: June 10, 2002Date of Patent: June 14, 2005Assignee: Daikin Industries, Ltd.Inventors: Makoto Hanazawa, Yasuo Itami
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Patent number: 6881784Abstract: A method for producing submicron polytetrafluoroethylene (“PTFE”) powder in a free-flowing, readily dispersible form. The irradiated PTFE starting material is placed in a desired solvent and undergoes grinding until the PTFE particles reach submicron size. The submicron particles are subsequently recovered from the solvent and dried to form a powder that may have particles less than 1.00 ?m in size. The dry PTFE powder may then be readily dispersed to submicron size into a desired application system. The submicron PTFE powder of this method is free-flowing, readily dispersible in various application systems, tends not to “dust” or self-agglomerate. Improved aqueous and organic dispersions of submicron PTFE particles may also be formed that display increased stability and require much less agitation than other processes of forming such dispersions. Such improved PTFE dispersions may be formed with or without the addition of surfactants, wetting agents, rheology modifiers, pH-adjusting agents, and the like.Type: GrantFiled: March 14, 2003Date of Patent: April 19, 2005Inventors: Charles A. Cody, William Neuberg, Manshi Sui, Youssef Awad
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Patent number: 6855798Abstract: Macrocyclic oligoesters and compositions comprising macrocyclic oligoesters are prepared from intermediate molecular weight polyesters. In one embodiment, a diol is contacted with a dicarboxylic acid or a dicarboxylate in the presence of a catalyst to produce a composition comprising a hydroxyalkyl-terminated polyester oligomer. The hydroxyalkyl-terminated polyester oligomer is heated to produce a composition comprising an intermediate molecular weight polyester which preferably has a molecular weight between about 20,000 Daltons and about 70,000 Daltons. The intermediate molecular weight polyester is heated and a solvent is added prior to or during the heating process to produce a composition comprising a macrocyclic oligoester. An optional step is to separate the macrocyclic oligoester from the composition comprising the macrocyclic oligoester.Type: GrantFiled: February 24, 2003Date of Patent: February 15, 2005Assignee: Cyclics CorporationInventor: Gary R. Faler
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Publication number: 20040192837Abstract: A method to form a polymeric material is disclosed. The method provides a water immiscible solvent and one or more condensation monomers, where those one or more condensation monomers are essentially insoluble in the water immiscible solvent. The one or more condensation monomers may be either a solid or a liquid at room temperature. The method forms a reaction mixture comprising a suspension of one or more solid condensation monomers, or an emulsion of one or more liquid condensation monomers, in the water immiscible solvent. The method includes heating the reaction mixture to form the polymeric material product. That polymeric material is then separated from said reaction mixture.Type: ApplicationFiled: March 31, 2004Publication date: September 30, 2004Inventors: Bernard Gordon, Jim DiBattista
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Patent number: 6525164Abstract: Macrocyclic oligoesters and compositions comprising macrocyclic oligoesters are prepared from intermediate molecular weight polyesters. In one embodiment, a diol is contacted with a dicarboxylic acid or a dicarboxylate in the presence of a catalyst to produce a composition comprising a hydroxyalkyl-tenninated polyester oligomer. The hydroxyalkyl-terminated polyester oligomer is heated to produce a composition comprising an intermediate molecular weight polyester which preferably has a molecular weight between about 20,000 Daltons and about 70,000 Daltons. The intermediate molecular weight polyester is heated and a solvent is added prior to or during the heating process to produce a composition comprising a macrocyclic oligoester. An optional step is to separate the macrocyclic oligoester from the composition comprising the macrocyclic oligoester.Type: GrantFiled: August 31, 2001Date of Patent: February 25, 2003Assignee: Cyclics CorporationInventor: Gary R. Faler
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Patent number: 6486298Abstract: A process for making a stabilized, liquid, diepisulfide based prepolymer having a viscosity at 25 C. ranging from 20 to 330000 centipoises which comprises polymerizing at room temperature a monomer composition comprising at least one diepisulfide monomer in the presence of at least one anionic polymerization initiator and at least one halogenated polymerization inhibitor and compositions made therefrom.Type: GrantFiled: December 22, 2000Date of Patent: November 26, 2002Assignee: Essilor International Compagnie Generale d'OptiqueInventors: Aref Ben Ahmed Jallouli, Joey Oliveros Obordo, Yassin Yusef Turshani
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Patent number: 6197426Abstract: A method is disclosed of treating a substrate, comprising applying to the substrate a fluorochemical composition comprising fluorochemical copolymer derived from at least one fluorochemical monomer A, at least one monomer B, at least one monomer C and at least one monomer D, wherein the fluorochemical monomer A contains a fluoroaliphatic group and is an ester of an &agr;,&bgr;-ethylenically unsaturated carboxylic acid, the monomer B is an ester of an &agr;,&bgr;-ethylenically unsaturated carboxylic acid, the monomer C is an ethylenically unsaturated dicarboxylic acid anhydride, the monomer D is an ester of an &agr;,&bgr;-ethylenically unsaturated carboxylic acid, the fluorochemical monomer A and the monomers B and C contain only one polymerizable group and monomer D contains, as a second polymerizable group, an ethylenically unsaturated group that has a higher affinity to copolymerize with the monomer C than fluorochemical monomer A or monomers B or D.Type: GrantFiled: January 12, 1998Date of Patent: March 6, 2001Assignee: 3M Innovative Properties CompanyInventor: Dirk M. Coppens
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Patent number: 6168782Abstract: Elastomeric silicones, especially elastomeric silicone polyethers, are prepared by combining and reacting (A) an ≡Si—H containing polysiloxane, (B) a mono-alkenyl polyether, (C) an active ingredient such as a vitamin, antimicrobial agent, sunburn prevention agent, astringent, or sex hormone, (D) an &agr;,&ohgr;-unsaturated hydrocarbon, (E) a platinum catalyst, and (F) an oil. The reaction of components (A)-(F) is allowed to continue, forming a crosslinked three-dimensional gelled network of the elastomeric silicone polyether containing the active ingredient and the oil. The compositions are useful in personal and health care applications, personal hygiene, and household cleaning applications.Type: GrantFiled: May 24, 1999Date of Patent: January 2, 2001Assignee: Dow Corning CorporationInventors: Zuchen Lin, William James Schulz, Jr., Janet Mary Smith
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Patent number: 6121406Abstract: A hydrophilic dicyclohexylmethanecarbodiimide represented by the formula (1): wherein n is an integer of 1 to 10 and R.sup.1 is a residue of a mixture of organic compounds of different hydrophilicities each having at least one hydroxyl group capable of reacting with an isocyanate group. The hydrophilic dicyclohexylmethanecarbodiimide is improved in reactivity and storage stability, and is thereby easy to handle as a crosslinking agent for hydrophilic resins.Type: GrantFiled: April 15, 1999Date of Patent: September 19, 2000Assignee: Nisshinbo Industries, Inc.Inventors: Yasuo Imashiro, Ikuo Takahashi, Yoshihiro Yamazaki
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Patent number: 6111022Abstract: The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydispersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand; the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a maType: GrantFiled: December 8, 1998Date of Patent: August 29, 2000Assignee: Carnegie-Mellon UniversityInventors: Krzysztof Matyjaszewski, Simion Coca, Scott G. Gaynor, Yoshiki Nakagawa, Seong Mu Jo
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Patent number: 6034207Abstract: A hexafluoropropene oxide polymer of formula (1) having a dispersity Mw/mn of up to 1.10 is useful as a raw material for liquid rubber. In formula (1), R is --COF, --I, --Br, --CH.sub.2 OH, --CH.sub.2 OCH.sub.2 CH.dbd.CH.sub.2, --COOR.sup.1 or --CONR.sup.2 R.sup.3 wherein R.sup.1, R.sup.2 and R.sup.3 are independently hydrogen or monovalent C.sub.1-20 hydrocarbon groups which may contain N, O, Si or S, or R.sup.2 and R.sup.3 form a ring with the N atom, Rf is a C.sub.1-6 perfluoroalkylene group or a C.sub.2-10 perfluorooxyalkylene group, and x+y=30 to 400.Type: GrantFiled: April 1, 1999Date of Patent: March 7, 2000Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Noriyuki Koike, Takashi Matsuda, Shinichi Sato
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Patent number: 5994455Abstract: A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.Type: GrantFiled: September 8, 1998Date of Patent: November 30, 1999Assignee: Ticonna GmbHInventors: Karl-Friedrich Muck, Horst Roschert, Robert M. Gronner, Satyajit Verma, Michael G. Yearwood
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Patent number: 5945478Abstract: Extrusion rheology of thermoplastic polymer as manifested by surface smoothness is improved by incorporating foam cell nucleating agents into the polymer and extruding the polymer under laminar flow to form unfoamed extrudate.Type: GrantFiled: June 25, 1997Date of Patent: August 31, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Marlin Dwight Buckmaster, Stuart Karl Randa
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Patent number: 5939478Abstract: The viscosity of a solvent is modified by thickening the solvent with a silicone latex. A silicone latex having a plurality of crosslinked polysiloxane particles is first prepared by mixing the siloxane polymer, a surfactant, and water; emulsifying the mixture to a gel phase; diluting the emulsion with water; adding a cure package (i.e., a catalyst, a crosslinker, or both, or a self catalytic crosslinker); and then without removing the water from the latex and after the particles of siloxane polymer in the latex have been cured, mixing the latex and solvent to thicken the solvent, forming viscous liquids, gels, and pastes. Water in the latex thickened solvent composition can be stabilized by adding a silicone polyether during mixing of the latex and the solvent.Type: GrantFiled: November 13, 1997Date of Patent: August 17, 1999Assignee: Dow Corning CorporationInventors: James Anderson Beck, Vicky Sue Cobb, Cassie Emelia Cuthbert, Eric Jude Joffre, Virginia Kay O'Neil, Burt Michael Wrolson
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Patent number: 5936030Abstract: A block copolymer containing one or more polyoxyethylene blocks and one or more polyoxy(higher alkylene) blocks, wherein at least some of the blocks are linked together by an oxymethylene group, can be prepared by reacting one or more dihydroxy terminated polymers selected from poly(ethylene glycol), poly(higher alkylene glycol), and block copolymers thereof in solution with a dihalomethane in the presence of a base. Such copolymers can be used as surfactants and surface modifiers. The reaction can be conducted at ambient temperature, and does not require the addition of heat.Type: GrantFiled: August 14, 1997Date of Patent: August 10, 1999Assignee: NanosystemsInventors: Christian Vaughan Nicholas, Malcolm Donald Purbrick
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Patent number: 5889108Abstract: Low molecular weight siloxane fluids are thickened by silicone elastomers. The silicone elastomers are made by combining in one pot an .tbd.Si--H containing siloxane, a mono-alkenyl polyether, an alpha, omega-diene, and a low molecular weight siloxane fluid. An elastomer, i.e. gel, with polyether groups is produced. The elastomer can be swollen with the low molecular weight siloxane fluid under shear force, to provide a uniform silicone paste. The silicone paste has excellent spreadability upon rubbing, and possesses unique rheological properties in being thixotropic and shear thinning. The silicone paste can be easily emulsified with water to form a stable uniform emulsion, without using a surfactant to allow normally immiscible materials to become intimately mixed.Type: GrantFiled: June 2, 1997Date of Patent: March 30, 1999Assignee: Dow Corning CorporationInventor: Shizhong Zhang
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Patent number: 5854340Abstract: The present invention provides (a) a reflux solvent for condensation polymerization which is an admixture blend of a diether described by the formula R.sub.1 --O--(CH.sub.2 --CHR.sub.2 --O).sub.n --R.sub.1 having a weight percentage between about 15 percent to about 60 percent (where R.sub.1 is independently selected from C.sub.1 -C.sub.6, R.sub.2 =CH.sub.3 or C.sub.2 H.sub.5, and n=1-3), and a second fluid which is an aromatic petroleum distillate solvent characterized as having an essential preponderance of aromatic distillates and having a boiling temperature between about 136.degree. C. to about 232.degree. C., where the admixture has an autoignition temperature greater than about 300.degree. C.Type: GrantFiled: September 24, 1997Date of Patent: December 29, 1998Assignee: The Dow Chemical CompanyInventors: Felipe A. Donate, Joseph Warren Kappen, Debra Anne Timmers
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Patent number: 5847070Abstract: New compounds including bis-.beta.-hydroxy ethyl bibenzoate containing less than 2.5%, and preferably less than 1%, diethylene glycol and a process for the production of the bis-.beta.-hydroxy ethyl bibenzoate by the condensation of 4,4'-biphenyl dicarboxylic acid and ethylene glycol at low temperature and pressure in the presence of a catalyst are disclosed. Use of the compounds to produce polyesters is also disclosed.Type: GrantFiled: December 1, 1994Date of Patent: December 8, 1998Assignee: Monsanto CompanyInventors: Jawed Asrar, David J. Weinkauff, A. Hameed Bhombal
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Patent number: 5767192Abstract: The present invention relates to an organopolysiloxane compound having at least one group having the formula ##STR1## wherein R.sup.3 is a divalent hydrocarbon group having from 1 to 20 carbon atoms, R.sup.5 and R.sup.6 are selected from a hydrogen atom or a group having the formula --(C.sub.n H.sub.2n+1) where n has a value from 1 to 30, R.sup.4 is selected from a hydrogen atom, an alkyl group, or an aryl group, d has a value from 0 to 150, and e has a value from 0 to 150, with the proviso that the value of d+e is greater than zero. The organopolysiloxane compounds of this invention reduce the amount of foam in hydrocarbon fuel, especially in diesel fuels and jet fuels. The organopolysiloxane compounds act as foam control agents which display consistent compatibility and miscibility with additives which are frequently present in hydrocarbon fuels.Type: GrantFiled: January 11, 1996Date of Patent: June 16, 1998Assignee: Dow Corning CorporationInventors: David Robert Battice, Kenneth Christopher Fey, Lenin James Petroff, Michael Allen Stanga
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Patent number: 5756656Abstract: A process for the preparation of a copolymer of carbon monoxide with an olefinically unsaturated compound, comprising copolymerizing the monomers in the presence of a Group VIII metal containing catalyst composition and in the presence of an olefinically unsaturated compound (A) which contains in its molecular structure an organic group imparting steric hindrance on the vinyl group. A copolymer obtainable by the said process.Type: GrantFiled: January 30, 1997Date of Patent: May 26, 1998Assignee: Shell Oil CompanyInventors: Arleen Marie Bradford, Andre Buys
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Patent number: 5708075Abstract: The present invention relates to a curable silicone release coating composition comprising (A) an organopolysiloxane having at least two alkenyl groups per molecule, (B) an organohydrogensiloxane having at least two silicon-bonded hydrogen atoms per molecule, (C) a siloxane resin having silicon-bonded hydrogen groups, (D) a platinum group metal-containing catalyst, and optionally (E) an inhibitor. The compositions of this invention are useful as release coatings for pressure sensitive adhesives.Type: GrantFiled: December 30, 1996Date of Patent: January 13, 1998Assignee: Dow Corning CorporationInventors: Kyuha Chung, Robert Alan Ekeland, Randall Gene Schmidt
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Patent number: 5708046Abstract: The present invention relates to a curable silicone release coating composition comprising a mixture of an organopolysiloxane containing at least two alkenyl groups per compound, an organohydrogensilicon compound, inhibitors having a boiling point of up to 130.degree. C. at atmospheric pressure, inhibitors having a boiling point of at least 170.degree. C. at atmospheric pressure a platinum group metal-containing catalyst, and optionally a diluent. The silicone release coating compositions are stable when stored at room temperature, especially when the composition is used on a coating roll for the production of a thin films. The compositions of this invention also quickly form a cured film having good release properties for adhesive materials at a comparatively low temperatures.Type: GrantFiled: September 20, 1996Date of Patent: January 13, 1998Assignees: Dow Corning Corporation, Dow Corning Toray Silicone Co., Ltd.Inventors: John Darrell Jones, Michael Ward Skinner, Nobuo Kaiya, Atsushi Togashi, Takateru Yamada
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Patent number: 5688457Abstract: Extrusion theology of thermoplastic polymer as manifested by surface smoothness is improved by incorporating foam cell nucleating agents into the polymer and extruding the polymer under laminar flow to form unfoamed extrudate.Type: GrantFiled: April 10, 1996Date of Patent: November 18, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Marlin Dwight Buckmaster, Donald Leonidas Henry, Stuart Karl Randa
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Patent number: 5677416Abstract: There are disclosed a wholly aromatic polyester represented by formula I with enhanced flame retardance and chemical stability, and a method for the preparing the same. The polymer is prepared in interface polymerization wherein an alkali aqueous phase containing cyclotriphosphagene-containing bisphenols is in contact with an organic phase containing aromatic dicarboxylic acid chlorides in the presence of a phase transfer catalyst. ##STR1## wherein m and n each are an integer which satisfies the following conditions: 0<m/(m+n)<1 and 0<n/(m+n)<1; X represents --O--, --S--, --SO.sub.2 --, --SO--, --CO--, an alkylene group of C.sub.1-4, or an alkylidene group of C.sub.1-4 ; and R.sub.1, R.sub.2, R.sub.3, R.sub.1 ', R.sub.2 ', R.sub.3 ' and R.sub.4 ' are the same or different, and represent a hydrogen atom, a halogen atom, or an alkyl group of C.sub.1-4 or the derivatives thereof, respectively.Type: GrantFiled: October 30, 1996Date of Patent: October 14, 1997Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Young-Hoon Ko, Seonkyeong Cheong
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Patent number: 5639820Abstract: A method for preparing an aqueous dispersion composition containing a fluorocopolymer by the emulsion polymerizing of a polymerizable compound containing a polyfluoroalkyl group and another copolymerizable compound noncompatible with the polymerizable compound in an aqueous solution containing a compatibilizer, wherein the compatibilizer is selected from the group consisting of (a) a low-molecular weight compound having a perfluoroalkyl group and a hydrocarbon alkyl group in a molecule, (b) a low-molecular weight compound having a perfluoropolyether group and a hydrocarbon alkyl group in a molecule, (c) a macromolecular compound prepared by the copolymerization of a polymerizable compound containing a perfluoroalkyl group and a polymerizable hydrocarbon compound, and (d) a hydrocarbon macromolecular compound having a perfluoropolyether group in a molecule does not cause coagulation and can give an aqueous dispersion composition having the improved compatibility between the polymerizable monomers.Type: GrantFiled: June 2, 1995Date of Patent: June 17, 1997Assignee: Daikin Industries, Ltd.Inventors: Motonobu Kubo, Masamichi Morita
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Patent number: 5614575Abstract: A sprayable polyurethane composition containing an isocyanate component and a polyol component is provided, wherein the polyol component includes a polyether polyol amine; a nitrogen-free hydoxy-terminated polyether; and a sucrose-polyether polyol. Preferably, these two components are combined while spraying them individually into a mold along with a fibrous-reinforcing material.Type: GrantFiled: April 24, 1995Date of Patent: March 25, 1997Assignee: RPG. Inc.Inventor: Rex R. Kotschwar
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Patent number: 5605958Abstract: A composition for surface treatment, which comprises the following components (I), (II) and (III) as essential components:(I) at least one compound capable of forming a coating film with a contact angle of at least 70.degree. against water;(II) a solvent capable of dissolving the component (I); and(III) a solvent having an evaporation rate lower than the component (II).Type: GrantFiled: September 20, 1995Date of Patent: February 25, 1997Assignee: Asahi Glass Company Ltd.Inventors: Takashige Yoneda, Fumiaki Gunji, Takeshi Morimoto, Yukiko Ono
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Patent number: 5578381Abstract: The present invention relates to a release coating composition comprising an organopolysiloxane having fluorine containing organic groups and alkenyl groups, an organohydrogensiloxane, and a platinum-containing catalyst. The present invention also relates to a release coating composition comprising an organopolysiloxane having fluorine containing organic groups and silicon-bonded hydrogen groups, an alkenyl functional organopolysiloxane, and a platinum-containing catalyst. The curable silicone release coating compositions of this invention have excellent release properties from various tacky substances, especially silicone-based pressure sensitive adhesives, after curing, and also have excellent bonding characteristics when applied to various substrates.Type: GrantFiled: August 30, 1995Date of Patent: November 26, 1996Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Yuji Hamada, Hideki Kobayashi, Wataru Nishiumi
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Patent number: 5567347Abstract: The present invention relates to fiber treatment compositions comprising an unsaturated acetate, an organohydrogensiloxane, a metal catalyst, an organosilicon compound, and optionally a dispersant. The compositions of the present invention impart beneficial characteristics such as slickness, softness, compression resistance and water repellency to substrates such as fibers and fabrics.Type: GrantFiled: January 29, 1996Date of Patent: October 22, 1996Assignee: Dow Corning CorporationInventors: Jeffrey A. Kosal, Diane M. Kosal, Anthony Revis
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Patent number: 5466744Abstract: Macrocyclic polyester oligomer compositions comprising alkylene isophthalate or terephthalate units or the like are prepared by the reaction of a diol with a diacid chloride in the presence of at least one amine characterized by substantially no steric hindrance around the basic nitrogen atom. The reaction is conducted under substantially anhydrous conditions and at a temperature from about -25.degree. to about +25.degree. C. The resulting macrocyclic oligomers may be converted to linear polyesters by contact with catalysts including basic reagents, stannous alkoxides, organotin compounds, titanate esters and metal acetylacetonates.Type: GrantFiled: January 9, 1995Date of Patent: November 14, 1995Assignee: General Electric CompanyInventors: Thomas L. Evans, Daniel J. Brunelle, Jean E. Bradt, Eric J. Pearce, Paul R. Wilson
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Patent number: 5466770Abstract: The invention provides new fluorine-efficient oil- and water-repellent compositions comprising a fluorochemical oil- and water-repellent agent and a polymer extender comprising at least one percent by weight based on the weight of the extender of interpolymerized units derived from monomers containing at least one blocked or masked isocyanate function.Type: GrantFiled: May 26, 1994Date of Patent: November 14, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Frans A. Audenaert, Rudolf J. Dams, Robert F. Kamrath
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Patent number: 5416184Abstract: This invention provides methods for producing a high-molecular weight polycarbodiimide solution from an organic diisocyanate in the presence of a carbodiimidation catalyst, wherein 1) a chlorinated aliphatic hydrocarbon or 2) an alicyclic ether is used as a solvent. This invention also provides a polycarbodiimide solution with excellent stability in preservation.Type: GrantFiled: May 1, 1990Date of Patent: May 16, 1995Assignee: Nisshinbo Industries, Inc.Inventors: Satoshi Amano, Yasuo Imashiro
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Patent number: 5413724Abstract: The present invention relates to fiber treatment compositions comprising an unsaturated acetate, an organohydrogensiloxane, a metal catalyst, and a dispersant selected from the group consisting of one or more surfactants and one or more solvents. The compositions of the present invention impart beneficial characteristics such as slickness, softness, compression resistance and water repellency to substrates such as fibers and fabrics.Type: GrantFiled: December 30, 1993Date of Patent: May 9, 1995Assignee: Dow Corning CorporationInventors: Jeffrey A. Kosal, Anthony Revis
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Patent number: 5409620Abstract: The present invention relates to fiber treatment compositions comprising an unsaturated acetate, an organohydrogensiloxane, a metal catalyst, an organosilicon compound, and optionally a dispersant. The compositions of the present invention impart beneficial characteristics such as slickness, softness, compression resistance and water repellency to substrates such as fibers and fabrics.Type: GrantFiled: December 30, 1993Date of Patent: April 25, 1995Assignee: Dow Corning CorporationInventors: Jeffrey A. Kosal, Diane M Kosal, Anthony Revis
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Patent number: 5374707Abstract: New compounds including bis-.beta.-hydroxy ethyl bibenzoate containing less than 2.5%, and preferably less than 1%, diethylene glycol and a process for the production of the bis-.beta.-hydroxy ethyl bibenzoate by the condensation of 4,4'-biphenyl dicarboxylic acid and ethylene glycol at low temperature and pressure in the presence of a catalyst are disclosed. Use of the compounds to produce polyesters is also disclosed.Type: GrantFiled: February 18, 1993Date of Patent: December 20, 1994Assignee: Monsanto CompanyInventors: Jawed Asrar, David J. Weinkauff, A. Hameed Bhombal
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Patent number: 5338794Abstract: A process for producing a high-molecular weight polycarbodiimide solution by subjecting isophorone diisocyanate, 4,4'-dicyclohexylmethane diisocyanate, tetramethylxylylene diisocyanate or a mixture thereof to decarboxylation and condensation reaction in the presence of a carbodiimidization catalyst, in which process tetrachloroethylene, trichloroethylene, tetrachloroethane, trichloroethane or a mixture thereof is used as the polymerization solvent, the monomer concentration is 18% by weight or less, and the reaction temperature is 80.degree. C. or above.Type: GrantFiled: December 17, 1992Date of Patent: August 16, 1994Assignee: Nisshinbo Industries, Inc.Inventors: Yasuo Imashiro, Ikuo Takahashi
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Patent number: 5326844Abstract: A primer composition has blended therein an organic silicon compound having in a molecule at least one group of the formula: ##STR1## wherein R.sup.1 is a monovalent hydrocarbon group or a group represented by QSi( R.sup.4 O).sub.a (R.sup.5).sub.3-a, Q is a divalent organic group, R.sup.4 and R.sup.5 each are a monovalent hydrocarbon group, a is an integer of 0 to 3, R.sup.2 and R.sup.3 each are a hydrogen atom or a monovalent hydrocarbon group, and n is 0, 1 or 2. The primer composition is a useful adhesive since it is effective for joining silicone elastomers and similar adherends to supports such as paint coated metals and resins.Type: GrantFiled: April 7, 1993Date of Patent: July 5, 1994Assignee: Shin-Etsu Chemical Company, LimitedInventors: Hironao Fujiki, Masanobu Miyakoshi, Takeo Yoshida, Yoshifumi Inoue, Masatoshi Arai
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Patent number: 5288794Abstract: A cyanoacrylate monomer adhesive formulation which has improved thermal properties resulting from the inclusion in the formulation of an effective amount for enhancing the thermal resistance of the cured polymer of a mono, poly or hetero aromatic compound characterized by at least three substitutions on an aromatic ring thereof, two or more of said substitutions being electron withdrawing groups selected from the group consisting of NO.sub.2, CN, CF.sub.3, NR.sup.1.sub.3.sup.+, SR.sup.1.sub.2.sup.+, C(.dbd.O)R.sup.1, C(.dbd.O)OR.sup.1, NO, CCl.sub.3, SO.sub.2, S(.dbd.O), SO.sub.3, SO.sub.2 R.sup.1, SO.sub.2 OR.sup.1 and F, one or more of said substitutions being leaving groups selected from the group consisting of F, Br, Cl, I, NO.sub.2, CN, SOR.sup.1, SO.sub.2 R.sup.1 and SO.sub.2 OR.sup.1, and R.sup.1 is an optionally substituted hydrocarbon group. Example such compounds have the formula: ##STR1## where L is the leaving group and the W groups are the electron withdrawing groups.Type: GrantFiled: October 23, 1992Date of Patent: February 22, 1994Assignee: Loctite CorporationInventor: Shabbir Attarwala
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Patent number: 5286787Abstract: Moisture-curing jointing and sealing compounds containing polyurethane prepolymers are made more stable to weathering conditions by addition thereto of a reactive polysiloxane containing one or more functional groups which react with the polyurethane propolymers.Type: GrantFiled: June 26, 1992Date of Patent: February 15, 1994Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Tore Podola, Martin Majolo
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Patent number: RE39182Abstract: A process for the preparation of polyoxymethylene copolymers, wherein 1,3,5-trioxane is polymerized with generally known comonomers in the presence of a strong protonic acid initiator and in the presence of a formaldehyde dialkyl acetal, and wherein the initiator is dissolved in the formaldehyde dialkyl acetal before admixing to the trioxane and the comonomers.Type: GrantFiled: November 30, 2001Date of Patent: July 11, 2006Assignee: Ticona GmbHInventors: Karl-Friedrich Mück, Horst Röschert, Robert M. Gronner, Satyajit Verma, Michael G. Yearwood